CN1098350C

CN1098350C - Fabric softening compound/composition

Info

Publication number: CN1098350C
Application number: CN97194864A
Authority: CN
Inventors: E·H·瓦尔; T·特林; E·P·戈瑟林克; J·C·勒顿; M·R·思维克
Original assignee: Procter and Gamble Co
Current assignee: Procter and Gamble Co
Priority date: 1996-03-22
Filing date: 1997-03-05
Publication date: 2003-01-08
Anticipated expiration: 2017-03-05
Also published as: CN1219953A; CA2249587A1; JP3102894B2; AU2066597A; EP0888424A1; CA2249587C; BR9710409A; WO1997034972A1; JPH11507095A; TR199801784T2; CZ304798A3

Abstract

Fabric softening actives having hydrophobic moieties containing, preferably, ester, or amide, linkages and mixed branched and unsaturated hydrophobic groups provide improved processing and stability as well as surprisingly good softening. Preferred compositions contain mono-ol and diol principal solvents having a ClogP of from about 0.15 to about 0.64, that have the ability to make clear aqueous fabric softener compositions containing relatively high concentrations of the said fabric softener actives having ester linkages in their long, hydrophobic chains. Other solvents may be present. Premixes of the fabric softening actives, the principal solvents, and, optionally, other solvents are useful in the preparation of complete formulations by obviating/limiting the need for heating. Other compositions can be prepared which are solid or dispersions of the said fabric softening actives.

Description

Fabric soft compound/composition

Technical field

The present invention relates to fabric soft compound and/or composition, they are preferred for preparing and are applicable to the translucent of soft fabric, and are perhaps preferably transparent, water base concentrated liquid soft compound.The present invention be more particularly directed to fabric soft compound and/or composition, they are fit to the textiles soft compound that preparation is used for textile washing operation rinse stage, so that good fabric sofetening/Electrostatic Control effect to be provided, the feature of said composition comprise fabric for example stain reduce, good water-dispersible, rewetting and/or storage and viscosity stability under subnormal temperature (that is, temperature is lower than normal room temperature as 25 ℃).

Background of invention

The present technique field discloses transparent concentrated fabric conditioner preparation.For example, european patent application 404,471 (Machin etc. announce December 27 nineteen ninety) is mentioned the isotropic liquid soft compound that contains at least 20% weight softening agent and at least 5% weight short chain organic acid.

The invention provides fabric softener active matter, it is fit to formulation example such as spissated, preferably transparent and water base, liquid textile treatment composition preferably has the organic solvent (that is, be lower than composition weight about 40%) of low levels, said composition is under normal (being room temperature) and subnormal temperature, stability improves (that is, keep transparent or semitransparent, do not precipitate, gelling, retrogradation or curing) under the standing storage condition.Said composition also demonstrates fabric and stains minimizing, good cold water-dispersible, and good softnessization, antistatic and fabric rewetting performance, and the accumulation of the residue of distribution device reduces and good freeze-thaw restorability.But,, need a kind of fabric softener active matter with relative current volume property in order to prepare this based composition.This class softening agent actives can still have a lot of problems with this material with highly undersaturated material preparation, comprises their chemical instability and generally effective not as the soft effect of saturate.

Brief summary of the invention

It is biodegradable being used for fabric softener active matter of the present invention, and contains ester bond in long hydrophobic chain.They comprise side chain and undersaturated acyl chain.Specifically, this actives preferably has following chemical formula:

1.[(R) _4-m-N ⁽⁺⁾-[(CH ₂) _n-Y-R ¹] _m] X ^(-)(1) wherein each R substituting group is hydrogen or short chain C ₁-C ₆, preferred C ₁-C ₃Alkyl or hydroxyalkyl, for example methyl (most preferably), ethyl, propyl group, hydroxyethyl etc., benzyl or their mixture; Each m is 2 or 3, preferred 2; Each n is from 1 to about 4, preferred 2; Each Y is-O-(O) C-,-(R) N-(O) C-,-C (O)-N (R)-or-C (O)-O-, preferred-O-(O) C-; Each R ¹In the carbonatoms summation, when Y be-O-(O) C-or-(R) add 1 (" YR during N-(O) C- ¹Summation ") be C ₆-C ₂₂, preferred C ₁₂-C ₂₂, more preferably C ₁₄-C ₂₀(hereinafter, R ¹And YR ¹Be used for representing hydrophobic chain convertibly, R ¹Chain length is an even number for Fatty Alcohol(C12-C14 and C12-C18) generally, is odd number to lipid acid), but summation is less than the YR of about 12 carbon atoms ¹Be no more than 1, and other R ¹Or YR ¹It is about 16 that summation is at least, each R ¹Contain long-chain C ₅-C ₂₁(or C ₆-C ₂₂), preferred C ₁₀-C ₂₀(or C ₉-C ₁₉) branched-alkyl or unsaturated alkyl, most preferably C ₁₂-C ₁₈(or C ₁₁-C ₁₇) branched-alkyl or unsaturated alkyl, branched-alkyl is about 95 with the ratio of unsaturated alkyl: about 5: 95 of 5-, and preferably from about 75: 25 to about 25: 75, more preferably from about 50: 50 to about 30: 70, and for unsaturated alkyl, this R ¹The iodine number of the maternal fatty acid of base is preferably about 20-about 140, more preferably about 50-about 130, (used here " branched-alkyl " comprises the group that is connecting hydrophobic substituent on those main chains most preferably to be about 70-about 115, even these substituting groups are by non-C-C, for example oxygen is connected with main chain, as alkoxy substituent, and the iodine number of " parent " lipid acid or " accordingly " lipid acid is to be used for defining R ¹The degree of unsaturation of group, this degree of unsaturation with contain same R ¹The degree of unsaturation of the lipid acid of base is identical.As an independent R ¹Be branching, when being unsaturated again, with its processing as branching); Gegenion X wherein ^-Can be any negatively charged ion compatible with softening agent, preferred chlorine, bromine, methylsulfate, ethyl sulphate, sulfate radical and/or nitrate radical, more preferably chlorine.

2. the softening agent that has following chemical formula:

Wherein each Y, R, R ¹And X ^(-)Definition the same (this compounds comprises the compound that chemical formula is following:

[CH ₃] ₃N ⁽⁺⁾[CH ₂CH (CH ₂O (O) CR ¹) O (O) CR ¹] Cl ^(-)Wherein-O-(O) CR ¹A part is derived from unsaturated fatty acids, as oleic acid, and also each R preferably methyl or ethyl, each R ¹Preferably at C ₁₅-C ₁₉Scope in, have the degree of branching and substitution value in this hydrocarbyl chain, another part is then derived from branched chain fatty acid, as Unimac 5680); With

3. their mixture.

The present composition preferably contains: A. accounts for about 80%, preferred about 75%, about 70%, the biodegradable fabric softener active matter of about 19-about 65% preferably of 15-more preferably from about of about 13-of the about 2-of composition weight, is selected from following compound:

1. the softening agent that has following chemical formula:

[(R) _4-m-N ⁽⁺⁾-[(CH ₂) _n-Y-R ¹] _m] X ^(-)(1) wherein each R substituting group is the hydrogen or the C of short chain ₁-C ₆, preferred C ₁-C ₃Alkyl or hydroxyalkyl, for example methyl (most preferably), ethyl, propyl group, hydroxyethyl etc., benzyl, or their mixture; Each m is 2 or 3, is preferably 2; Each n is 1 to about 4, preferred 2; Each Y is-O-(O) C-,-(R) N-(O) C-,-C (O)-N (R)-or-C (O)-O-, preferred-O-(O) C-; Each R ¹In the carbonatoms summation, when Y be-O-(O) C-or-(R) add 1 during N-(O) C-, be C ₆-C ₂₂, preferred C ₁₂-C ₂₂, more preferably C ₁₄-C ₂₀But summation is less than the R of about 12 carbon atoms ¹Or YR ¹Can not surpass 1, and other R ¹Or YR ¹It is about 16 that summation is at least, each R ¹Be long-chain C ₅-C ₂₁(or C ₆-C ₂₂), preferred C ₉-C ₁₉(or C ₁₀-C ₂₀) or more preferably C ₁₁-C ₁₇(or C ₁₂-C ₁₈) branched-alkyl and unsaturated alkyl (alkenyl for example, sometimes be also referred to as " alkylene ", comprise polyunsaturated alkyl), branched-alkyl is from about 5: 95 to about 95: 5 with the ratio of unsaturated alkyl, preferably from about 75: 25 to about 25: 75, more preferably from about 50: 50 to about 30: 70, for unsaturated alkyl, this R ¹It is about 140 that the iodine number of the maternal fatty acid of group is preferably about 20-, and more preferably from about 50-is about 130, and most preferably from about 70-about 115; And gegenion X wherein ^-Can be any negatively charged ion compatible with softening agent, preferred chlorine, bromine, methylsulfate, ethyl sulphate, sulfate radical and/or nitrate radical, more preferably chlorine.

2. the softening agent of following chemical formula: Wherein each Y, R, R ¹And X ^(-)Has aforesaid identical definition; With

3. their mixture.

(in a kind of preferred biodegradable quaternary amines fabric soft compound, C (O) R ¹A part is derived from unsaturated fatty acids, oleic acid for example, and/or the lipid acid and/or the partially hydrogenated lipid acid of deriving and forming from vegetables oil and/or partially hydrogenated vegetables oil (as Tower rape oil, Thistle oil, peanut oil, Oleum Helianthi, soya-bean oil, Semen Maydis oil, Yatall MA, rice bran wet goods); A part is derived from branched chain fatty acid, as Unimac 5680.) (hereinafter, these biodegradable fabric softener active matters that contain the fat key are known as " DEQA ", and it comprises diester, three esters and the monoester compound that contains 1-3, preferred 2 long-chain hydrophobic groups.Corresponding amide softening agent actives and blended ester-acid amide softening agent actives also can contain 1-3, preferred 2 long-chain hydrophobic groupings).B. randomly, but preferably, also contain in the composition less than about 40%, preferred about 10-about 35%, more preferably from about 12-about 25%, the main solvent of about 20% weight of preferably about 14-, its Clog P is about 0.15-about 0.64, be preferably about 0.25-about 0.62, more preferably about 0.40-about 0.60, this main solvent is when using separately, preferably contain and be selected from 2,2,4-trimethylammonium-1, the 3-pentanediol, 2,2,4-trimethylammonium-1, the ethoxylate of 3-pentanediol, diethoxy thing or triethoxy compound derivative, with and/or 2-ethylhexyl-1, the solvent of 3-glycol and their mixture, its quantity not sufficient is to form transparent product, preferably be not enough to form stable product, more preferably being not enough to produce noticeable variation aspect the physical property of composition, preferably do not change fully especially, described main solvent is preferably selected from the compound that illustrates later.C. randomly, but preferably, be enough to improve the low-molecular weight water-soluble solvent of effective quantity of transparency, for example ethanol, Virahol, propylene glycol, 1, ammediol, Texacar PC etc., the content of this water-soluble solvent can not form clear composition by himself; D. randomly, but preferably, the water-soluble Ca salt of effective quantity of enhancing the transparency and/or magnesium salts, preferred muriate; Water with the E. equal amount.

Preferably, the present composition is to contain about 95%, preferred about 80%, about 40%, preferred about 35%, about 25%, the composition of the above-mentioned alcohols main solvent B of about 14-about 20% water base, translucent or transparent (preferably transparent) preferably of 12-more preferably from about of about 10-of 30-water about 70%, preferably about 40-about 60% and about 3-more preferably from about of about 10-of the 3-that has an appointment, and these preferred products (composition) are not if no main solvent B then is translucent or transparent.For the quantity that makes composition become translucent or transparent, required main solvent B preferably surpasses 50% of organic solvent total content, more preferably surpass approximately 60%, preferably surpass about 75%.

Said composition also can be prepared into and contain about 50%, preferred about 40%, the fabric softener active matter dispersion of the routine of the fabric softener active matter of 15-about 30% more preferably from about of about 10-of the 2-that has an appointment.As hereinafter disclosed, composition can also be prepared into or particulate state or attached to the solid on the carrier.

It is about 7 that the pH of this aqueous composition should be about 1-, and preferably about 1.5-is about 5, and more preferably from about 2-about 3.5. Detailed Description Of The Invention The fabric sofetening actives

The present invention relates to fabric sofetening actives and composition, said composition contain as basal component, account for the about 2-80% of composition weight, preferably about 13-75%, more preferably from about 15-70%, the described fabric sofetening actives of about 19-65% preferably, compound of determining below this actives is selected from and composition thereof.

(A) diester quaternary amines fabric sofetening active compound (DEQA)

(1) first kind DEQA preferably contains the following formula: compound as main actives:

[(R) _4-m-N ⁽⁺⁾-[(CH ₂) _n-Y-R ¹] _m] X ^(-)(1) wherein each R substituting group is the C of hydrogen or short chain ₁-C ₆, preferred C ₁-C ₃Alkyl or hydroxyalkyl, for example methyl (most preferably), ethyl, propyl group, hydroxyethyl etc., benzyl, or its mixture; Each m is 2 or 3; Each n is from 1 to about 4, preferred 2; Each Y is-O-(O) C-,-(R) N-(O) C-,-C (O)-N (R)-or-C (O)-O-, preferred-O-(O) C-; Each R ¹In the carbon atom summation, when Y be-O-(O) C-or-(R) add 1 during N-(O) C-, be C ₆-C ₂₂, preferred C ₁₂-C ₂₂, more preferably C ₁₄-C ₂₀But summation is less than about 12 R ¹Or YR ¹Be no more than one, and other R ¹Or YR ¹Summation is at least about 16, each R ¹Be long-chain C ₅-C ₂₁(or C ₆-C ₂₂), preferred C ₉-C ₁₉(or C ₉-C ₂₀), C preferably ₁₁-C ₁₇(or C ₁₂-C ₁₈), branched-chain alkyl and unsaturated alkyl (comprising many unsaturated alkyls), branched-chain alkyl is from about 5: 95 to about 95: 5 with the ratio of unsaturated alkyl, preferably from about 75: 25 to about 25: 75, more preferably from about 50: 50 to about 30: 70, especially 35: 65, and for unsaturated alkyl, this R ¹The R of the maternal fatty acid of base ¹Iodine number to be preferably about 20-about 140, more preferably about 50-is about 130, most preferably is about 70-about 115; Gegenion X wherein ^-Can be any negatively charged ion compatible with softening agent, preferred chlorine, bromine, methylsulfate, ethyl sulphate and/or nitrate radical, more preferably chlorine;

2. the softening agent of following chemical formula Wherein each Y, R, R ¹And X ^(-)Have aforesaid identical meanings (this compounds comprises the compound of following chemical formula:

[CH ₃] ₃N ⁽⁺⁾[CH ₂CH (CH ₂O (O) CR ¹) O (O) CR ¹] Cl ^(-)Wherein-O-(O) CR ¹A part is derived from undersaturated lipid acid, oleic acid for example, and preferably each R is methyl or ethyl, each R ¹Preferably at C ₁₅-C ₁₉In the scope, in this hydrocarbyl chain, there are the degree of branching and substitution value; A part is then derived from branched chain fatty acid, as Unimac 5680); With

3. their mixture.

Above gegenion X ^(-)Can be any negatively charged ion compatible with softening agent, the negatively charged ion of preferred strong acid, for example chlorine, bromine, methylsulfate, ethyl sulphate, sulfate radical, nitrate radical etc., more preferably chlorion.Negatively charged ion also can be with two electric charges, at this moment X ^(-)Represent half of group, but this situation is not too desirable.

Fabric softener active matter can comprise and contains branching and mixtures undersaturated several compounds respectively.The preferred biodegradable quaternary ammonium kind fabric softening compound thing that can be used for preparing this class mixture can contain group-O-(O) CR ¹This group derives from undersaturated and polyunsaturated lipid acid, as oleic acid, with and/or partially hydrogenated lipid acid, this partially hydrogenated fatty acid derived is from vegetables oil and/or partially hydrogenated vegetable oil (as low leaf mustard seed oil, Thistle oil, peanut oil, Oleum Helianthi, Semen Maydis oil, soybean oil, Yatall MA, rice bran wet goods).Can use and preferably use the mixture of unsaturated fatty acids and the mixture of the DEQA that derives from different unsaturated fatty acidss.The limiting examples of the DEQA that is made by preferred unsaturated fatty acids is later with DEQA ¹To DEQA ⁸Explanation.

DEQA ⁶By soya fatty acid preparation, DEQA ⁷By slight hydrogenant tallow fatty acid preparation, and DEQA ⁸By the low mustard seed fatty acid oil preparation of slight hydrogenant.

With the R that contains side chain ¹Base (for example derives from the R of Unimac 5680 ¹Base, side chain is as R ¹At least a portion of base) DEQA that makes has constituted another part of mixture.Also preferred fabric softening agent actives itself contains blended side chain and unsaturated R ¹The compound of base.It is about 95% to be generally about 5-by the actives total amount of branched group representative, and preferably about 25-is about 75%, and more preferably from about 35-about 50%.

Be applicable to the branched chain fatty acid of preparation branched-alkyl or branched-alkyl and unsaturated alkyl blended DEQA, preparation can in all sorts of ways.Corresponding branched fatty alcohol can be by using standard reaction, for example according to the method (JACS (J.Amer.Chem.Soc.) (1970) of Brown 92, 1637) with borine-THF branched chain fatty acid is reduced, make.Above-mentioned document is quoted as a reference at this paper.It below is the limiting examples of branched chain fatty acid. Branched chain fatty acid 1:2-n-heptyl undecanoic acid

2-n-heptyl undecanoic acid (22890-21-7) can be obtained (production code member IO 281) by TCI America.It can be obtained by the oxidation of Guerbet alcohol 2-heptyl hendecanol, and should alcohol be the aldol condensation product of aldehyde C-9.Guerbet alcohol can be buied by Condea, trade name ISOFOL ^Alcohol. Branched chain fatty acid 2:2-n-hexyl capric acid

2-n-hexyl capric acid (25354-97-6) can be obtained production code member H0507 by TCI America.It can obtain by the oxidation of Guerbet alcohol 2-hexyl decyl alcohol, and this alcohol is again the aldol condensation product of octanal. Branched chain fatty acid 3:2-normal-butyl is sad

The 2-normal-butyl is sad can be obtained trade name ISOCARB by Union Carbide ^12 acid.It can be by obtaining the oxidation of Guerbet alcohol 2-butyl octanol. Branched chain fatty acid 4:5,7,9-trimethylammonium n-nonanoic acid

5,7,9-trimethylammonium n-nonanoic acid and 3,5,7,9-tetramethyl-n-nonanoic acid are to learn magazine 1981 with N.E.Lawson etc. U.S. oiling scholar by Union CampCorporation, 58, the oxo synthesis of describing in 59 makes. Branched chain fatty acid 5: alpha-alkyl carboxylic acid

RR ¹CHCO ₂H

Alpha-substitution acid can be by carrying out the C-alkylation and prepare from linear chain aldehyde (as octanal or capraldehyde) the derive enamine that forms.The deutero-enamine will form carbanion on the carbon atom that to terminal N is the α position.Enamine negatively charged ion and alkyl bromide react in the presence of the NaI of catalytic quantity, obtain the enamine of side chain, and it generates alpha-alkyl aldehyde when hydrolysis.This aldehyde can be subsequently oxidized to corresponding carboxylic acid. α-heptyl capric acid

Capraldehyde can with excessive cyclammonium (as tetramethyleneimine) in toluene in the presence of the trace equal toluene azochlorosulfonate acid heating of rotation stream react.The water that forms owing to amine and aldehyde condensation can lead to rotation stream to be removed through water trap.After the water of having removed theoretical quantity, can add heptyl bromine and sodium iodide, in same solvent system, finish alkylation.In alkylation (spending the night) afterwards, reaction mixture is poured in the ice and made and be acid with 20%HCl.This hydrolysis reaction changes into α-heptyl capraldehyde with the alkylation enamine.Product can separate with solvent layer by separating, wash with dry, removes solvent with vacuum distillation method subsequently.

Isolated branched chain aldehyde can change into desired carboxylic acid by oxidation in the appropriate solvent system subsequently.The example of oxygenant comprises: potassium permanganate solution; Jones reagent (CrO ₃/ H ₂SO ₄/ H ₂O)/acetone; CrO ₃-acetate etc.Adding high-molecular weight acid can help desired α-heptyl capric acid to separate with oxidizing medium. Branched chain fatty acid 6:9-and 10-alkoxyl group octadecanoic acid, other positional isomers with mutually The alkoxyl group Stearyl alcohol of answering

9-and 10-methoxyl group octadecanoic acid: according to Siouffi etc. at chemistry of lipids and physics (Chemistry and Physics of Lipids) (1972) 8 (2), the method described in the 91-101.Be dissolved in a Witconol 2301 of about 5g in about 8g methyl alcohol and with the processing of the hypobromous acid tert-butyl ester to obtain blended methoxyl group br-derivatives.With its separation and with the debrominate of Rany catalyzer, isolate crude acid after the acidifying.Carry out the hydrogenation of olefinic component in the crude acid in hexanaphthene with platinum oxide, this has produced the crude mixture of desired 9-and 10-methoxyl group octadecanoic acid.

9-and 10-isopropoxy octadecanoic acid: adopt same step, just in bromination step, replace methyl alcohol with the 2-propyl alcohol.This has produced desired 9-and 10-isopropoxy octadecanoic acid.

The positional isomers of alkoxyl group octadecanoic acid: adopt same step, but, oleic acid is isomerizated into the mixture of unsaturated acid earlier by heating with methylsulfonic acid.In this case alkoxyl group bromination-reduction sequence has formed the mixture of the other positional isomers of alkoxyl group octadecanoic acid.

Corresponding Fatty Alcohol(C12-C14 and C12-C18): according to the method for Brown (JACS (J.Amer.Chem.Soc.) (1970), 92, 1637) and with borine-THF the octadecanoic acid that replaces is reduced into corresponding Stearyl alcohol. Branched chain fatty acid 7: phenyl octadecanoic acid, alkyl phenyl octadecanoic acid and corresponding Stearyl alcohol

The phenyl octadecanoic acid: use Nakano and Foglia to understand will (J.Amer.Oil.Chem.Soc.) (1984) U.S. oiling scholar 61(3) method of describing among the 569-73.The oleic acid of a approximately 5g and about 6.91g benzene are dropwise handled with about 10.2g methylsulfonic acid down at about 50 ℃, and stir about is 6 hours subsequently.Reaction mixture is added in the water, uses extracted with diethyl ether.The vacuum desorption method removes solvent, obtains the crude mixture of phenyl octadecanoic acid positional isomers.

The aminomethyl phenyl octadecanoic acid: repeat above-mentioned synthesizing, but replace benzene to obtain the mixture of aminomethyl phenyl octadecanoic acid positional isomers with toluene.

Corresponding Stearyl alcohol: with the octadecanoic acid that replaces according to the method for Brown (JACS (J.Amer.Chem.Soc.) (1970), 92, 1637) and be reduced into corresponding Stearyl alcohol with borine-THF. Branched chain fatty acid 8: phenoxy group octadecanoic acid, hydroxy phenyl octadecanoic acid and corresponding Stearyl alcohol

The hydroxyphenyl octadecanoic acid: use Nakano and Foglia to understand will (J.Amer.Oil.Chem.Soc.) (1984) U.S. oiling scholar 61(3) method described in the 569-73.Oleic acid, phenol and the methylsulfonic acid of about 1: 5: 6 mol ratio were reacted 48 hours down at about 25 ℃.Reaction mixture added use extracted with diethyl ether in the entry.Extract is removed solvent and phenol, obtain desired hydroxyphenyl octadecanoic acid positional isomers and slightly mix thing.

The phenoxy group octadecanoic acid: repeat above-mentioned reaction, but use mol ratio to be about 1: 5: 2 oleic acid, phenol and methylsulfonic acid.Isolated crude product mainly is the phenoxy group octadecanoic acid, but also contains the hydroxyphenyl octadecanoic acid.Obtain the mixture of the phenoxy group octadecanoic acid positional isomers of purifying with chromatography.

Corresponding Stearyl alcohol: according to the method for Brown (JACS (1970), 92, 1637) and with borine-THF the octadecanoic acid that replaces is reduced into corresponding Stearyl alcohol. Branched chain fatty acid 9: Unimac 5680

Unimac 5680 is the United States Patent (USP) 2,812,342 that is presented to R.M.Peters according to November 5 nineteen fifty-seven, by at undersaturated C ₁₈The monomer acids that obtains in the lipid acid dimerization reaction makes, and above-mentioned patent is quoted as a reference in this article.

Can mix the suitable branching fabric sofetening actives that forms fabric sofetening actives of the present invention with above-mentioned undersaturated fabric sofetening actives (DEQA), can form with above branched chain fatty acid and/or corresponding branched fatty alcohol.Similarly, branched chain fatty acid and/or alcohol can use with unsaturated fatty acids and/or alcohol, form suitable combination chain actives.Hereinafter as DEQA ¹⁰-DEQA ²⁵The specific examples of the disclosed DEQA that contains side chain can with undersaturated DEQA blending.DEQA ¹⁰-DEQA ¹²Be to prepare by different commercially available Unimac 5680s.

As mentioned before, other preferred DEQA is those DEQA that make with in the blend (total fatty acids blend) of single DEQA form by all the various side chains listed and unsaturated fatty acids, rather than obtains in the blend of the mixture of each the finished product DEQA that is made by the different piece of total fatty acids blend.

The fatty acyl group that preferably has quite big percentage ratio at least is undersaturated, for example about 25-70%, preferably about 50-about 65%.Can use the polyunsaturated fatty acid base.The actives total concn (TPU) that contains the polyunsaturated fat acyl group can be about 30% for about 3-, and preferably about 5-is about 25%, and more preferably from about 10-about 18%.Cis and trans-isomer(ide) all can be used, and preferably suitable/reverse proportionality is 1: 1 to about 50: 1, and Schwellenwert is 1: 1, and preferably at least 3: 1, (said contain given R here more preferably from about 4: 1 to about 20: 1 ¹" the softening agent actives percentage ratio " of base and same R ¹Group is with respect to the whole R that are used for forming all softening agent activess ¹The percentage composition of group is identical).

Before this and hereinafter discussed undersaturated, comprise polyunsaturated fatty acyl group; when using with the side chain fatty acyl group; provide effective softness to turn usefulness into astoundingly; but also good rewetting characteristic, good antistatic property are provided; especially, excellent freezing-restorability after thawing.

This blended side chain is prepared than conventional saturated straight chain fabric softener active matter easily with unsaturated materials.They can be used for forming and keep its low viscous dense pre-composition, therefore process for example pumping, mixing etc. easily.These materials are if only contain usually a small amount of and its bonded solvent, that is, it is about 20% to account for about 5-of softening agent/solvent mixture gross weight, preferably about 8-about 25%, more preferably from about 10-is about 20%, even then also be mixed with dense, the stable present composition at ambient temperature easily.This ability of at low temperatures actives being processed is for many unsaturated groups particularly important, because it has reduced degraded.As described later, when containing good antioxidant, sequestrant and/or reductive agent in compound and the softener composition, can provide other anti-degraded provide protection.The use of side chain fatty acyl group has improved anti-degradation capability when keeping mobile and improving soft voltinism energy.

The present invention can also comprise the biodegradable quaternary ammonium type fabric soft compound of some medium chain DEQA, and they have above-mentioned chemical formula (1) and/or following chemical formula (2), wherein:

Each Y is-O-(O) C-or-C (O)-O-, preferred-O-(O) C-;

M is 2 or 3; Preferred 2;

Each n is 1-4, preferred 2;

Each R substituting group is C ₁-C ₆Alkyl (preferable methyl, ethyl, propyl group), benzyl and their mixture, more preferably C ₁-C ₃Alkyl;

Each R ¹Or YR1 contains the alkyl or the saturated C of the hydrocarbyl substituent of replacement ₈-C ₁₄, preferred C _12-14Hydrophobic group, (IV preferably about 10 or littler is more preferably less than about 5), (the carbon atom summation in the acyl group, when Y be-O-(O) C-or-(R) R during N-(O) C- ¹+ 1) and gegenion X ^-Same as described above.Best X ^-Do not comprise phosphoric acid salt.

Saturated C ₈-C ₁₄Fatty acyl group can be pure derivative, or can have the mixing chain length.

The suitable fat acid source of described fatty acyl group has coconut acid, lauric acid, sad and capric acid.

For C ₁₂-C ₁₄(or C _11-13) alkyl, this group is preferably saturated, and for example, iodine number is preferably less than about 10, preferably less than about 5.

Should be clear, the R of branching ¹Substituting group can contain various groups, for example plays the alkoxyl group of branching, and the straight chain of very little percentage composition can be arranged, as long as R ¹Base keeps its hydrophobic basically characteristic.Admissible preferred compound is a kind of widely used fabric softener: the biodegradable diester variations of hardened chlorination ditallow dimethylammonium (being called " DTDMAC " later on).

As used in this article, when the regulation diester, it can comprise the monoesters of existence.Preferably, the DEQA at least about 80% is a diester form, and 0 to about 20% can be the DEQA monoesters, for example, and a YR ¹Group is-OH or-C (O) OH, and for formula 1, m is 2.Corresponding diamide and/or blended ester-acid amide also can comprise the actives that has a long-chain hydrophobic group, for example, and a YR ¹Group is-N (R) H or-C (O) OH.Hereinafter, for any explanation of monoesters actives, content for example is also applicable to the monoamide actives.For softnessization, do not having/wash conditions that seldom washing composition is taken out of under, the percentage composition of monoesters should be low as far as possible, preferably is no more than about 5%.But under the high condition of anionic detergent tensio-active agent or detergent builder drag-out, some monoesters is desirable.The overall proportion of diester and monoesters is from about 100: 1 to about 2: 1, preferably from about 50: 1 to about 5: 1, more preferably from about 13: 1 to about 8: 1.Taking out of under the high detergent amount condition, diester/monoesters ratio is preferably about 11: 1.The content of monoesters can be controlled when making DEQA.

As the explanation of back example, as the above compound of biodegradable quaternized ester-amine softnessization material, can prepare in the embodiment of this invention with the reactive chemistry of standard.In a kind of synthetic method of the diester variations of DTDMAC, formula RN (CH ₂CH ₂OH) ₂Amine be R all at two hydroxyl places with chemical formula ¹The chloride of acid esterification of C (O) Cl is to form a kind of amine, and this amine can become cationic (R is H) by acidifying, and this is a class softening agent, or makes it quaternized with alkylogen RX subsequently, forms desired reaction product (wherein R and R ¹Definition is the same).But chemical field the professional will appreciate that, this reaction sequence can be prepared the reagent of extensive selection.

Be fit to preparation fabric sofetening actives of the present invention and have above chemical formula (1) with the another kind of DEQA softening agent actives that concentrates transparent liquid fabric softener composition, one of them R base is C _1-4Hydroxyalkyl, preferably one of them R base is a hydroxyethyl.

(2) second class DEQA activess have following general formula:

Wherein each Y, R, R ¹And X ^(-)Has above identical meanings.This compounds comprises the compound that chemical formula is following:

[CH ₃] ₃N ⁽⁺⁾[CH ₂CH (CH ₂O (O) CR ¹) O (O) CR ¹] Cl ^(-)Wherein each R is methyl or ethyl, preferably each R ¹Be C ₁₅-C ₁₉In alkyl chain or unsaturated alkyl chain, can there be substitution value.Negatively charged ion X in the molecule ^(-)Identical with among the above DEQA (1).As using in this article, when specifying diester, it can comprise the monoesters of existence.The monoesters quantity that can exist identical with in DEQA (1).The example of preferred formula (2) DEQA is that chemical formula is chlorination 1, " propyl group " ester quaternary ammonium fabric of 2-two (acyloxy)-3-front three aminopropane soft actives, wherein acyl group and DEQA ⁵Identical, the back is exemplified as DEQA ⁹

The reagent of these types and general preparation method thereof are disclosed in the United States Patent (USP) 4,137,180 that was presented to Naik etc. on January 30th, 1979, and this patent is quoted as a reference at this paper.

In suitable softening agent actives (1) and (2), each R ¹Be the alkyl of branching, monounsaturated alkyl or polyunsaturated alkyl; The branched-alkyl and the unsaturated alkyl R that contain aforementioned ratio in the actives ¹Mixture, especially at one intramolecularly.

The DEQA of this paper can have the lipid acid of low levels, and it can be from any part degraded (hydrolysis) by product of softening agent actives in unreacted initiator that is used for forming DEQA and/or the final product composition having.The content of free fatty acids is preferably lower, preferably is lower than the about 10% of softening agent actives weight, more preferably less than about 5%.II. the main solvent system that optional (but preferred) exists

The present composition contains and accounts for about below 40%, preferred about 35%, about 25%, the main solvent of about 14-about 20% preferably of 12-more preferably from about of about 10-of composition weight.Selected main solvent will make solvent smell minimum in composition, and makes final composition have low viscosity.For example, Virahol is not very effective and the intensive smell is arranged.N-propyl alcohol is comparatively effective, but tangible smell is also arranged.Several butanols are scent of also, but because effectively the transparency/stability is especially used to reduce its smell as the part of main solvent system so can use.Selection to alcohols also comprises best low-temperature stability, that is, still to form under about 40 °F (about 4.4 ℃) be the composition of liquid being low to moderate for they, and it has acceptable low viscosity and translucent, preferably transparent, and after being low to moderate about 20 (about 6.7 ℃) following storage, can restore.

Preferably the main solvent content in the present composition is remained on to obtaining the minimum level of translucency or transparent actual capabilities.The existence of water is for for the required main solvent of these compositions transparencys of realization material impact being arranged.Water-content is high more, and is high more for reaching the transparent required main solvent content of composition (with respect to softening agent content).Otherwise water-content is few more, and the main solvent (with respect to softening agent) that needs is few more.For example, under the low water content of about 5-about 15%, softening agent actives/main solvent weight ratio is preferably about 55: 45 to about 85: 15, more preferably from about 60: 40 to about 80: 20.Under the water-content of about 15-about 70%, softening agent actives/main solvent weight ratio is preferably about 45: 55 to about 70: 30, more preferably from about 55: 45 to about 70: 30.But under the high water content of about 70-about 80%, softening agent actives/main solvent weight ratio is preferably about 30: 70 to about 55: 45, more preferably from about 35: 65 to about 45: 55.Under higher water-content, the ratio of softening agent/main solvent also should be higher.

For preparation have requirement stability liquid state of the present invention, concentrate, the fabric softener composition of preferably transparent, the suitability of any main solvent all is optionally astoundingly.Suitable solvent can be selected according to its octanol/water partition ratio (P).The octanol/water partition ratio of main solvent be its equilibrium concentration in octanol with in water ratio.The partition ratio of main solvent component of the present invention is represented their denary logarithm log P forms easily.

The existing report of the log P of a lot of components, for example, can be from Daylight Chemical Information System company (Daylight CIS), Irvine, Califonia, Pomona 92 databases that obtain comprise a lot of data and have quoted original.But log P value most convenient ground is to calculate with " CLOG P " program, and this program also can obtain from Daylight CIS.This program has also been listed the log P experimental value that has in the Pomona92 database." the log P of calculating " (Clog P) determines (referring to A.Leo with the segmentation method of Hansch and Leo, at " synthetic medicine chemistry " (Comprehensive Medicinal Chemistry) the 4th volume (C.Hansch, P.G.Sammens, J.B.Taylor and C.A.Ramsden compile), p 295, Pergamon Press, 1990, this paper quotes as a reference).Segmentation method is the chemical structure based on each component, and considers number and type, atom connectivity and the chemical bond of atom.These Clog P values are the most reliable and widely used estimated values for these physicochemical property, preferably use the experimental value of Clog P rather than log P when selecting to can be used for main solvent component of the present invention.Other method that can be used for calculating Clog P is included in chemical information and computational science magazine (J.Chem.Inf.Comput.Sci.) 27, the fragmented storage method of the Crippen described in 21 (1987); At chemical information and computational science magazine 29, the Viswanadhan fragmented storage method described in 163 (1989); With at European medicinal chemistry (Eur.J.Med.Chem.-Chim.Ther.) 19The method of Broto described in 71 (1984), the Clog P of selected main solvent should be about 0.15-about 0.64, preferred about 0.25-about 0.62, preferably about 0.40-about 0.60, this main solvent preferably is asymmetric to a certain degree at least, and preferably its fusing point (or solidification point) makes it be liquid state down near room temperature or room temperature.For some reason, lower molecular weight and biodegradable solvent also need.As if more asymmetric solvent is very desirable, and highly symmetric solvent is as 1,7-heptanediol or 1, two (methylol) hexanaphthenes of 4-, they have symmetry centre, show the composition that can not form substantial transparent when using separately, though its Clog P value is in the preferred value scope.

Most preferred main solvent can differentiate that this is to arrive with the cryogenic freezing electron microscopy observation after composition is diluted to the concentration of using in the rinsing by the appearance of softening agent vesica.It is the dispersion of fabric softener that these dilute compositions show, and its fabric softener composition than routine has more the unilamellar vesicle outward appearance.As if outward appearance is more near the individual layer system, and the performance of composition is good more.These compositions are compared with the analogous composition for preparing with same fabric softener active matter in the usual way, and good fabric sofetening effect is provided astoundingly.This composition is compared the deposition of also peculiarly having improved spices with the fabric sofetening composition of routine, especially when being added to spices in the composition under the temperature near room temperature or room temperature.

Under various layouts, list the available main solvent below, for example, had the aliphatic series and/or the alicyclic diol of given carbonatoms; Monohydroxy-alcohol; Glycerol derivative; The alcoxylates of dibasic alcohol; And the mixture of all above-mentioned substances.Preferred main solvent is marked with italic, and most preferred main solvent is then used boldface type.Reference number is chemical abstracts service's accession number (CAS No.) of those compounds of existing this number.New compound has the method for hereinafter described evaluation, and this method can be used to prepare this compound.Some inapplicable main solvent also is listed in following for comparing.But inapplicable main solvent can use as mixture with the main solvent that is suitable for.The available main solvent can be used for preparing the dense fabric softener composition that meets stability described herein/transparency requirement.

The glycols main solvent that much has same chemical formula can exist with multiple steric isomer and/or optically active isomer form.Each isomer is for example specified different CAS No. usually, 4-methyl-2, and the different isomer of 3-hexylene glycol has been specified following CAS No.:146452-51-9 at least; 146452-50-8; 146452-49-5; 146452-48-4; 123807-34-1; 123807-33-0; 123807-32-9; And 123807-31-8.

In following form, for simplicity, it only is exemplary that each chemical formula is only listed this explanation of a CAS No., and this is enough for enforcement of the present invention.This explanation is nonrestrictive.Therefore, in other isomer with different CAS No. and composition thereof is also included within certainly.By the same token, when certain CAS No. represents a branch period of the day from 11 p.m. to 1 a.m that contains specific isotope, for example deuterium, tritium, carbon-13 etc., be to be understood that then the isotopic material that contains natural distributed is also included within, vice versa.

Table I

Monohydroxy-alcohol

CAS No.N-propyl alcohol 71-23-8

CAS No.The inapplicable isomer 2-methyl isophthalic acid of 2-butanols 15892-23-62-methyl-2-propyl alcohol 75-65-0-propyl alcohol 78-83-1

Table II

The C6 dibasic alcohol The isomer that is suitable for CAS No.2, the 3-butyleneglycol, 2,3-dimethyl-76-09-51, the 2-butyleneglycol, 2,3-dimethyl-66553-15-91, the 2-butyleneglycol, 3,3-dimethyl-59562-82-22, the 3-pentanediol, 2-methyl-7795-80-42, the 3-pentanediol, 3-methyl-63521-37-92, the 3-pentanediol, 4-methyl-7795-79-12,3-hexylene glycol 617-30-13,4-hexylene glycol 922-17-81, the 2-butyleneglycol, 2-ethyl-66553-16-01, the 2-pentanediol, 2-methyl-20667-05-41, the 2-pentanediol, 3-methyl-159623-53-71, the 2-pentanediol, 4-methyl-72110-08-81,2-hexylene glycol 6920-22-5 Inapplicable isomer1, ammediol, 2-ethyl-2-methyl isophthalic acid, ammediol, 2-sec.-propyl-1, ammediol, 2-propyl group-1,3 butylene glycol, 2,2-dimethyl-1,3 butylene glycol, 2,3-dimethyl-1, the 3-butyleneglycol, 2-ethyl-1,4-butyleneglycol, 2,2-dimethyl-1,4-butyleneglycol, 2,3-dimethyl-1, the 4-butyleneglycol, 2-ethyl-1,3-pentanediol, 2-methyl isophthalic acid, the 3-pentanediol, 3-methyl isophthalic acid, 3-pentanediol, 4-methyl isophthalic acid, the 4-pentanediol, 2-methyl isophthalic acid, 4-pentanediol, 3-methyl isophthalic acid, the 4-pentanediol, 4-methyl isophthalic acid, 5-pentanediol, 2-methyl isophthalic acid, the 5-pentanediol, 3-methyl-2,4-pentanediol, 2-methyl-2, the 4-pentanediol, 3-methyl isophthalic acid, 3-hexylene glycol 1,4-hexylene glycol 1,5-hexylene glycol 1,6-hexylene glycol 2,4-hexylene glycol 2,5-hexylene glycol

Table III

The C7 glycol The isomer that is suitable for CAS No.1, ammediol, 2-butyl-2612-26-21, ammediol, 2,2-diethyl-115-76-41, ammediol, 2-(1-methyl-propyl)-33673-01-71, ammediol, 2-(2-methyl-propyl)-26462-20-81, ammediol, 2-methyl-2-propyl group-78-26-21, the 2-butyleneglycol, 2,3,3-trimethylammonium-method B1, the 4-butyleneglycol, 2-ethyl-2-methyl-76651-98-41, the 4-butyleneglycol, 2-ethyl-3-methyl-66225-34-11, the 4-butyleneglycol, 2-propyl group-62946-68-31, the 4-butyleneglycol, 2-sec.-propyl-39497-66-01, the 5-pentanediol, 2,2-dimethyl-3121-82-21, the 5-pentanediol, 2,3-dimethyl-81554-20-31,5-pentanediol, 2,4-dimethyl-2121-69-91,5-pentanediol, 3,3-dimethyl-53120-74-42, the 3-pentanediol, 2,3-dimethyl-6931-70-02, the 3-pentanediol, 2,4-dimethyl-66225-53-42,3-pentanediol, 3,4-dimethyl-37164-04-82,3-pentanediol, 4,4-dimethyl-89851-45-63, the 4-pentanediol, 2,3-dimethyl-method B1, the 5-pentanediol, 2-ethyl-14189-13-01,6-hexylene glycol, 2-methyl-25258-92-81, the 6-hexylene glycol, 3-methyl-4089-71-82,3-hexylene glycol, 2-methyl-59215-55-32, the 3-hexylene glycol, 3-methyl-139093-40-62,3-hexylene glycol, 4-methyl-* * * 2, the 3-hexylene glycol, 5-methyl-method B3,4-hexylene glycol, 2-methyl-method B3, the 4-hexylene glycol, 3-methyl-18938-47-11,3-heptanediol 23433-04-71,4-heptanediol 40646-07-91,5-heptanediol 60096-09-51,6-heptanediol 13175-27-4 Preferred isomers1, ammediol, 2-butyl-2612-26-21, the 4-butyleneglycol, 2-propyl group-62946-68-31, the 5-pentanediol, 2-ethyl-14189-13-02, the 3-pentanediol, 2,3-dimethyl-6931-70-02, the 3-pentanediol, 2,4-dimethyl-66225-53-42, the 3-pentanediol, 3,4-dimethyl-37164-04-82, the 3-pentanediol, 4,4-dimethyl-89851-45-63, the 4-pentanediol, 2,3-dimethyl-method B1, the 6-hexylene glycol, 2-methyl-25258-92-81, the 6-hexylene glycol, 3-methyl-4089-71-81,3-heptanediol 23433-04-71,4-heptanediol 40646-07-91,5-heptanediol 60096-09-51,6-heptanediol 13175-27-4 Preferred isomer2, the 3-pentanediol, 2,3-dimethyl-6931-70-02, the 3-pentanediol, 2,4-dimethyl-66225-53-42,3-pentanediol, 3,4-dimethyl-37164-04-82,3-pentanediol, 4,4-dimethyl-89851-45-63, the 4-pentanediol, 2,3-dimethyl-method B Inapplicable isomer1, ammediol, 2-methyl-2-sec.-propyl-1,2-butyleneglycol, 2-ethyl-3-methyl isophthalic acid, 3-butyleneglycol, 2,2,3-trimethylammonium-1,3-fourth two-alcohol, 2-ethyl-2-methyl isophthalic acid, 3-butyleneglycol, 2-ethyl-3-methyl isophthalic acid, 3-butyleneglycol, 2-sec.-propyl-1,3 butylene glycol, 2-propyl group-1,4-butyleneglycol, 2,2,3-trimethylammonium-1,4-butyleneglycol, 3-ethyl-1-methyl isophthalic acid, 2-pentanediol, 2,3-dimethyl-1,2-pentanediol, 2,4-dimethyl-1,2-pentanediol, 3,3-dimethyl-1,2-pentanediol, 3,4-dimethyl-1,2-pentanediol, 4,4-dimethyl-1,2-pentanediol, 2-ethyl-1, the 3-pentanediol, 2,2-dimethyl-1, the 3-pentanediol, 2,3-dimethyl-1, the 3-pentanediol, 2,4-dimethyl-1, the 3-pentanediol, 2-ethyl-1,3-pentanediol, 3,4-dimethyl-1,3-pentanediol, 4,4-dimethyl-1,4-pentanediol, 2,2-dimethyl-1,4-pentanediol, 2,3-dimethyl-1,4-pentanediol, 2,4-dimethyl-1,4-pentanediol, 3,3-dimethyl-1,4-pentanediol, 3,4-dimethyl-2,4-pentanediol, 2,3-dimethyl-2,4-pentanediol, 2,4-dimethyl-2,4-pentanediol, 3,3-dimethyl-1,2-hexylene glycol, the 2-methyl isophthalic acid, 2-hexylene glycol, 3-methyl isophthalic acid, the 2-hexylene glycol, 4-methyl isophthalic acid, 2-hexylene glycol, the 5-methyl isophthalic acid, 3-hexylene glycol, 2-methyl isophthalic acid, the 3-hexylene glycol, 3-methyl isophthalic acid, 3-hexylene glycol, the 4-methyl isophthalic acid, 3-hexylene glycol, 5-methyl isophthalic acid, the 4-hexylene glycol, 2-methyl isophthalic acid, 4-hexylene glycol, the 3-methyl isophthalic acid, 4-hexylene glycol, 4-methyl isophthalic acid, the 4-hexylene glycol, 5-methyl isophthalic acid, 5-hexylene glycol, the 2-methyl isophthalic acid, 5-hexylene glycol, 3-methyl isophthalic acid, the 5-hexylene glycol, 4-methyl isophthalic acid, 5-hexylene glycol, 5-methyl-2,4-hexylene glycol, 2-methyl-2, the 4-hexylene glycol, 3-methyl-2,4-hexylene glycol, 4-methyl-2,4-hexylene glycol, 5-methyl-2, the 5-hexylene glycol, 2-methyl-2,5-hexylene glycol, the 3-methyl isophthalic acid, 2-heptanediol 2,3-heptanediol 2,4-heptanediol 2,5-heptanediol 2,6-heptanediol 3,4-heptanediol 1,7-heptanediol 3,5-heptanediol ^{* *}146452-51-9; 146452-50-8; 146452-49-5;

146452-48-4；123807-34-1；123807-33-0；

123807-32-9; 123807-31-8; And composition thereof.

Table IV

Ethohexadiol isomery Ti propane diols Yan bioid Ming claimsCAS No. The isomery Ti of Shi Yong1, ammediol, 2-(2-methyl butyl)-87194-40-9 1, ammediol, 2-(1, 1-dimethyl propyl group)-method D 1, ammediol, 2-(1, 2-dimethyl propyl group)-method D 1, ammediol, 2-(1-Yi base propyl group)-25462-28-6 1, ammediol, 2-(1-methyl butyl)-22131-29-9 1, ammediol, 2-(2, 2-dimethyl propyl group)-method D 1, ammediol, 2-(3-methyl butyl)-25462-27-5 1, ammediol, 2-butyl-2-methyl-3121-83-3 1, ammediol, 2-Yi base-2-Yi propyl group-24765-55-7 1, ammediol, 2-Yi base-2-propyl group-25450-88-8 1, ammediol, 2-methyl-2-(1-methyl propyl group)-813-60-5 1, ammediol, 2-methyl-2-(2-methyl propyl group)-25462-42-4 1, ammediol, 2-Shu butyl-2-methyl-25462-45-7Preferred isomery Ti1, ammediol, 2-(1,1-dimethyl propyl group)-method D 1, ammediol, 2-(1,2-dimethyl propyl group)-method D 1, ammediol, 2-(1-Yi base propyl group)-25462-28-6 1, ammediol, 2-(2,2-dimethyl propyl group)-method D 1, ammediol, 2-Yi base-2-Yi propyl group-24765-55-7 1, ammediol, 2-methyl-2-(1-methyl propyl group)-813-60-5 1, ammediol, 2-methyl-2-(2-methyl propyl group)-25462-42-4 1, ammediol, 2-Shu butyl-2-methyl-25462-45-7Inapplicable isomery Ti1, ammediol, the isomery Ti 1 of 2-Wu base-butanediol Yan Sheng Wu Shi Yong, the 3-butanediol, 2, 2-diethyl-99799-77-6 1, the 3-butanediol, 2-(1-methyl propyl group)-method C 1, the 3-butanediol, 2-butyl-83988-22-1 1, the 3-butanediol, 2-Yi base-2, 3-dimethyl-method D 1, the 3-butanediol, 2-(1, 1-dimethyl Yi yl)-67271-58-3 1, the 3-butanediol, 2-(2-methyl propyl group)-method C 1, the 3-butanediol, 2-methyl-2-Yi propyl group-method C 1, the 3-butanediol, 2-methyl-2-propyl-99799-79-1, the 3-butanediol, 3-methyl-2-Yi propyl group-method C 1, the 3-butanediol, 3-methyl-2-propyl-method D 1, the 4-butanediol, 2, 2-diethyl-method H 1, the 4-butanediol, 2-methyl-2-propyl-method H 1, the 4-butanediol, 2-(1-methyl propyl group)-method H 1, the 4-butanediol, 2-Yi base-2, 3-dimethyl-method F 1, the 4-butanediol, 2-Yi base-3, 3-dimethyl-method F 1, the 4-butanediol, 2-(1, 1-dimethyl Yi yl)-36976-70-2 1, the 4-butanediol, 2-(2-dimethyl propyl group)-method F 1, the 4-butanediol, 2-methyl-3-propyl group-90951-76-1 1, the 4-butanediol, 3-methyl-2-Yi propyl group-99799-24-3The isomery Ti of You Xuan1, the 3-butanediol, 2, 2-diethyl-99799-77-6 1, the 3-butanediol, 2-(1-methyl propyl group)-method C 1, the 3-butanediol, 2-butyl-83988-22-1 1, the 3-butanediol, 2-Yi base-2, 3-dimethyl-method D 1, the 3-butanediol, 2-(1, 1-dimethyl Yi yl)-67271-58-3 1, the 3-butanediol, 2-(2-methyl propyl group)-method C 1, the 3-butanediol, 2-methyl-2-Yi propyl group-method C 1, the 3-butanediol, 2-methyl-2-propyl-99799-79-8 1, the 3-butanediol, 3-methyl-2-propyl-method D 1, the 4-butanediol, 2, 2-diethyl-method H 1, the 4-butanediol, 2-Yi base-2, 3-dimethyl-method F 1, the 4-butanediol, 2-Yi base-3, 3-dimethyl-method F 1, the 4-butanediol, 2-(1, 1-dimethyl Yi yl)-36976-70-2 1, the 4-butanediol, 3-methyl-2-Yi propyl group-99799-24-3Preferred isomery Ti1,3-butanediol, 2-(1-methyl propyl group)-method C 1, the 3-butanediol, 2-(2-methyl propyl group)-method C 1,3-butanediol, 2-butyl-83988-22-1 1,3-butanediol, 2-methyl-2-propyl-99799-79-8 1, the 3-butanediol, 3-methyl-2-propyl-method D 1,4-butanediol, 2,2-diethyl-method H 1, the 4-butanediol, 2-Yi base-2,3-dimethyl-method F 1, the 4-butanediol, 2-Yi base-3,3-dimethyl-method F 1,4-butanediol, 2-(1,1-dimethyl Yi yl)-36976-70-2Inapplicable isomery Ti1,4-butanediol, 2-butyl-1,2-butanediol, 2-Yi base-3,3-dimethyl-1,4-butanediol, 2-methyl-2-Yi propyl group-1,2-butanediol, 3-methyl-2-Yi propyl group-1,4-butanediol, 2,2,3,3-tetramethyl base-TMPD isomery TiThe isomery Ti of Shi Yong1, 3-Wu glycol, 2, 2, 3-San methyl-35512-54-0 1, 3-Wu glycol, 2, 2, 4-San methyl-144-19-4 1, 3-Wu glycol, 2, 3, 4-San methyl-116614-13-2 1, 3-Wu glycol, 2, 4, 4-San methyl-109387-36-2 1, 3-Wu glycol, 3, 4, 4-San methyl-81756-50-5 1, 4-Wu glycol, 2, 2, 3-San methyl-method H 1, 4-Wu glycol, 2, 2, 4-San methyl-80864-10-4 1, 4-Wu glycol, 2, 3, 3-San methyl-method H 1, 4-Wu glycol, 2, 3, 4-San methyl-92340-74-4 1, 4-Wu glycol, 3, 3, 4-San methyl-16466-35-6 1, 5-Wu glycol, 2, 2, 3-San methyl-method F 1, 5-Wu glycol, 2, 2, 4-San methyl-3465-14-3 1, 5-Wu glycol, 2, 3, 3-San methyl-method A 1, 5-Wu glycol, 2, 3, 4-San methyl-85373-83-7 2, 4-Wu glycol, 2, 3, 3-San methyl-24892-51-1 2, 4-Wu glycol, 2, 3, 4-San methyl-24892-52-2The isomery Ti of You Xuan1, 3-Wu glycol, 2, 2, 3-San methyl-35512-54-0 1, 3-Wu glycol, 2, 2, 4-San methyl-144-19-4 1, 3-Wu glycol, 2, 3, 4-San methyl-116614-13-2 1, 3-Wu glycol, 2, 4, 4-San methyl-109387-36-2 1, 3-Wu glycol, 3, 4, 4-San methyl-81756-50-5 1, 4-Wu glycol, 2, 2, 3-San methyl-method H 1, 4-Wu glycol, 2, 2, 4-San methyl-80864-10-4 1, 4-Wu glycol, 2, 3, 3-San methyl-method F 1, 4-Wu glycol, 2, 3, 4-San methyl-92340-74-4 1, 4-Wu glycol, 3, 3, 4-San methyl-16466-35-6 1, 5-Wu glycol, 2, 2, 3-San methyl-method A 1, 5-Wu glycol, 2, 2, 4-San methyl-3465-14-3 1, 5-Wu glycol, 2, 3, 3-San methyl-method A 2, 4-Wu glycol, 2, 3, 4-San methyl-24892-52-2Preferred isomery Ti1,3-Wu glycol, 2,3,4-San methyl-116614-13-2 1,4-Wu glycol, 2,3,4-San methyl-92340-74-4 1,5-Wu glycol, 2,2,3-San methyl-method A 1,5-Wu glycol, 2,2,4-San methyl-3465-14-3 1,5-Wu glycol, 2,3,3-San methyl-method AInapplicable isomery Ti1,2-Wu glycol, 2,3,3-San methyl-1,2-Wu glycol, 2,3,4-San methyl-1,2-Wu glycol, 2,4,4-San methyl-1,2-Wu glycol, 3,3,4-San methyl-1,2-Wu glycol, 3,4,4-San methyl-2,3-Wu glycol, 2,3,4-San methyl-2,3-Wu glycol, 2,4,4-San methyl-2,3-Wu glycol, 3,4,4-San methyl-Yi ylmethyl Wu glycol isomery TiThe isomery Ti of Shi Yong1, 3-Wu glycol, 2-Ethyl-2-Methyl-method C 1, 3-Wu glycol, 2-Yi base-3-methyl-method D 1, 3-Wu glycol, 2-Yi base-4-methyl-148904-97-6 1, 3-Wu glycol, 3-Ethyl-2-Methyl-55661-05-7 1, 4-Wu glycol, 2-Ethyl-2-Methyl-method H 1, 4-Wu glycol, 2-Yi base-3-methyl-method F 1, 4-Wu glycol, 2-Yi base-4-methyl-method G 1, 4-Wu glycol, 3-Ethyl-2-Methyl-method F 1, 4-Wu glycol, 3-Yi base-3-methyl-method F 1, 5-Wu glycol, 2-Ethyl-2-Methyl-method F 1, 5-Wu glycol, 2-Yi base-3-methyl-54886-83-8 1, 5-Wu glycol, 2-Yi base-4-methyl-method F 1, 5-Wu glycol, 3-Yi base-3-methyl-57740-12-2 2, 4-Wu glycol, 3-Ethyl-2-Methyl-method GPreferred isomery Ti1,3-Wu glycol, 2-Ethyl-2-Methyl-method C 1,3-Wu glycol, 2-Yi base-3-methyl-method D 1,3-Wu glycol, 2-Yi base-4-methyl-148904-97-6 1,3-Wu glycol, 3-Ethyl-2-Methyl-55661-05-7 1,4-Wu glycol, 2-Ethyl-2-Methyl-method H 1,4-Wu glycol, 2-Yi base-3-methyl-method F 1,4-Wu glycol, 2-Yi base-4-methyl-method G 1,5-Wu glycol, 3-Yi base-3-methyl-57740-12-2 2,4-Wu glycol, 3-Ethyl-2-Methyl-method GInapplicable isomery Ti1,2-Wu glycol, 2-Yi base-3-methyl-1,2-Wu glycol, 2-Yi base-4-methyl-1,2-Wu glycol, 3-Ethyl-2-Methyl-1,2-Wu glycol, 3-Yi base-3-methyl-1,2-Wu glycol, 3-Yi base-4-methyl-1,3-Wu glycol, 3-Yi base-4-methyl-1,4-Wu glycol, 3-Yi base-4-methyl-1,5-Wu glycol, 3-Ethyl-2-Methyl-2,3-Wu glycol, 3-Ethyl-2-Methyl-2,3-Wu glycol, 3-Yi base-4-methyl-2,4-Wu glycol, 3-Yi base-3-methyl-propyl group Wu glycol isomery TiThe isomery Ti of Shi Yong1,3-Wu glycol, 2-Yi propyl group-method D 1,3-Wu glycol, 2-propyl group-method C 1,4-Wu glycol, 2-Yi propyl group-method H 1,4-Wu glycol, 2-propyl group-method H 1,4-Wu glycol, 3-Yi propyl group-method H 1,5-Wu glycol, 2-Yi propyl group-90951-89-6 2,4-Wu glycol, 3-propyl group-method CPreferred isomery Ti1,3-Wu glycol, 2-Yi propyl group-method D 1,3-Wu glycol, 2-propyl group-method C 1,4-Wu glycol, 2-Yi propyl group-method H 1,4-Wu glycol, 2-propyl group-method H 1,4-Wu glycol, 3-Yi propyl group-method H 2,4-Wu glycol, 3-propyl group-method CInapplicable isomery Ti1,2-Wu glycol, 2-propyl group-1,2-Wu glycol, 2-Yi propyl group-1,4-Wu glycol, 3-propyl group-1,5-Wu glycol, 2-propyl group-2,4-Wu glycol, 3-Yi propyl group-dimethyl hexylene glycol isomery TiThe isomery Ti of Shi Yong1, the 3-hexylene glycol, 2, 2-dimethyl-22006-96-8 1, the 3-hexylene glycol, 2, 3-dimethyl-method D 1, the 3-hexylene glycol, 2, 4-dimethyl-78122-99-3 1, the 3-hexylene glycol, 2, 5-dimethyl-method C 1, the 3-hexylene glycol, 3, 4-dimethyl-method D 1, the 3-hexylene glycol, 3, 5-dimethyl-method D 1, the 3-hexylene glycol, 4, 4-dimethyl-method C 1, the 3-hexylene glycol, 4, 5-dimethyl-method C 1, the 4-hexylene glycol, 2, 2-dimethyl-method F 1, the 4-hexylene glycol, 2, 3-dimethyl-method F 1, the 4-hexylene glycol, 2, 4-dimethyl-method G 1, the 4-hexylene glycol, 2, 5-dimethyl-22417-60-3 1, the 4-hexylene glycol, 3, 3-dimethyl-method F 1, the 4-hexylene glycol, 3, 4-dimethyl-method E 1, the 4-hexylene glycol, 3, 5-dimethyl-method H 1, the 4-hexylene glycol, 4, 5-dimethyl-method E 1, the 4-hexylene glycol, 5, 5-dimethyl-38624-38-3 1, the 5-hexylene glycol, 2, 2-dimethyl-method A 1, the 5-hexylene glycol, 2, 3-dimethyl-62718-05-2 1, the 5-hexylene glycol, 2, 4-dimethyl-73455-82-0 1, the 5-hexylene glycol, 2, 5-dimethyl-58510-28-4 1, the 5-hexylene glycol, 3, 3-dimethyl-41736-99-6 1, the 5-hexylene glycol, 3, 4-dimethyl-method A 1, the 5-hexylene glycol, 3, 5-dimethyl-method G 1, the 5-hexylene glycol, 4, 5-dimethyl-method F 1, the 6-hexylene glycol, 2, 2-dimethyl-13622-91-8 1, the 6-hexylene glycol, 2, 3-dimethyl-method F 1, the 6-hexylene glycol, 2, 4-dimethyl-method F 1, the 6-hexylene glycol, 2, 5-dimethyl-49623-11-2 1, the 6-hexylene glycol, 3, 3-dimethyl-method F 1, the 6-hexylene glycol, 3, 4-dimethyl-65363-45-3 2, the 4-hexylene glycol, 2, 3-dimethyl-26344-17-2 2, the 4-hexylene glycol, 2, 4-dimethyl-29649-22-7 2, the 4-hexylene glycol, 2, 5-dimethyl-3899-89-6 2, the 4-hexylene glycol, 3, 3-dimethyl-42412-51-1 2, the 4-hexylene glycol, 3, 4-dimethyl-90951-83-0 2, the 4-hexylene glycol, 3, 5-dimethyl-159300-34-2 2, the 4-hexylene glycol, 4, 5-dimethyl-method D 2, the 4-hexylene glycol, 5, 5-dimethyl-108505-10-8 2, the 5-hexylene glycol, 2, 3-dimethyl-method G 2, the 5-hexylene glycol, 2, 4-dimethyl-method G 2, the 5-hexylene glycol, 2, 5-dimethyl-110-03-2 2, the 5-hexylene glycol, 3, 3-dimethyl-method H 2, the 5-hexylene glycol, 3, 4-dimethyl-99799-30-1 2, the 6-hexylene glycol, 3, 3-dimethyl-method APreferred isomery Ti1, the 3-hexylene glycol, 2, 2-dimethyl-22006-96-8 1, the 3-hexylene glycol, 2, 3-dimethyl-method D 1, the 3-hexylene glycol, 2, 4-dimethyl-78122-99-3 1, the 3-hexylene glycol, 2, 5-dimethyl-method C 1, the 3-hexylene glycol, 3, 4-dimethyl-method D 1, the 3-hexylene glycol, 3, 5-dimethyl-method D 1, the 3-hexylene glycol, 4, 4-dimethyl-method C 1, the 3-hexylene glycol, 4, 5-dimethyl-method C 1, the 4-hexylene glycol, 2, 2-dimethyl-method H 1, the 4-hexylene glycol, 2, 3-dimethyl-method F 1, the 4-hexylene glycol, 2, 4-dimethyl-method G 1, the 4-hexylene glycol, 2, 5-dimethyl-22417-60-3 1, the 4-hexylene glycol, 3, 3-dimethyl-method F 1, the 4-hexylene glycol, 3, 4-dimethyl-method E 1, the 4-hexylene glycol, 3, 5-dimethyl-method H 1, the 4-hexylene glycol, 4, 5-dimethyl-method E 1, the 4-hexylene glycol, 5, 5-dimethyl-38624-38-3 1, the 5-hexylene glycol, 2, 2-dimethyl-method A 1, the 5-hexylene glycol, 2, 3-dimethyl-62718-05-2 1, the 5-hexylene glycol, 2, 4-dimethyl-73455-82-0 1, the 5-hexylene glycol, 2, 5-dimethyl-58510-28-4 1, the 5-hexylene glycol, 3, 3-dimethyl-41736-99-6 1, the 5-hexylene glycol, 3, 4-dimethyl-method A 1, the 5-hexylene glycol, 3, 5-dimethyl-method G 1, the 5-hexylene glycol, 4, 5-dimethyl-method F 2, the 6-hexylene glycol, 3, 3-dimethyl-method AInapplicable isomery Ti1, the 2-hexylene glycol, 2, 3-dimethyl-1, the 2-hexylene glycol, 2, 4-dimethyl-1, the 2-hexylene glycol, 2, 5-dimethyl-1, the 2-hexylene glycol, 3, 3-dimethyl-1, the 2-hexylene glycol, 3, 4-dimethyl-1, the 2-hexylene glycol, 3, 5-dimethyl-1, the 2-hexylene glycol, 4, 4-dimethyl-1, the 2-hexylene glycol, 4, 5-dimethyl-1, the 2-hexylene glycol, 5, 5-dimethyl-2, the 3-hexylene glycol, 2, 3-dimethyl-2, the 3-hexylene glycol, 2, 4-dimethyl-2, the 3-hexylene glycol, 2, 5-dimethyl-2, the 3-hexylene glycol, 3, 4-dimethyl-2, the 3-hexylene glycol, 3, 5-dimethyl-2, the 3-hexylene glycol, 4, 4-dimethyl-2, the 3-hexylene glycol, 4, 5-dimethyl-2, the 3-hexylene glycol, 5, 5-dimethyl-3, the 4-hexylene glycol, 2, 2-dimethyl-3, the 4-hexylene glycol, 2, 3-dimethyl-3, the 4-hexylene glycol, 2, 4-dimethyl-3, the 4-hexylene glycol, 2, 5-dimethyl-3, the 4-hexylene glycol, 3, 4-dimethyl-ethohexadiol isomery TiPreferred isomery Ti1,3-hexylene glycol, 2-Yi base-94-96-2 1, the 3-hexylene glycol, 4-Yi base-method C 1,4-hexylene glycol, 2-Yi base-148904-97-6 1,4-hexylene glycol, 4-Yi base-1113-00-4 1, the 5-hexylene glycol, 2-Yi base-58374-34-8 2,4-hexylene glycol, 3-Yi base-method C 2,4-hexylene glycol, 4-Yi base-33683-47-5 2, the 5-hexylene glycol, 3-Yi base-method FInapplicable isomery Ti1,5-hexylene glycol, 4-Yi base-1,6-hexylene glycol, 2-Yi base-1, the 4-hexylene glycol, 3-Yi base-1,5-hexylene glycol, 3-Yi base-1, the 6-hexylene glycol, 3-Yi base-1,2-hexylene glycol, 2-Yi base-1, the 2-hexylene glycol, 3-Yi base-1,2-hexylene glycol, 4-Yi base-2, the 3-hexylene glycol, 3-Yi base-2,3-hexylene glycol, 4-Yi base-3, the 4-hexylene glycol, 3-Yi base-1,3-hexylene glycol, 3-Yi base-methyl heptandiol isomery TiThe isomery Ti of Shi Yong1, the 3-heptandiol, 2-methyl-109417-38-1 1, the 3-heptandiol, 3-methyl-165326-88-5 1, the 3-heptandiol, 4-methyl-method C 1, the 3-heptandiol, 5-methyl-method D 1, the 3-heptandiol, 6-methyl-method C 1, the 4-heptandiol, 2-methyl-15966-03-7 1, the 4-heptandiol, 3-methyl-7748-38-1 1, the 4-heptandiol, 4-methyl-72473-94-0 1, the 4-heptandiol, 5-methyl-63003-04-3 1, the 4-heptandiol, 6-methyl-99799-25-4 1, the 5-heptandiol, 2-methyl-141605-00-7 1, the 5-heptandiol, 3-methyl-method A 1, the 5-heptandiol, 4-methyl-method A 1, the 5-heptandiol, 5-methyl-99799-26-5 1, the 5-heptandiol, 6-methyl-57740-00-8 1, the 6-heptandiol, 2-methyl-132148-22-2 1, the 6-heptandiol, 3-methyl-method G 1, the 6-heptandiol, 4-methyl-156307-84-5 1, the 6-heptandiol, 5-methyl-method A 1, the 6-heptandiol, 6-methyl-5392-57-4 2, the 4-heptandiol, 2-methyl-38836-26-9 2, the 4-heptandiol, 3-methyl-6964-04-1 2, the 4-heptandiol, 4-methyl-165326-87-4 2, the 4-heptandiol, 5-methyl-method C 2, the 4-heptandiol, 6-methyl-79356-95-9 2, the 5-heptandiol, 2-methyl-141605-02-9 2, the 5-heptandiol, 3-methyl-method G 2, the 5-heptandiol, 4-methyl-156407-38-4 2, the 5-heptandiol, 5-methyl-148843-72-5 2, the 5-heptandiol, 6-methyl-51916-46-2 2, the 6-heptandiol, 2-methyl-73304-48-0 2, the 6-heptandiol, 3-methyl-29915-96-6 2, the 6-heptandiol, 4-methyl-106257-69-6 3, the 4-heptandiol, 3-methyl-18938-50-6 3, the 5-heptandiol, 2-methyl-method C 3, the 5-heptandiol, 3-methyl-99799-27-6 3, the 5-heptandiol, 4-methyl-156407-37-3Preferred isomery Ti1, the 3-heptandiol, 2-methyl-109417-38-1 1, the 3-heptandiol, 3-methyl-165326-88-5 1, the 3-heptandiol, 4-methyl-method C 1, the 3-heptandiol, 5-methyl-method D 1, the 3-heptandiol, 6-methyl-method C 1, the 4-heptandiol, 2-methyl-15966-03-7 1, the 4-heptandiol, 3-methyl-7748-38-1 1, the 4-heptandiol, 4-methyl-72473-94-0 1, the 4-heptandiol, 5-methyl-63003-04-3 1, the 4-heptandiol, 6-methyl-99799-25-4 1, the 5-heptandiol, 2-methyl-141605-00-7 1, the 5-heptandiol, 3-methyl-method A 1, the 5-heptandiol, 4-methyl-method A 1, the 5-heptandiol, 5-methyl-99799-26-5 1, the 5-heptandiol, 6-methyl-57740-00-8 1, the 6-heptandiol, 2-methyl-132148-22-2 1, the 6-heptandiol, 3-methyl-method G 1, the 6-heptandiol, 4-methyl-156307-84-5 1, the 6-heptandiol, 5-methyl-method A 1, the 6-heptandiol, 6-methyl-5392-57-4 2, the 4-heptandiol, 2-methyl-38836-26-9 2, the 4-heptandiol, 3-methyl-6964-04-1 2, the 4-heptandiol, 4-methyl-165326-87-4 2, the 4-heptandiol, 5-methyl-method C 2, the 4-heptandiol, 6-methyl-79356-95-9 2, the 5-heptandiol, 2-methyl-141605-02-9 2, the 5-heptandiol, 3-methyl-method H 2, the 5-heptandiol, 4-methyl-156407-38-4 2, the 5-heptandiol, 5-methyl-148843-72-5 2, the 5-heptandiol, 6-methyl-51916-46-2 2, the 6-heptandiol, 2-methyl-73304-48-0 2, the 6-heptandiol, 3-methyl-29915-96-6 2, the 6-heptandiol, 4-methyl-106257-69-6 3, the 4-heptandiol, 3-methyl-18938-50-6 3, the 5-heptandiol, 2-methyl-method C 3, the 5-heptandiol, 4-methyl-156407-37-3Inapplicable isomery Ti1, the 7-heptandiol, 2-methyl-1, the 7-heptandiol, 3-methyl-1, the 7-heptandiol, 4-methyl-2, the 3-heptandiol, 2-methyl-2, the 3-heptandiol, 3-methyl-2, the 3-heptandiol, 4-methyl-2, the 3-heptandiol, 5-methyl-2, the 3-heptandiol, 6-methyl-3, the 4-heptandiol, 2-methyl-3, the 4-heptandiol, 4-methyl-3, the 4-heptandiol, 5-methyl-3, the 4-heptandiol, 6-methyl-1, the 2-heptandiol, 2-methyl-1, the 2-heptandiol, 3-methyl-1, the 2-heptandiol, 4-methyl-1, the 2-heptandiol, 5-methyl-1, the 2-heptandiol, 6-methyl-ethohexadiol isomery TiPreferred isomery Ti2,4-ethohexadiol 90162-24-6 2,5-ethohexadiol 4527-78-0 2,6-ethohexadiol method A 2,7-ethohexadiol 19686-96-5 3,5-ethohexadiol 24892-55-5 3,6-ethohexadiol 24434-09-1Inapplicable isomery Ti1,2-ethohexadiol 1117-86-8 1,3-ethohexadiol 23433-05-8 1,4-ethohexadiol 51916-47-3 1,5-ethohexadiol 2736-67-6 1,6-ethohexadiol 4060-76-6 1,7-ethohexadiol 13175-32-1 1,8-ethohexadiol 629-41-4 2,3-ethohexadiol be for example: 98464-24-5 3, the 4-ethohexadiol is for example: 99799-31-2 3, the 5-ethohexadiol for example: 129025-63-4

Table V

Nonanediol isomer chemical name CAS No. Preferred isomers2,4-pentanediol, 2,3,3,4-tetramethyl--19424-43-2 The isomer that is suitable for2,4-pentanediol, the 3-tertiary butyl-142205-14-92, the 4-hexylene glycol, 2,5,5-trimethylammonium-97460-08-72,4-hexylene glycol, 3,3,4-trimethylammonium-method D2,4-hexylene glycol, 3,3,5-trimethylammonium-27122-58-32, the 4-hexylene glycol, 3,5,5-trimethylammonium-method D2,4-hexylene glycol, 4,5,5-trimethylammonium-method D2,5-hexylene glycol, 3,3,4-trimethylammonium-method H2,5-hexylene glycol, 3,3,5-trimethylammonium-method G Inapplicable isomerHave to surpass inapplicable isomer of 500, comprise following compound: 2, the 4-hexylene glycol, 2,4,5-trimethylammonium-36587-81-22, the 4-hexylene glycol, 2,3, the 5-trimethylammonium-, red-26344-20-72,4-hexylene glycol, 2,3, the 5-trimethylammonium-, Soviet Union-26343-49-71, ammediol, 2-butyl-2-ethyl-115-84-42, the 4-hexylene glycol, 2,3, the 5-trimethylammonium-, Soviet Union-26343-49-7

Table VI

Alkyl glycerol base ether, two (hydroxyalkyl) ethers and aryl glyceryl ether Preferred single glyceryl ether and derivative1, the 2-propylene glycol, 3-(butoxy)-, triethoxyization 1, the 2-propylene glycol, 3-(butoxy)-, tetraethoxyization Preferred single glyceryl ether and derivativeCAS No.1,2-propylene glycol, 3-(n-pentyloxy)-22636-32-41, the 2-propylene glycol, 3-(2-pentyloxy)-1,2-propylene glycol, 3-(3-pentyloxy)-1,2-propylene glycol, 3-(2-methyl-1-butene oxygen base)-1, the 2-propylene glycol, 3-(isopentyloxy)-1,2-propylene glycol, 3-(3-methyl-2-butoxy)-1,2-propylene glycol, 3-(cyclohexyloxy)-1, the 2-propylene glycol, 3-(1-hexamethylene-1-alkene oxygen base)-1, ammediol, 2-(pentyloxy)-1, ammediol, 2-(2-pentyloxy)-1, ammediol, 2-(3-pentyloxy)-1, ammediol, 2-(2-methyl-1-butene oxygen base)-1, ammediol, 2-(isopentyloxy)-1, ammediol, 2-(3-methyl-2-butoxy)-1, ammediol, 2-(cyclohexyloxy)-1, ammediol, 2-(1-hexamethylene-1-alkene oxygen base)-1, the 2-propylene glycol, 3-(butoxy)-, five ethoxylations 1, the 2-propylene glycol, 3-(butoxy)-, six ethoxylations 1, the 2-propylene glycol, 3-(butoxy)-, seven ethoxylations 1,2-propylene glycol, 3-(butoxy)-, eight ethoxylations 1, the 2-propylene glycol, 3-(butoxy)-, nine ethoxylations 1, the 2-propylene glycol, 3-(butoxy)-,-propoxylation 1, the 2-propylene glycol, 3-(butoxy)-, dibutoxyization 1,2-propylene glycol, 3-(butoxy)-, three butoxyization Preferred two (hydroxyalkyl) etherTwo (2-hydroxyl butyl) ether two (2-hydroxycyclopent base) ether Inapplicable single glyceryl ether1,2-propylene glycol, 3-oxyethyl group-1,2-propylene glycol, 3-propoxy--1,2-propylene glycol, 3-isopropoxy-1,2-propylene glycol, 3-butoxy-1,2-propylene glycol, 3-isobutoxy-1,2-propylene glycol, 3-tert.-butoxy-1,2-propylene glycol, 3-octyloxy-1,2-propylene glycol, 3-(2-ethyl hexyl oxy)-1,2-propylene glycol, 3-(cyclopentyloxy)-1,2-propylene glycol, 3-(1-hexamethylene-2-alkene oxygen base)-1, ammediol, 2-(1-hexamethylene-2-alkene oxygen base)-

The aromatics glyceryl ether The aromatics glyceryl ether that is suitable for1,2-propylene glycol, 3-phenoxy group-1,2-propylene glycol, 3-benzyloxy-1,2-propylene glycol, 3-(2-phenyl ethoxy)-1,2-propylene glycol, 3-(1-phenyl-2-propoxy-)-1, ammediol, 2-phenoxy group-1, ammediol, 2-(a hydroxy toluene oxygen base)-1, ammediol, 2-(to hydroxy toluene oxygen base)-1, ammediol, 2-benzyloxy-1, ammediol, 2-(2-phenyl ethoxy)-1, ammediol, 2-(1-phenyl ethoxy)- Preferred aromatics glyceryl ether1,2-propylene glycol, 3-phenoxy group-1,2-propylene glycol, 3-benzyloxy-1, the 2-propylene glycol, 3-(2-phenyl ethoxy)-1, ammediol, 2-(a hydroxy toluene oxygen base)-1, ammediol, 2-(to hydroxy toluene oxygen base)-1, ammediol, 2-benzyloxy-1, ammediol, 2-(2-phenyl ethoxy)- Preferred aromatics glyceryl ether1, the 2-propylene glycol, 3-phenoxy group-1, the 2-propylene glycol, 3-benzyloxy-1, the 2-propylene glycol, 3-(2-phenyl ethoxy)-1, ammediol, 2-(a hydroxy toluene oxygen base)-1, ammediol, 2-(to hydroxy toluene oxygen base)-1, ammediol, 2-(2-phenyl ethoxy)-

Table VII

Alicyclic diol and derivatives chemical title CAS No. Preferred cyclic diols and derivative1-sec.-propyl-1,2-cyclobutanediol 59895-32-83-ethyl-4-methyl isophthalic acid, 2-cyclobutanediol 3-propyl group-1,2-cyclobutanediol 3-sec.-propyl-1,2-cyclobutanediol 42113-90-61-ethyl-1,2-ring pentanediol 67396-17-21,2-dimethyl-1,2-ring pentanediol 33046-20-71,4-dimethyl-1,2-ring pentanediol 89794-56-92,4,5-trimethylammonium-1,3-encircles pentanediol 3,3-dimethyl-1,2-ring pentanediol 89794-57-03,4-dimethyl-1,2-ring pentanediol 70051-69-33,5-dimethyl-1,2-ring pentanediol 89794-58-13-ethyl-1,2-encircles pentanediol 4,4-dimethyl-1,2-ring pentanediol 70197-54-54-ethyl-1,2-encircles pentanediol 1,1-two (methylol) hexanaphthene 2658-60-81,2-two (methylol) hexanaphthene 76155-27-61,2-dimethyl-1,3-cyclohexanediol 53023-07-71,3-two (methylol) hexanaphthene 13022-98-51,3-dimethyl-1,3-cyclohexanediol 128749-93-91,6-dimethyl-1,3-cyclohexanediol 164713-16-01-hydroxyl hexanaphthene ethanol 40894-17-51-hydroxyl cyclohexane methanol 15753-47-61-ethyl-1,3-cyclohexanediol 10601-18-01-methyl isophthalic acid, 2-cyclohexanediol 52718-65-72,2-dimethyl-1,3-cyclohexanediol 114693-83-32,3-dimethyl-1,4-cyclohexanediol 70156-82-02,4-dimethyl-1,3-cyclohexanediol 2,5-dimethyl-1,3-cyclohexanediol 2,6-dimethyl-1,4-cyclohexanediol 34958-42-42-ethyl-1,3-cyclohexanediol 155433-88-82-hydroxyl hexanaphthene ethanol 24682-42-62-hydroxyethyl-1-hexalin 2-methylol hexalin 89794-52-53-hydroxyethyl-1-hexalin 3-hydroxyl hexanaphthene ethanol 86576-87-63-methylol hexalin 3-methyl isophthalic acid, 2-cyclohexanediol 23477-91-04,4-dimethyl-1,3-cyclohexanediol 14203-50-04,5-dimethyl-1,3-cyclohexanediol 4,6-dimethyl-1,3-cyclohexanediol 16066-66-34-ethyl-1,3-cyclohexanediol 4-hydroxyethyl-1-hexalin 4-methylol hexalin 33893-85-54-methyl isophthalic acid, 2-cyclohexanediol 23832-27-15,5-dimethyl-1,3-cyclohexanediol 51335-83-25-ethyl-1,3-cyclohexanediol 1,2-ring heptanediol 108268-28-62-methyl isophthalic acid, 3-ring heptanediol 101375-80-82-methyl isophthalic acid, 4-ring heptanediol 4-methyl isophthalic acid, 3-ring heptanediol 5-methyl isophthalic acid, 3-ring heptanediol 5-methyl isophthalic acid, 4-ring heptanediol 90201-00-66-methyl isophthalic acid, 4-encircles heptanediol 1,3-ring ethohexadiol 101935-36-81,4-ring ethohexadiol 73982-04-41,5-ring ethohexadiol 23418-82-81,2-cyclohexanediol, diethoxy thing 1, the 2-cyclohexanediol, triethoxy thing 1,2-cyclohexanediol, tetraethoxy thing 1, the 2-cyclohexanediol, five ethoxylates 1,2-cyclohexanediol, six ethoxylates 1, the 2-cyclohexanediol, seven ethoxylates 1,2-cyclohexanediol, eight ethoxylates 1, the 2-cyclohexanediol, nine ethoxylates 1,2-cyclohexanediol, a propoxylated glycerine 1, the 2-cyclohexanediol, one butoxy thing 1,2-cyclohexanediol, dibutoxy thing 1, the 2-cyclohexanediol, three butoxy materialization formal names used at school claim CAS No. Preferred cyclic diols and derivative1-sec.-propyl-1,2-cyclobutanediol 59895-32-83-ethyl-4-methyl isophthalic acid, 2-cyclobutanediol 3-propyl group-1,2-cyclobutanediol 3-sec.-propyl-1,2-cyclobutanediol 42113-90-61-ethyl-1,2-ring pentanediol 67396-17-21,2-dimethyl-1,2-ring pentanediol 33046-20-71,4-dimethyl-1,2-ring pentanediol 89794-56-93,3-dimethyl-1,2-ring pentanediol 89794-57-03,4-dimethyl-1,2-ring pentanediol 70051-69-33,5-dimethyl-1,2-ring pentanediol 89794-58-13-ethyl-1,2-encircles pentanediol 4,4-dimethyl-1,2-ring pentanediol 70197-54-54-ethyl-1,2-encircles pentanediol 1,1-two (methylol) hexanaphthene 2658-60-81,2-two (methylol) hexanaphthene 76155-27-61,2-dimethyl-1,3-cyclohexanediol 53023-07-71,3-two (methylol) hexanaphthene 13022-98-51-hydroxyl cyclohexane methanol 15753-47-61-methyl isophthalic acid, 2-cyclohexanediol 52718-65-73-methylol hexalin 3-methyl isophthalic acid, 2-cyclohexanediol 23477-91-04,4-dimethyl-1,3-cyclohexanediol 14203-50-04,5-dimethyl-1,3-cyclohexanediol 4,6-dimethyl-1,3-cyclohexanediol 16066-66-34-ethyl-1,3-cyclohexanediol 4-hydroxyethyl-1-hexalin 4-methylol hexalin 33893-85-54-methyl isophthalic acid, 2-cyclohexanediol 23832-27-11,2-ring heptanediol 108268-28-61, the 2-cyclohexanediol, five ethoxylates 1, the 2-cyclohexanediol, six ethoxylates 1, the 2-cyclohexanediol, seven ethoxylates 1, the 2-cyclohexanediol, eight ethoxylates 1, the 2-cyclohexanediol, nine ethoxylates 1, the 2-cyclohexanediol, one propoxylated glycerine 1, the 2-cyclohexanediol, the dibutoxy thing

Undersaturated alicyclic diol comprises following known unsaturated alicyclic ring glycol: The unsaturated alicyclic ring glycol that is suitable for Chemical nameCAS No.1, the 2-cyclobutanediol, 1-vinyl-2-ethyl-58016-14-13-cyclobutene-1, the 2-glycol, 1,2,3,4-tetramethyl--90112-64-43-cyclobutene-1, the 2-glycol, 3,4-diethyl-142543-60-03-cyclobutene-1, the 2-glycol, 3-(1, the 1-dimethyl ethyl)-142543-56-43-cyclobutene-1, the 2-glycol, 3-butyl-142543-55-31,2-encircles pentanediol, 1,2-dimethyl-4-methylene radical-103150-02-31,2-encircles pentanediol, 1-ethyl-3-methylene radical-90314-52-61,2-encircles pentanediol, 4-(1-propenyl)-128173-45-53-cyclopentenes-1, the 2-glycol, 1-ethyl-3-methyl-90314-43-51, the 2-cyclohexanediol, 1-vinyl-134134-16-01, the 2-cyclohexanediol, 1-methyl-3-methylene radical-98204-78-51, the 2-cyclohexanediol, 1-methyl-4-methylene radical-133358-53-91, the 2-cyclohexanediol, 3-vinyl-55310-51-51, the 2-cyclohexanediol, 4-vinyl-85905-16-43-tetrahydrobenzene-1, the 2-glycol, 2,6-dimethyl-81969-75-73-tetrahydrobenzene-1, the 2-glycol, 6,6-dimethyl-61875-93-24-tetrahydrobenzene-1, the 2-glycol, 3,6-dimethyl-156808-73-04-tetrahydrobenzene-1, the 2-glycol, 4,5-dimethyl-154351-54-93-cyclooctene-1,2-glycol 170211-27-54-cyclooctene-1,2-glycol 124791-61-35-cyclooctene-1,2-glycol 117468-07-2 Inapplicable unsaturated annular glycol1,2-encircles pentanediol, 1-(1-methyl ethylene)-61447-83-41, the 2-propylene glycol, 1-cyclopentyl-55383-20-51,3-encircles pentanediol, 2-(1-methyl ethylidene)-65651-46-91, ammediol, 2-(1-cyclopentenes-1-yl)-77192-43-91, ammediol, 2-(2-cyclopentenes-1-yl)-25462-31-11,2-ethylene glycol, 1-(1-tetrahydrobenzene-1-yl)-151674-61-21,2-ethylene glycol, 1-(3-tetrahydrobenzene-1-yl)-64011-53-62-tetrahydrobenzene-1, the 4-glycol, 5,5-dimethyl-147274-55-34-tetrahydrobenzene-1, the 3-glycol, 3,6-dimethyl-127716-90-91,3-encircles heptanediol, 2-methylene radical-132292-67-25-suberene-1,3-glycol, 1-methyl-160813-33-25-suberene-1, the 3-glycol, 5-methyl-160813-32-12-cyclooctene-1,4-glycol 37996-40-0

Table VIII

C ₃-C ₇The glycol alkoxy derivative

In following each table, " EO " represents polyethoxylated, that is, and and-(CH ₂CH ₂O) _nH; The end capped polyethoxylated of Me-En represent methylidene-(CH ₂CH ₂O) _nCH ₃" 2 (Me-En) " representative needs 2 Me-En groups; The poly-propoxylated glycerine of " PO " representative ,-(CH (CH ₃) CH ₂O) _nH; " BO " represents polytetramethylene oxygen base, (CH (CH ₂CH ₃) CH ₂O) _nH; " n-BO " representative poly-(just-Ya butoxy) or poly-(tetramethylene) oxygen base-(CH ₂CH ₂CH ₂CH ₂O) _nH.Listed alcoxylates derivative is applicatory entirely, wherein with boldface type be preferred, be listed in second row.The back has provided the typical synthetic method of nonrestrictive these alkoxy derivatives of preparation.

Table VIII A

Base substance (a)	Base substance CAS No.	EO’s	1(Me-En)	2(Me-En)	PO’s	n-BO’s	BO’s
Base substance (a)	Base substance CAS No.	EO’s	1(Me-En)	2(Me-En)	PO’s	n-BO’s	BO’s			(b)	(c)	(d)	(e)	(f)	(g)
1,2-propylene glycol (C3)	57-55-6			1-4 3-4	4					(b)	(c)	(d)	(e)	(f)	(g)
1,2-propylene glycol (C3)	57-55-6			1-4 3-4	4			2-methyl 1,2-propyl alcohol (C)	558-43-0		4-10 8-10	1	3		1
1, ammediol (C3)	504-63-2			6-8 8	5-6 6			2-methyl 1,2-propyl alcohol (C)	558-43-0		4-10 8-10	1	3		1
1, ammediol (C3)	504-63-2			6-8 8	5-6 6			2,2-diethyl-1, ammediol (C7)	115-76-4	1-7 4-7			1	1-2 2
2 (C5)	126-30-7			1-2	3-4 4			2,2-diethyl-1, ammediol (C7)	115-76-4	1-7 4-7			1	1-2 2
2 (C5)	126-30-7			1-2	3-4 4			2-(1-methyl-propyl)-1, ammediol (C7)	33673-01-7	1-7 4-7			1	1-2 2
2-(2-methyl-propyl)-1, ammediol (C7)	26462-20-8	1-7 4-7			1	1-2 2		2-(1-methyl-propyl)-1, ammediol (C7)	33673-01-7	1-7 4-7			1	1-2 2
2-(2-methyl-propyl)-1, ammediol (C7)	26462-20-8	1-7 4-7			1	1-2 2		2-ethyl-1, ammediol (C5)	2612-29-5		6-10 9-10	1	3
2-ethyl-2-methyl isophthalic acid, ammediol (C6)	77-84-9		1-6 3-6		2		1	2-ethyl-1, ammediol (C5)	2612-29-5		6-10 9-10	1	3

2-sec.-propyl-1, ammediol (C6)	2612-27-3		1-6 3-6	2		1
2-sec.-propyl-1, ammediol (C6)	2612-27-3		1-6 3-6	2		1	The 2-methyl isophthalic acid, ammediol (C4)	2163-42-0		2-5 4-5	4-5 5		2
2-methyl-2-sec.-propyl-1,3-propylene glycol (C7)	2109-23-1	2-9 6-9		1	1-3 2-3		The 2-methyl isophthalic acid, ammediol (C4)	2163-42-0		2-5 4-5	4-5 5		2
2-methyl-2-sec.-propyl-1,3-propylene glycol (C7)	2109-23-1	2-9 6-9		1	1-3 2-3		2-methyl-2-propyl group-1, ammediol (C7)	78-26-2	1-7 4-7		1	1-2 2
2-propyl group 1, ammediol (C6)	2612-28-4		1-4	2		1	2-methyl-2-propyl group-1, ammediol (C7)	78-26-2	1-7 4-7		1	1-2 2

(a) numeral of the alkoxylate group of listing in the Table VIII below this table reaches is suitable for entirely, and general scope is listed in first row, and preferred range is to be listed in second row with boldface type.

(b) numeral in this hurdle is the interior (CH of derivative of polyethoxylated ₂CH ₂O) mean number of group.

(c) numeral in this hurdle is the (CH in the polyethoxylated substituting group of a methyl blocking of each derivative ₂CH ₂O) group mean number.

(d) numeral in this hurdle is the interior (CH of polyethoxylated substituting group of each two methyl blocking in each derivative ₂CH ₂O) group mean number.

(e) numeral in this hurdle is the (CH (CH in the poly-propoxylated derivative ₃) CH ₂O) mean number of group.

(f) numeral in this hurdle is group (CH in the poly-four inferior methoxylation derivatives ₂CH ₂CH ₂CH ₂O) mean number.

(g) numeral in this hurdle is group (CH (CH in the poly-butoxy derivative ₂CH ₃) CH ₂O) mean number.

Table VIII B

Base substance ^(a)	Base substance CAS No.	EO’s	1(Me-En)	2(Me-En)	PO’s	n-BO’s	BO’s
Base substance ^(a)	Base substance CAS No.	EO’s	1(Me-En)	2(Me-En)	PO’s	n-BO’s	BO’s			(b)	(c)	(d)	(e)	(f)	(g)
1,2-butyleneglycol (C4)	584-03-2		2-8 6-8		2-3		1			(b)	(c)	(d)	(e)	(f)	(g)
1,2-butyleneglycol (C4)	584-03-2		2-8 6-8		2-3		1	2,3-dimethyl-1,2-butyleneglycol (C6)	66553-15-9	1-6 2-5				1-2 1
2-ethyl-1,2-butyleneglycol (C6)	66553-16-0	1-3				1		2,3-dimethyl-1,2-butyleneglycol (C6)	66553-15-9	1-6 2-5				1-2 1
2-ethyl-1,2-butyleneglycol (C6)	66553-16-0	1-3				1		The 2-methyl isophthalic acid, 2-butyleneglycol (C5)	41051-72-3		1-2		1
3,3-dimethyl-1,2-butyleneglycol (C6)	59562-82-2	1-6 2-5				1-2 1		The 2-methyl isophthalic acid, 2-butyleneglycol (C5)	41051-72-3		1-2		1
3,3-dimethyl-1,2-butyleneglycol (C6)	59562-82-2	1-6 2-5				1-2 1		The 3-methyl isophthalic acid, 2-butyleneglycol (C5)	50468-22-9		1-2		1
1,3 butylene glycol (C4)	107-88-0			3-6 5-6	5		2	The 3-methyl isophthalic acid, 2-butyleneglycol (C5)	50468-22-9		1-2		1
1,3 butylene glycol (C4)	107-88-0			3-6 5-6	5		2	2,2,3-trimethylammonium-1,3 butylene glycol (C7)	16343-75-2		1-3		1-2 2
2,2-dimethyl-1,3 butylene glycol (C6)	76-35-7		3-8 6-8		3			2,2,3-trimethylammonium-1,3 butylene glycol (C7)	16343-75-2		1-3		1-2 2
2,2-dimethyl-1,3 butylene glycol (C6)	76-35-7		3-8 6-8		3			2,3-dimethyl-1,3 butylene glycol (C6)	24893-35-4		3-8 6-8		3
2-ethyl-1,3 butylene glycol (C6)	66553-17-1		1-6 4-6		2-3		1	2,3-dimethyl-1,3 butylene glycol (C6)	24893-35-4		3-8 6-8		3
2-ethyl-1,3 butylene glycol (C6)	66553-17-1		1-6 4-6		2-3		1	2-ethyl-2-methyl isophthalic acid, 3-butyleneglycol (C7)	Method C		1		1	2-4 3
2-ethyl-3-methyl isophthalic acid, 3-butyleneglycol (C7)	68799-03-1		1		1	2-4 3		2-ethyl-2-methyl isophthalic acid, 3-butyleneglycol (C7)	Method C		1		1	2-4 3
2-ethyl-3-methyl isophthalic acid, 3-butyleneglycol (C7)	68799-03-1		1		1	2-4 3		2-sec.-propyl-1,3 butylene glycol (C7)	66567-04-2		1		1	2-4 3

The 2-methyl isophthalic acid, 3-butyleneglycol (C5)	684-84-4			1-3 2-3	4
The 2-methyl isophthalic acid, 3-butyleneglycol (C5)	684-84-4			1-3 2-3	4			2-propyl group-1,3 butylene glycol (C7)	66567-03-1	2-9 6-8			1	1-3 2-3
The 3-methyl isophthalic acid, 3-butyleneglycol (C5)	2568-33-4			1-3 2-3	4			2-propyl group-1,3 butylene glycol (C7)	66567-03-1	2-9 6-8			1	1-3 2-3
The 3-methyl isophthalic acid, 3-butyleneglycol (C5)	2568-33-4			1-3 2-3	4			1,4-butyleneglycol (C4)	110-63-4			2-4 3-4	4-5 4-5		2
2,2,3-trimethylammonium-1,4-butyleneglycol (C7)	162108-60-3	2-9 6-9			1	1-3 2-3		1,4-butyleneglycol (C4)	110-63-4			2-4 3-4	4-5 4-5		2
2,2,3-trimethylammonium-1,4-butyleneglycol (C7)	162108-60-3	2-9 6-9			1	1-3 2-3		2,2-dimethyl-1,4-butyleneglycol (C6)	32812-23-0		1-6 3-6		2		1
2,3-dimethyl-1,4-butyleneglycol (C6)	57716-80-0		1-6 3-6		2		1	2,2-dimethyl-1,4-butyleneglycol (C6)	32812-23-0		1-6 3-6		2		1
2,3-dimethyl-1,4-butyleneglycol (C6)	57716-80-0		1-6 3-6		2		1	2-ethyl-1,4-butyleneglycol (C6)	57716-79-7		1-4		2		1
2-ethyl-2-methyl isophthalic acid, 4-butyleneglycol (C7)	76651-98-4	1-7 4-7			1	1-2 2		2-ethyl-1,4-butyleneglycol (C6)	57716-79-7		1-4		2		1
2-ethyl-2-methyl isophthalic acid, 4-butyleneglycol (C7)	76651-98-4	1-7 4-7			1	1-2 2		2-ethyl-3-methyl isophthalic acid, 4-butyleneglycol (C7)	66225-34-1	1-7 4-7			1	1-2 2
2-sec.-propyl-1,4-butyleneglycol (C7)	39497-66-0	1-7 4-7			1	1-2 2		2-ethyl-3-methyl isophthalic acid, 4-butyleneglycol (C7)	66225-34-1	1-7 4-7			1	1-2 2
2-sec.-propyl-1,4-butyleneglycol (C7)	39497-66-0	1-7 4-7			1	1-2 2		The 2-methyl isophthalic acid, 4-butyleneglycol (C5)	2938-98-9		6-10 9-10	1	3		1
2-propyl group-1,4-butyleneglycol (C7)	62946-68-3	1-5 2-5				1-2 1		The 2-methyl isophthalic acid, 4-butyleneglycol (C5)	2938-98-9		6-10 9-10	1	3		1
2-propyl group-1,4-butyleneglycol (C7)	62946-68-3	1-5 2-5				1-2 1		3-ethyl-1-methyl 1,4-butyleneglycol (C7)	Method F	2-9 6-8			1	1-3 2-3
2,3-butyleneglycol (C4)	513-85-9		6-10 9-10	1	3-4		1	3-ethyl-1-methyl 1,4-butyleneglycol (C7)	Method F	2-9 6-8			1	1-3 2-3
2,3-butyleneglycol (C4)	513-85-9		6-10 9-10	1	3-4		1	2,3-dimethyl-2,3-butyleneglycol (C6)	76-09-5	3-9 7-9			1	1-3 2-3
2-methyl-2,3-butyleneglycol (C5)	5396-58-7		1-5 2-5		2		1	2,3-dimethyl-2,3-butyleneglycol (C6)	76-09-5	3-9 7-9			1	1-3 2-3

(a) the alkoxyl group number of listing in this table is suitable for entirely, and general scope is listed in first row, and preferred range is listed in second row with boldface type.

(b) (the CH in the polyethoxylated derivative of the numeral in this hurdle ₂CH ₂O) group mean number.

(c) numeral in this hurdle is the substituent (CH of the end capped polyethoxylated of monomethyl in each derivative ₂CH ₂O) group mean number.

(d) numeral in this hurdle is (CH in the end capped polyethoxylated substituting group of each dimethyl in each derivative ₂CH ₂O) group mean number.

(e) (CH (CH in poly-propoxylated derivative of the numeral in this hurdle ₃) CH ₂O) mean number of group.

(f) numeral in this hurdle is (CH in the poly-four inferior methoxylation derivatives ₂CH ₂CH ₂CH ₂O) mean number of group.

(g) numeral in this hurdle is (CH (CH in the poly-butoxy derivative ₂CH ₃) CH ₂O) mean number of group.

Table VIII C

Base substance ^(a)	Base substance CAS No.	EO’s	1(Me-En)	2(Me-En)	PO’s	n-BO’s	BO’s
Base substance ^(a)	Base substance CAS No.	EO’s	1(Me-En)	2(Me-En)	PO’s	n-BO’s	BO’s			(b)	(c)	(d)	(e)	(f)	(g)
1,2-pentanediol (C5)	5343-92-0	3-10 7-10			1	2-3 3				(b)	(c)	(d)	(e)	(f)	(g)
1,2-pentanediol (C5)	5343-92-0	3-10 7-10			1	2-3 3		The 2-methyl isophthalic acid, 2-pentanediol (C6)	20667-05-4	1-3				1
The 3-methyl isophthalic acid, 2-pentanediol (C6)	159623-53-7	1-3				1		The 2-methyl isophthalic acid, 2-pentanediol (C6)	20667-05-4	1-3				1
The 3-methyl isophthalic acid, 2-pentanediol (C6)	159623-53-7	1-3				1		The 4-methyl isophthalic acid, 2-pentanediol (C6)	72110-08-8	1-3				1
1,3-pentanediol (C5)	3174-67-2			1-2	3-4			The 4-methyl isophthalic acid, 2-pentanediol (C6)	72110-08-8	1-3				1
1,3-pentanediol (C5)	3174-67-2			1-2	3-4			2,2-dimethyl-1,3-pentanediol (7)	2157-31-5		1		1	2-4 3
2,3-dimethyl-1,3-pentanediol (7)	66225-52-3		1		1	2-4 3		2,2-dimethyl-1,3-pentanediol (7)	2157-31-5		1		1	2-4 3

2,4-dimethyl-1,3-pentanediol (7)	60712-38-1	1		1	2-4 3
2,4-dimethyl-1,3-pentanediol (7)	60712-38-1	1		1	2-4 3		2-ethyl-1,3-pentanediol (7)	29887-11-4	2-9 6-8			1	1-3 2-3
The 2-methyl isophthalic acid, 3-pentanediol (6)	149-31-5	1-6 4-6		2-3		1	2-ethyl-1,3-pentanediol (7)	29887-11-4	2-9 6-8			1	1-3 2-3
The 2-methyl isophthalic acid, 3-pentanediol (6)	149-31-5	1-6 4-6		2-3		1	3,4-dimethyl-1,3-pentanediol (7)	129851-50-9		1		1	2-4 3
3-methyl 1,3-pentanediol (6)	33879-72-0	1-6 4-6		2-3		1	3,4-dimethyl-1,3-pentanediol (7)	129851-50-9		1		1	2-4 3
3-methyl 1,3-pentanediol (6)	33879-72-0	1-6 4-6		2-3		1	4,4 dimethyl-1,3-pentanediol (7)	30458-16-3		1		1	2-4 3
4-methyl 1,3-pentanediol (6)	54876-99-2	1-6 4-6		2-3		1	4,4 dimethyl-1,3-pentanediol (7)	30458-16-3		1		1	2-4 3
4-methyl 1,3-pentanediol (6)	54876-99-2	1-6 4-6		2-3		1	1,4-pentanediol (C5)	626-95-9			1-2	3-4
2,2-dimethyl-1,4-pentanediol (7)	Method F	1		1	2-4 3		1,4-pentanediol (C5)	626-95-9			1-2	3-4
2,2-dimethyl-1,4-pentanediol (7)	Method F	1		1	2-4 3		2,3-dimethyl-1,4-pentanediol (7)	Method F		1		1	2-4 3
2,4-dimethyl-1,4-pentanediol (7)	Method F	1		1	2-4 3		2,3-dimethyl-1,4-pentanediol (7)	Method F		1		1	2-4 3
2,4-dimethyl-1,4-pentanediol (7)	Method F	1		1	2-4 3		2-methyl 1,4-pentanediol (6)	6287-17-8		1-6 4-6		2-3		1
3,3-dimethyl-1,4-pentanediol (7)	81887-62-9	1		1	2-4 3		2-methyl 1,4-pentanediol (6)	6287-17-8		1-6 4-6		2-3		1
3,3-dimethyl-1,4-pentanediol (7)	81887-62-9	1		1	2-4 3		3,4-dimethyl-1,4-pentanediol (7)	63521-36-8		1		1	2-4 3
The 3-methyl isophthalic acid, 4-pentanediol (6)	26787-63-3	1-6 4-6		2-3		1	3,4-dimethyl-1,4-pentanediol (7)	63521-36-8		1		1	2-4 3
The 3-methyl isophthalic acid, 4-pentanediol (6)	26787-63-3	1-6 4-6		2-3		1	4-methyl 1,4-pentanediol (6)	1462-10-8		1-6 4-6		2-3		1
1,5-pentanediol (C5)	111-29-5	4-10 8-10	1	3			4-methyl 1,4-pentanediol (6)	1462-10-8		1-6 4-6		2-3		1

2,2-dimethyl-1,5-pentanediol (7)	3121-82-2	1-7 4-7		1	1-2 2
2,2-dimethyl-1,5-pentanediol (7)	3121-82-2	1-7 4-7		1	1-2 2	2,3-dimethyl-1,5-pentanediol (7)	81554-20-3	1-7 4-7			1	1-2 2
2,4-dimethyl-1,5-pentanediol (7)	2121-69-9	1-7 4-7		1	1-2 2	2,3-dimethyl-1,5-pentanediol (7)	81554-20-3	1-7 4-7			1	1-2 2
2,4-dimethyl-1,5-pentanediol (7)	2121-69-9	1-7 4-7		1	1-2 2	2-ethyl-1,5-pentanediol (7)	14189-13-0	1-5 2-5				1-2 1
2-methyl 1,5-pentanediol (6)	42856-62-2		1-4	2		2-ethyl-1,5-pentanediol (7)	14189-13-0	1-5 2-5				1-2 1
2-methyl 1,5-pentanediol (6)	42856-62-2		1-4	2		3,3-dimethyl-1,5-pentanediol (7)	53120-74-4	1-7 4-7			1	1-2 2
3-methyl 1,5-pentanediol (6)	4457-71-0		1-4	2		3,3-dimethyl-1,5-pentanediol (7)	53120-74-4	1-7 4-7			1	1-2 2
3-methyl 1,5-pentanediol (6)	4457-71-0		1-4	2		2,3-pentanediol (C5)	42027-23-6		1-3		2
2-methyl-2,3-pentanediol (6)	7795-80-4	1-7 4-7		1	1-2 2	2,3-pentanediol (C5)	42027-23-6		1-3		2
2-methyl-2,3-pentanediol (6)	7795-80-4	1-7 4-7		1	1-2 2	3-methyl-2,3-pentanediol (6)	63521-37-9	1-7 4-7			1	1-2 2
4-methyl 2,3-pentanediol (6)	7795-79-1	1-7 4-7		1	1-2 2	3-methyl-2,3-pentanediol (6)	63521-37-9	1-7 4-7			1	1-2 2
4-methyl 2,3-pentanediol (6)	7795-79-1	1-7 4-7		1	1-2 2	2,4-pentanediol (C5)	625-69-4			1-4 2-4	4
2,3-dimethyl-2,4-pentanediol (7)	24893-39-8		1-4 2-4	2		2,4-pentanediol (C5)	625-69-4			1-4 2-4	4
2,3-dimethyl-2,4-pentanediol (7)	24893-39-8		1-4 2-4	2		2,4-dimethyl-2,4-pentanediol (7)	24892-49-7		1-4 2-4		2
2-methyl 2,4-pentanediol (6)	107-41-5		5-10 8-10	3		2,4-dimethyl-2,4-pentanediol (7)	24892-49-7		1-4 2-4		2
2-methyl 2,4-pentanediol (6)	107-41-5		5-10 8-10	3		3,3-dimethyl-2,4-pentanediol (7)	24892-50-0		1-4 2-4		2
3-methyl-2,4-pentanediol (6)	Method H		5-10 8-10	3		3,3-dimethyl-2,4-pentanediol (7)	24892-50-0		1-4 2-4		2

(a) number of the alkoxylate group of listing in this table is suitable for entirely, and general range is listed in first row, and preferable range is listed in second row with boldface type.

(b) numeral in this hurdle is (CH in the polyethoxylated derivative ₂CH ₂O) group mean number.

(c) numeral in this hurdle is the interior (CH of the end capped polyethoxylated derivative of monomethyl in each derivative ₂CH ₂O) mean number of group.

(d) numeral in this hurdle is the interior (CH of the end capped polyethoxylated derivative of each dimethyl in each derivative ₂CH ₂O) mean number of group.

(e) numeral in this hurdle is (CH (CH in the poly-propoxylated derivative ₃) CH ₂O) mean number of group.

(f) numeral in this hurdle is the (CH in the poly-four inferior methoxylation derivatives ₂CH ₂CH ₂CH ₂O) group mean number.

Table VIII D

Base substance ^(a)	Base substance CAS No.	EO’s	1(Me-En)	PO’s	n-BO’s	BO’s
Base substance ^(a)	Base substance CAS No.	EO’s	1(Me-En)	PO’s	n-BO’s	BO’s			(b)	(c)	(e)	(f)	(g)
1,3-hexylene glycol (C6)	21531-91-9		1-5 2-5	2		1			(b)	(c)	(e)	(f)	(g)
1,3-hexylene glycol (C6)	21531-91-9		1-5 2-5	2		1	The 2-methyl isophthalic acid, 3-hexylene glycol (C7)	66072-21-7	2-9 6-8		1	1-3 2-3	1
The 3-methyl isophthalic acid, 3-hexylene glycol (C7)	Method D	2-9 6-8		1	1-3 2-3		The 2-methyl isophthalic acid, 3-hexylene glycol (C7)	66072-21-7	2-9 6-8		1	1-3 2-3	1
The 3-methyl isophthalic acid, 3-hexylene glycol (C7)	Method D	2-9 6-8		1	1-3 2-3		The 4-methyl isophthalic acid, 3-hexylene glycol (C7)	Method C	2-9 6-8		1	1-3 2-3
The 5-methyl isophthalic acid, 3-hexylene glycol (C7)	109863-14-1	2-9 6-8		1	1-3 2-3		The 4-methyl isophthalic acid, 3-hexylene glycol (C7)	Method C	2-9 6-8		1	1-3 2-3
The 5-methyl isophthalic acid, 3-hexylene glycol (C7)	109863-14-1	2-9 6-8		1	1-3 2-3		1,4-hexylene glycol (C6)	16432-53-4		1-5 2-5	2		1
The 2-methyl isophthalic acid, 4-hexylene glycol (C7)	Method F	2-9 6-8		1	1-3 2-3		1,4-hexylene glycol (C6)	16432-53-4		1-5 2-5	2		1

The 3-methyl isophthalic acid, 4-hexylene glycol (C7)	66225-36-3	2-9 6-8		1	1-3 2-3
The 3-methyl isophthalic acid, 4-hexylene glycol (C7)	66225-36-3	2-9 6-8		1	1-3 2-3	The 4-methyl isophthalic acid, 4-hexylene glycol (C7)	40646-08-0	2-9 6-8		1	1-3 2-3
The 5-methyl isophthalic acid, 4-hexylene glycol (C7)	38624-36-1	2-9 6-8		1	1-3 2-3	The 4-methyl isophthalic acid, 4-hexylene glycol (C7)	40646-08-0	2-9 6-8		1	1-3 2-3
The 5-methyl isophthalic acid, 4-hexylene glycol (C7)	38624-36-1	2-9 6-8		1	1-3 2-3	1,5-hexylene glycol (C6)	928-40-5		1-5 2-5	2		1
The 2-methyl isophthalic acid, 5-hexylene glycol (C7)	Method F	2-9 6-8		1	1-3 2-3	1,5-hexylene glycol (C6)	928-40-5		1-5 2-5	2		1
The 2-methyl isophthalic acid, 5-hexylene glycol (C7)	Method F	2-9 6-8		1	1-3 2-3	The 3-methyl isophthalic acid, 5-hexylene glycol (C7)	Method F	2-9 6-8		1	1-3 2-3
The 4-methyl isophthalic acid, 5-hexylene glycol (C7)	66225-37-4	2-9 6-8		1	1-3 2-3	The 3-methyl isophthalic acid, 5-hexylene glycol (C7)	Method F	2-9 6-8		1	1-3 2-3
The 4-methyl isophthalic acid, 5-hexylene glycol (C7)	66225-37-4	2-9 6-8		1	1-3 2-3	The 5-methyl isophthalic acid, 5-hexylene glycol (C7)	1462-11-9	2-9 6-8		1	1-3 2-3
1,6-hexylene glycol (C6)	629-11-8		1-2	1-2	4	The 5-methyl isophthalic acid, 5-hexylene glycol (C7)	1462-11-9	2-9 6-8		1	1-3 2-3
1,6-hexylene glycol (C6)	629-11-8		1-2	1-2	4	The 2-methyl isophthalic acid, 6-hexylene glycol (C7)	25258-92-8	1-5 2-5			1-2 1
The 3-methyl isophthalic acid, 6-hexylene glycol (C7)	4089-71-8	1-5 2-5			1-2 1	The 2-methyl isophthalic acid, 6-hexylene glycol (C7)	25258-92-8	1-5 2-5			1-2 1
The 3-methyl isophthalic acid, 6-hexylene glycol (C7)	4089-71-8	1-5 2-5			1-2 1	2,3-hexylene glycol (C6)	617-30-1	1-5 2-5			1-2 1
2,4-hexylene glycol (C6)	19780-90-6		3-8 5-8	3		2,3-hexylene glycol (C6)	617-30-1	1-5 2-5			1-2 1
2,4-hexylene glycol (C6)	19780-90-6		3-8 5-8	3		2-methyl-2,4-hexylene glycol (C7)	66225-35-2		1-2	1-2
3-methyl-2,4-hexylene glycol (C7)	116530-79-1		1-2	1-2		2-methyl-2,4-hexylene glycol (C7)	66225-35-2		1-2	1-2

4-methyl-2,4-hexylene glycol (C7)	38836-25-8	1-2	1-2
4-methyl-2,4-hexylene glycol (C7)	38836-25-8	1-2	1-2	5-methyl-2,4-hexylene glycol (C7)	54877-00-8		1-2	1-2
2,5-hexylene glycol (C6)	2935-44-6	3-8 5-8	3	5-methyl-2,4-hexylene glycol (C7)	54877-00-8		1-2	1-2
2,5-hexylene glycol (C6)	2935-44-6	3-8 5-8	3	2-methyl-2,5-hexylene glycol (C7)	29044-06-2		1-2	1-2
3-methyl-2,5-hexylene glycol (C7)	Method H	1-2	1-2	2-methyl-2,5-hexylene glycol (C7)	29044-06-2		1-2	1-2
3-methyl-2,5-hexylene glycol (C7)	Method H	1-2	1-2	3,4-hexylene glycol (C6)	922-17-8	1-5 2-5			1

(a) numeral of the alkoxylate group of listing in this table is suitable for entirely, and general range is listed in first row, and preferable range is listed in second row with boldface type.

(b) numeral in this hurdle is (CH in the polyethoxylated derivative ₂CH ₂O) mean number of group.

(c) numeral in this hurdle is the interior (CH of the end capped polyethoxylated substituting group of monomethyl in each derivative ₂CH ₂O) mean number of group.

(e) numeral in this hurdle is the (CH (CH in the poly-propoxylated derivative ₃) CH ₂O) group mean number.

(g) numeral in this hurdle is (CH (CH in the poly-butoxy derivative ₂CH ₃) CH ₂O) group mean number.

Table VIII E

Base substance ^(a)	Base substance CAS No.	EO’s	1(Me-En)	PO’s	n-BO’s
Base substance ^(a)	Base substance CAS No.	EO’s	1(Me-En)	PO’s	n-BO’s			(b)	(c)	(e)	(f)
1,3-heptanediol (C7)	23433-04-7	1-7 3-6		1	1-2 2			(b)	(c)	(e)	(f)
1,3-heptanediol (C7)	23433-04-7	1-7 3-6		1	1-2 2	1,4-heptanediol (C7)	40646-07-9	1-7 3-6		1	1-2 2
1,5-heptanediol (C7)	60096-09-5	1-7 3-6		1	1-2 2	1,4-heptanediol (C7)	40646-07-9	1-7 3-6		1	1-2 2
1,5-heptanediol (C7)	60096-09-5	1-7 3-6		1	1-2 2	1,6-heptanediol (C7)	13175-27-4	1-7 3-6		1	1-2 2
1,7-heptanediol (C7)	629-30-1	1-2			1	1,6-heptanediol (C7)	13175-27-4	1-7 3-6		1	1-2 2
1,7-heptanediol (C7)	629-30-1	1-2			1	2,4-heptanediol (C7)	20748-86-1	3-10 7-10	1	1	3
2,5-heptanediol (C7)	70444-25-6	3-10 7-10	1	1	3	2,4-heptanediol (C7)	20748-86-1	3-10 7-10	1	1	3
2,5-heptanediol (C7)	70444-25-6	3-10 7-10	1	1	3	2,6-heptanediol (C7)	5969-12-0	3-10 7-10	1	1	3
3,5-heptanediol (C7)	86632-40-8	3-10 7-10	1	1	3	2,6-heptanediol (C7)	5969-12-0	3-10 7-10	1	1	3

Table I X

Aromatic diol

Suitable aromatic diol comprises: chemical name CAS No. The aromatic diol that is suitable for1-phenyl-1,2-ethylene glycol 93-56-11-phenyl-1,2-propylene glycol 1855-09-02-phenyl-1,2-propylene glycol 87760-50-73-phenyl-1,2-propylene glycol 17131-14-51-(3-aminomethyl phenyl)-1, ammediol 51699-43-51-(4-aminomethyl phenyl)-1, ammediol 159266-06-52-methyl isophthalic acid-phenyl-1, ammediol 139068-60-31-phenyl-1,3-butyleneglycol 118100-60-03-phenyl-1,3-butyleneglycol 68330-54-11-phenyl-1,4-butyleneglycol 136173-88-12-phenyl-1,4-butyleneglycol 95840-73-61-phenyl-2,3-butyleneglycol 169437-68-7 Preferred aromatic diol1-phenyl-1,2-ethylene glycol 93-56-11-phenyl-1,2-propylene glycol 1855-09-02-phenyl-1,2-propylene glycol 87760-50-73-phenyl-1,2-propylene glycol 17131-14-51-(3-aminomethyl phenyl)-1, ammediol 51699-43-51-(4-aminomethyl phenyl)-1, ammediol 159266-06-52-methyl isophthalic acid-phenyl-1, ammediol 139068-60-31-phenyl-1,3-butyleneglycol 118100-60-03-phenyl-1,3-butyleneglycol 68330-54-11-phenyl-1,4-butyleneglycol 136173-88-1 Preferred aromatic diol1-phenyl-1,2-propylene glycol 1855-09-02-phenyl-1,2-propylene glycol 87760-50-73-phenyl-1,2-propylene glycol 17131-14-51-(3-aminomethyl phenyl)-1, ammediol 51699-43-51-(4-aminomethyl phenyl)-1, ammediol 159266-06-52-methyl isophthalic acid-phenyl-1, ammediol 139068-60-33-phenyl-1,3-butyleneglycol 68330-54-11-phenyl-1,4-butyleneglycol 136173-88-1 Inapplicable aromatic diol1-phenyl-1, ammediol 2-phenyl-1, ammediol 1-phenyl-1,2-butyleneglycol 154902-08-62-phenyl-1,2-butyleneglycol 157008-55-43-phenyl-1,2-butyleneglycol 141505-72-84-phenyl-1,2-butyleneglycol 143615-31-02-phenyl-1,3-butyleneglycol 103941-94-24-phenyl-1,3-butyleneglycol 81096-91-52-phenyl-2,3-butyleneglycol 138432-94-7X. also can use as the homologue of above structure or the main solvent of analogue, and wherein the hydrogen atom sum is owing to add one or more additional CH ₂Group and increasing, but keep the hydrogen atom sums identical by introducing two keys, the example comprises following known compound:

Table X

Unsaturated compound Shi example The unsaturated diol of Shi Yong1,3 - propanediol, 2,2 - di-2 - propenyl - 55038-13-6 1,3 - propanediol, 2 - (1 - pentenyl) - 138436-18-7 1,3 - propanediol, 2 - (2 - methyl - 2 - propenyl) -2 - (propenyl) - 121887-76-1 1,3 - propanediol, 2 - (3 - methyl-1 - butenyl) - 138436-17-6 1,3 - propanediol, 2 - (4 - pentenyl) - 73012-46-1 1,3 - propanediol, 2 - ethyl-2 - (2 - methyl - 2 - propenyl) - 91367-61-2 1,3 - propanediol, 2 - ethyl-2 - (2 - propenyl) - 27606-26-4 1,3 - propanediol, 2 - methyl -2 - (3 - methyl - 3 - butenyl) - 132130-95-1 1,3 - butanediol, 2,2 - diallyl - 103985-49-5 1,3 - butanediol, 2 - (1 - ethyl-1 - propenyl) - 116103-35-6 1,3 - butanediol, 2 - (2 - butenyl)-2 - methyl - 92207-83-5 1,3 - butanediol, 2 - (3 - methyl - 2 - butenyl) - 98955-19-2 1,3 - butanediol, 2 - ethyl-2 - (2 - propenyl) - 122761-93-7 1,3 - butanediol, 2 - methyl -2 - (1 - methyl - 2 - propenyl) - 141585-58-2 1,4 - butanediol, 2,3 - bis (1 - methylethylidene) - 52127-63-6 1,4 - butanediol, 2 - (3 - methyl - 2 - butenyl)-3 - methylene - 115895-78-8 2 - butene-1, 4 - diol, 2 - (1,1 - dimethyl-propyl) - 91154-01-7 2 - butene-1, 4 - diol, 2 - (1 - dimethylpropyl) - 91154-00-6 2 - butene-1, 4 - diol, 2 - butyl 153943-66-9 1,3 - pentanediol, 2 - vinyl-3 - ethyl - 104683-37-6 1,3 - pentanediol, 2 - vinyl-4 ,4 - dimethyl - 143447-08-9 1,4 - pentanediol, 3 - methyl - 2 - (2 - propenyl) - 139301-86-3 1,5 - pentanediol, 2 - (1 - propenyl) - 84143-44-2 1,5 - pentanediol, 2 - (2 - propenyl) - 134757-01-0 1,5 - pentanediol, 2 - ethylidene-3 - methyl - 42178-93-8 1,5 - pentanediol, 2 - propylene - 58203-50-2 2,4 - pentanediol, 3 - ethylidene-2 ,4 - dimethyl - 88610-19-9 4 - pentyl-1 ,3 - diol, 2 - (1,1 - dimethylethyl) - 109788-04-7 4 - pentyl-1 ,3 - diol, 2 - ethyl -2,3 - dimethyl - 90676-97-4 1,4 - hexanediol 4 - ethyl-2 - methylene - 66950-87-6 1,5 - hexadiene-3 ,4 - diol, 2,3,5 - trimethyl - 18984-03-7 1,5 - hexadiene-3 ,4 - diol, 5 - ethyl-3 - methyl - 18927-12-3 1,5 - hexanediol, 2 - (1 - methyl-ethenyl) - 96802-18-5 1,6 - diol, 2 - vinyl - 66747-31-7 1 - hexene-3 ,4 - diol, 5,5 - dimethyl - 169736-29-2 1 - hexene-3 ,4 - diol, 5,5 - dimethyl - 120191-04-0 2 - hexene 1,5 - diol, 4 - vinyl 2,5 - dimethyl - 70101-76-7 3 - hexene-1 ,6 - diol, 2 - vinyl-2 ,5 - dimethyl - 112763-52-7 3 - hexene-1 ,6 - diol, 2 - ethyl - 84143-45-3 3 - hexene-1 ,6 - diol, 3,4 - dimethyl - 125032-66-8 4 - Hexene-2 ,3 - diol, 2,5 - dimethyl - 13295-61-9 4 - Hexene-2 ,3 - diol, 3,4 - dimethyl - 135367-17-8 5 - hexyl-1 ,3 - diol, 3 - (2 - propenyl) - 74693-24-6 5 - Hexene-2 ,3 - diol, 2,3 - dimethyl - 154386-00-2 5 - Hexene-2 ,3 - diol, 3,4 - dimethyl - 135096-13-8 5 - Hexene-2 ,3 - diol, 3,5 - dimethyl - 134626-63-4 5 - hexene 2,4 - hexanediol, 3 - vinyl -2,5 - dimethyl - 155751-24-9 1,4 - heptanediol, 6 - methyl-5 - methylene - 100590-29-2 1,5 - heptadiene ,4 - diol, 2,3 - dimethyl - 18927-06-5 1,5 - heptadiene ,4 - diol, 2,5 - dimethyl - 22607-16-5 1,5 - heptadiene ,4 - diol, 3,5 - dimethyl - 18938-51-7 1,7 - heptane diol, 2,6 - bis (methylene) - 139618-24-9 1,7 - heptanediol, 4 - methylene - 71370-08-6 1 - heptene-3, 5 - diol, 2,4 - dimethyl - 155932-77-7 1 - heptene-3, 5 - diol, 2,6 - dimethyl - 132157-35-8 1 - heptene 3,5 - hexanediol, 3 - vinyl-5 - methyl - 61841-10-9 1 - heptene 3,5 - diol, 6,6 - dimethyl - 109788-01-4 2,4 - heptadiene ,6 - diol, 4,6 - dimethyl - 102605-95-8 2,5 - heptane-1 ,7-diene - diol, 4,4 - dimethyl - 162816-19-5 2,6 - Heptadiene -1,4 - diol, 2,5,5 - trimethyl - 115346-30-0 2 - heptene-1, 4 - diol, 5,6 - dimethyl - 103867-76-1 2 - heptene 1,5 - diol, 5 - ethyl - 104683-39-8 2 - heptene-1 ,7 - diol, 2 - methyl - 74868-68-1 3 - heptene 1,5 - diol, 4,6 - dimethyl - 147028-45-3 3 - heptene-1 ,7 - hexanediol, 3 - methyl-6 - methylene - 109750-55-2 3 - heptene 2,5 - diol, 2,4 - dimethyl - 98955-40-9 3 - heptene 2,5 - diol, 2,5 - dimethyl - 24459-23-2 3 - heptene-2, 6 - diol, 2,6 - dimethyl - 160524-66-3 3 - heptene-2, 6 - diol, 4,6 - dimethyl - 59502-66-8 5 - heptene-1 ,3 - diol, 2,4 - dimethyl - 123363-69-9 5 - heptene 1,3 - diol, 3,6 - dimethyl - 96924-52-6 5 - heptene-1, 4 - diol, 2,6 - dimethyl - 106777-98-4 5 - heptene-1, 4 - diol, 3,6 - dimethyl - 106777-99-5 5 - heptene-2, 4 - diol, 2,3 - dimethyl - 104651-56-1 6 - heptene-1 ,3 - diol, 2,2 - dimethyl - 140192-39-8 6 - heptene-1, 4 - diol, 4 - (2 - propenyl) - 1727-87-3 6 - heptene-1, 4 - diol, 5,6 - dimethyl - 152344-16-6 6 - heptene 1,5 - diol, 2,4 - dimethyl - 74231-27-9 6 - heptene 1,5 - diol, 2 - ethyl-6 alkylene - methyl - 91139-73-0 6 - heptene-2, 4 - diol, 4 - (2 - propenyl) - 101536-75-8 6 - heptene-2, 4 - diol, 5,5 - dimethyl - 98753-77-6 6 - heptene 2,5 - diol, 4,6 - dimethyl - 134876-94-1 6 - heptene 2,5 - diol, 5 - vinyl-4 - methyl - 65757-31-5 1,3 - octanediol 2 - methylene - 108086-78-8 1,6 - octadiene, 3,5 - hexanediol, 2,6 - dimethyl - 91140-06-6 1,6 - octadiene, 3,5 - hexanediol, 3,7 - dimethyl - 75654-19-2 1,7 - octadiene-3 ,6 - diol, 2,6 - dimethyl - 51276-33-6 1,7 - octadiene 3,6 - diol, 2,7 - dimethyl - 26947-10-4 1,7 - octadiene 3,6 - diol, 3,6 - dimethyl - 31354-73-1 1 - octene-3, 6 - hexanediol, 3 - vinyl - 65757-34-8 2,4,6 - octatrienyl -1,8 - diol, 2,7 - dimethyl - 162648-63-7 2,4 - octadiene, 1,7 - hexanediol, 3,7 - dimethyl - 136054-24-5 2,5 - octadiene, 1,7 - hexanediol, 2,6 - dimethyl - 91140-07-7 2,5 - octadiene, 1,7 - hexanediol, 3,7 - dimethyl - 117935-59-8 2,6 - octadiene, 1,4 - diol, 3,7 - dimethyl - (Rosiridol) 101391-01-9 2,6 - octadiene-1 ,8 - diol, 2 - methyl - 149112-02-7 2,7 - octadiene, 1,4 - diol, 3,7 - dimethyl - 91140-08-8 2,7 - octadiene, 1,5 - hexanediol, 2,6 - dimethyl - 91140-09-9 2,7 - octadiene-1 ,6 - diol, 2,6 - dimethyl - (8 - hydroxy linalool) - 103619-06-3 2,7 - octadiene 1,6 - diol, 2,7 - dimethyl - 60250-14-8 2 - octene 1,4 - diol 40735-15-7 2 - octene -1,7 - diol 73842-95-2 2 - octene-1 ,7 - diol, 2 - methyl-6 - methylene - 91140-168 3,5 - octadiene, 1,7 - hexanediol, 3,7 - dimethyl - 62875-09-6 3,5 - octadiene 2,7 - diol, 2,7 - dimethyl - 7177-18-6 3,5 - octanediol -4 - methylene - 143233-15-2 3,7 - octadiene-1 ,6 - diol, 2,6 - dimethyl - 127446-29-1 3,7 - octadiene 2,5 - diol, 2,7 - dimethyl - 171436-39-8 3,7 - octadiene-2 ,6 - diol, 2,6 - dimethyl - 150283-67-3 3 - Octene-1 ,5 - diol, 4 - methyl - 147028-43-1 3 - Octene-1 ,5 - diol, 5 - methyl - 19764-77-3 4,6 - octadiene, 1,3 - hexanediol, 2,2 - dimethyl - 39824-01-6 4,7 - octadiene, 2,3 - hexanediol, 2,6 - dimethyl - 51117-38-5 4,7 - octadiene-2 ,6 - diol, 2,6 - dimethyl - 59076-71-0 4 - octene 1,6 - diol 7 - methyl - 84538-24-9 4 - octene-1 ,8 - diol, 2,7 - bis (methylene) - 109750-56-3 4 - octene-1 ,8 - diol, 2 - methylene - 109750-58-5 5,7 - octadiene 1,4 - diol, 2,7 - dimethyl - 105676-78-6 5,7 - octadiene 1,4 - diol 7 - methyl - 105676-80-0 5 - octene-1 ,3 - diol, 130272-38-7 6 - octene-1 ,3 - diol 7 - methyl - 110971-19-2 6 - octene 1,4 - diol 7 - methyl - 152715-87-2 6 - octene 1,5 - diol 145623-79-6 6 - octene 1,5 - diol 7 - methyl - 116214-61-0 6 - octene-3, 5 - diol, 2 - methyl - 65534-66-9 6 - octene-3, 5 - diol, 4 - methyl - 156414-25-4 7 - oct-1 ,3 - diol, 2 - methyl - 155295-38-8 7 - octene-1 ,3 - diol 4 - methyl - 142459-25-4 7 - octene-1 ,3 - diol 7 - methyl - 132130-96-2 7 - octene 1,5 - diol 7310-51-2 7 - octene 1,6 - diol 159099-43-1 7 - octene 1,6 - diol and 5 - methyl - 144880-56-8 7 - octene, 2,4 - diol, 2 - methyl-6 - methylene - 72446-81-2 7 - octene 2,5 - diol 7 - methyl - 152344-12-2 7 - octene, 3,5 - diol, 2 - methyl - 98753-85-6 1 - nonene 3,5 - diol 119554-56-2 1 - nonene -3,7 - diol 23866-97-9 3 - nonene 2,5 - diol 165746-84-9 4,6 - diene-nonyl-1 ,3 - diol 8 - methyl - 124099-52-1 4 - nonene -2,8 - diol 154600-80-3 6,8 - nonadiene -1,5 - diol 108586-03-4 7 - nonene 2,4 - diol 30625-41-3 8 - nonene 2,4 - diol 119785-59-0 8 - nonene 2,5 - diol 132381-58-9 1,9 - decadiene -3,8 - diol 103984-04-9 1,9 - decadiene -4,6 - diol 138835-67-3 ...The unsaturated diol of You Xuan1, the 3-butanediol, 2, 2-diallyl-103985-49-5 1, the 3-butanediol, 2-(1-Yi base-1-acrylic)-116103-35-6 1, the 3-butanediol, 2-(2-cyclobutenyl)-2-methyl-92207-83-5 1, the 3-butanediol, 2-(3-methyl-2-cyclobutenyl)-98955-19-2 1, the 3-butanediol, 2-Yi base-2-(2-acrylic)-122761-93-7 1, the 3-butanediol, 2-methyl-2-(1-methyl-2-acrylic)-141585-58-2 1, the 4-butanediol, 2, 3-two (1-methyl Ya Yi yl)-52127-63-6 1, 3-Wu glycol, 2-Yi thiazolinyl-3-Yi base-104683-37-6 1, 3-Wu glycol, 2-Yi thiazolinyl-4, 4-dimethyl-143447-08-9 1, 4-Wu glycol, 3-methyl-2-(2-acrylic)-139301-86-3 4-Wu Xi-1, the 3-glycol, 2-(1, 1-dimethyl Yi yl)-109788-04-7 4-Wu Xi-1, the 3-glycol, 2-Yi base-2, 3-dimethyl-90676-97-4 1, the 4-hexylene glycol, 4-Yi base-2-methylene base-66950-87-6 1, 5-hexadiene-3, the 4-glycol, 2, 3, 5-San methyl-18984-03-7 1, the 5-hexylene glycol, 2-(1-ethylene methacrylic base)-96802-18-5 2-hexene-1, the 5-glycol, 4-Yi thiazolinyl-2, 5-dimethyl-70101-76-7 1, the 4-heptandiol, 6-methyl-5-methylene base-100590-29-2 2, 4-heptadiene-2, the 6-glycol, 4, 6-dimethyl-102605-95-8 2, 6-heptadiene-1, the 4-glycol, 2, 5, 5-San methyl-115346-30-0 2-heptene-1, the 4-glycol, 5, 6-dimethyl-103867-76-1 3-heptene-1, the 5-glycol, 4, 6-dimethyl-147028-45-3 5-heptene-1, the 3-glycol, 2, 4-dimethyl-123363-69-9 5-heptene-1, the 3-glycol, 3, 6-dimethyl-96924-52-6 5-heptene-1, the 4-glycol, 2, 6-dimethyl-106777-98-4 5-heptene-1, the 4-glycol, 3, 6-dimethyl-106777-99-5 6-heptene-1, the 3-glycol, 2, 2-dimethyl-140192-39-8 6-heptene-1, the 4-glycol, 5, 6-dimethyl-152344-16-6 6-heptene-1, the 5-glycol, 2, 4-dimethyl-74231-27-9 6-heptene-1, the 5-glycol, 2-Ya Yi base-6-methyl-91139-73-0 6-heptene-2, the 4-glycol, 4-(2-acrylic)-101536-75-8 1-Xin Xi-3, the 6-glycol, 3-Yi thiazolinyl-65757-34-8 2, 4, 6-Xin San Xi-1, the 8-glycol, 2, 7-dimethyl-162648-63-7 2, 5-Xin diene-1, the 7-glycol, 2, 6-dimethyl-91140-07-7 2, 5-Xin diene-1, the 7-glycol, 3, 7-dimethyl-117935-59-8 2, 6-Xin diene-1, the 4-glycol, 3, the 101391-01-9 2 of 7-dimethyl-(Rosiridol), 6-Xin diene-1, the 8-glycol, 2-methyl-149112-02-7 2, 7-Xin diene-1, the 4-glycol, 3, 7-dimethyl-91140-08-8 2, 7-Xin diene-1, the 5-glycol, 2, 6-dimethyl-91140-09-9 2, 7-Xin diene-1, the 6-glycol, 2, 6-dimethyl-(8-Qiang base linalool)-103619-06-3 2, 7-Xin diene-1, the 6-glycol, 2, 7-dimethyl-60250-14-8 2-Xin Xi-1, the 7-glycol, 2-methyl-6-methylene base-91140-16-8 3, 5-Xin diene-2, the 7-glycol, 2, 7-dimethyl-7177-18-6 3, 5-ethohexadiol-4-methylene base-143233-15-2 3, 7-Xin diene-1, the 6-glycol, 2, 6-dimethyl-127446-29-1 4-Xin Xi-1, the 8-glycol, 2-methylene base-109750-58-5 6-Xin Xi-3, the 5-glycol, 2-methyl-65534-66-9 6-Xin Xi-3, the 5-glycol, 4-methyl-156414-25-4 7-Xin Xi-2, the 4-glycol, 2-methyl-6-methylene base-72446-81-2 7-Xin Xi-2, the 5-glycol, 7-methyl-152344-12-2 7-Xin Xi-3, the 5-glycol, 2-methyl-98753-85-6 1-Ren Xi-3, 5-glycol 119554-56-2 1-Ren Xi-3, 7-glycol 23866-97-9 3-Ren Xi-2, 5-glycol 165746-84-9 4-Ren Xi-2, 8-glycol 154600-80-3 6, 8-Ren diene-1, 5-glycol 108586-03-4 7-Ren Xi-2, 4-glycol 30625-41-3 8-Ren Xi-2, 4-glycol 119785-59-0 8-Ren Xi-2, 5-glycol 132381-58-9 1, 9-decadinene-3, 8-glycol 103984-04-9 1, 9-decadinene-4, the mixture of 6-glycol 138835-67-3 and XI. Ta

C _1-2Monohydroxy-alcohol can not provide the transparent dense fabric softener composition on the meaning of the present invention.Has only a kind of C ₃Monohydroxy-alcohol (n-propyl alcohol) is forming transparent product and is keeping transparent in about 20 ℃ or have qualified performance aspect the recovery when being warmed to room temperature again, but it has unfavorable lower boiling.At C ₄In the monohydroxy-alcohol, have only 2-butanols and 2-methyl-2-propyl alcohol to have good performance, but 2-methyl-2-propyl alcohol have unfavorable lower boiling.Except top and the unsaturated monohydroxy-alcohol mentioned later, C _5-6Monohydroxy-alcohol can not form transparent product.

Find that some main solvent that two hydroxyls are arranged is suitable for preparing liquid state of the present invention, dense, transparent fabric softener composition in chemical formula.The suitability of various main solvents has selectivity astoundingly, and this depends on the number of carbon atom, the molecule isomer configuration that same carbon atoms number is arranged, degree of unsaturation etc.The main solvent that has similar dissolubility property and at least some asymmetry with above main solvent will have same benefit.The ClogP value of finding suitable main solvent is about 0.64 for about 0.15-, and preferably about 0.25-is about 0.62, and more preferably from about 0.40-about 0.60.

For example, for general formula HO-CH ₂-CHOH-(CH ₂) _n1 of-H, 2-alkanediol, n are 1-8, have only 1, the ClogP value of 2-hexylene glycol (n=4) is about 0.53, and it is in effective ClogP scope of about 0.15-about 0.64, this solvent is a kind of good main solvent, belong within the claim scope of the present invention, and the ClogP value exceeds other glycol outside the useful range 0.15-0.64, for example 1,2-propylene glycol, 1,2-butyleneglycol, 1,2-pentanediol, 1,2-ethohexadiol, 1, the 2-decanediol then is not.In addition, among the isomer of hexylene glycol, 1, the 2-hexylene glycol is good main solvent, and the ClogP value exceeds a lot of other isomer outside the useful range 0.15-0.64 as 1,3-hexylene glycol, 1,4-hexylene glycol, 1,5-hexylene glycol, 1,6-hexylene glycol, 2,4-hexylene glycol and 2, the 5-hexylene glycol then is not.These are by embodiment and comparative examples I-A and I-B explanation (seeing below).

C ₃-C ₅Dibasic alcohol can not form the transparent concentrated composition on the meaning of the present invention.

Though a lot of C are arranged ₆Dibasic alcohol is possible isomer, but has only just being fit to of listing above to prepare transparent product, and wherein has only 2,3-dimethyl-1,2-butyleneglycol; 3,3-dimethyl-1,2-butyleneglycol; 2-methyl-2, the 3-pentanediol; 3-methyl-2, the 3-pentanediol; 4-methyl-2, the 3-pentanediol; 2, the 3-hexylene glycol; 3, the 4-hexylene glycol; 2-ethyl-1, the 2-butyleneglycol; The 2-methyl isophthalic acid, the 2-pentanediol; The 3-methyl isophthalic acid, the 2-pentanediol; The 4-methyl isophthalic acid, the 2-pentanediol; With 1, the 2-hexylene glycol is preferred, most preferably: 2-ethyl-1,2-butyleneglycol; The 2-methyl isophthalic acid, the 2-pentanediol; The 3-methyl isophthalic acid, the 2-pentanediol; The 4-methyl isophthalic acid, the 2-pentanediol; With 1, the 2-hexylene glycol.

C ₇The possible isomer of glycol is more, but just list those can form transparent product, preferably: 2-butyl-1,3 butylene glycol; 2-propyl group-1, the 4-butyleneglycol; 2-ethyl-1, the 5-pentanediol; 2,3-dimethyl-2,3-pentanediol; 2,4-dimethyl-2,3-pentanediol; 4,4-dimethyl-2,3-pentanediol; 2,3-dimethyl-3,4-pentanediol; The 2-methyl isophthalic acid, the 6-hexylene glycol; The 3-methyl isophthalic acid, the 6-hexylene glycol; 1, the 3-heptanediol; 1, the 4-heptanediol; 1, the 5-heptanediol; 1, the 6-heptanediol; Wherein most preferably: 2,3-dimethyl-2,3-pentanediol; 2,4-dimethyl-2,3-pentanediol; 3,4-dimethyl-2,3-pentanediol; 4,4-dimethyl-2,3-pentanediol and 2,3-dimethyl-3,4-pentanediol.

Similarly, C ₈It is many that the glycol isomer is also wanted, but just list those can form transparent product, preferably: 2-(1, the 1-dimethyl propyl)-1, ammediol; 2-(1, the 2-dimethyl propyl)-1, ammediol; 2-(1-ethyl propyl)-1, ammediol; 2-(2, the 2-dimethyl propyl)-1, ammediol; 2-ethyl-2-sec.-propyl-1, ammediol; 2-methyl-2-(1-methyl-propyl)-1, ammediol; 2-methyl-2-(2-methyl-propyl)-1, ammediol; The 2-tertiary butyl-2-methyl isophthalic acid, ammediol; 2,2-diethyl-1,3 butylene glycol; 2-(1-methyl-propyl)-1,3 butylene glycol; 2-butyl-1,3 butylene glycol; 2-ethyl-2,3-dimethyl-1,3 butylene glycol; 2-(1, the 1-dimethyl ethyl)-1,3 butylene glycol; 2-(2-methyl-propyl)-1,3 butylene glycol; 2-methyl-2-propyl group-1,3 butylene glycol; 2-methyl-2-sec.-propyl-1,3 butylene glycol; 3-methyl-2-propyl group-1,3 butylene glycol; 2,2-diethyl-1,4-butyleneglycol; 2-ethyl-2,3-dimethyl-1,4-butyleneglycol; 2-ethyl-3,3-dimethyl-1,4-butyleneglycol; 2-(1, the 1-dimethyl ethyl)-1, the 4-butyleneglycol; 3-methyl-2-sec.-propyl-1, the 4-butyleneglycol; 2,2,3-trimethylammonium-1,3-pentanediol; 2,2,4-trimethylammonium-1,3-pentanediol; 2,3,4-trimethylammonium-1,3-pentanediol; 2,4,4-trimethylammonium-1,3-pentanediol; 3,4,4-trimethylammonium-1,3-pentanediol; 2,2,3-trimethylammonium-1,4-pentanediol; 2,2,4-trimethylammonium-1,4-pentanediol; 2,3,3-trimethylammonium-1,4-pentanediol; 2,3,4-trimethylammonium-1,4-pentanediol; 3,3,4-trimethylammonium-1,4-pentanediol; 2,2,3-trimethylammonium-1,5-pentanediol; 2,2,4-trimethylammonium-1,5-pentanediol; 2,3,3-trimethylammonium-1,5-pentanediol; 2,3,4-trimethylammonium-2,4-pentanediol; 2-ethyl-2-methyl isophthalic acid, the 3-pentanediol; 2-ethyl-3-methyl isophthalic acid, the 3-pentanediol; 2-ethyl-4-methyl isophthalic acid, the 3-pentanediol; 3-ethyl-2-methyl isophthalic acid, the 3-pentanediol; 2-ethyl-2-methyl isophthalic acid, the 4-pentanediol; 2-ethyl-3-methyl isophthalic acid, the 4-pentanediol; 2-ethyl-4-methyl isophthalic acid, the 4-pentanediol; 3-ethyl-3-methyl isophthalic acid, the 5-pentanediol; 3-ethyl-2-methyl-2, the 4-pentanediol; 2-sec.-propyl-1, the 3-pentanediol; 2-propyl group-1, the 3-pentanediol; 2-sec.-propyl-1, the 4-pentanediol; 2-propyl group-1, the 4-pentanediol; 3-sec.-propyl-1, the 4-pentanediol; 3-propyl group-2, the 4-pentanediol; 2,2-dimethyl-1,3-hexylene glycol; 2,3-dimethyl-1,3-hexylene glycol; 2,4-dimethyl-1,3-hexylene glycol; 2,5-dimethyl-1,3-hexylene glycol; 3,4-dimethyl-1,3-hexylene glycol; 3,5-dimethyl-1,3-hexylene glycol; 4,4-dimethyl-1,3-hexylene glycol; 4,5-dimethyl-1,3-hexylene glycol; 2,2-dimethyl-1,4-hexylene glycol; 2,3-dimethyl-1,4-hexylene glycol; 2,4-dimethyl-1,4-hexylene glycol; 2,5-dimethyl-1,4-hexylene glycol; 3,3-dimethyl-1,4-hexylene glycol; 3,4-dimethyl-1,4-hexylene glycol; 3,5-dimethyl-1,4-hexylene glycol; 4,5-dimethyl-1,4-hexylene glycol; 5,5-dimethyl-1,4-hexylene glycol; 2,2-dimethyl-1,5-hexylene glycol; 2,3-dimethyl-1,5-hexylene glycol; 2,4-dimethyl-1,5-hexylene glycol; 2,5-dimethyl-1,5-hexylene glycol; 3,3-dimethyl-1,5-hexylene glycol; 3,4-dimethyl-1,5-hexylene glycol; 3,5-dimethyl-1,5-hexylene glycol; 4,5-dimethyl-1,5-hexylene glycol; 3,3-dimethyl-2,6-hexylene glycol; 2-ethyl-1, the 3-hexylene glycol; 4-ethyl-1, the 3-hexylene glycol; 2-ethyl-1, the 4-hexylene glycol; 4-ethyl-1, the 4-hexylene glycol; 2-ethyl-1, the 5-hexylene glycol; 3-ethyl-2, the 4-hexylene glycol; 4-ethyl-2, the 4-hexylene glycol; 3-ethyl-2, the 5-hexylene glycol; The 2-methyl isophthalic acid, the 3-heptanediol; The 3-methyl isophthalic acid, the 3-heptanediol; The 4-methyl isophthalic acid, the 3-heptanediol; The 5-methyl isophthalic acid, the 3-heptanediol; The 6-methyl isophthalic acid, the 3-heptanediol; The 2-methyl isophthalic acid, the 4-heptanediol; The 3-methyl isophthalic acid, the 4-heptanediol; The 4-methyl isophthalic acid, the 4-heptanediol; The 5-methyl isophthalic acid, the 4-heptanediol; The 6-methyl isophthalic acid, the 4-heptanediol; The 2-methyl isophthalic acid, the 5-heptanediol; The 3-methyl isophthalic acid, the 5-heptanediol; The 4-methyl isophthalic acid, the 5-heptanediol; The 5-methyl isophthalic acid, the 5-heptanediol; The 6-methyl isophthalic acid, the 5-heptanediol; The 2-methyl isophthalic acid, the 6-heptanediol; The 3-methyl isophthalic acid, the 6-heptanediol; The 4-methyl isophthalic acid, the 6-heptanediol; The 5-methyl isophthalic acid, the 6-heptanediol; The 6-methyl isophthalic acid, the 6-heptanediol; 2-methyl-2, the 4-heptanediol; 3-methyl-2, the 4-heptanediol; 4-methyl-2, the 4-heptanediol; 5-methyl-2, the 4-heptanediol; 6-methyl-2, the 4-heptanediol; 2-methyl-2, the 5-heptanediol; 3-methyl-2, the 5-heptanediol; 4-methyl-2, the 5-heptanediol; 5-methyl-2, the 5-heptanediol; 6-methyl-2, the 5-heptanediol; 2-methyl-2, the 6-heptanediol; 3-methyl-2, the 6-heptanediol; 4-methyl-2, the 6-heptanediol; 3-methyl-3, the 4-heptanediol; 2-methyl-3, the 5-heptanediol; 4-methyl-3, the 5-heptanediol; 2, the 4-ethohexadiol; 2, the 5-ethohexadiol; 2, the 6-ethohexadiol; 2, the 7-ethohexadiol; 3, the 5-ethohexadiol; And/or 3, the 6-ethohexadiol; Be most preferred wherein: 2-(1, the 1-dimethyl propyl)-1, ammediol; 2-(1, the 2-dimethyl propyl)-1, ammediol; 2-(1-ethyl propyl)-1, ammediol; 2-(2, the 2-dimethyl propyl)-1, ammediol; 2-ethyl-2-sec.-propyl-1, ammediol; 2-methyl-2-(1-methyl-propyl)-1, ammediol; 2-methyl-2-(2-methyl-propyl)-1, ammediol; The 2-tertiary butyl-2-methyl isophthalic acid, ammediol; 2-(1-methyl-propyl)-1,3 butylene glycol; 2-(2-methyl-propyl)-1,3 butylene glycol; 2-butyl-1,3 butylene glycol; 2-methyl-2-propyl group-1,3 butylene glycol; 3-methyl-2-propyl group-1,3 butylene glycol; 2,2-diethyl-1,4-butyleneglycol; 2-ethyl-2,3-dimethyl-1,4-butyleneglycol; 2-ethyl-3,3-dimethyl-1,4-butyleneglycol; 2-(1, the 1-dimethyl ethyl)-1, the 4-butyleneglycol; 2,3,4-trimethylammonium-1,3-pentanediol; 2,2,3-trimethylammonium-1,5-pentanediol; 2,2,4-trimethylammonium-1,5-pentanediol; 2,3,3-trimethylammonium-1,5-pentanediol; 2-ethyl-2-methyl isophthalic acid, the 3-pentanediol; 2-ethyl-3-methyl isophthalic acid, the 3-pentanediol; 2-ethyl-4-methyl isophthalic acid, the 3-pentanediol; 3-ethyl-2-methyl isophthalic acid, the 3-pentanediol; 2-ethyl-2-methyl isophthalic acid, the 4-pentanediol; 2-ethyl-3-methyl isophthalic acid, the 4-pentanediol; 2-ethyl-4-methyl isophthalic acid, the 4-pentanediol; 3-ethyl-3-methyl isophthalic acid, the 5-pentanediol; 3-ethyl-2-methyl-2, the 4-pentanediol; 2-sec.-propyl-1, the 3-pentanediol; 2-propyl group-1, the 3-pentanediol; 2-sec.-propyl-1, the 4-pentanediol; 2-propyl group-1, the 4-pentanediol; 3-sec.-propyl-1, the 4-pentanediol; 3-propyl group-2, the 4-pentanediol; 2,2-dimethyl-1,3-hexylene glycol; 2,3-dimethyl-1,3-hexylene glycol; 2,4-dimethyl-1,3-hexylene glycol; 2,5-dimethyl-1,3-hexylene glycol; 3,4-dimethyl-1,3-hexylene glycol; 3,5-dimethyl-1,3-hexylene glycol; 4,4-dimethyl-1,3-hexylene glycol; 4,5-dimethyl-1,3-hexylene glycol; 2,2-dimethyl-1,4-hexylene glycol; 2,3-dimethyl-1,4-hexylene glycol; 2,4-dimethyl-1,4-hexylene glycol; 2,5-dimethyl-1,4-hexylene glycol; 3,3-dimethyl-1,4-hexylene glycol; 3,4-dimethyl-1,4-hexylene glycol; 3,5-dimethyl-1,4-hexylene glycol; 4,5-dimethyl-1,4-hexylene glycol; 5,5-dimethyl-1,4-hexylene glycol; 2,2-dimethyl-1,5-hexylene glycol; 2,3-dimethyl-1,5-hexylene glycol; 2,4-dimethyl-1,5-hexylene glycol; 2,5-dimethyl-1,5-hexylene glycol; 3,3-dimethyl-1,5-hexylene glycol; 3,4-dimethyl-1,5-hexylene glycol; 3,5-dimethyl-1,5-hexylene glycol; 4,5-dimethyl-1,5-hexylene glycol; 3,3-dimethyl-2,6-hexylene glycol; 2-ethyl-1, the 3-hexylene glycol; 4-ethyl-1, the 3-hexylene glycol; 2-ethyl-1, the 4-hexylene glycol; 4-ethyl-1, the 4-hexylene glycol; 2-ethyl-1, the 5-hexylene glycol; 3-ethyl-2, the 4-hexylene glycol; 4-ethyl-2, the 4-hexylene glycol; 3-ethyl-2, the 5-hexylene glycol; The 2-methyl isophthalic acid, the 3-heptanediol; The 3-methyl isophthalic acid, the 3-heptanediol; The 4-methyl isophthalic acid, the 3-heptanediol; The 5-methyl isophthalic acid, the 3-heptanediol; The 6-methyl isophthalic acid, the 3-heptanediol; The 2-methyl isophthalic acid, the 4-heptanediol; The 3-methyl isophthalic acid, the 4-heptanediol; The 4-methyl isophthalic acid, the 4-heptanediol; The 5-methyl isophthalic acid, the 4-heptanediol; The 6-methyl isophthalic acid, the 4-heptanediol; The 2-methyl isophthalic acid, the 5-heptanediol; The 3-methyl isophthalic acid, the 5-heptanediol; The 4-methyl isophthalic acid, the 5-heptanediol; The 5-methyl isophthalic acid, the 5-heptanediol; The 6-methyl isophthalic acid, the 5-heptanediol; The 2-methyl isophthalic acid, the 6-heptanediol; The 3-methyl isophthalic acid, the 6-heptanediol; The 4-methyl isophthalic acid, the 6-heptanediol; The 5-methyl isophthalic acid, the 6-heptanediol; The 6-methyl isophthalic acid, the 6-heptanediol; 2-methyl-2, the 4-heptanediol; 3-methyl-2, the 4-heptanediol; 4-methyl-2, the 4-heptanediol; 5-methyl-2, the 4-heptanediol; 6-methyl-2, the 4-heptanediol; 2-methyl-2, the 5-heptanediol; 3-methyl-2, the 5-heptanediol; 4-methyl-2, the 5-heptanediol; 5-methyl-2, the 5-heptanediol; 6-methyl-2, the 5-heptanediol; 2-methyl-2, the 6-heptanediol; 3-methyl-2, the 6-heptanediol; 4-methyl-2, the 6-heptanediol; 3-methyl-3, the 4-heptanediol; 2-methyl-3, the 5-heptanediol; 4-methyl-3, the 5-heptanediol; 2, the 4-ethohexadiol; 2, the 5-ethohexadiol; 2, the 6-ethohexadiol; 2, the 7-ethohexadiol; 3, the 5-ethohexadiol; And/or 3, the 6-ethohexadiol.

Preferred eight carbon atom 1, the mixture condensation that 3 diol mixtures can pass through butyraldehyde, isobutyric aldehyde and/or methylethylketone (2-butanone) forms, as long as in the reaction mixture at least two kinds of these reactants are arranged, is reflected under the existence of high alkalinity catalyzer and carries out, change into eight carbon 1 by hydrogenation subsequently, the mixture of 3-glycol, that is, and main eight carbon 1 that constitute by following compound, 3 diol mixtures: 2,2,4-trimethylammonium-1,3-pentanediol; 2-ethyl-1, the 3-hexylene glycol; 2,2-dimethyl-1,3-hexylene glycol; 2-ethyl-4-methyl isophthalic acid, the 3-pentanediol; 2-ethyl-3-methyl isophthalic acid, the 3-pentanediol; 3, the 5-ethohexadiol; 2,2-dimethyl-2,4-hexylene glycol; 2-methyl-3, the 5-heptanediol; And/or 3-methyl-3,5-heptanediol, wherein 2,2,4-trimethylammonium-1, the content of 3-pentanediol in any mixture all fewer than half, may also have because other a small amount of isomer that condensation forms on the 2-butanone methylene radical of (when it exists) rather than on methyl.

Some the not preferred C that lists among Table II-IV in the above _6-8The property prepared of glycol and other character, for example smell, flowability, fusing point reduction etc. can improve by poly-alkoxylation.In addition, some oxyalkylated C _3-5Glycol is preferred.

In the nonane isomer, have only 2,3,3,4-tetramethyl--2, the 4-pentanediol is highly preferred.

Except the aliphatic diol main solvent and its some alkoxy derivative discussed before this and later on, also find-a little special glycol ethers be suitable for preparing liquid state of the present invention, concentrate, the main solvent of transparent fabric softener composition.Similar to the aliphatic diol main solvent, find that the suitability of various main solvents has selectivity, depend on the carbon atom number in for example concrete glycol ethers molecule.For example, as providing in the Table VI, be C for wherein R ₂-C ₈The chemical formula of alkyl is HOCH ₂-CHOH-CH ₂The glyceryl ether series of-O-R, having only chemical formula is HOCH ₂-CHOH-CH ₂-O-C ₅H ₁₁(C wherein ₅H ₁₁Comprise different amyl group isomer) the ClogP value of single amyl ether (3-pentyloxy-1,2-propylene glycol) be in the preferred ClogP scope of about 0.25-0.62, be suitable for the fabric sofetening agent formulation of spissated liquid clear of the present invention.This is illustrated by embodiment and comparative examples XXXIIA-7 to XXXIIA-7F.Find that also cyclohexyl derivatives is suitable for, but cyclopentyl derivates is then denied.Similarly, when selecting Arylglycerine ether, demonstrate selectivity.In a lot of possible aromatic groups, have only the phenol derivatives of minority to be suitable for.

Also find same narrow selectivity for two (hydroxyalkyl) ether.Find that two (2-hydroxybutyl) ether is suitable for, but two (2-hydroxyl amyl ethers) are then denied.For two (ring hydroxyalkyl) analogue, two (2-hydroxycyclopent base) ether is suitable for, but two (2-hydroxy-cyclohexyl) ether is inapplicable.The back has provided the limiting examples about the synthetic method for preparing some preferred two (hydroxyalkyl) ether.

Butyl list glyceryl ether (being also referred to as 3-butoxy-1, the 2-propylene glycol) not too is fit to form the fabric softener of spissated liquid clear of the present invention.But, as shown in Table VI, its polyethoxylated derivative, preferably about triethoxyization more preferably from five ethoxylation to eight ethoxylations, is suitable main solvent to about nine ethoxylations.

The preferred alkyl glycerylether of all that are identified and/or two (hydroxyalkyl) ether all are listed in the Table VI, most preferably: 3-(n-pentyloxy)-1,2-propylene glycol; 3-(2-pentyloxy)-1,2 propylene glycol; 3-(3-pentyloxy)-1, the 2-propylene glycol; 3-(2-methyl-1-butene oxygen base)-1, the 2-propylene glycol; 3-(isopentyloxy)-1, the 2-propylene glycol; 3-(3-methyl-2-butoxy)-1, the 2-propylene glycol; 3-(cyclohexyloxy)-1, the 2-propylene glycol; 3-(1-hexamethylene-1-alkene oxygen base)-1, the 2-propylene glycol; 2-(pentyloxy)-1, ammediol; 2-(2-pentyloxy)-1, ammediol; 2-(3-pentyloxy)-1, ammediol; 2-(2-methyl-1-butene oxygen base)-1, ammediol; 2-(isopentyloxy)-1, ammediol; 2-(3-methyl-2-butoxy)-1, ammediol; 2-(cyclohexyloxy)-1, ammediol; 2-(1-hexamethylene-1-alkene oxygen base)-1, ammediol; 3-(butoxy)-1, the 2-propylene glycol; Five ethoxylates; 3-(butoxy)-1, the 2-propylene glycol; Six ethoxylates; 3-(butoxy)-1, the 2-propylene glycol; Seven ethoxylates; 3-(butoxy)-1, the 2-propylene glycol; Eight ethoxylates; 3-(butoxy)-1, the 2-propylene glycol; Nine ethoxylates; 3-(butoxy)-1, the 2-propylene glycol;-propoxylated glycerine; 3-(butoxy)-1, the 2-propylene glycol; The dibutoxy thing; And/or 3-(butoxy)-1, the 2-propylene glycol; Three butoxy things.Preferred aromatics glyceryl ether comprises: 3-phenoxy group-1,2-propylene glycol; 3-benzyloxy-1, the 2-propylene glycol; 3-(2-phenyl ethoxy)-1, the 2-propylene glycol; 2-(a hydroxy toluene oxygen base)-1, the 2-propylene glycol; With-1, ammediol; 2-(to hydroxy toluene oxygen base)-1, ammediol; 2-benzyloxy-1, ammediol; 2-(2-phenyl ethoxy)-1, ammediol; And their mixture.Preferred aromatics glyceryl ether comprises: 3-phenoxy group-1,2-propylene glycol; 3-benzyloxy-1, the 2-propylene glycol; 3-(2-phenyl ethoxy)-1, the 2-propylene glycol; 2-(a hydroxy toluene oxygen base)-1, the 2-propylene glycol; With-1, ammediol; 2-(to hydroxy toluene oxygen base)-1, ammediol; 2-(2-phenyl ethoxy)-1, ammediol; And their mixture.Most preferred two (hydroxyalkyl) ether comprises: two (2-hydroxyl butyl) ether and two (Alpha-hydroxy cyclopentyl) ethers;

The back has provided the illustrative and the non-restrictive example of the synthetic method for preparing preferred alkyl and aryl list glyceryl ether.

Preferred alicyclic diol and derivative thereof comprise: glycol that (1) is saturated and derivative thereof comprise: 1-sec.-propyl-1,2-cyclobutanediol; 3-ethyl-4-methyl isophthalic acid, the 2-cyclobutanediol; 3-propyl group-1, the 2-cyclobutanediol; 3-sec.-propyl-1, the 2-cyclobutanediol; 1-ethyl-1,2-encircles pentanediol; 1,2-dimethyl-1,2-encircles pentanediol; 1,4-dimethyl-1,2-encircles pentanediol; 2,4,5-trimethylammonium-1,3-encircles pentanediol; 3,3-dimethyl-1,2-encircles pentanediol; 3,4-dimethyl-1,2-encircles pentanediol; 3,5-dimethyl-1,2-encircles pentanediol; 3-ethyl-1,2-encircles pentanediol; 4,4-dimethyl-1,2-encircles pentanediol; 4-ethyl-1,2-encircles pentanediol; 1,1-two (methylol) hexanaphthene; 1,2-two (methylol) hexanaphthene; 1,2-dimethyl-1,3-cyclohexanediol; 1,3-two (methylol) hexanaphthene; 1,3-dimethyl-1,3-cyclohexanediol; 1,6-dimethyl-1,3-cyclohexanediol; 1-hydroxyl hexanaphthene ethanol; 1-hydroxyl cyclohexane methanol; 1-ethyl-1, the 3-cyclohexanediol; The 1-methyl isophthalic acid, the 2-cyclohexanediol; 2,2-dimethyl-1,3-cyclohexanediol; 2,3-dimethyl-1,4-cyclohexanediol; 2,4-dimethyl-1,3-cyclohexanediol; 2,5-dimethyl-1,3-cyclohexanediol; 2,6-dimethyl-1,4-cyclohexanediol; 2-ethyl-1, the 3-cyclohexanediol; 2-hydroxyl hexanaphthene ethanol; 2-hydroxyethyl-1-hexalin; 2-methylol hexalin; 3-hydroxyethyl-1-hexalin; 3-hydroxyl hexanaphthene ethanol; 3-methylol hexalin; The 3-methyl isophthalic acid, the 2-cyclohexanediol; 4,4-dimethyl-1,3-cyclohexanediol; 4,5-dimethyl-1,3-cyclohexanediol; 4,6-dimethyl-1,3-cyclohexanediol; 4-ethyl-1, the 3-cyclohexanediol; 4-hydroxyethyl-1-hexalin; 4-methylol hexalin; The 4-methyl isophthalic acid, the 2-cyclohexanediol; 5,5-dimethyl-1,3-cyclohexanediol; 5-ethyl-1, the 3-cyclohexanediol; 1,2-encircles heptanediol; The 2-methyl isophthalic acid, 3-encircles heptanediol; The 2-methyl isophthalic acid, 4-encircles heptanediol; The 4-methyl isophthalic acid, 3-encircles heptanediol; The 5-methyl isophthalic acid, 3-encircles heptanediol; The 5-methyl isophthalic acid, 4-encircles heptanediol; The 6-methyl isophthalic acid, 4-encircles heptanediol; 1,3-encircles ethohexadiol; 1,4-encircles ethohexadiol; 1,5-encircles ethohexadiol; 1,2-cyclohexanediol, diethoxy thing; 1,2-cyclohexanediol, triethoxy thing; 1,2-cyclohexanediol, tetraethoxy thing; 1,2-cyclohexanediol, five ethoxylates; 1,2-cyclohexanediol, six ethoxylates; 1,2-cyclohexanediol, seven ethoxylates; 1,2-cyclohexanediol, eight ethoxylates; 1,2-cyclohexanediol, nine ethoxylates; 1,2-cyclohexanediol, a propoxylated glycerine; 1, the 2-cyclohexanediol; One butoxy thing; 1,2-cyclohexanediol, dibutoxy thing; And/or 1, the 2-cyclohexanediol; Three butoxy things.Most preferred radical of saturated aliphatic glycol and derivative thereof are: 1-sec.-propyl-1,2-cyclobutanediol; 3-ethyl-4-methyl isophthalic acid, the 2-cyclobutanediol; 3-propyl group-1, the 2-cyclobutanediol; 3-sec.-propyl-1, the 2-cyclobutanediol; 1-ethyl-1,2-encircles pentanediol; 1,2-dimethyl-1,2-encircles pentanediol; 1,4-dimethyl-1,2-encircles pentanediol; 3,3-dimethyl-1,2-encircles pentanediol; 3,4-dimethyl-1,2-encircles pentanediol; 3,5-dimethyl-1,2-encircles pentanediol; 3-ethyl-1,2-encircles pentanediol; 4,4-dimethyl-1,2-encircles pentanediol; 4-ethyl-1,2-encircles pentanediol; 1,1-two (methylol) hexanaphthene; 1,2-two (methylol) hexanaphthene; 1,2-dimethyl-1,3-cyclohexanediol; 1,3-two (methylol) hexanaphthene; 1-hydroxyl cyclohexane methanol; The 1-methyl isophthalic acid, the 2-cyclohexanediol; 3-methylol hexalin; The 3-methyl isophthalic acid, the 2-cyclohexanediol; 4,4-dimethyl-1,3-cyclohexanediol; 4,5-dimethyl-1,3-cyclohexanediol; 4,6-dimethyl-1,3-cyclohexanediol; 4-ethyl-1, the 3-cyclohexanediol; 4-hydroxyethyl-1-hexalin; 4-methylol hexalin; The 4-methyl isophthalic acid, the 2-cyclohexanediol; 1,2-encircles heptanediol; 1,2-cyclohexanediol, five ethoxylates; 1,2-cyclohexanediol, six ethoxylates; 1,2-cyclohexanediol, seven ethoxylates; 1,2-cyclohexanediol, eight ethoxylates; 1,2-cyclohexanediol, nine ethoxylates; 1, the 2-cyclohexanediol; One propoxylated glycerine; And/or 1,2-cyclohexanediol, dibutoxy thing.

Optional aromatic diol comprises: 1-phenyl-1; 1-phenyl-1, the 2-propylene glycol; 2-phenyl-1, the 2-propylene glycol; 3-phenyl-1, the 2-propylene glycol; 1-(3-aminomethyl phenyl)-1, ammediol; 1-(4-aminomethyl phenyl)-1, ammediol; 2-methyl isophthalic acid-phenyl-1, ammediol; 1-phenyl-1,3 butylene glycol; 3-phenyl-1,3 butylene glycol; And/or 1-phenyl-1, the 4-butyleneglycol, wherein most preferably: 1-phenyl-1,2-propylene glycol; 2-phenyl-1, the 2-propylene glycol; 3-phenyl-1, the 2-propylene glycol; 1-(3-aminomethyl phenyl)-1, ammediol; 1-(4-aminomethyl phenyl)-1, ammediol; 2-methyl isophthalic acid-phenyl-1, ammediol; And/or 1-phenyl-1, the 4-butyleneglycol.

As previously mentioned, all are according to the relevant unsaturated materials of the preferred main solvent of identical relation and other,, Duo a CH than saturated main solvent that is ₂Group also will be preferred.But concrete preferred unsaturated diol main solvent is: 2, and 2-diallyl-1,3 butylene glycol; 2-(1-ethyl-1-propenyl)-1,3 butylene glycol; 2-(crotyl)-2-methyl isophthalic acid, the 3-butyleneglycol; 2-(3-methyl-2-butene base)-1,3 butylene glycol; 2-ethyl-2-(2-propenyl)-1,3 butylene glycol; 2-methyl-2-(1-methyl-2-propenyl)-1,3 butylene glycol; 2,3-two (1-methyl ethylidene)-1,4-butyleneglycol; 2-vinyl-3-ethyl-1, the 3-pentanediol; 2-vinyl-4,4-dimethyl-1,3-pentanediol; 3-methyl-2-(2-propenyl)-1, the 4-pentanediol; 2-(1, the 1-dimethyl ethyl)-4-amylene-1, the 3-glycol; 2-ethyl-2,3-dimethyl-4-amylene-1,3-glycol; 4-ethyl-2-methylene radical-1, the 4-hexylene glycol; 2,3,5-trimethylammonium-1,5-hexadiene-3,4-glycol; 2-(1-methyl ethylene)-1, the 5-hexylene glycol; 4-vinyl-2,5-dimethyl-2-hexene-1,5-glycol; 6-methyl-5-methylene radical-1, the 4-heptanediol; 4,6-dimethyl-2,4-heptadiene-2,6-glycol; 2,5,5-trimethylammonium-2,6-heptadiene-1,4-glycol; 5,6-dimethyl-2-heptene-1,4-glycol; 4,6-dimethyl-3-heptene-1,5-glycol; 2,4-dimethyl-5-heptene-1,3-glycol; 3,6-dimethyl-5-heptene-1,3-glycol; 2,6-dimethyl-5-heptene-1,4-glycol; 3,6-dimethyl-5-heptene-1,4-glycol; 2,2-dimethyl-6-heptene-1,3-glycol; 5,6-dimethyl-6-heptene-1,4-glycol; 2,4-dimethyl-6-heptene-1,5-glycol; 2-ethylidene-6-methyl-6-heptene-1, the 5-glycol; 4-(2-propenyl)-6-heptene-2, the 4-glycol; 3-vinyl-1-octene-3, the 6-glycol; 2,7-dimethyl-2,4,6-sarohornene-1,8-glycol; 2,6-dimethyl-2,5-octadiene-1,7-glycol; 3,7-dimethyl-2,5-octadiene-1,7-glycol; 3,7-dimethyl-2,6-octadiene-1,4-glycol (Rosiridol); 2-methyl-2,6-octadiene-1,8-glycol; 3,7-dimethyl-2,7-octadiene-1,4-glycol; 2,6-dimethyl-2,7-octadiene-1,5-glycol; 2,6-dimethyl-2,7-octadiene-1,6-glycol (8-hydroxyl phantol); 2,7-dimethyl-2,7-octadiene-1,6-glycol; 2-methyl-6-methylene radical-2-octene-1, the 7-glycol; 2,7-dimethyl-3,5-octadiene-2,7-glycol; 4-methylene radical-3, the 5-ethohexadiol; 2,6-dimethyl-3,7-octadiene-1,6-glycol; 2-methylene radical-4-octene-1, the 8-glycol; 2-methyl-6-octene-3, the 5-glycol; 4-methyl-6-octene-3, the 5-glycol; 2-methyl-6-methylene radical-7-octene-2, the 4-glycol; 7-methyl-7-octene-2, the 5-glycol; 2-methyl-7-octene-3, the 5-glycol; 1-nonene-3, the 5-glycol; 1-nonene-3, the 7-glycol; 3-nonene-2, the 5-glycol; 4-nonene-2, the 8-glycol; 6,8-nonadiene-1,5-glycol; 7-nonene-2, the 4-glycol; 8-nonene-2, the 4-glycol; 8-nonene-2, the 5-glycol; 1,9-decadiene-3,8-glycol; And/or 1,9-decadiene-4,6-glycol.

Described alcohols main solvent also can preferably be selected from: 2, and 5-dimethyl-2,5-hexylene glycol; 2-ethyl-1, the 3-hexylene glycol; 2-methyl-2-propyl group-1, ammediol; 1, the 2-hexylene glycol; And their mixture.Preferred alcohols main solvent then is selected from: 2-ethyl-1,3-hexylene glycol, 2-methyl-2-propyl group-1, ammediol, 1,2-hexylene glycol and their mixture.Preferably, described alcohols main solvent is to be selected from 2-ethyl-1,3-hexylene glycol, 1,2-hexylene glycol and composition thereof.

Several derivatives that have different alkylene oxide bases when same glycol, 3-5 ethylene oxide group or 2 propylene oxide groups are for example arranged, or the 2-methyl-2 of a butylene oxide groups, the 3-butyleneglycol, when available, the preferred derivative that uses the group minimum number promptly is the derivative with a butylene oxide groups in this situation.But when only needing about 1-4 ethylene oxide group that the good property prepared is provided, this analog derivative also is preferred.Undersaturated glycol

A wonderful discovery is, has at saturated dibasic alcohol and its between acceptability (property prepared) of unsaturated homologue (or analogue) of higher molecular weight tangible similarity is arranged.Undersaturated homologue (analogue) unsaturated main solvent for its chemical formula in each two key all to add a methylene radical in addition (be CH ₂) condition under, have and the identical property prepared of the saturated main solvent of parent.In other words, have one tangible " adding normally ", that is, all there is suitable undersaturated main solvent in the various of the present invention good saturated main solvent for being fit to preparation transparent, concentrated fabric soft compound of the present invention, wherein adds one or more CH ₂Group, and for added each CH ₂Group, all the adjacent carbons from molecule is removed two hydrogen atoms forming carbon-to-carbon double bond, thereby makes hydrogen atom sum in the molecule keep constant with respect to the chemical formula of " parent " saturated main solvent.This is because a wonderful fact promptly, adds one-CH in the solvent chemical formula ₂-group has makes its ClogP value increase by about 0.53 effect, remove two adjacent hydrogen atoms with form two keys then make ClogP reduce same approximately quantity (that is) effect, about 0.48, thus roughly offset-CH ₂-adding.Therefore, from preferred saturated main solvent, by each CH for increase ₂Group inserts two keys to keep the hydrogen atom sum identical with the saturated main solvent of parent, at least unsaturated analogue/homologues of preferred higher molecular weight that contain a carbon atom have been become, as long as the ClogP value of new solvent remains in the valid value range of 0.15-0.64 more.Below be some illustrative example:

2,2-dimethyl-6-heptene-1,3-glycol (CAS No.140192-39-8) is preferred C9-glycols main solvent, can think by suitably adding a CH to following any preferred C8-glycol main solvent ₂Group and one two keys are derived and are formed: 2-methyl isophthalic acid, 3-heptanediol or 2,2-dimethyl-1,3-hexylene glycol.

2,4-dimethyl-5-heptene-1,3-glycol (CAS No.123363-69-9) is preferred C9-glycol main solvent, can think by suitably adding a CH to following any preferred C8-glycol main solvent ₂Group and one two keys are derived and are formed: 2-methyl isophthalic acid, 3-heptanediol or 2,4-dimethyl-1,3-hexylene glycol.

2-(1-ethyl-1-propenyl)-1,3 butylene glycol (CAS No.116103-35-6) is preferred C9-glycol main solvent, can think by suitably adding a CH to following any preferred C8-glycol main solvent ₂Group and one two keys are derived and are formed: 2-(1-ethyl propyl)-1, ammediol or 2-(1-methyl-propyl)-1,3 butylene glycol.

2-vinyl-3-ethyl-1,3-pentanediol (CAS No.104683-37-6) is preferred C9-glycol main solvent, can think by suitably adding a CH to following any preferred C8-glycol main solvent ₂Group and one two keys are derived and are formed: 3-ethyl-2-methyl isophthalic acid, 3-pentanediol or 2-ethyl-3-methyl isophthalic acid, 3-pentanediol.

3,6-dimethyl-5-heptene-1,4-glycol (as CAS No.106777-99-5) is preferred C9-glycol main solvent, can think by suitably adding a CH to following any preferred C8-glycol main solvent ₂Group and one two keys are derived and are formed: 3-methyl isophthalic acid, 4-heptanediol; The 6-methyl isophthalic acid, the 4-heptanediol; Or 3,5-dimethyl-1,4-hexylene glycol.

5,6-dimethyl-6-heptene-1,4-glycol (as CAS No.152344-16-6) is preferred C9-glycol main solvent, can think by suitably adding a CH to following any preferred C8-glycol main solvent ₂Group and one two keys are derived and are formed: 5-methyl isophthalic acid, 1-heptanediol; The 6-methyl isophthalic acid, the 4-heptanediol; Or 4,5-dimethyl-1,3-hexylene glycol.

4-methyl-6-octene-3,5-glycol (CAS No.156414-25-4) is preferred C9-glycol main solvent, can think by suitably adding a CH to following any preferred C8-glycol main solvent ₂Group and one two keys are derived and are formed: 3, and the 5-ethohexadiol; 3-methyl-2,4-heptanediol or 4-methyl-3,5-heptanediol.

Rosiridol (CAS No.101391-01-9) and isorosiridol (CAS No.149252-15-3) are 3,7-dimethyl-2,6-octadiene-1, two kinds of isomer of 4-glycol, and be preferred C10-glycol main solvent, they can be thought by suitably add two CH in any following preferred C8-glycol main solvent ₂Group and two two keys are derived and are formed: 2-methyl isophthalic acid, 3-heptanediol; The 6-methyl isophthalic acid, the 3-heptanediol; The 3-methyl isophthalic acid, the 4-heptanediol; The 6-methyl isophthalic acid, the 4-heptanediol; 2,5-dimethyl-1,3-hexylene glycol; Or 3,5-dimethyl-1,4-hexylene glycol.

8-hydroxyl phantol (CAS No.103619-06-3,2,6-dimethyl-2,7-octadiene-1,6-glycol) is preferred C10-glycol main solvent, can think by suitably add two CH in any following preferred C8-glycol main solvent ₂Group and two two keys are derived and are formed: 2-methyl isophthalic acid, 5-heptanediol; The 5-methyl isophthalic acid, the 5-heptanediol; The 2-methyl isophthalic acid, the 6-heptanediol; The 6-methyl isophthalic acid, the 6-heptanediol; Or 2,4-dimethyl-1,4-hexylene glycol.

2,7-dimethyl-3,7-octadiene-2,5-glycol (CAS No.171436-39-8) is preferred C10-glycol main solvent, can think by suitably adding two CH to any following preferred C8-glycol main solvent ₂Group and two two keys are derived and are formed: 2, and the 5-ethohexadiol; The 6-methyl isophthalic acid, the 4-heptanediol; 2-methyl-2, the 4-heptanediol; 6-methyl-2, the 4-heptanediol; 2-methyl-2, the 5-heptanediol; 6-methyl-2, the 5-heptanediol; With 2,5-dimethyl-2,4-hexylene glycol.

4-butyl-2-butylene-1,4-glycol (CAS No.153943-66-9) is preferred C8-glycol main solvent, can think by suitably adding a CH to any following preferred C7-glycol main solvent ₂Group and one two keys are derived and are formed: 2-propyl group-1,4-butyleneglycol or 2-butyl-1, ammediol.

Based on same reason, a lot of situations itself are poor solvents by the derive unsaturated homologue of the higher molecular weight that forms of bad, inapplicable saturated solvent.For example, 3,5-dimethyl-5-hexene-2,4-glycol (for example CAS No.160429-40-3) is bad unsaturated C8 solvent, can think to be derived by following bad saturated C7 solvent to form: 3-methyl-2,4-hexylene glycol; 5-methyl-2, the 4-hexylene glycol; Or 2,4-dimethyl-1,3-pentanediol; And 2,6-dimethyl-5-heptene-1,2-glycol (for example CASNo.141505-71-7) they are bad unsaturated C9 solvents, can think to be derived by following bad saturated C8 solvent to form: 2-methyl isophthalic acid, 2-heptanediol; The 6-methyl isophthalic acid, the 2-heptanediol; Or 2,5-dimethyl-1,2-hexylene glycol.

Also find unexpectedly, more than always have the adding of unsaturated analogue/homologue of identical acceptable degree that an exception is arranged normally about saturated main solvent.This exception relates to the saturated glycol main solvent that two hydroxyls are arranged on two adjacent carbon atoms.In some example, between two of poor solvent adjacent hydroxyls, insert one or more CH ₂The unsaturated homologue of higher molecular weight that group forms be more suitable in transparent concentrated fabric softener preparation, but such was the case with.For example, do not have the preferred unsaturated 6 of adjacent hydroxyl, 6-dimethyl-1-teracrylic acid, 5-glycol (CAS No.109788-01-4) can think by having the inapplicable 2 of adjacent hydroxyl, and 2-dimethyl-3,4-hexylene glycol are derived and formed.In this embodiment, think 6,6-dimethyl-1-teracrylic acid, 5-glycol are by 2-methyl-3, and it is more credible that 5-heptanediol or 5,5-dimethyl-2,4-hexylene glycol are derived and formed, and these two kinds of alcohol all are preferred main solvents, and do not have adjacent hydroxyl.Otherwise, between the adjacent hydroxyl of preferred main solvent, insert CH ₂Group can form the unsaturated diol solvent of inapplicable higher molecular weight.For example, do not have the inapplicable unsaturated 2 of adjacent hydroxyl, 4-dimethyl-5-hexene-2,4-glycol (CASNo.87604-24-8) can think by having the preferred 2 of adjacent hydroxyl, and 3-dimethyl-2,3-pentanediol are derived and formed.In this embodiment, more believable is by 2-methyl-2,4-hexylene glycol or 4-methyl-2,4-hexylene glycol derive form inapplicable undersaturated 2,4-dimethyl-5-hexene-2, the 4-glycol, the first two is planted alcohol and is inapplicable solvent and does not all have adjacent hydroxyl.Also have-a little situations, do not have the inapplicable unsaturated solvent of adjacent hydroxyl can think to derive and form by inapplicable solvent with adjacent hydroxyl, for example 4,5-dimethyl-6-hexene-1,3-two is pure and mild 3,4-dimethyl-1, this is a pair of for the 2-pentanediol.Therefore, in order to infer the property prepared of the unsaturated solvent that does not have adjacent hydroxyl, should set out by the saturated homologue of the lower molecular weight that does not have adjacent hydroxyl equally.That is, in general, when two hydroxyls distance/when relation was kept, above-mentioned relation was more reliable.That is, reliably the practice is the property prepared that goes out to send the unsaturated homologue of the higher molecular weight that deduction also has adjacent hydroxyl from the saturated solvent with adjacent hydroxyl.

Have been found that and use these special alcohols main solvents can be under astonishing low main solvent content that promptly, about 40% less than composition weight makes transparent, low viscosity, stable fabric softener composition.Find that also use this alcohols main solvent can make highly spissated fabric softener composition, they are stable, and for example can dilute from about 2: 1 to about 10: 1, and still stablize with the composition of formation low levels fabric softener.

As previously mentioned, preferably main solvent content is remained on to making composition reach the translucent or transparent minimum level that can realize.The existence of water is for for reaching the transparent required main solvent of these compositions material impact being arranged.Water-content is high more, and is high more for realizing the transparent required main solvent content of product (with respect to softening agent content).Otherwise water-content is few more, and the main solvent (with respect to softening agent) that needs is few more.For example, under the low water content of about 5-15%, the weight ratio of softening agent actives and main solvent is about 55: 45 to about 85: 15, more preferably from about 60: 40 to about 80: 20.Under the water-content of about 15-70%, the weight ratio of softening agent actives and main solvent is preferably about 45: 55 to about 70: 30, more preferably from about 55: 45 to about 70: 30.But under the high water content of about 70-about 80%, the softening agent actives is preferably about 30: 70 to about 55: 45 with the weight of solvent ratio, more preferably from about 35: 65 to about 45: 55.When the water yield was also high, the ratio of softening agent/main solvent also should be higher.

The mixture of above main solvent is superior especially, because one of problem relevant with a large amount of solvents is security.Mixture has reduced the quantity of any existing material.Smell and combustibility also can reduce by using mixture, and especially when one of main solvent was volatility and/or scent of, this was likely for low molecular weight substance.Can have being not enough to form the suitable solvent that uses under the content of opaque products: 2,2,4-trimethylammonium-1,3-pentanediol; 2,2,4-trimethylammonium-1, the ethoxylate of 3-pentanediol, diethoxy thing or triethoxy compound derivative; With and/or 2-ethyl-1, the 3-hexylene glycol.For the present invention, these solvents only should use under the content that does not form stable or opaque products.Primary solvent is one or more solvents of having confirmed as most preferred solvent before this in the preferred mixture.It also is desirable using solvent mixture, and especially when in the preferred main solvent one or more at room temperature were solid, in this situation, mixture was a fluid, or has lower fusing point, thereby has improved the workability of softener composition.

Also find, might can not replace a part of main solvent of the present invention or main solvent mixture as second solvent or second solvent mixture that main solvent of the present invention uses with itself, as long as in the fabric softener composition of spissated liquid clear, still there is the of the present invention suitable main solvent of effective quantity.Effective quantity of main solvent of the present invention, under the situation that at least also has about 15% softening agent actives, about 5% greater than composition at least, be preferably greater than about 7%, more preferably greater than about 10%.Substituting solvent can use with any content, but preferably is substantially equal to or is less than the quantity of the main solvent that is suitable for of the above-mentioned definition that exists in fabric softener composition.

For example, according to the present invention, though 1,2-pentanediol, 1, the following hydroxypivalyl hydroxypivalate (claiming HPHP later on) of 3-ethohexadiol and chemical formula is inapplicable solvent: HO-CH ₂-C (CH ₃) ₂-CH ₂-O-CO-C (CH ₃) ₂-CH ₂The mixture of-OH (CAS#1115-20-4) but these solvents and main solvent (for example preferred 1,2-hexylene glycol main solvent), wherein 1, the content of 2-hexylene glycol main solvent also forms spissated transparent liquid fabric softener composition when useful range.

Operable some second solvent is before this and the solvent of listing as inapplicable solvent later on, and some not oxyalkylated parent solvent of listing among the Table VIII A-VIIIE.

Main solvent can be used for making composition translucent or transparent, perhaps can be used to reduce composition and becomes temperature when translucent or transparent.Therefore, the present invention also comprises to not being translucent or transparent or having the method that adds aforementioned content main solvent in the too high composition of unstable occurrence temperature, so that it is translucent or transparent that composition is become, perhaps under composition in for example envrionment temperature or when reducing to certain specified temp is transparent situation, the temperature that unstable is taken place reduces preferably at least about 5 ℃, more preferably reduces at least about 10 ℃.The major advantage of main solvent is that it provides maximum benefit for the solvent of given weight.Should be appreciated that said " solvent " is meant effect rather than its physical form under assigned temperature of main solvent, because some main solvent is solid at ambient temperature here. Lactic acid alkyl ester

Some lactic acid alkyl ester, for example ethyl lactate and isopropyl lactate, its ClogP value is in the useful range of about 0.15-0.64, can form with fabric softener active matter of the present invention and concentrate transparent liquid fabric softener composition, but need use down at the consumption slightly higher than more effective glycolic solvents (as 1, the 2-hexylene glycol).They also can be used for replacing a part other main solvent of the present invention to concentrate transparent liquid fabric softener composition to form.This illustrates in example I-C.

These main solvents all provide previously described not conspicuous benefit.III. The optional component that adds

(A) the low-molecular weight water-soluble solvent also can use, and its consumption is about 12% for about 0-, and preferably about 1-is about 10%, and more preferably from about 2-about 8%.This water-soluble solvent can not with the same low content of aforesaid main solvent under form transparent product, but when the product that main solvent is not enough to provide transparent fully, this water-soluble solvent can provide transparent product.Therefore the existence of these water-soluble solvents is the height ideal.This kind solvent comprises: ethanol, Virahol, 1, and 2-propylene glycol, 1, ammediol, Texacar PC etc., but do not comprise any main solvent (B).These water-soluble solvents affinity to water in the presence of lyophobic dust such as softening agent actives is stronger than main solvent.

(B) Whitening agent

The wetting ability white dyes that also can randomly contain some type of 0.005-5% weight of having an appointment in the composition, they also work to suppress dye transfer.If use, preferably contain this fluorescent bleaches of about 0.001-1% weight in the composition.

Can be used for wetting ability white dyes of the present invention is the following compound of structural formula: R wherein ₁Be selected from anilino, N-2-two (hydroxyethyl) and NH-2-hydroxyethyl; R ₂Be selected from N-2-two (hydroxyethyl), N-2-hydroxyethyl-N-methylamino-, morpholinyl, chlorine and amino; M is a salt-forming cation, as sodium or potassium.

R in above chemical formula ₁Be anilino, R ₂Be N-2-two (hydroxyethyl), and M is when being positively charged ion such as sodium, whitening agent be 4,4 '-two ((4-anilino-6-(N-2-dihydroxy ethyl)-S-triazine-2-yl) amino)-2,2 '-stilbene disulfonic acid and disodium salt.This special brightener species by Ciba-Geigy Corporation with Tinopal-UNPA-GX ^Trade name sell.Tinopal-UNPA-GX is the preferred wetting ability white dyes in the composition that adds when can be used for rinsing of the present invention.

R in above chemical formula ₁Be anilino, R ₂Be N-2-hydroxyethyl-N-2-methylamino-, and M is when being positively charged ion such as sodium, then whitening agent be 4,4 '-two ((4-anilino-6-(N-2-hydroxyethyl-N-methylamino-)-S-triazine-2-yl) amino)-2,2 '-the stilbene disulfonic acid disodium salt.This special brightener species by Ciba-GeigyCorporation with Tinopal-5BM-GX ^Trade name sell.

R in following formula ₁Be anilino, R ₂Be morpholinyl, and M is when being positively charged ion such as sodium, then whitening agent be 4,4 '-two ((4-anilino-6-morpholino-S-triazine-2-yl) amino)-2,2 '-the stilbene disulfonic acid, sodium salt.This special whitening agent by Ciba-GeigyCorporation with Tinopal-AMS-GX ^Trade name sell.

(C) Dispersing auxiliary

Optional viscosity/dispersity conditioning agent

Containing saturated and the denseer composition unsaturated diol quaternary ammonium compound can be prepared into stabilising system and needn't add the concentration auxiliary agent.But composition of the present invention may need organic and/or inorganic concentration auxiliary agent to reach higher concentration and/or to satisfy higher stability criterion, and this depends on other component.May or preferably need these normally concentration auxiliary agents of viscosity modifier, so that guarantee when using the softening agent actives of certain content stability under extreme conditions.The surfactant concentration auxiliary agent is selected from usually: the alkyl cats product of (1) single long-chain; (2) nonionogenic tenside; (3) oxidation amine; (4) lipid acid; (5) their mixture.These auxiliary agents are at P﹠amp; In the application 08/461,207 of G pending trial (application on June 5 nineteen ninety-five, Wahl etc.) explanation is arranged, particularly walk to the 20th page of 12 row at the 14th page 12, this article is quoted as a reference in this article.

When having described dispersing auxiliary, its total content is about 2-25% of composition weight, preferably about 3-17%, more preferably from about 4-15%, preferably 5-13%.These materials or add as the part of REACTIVE SOFTNER raw material (I), for example, single-long-chain alkyl cats product and/or lipid acid as previously mentioned, or to add said lipid acid as isolating component be the reactant that is used for forming biodegradable fabric softener active matter.The total content of dispersing auxiliary comprises any amount that may exist as the part of component (I).

(1) Monoalkyl cationic type quaternary ammonium compound

When having monoalkyl cationic type quaternary ammonium compound, it is about 25% that its content is generally about 2-of composition weight, and preferably about 3-is about 17%, and more preferably from about 4-about 15%, preferably about 5-is about 13%, and total monoalkyl cationic type quaternary ammonium compound is in effective content range at least.

Can be used for the preferably following quaternary ammonium salt of general formula of this class monoalkyl cationic type quaternary ammonium compound of the present invention:

[R ⁴N ⁺(R ⁵) ₃] X ^-Wherein: R ⁴Be C ₈-C ₂₂Alkyl or alkenyl, preferred C ₁₀-C ₁₈Alkyl or alkenyl, more preferably C ₁₀-C ₁₄Or C ₁₆-C ₁₈Alkyl or alkenyl; Each R ⁵Be C _1-6The alkyl of alkyl or replacement (as hydroxyalkyl), preferred C ₁-C ₃Alkyl, as methyl (most preferably), ethyl, propyl group etc., benzyl, hydrogen has about 2-20 oxygen ethylene unit, preferably about 2.5-13 oxygen ethylene unit, the preferably polyethoxylated chain of about 3-10 oxygen ethylene unit, and their mixture; X ^-With front identical to formula (1) definition.

Particularly preferred dispersing auxiliary is single lauryl trimethyl ammonium chloride and single tallow trimethyl ammonium chloride, and they can be by Witco with Varisoft ^471 trade name has been bought, and can be by Witco with trade name Varisoft ^417 single oil base trimethyl ammonium chlorides of having bought.

R ⁴Base also can be connected with azonia by a group that contains linking groups such as one or more esters, acid amides, ether, amine, and the basic condensability for raising component (1) etc. of this connections is an ideal.These linking groups are preferably in about 1-3 carbon atom of nitrogen-atoms.

Monoalkyl cationic type quaternary ammonium compound also comprises C ₈-C ₂₂The alkyl cholinesterase.The preferred dispersing auxiliary of this type has following chemical formula:

R ¹C (O)-O-CH ₂CH ₂N ⁺(R) ₃X ^-R wherein ¹, R and X ^-Definition the same.

Highly preferred dispersing auxiliary comprises C ₁₂-C ₁₄Cocoyl cholinesterase and C ₁₆-C ₁₈The tallow cholinesterase.

At United States Patent (USP) 4,840, narrated the single-long-chain alkyl dispersing auxiliary of the suitable biodegradation type that in long-chain, contains ester bond among 738 (Hardy and the Walley, on June 20th, 1989 issued), this patent is quoted as a reference in this article.

When dispersing auxiliary contains the alkyl cholinesterase, preferably also contain in the composition a spot of, preferably account for the organic acid of the about 2-5% of composition weight.Narrated organic acid in european patent application 404471 (Machin etc., announce December 27 nineteen ninety, preamble), this article is here quoted as a reference.Organic acid preferably is selected from oxyacetic acid, acetate, citric acid and composition thereof.

The ethoxylation quaternary ammonium compound that can be used as the dispersing auxiliary use comprises ethyl two (polyethoxyethanols) the alkyl ethylsulfuric acid ammonium that has 17 moles of ethylene oxide, and it can be obtained trade name Variquat by SherexChemical Company ^66; Polyoxyethylene glycol (15) dihydroxy ethyl methyl oil base ammonium chloride can be obtained by Akzo, and trade name Ethoquad 0/25; With polyoxyethylene glycol (15) dihydroxy ethyl methyl cocoyl ammonium chloride, can obtain by Akzo, trade name Ethoquad 0/25.

Though the major function of dispersing auxiliary is to improve the dispersiveness of ester class softening agent, dispersing auxiliary of the present invention preferably also has some softening character so that promote the softness function of composition.Therefore, the present composition preferably is substantially free of the ethoxylated non-ionic type dispersing auxiliary of non-nitrogen, and this type of material can reduce the total soft voltinism energy of composition.

In addition, have only the quaternary ammonium compound of a single long alkyl chain can protect cationic softener not interact with aniorfic surfactant and/or the detergent builder from washing soln, brought in the rinsing liquid.

(2) oxidation amine

Suitable amine oxide comprises and has about 8-22 carbon atom, preferably about 10-18 carbon atom, the more preferably from about alkyl or the hydroxyalkyl part of 8-14 carbon atom, and the amine oxide that is selected from two moieties of the alkyl that contains 1-3 the carbon atom of having an appointment and hydroxyalkyl.

Example comprises dimethyloctylamine oxide, diethyl decyl amine oxide, two (2-hydroxyethyl) decyl amine oxide, the dimethyl dodecyl amine oxide, dipropyl tetradecyl amine oxide, methylethyl hexadecyl amine oxide, dimethyl-2-hydroxyl octadecyl amine oxide and cocounut oil aliphatic alkyl dimethyl oxidation amine.

(D) stablizer

In the present composition, can there be stablizer.Here used " stablizer " speech comprises antioxidant and reductive agent.The content of these reagent is about 2% for about 0-, and preferably about 0.01-0.2% is for antioxidant 0.035-0.1% more preferably from about, for reductive agent 0.01-0.2% more preferably from about.This has guaranteed the good odor stable under the standing storage condition.Antioxidant and reductive agent stablizer are for product perfuming or low fragrance (do not have or seldom spices) particularly important.

The example that can be added to the antioxidant in the present composition comprises EastmanChemical Product, and Inc is with trade name Tenox ^PG and Tenox ^The mixture of xitix, ascorbyl palmitate and propyl gallate that S-1 sells; Can be by EastmanChemical Product, the trade name that Inc. obtains is Tenox ^The mixture of-6 BHT (butylation hydroxymethyl), BHA (butylated hydroxyanisol), propyl gallate and citric acid; The trade name that can be obtained by Uop Process Division is Sustane ^The Yoshinox BHT of BHT; Eastman Chemical Products, the trade name of Inc. is Tenox ^The tertiary butylated hydroquinone of TBHQ; Eastman Chemical Products, Inc. is with Tenox ^The natural tocopherol that the trade name of GT-1/GT-2 is sold; And EastmanChemical Products, the butylated hydroxyanisol of the trade name BHA of Inc.; Long-chain (the C of gallate ₈-C ₂₂) ester, for example gallate dodecyl ester; Irganox ^1010; Irganox ^1035; Irganox ^B1171; Irganox ^1425; Irganox ^3114; Irganox ^3125; And their mixture; Preferred Irganox ^3125; Irganox ^1425; Irganox ^3114 and composition thereof; More preferably Irganox ^3125 itself or with citric acid and/or other sequestrant for example, the citric acid isopropyl ester mixes; The chemical name that can be obtained by Monsanto is a 1-hydroxy ethylene-1, the Dequest of 1-di 2 ethylhexyl phosphonic acid (Etidronic Acid) ^2010, the chemical name that can be obtained by Kodak company is 4, the Tiron of Phenylsulfonic acid/sodium salt between the 5-dihydroxyl ^, and the chemical name that can be obtained by Aldrich is the DTPA of diethylene triaminepentaacetic acid(DTPA) ^

Below listed the chemical name and the CAS numbering of some aforementioned stable agent that can be used in the present composition in the table 1.

(E) Dirt release agent

In the present invention, can add optional dirt release agent.The adding of dirt release agent can be to be blended in the pre-composition, is blended in acid/water-bed liquid, and before or after adding ionogen, or after making final composition.Can contain 0% to about 10% with the softness composition of the inventive method preparation, preferably from 0.2% to about 5% dirt release agent.This class dirt release agent is polymkeric substance preferably.The polymkeric substance dirt release agent that can be used among the present invention comprises copolymerization block thing of terephthalate and polyoxyethylene or polyoxypropylene etc.

Preferred dirt release agent is the multipolymer with terephthalate and polyoxyethylated block.More particularly, these polymkeric substance are to about 35: 65 ethylene glycol terephthalate and polyoxyethylene terephthalate repeating unit to constitute at 25: 75 by mol ratio, and described polyoxyethylene terephthalate contains the polyoxyethylene blocks of molecular weight for about 300-about 2000.The molecular weight ranges of this polymkeric substance dirt release agent is about 5000 to 55000.

But another kind of preferred polymkeric substance dirt release agent is a kind of polyester with crystallization of ethylene glycol terephthalate repeating unit, the polyoxyethylene glycol that wherein contains the ethylene glycol terephthalate unit of about 15% weight of the 10-that has an appointment and about 50% weight of the about 10-polyoxyethylene terephthalate unit of formation of deriving from the about 300-of molecular weight about 6000, but ethylene glycol terephthalate unit and the unitary mol ratio of polyoxyethylene terephthalate are 2: 1 to 6: 1 in the polymkeric substance of crystallization.The example of this polymkeric substance comprises commercial goods Zelcon 4780 ^(from Dupont) and Milease T (from ICI).

Highly preferred dirt release agent is the following polymkeric substance of general formula: Wherein each X can be suitable capping group, and each X is selected from H usually, contains the alkyl or the acyl group of about 4 carbon atoms of about 1-.The selection of p will be considered water solubility, generally is for about 6-is about 113, is preferably about 20-about 50.U is crucial for preparation in having the liquid composition of relative high ionic strength.Wherein u should be seldom greater than 10 material.In addition, should have 20% at least, preferably have 40% wherein u at least is from about 3 to about 5 material.

R ¹⁴Part is 1 basically, the 4-phenylen moiety.Terminology used here " R ¹⁴Part is 1 basically, the 4-phenylen moiety " be meant the R in the compound ¹⁴Part is fully by 1, and the 4-phenylen moiety constitutes, and is perhaps partly replaced by other arylidene or alkyl arylene part, alkylene moiety, alkenylene part or their mixture.Can partly replace 1, the arylidene and the alkyl arylene of 4-phenylene partly comprise: 1, and 3-phenylene, 1,2-phenylene, 1,8-naphthylidene, 1,4-naphthylidene, 2,2-diphenylene, 4,4-diphenylene and their mixture.The alkylidene group and the alkenylene that can partly replace partly comprise: propylene, tetramethylene, pentamethylene, hexamethylene, 1, the inferior heptyl of 7-, octamethylene, 1,4-cyclohexylidene and their mixture.

For R ¹⁴Part, with non-1, the degree that the 4-phenylene group partly replaces should make the dirt character of freeing of compound not be subjected to any otherwise impact largely.In general, admissible part substitution value depends on the backbone length of compound, that is, long main chain can have bigger by 1,4-phenylen moiety substitution value.Usually, R wherein ¹⁴It is about 100%1 to contain the 50-that has an appointment, and the compound of 4-phenylen moiety (0% to about 50% non-1,4-phenylen moiety) has enough dirt activity of freeing.For example, the polyester made from m-phthalic acid of 40: 60 mol ratios (1, the 3-phenylene) and terephthalic acid (1, the 4-phenylene) according to the present invention has enough dirt activity of freeing.But because the most of polyester that use in the fiber manufacturing contain the ethylene glycol terephthalate unit, so normal hope reduces with 1, the degree that the group outside the 4-phenylene partly replaces is active to obtain optimum solution decontamination dirt.Preferably, R ¹⁴Part complete (that is, containing 100%) is by 1, and the 4-phenylen moiety constitutes, that is, and and each R ¹⁴Part is 1, the 4-phenylene.

For R ¹⁵Part, the suitable ethylidene or the ethylidene of replacement partly comprise ethylidene, propylene, 1,2-butylidene, 1,2-hexylidene, 3-methoxyl group-propylene and their mixture.Preferably, R ¹⁵Part is ethylidene, propylene or its mixture basically.The ethylidene part that comprises big percentage composition can be improved the activity that compound is freed dirt.Surprisingly, comprise the water solubility that can improve compound than the propylene part of big percentage composition.

Therefore, using propylene part or similar branching equivalent is desired for mix any most dirt release agent in the fabric softener composition of liquid state.Preferably, propylene partly is about 75-100%.

It is about 6 that each p value is at least, and preferably is at least about 10.Each n value is generally about 12-about 113.Generally, each p value is about 12-about 43.

Illustrating more completely in following document relevant for dirt release agent: United States Patent (USP) 4,661,267 (Decker, Konig, Straathof and Gosselink, on April 28th, 1987 issued); 4,711,730 (Gosselink and Diehl, on December 8th, 1987 issued); 4,749,596 (Evans, Huntington, Stewart, Wolf and Zimmerer, on June 7th, 1988 issued); 4,818,569 (on April 4th, 1989 issued for Trinh, Gosselink and Rattinger); 4,877,896 (on October 31st, 1989 issued for Maldonado, Trinh and Gosselink); 4,956,447 (Gosselink etc., issue September 11 nineteen ninety) and 4,976,879 (issue December 11 nineteen ninety for Maldonado, Trinh and Gosselink).These patents all are cited as a reference in this article.

These dirt release agents also can play the soap scum dispersion agent.

(F) The soap scum dispersion agent

In the present invention, pre-composition can with a kind of soap scum dispersant that is different from the optional adding of dirt release agent, and be heated to each component fusing point or higher temperature.

Preferred soap scum dispersion agent is that the lyophobic dust by the height ethoxylation forms.These lyophobic dusts can be Fatty Alcohol(C12-C14 and C12-C18), lipid acid, aliphatic amide, fatty amide, amine oxide, quaternary ammonium compound, or are used for forming the hydrophobic parts of soil release polymers.Preferred soap scum dispersion agent is the height ethoxylation, and for example each molecule on average has and surpasses approximately 17, and preferably more than about 25, more preferably more than about 40 ethylene oxide molecules, it is about 97% that polyoxyethylene partly accounts for about 76-of total molecular weight, preferably about 81-about 94%.

The content of soap scum dispersion agent is enough to make under working conditions soap scum to remain on acceptable, the unnoticed level preferably of human consumer, but is not enough to that softnessization is had disadvantageous effect.For some purpose, wish not exist soap scum.Quantity according to anionic that in the washing stage of typical laundry processes, uses or non-ionic detergent etc., the efficient that adds present composition rinse stage before, and water hardness, the quantity of negatively charged ion of carrying secretly in fabric (laundry) or nonionic detergent tensio-active agent and detergent builder (especially phosphoric acid salt and zeolite) can change.Usually, should use the soap scum dispersion agent of minimum quantity to avoid disadvantageous effect to soft voltinism matter.Generally, the requirement of soap scum dispersion agent is at least the about 2% of softening agent active matter content, preferably is at least about 4% (for farthest avoiding soap scum, at least 6%, preferably at least 10%).But under about 10% (with respect to softening agent material) or higher content, the softness effect of product has the danger of reduction, especially contains in fabric under the situation of a high proportion of nonionogenic tenside that absorbs during the washing operation.

Preferred soap scum dispersion agent is: Brij700 ^, Varonic U-250 ^, Genapol T-500 ^, Genapol T-800 ^, Plurafac A-79 ^With Neodol 25-50 ^

(G) sterilant

The example of the sterilant that uses in the present composition comprises glutaraldehyde, formaldehyde, 2-bromo-2-nitro the third-1, and (Inolex Chemical sells the 3-glycol, is positioned at Philadelphia, Binzhou, trade name Bronopol ^), and mixture (the Rohm ﹠amp of 5-chloro-2-methyl-4-isothiazoline-3-ketone and 2-methyl-4-isothiazoline-3-ketone; HaasCompany, trade name Kathon), consumption is about 1-1000ppm.

(H) spices

The present invention can comprise any spices compatible with softening agent.Suitable spices is disclosed in the United States Patent (USP) of issuing on March 19th, 1,996 5,500,138 (people such as Bacon), and this patent is quoted as a reference at this paper.

Here said spices comprises aromatoising substance or aromatoising substance mixture, comprising natural (promptly, extracting flower, grass, leaf, root, bark, wood, flowers or plant obtains), synthetical (promptly, the mixture of different natural oils or oil component) and the fragrant containing substance of synthetic (that is, synthesize make).These materials often are accompanied by auxiliary substance, for example fixative, extender, stablizer and solvent.These auxiliary substances are also included within this paper said " spices " implication.Usually, spices is the mixture of the complexity of many organic compound.

The example that can be used on the perfume composition in the spices of the present composition includes but not limited to: hexyl cinnamic aldehyde, amyl cinnamic aldehyde, orchidae, n-Hexyl salicylate, terpinol, 3,7-dimethyl-suitable-2,6-octadiene-1-alcohol, 2,6-dimethyl-sec-n-octyl alcohol, 2,6-dimethyl-7-octen-2-ol, 3,7-dimethyl-3-octanol, 3,7-dimethyl-anti--2,6-octadiene-1-alcohol, 3,7-dimethyl-6-octen-1-ol, 3,7-dimethyl-1-octanol, 2-methyl-3-(to tert-butyl-phenyl) propionic aldehyde, 4-(4-hydroxy-4-methyl amyl group)-3-tetrahydrobenzene-1-formaldehyde, tricyclo decenyl propionate, verdy acetate, aubepine, 2-methyl-2-(p-isopropyl phenyl) propionic aldehyde, glycidic acid ethyl-3-methyl-3-phenylester, 4-(p-hydroxybenzene) fourth-2-ketone, 1-(2,6,6-trimethylammonium-2-tetrahydrobenzene-1-yl)-2-butylene-1-ketone, to *-methoxy acetophenone, to methoxyl group-α-phenyl propylene, methyl-2-n-hexyl-3-oxo-cyclopentane carboxylicesters, peach aldehyde.

Other example of aromatoising substance includes but not limited to: orange oil, lemon oil, Oil of grapefruit, Oils, bergamot peel, clove(bud)oil, γ-dodecylic acid lactone, methyl-2-(2-amyl group-3-oxocyclopentyl) acetic ester, β-Nai Jiami, methyl-β-naphthalenone, tonka bean camphor, capraldehyde, phenyl aldehyde, acetate 4-tertiary butyl cyclohexyl, acetate α, alpha-alpha-dimethyl phenethyl ester, acetate aminomethyl phenyl methyl esters, the Schiff's base of 4-(4-hydroxy-4-methyl amyl group)-3-tetrahydrobenzene-1-formaldehyde and methyl oaminobenzoate, the ring-type ethylene glycol diester of undecane dicarboxylic acid, 3,7-dimethyl-2,6-octadiene-1-nitrile, cetone gamma, α-Zi Luolantong, alpha, beta-lonone, petitgrain oil, vertofix coeur, 7-ethanoyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethyl-naphthalene, methylionone, methyl isophthalic acid, 6,10-trimethylammonium-2,5,9-cyclododecatriene-1-base ketone, 7-ethanoyl-1,1,3,4,4, the 6-vegolysen, 2,3, the 4-tetraline, the 4-ethanoyl-6-tertiary butyl-1,1-dimethyl-1, the 2-indane, benzophenone, 6-ethanoyl-1,1,2,3,3,5-vegolysen, 2-indane, 5-ethanoyl-3-sec.-propyl-1,1,2,6-tetramethyl--1,2-indane, 1-dodecanal, 7-hydroxyl-3,7-dimethyl octanal, 10-hendecene-1-aldehyde, dissident's thiazolinyl hexahydrobenzaldehyde, the formyl radical tristane, the cyclopentadecane acid lactide, 16-hydroxyl-9-hexadecanoic acid lactone, 1,3,4,6,7,8-six hydrogen-4,6,6,7,8,8-hexamethyl cyclopenta-γ-2-chromene, ambroxane, ten dihydros-3a, 6,6,9a-tetramethyl-naphtho-(2,1b) furans, cypress camphor, 5-(2,2,3-front three basic ring penta-3-thiazolinyl)-3-methylpent-2-alcohol, 2-ethyl-4-(2,2,3-trimethylammonium-3-cyclopentenes-1-yl)-2-butylene-1-alcohol, caryophyllenol, cedryl acetate, to the tert-butylcyclohexyl acetic ester, Wrinkled Gianthyssop Herb, frankincense balm, cistus creticus, Vetiveria zizanoides, flaw in a piece of jade  face cream, Canada turpentine; And the condensation product of following substances: laurine and methyl o-aminobenzoate; Laurine and indoles; Phenylacetic aldehyde and indoles; 4-(4-hydroxy-4-methyl amyl group)-3-tetrahydrobenzene-1-formaldehyde and methyl o-aminobenzoate.

Other example of perfume composition has Geraniol, meraneine, phantol, phanteine, tetrahydrolinalool, geraniol, citronellyl acetate, dihydromyrcenol, acetate dihydromyrcene ester, Tetrahydromyrcenol, tirpinyl acetate, nopol, nopyl acetate, 2-phenylethyl alcohol, acetate 2-phenyl chlorocarbonate, phenylcarbinol, jasmal, benzyl salicylate, peruscabin, acetate 1-phenyl chlorocarbonate, dimethylbenzylcarbinol, trichloromethyl phenyl methyl alcohol methyl phenyl carbinol acetic ester, vanoris, acetate vetiveryl ester, vetiverol, 2-methyl-3-(to tert-butyl-phenyl) propionic aldehyde, 2-methyl-3-(p-isopropyl phenyl) propionic aldehyde, 3-(to tert-butyl-phenyl) propionic aldehyde, 4-(4-methyl-3-pentenyl)-3-tetrahydrobenzene formaldehyde, 4-acetoxy-3-amyl group tetrahydropyrans, methyl dihydrojasmonate, 2-n-heptyl cyclopentanone, 3-methyl-2-amyl group cyclopentanone, n-capric aldehyde, n-dodecane aldehyde, 9-decenol-1, phenoxyethyl isobutanoate, the phenylacetic aldehyde dimethyl acetal, the phenylacetic aldehyde diethyl acetal, lemonile, citronellyl nitrile, cypress base acetal, the 3-Santalex, cypress base methyl ether, the different ketone that comes into leaves, the aubepine nitrile, aubepine, heliotropine, oxymethoxyallylbenzene, vanillin food grade,1000.000000ine mesh, phenyl ether, laurine, jononeionone, methylionone, isoraldeine, irone, suitable-3-hexenol and ester thereof, the indane musk odorant, tetralin musk spices, isochroman musk spices, macrocyclic ketone, big lactone musk odorant, the undecane dicarboxylic acid glycol ester.

The spices that can be used for the present composition is not halide matter and nitro musk basically.

The suitable solvent of above-mentioned perfume composition, diluent or carrier for example have: ethanol, Virahol, Diethylene Glycol, monoethyl ether, dipropylene glycol, diethyl phthalate, triethyl citrate etc.Mix these solvents in the spices, the minimum quantity that provides uniform spice solution required preferably is provided the quantity of diluent or carrier.

The content of spices can be final product composition having weight 0% to about 10%, it is about 5% to be preferably about 0.1-, more preferably about 0.2-about 3%.Fabric softener composition of the present invention has improved the deposition of fabric spices.

(I) sequestrant

The compositions and methods of the invention can randomly use one or more copper and/or nickel sequestrant.This water-soluble chelator can be selected from the aromatic chelating agent of aminocarboxylate, amino phosphonates do, multifunctional replacement and their mixture, and they are all with the definition of back.The whiteness of fabric and/or brightness improve greatly owing to this sequestrant or recover, and each Stability of Substance is improved in the composition.

The aminocarboxylate that can be used as sequestrant of the present invention comprises edetate (EDTA), N-hydroxyethyl-ethylenediamine triacetate, nitrilotriacetic acid(NTA) salt (NTA), ethylenediamine tetrapropionic acid(EDTP) salt, quadrol-N, N '-two glutaminate, 2-hydroxyl propylene diamine-N, N '-two succinate, triethylenetetraaminehexaacetic acid salt, diethylentriamine pentacetate (DETPA) and ethanol Diglycocol ester comprise their water-soluble salt, an alkali metal salt for example, ammonium salt of ammonium salt and replacement and composition thereof.

When allowing low total phosphorous to exist in the detergent composition at least, phosphoro-amidate also is adapted at using as sequestrant in the present composition, this comprises ethylenediamine tetraacetic (methylene phosphonic acid salt), diethylenetriamine-N, N, N ', N "; N "-five (methane phosphonic acid) salt (DETMP) and 1-hydroxyl ethane-1,1-diphosphonate (HEDP).Preferably, these amino phosphonates do do not contain alkyl or the alkenyl more than 6 carbon atoms.

The consumption of sequestrant is generally about 2ppm to about 25ppm in rinse stage, soak time from 1 minute until several hours.

The preferred EDDS (being also referred to as quadrol-N, N '-two succinate) that the present invention uses is the material of describing in the above-mentioned United States Patent (USP) 4,704,233, has following chemical formula (listing free acid form):

As described in this patent, EDDS can prepare with maleic anhydride and quadrol.(S, S) isomer of preferred biodegradable EDDS can pass through L-aspartic acid and glycol dibromide prepared in reaction.EDDS is that than the superior part of other sequestrant it is all effective to two kinds of positively charged ions of chelating copper and mickel, can obtain with biodegradable form, and not phosphorous.The EDDS that uses as sequestrant among the present invention is generally its salt form, that is, one or more in four acidic hydrogens are replaced by water-soluble cationic M (for example sodium, potassium, ammonium, triethanol ammonium etc.).As previously mentioned, the EDDS sequestrant usually also with the consumption use of about 2ppm to about 25ppm, soaked 1 minute to several hours in rinse cycle.Under certain pH, EDDS preferably is used in combination with zinc cation.

As seen by above-mentioned, a very big class sequestrant can be used for the present invention.Really, simple multi-carboxylate and Citrate trianion, hydroxyl two succinates etc. also can use, though these sequestrants are effective not as aminocarboxylate and phosphonate by weight.Therefore, consider different chelating effectiveness degree, can regulate dosage level.Sequestrant to be advisable at least about 5, preferably is at least about 7 to the stability constant (complete Ionized sequestrant) of cupric ion among the present invention.Generally, it is about 10% that sequestrant constitutes about 0.5-of composition weight, and more preferably from about 0.75-about 5%.Preferred sequestrant comprises DETMP, DETPA, NTA, EDDS and their mixture.

(J) other optional component that adds

The present invention can be included in normally used optional components in the textile treatment composition, for example: tinting material, sanitas, tensio-active agent, sanforzing agent, fabric stiffener, spotting agent, sterilant, mycocide, antioxidant such as Yoshinox BHT, anticorrosive agent etc.

Particularly preferred component comprises water-soluble calcium and/or magnesium compound, and they can provide additional stability.Chloride salt is preferred, but acetate, nitrate etc. also can use.The consumption of calcium salt and/or magnesium salts is about 2% for about 0-, and preferably about 0.05-is about 0.5%, and more preferably from about 0.1-about 0.25%.

The present invention also comprises the component that other is compatible, is included in disclosed compound in the following patent application: the application 08/372,068 of pending trial (submit to January 12 nineteen ninety-five, people such as Rusche); 08/372,490 (submit to January 12 nineteen ninety-five, people such as Shaw); With 08/277,558 (on July 19th, 1994 submitted to, people such as Hartman).Above-mentioned document is quoted as a reference in this article. Solids composition1. Solid particle composition

As previously mentioned, the present invention also comprises solid particle composition, wherein contains:

(A) about 50-is about 95%, the described biodegradable fabric sofetening actives of preferably about 60-about 90%;

(B) randomly, 0% to about 30%, the dispersity conditioning agent of preferably about 3-about 15%; With

(C) from 0% to about 10% pH regulator agent. Optional pH regulator agent

Because how many hydrolysis easily of biodegradable ester kind fabric softening agent actives, optional pH regulator agent preferably in the solid particle composition that will add water, comprised, to form stable rare or dense liquid softener composition.It is about 5 that the pH (net value) of this stable fluid composition should be about 2-, and preferably about 2-is about 4.5, and more preferably from about 2-about 4.

PH can regulate by adding a kind of water-soluble solid Bronsted acid.The example of suitable Bronsted acid comprises inorganic mineral acid, as boric acid, sodium pyrosulfate, sal enixum, SODIUM PHOSPHATE, MONOBASIC, potassium primary phosphate and their mixture; Organic acid, as citric acid, fumaric acid, toxilic acid, oxysuccinic acid, tannic acid, glyconic acid, L-glutamic acid, tartrate, oxyacetic acid, Mono Chloro Acetic Acid, phenylium, 1,2,3,4-ethylene-dimalonic acid, Phenylsulfonic acid, phosphenylic acid, o-toluene sulfonic acid, tosic acid, sulfocarbolic acid, naphthene sulfonic acid, oxalic acid, 1,2,4,5-pyromellitic acid, 1,2,4-benzenetricarboxylic acid, hexanodioic acid, phenylformic acid, toluylic acid, Whitfield's ointment, Succinic Acid and their mixture; And mineral acid and organic acid mixture.Preferred pH regulator agent is citric acid, glyconic acid, tartrate, 1,2,3,4-ethylene-dimalonic acid, oxysuccinic acid and their mixture.

Can form the material of solid clathrate compound, for example cyclodextrin and/or zeolite etc., can be randomly in solid particle composition the host's carrier as dense liquid acids and/or acid anhydrides (as acetate, hydrochloric acid, sulfuric acid, phosphoric acid, nitric acid, carbonic acid etc.) play auxiliary.The example of this class solid clathrate compound is a United States Patent (USP) 3,888,998 (Whyte and Samps, announced on June 10th, 1975) and United States Patent (USP) 4,007, the disclosed carbonic acid gas that is adsorbed among the zeolite A among 134 (Liepe and the Japikse, on February 8th, 1977 issued), above-mentioned two patents are all quoted as a reference in this article.At United States Patent (USP) 4,365, the example of the inclusion complex of phosphoric acid, sulfuric acid and nitric acid is disclosed among 061 (Szejetli etc., issue December 21 nineteen eighty-two), this patent is quoted as a reference in this article.

In use, it is about 10% that the consumption of pH regulator agent is generally about 0.01%-of composition weight, preferably about 0.1%-about 5%. The preparation of solid granular fabric softener

By the preparation melt, with its cooling curing, grind and be sized to desired size then, can form particle.In a ternary mixture, for example in the mixture of nonionogenic tenside, single long chain cation tensio-active agent and DEQA, when forming particle, more preferably nonionic surface active agent and more diffluent single-long-chain alkyl cationic compound are pre-mixed, are mixed into then in the melt of diester type quaternary amines cation compound.

The about 1000 μ m of the preferably about 50-of the diameter of particulate primary particle, the about 400 μ m of preferably about 50-, the about 200 μ m of more preferably about 50-.Can contain littler and bigger particle in the particle, but preferably about 85-is about 95%, preferably about 95-about 100% is in pointed scope.Littler and bigger particle does not form best milk sap/dispersion in being added to water the time.Can use other the method for preparing primary particle, comprise melt spray is cooled off.That primary particle can agglomerate into is dustless, sticking and free-pouring powder.Can in the agglomerating device (that is, zig-zag mixing machine, Lodige mixing machine) of routine, carry out agglomeration with water-soluble binder.The example that can be used for the water-soluble binder in the above-mentioned agglomeration method comprises glycerine, polyoxyethylene glycol, polymkeric substance such as PVA, polyacrylic ester, and natural polymer such as sugar.

The particulate flowability can be by using flow improver additive, and for example clay, silicon-dioxide or zeolite particles, water-soluble inorganic salt, starch etc. are handled particle surface and improved. Using method

Can in the granulous solids composition, add water to form rare or the softener composition that thicks liquid, be used for being added to afterwards the rinse stage of laundry processes, wherein biodegradable cationic softener compound concentrations is about 0.5-about 50%, preferred about 1-is about 35%, preferably about 4-about 32%.The solids composition that adds when this granulous, rinsing (1) also can directly be added in the rinsing bath so that enough working concentrations (for example, total softening agent active ingredient is the about 1000ppm of about 10-, is preferably the about 500ppm of about 50-) to be provided.Can in bathing, rinsing add liquid composition, so that same working concentration to be provided.

The water temperature of preparation usefulness should be about 90 ℃ of about 20-, about 80 ℃ of preferably about 25-.For solids composition, it is about 15% to be preferably about 0-of composition weight as the content of the single-long-chain alkyl cationic surfactant of viscosity/dispersity conditioning agent, and preferably about 3-is about 15%, more preferably about 5-about 15%.Content is about 20% for about 5-, be preferably the nonionic surface active agent of about 8-about 15% and the mixture of these reagent also can play viscosity/dispersity conditioning agent effectively.

Particle is being added in the water when forming water base enriched material, the median size of the particle of formed emulsification/dispersion is usually less than about 10/ μ m, and preferably less than about 2 μ m, the about 2 μ m of more preferably about 0.2-are so that be implemented in effective deposition on the fabric." median size " used in this manual is meant number average bead diameter, that is, the diameter of the particle more than 50% is less than the size of regulation.

The particle diameter of the particle of emulsification/dispersion is measured with for example Malvern particle-size analyzer.

According to the nonionic and the cats product of concrete selection, when using the solid obtaining liq, may need to use a kind of in some situation with particle dispersion and emulsive effective means (as mixing machine).

The solid particle composition that is used for preparing liquid composition can randomly contain ionogen, spices, defoamer, flow promotor (as silicon-dioxide), dyestuff, sanitas and/or aforesaid other optional component that adds.

Adding water in the particulate solid composition comprises to form the benefit that was added to the aqueous composition in the rinsing bath afterwards: can make the weight of transportation less, thereby make transportation more economical; And can form and similar (example as described in this article) liquid composition of selling the human consumer usually with lower energy consumption (that is, less shearing and/or lower temperature).Moreover granulous solid fabric softening agent composition is when directly selling to the human consumer, and is lower to the requirement of packing, and container is less, easier disposal.The human consumer is added to composition in the available more competent container subsequently, and adds water so that composition is diluted in advance, prepares to be used for rinsing then and bathes, as liquid composition of the present invention.Liquid form uses easily, because it makes and measures and distribution becomes simple.2. Drying machine activatory composition

The invention still further relates to improved drying machine activatory fabric softener solids composition, it or (A) be incorporated in the finished product of manufacturing, for example on carrier, or (B) to be similar to above-mentioned particle form (comprising the suitable coacervate of described particulate, pill and small pieces).These compositions contain the fabric softener of about 10-about 95% usually.A. Carrier products

In preferred embodiments, the present invention includes the finished product of manufacturing.Representational goods are to be suitable for being included in disclosed all kinds in the following patent: United States Patent (USP) 3,989 forming unique fragrance and the goods that make fabric sofetening in the washing dryer automatically, 631 (Marsan, on November 2nd, 1976 issued), 4,055,248 (Marsan, on October 25th, 1977 issued), 4,073,996 (Bedenk etc., on February 14th, 1978 issued), 4,022,938 (Zaki etc., on May 10th, 1977 issued), 4,764,289 (Trinh, on August 16th, 1988 issued), 4,808,086 (Evans etc., on February 28th, 1989 issued), 4,103,047 (Zaki etc., on July 25th, 1978 issued), 3,736,668 (Dillarstone, on June 5th, 1973 issued), 3,701,202 (Compa etc., on October 31st, 1972 issued), 3,634,947 (Furgal, on January 18th, 1972 issued), 3,633,538 (Hoeflin, on January 11st, 1972 issued), 3,435,537 (Rumsey, on April 1st, 1969 issued) and 4,000,340 (Murphy etc., on December 28th, 1976 issued), all these patents are all quoted as a reference in this article.

The typical products and its of this type comprises the goods that contain following component:

I. fabric-conditioning compositions, but wherein contain about 30-about 95% be generally solid, drying machine remollescent fabric softener, contain said biodegradable fabric sofetening actives in this softening agent;

II. device for dispensing, it can discharge the described composition of effective quantity, comprises the ii of effective quantity, is enough to that the fabric in automatic washing dryer provides smell to control under washing dryer service temperature (for example about 35-115 ℃) automatically.

When this device for dispensing was flaky flexible carrier, fabric-conditioning compositions was fixed on the carrier with releasable form, and the weight ratio that makes care composition and dried carrier is about 10: 1 to about 0.5: 1, was preferably about 5: 1 to about 1: 1.

Solid fabric softening agent composition of the present invention can comprise the cationic and non-ionic type fabric softener active matter that combination with one another is used.The preparation of the preparation glycols main solvent of main solvent

A lot of synthetic methods can be used for preparing glycols main solvent of the present invention.Suitable method will require according to the concrete structure of each main solvent to select.In addition, most of main solvents also can prepare with more than one method.Therefore, the described method of each specific main solvent is only supplied the usefulness of example explanation here, should not think a kind of restriction. Method A1,5-, 1,6-and 1, the preparation of 7-glycol Method 1

This synthetic method is to be derived by the cycloolefin that replaces to form α, the general preparation method of ω-type glycol.The example of cycloolefin is the alkylation isomer of cyclopentenes, tetrahydrobenzene and suberene.The general formula of the alkylation cycloolefin that is suitable for is:

Wherein each R is H or C ₁-C ₄Alkyl, x are 3,4 or 5.

Cycloolefin can utilize a three-step reaction to change into the end glycol.

Step 1 is cycloolefin and ozone (O ₃) reaction in solvent (as anhydrous ethyl acetate), form the intermediate ozonide.In step 2 with ozonide with palladium catalyst/H for example ₂Be reduced into dialdehyde, in step 3, utilize the borohydride reduction to change into the target glycol then.

1, the 2-glycol is generally prepared through direct hydroxylation by suitable substituted olefine.The example of substituted olefine is: Wherein each R is H, alkyl etc.

In a typical reaction, the perosmic anhydride of alkene and hydrogen peroxide (30%) and catalytic quantity reacts in the trimethyl carbinol or in other suitable solvent.Reaction is cooled to about 0 ℃, and the order reaction is spent the night.Unreacted compound and solvent are removed in distillation, and it is desired 1 to utilize distillation or Crystallization Separation to go out, the 2-glycol. Method 2

Another kind method be utilization and metachloroperbenzoic acid or peracetic acid in solvent (as methylene dichloride) in the reaction that is lower than under about 25 ℃ temperature, conversion of olefines is become epoxide.The epoxide that produces with this reaction is subsequently by for example coming open loop formation glycol with the dilute sulphuric acid hydrolysis.In step 3, form the target glycol by the borohydride reduction. Method 3

The other method for preparing these compounds is to use the perosmic anhydride of hydrogen peroxide and catalytic quantity with the direct hydroxylation of cycloolefin.This reaction forms cyclic diols, and it changes into the dialdehyde of open chain subsequently with periodate or lead tetraacetate.Then dialdehyde is reduced into as method 1 usefulness borohydride desired 1,5-or 1,6-glycol etc. Method B1, the preparation of 2-glycol Method 1 Method C1, the preparation of 3-glycol The acidylate of enamine

This preparation method is used for 1 of general type, and the 3-glycol also adapts to constructional feature miscellaneous.Enamine is formed by ketone and aldehyde, and they and chloride of acid react, and form acylate.The sulfonamide derivatives of acidylate is hydrolyzed into the carbonyl compound of its acidylate again, and it is desired 1,1 of 3-glycol, 3-dicarbapentaborane precursor.Glycol then by with borohydride with 1,3-dicarbonyl compound reduction generates.

For example acetaldehyde (aldehyde) can with secondary amine, preferred cyclic amine such as tetramethyleneimine or morpholine add the reaction of hot rotation stream together in solvent (as toluene) and under the tosic acid of catalytic quantity.When amine and carbonyl compound reaction (condensation), produced water and utilization and for example removed through Tuo Shui Qi rotation stream.After the water of removing theoretical quantity, if desired, the stripping reaction mixture removes solvent (can carry out in most of situation acylation reactions) in same solvent under vacuum for example.

The anhydrous rough enamine that contains some superfluous amine obtains the enamine of acylations in about 20 ℃ of following and suitable chloride of acid reactions.This reaction can at room temperature be stirred usually and be spent the night.Subsequently total reaction mixture is poured on the trash ice, stirs, make mixture be acid with 20% hydrochloric acid.This processing is hydrolyzed into enamine the dicarbonyl compound of acidylate.Then remove lower-boiling impurity, intermediate separated by extraction and distillation, be reduced into sodium borohydride more desired 1, the 3-glycol. Method DBy aldol condensation and reduction, preparation 1,4-glycol

Typical reaction relates to one or more aldehyde that at least one α-hydrogen atom is arranged, one or more ketone, and their mixture on the close carbon atom of carbonyl.The representative instance of some reactants and some possible final products are as follows:

R-CH ₂-CHO+R′-CH ₂-CHO→HO-CH ₂-CH(R)-CHOH-CH ₂-R+

HO-CH ₂-CH(R′)-CHOH-CH ₂-R′+

HO-CH ₂-CH(R′)-CHOH-CH ₂-R+

HO-CH ₂-CH(R)-CHOH-CH ₂-R′

R-CH ₂-CHO+R′-CO-CH ₃→HO-CH ₂-CH(R)-CHOH-CH ₂-R+

R-CH ₂-CHOHCH ₂-CHOH-R′

Want aldehyde, ketone or its mixture of condensation to be placed in the autoclave under the inert atmosphere, be added with a kind of solvent such as butanols or a kind of phase transition medium such as polyoxyethylene glycol.When target is when for example using the mixing condensation of ketone and aldehyde, two kinds of common consumptions of reactant are about 1: 1 mol ratio.The strong alkali catalyst such as the sodium methylate that add catalytic quantity are generally about 0.5-10% of reactant mole number.With the autoclave sealing, mixture has transformed up to most of primitive reaction thing about 35-100 ℃ of heating down, needs 5 minutes to 3 hours approximately usually.With the neutralization of rough mixture, under about 100 ℃ and about 50 normal atmosphere, on Raney nickel, make carbonyl functional group's hydro-reduction of existence, about 1 hour.Volatile constituent is removed in distillation, obtains desired glycol main solvent with vacuum distillation method.

More information about this preparation method is disclosed in synthetic (Synthesis), (3), 164-5 (1975), A.Pochini and R.Ungaro; Pct international patent application WO9,507,254, Kulmala etc., March 16 nineteen ninety-five; Japanese patent application No.40,333, Sato etc., February 9 nineteen ninety; Japanese patent application No.299,240, Sato etc., on December 4th, 1989; European patent application No.367,743, Ankner etc., May 9 nineteen ninety; All these articles and patent are all quoted as a reference at this paper.

Embodiment illustrates the condensation of butyraldehyde and/or isobutyric aldehyde and changes into eight carbon-1, the 3-glycol

Be equipped with at a 500ml that (about 2.3g, about 0.1 mole, (about 148g, Aldrich), dissolves up to sodium fully by about 2 moles Aldrich) to handle a propyl carbinol with sodium Metal 99.5 in the 3 neck round-bottomed flasks of splash bar, built-in temperature meter, prolong and nitrogen atmosphere pipe connecting.Add then butyraldehyde (about 72g, about 1 mole, Aldrich) and isobutyric aldehyde (about 72g, about 1 mole, mixture Aldrich) is maintained at about system under 40 ℃, reacts up to the original aldehyde of major part.Add sulfuric acid carefully alkaline catalysts neutralized, remove by filter any salt, solution under about 100 ℃ and about 50 normal atmosphere on Raney nickel about 1 hour of hydrogenation to form 8 carbon-1, the mixture of 3-glycol.Any isopropylcarbinol that forms during butanols solvent and the hydrogenation is removed in distillation, to obtain 2,2,4-trimethylammonium-1,3-pentanediol, 2-ethyl-1,3-hexylene glycol, 2,2-dimethyl-1,3-hexylene glycol and 2-ethyl-4-methyl isophthalic acid, eight carbon-1 of 3-pentanediol, the mixture of 3-glycol.Randomly, this mixture vacuum available distillation method or be further purified with activated carbon decolorizing.Recovered solvent is used for the preparation of next batch glycol.

When only using butyraldehyde in reaction, the principal product that obtains is a 2-ethyl-1, the 3-hexylene glycol.

When only using isobutyric aldehyde in reaction, the principal product that obtains is 2,2,4-trimethylammonium-1,3-pentanediol.The mixing condensation of butyraldehyde and methylethylketone and conversion form eight carbon-1, the mixture of 3-glycol. Condition A. in the 500ml three neck round-bottomed flasks that splash bar, built-in temperature meter, condenser and nitrogen atmosphere connecting leg are housed, (about 2.3g, about 0.1 mole, (about 148g, Aldrich), dissolves until sodium fully by about 2 moles Aldrich) to handle a propyl carbinol with sodium Metal 99.5.Add subsequently butyraldehyde (about 72g, about 1 mole, Aldrich) and 2-butanone (about 72g, about 1 mole, mixture Aldrich), system is maintained at about under 40 ℃, reacts up to most of primary butyraldehyde.Add sulfuric acid carefully alkaline catalysts is neutralized, cross and filter out any salt.Randomly, can utilize distillation that unreacted initiator is removed with reaction solvent.The mixture that contains condensation product is about 1 hour of hydrogenation on Raney nickel under about 100 ℃ and about 50 normal atmosphere, generates 8-carbon-1, the mixture of 3-glycol, wherein comprise 2-ethyl-1,3-hexylene glycol, 2-ethyl-3-methyl isophthalic acid, the 3-pentanediol, 3, the 5-ethohexadiol, 3-methyl-3, the 5-heptanediol and more a spot of other 1,3-glycol isomer, 3-methyl-2 for example, 4-heptanediol and 3,4-dimethyl-2,4-hexylene glycol.This rough diol mixture can utilize fractionating process to be further purified. Condition B. repeat above reaction, but every mole of 2-butanone is with about 2 moles of butyraldehyde.This make reaction product have higher proportion from aldehyde from the glycol of condensation (promptly, 2-ethyl-1, the 3-hexylene glycol) with from the glycol of aldehyde and 2-butanone mixing condensation (2-ethyl-3-methyl isophthalic acid for example, 3-pentanediol and 3, the 5-ethohexadiol), and than small proportion from 2-butanone from the glycol of condensation (as 3-methyl-3,5-heptanediol and 3,4-dimethyl-2, the 4-hexylene glycol). Condition C. repeat above condensation, difference is, puts into about 1 mole of 2-butanone in the reactor that solvent and catalyzer are housed, and adds about 1 mole of butyraldehyde gradually.Adjusting condition makes the slow from condensation rates of 2-butanone, and the active carbonyl group of more aldehyde is adding fashionable just reaction rapidly.It is a high proportion of by 2-butanone and butyraldehyde condensation and the glycol that formed from condensation by 2-butanone that this contains reaction product, the glycol that is formed from condensation by butyraldehyde of low ratio. Condition D. under cold condition, repeat above condensation reaction C.About 1.0 moles 2-butanone is dissolved in the anhydrous tetrahydro furan of about 5 times of volumes.Solution is cooled to-78 ℃ approximately, adds about 0.95 mole of potassium hydride KH in batches.After hydrogen stops to emit, solution is kept about 1 hour to reach the more stable enolate of balance formation, be slowly to add one mole of butyraldehyde-n under about-78 ℃ fully stirring and keeping temperature then.Make solution be warmed to room temperature gradually after adding, add sulfuric acid carefully and neutralize.Remove by filter salt.Randomly, can utilize distillation that unreacted initiator is removed with reaction solvent.The mixture that contains condensation product is about 1 hour of hydrogenation on Raney nickel under about 100 ℃ and about 50 normal atmosphere, main formation by the enolate of 2-butanone and the glycol of butyraldehyde condensation generation, 3,5-ethohexadiol.Can randomly carry out purifying with distillation method.The mixing condensation of isobutyric aldehyde and methylethylketone and conversion form eight carbon-1, the mixture of 3-diketone

Repeat the reaction of above condition A, just replace butyraldehyde with isobutyric aldehyde.Condensation and reduction are all carried out similarly, and final diol product mainly is 2,2,4-trimethylammonium-1,3-pentanediol, 2,2,3-trimethylammonium-1,3-pentanediol, 2-methyl-3,5-heptanediol and 3-methyl-3,5-heptanediol.The mixing condensation of butyraldehyde, isobutyric aldehyde and methylethylketone and conversion form eight carbon-1, the mixture of 3-glycol

Repeat the reaction of above condition A, but butyraldehyde, isobutyric aldehyde and 2-butanone all use about 1 mole.Condensation is carried out in a similar manner with reduction, obtains eight carbon-1, the mixture of 3-glycol, wherein mainly contain 2,2,4-trimethylammonium-1, the 3-pentanediol, 2-ethyl-1,3-hexylene glycol, 2,2-dimethyl-1,3-hexylene glycol, 2-ethyl-4-methyl isophthalic acid, 3-pentanediol, 2-ethyl-3-methyl isophthalic acid, the 3-pentanediol, 3, the 5-ethohexadiol, 2,2,3-trimethylammonium-1,3-pentanediol, 2-methyl-3,5-heptanediol and 3-methyl-3, the 5-heptanediol, and by 2-butanone other a small amount of isomer that condensation forms at methylene radical rather than on methyl.

Mixture by butyraldehyde, isobutyric aldehyde and/or methylethylketone condensation prepared, wherein the content of any specific compound is advisable to be no more than about 90% weight, preferably be no more than about 80%, more preferably no more than about 70%, be no more than about 60% better, preferably be no more than about 50%.In addition, the content of butyraldehyde and isobutyric aldehyde should not surpass approximately 95% in the reaction mixture, preferably is no more than approximately 90%, more preferably no more than about 85%, preferably is no more than about 80% weight. Method EUtilize the addition preparation 1 of acetylide and carbonyl compound, the 4-glycol

Bimetal acetylide Na ^+-: C ≡ C: ⁺Na ⁺Form unsaturated alcohol with the aldehydes or ketones reaction, for example:

Formed alkyne diol is reduced into alkene then or is reduced into saturated glycol fully.This reaction also can be undertaken by following: the reaction of the sodium acetylide slurry with about 18% and carbonyl compound to be forming alkynol, it can change into sodium salt and with the carbonyl compound reaction of another mole, form undersaturated 1, the 4-glycol.When using blended carbonyl compound and diethyl acetylide, will form diol mixture.Under the situation of using an acetylide, can obtain specific structure with higher productive rate.Illustrative embodiment: 6-methyl-2, the preparation of 5-heptanediol

Sodium carbide (in dimethylbenzene, about 18%) slurry and isobutyric aldehyde reaction form alkynol

This alkynol changes into sodium carbide R-CHOH-C ≡ CNa with alkali, and it reacts with a mole of acetaldehyde subsequently, generates alkyne diol R-CHOH-C ≡ C-CHOH-R ¹This compound, (CH ₃) ₂CH-CHOH-C ≡ C-CHOH-CH ₃Can be used as unsaturated diol and separate, if desired, utilize catalytic hydrogenating reduction Cheng Hanshuan key but not the triple-linked respective compound, or further be reduced into shortening saturated 1, the 4-glycol. Method FReplace the preparation of glycol by cyclic anhydride, lactone and the ester deutero-of dicarboxylic acid

This preparation method is used for synthetic glycol, and is especially several by dicarboxylic acid anhydride, diester and lactone deutero-1, the 4-glycol, but be not limited to 1,4-glycol or four-carbon dicarboxylic acid.

The glycol of these types is generally by coming synthetic with two (2-methoxy ethoxy) sodium aluminum hydrides (Red-Al) as reductive agent reduction parent acid anhydrides, lactone or diester.This reductive agent is commercially available as 3.1 molar solutions in toluene, and every mole of reagent is emitted a moles of hydrogen.Every mole of substrate of diester and cyclic anhydride needs about 3 moles of Red-Al.The Succinic anhydried example of utilizing alkyl to replace illustrates this method, and typical reduction reaction is carried out as follows:

Earlier acid anhydrides is dissolved in the dry toluene, puts into the reactor that dropping funnel, mechanical stirrer, warm degree meter and rotation stream prolong are housed, connecting calcium chloride and soda-lime pipe that isolated steam and carbonic acid gas are used on the prolong.Reductive agent in toluene is put into dropping funnel, slowly be added in the acid anhydrides solution that is stirring.Exothermic heat of reaction makes temperature near about 80 ℃.In the remaining reinforced time and add the back to keep temperature in about 2 hours be about 80 ℃.

Make the reaction mixture cool to room temperature subsequently.Mixture is added in the aqueous hydrochloric acid that refrigerative is stirring in ice bath (concentration about 20%), and temperature is maintained at about 20-30 ℃.After the acidifying, with mixture separation, organic layer is washed with rare salts solution in separating funnel, is neutral until pH paper.With neutral glycol solution dried over mgso, filter, the decompression stripping, obtain desired 1, the 4-glycol. Method GHas one or two preparation for the second month in a season or tertiary alcohol functional group's glycol

This is to utilize methyl-magnesium-bromide (Grignard reagent) or alkyl lithium compounds (being generally lithium methide) that carboxyl is carried out the universal method of alkylation from the glycol of lactone and/or diester preparation replacement, for example:

This class alkylated reaction can expand to diester.Methylating reagent is excessive can to produce the glycol that two alcohol radicals are tertiary alcohol base. Method H1 of replacement, 3-, 1,4-and 1, the preparation of 5-glycol

This method be adopt the principles of chemistry described in method A-1 and the method A-2 prepare some 1,3-, 1,4-and 1, the universal method of 5-glycol.The change here is to use the cycloolefin described in the closed chain diene replacement method A.The general formula of initiator is: Wherein each R is H or C ₁-C ₄Alkyl, x are 1,2 or 3.

The reaction with method A in identical, difference is, for formed every mole of desired glycol main solvent, produces one mole ethylene glycol, for example, below by 1-ethyl-5,5-dimethyl-1,3-cyclohexanediol (CAS No.79419-18-4) preparation 2,2-dimethyl-1, the 4-hexylene glycol:

The preparation of polyethoxylated derivative

The polyethoxylated derivative of glycol main solvent generally prepares in high-pressure reactor under nitrogen atmosphere.The oxyethane of suitable quantity is added in the mixture of diol solvent and potassium hydroxide under high temperature (about 170 ℃ of about 80-).The quantity of oxyethane is calculated with respect to diol solvent quantity, so that add the ethylene oxide group of correct number in each glycol molecules.When reaction was finished, after for example about 1 hour, residual unreacted oxyethane was removed in decompression.Illustrative embodiment: 3 of tetraethoxyization, 3-dimethyl-1, the preparation of 2-butyleneglycol

Rise the about 354g of adding (about 3.0 moles) 3 in the Parr reactor, 3-dimethyl-1,2-butyleneglycol and about 0.54g potassium hydroxide to the 2-that temperature-control device is housed.Reactor purges with nitrogen and finds time three times to about 30mmHg pressure.Then reactor is full of nitrogen again to barometric point, is heated to about 130 ℃.Slightly vacuumize the pressure of reactor is adjusted to a little less than normal atmosphere.Added oxyethane (about 528g, about 12.0 moles) in one hour, controlled temperature is about 130 ℃ simultaneously.After reacting about one hour again, reactor content is cooled to about 90 ℃, any residual oxyethane is removed in decompression.The preparation of the polyethoxylated derivative of methyl blocking

The polyethoxylated derivative of the methyl blocking of glycol utilizes poly-(oxyethyl group) ethyl chloride (that is CH, of the methoxyl group of the chain length of wanting usually ₃O-(CH ₂CH ₂O) _n-CH ₂CH ₂-Cl) with selected glycol prepared in reaction, or utilize polyoxyethylene glycol (that is CH, of the methyl blocking of the chain length of wanting ₃O-(CH ₂CH ₂O) _n-CH ₂CH ₂-OH) with the preparation of the epoxidation precursors reaction of glycol, or with the combination of these methods.Illustrative embodiment: 2-methyl-2, the tetraethoxy derivative (CH of the methyl blocking of 3-butyleneglycol ₃) ₂C (OH) CH (CH ₃) (OCH ₂CH ₂) ₄OCH ₃Synthetic

To magnetic splash bar, condenser, thermometer and temperature regulator (ThermowatchI are housed ²R) add tetraethylene-glycol methyl ether (about 208g, about 1.0 moles) and sodium Metal 99.5 (Aldrich, about 2.3g, about 0.10 mole) in 1 liter of three neck round-bottomed flask, mixture is heated to about 100 ℃ under argon gas.After the sodium dissolving, add 2-methyl-2,3-butylene oxide ring (about 86g, about 1.0 moles), solution spends the night at argon gas and about 120 ℃ of following stirrings. ¹³C-NMR (DMSO-d ₆) show that the epoxide peak disappears, and reacts complete.With the reaction mixture cooling, pour in isopyknic water, saturated with the neutralization of 6N hydrochloric acid with sodium-chlor, use the dichloromethane extraction secondary.The dichloromethane layer dried over sodium sulfate that merges removes solvent, obtains the desired Aethoxy Sklerol of rough form.Can randomly carry out purifying with the vacuum fractionation method.Synthesizing of methoxyl group triethoxy ethyl chloride

Under argon atmospher to magnetic splash bar, condenser and temperature regulator (ThermowatchI are housed ²R) add tetraethylene-glycol methyl ether (about 208g, about 1.0 moles) in one liter of three neck round-bottomed flask.Dropwise added thionyl chloride (about 256.0g, about 2.15 moles) under fully stirring in about 3 hours, keeping temperature is 50-60 ℃.Then with reaction mixture in about 55 ℃ of following heated overnight. ¹³C-NMR (D ₂O) show that at～60ppm place the small peak of unreacted alcohol is only arranged ,～there is representative chlorizate (CH at the 43.5ppm place ₂Cl) sizable peak.In this material, slowly add saturated nacl aqueous solution, destroyed up to thionyl chloride.Dissolve in about 300ml saturated nacl aqueous solution reaction mixture and about 500ml dichloromethane extraction.With the organic layer drying, on Rotary Evaporators, remove solvent, obtain rough methoxyethoxyethyl chlorine.Can randomly carry out purifying with the vacuum fractionation method.The 2-methyl isophthalic acid, the tetraethoxy derivative C of the methyl blocking of 3-pentanediol ₂H ₅CH (OH) CH (CH ₃) CH ₂(OCH ₂CH ₂) ₄OCH ₃Synthetic

With pure C ₂H ₅CH (OH) CH (CH ₃) CH ₂OH (about 116g, about 1.0 moles) puts into one with about 100ml as the tetrahydrofuran (THF) of solvent magnetic splash bar, condenser and temperature regulator (Thermowatch is housed ^I ²R) in one liter of three neck round-bottomed flask.Add sodium hydride (about 32g, about 1.24 moles) in this solution, system Bao Chi rotation stream stops to emit until gas in batches.Add methoxyl group triethoxy ethyl chloride (about 242g, about 1.2 moles, as above preparation), system Bao Chi rotation flowed about 48 hours.Reaction mixture is cooled to room temperature, under agitation dropwise adds water carefully unnecessary hydride is decomposed.On Rotary Evaporators, remove tetrahydrofuran (THF).Rough product is dissolved in about 400ml water and Xiang Shuizhong dissolves in enough sodium-chlor and makes it near saturated level.Use the dichloromethane extraction mixture secondary of about 300ml subsequently.The dichloromethane layer dried over sodium sulfate that merges removes solvent on Rotary Evaporators, obtain crude product.Can randomly utilize the bulb device under about 150 ℃ and vacuum, further to remove unreacted initiator and low molecular weight by-products is carried out purifying.Randomly, but vacuum distilling be further purified to obtain the title polyethers.The preparation of poly-propoxylated derivative

One three neck circle flask is equipped with magnetic splash bar, solid CO ₂Cooler condenser, addition funnel, thermometer and temperature-control device (Therm-O-Watch, I2R).Blow off air in the system with nitrogen gas stream, load onto the device that covers reaction mixture with nitrogen then.In reaction flask, add and want propenoxylated absolute alcohol or glycol.In reactor, add the sodium Metal 99.5 of about 0.1-5 mole % carefully, if be necessary then to heat, so that the reaction of all sodium in batches.With extremely about 80-130 ℃ of reaction mixture heat, dropwise add propylene oxide (Aldrich) from addition funnel subsequently, the speed of adding should keep from solid-state CO ₂Cooler condenser has Shao Liang rotation stream.Continue to add propylene oxide, up to adding the desired quantity of specific propoxylation degree.Continue heating,, keep about 1 hour of this temperature to react completely guaranteeing again up to propylene oxide Ting Zhi rotation stream.Subsequently reaction mixture is cooled to room temperature, adds suitable acid such as methylsulfonic acid carefully and neutralize.Cross and filter out all salt, obtain desired propoxylation products.Average propoxylation degree is determined by the quadrature of 1H-NMR spectrum usually.The preparation of poly-butoxy derivative

One three neck circle flask is loaded onto magnetic splash bar, solid CO ₂Cooler condenser, addition funnel, thermometer and temperature-control device (Therm-O-Watch, I2R).Blow off the air of system with nitrogen gas stream, load onto the device that covers reaction mixture with nitrogen atmosphere then.In reaction flask, add absolute alcohol or the glycol of wanting butoxyization.The sodium Metal 99.5 that in batches adds about 0.1-5 mole % carefully in reactor, heating in case of necessity is so that all sodium reactions.To react mixture heat subsequently to about 80-130 ℃, and dropwise add α-butylene oxide ring (Aldrich) from dropping funnel, the speed of adding should keep by solid-state CO ₂The refrigerative condenser has Shao Liang rotation stream.Continue to add butylene oxide ring, up to adding the desired quantity of specific butoxy degree.Continue heating up to butylene oxide ring Ting Zhi rotation stream, keep again reacting completely with assurance in the about 1-2 of this temperature hour.Subsequently reaction mixture is cooled to room temperature, adds suitable acid such as methylsulfonic acid carefully and neutralize.Remove by filter all salt, obtain desired butoxy product.Average butoxy degree is used usually ¹The quadrature of H-NMR spectrum is determined.The preparation of poly-four inferior methoxylation derivatives

About 0.1 mole a desired absolute alcohol or glycol initiator are put into three mouthfuls of round-bottomed flasks that magnetic stirrer, condenser, built-in temperature meter and argon cover gas system are housed.If desired " four inferior methoxylations " average degree is about one of each hydroxyl, then add about 0.11 mole of 2-(4-chlorine butoxy) tetrahydropyrans (ICI) for every mol of alcohol functional group.Add solvent in case of necessity, as anhydrous tetrahydrofuran (THF), diox or dimethyl formamide.Divide short run to add sodium hydride (with respect to excessive about 5% mole of chlorine-containing compound) under fully stirring subsequently, keeping temperature simultaneously is about 30-120 ℃.After all hydride has reacted, keep this temperature until the equal hexylization of all alcohol radicals, need 4-24 hour usually approximately.With its cooling, the branch short run adds methyl alcohol carefully unnecessary hydride is decomposed after reaction is finished.Add the water of about equal volume then, pH regulator is arrived about 2 with sulfuric acid.Be warmed to about 40 ℃ and kept about 15 minutes on Rotary Evaporators, removing solvent so that after the hydrolysis of tetrahydropyrans protecting group, reaction mixture neutralizes with sodium hydroxide.Resistates is dissolved in ether or the methylene dichloride, crosses to filter out salt.Remove the alcohol or the glycol that obtain four rough inferior methoxylations behind the solvent.Can be further purified with vacuum distilling.If wish that average four final inferior methoxylation degree less than 1, then use the chlorine-containing compound and the hydride of relative lesser amt.Greater than 1 situation, the circulation whole process repeated reaches target level up to accumulation for average four inferior methoxylation degree.The preparation of alkyl and aryl list glyceryl ether

A kind of method that makes things convenient for for preparing alkyl and/or aryl list glyceryl ether comprises the corresponding alkyl glycidyl ether precursor of preparation earlier.Subsequently it is changed into ketone acetal, be hydrolyzed into single glyceryl ether (glycol) again.Be below the preparation preferred n-pentyl list glyceryl ether (that is, 3-(pentyloxy)-1,2-propylene glycol) just-C ₅H ₁₁-O-CHOH-CH ₂OH) illustrative embodiment.3-(pentyloxy)-1, the preparation of 2-pentanediol

In 2 liters of round-bottom reaction flask of one three mouthfuls (suspention agitator, water-cooled condenser, mercurythermometer and addition funnel are housed), pack into about 546g NaOH aqueous solution (about 50% concentration) and about 38.5g sulfuric acid hydrogenation tetrabutylammonium (PTC, phase-transfer catalyst).With the contents stirred of flask so that dissolving adds about 200g 1-propyl alcohol and about 400ml hexane (isomer mixture contains about 85% normal hexane) then.About 418g Epicholorohydrin of in addition funnel, packing into, with it at leisure (dropwise) be added in the reaction mixture that is stirring.Because exothermic heat of reaction, temperature rises to about 68 ℃ gradually.The order reaction continues about 1 hour (not having extra heat release) after adding Epicholorohydrin.

Rough reaction mixture is with about 500ml warm water dilution, stirring leniently, and water layer and removing subsequently settles out.Hexane layer is with about 1 liter warm water mixed diluting once more, add dilute sulfuric acid aqueous solution with the pH regulator of mixture to about 6.5.Divide water-yielding stratum again and outwell, hexane layer is with fresh washing 3 times.Isolate hexane layer subsequently, be evaporated to driedly with Rotary Evaporators, obtain rough n-pentyl glycidyl ether. Acetonation (changing into ketone acetal)

About 1 liter of acetone of in 2 liters 3 neck round-bottomed flasks (being furnished with suspention agitator, water-cooled condenser, mercurythermometer and addition funnel), packing into.Under agitation in acetone, add about 1mlSnCl ₄Add the n-pentyl glycidyl ether that about 200g has just prepared at an addition funnel that is arranged in above the reaction flask.Glycidyl ether is added to very lentamente (governing speed is with the control heat release) in the acetone soln that is stirring.About 1 hour (about 52 ℃ of top temperature) carried out in the order reaction after adding glycidyl ether. Hydrolysis

Conversion be will install to be used for distillation, heating jacket and temperature regulator added.Distilling about 600ml acetone concentrates the reaction mixture crude product.In the refrigerative concentrated solution, add about 1 liter of aqueous sulfuric acid (concentration about 20%) and about 500ml hexane.Subsequently flask contents is heated to about 50 ℃ (setting device is to collect and the acetone that separates to emit) down in stirring.Continuing this hydrolysis reaction determines to react completely up to TLC (thin-layer chromatography) analysis.

With the cooling of rough reaction mixture, separate and discard water layer.Organic layer with the dilution of 1 intensification water, adds rare NaOH aqueous solution (1N) pH is transferred to about 7 subsequently.Divide water-yielding stratum once more, organic layer is with fresh washing 3 times.Isolate organic phase subsequently, evaporate with Rotary Evaporators.Resistates dilutes with fresh hexane, and desired product is extracted into (about 70/30 weight ratio) in the methanol/water solution.Methanol/water solution is evaporated to dried (adding methyl alcohol in addition to promote the water evaporation) with Rotary Evaporators.Resistates is knitted the filter paper heat filtering through glass micro-fibers, obtains n-pentyl list glyceryl ether.Synthesizing of the preparation two of two (hydroxyalkyl) ether (2-hydroxyl butyl) ether

Three mouthfuls of round-bottomed flasks of 500ml of magnetic stirrer, built-in temperature meter, addition funnel, condenser, argon gas source and heating jacket are housed with one of argon gas purge.Add 1 subsequently, the 2-butyleneglycol (about 270g, about 3 moles, Aldrich) and sodium Metal 99.5 (about 1.2g, Aldrich), makes sodium dissolving by about 0.05 mole.Subsequently reaction mixture is heated to about 100 ℃, under agitation dropwise add butylene oxide ring (about 71g, about 1 mole, Aldrich).Continue heating and stop, continuing heating 1 hour again and react completely so that make up to butylene oxide ring De rotation stream.With sulfuric acid neutralization reaction mixture, remove by filter salt, liquid under vacuum fractionation to reclaim unnecessary butyleneglycol.Desired ether obtains with the resistates form.Can randomly carry out purifying with further vacuum distilling.Synthesizing of two (2-hydroxycyclopent base) ether

1 liter of 3 mouthfuls of round-bottomed flask of magnetic stirrer, built-in temperature meter, addition funnel, condenser, argon gas source and heating jacket are housed with one of argon gas purge.Add 1 successively subsequently, 2-ring pentanediol (about 306g, about 3 moles, Aldrich) with the boron trifluoride diethyl etherate title complex (about 0.14g, about 0.01 mole, the cis-trans isomer mixture, Aldrich).Reaction mixture is maintained at about 10-40 ℃ subsequently, (about 84g, Aldrich), reacts up to all epoxy amylenes by about 1 mole under agitation dropwise to add the epoxy amylene.With sodium hydroxide neutralization reaction mixture, liquid under vacuum fractionation to reclaim superfluous ring pentanediol.Desired ether obtains as resistates.Can randomly carry out purifying by further vacuum distilling.

Above disclosed method is only for the example explanation, and purpose is to help those skilled in the art to implement the present invention, rather than limitation of the present invention.

In the specification sheets and embodiment of this paper, all percentage ratio, ratio and umber, except as otherwise noted, all by weight, and all numerical value limit all are regular approximate.All quote as a reference in this article at all documents that relative section is quoted.

Below be non-limiting example of the present invention:

Be suitable N below, N-two (unsaturated fatty acyl group-oxygen ethyl)-N, N-alkyl dimethyl ammonium chloride fabric sofetening actives (DEQA) has the fatty acyl group APPROXIMATE DISTRIBUTION that provides, and they are used for preparing following composition in the back. Fatty acyl group DEQA ¹ DEQA ² DEQA ³ DEQA ⁴ DEQA ⁵C12 trace trace 00 0,C14 3300 0,C16 4455 5,C18 0056 6C14: 1330 0C16: 1 11 700 3C18: 1 74 73 71 68 67C18: 2488 11 11C18: 30112 2C20: 10022 2C20 and in Shang 00200 Wei Zhi 00667 Zong 99 99 100 100 102IV 86-90 88-95 99 100 95 Shun/anti-20-30 20-30 45 5TPU 49 10 13 13TPU=polyunsaturated fat Xian base Zong amounts, by weightFatty acyl group DEQA ⁶ DEQA ⁷ DEQA ⁸C14 01 0,C16 11 25 5,C18 4 20 14C14: 100 0C16: 110 1C18: 1 27 45 74C18: 2 50 63 C18: 3700 Qi Ta 033 Zong meter 100 100 100IV 125-138 56 Wu Shuo according to Shun/anti-(C18: 1) Wu Shuo according to 7 Wu Shuo according to TPU 57 6 Wu the Shuo certificate

Below be suitable N, N-two (side chain fatty acyl group oxygen ethyl)-N, N-alkyl dimethyl ammonium chloride fabric sofetening actives (DEQA), it has the fatty acyl group APPROXIMATE DISTRIBUTION that provides, and is used to prepare following composition in the back.

Fatty acyl group DEQA ¹⁰ DEQA ¹¹ DEQA ¹²

Different tetradecanoic acid--1-2--

Tetradecanoic acid 7-11 0.5-1--

Different palmitinic acid 6-7 6-7 1-3

Palmitinic acid 4-5 6-7--

Unimac 5680 70-76 80-82 60-66

Stearic acid--2-3 8-10

Isooleic acid----13-17

Oleic acid----6-12

IV 32 7-12 The softening agent actives DEQA ¹³ DEQA ¹⁴ DEQA ¹⁵ DEQA ¹⁶Fatty acyl group side chain fat side chain fat side chain fat side chain fat

Fat acid 1 fat acid 2 fat acid 3 fat acid 4 The softening agent actives DEQA ¹⁷ DEQA ¹⁸ DEQA ¹⁹ DEQA ²⁰Fatty acyl group α-heptyl 9-and 10-9-and 10-methoxyl group 18

Capric acid methoxyl group 18 isopropoxies ten alkanoic acid isomer

Alkanoic acid eight alkanoic acid mixtures The softening agent actives DEQA ²¹ DEQA ²² DEQA ²³Fatty acyl group phenyl ten prestox phenyl phenoxy groups

Alkanoic acid octadecanoic acid octadecanoic acid The softening agent actives DEQA ²⁴ DEQA ²⁵Fatty acyl group is used to prepare DEQA ²Be used to prepare DEQA ⁸With

DEQA ¹⁰The DEQA of lipid acid ¹⁰Lipid acid

65: 35 mixture of 65: 35 mixture

Following examples have shown the transparent or semitransparent product with acceptable viscosity.

Preparation of compositions method in following examples is to pass through earlier to make the softening agent pre-composition at room temperature with the DEQA and the blending of undersaturated DEQA actives of suitable branching.If the softening agent actives at room temperature is not a fluid, can be with softening agent actives heat fused under for example about 130-150 (about 55-66 ℃).With IKA RW 25 ^Mixing machine mixes the softening agent mixture about 2-5 minute under about 150rpm.In addition, hydrochloric acid is at room temperature mixed with deionization (DI) water, make acid/water-bed liquid.If softening agent actives and/or main solvent at room temperature be not fluid and need the heating, then acid/water-bed liquid also should be heated to about 100 °F (about 38 ℃) and keep this temperature with water-bath.Main solvent (if its fusing point is higher than room temperature and then melts under suitable temperature) is added in the softening agent pre-composition, mixed about 5 minutes.In the softening agent pre-composition, add acid/water-bed liquid then and mixed about 20-about 30 minutes, perhaps become transparent and even to composition.Necessary seasonal composition air cooling is to envrionment temperature.

Embodiment 1 to 6

Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6 Composition Wt.% Wt.% Wt.% Wt.% Wt.% Wt.%DEQA ²(85% 19.9--15.3--32.5--actives/ethanol) DEQA ⁸(85%--19.9--15.3--, 32.5 activess/ethanol) DEQA ¹⁰(85% 10.7 10.7 15.3 15.3 17.5 17.5 active matters/Yi alcohol) Yi alcohol----222 21,2-hexylene glycol 18 18 18 18 28 28 Xiang material 1.2 1.2 1 1.35 1.3 1.3HCl (pH2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 Zheng heat up in a steamer Shui Yu amount Yu amount Yu amount Yu amount Yu amount Yu amount

Embodiment 7 to 12

Embodiment 7 Embodiment 8 Embodiment 9 Embodiment 10 Embodiment 11 Embodiment 12 Composition Wt.% Wt.% Wt.% Wt.% Wt.% Wt.%DEQA ²(85% 19.9------32--actives/ethanol) DEQA ⁸(85%----19.9 19--19 activess/ethanol) DEQA ¹¹(85% 10.7----------actives/ethanol) DEQA ¹²(85%--28--------actives/ethanol) DEQA ¹³(85%----5.4------actives/ethanol) DEQA ¹⁴(85%----5.4------actives/ethanol) DEQA ¹⁵(85%------59--actives/ethanol) DEQA ¹⁶(85%------69--actives/ethanol) DEQA ¹⁸(85%----------6 activess/ethanol) DEQA ¹⁹(85%----------6 active matters/Yi alcohol) 1,--1------1 Xiang material 1.2 1 1.2 1.35 2 1.3HCl (pH2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 Zheng heats up in a steamer Shui Yu amount Yu amount Yu amount Yu amount Yu amount Yu amount to 2-hexylene glycol 18 15 18 18 28 18 Yi alcohol

Embodiment 13 to 18

Embodiment 13 Embodiment 14 Embodiment 15 Embodiment 16 Embodiment 17 Embodiment 18 Composition Wt.% Wt.% Wt.% Wt.% Wt.% Wt.%DEQA ¹(85% 19.9----19.9 activess/ethanol) DEQA ⁶(85%--17--------actives/ethanol) DEQA ⁸(85%----19.9------actives/ethanol) DEQA ⁹(85%--19.9 19.9 activess/ethanol) DEQA ¹⁰(85%--6.8 7777 activess/ethanol) DEQA ¹¹(85% 5.3----------actives/ethanol) DEQA ²⁰(85% 5.3----------actives/ethanol) DEQA ²¹(85%--6.8--------actives/ethanol) DEQA ²²(85%----3.7------actives/ethanol) DEQA ²³(85%------3.7----actives/ethanol) DEQA ²⁴(85%--------3.7--actives/ethanol) DEQA ²⁵(85%----------3.7 activess/ethanol) 1,2-hexylene glycol 99 18 18 18 92-ethyl-8------91,3-hexylene glycol 2,2,4-trimethylammonium--9-----1,3-pentanediol ethanol 2----------spices 1.2 1.2 1.2 1.2 1.2 1.2HCl (pH2-3.5) 0.005 0.005 0.005 0.005 0.005 0.005 distilled water surplus surplus surplus surplus surplus surplus

Embodiment 19-21

Embodiment 13 Embodiment 14 Embodiment 15 Composition Wt.% Wt.% Wt.%DEQA ²⁴(85% actives/ethanol) 30--15DEQA ²⁵(85% actives/ethanol)--30 151,2-hexylene glycol 18 18 18HCl (pH2-3.5) 0.005 0.005 0.005 distilled water surplus surplus surplus

Above embodiment has shown the transparent or semitransparent product with acceptable viscosity value.

The composition of embodiment 22 prepares at ambient temperature in order to following method:

1. preparation contains the water-bed liquid of HCl.

2. respectively, spices and Tenox antioxidant are mixed in the diester softening agent actives.

3. at the bottom of diester actives blend being added to sour water under stirring in the liquid.

4. adding diester adds about 10-20% when roughly half is measured CaCl ₂Solution.

5. after adding glycol, under stirring, add remaining CaCl ₂Solution.

Embodiment 22 to 27

Embodiment 22 Embodiment 23 Embodiment 24 Embodiment 25 Embodiment 26 Embodiment 27 Composition Wt.% Wt.% Wt.% Wt.% Wt.% Wt.%DEQA ²(85% 18--15------actives/ethanol) DEQA ⁸(85%--18--12----actives/ethanol) DEQA ¹⁰(85% 9.2 9.2 15 12----actives/ethanol) DEQA ²⁴(85%--------20.8--actives/ethanol) DEQA ²⁵(85%----------28 activess/ethanol) spices 1.35 1.35 1.35 1.35 1.35 1.35Tenox 6 0.04 0.04 0.04 0.04 0.04 0.04CaCl ₂(25% 222222 solution) HCl 1N 0.30 0.30 0.30 0.30 0.30 0.30 distilled water surplus surplus surplus surplus surplus surplus

Above embodiment has shown the dispersion composite with good stability and performance.The processing situation

Some mixture of aforesaid main solvent B and main solvent B and second solvent, can prepare and contain the softening agent actives A (55-about 85% that is about pre-composition weight, preferred about 60-about 80%, more preferably from about 65-about 75%), main solvent B (is about 10-about 30% of pre-composition weight, preferred about 13-about 25%, more preferably from about 15-about 20%) and the pre-composition of optional water-soluble solvent C (be that about 5-of pre-composition weight is about 20%, preferably about 5-is about 17%, and more preferably from about 5-about 15%).As mentioned before, main solvent B can randomly replace with the main solvent B of effective quantity and the mixture of some inapplicable solvent.Contain the fabric sofetening actives A of requested number and the main solvent B of sufficient amount to some extent in these pre-compositions, and randomly also contain solvent C, so that make pre-composition have desirable viscosity number for desired temperature range.The typical viscosities that is fit to processing preferably less than about 500 centipoises, is more preferably less than about 300 centipoises less than about 1000 centipoises.Adopt low temperature to improve security, reduced degraded and/or loss, and reduced demand, thereby save processing charges heating such as materials such as biodegradable fabric softener active matter, spices owing to having reduced solvent evaporation.By during the actives preparation, adding for example sequestrant (as the quadrol pentaacetic acid), can provide extra provide protection to the softening agent actives.Consequently improved the influence of environment and the security of preparation manipulation have been improved.

Pre-composition and use the example of their method to comprise following pre-composition, as example explanation among the above embodiment, usually contain about 85%, preferred about 80%, the fabric softener active matter A of 65-about 75% more preferably from about of about 60-of about 55-, and, preferably about 13-about 25%, the more preferably from about main solvent of 15-about 20% (as 1,2-hexylene glycol) and about 5-about 20%, the preferably water-soluble solvent C of about 5-about 15% (as ethanol and/or Virahol) about 30% with the about 10-of its blended.

These pre-compositions can be used to prepare final product composition having in the method that may further comprise the steps:

1. the pre-composition of preparation fabric sofetening actives, about 11% ethanol and about 17% main solvent makes it be cooled to envrionment temperature.

2. spices is sneaked in the pre-composition.

3. prepare liquid at the bottom of the mixing of water and HCl at ambient temperature.Can randomly add sequestrant.

4. under fully stirring, pre-composition is added in the water-bed liquid.

5. use CaCl ₂Solution is adjusted to desired viscosity.

6. add dye solution to obtain desirable color.

Fabric sofetening actives (DEQA), main solvent B and the optional water-soluble solvent that adds can be mixed with pre-composition, and this pre-composition can be used to prepare above composition.

On commercial applications, above transparent composition is packed in the container, particularly by polypropylene (but glass, oriented polyethylene etc. can substitute) bottle made, especially in the transparent bottle (but also available translucent bottle), bottle have that light blue tone exists with counteracting or the issuable any yellow of lay up period (still, short-term is used and complete transparent product, can use the transparent vessel that does not have tone or have other tone), and ultraviolet absorbers is arranged to reduce the effect of UV-light in the bottle to inner material, especially to the effect (absorption agent also can be from the teeth outwards) of highly unsaturated actives.Total effect of the transparency and container is the clarity that shows composition, thereby makes the human consumer be sure of the quality of product.

Claims

1. the biodegradable fabric softener active matter that has following each chemical formula:

(1)

[(R) _4-m-N ⁽⁺⁾-[(CH ₂) _n-Y-R ¹] _m] X ^(-)(1) wherein each R substituting group is hydrogen or short chain C ₁-C ₆Alkyl or hydroxyalkyl; Each m is 2 or 3; Each n is 1-4; Each Y is-O-(O) C-,-(R) N-(O) C-,-C (O)-N (R)-or-C (O)-O-; Each R ¹In the carbonatoms summation, Y for-O-(O) C-or-(R) add 1 during N-(O) C-, be C ₆-C ₂₂But the carbon atom summation is less than 12 R ¹Or YR ¹Be no more than 1, and other R ¹Or YR ¹The carbon atom summation is at least 16, each R ¹Contain a long-chain C ₅-C ₂₁Branched-chain alkyl or unsaturated alkyl can be chosen wantonly and be substituted, and branched-chain alkyl is 5: 95 to 95: 5 with the ratio of unsaturated alkyl, for unsaturated alkyl, and this R ¹The iodine number of the maternal fatty acid of base is 20-140, wherein gegenion X ^-Can be any negatively charged ion compatible with softening agent;

(2) softening agent of following chemical formula: Wherein each Y, R, R ¹And X ^(-)Implication the same; And

(3) their mixture, this softening agent actives randomly contain and are up to single long-chain softening agent of 20%, one of them YR ¹Base is-OH ,-N (R) H or-C (O) OH.

2. the fabric softener active matter of claim 1, it has following chemical formula:

[(R) _4-m-N ⁽⁺⁾-[(CH ₂) _n-Y-R ¹] _m] X ^(-)(1) wherein each R substituting group is hydrogen or short chain C ₁-C ₆Alkyl or hydroxyalkyl; Each m is 2 or 3; Each Y is-O-(O) C-; Each R ¹It is C that middle carbonatoms summation adds 1 ₆-C ₂₂But the carbon atom summation is less than 12 YR ¹Be no more than 1, and other YR ¹The carbon atom summation be at least 16, each R ¹Be long-chain C ₅-C ₂₁Branched-chain alkyl or unsaturated alkyl can randomly be substituted, and branched-chain alkyl is 75: 25 to 25: 75 with the ratio of unsaturated alkyl, for unsaturated alkyl, and this R ¹The iodine number of the maternal fatty acid of group is 50-130.

3. claim 1 or 2 fabric sofetening actives, it comprises the mixture of compound, contains (1) in the described compound and is the R of branched-chain alkyl ¹Group and (2) are the R of unsaturated alkyl ¹Group.

4. claim 1 or 2 fabric softener active matter, the compound that wherein contains contains the following group of blended: (1) is the R of branched-chain alkyl ¹Group and (2) are the R of unsaturated alkyl ¹Group.

5. fabric softener composition, wherein contain:

A. be the biodegradable fabric softener active matter of composition weight 2-80%, this actives is selected from: (1) has the softening agent of following chemical formula:

[(R) _4-m-N ⁽⁺⁾-[(CH ₂) _n-Y-R ¹] _m] X ^(-)(1) wherein each R substituting group is hydrogen or short chain C ₁-C ₆Alkyl or hydroxyalkyl; Each m is 2 or 3; Each n is 1 to 4; Each Y is-O-(O) C-,-(R) N-(O) C-,-C (O)-N (R)-or-C (O)-O-; Each R ¹In the carbonatoms summation, when Y for-O-(O) C-or-(R) add 1 during N-(O) C-, be C ₆-C ₂₂But the carbon atom summation is less than 12 R ¹Or YR ¹Be no more than one, and other R ¹Or YR ¹The carbon atom summation is at least 16, each R ¹Contain long-chain C ₅-C ₂₁Branched-chain alkyl or unsaturated alkyl can randomly be substituted, and branched-chain alkyl is 5: 95 to 95: 5 with the ratio of unsaturated alkyl, and for unsaturated alkyl, this R ¹The iodine number of the maternal fatty acid of base is 20-140, gegenion X wherein ^-Can be any negatively charged ion compatible with softening agent.

(2) have the softening agent of following chemical formula:

Wherein each Y, R, R ¹And X ^(-)Has above-mentioned identical meanings;

(3) their mixture and

The softening agent actives randomly contains and is up to single long-chain softening agent of 20%, one of them YR ¹Base is-OH ,-N (R) H or-C (O) OH;

B. randomly, be less than 40% main solvent of composition weight, its ClogP is 0.15-0.64;

C. randomly, be enough to improve the low-molecular weight water-soluble solvent of effective quantity of transparency, be selected from ethanol, Virahol, propylene glycol, 1, ammediol, Texacar PC and composition thereof, the content of this water-soluble solvent itself will can not form clear composition;

D. randomly, can improve the water-soluble calcium and/or the magnesium salts of effective quantity of transparency; With

E. all the other are water.

6. the fabric softener composition of claim 5 wherein contains the softening agent actives of 15-70%, and this fabric softener active matter has following chemical formula:

[(R) _4-m-N ⁽⁺⁾-[(CH ₂) _n-Y-R ¹] _m] X ^(-)(1) wherein each R substituting group is hydrogen or short chain C ₁-C ₆Alkyl or hydroxyalkyl; Each m is 2 or 3; Each Y is-O-(O) C-; Each R ¹Middle carbon atom summation adds 1 and is C ₆-C ₂₂But the carbon atom summation is less than 12 YR ¹Be no more than one, and other YR ¹The carbon atom summation is at least 16, each R ¹Be long-chain C ₅-C ₂₁Branched-chain alkyl or unsaturated alkyl can randomly be substituted, and branched-chain alkyl is 75: 25 to 25: 75 with the ratio of unsaturated alkyl, for unsaturated alkyl, and this R ¹The iodine number of the maternal fatty acid of group is 50-130.

7. claim 5 or 6 fabric softener composition, wherein said ClogP is 0.25-0.62.

8. the fabric softener composition in the claim 5, wherein under the low water content of 5-15%, softening agent actives/main solvent weight ratio is 55: 45 to 85: 15; Under the water-content of 15-70%, softening agent actives/main solvent weight ratio is 45: 55 to 70: 30; Under the high water content of 70-80%, softening agent actives/main solvent weight ratio is 30: 70 to 55: 45.

9. the fabric softener composition in the claim 5, wherein main solvent is to be selected from:

I. monohydroxy-alcohol comprises:

A. n-propyl alcohol; And/or

B.2-butanols and/or 2-methyl-2-propyl alcohol;

II. the hexylene glycol isomer comprises 2,3-dimethyl-2,3-butyleneglycol; 2,3-dimethyl-1,2-butyleneglycol; 3,3-dimethyl-1,2-butyleneglycol; 2-methyl-2, the 3-pentanediol; 3-methyl-2, the 3-pentanediol; 4-methyl-2, the 3-pentanediol; 2, the 3-hexylene glycol; 3, the 4-hexylene glycol; 2-ethyl-1, the 2-butyleneglycol; The 2-methyl isophthalic acid, the 2-pentanediol; The 3-methyl isophthalic acid, the 2-pentanediol; The 4-methyl isophthalic acid, the 2-pentanediol; And/or 1, the 2-hexylene glycol;

III. the heptanediol isomer comprises: 2-butyl-1, ammediol; 2,2-diethyl-1, ammediol; 2-(1-methyl-propyl)-1, ammediol; 2-(2-methyl-propyl)-1, ammediol; 2-methyl-2-propyl group-1, ammediol; 2,3,3-trimethylammonium-1,2-butyleneglycol; 2-ethyl-2-methyl isophthalic acid, the 4-butyleneglycol; 2-ethyl-3-methyl isophthalic acid, the 4-butyleneglycol; 2-propyl group-1, the 4-butyleneglycol; 2-sec.-propyl-1, the 4-butyleneglycol; 2,2-dimethyl-1,5-pentanediol; 2,3-dimethyl-1,5-pentanediol; 2,4-dimethyl-1,5-pentanediol; 3,3-dimethyl-1,5-pentanediol; 2,3-dimethyl-2,3-pentanediol; 2,4-dimethyl-2,3-pentanediol; 3,4-dimethyl-2,3-pentanediol; 4,4-dimethyl-2,3-pentanediol; 2,3-dimethyl-3,4-pentanediol; 2-ethyl-1, the 5-pentanediol; The 2-methyl isophthalic acid, the 6-hexylene glycol; The 3-methyl isophthalic acid, the 6-hexylene glycol; 2-methyl-2, the 3-hexylene glycol; 3-methyl-2, the 3-hexylene glycol; 4-methyl-2, the 3-hexylene glycol; 5-methyl-2, the 3-hexylene glycol; 2-methyl-3, the 4-hexylene glycol; 3-methyl-3, the 4-hexylene glycol; 1, the 3-heptanediol; 1, the 4-heptanediol; 1, the 5-heptanediol; And/or 1, the 6-heptanediol;

IV. the ethohexadiol isomer comprises: 2-(2-methyl butyl)-1, ammediol; 2-(1, the 1-dimethyl propyl)-1, ammediol; 2-(1, the 2-dimethyl propyl)-1, ammediol; 2-(1-ethyl propyl)-1, ammediol; 2-(1-methyl butyl)-1, ammediol; 2-(2, the 2-dimethyl propyl)-1, ammediol; 2-(3-methyl butyl)-1, ammediol; 2-butyl-2-methyl isophthalic acid, ammediol; 2-ethyl-2-sec.-propyl-1, ammediol; 2-ethyl-2-propyl group-1, ammediol; 2-methyl-2-(1-methyl-propyl)-1, ammediol; 2-methyl-2-(2-methyl-propyl)-1, ammediol; The 2-tertiary butyl-2-methyl isophthalic acid, ammediol; 2,2-diethyl-1,3 butylene glycol; 2-(1-methyl-propyl)-1,3 butylene glycol; 2-butyl-1,3 butylene glycol; 2-ethyl-2,3-dimethyl-1,3 butylene glycol; 2-(1, the 1-dimethyl ethyl)-1,3 butylene glycol; 2-(2-methyl-propyl)-1,3 butylene glycol; 2-methyl-2-sec.-propyl-1,3 butylene glycol; 2-methyl-2-propyl group-1,3 butylene glycol; 3-methyl-2-sec.-propyl-1,3 butylene glycol; 3-methyl-2-propyl group-1,3 butylene glycol; 2,2-diethyl-1,4-butyleneglycol; 2-methyl-2-propyl group-1, the 4-butyleneglycol; 2-(1-methyl-propyl)-1, the 4-butyleneglycol; 2-ethyl-2,3-dimethyl-1,4-butyleneglycol; 2-ethyl-3,3-dimethyl-1,4-butyleneglycol; 2-(1, the 1-dimethyl ethyl)-1, the 4-butyleneglycol; 2-(2-methyl-propyl)-1, the 4-butyleneglycol; 2-methyl-3-propyl group-1, the 4-butyleneglycol; 3-methyl-2-sec.-propyl-1, the 4-butyleneglycol; 2,2,3-trimethylammonium-1,3-pentanediol; 2,2,4-trimethylammonium-1,3-pentanediol; 2,3,4-trimethylammonium-1,3-pentanediol; 2,4,4-trimethylammonium-1,3-pentanediol; 3,4,4-trimethylammonium-1,3-pentanediol; 2,2,3-trimethylammonium-1,4-pentanediol; 2,2,4-trimethylammonium-1,4-pentanediol; 2,3,3-trimethylammonium-1,4-pentanediol; 2,3,4-trimethylammonium-1,4-pentanediol; 3,3,4-trimethylammonium-1,4-pentanediol; 2,2,3-trimethylammonium-1,5-pentanediol; 2,2,4-trimethylammonium-1,5-pentanediol; 2,3,3-trimethylammonium-1,5-pentanediol; 2,3,4-trimethylammonium-1,5-pentanediol; 2,3,3-trimethylammonium-2,4-pentanediol; 2,3,4-trimethylammonium-2,4-pentanediol; 2-ethyl-2-methyl isophthalic acid, the 3-pentanediol; 2-ethyl-3-methyl isophthalic acid, the 3-pentanediol; 2-ethyl-4-methyl isophthalic acid, the 3-pentanediol; 3-ethyl-2-methyl isophthalic acid, the 3-pentanediol; 2-ethyl-2-methyl isophthalic acid, the 4-pentanediol; 2-ethyl-3-methyl isophthalic acid, the 4-pentanediol; 2-ethyl-4-methyl isophthalic acid, the 4-pentanediol; 3-ethyl-2-methyl isophthalic acid, the 4-pentanediol; 3-ethyl-3-methyl isophthalic acid, the 4-pentanediol; 2-ethyl-2-methyl isophthalic acid, the 5-pentanediol; 2-ethyl-3-methyl isophthalic acid, the 5-pentanediol; 2-ethyl-4-methyl isophthalic acid, the 5-pentanediol; 3-ethyl-3-methyl isophthalic acid, the 5-pentanediol; 3-ethyl-2-methyl-2, the 4-pentanediol; 2-sec.-propyl-1, the 3-pentanediol; 2-propyl group-1, the 3-pentanediol; 2-sec.-propyl-1, the 4-pentanediol; 2-propyl group-1, the 4-pentanediol; 3-sec.-propyl-1, the 4-pentanediol; 2-sec.-propyl-1, the 5-pentanediol; 3-propyl group-2, the 4-pentanediol; 2,2-dimethyl-1,3-hexylene glycol; 2,3-dimethyl-1,3-hexylene glycol; 2,4-dimethyl-1,3-hexylene glycol; 2,5-dimethyl-1,3-hexylene glycol; 3,4-dimethyl-1,3-hexylene glycol; 3,5-dimethyl-1,3-hexylene glycol; 4,4-dimethyl-1,3-hexylene glycol; 4,5-dimethyl-1,3-hexylene glycol; 2,2-dimethyl-1,4-hexylene glycol; 2,3-dimethyl-1,4-hexylene glycol; 2,4-dimethyl-1,4-hexylene glycol; 2,5-dimethyl-1,4-hexylene glycol; 3,3-dimethyl-1,4-hexylene glycol; 3,4-dimethyl-1,4-hexylene glycol; 3,5-dimethyl-1,4-hexylene glycol; 4,5-dimethyl-1,4-hexylene glycol; 5,5-dimethyl-1,4-hexylene glycol; 2,2-dimethyl-1,5-hexylene glycol; 2,3-dimethyl-1,5-hexylene glycol; 2,4-dimethyl-1,5-hexylene glycol; 2,5-dimethyl-1,5-hexylene glycol; 3,3-dimethyl-1,5-hexylene glycol; 3,4-dimethyl-1,5-hexylene glycol; 3,5-dimethyl-1,5-hexylene glycol; 4,5-dimethyl-1,5-hexylene glycol; 2,2-dimethyl-1,6-hexylene glycol; 2,3-dimethyl-1,6-hexylene glycol; 2,4-dimethyl-1,6-hexylene glycol; 2,5-dimethyl-1,6-hexylene glycol; 3,3-dimethyl-1,6-hexylene glycol; 3,4-dimethyl-1,6-hexylene glycol; 2,3-dimethyl-2,4-hexylene glycol; 2,4-dimethyl-2,4-hexylene glycol; 2,5-dimethyl-2,4-hexylene glycol; 3,3-dimethyl-2,4-hexylene glycol; 3,4-dimethyl-2,4-hexylene glycol; 3,5-dimethyl-2,4-hexylene glycol; 4,5-dimethyl-2,4-hexylene glycol; 5,5-dimethyl-2,4-hexylene glycol; 2,3-dimethyl-2,5-hexylene glycol; 2,4-dimethyl-2,5-hexylene glycol; 2,5-dimethyl-2,5-hexylene glycol; 3,3-dimethyl-2,5-hexylene glycol; 3,4-dimethyl-2,5-hexylene glycol; 3,3-dimethyl-2,6-hexylene glycol; 2-ethyl-1, the 3-hexylene glycol; 4-ethyl-1, the 3-hexylene glycol; 2-ethyl-1, the 4-hexylene glycol; 4-ethyl-1, the 4-hexylene glycol; 2-ethyl-1, the 5-hexylene glycol; 3-ethyl-2, the 4-hexylene glycol; 4-ethyl-2, the 4-hexylene glycol; 3-ethyl-2, the 5-hexylene glycol; The 2-methyl isophthalic acid, the 3-heptanediol; The 3-methyl isophthalic acid, the 3-heptanediol; The 4-methyl isophthalic acid, the 3-heptanediol; The 5-methyl isophthalic acid, the 3-heptanediol; The 6-methyl isophthalic acid, the 3-heptanediol; The 2-methyl isophthalic acid, the 4-heptanediol; The 3-methyl isophthalic acid, the 4-heptanediol; The 4-methyl isophthalic acid, the 4-heptanediol; The 5-methyl isophthalic acid, the 4-heptanediol; The 6-methyl isophthalic acid, the 4-heptanediol; The 2-methyl isophthalic acid, the 5-heptanediol; The 3-methyl isophthalic acid, the 5-heptanediol; The 4-methyl isophthalic acid, the 5-heptanediol; The 5-methyl isophthalic acid, the 5-heptanediol; The 6-methyl isophthalic acid, the 5-heptanediol; The 2-methyl isophthalic acid, the 6-heptanediol; The 3-methyl isophthalic acid, the 6-heptanediol; The 4-methyl isophthalic acid, the 6-heptanediol; The 5-methyl isophthalic acid, the 6-heptanediol; The 6-methyl isophthalic acid, the 6-heptanediol; 2-methyl-2, the 4-heptanediol; 3-methyl-2, the 4-heptanediol; 4-methyl-2, the 4-heptanediol; 5-methyl-2, the 4-heptanediol; 6-methyl-2, the 4-heptanediol; 2-methyl-2, the 5-heptanediol; 3-methyl-2, the 5-heptanediol; 4-methyl-2, the 5-heptanediol; 5-methyl-2, the 5-heptanediol; 6-methyl-2, the 5-heptanediol; 2-methyl-2, the 6-heptanediol; 3-methyl-2, the 6-heptanediol; 4-methyl-2, the 6-heptanediol; 3-methyl-3, the 4-heptanediol; 2-methyl-3, the 5-heptanediol; 3-methyl-3, the 5-heptanediol; 4-methyl-3, the 5-heptanediol; 2, the 4-ethohexadiol; 2, the 5-ethohexadiol; 2, the 6-ethohexadiol; 2, the 7-ethohexadiol; 3, the 5-ethohexadiol; And/or 3, the 6-ethohexadiol;

V. nonanediol isomer comprises: 2,3,3, and 4-tetramethyl--2,4-pentanediol; The 3-tertiary butyl-2, the 4-pentanediol; 2,5,5-trimethylammonium-2,4-hexylene glycol; 3,3,4-three bases-2,4-hexylene glycol; 3,3,5-trimethylammonium-2,4-hexylene glycol; 3,5,5-trimethylammonium-2,4-hexylene glycol; 4,5,5-trimethylammonium-2,4-hexylene glycol; 3,3,4-trimethylammonium-2,5-hexylene glycol; And/or 3,3,5-trimethylammonium-2,5-hexylene glycol;

VI. glyceryl ether and/or two (hydroxyalkyl) ether comprises: 3-(n-pentyloxy)-1,2-propylene glycol; 3-(2-pentyloxy)-1, the 2-propylene glycol; 3-(3-pentyloxy)-1, the 2-propylene glycol; 3-(2-methyl-1-butene oxygen base)-1, the 2-propylene glycol; 3-(isopentyloxy)-1, the 2-propylene glycol; 3-(3-methyl-2-butoxy)-1, the 2-propylene glycol; 3-(cyclohexyloxy)-1, the 2-propylene glycol; 3-(1-hexamethylene-1-alkene oxygen base)-1, the 2-propylene glycol; 2-(pentyloxy)-1, ammediol; 2-(2-pentyloxy)-1, ammediol; 2-(3-pentyloxy)-1, ammediol; 2-(2-methyl-1-butene oxygen base)-1, ammediol; 2-(isopentyloxy)-1, ammediol; 2-(3-methyl-2-butoxy)-1, ammediol; 2-(cyclohexyloxy)-1, ammediol; 2-(1-hexamethylene-1-alkene oxygen base)-1, ammediol; 3-(butoxy)-1,2-propylene glycol, triethoxy thing; 3-(butoxy)-1,2-propylene glycol, tetraethoxy thing; 3-(butoxy)-1,2-propylene glycol, five ethoxylates; 3-(butoxy)-1,2-propylene glycol, six ethoxylates; 3-(butoxy)-1,2-propylene glycol, seven ethoxylates; 3-(butoxy)-1,2-propylene glycol, eight ethoxylates; 3-(butoxy)-1,2-propylene glycol, nine ethoxylates; 3-(butoxy)-1,2-propylene glycol, a propoxylated glycerine; 3-(butoxy)-1,2-propylene glycol, dibutoxy thing; 3-(butoxy)-1,2-propylene glycol, three butoxy things; 3-phenoxy group-1, the 2-propylene glycol; 3-benzyloxy-1, the 2-propylene glycol; 3-(2-phenyl ethoxy)-1, the 2-propylene glycol; 3-(1-phenyl-2-propoxy-)-1, the 2-propylene glycol; 2-phenoxy group-1, ammediol; 2-(a hydroxy toluene oxygen base)-1, ammediol; 2-(to hydroxy toluene oxygen base)-1, ammediol; Benzyloxy-1, ammediol; 2-(2-phenyl ethoxy)-1, ammediol; 2-(1-phenyl ethoxy)-1, ammediol; Two (2-hydroxyl butyl) ether; And/or two (2-hydroxycyclopent base) ether;

VII. saturated and undersaturated alicyclic diol and derivative thereof comprise:

(a) saturated dibasic alcohol and derivative thereof comprise: 1-sec.-propyl-1,2-cyclobutanediol; 3-ethyl-4-methyl isophthalic acid, the 2-cyclobutanediol; 3-propyl group-1, the 2-cyclobutanediol; 3-sec.-propyl-1, the 2-cyclobutanediol; 1-ethyl-1,2-encircles pentanediol; 1,2-dimethyl-1,2-encircles pentanediol; 1,4-dimethyl-1,2-encircles pentanediol; 2,4,5-trimethylammonium-1,3-encircles pentanediol; 3,3-dimethyl-1,2-encircles pentanediol; 3,4-dimethyl-1,2-encircles pentanediol; 3,5-dimethyl-1,2-encircles pentanediol; 3-ethyl-1,2-encircles pentanediol; 4,4-dimethyl-1,2-encircles pentanediol; 4-ethyl-1,2-encircles pentanediol; 1,1-two (methylol) hexanaphthene; 1,2-two (methylol) hexanaphthene; 1,2-dimethyl-1,3-cyclohexanediol; 1,3-two (methylol) hexanaphthene; 1,3-dimethyl-1,3-cyclohexanediol; 1,6-dimethyl-1,3-cyclohexanediol; 1-hydroxyl hexanaphthene ethanol; 1-hydroxyl cyclohexane methanol; 1-ethyl-1, the 3-cyclohexanediol; The 1-methyl isophthalic acid, the 2-cyclohexanediol; 2,2-dimethyl-1,3-cyclohexanediol; 2,3-dimethyl-1,4-cyclohexanediol; 2,4-dimethyl-1,3-cyclohexanediol; 2,5-dimethyl-1,3-cyclohexanediol; 2,6-dimethyl-1,4-cyclohexanediol; 2-ethyl-1, the 3-cyclohexanediol; 2-hydroxyl hexanaphthene ethanol; 2-hydroxyethyl-1-hexalin; 3-hydroxyethyl-1-hexalin; 3-hydroxyl hexanaphthene ethanol; 3-methylol hexalin; The 3-methyl isophthalic acid, the 2-cyclohexanediol; 4,4-dimethyl-1,3-cyclohexanediol; 4,5-dimethyl-1,3-cyclohexanediol; 4,6-dimethyl-1,3-cyclohexanediol; 4-ethyl-1, the 3-cyclohexanediol; 4-hydroxyethyl-1-hexalin; The 4-methyl isophthalic acid, the 2-cyclohexanediol; 5,5-dimethyl-1,3-cyclohexanediol; 5-ethyl-1, the 3-cyclohexanediol; 1,2-encircles heptanediol; The 2-methyl isophthalic acid, 3-encircles heptanediol; The 2-methyl isophthalic acid, 4-encircles heptanediol; The 4-methyl isophthalic acid, 3-encircles heptanediol; The 5-methyl isophthalic acid, 3-encircles heptanediol; The 5-methyl isophthalic acid, 4-encircles heptanediol; The 6-methyl isophthalic acid, 4-encircles heptanediol; 1,3-encircles ethohexadiol; 1,4-encircles ethohexadiol; 1,5-encircles ethohexadiol; 1,2-cyclohexanediol, diethoxy thing; 1,2-cyclohexanediol, triethoxy thing; 1,2-cyclohexanediol, tetraethoxy thing; 1,2-cyclohexanediol, five ethoxylates; 1,2-cyclohexanediol, six ethoxylates; 1,2-cyclohexanediol, seven ethoxylates; 1,2-cyclohexanediol, eight ethoxylates; 1,2-cyclohexanediol, nine ethoxylates; 1,2-cyclohexanediol, a propoxylated glycerine; 1,2-cyclohexanediol, a butoxy thing; 1,2-cyclohexanediol, dibutoxy thing; And/or 1,2-cyclohexanediol, three butoxy things; With

(b) undersaturated alicyclic diol comprises: 1-vinyl-2-ethyl-1,2-cyclobutanediol; 1,2,3,4-tetramethyl--3-cyclobutene-1,2-glycol; 3,4-diethyl-3-cyclobutene-1,2-glycol; 3-(1, the 1-dimethyl ethyl)-3-cyclobutene-1, the 2-glycol; 3-butyl-3-cyclobutene-1, the 2-glycol; 1,2-dimethyl-4-methylene radical-1,2-encircles pentanediol; 1-ethyl-3-methylene radical-1,2-encircles pentanediol; 4-(1-propenyl)-1,2-encircles pentanediol; 1-ethyl-3-methyl-3-cyclopentenes-1, the 2-glycol; 1-vinyl-1, the 2-cyclohexanediol; 1-methyl-3-methylene radical-1, the 2-cyclohexanediol; 1-methyl-4-methylene radical-1, the 2-cyclohexanediol; 3-vinyl-1, the 2-cyclohexanediol; 4-vinyl-1, the 2-cyclohexanediol; 2,6-dimethyl-3-tetrahydrobenzene-1,2-glycol; 6,6-dimethyl-3-tetrahydrobenzene-1,2-glycol; 3,6-dimethyl-4-tetrahydrobenzene-1,2-glycol; 4,5-dimethyl-4-tetrahydrobenzene-1,2-glycol; 3-cyclooctene-1, the 2-glycol; 4-cyclooctene-1, the 2-glycol; And/or 5-cyclooctene-1, the 2-glycol;

VIII.C _3-7The alkoxy derivative of glycol comprises:

(1) .1,2-propylene glycol (C3) 2 (Me-E _1-4); 1,2-propylene glycol (C3) PO ₄The 2-methyl isophthalic acid, 2-propylene glycol (C4) (Me-E _4-10); The 2-methyl isophthalic acid, 2-propylene glycol (C4) 2 (Me-E ₁); The 2-methyl isophthalic acid, 2-propylene glycol (C4) PO ₃The 2-methyl isophthalic acid, 2-propylene glycol (C4) BO ₁1, ammediol (C3) 2 (Me-E _6-8); 1, ammediol (C3) PO _5-62,2-diethyl-1, ammediol (C7) E _1-72,2-diethyl-1, ammediol (C7) PO ₁2,2-diethyl-1, ammediol (C7) n-BO _1-22 (C5) 2 (MeE _1-2); 2 (C5) PO _3-42-(1-methyl-propyl)-1, ammediol (C7) E _1-72-(1-methyl-propyl)-1, ammediol (C7) PO ₁2-(1-methyl-propyl)-1, ammediol (C7) n-BO _1-22-(2-methyl-propyl)-1, ammediol (C7) E _1-72-(2-methyl-propyl)-1, ammediol (C7) PO ₁2-(2-methyl-propyl)-1, ammediol (C7) n-BO _1-22-ethyl-1, ammediol (C5) (MeE _6-10); 2-ethyl-1, ammediol (C5) 2 (MeE ₁); 2-ethyl-1, ammediol (C5) PO ₃2-ethyl-2-methyl isophthalic acid, ammediol (C6) (Me E _1-6); 2-ethyl-2-methyl isophthalic acid, ammediol (C6) PO ₂2-ethyl-2-methyl isophthalic acid, ammediol (C6) BO ₁2-sec.-propyl-1, ammediol (C6) (MeE _1-6); 2-sec.-propyl-1, ammediol (C6) PO ₂2-sec.-propyl-1, ammediol (C6) BO ₁The 2-methyl isophthalic acid, ammediol (C4) 2 (MeE ₂-5); The 2-methyl isophthalic acid, ammediol (C4) PO _4-5The 2-methyl isophthalic acid, ammediol (C4) BO ₂2-methyl-2-sec.-propyl-1, ammediol (C7) E _2-92-methyl-2-sec.-propyl-1, ammediol (C7) PO ₁2-methyl-2-sec.-propyl-1, ammediol (C7) n-BO _1-32-methyl-2-propyl group-1, ammediol (C7) E _1-72-methyl-2-propyl group-1, ammediol (C7) PO ₁2-methyl-2-propyl group-1, ammediol (C7) n-BO _1-22-propyl group-1, ammediol (C6) (MeE _1-4); 2-propyl group-1, ammediol (C6) PO ₂2-propyl group-1, ammediol (C6) BO ₁

(2) .1,2-butyleneglycol (C4) (MeE _2-8); 1,2-butyleneglycol (C4) PO _2-31,2-butyleneglycol (C4) BO ₁2,3-dimethyl-1,2-butyleneglycol (C6) E _1-62,3-dimethyl-1,2-butyleneglycol (C6) n-BO _1-22-ethyl-1,2-butyleneglycol (C6) E _1-32-ethyl-1,2-butyleneglycol (C6) n-BO ₁The 2-methyl isophthalic acid, 2-butyleneglycol (C5) (MeE _1-2); The 2-methyl isophthalic acid, 2-butyleneglycol (C5) PO ₁3,3-dimethyl-1,2-butyleneglycol (C6) E _1-63,3-dimethyl-1,2-butyleneglycol (C6) n-BO _1-2The 3-methyl isophthalic acid, 2-butyleneglycol (C5) (MeE _1-2); The 3-methyl isophthalic acid, 2-butyleneglycol (C5) PO ₁1,3 butylene glycol (C4) 2 (MeE _3-6); 1,3 butylene glycol (C4) PO ₅1,3 butylene glycol (C4) BO ₂2,2,3-trimethylammonium-1,3 butylene glycol (C7) (MeE _1-3); 2,2,3-trimethylammonium-1,3 butylene glycol (C7) PO _1-22,2-dimethyl-1,3 butylene glycol (C6) (MeE _3-8); 2,2-dimethyl-1,3 butylene glycol (C6) PO ₃2,3-dimethyl-1,3 butylene glycol (C6) (MeE _3-8); 2,3-dimethyl-1,3 butylene glycol (C6) PO ₃2-ethyl-1,3 butylene glycol (C6) (MeE _1-6); 2-ethyl-1,3 butylene glycol (C6) PO _2-32-ethyl-1,3 butylene glycol (C6) BO ₁2-ethyl-2-methyl isophthalic acid, 3-butyleneglycol (C7) (MeE ₁); 2-ethyl-2-methyl isophthalic acid, 3-butyleneglycol (C7) PO ₁2-ethyl-2-methyl isophthalic acid, 3-butyleneglycol (C7) n-BO _2-42-ethyl-3-methyl isophthalic acid, 3-butyleneglycol (C7) (MeE ₁); 2-ethyl-3-methyl isophthalic acid, 3-butyleneglycol (C7) PO ₁2-ethyl-3-methyl isophthalic acid, 3-butyleneglycol (C7) n-BO _2-42-sec.-propyl-1,3 butylene glycol (C7) (MeE ₁); 2-sec.-propyl-1,3 butylene glycol (C7) PO ₁2-sec.-propyl-1,3 butylene glycol (C7) n-BO _2-4The 2-methyl isophthalic acid, 3-butyleneglycol (C5) 2 (MeE _1-3); The 2-methyl isophthalic acid, 3-butyleneglycol (C5) PO ₄2-propyl group-1,3 butylene glycol (C7) E _2-92-propyl group-1,3 butylene glycol (C7) PO ₁2-propyl group-1,3 butylene glycol (C7) n-BO _1-3The 3-methyl isophthalic acid, 3-butyleneglycol (C5) 2 (MeE _1-3); The 3-methyl isophthalic acid, 3-butyleneglycol (C5) PO ₄1,4-butyleneglycol (C4) 2 (MeE _2-4); 1,4-butyleneglycol (C4) PO _4-51,4-butyleneglycol (C4) BO ₂2,2,3-trimethylammonium-1,4-butyleneglycol (C7) E _2-92,2,3-trimethylammonium-1,4-butyleneglycol (C7) PO ₁2,2,3-trimethylammonium-1,4-butyleneglycol (C7) n-BO _1-32,2-dimethyl-1,4-butyleneglycol (C6) (MeE _1-6); 2,2-dimethyl-1,4-butyleneglycol (C6) PO ₂2,2-dimethyl-1,4-butyleneglycol (C6) BO ₁2,3-dimethyl-1,4-butyleneglycol (C6) (MeE _1-6); 2,3-dimethyl-1,4-butyleneglycol (C6) PO ₂2,3-dimethyl-1,4-butyleneglycol (C6) BO ₁2-ethyl-1,4-butyleneglycol (C6) (MeE _1-4); 2-ethyl-1,4-butyleneglycol (C6) PO ₂2-ethyl-1,4-butyleneglycol (C6) BO ₁2-ethyl-2-methyl isophthalic acid, 4-butyleneglycol (C7) E _1-72-ethyl-2-methyl isophthalic acid, 4-butyleneglycol (C7) PO ₁2-ethyl-2-methyl isophthalic acid, 4-butyleneglycol (C7) n-BO _1-22-ethyl-3-methyl isophthalic acid, 4-butyleneglycol (C7) E _1-72-ethyl-3-methyl isophthalic acid, 4-butyleneglycol (C7) PO ₁2-ethyl-3-methyl isophthalic acid, 4-butyleneglycol (C7) n-BO _1-22-sec.-propyl-1,4-butyleneglycol (C7) E _1-72-sec.-propyl-1,4-butyleneglycol (C7) PO ₁Different third methyl isophthalic acid of 2-, 4-butyleneglycol (C7) n-BO _1-2The 2-methyl isophthalic acid, 4-butyleneglycol (C5) (MeE _6-10); The 2-methyl isophthalic acid, 4-butyleneglycol (C5) 2 (MeE ₁); The 2-methyl isophthalic acid, 4-butyleneglycol (C5) PO ₃The 2-methyl isophthalic acid, 4-butyleneglycol (C5) BO ₁2-propyl group-1,4-butyleneglycol (C7) E _1-52-propyl group-1,4-butyleneglycol (C7) n-BO _1-23 ethyls-1-methyl isophthalic acid, 4-butyleneglycol (C7) E _2-93-ethyl-1-methyl isophthalic acid, 4-butyleneglycol (C7) PO ₁3-ethyl-1-methyl isophthalic acid, 4-butyleneglycol (C7) n-BO _1-32,3-butyleneglycol (C4) (Me E _6-10); 2,3-butyleneglycol (C4) 2 (MeE ₁); 2,3-butyleneglycol (C4) PO _3-42,3-butyleneglycol (C4) BO ₁2,3-dimethyl-2,3-butyleneglycol (C6) E _3-92,3-dimethyl-2,3-butyleneglycol (C6) PO ₁2,3-dimethyl-2,3-butyleneglycol (C6) BO _1-32-methyl-2,3-butyleneglycol (C5) (MeE _1-5); 2-methyl-2,3-butyleneglycol (C5) PO ₂2-methyl-2,3-butyleneglycol (C5) BO ₁

(3) .1,2-Wu glycol (C5) E_3-10 1,2-Wu glycol (C5) PO₁ 1,2-Wu glycol (C5) n-BO_2-3 The 2-methyl isophthalic acid, 2-Wu glycol (C6) E_1-3 The 2-methyl isophthalic acid, 2-Wu glycol (C6) n-BO₁ The 2-methyl isophthalic acid, 2-Wu glycol (C6) BO₁ The 3-methyl isophthalic acid, 2-Wu glycol (C6) E_1-3 The 3-methyl isophthalic acid, 2-Wu glycol (C6) n-BO₁ The 4-methyl isophthalic acid, 2-Wu glycol (C6) E_1-3 The 4-methyl isophthalic acid, 2-Wu glycol (C6) n-BO₁ 1,3-Wu glycol (C5), 2 (Me-E_1-2); 1,3-Wu glycol (C5) PO_3-4 2,2-dimethyl-1,3-Wu glycol (C7) (Me-E₁); 2,2-dimethyl-1,3-Wu glycol (C7) PO₁ 2,2-dimethyl-1,3-Wu glycol (C7) n-BO_2-4 2,3-dimethyl-1,3-Wu glycol (C7) (Me-E₁); 2,3-dimethyl-1,3-Wu glycol (C7) PO₁ 2,3-dimethyl-1,3-Wu glycol (C7) n-BO_2-4 2,4-dimethyl-1,3-Wu glycol (C7) (Me-E₁); 2,4-dimethyl-1,3-Wu glycol (C7) PO₁ 2,4-dimethyl-1,3-Wu glycol (C7) n-BO_2-4 2-Yi base-1,3-Wu glycol (C7) E_2-9 2-Yi base-1,3-Wu glycol (C7) PO₁ 2-Yi base-1,3-Wu glycol (C7) n-BO_1-3 The 2-methyl isophthalic acid, 3-Wu glycol (C6) 2 (Me-E_1-6); The 2-methyl isophthalic acid, 3-Wu glycol (C6) PO_2-3 The 2-methyl isophthalic acid, 3-Wu glycol (C6) BO₁ 3,4-dimethyl-1,3-Wu glycol (C7) (Me-E₁); 3,4-dimethyl-1,3-Wu glycol (C7) PO₁ 3,4-dimethyl-1,3-Wu glycol (C7) n-BO_2-4 The 3-methyl isophthalic acid, 3-Wu glycol (C6) 2 (Me-E_1-6); The 3-methyl isophthalic acid, 3-Wu glycol (C6) PO_2-3 The 3-methyl isophthalic acid, 3-Wu glycol (C6) BO₁ 4,4-dimethyl-1,3-Wu glycol (C7) (Me-E₁); 4,4-dimethyl-1,3-Wu glycol (C7) PO₁ 4,4-dimethyl-1,3-Wu glycol (C7) n-BO_2-4 The 4-methyl isophthalic acid, 3-Wu glycol (C6) 2 (Me-E_1-6); The 4-methyl isophthalic acid, 3-Wu glycol (C6) PO_2-3 The 4-methyl isophthalic acid, 3-Wu glycol (C6) BO₁ 1,4-Wu glycol (C5), 2 (Me-E_1-2); 1,4-Wu glycol (C5) PO_3-4 2,2-dimethyl-1,4-Wu glycol (C7) (Me-E₁); 2,2-dimethyl-1,4-Wu glycol (C7) PO₁ 2,2-dimethyl-1,4-Wu glycol (C7) n-BO_2-4 2,3-dimethyl-1,4-Wu glycol (C7) (Me-E₁); 2,3-dimethyl-1,4-Wu glycol (C7) PO₁ 2,3-dimethyl-1,4-Wu glycol (C7) n-BO_2-4 2,4-dimethyl-1,4-Wu glycol (C7) (Me-E₁); 2,4-dimethyl-1,4-Wu glycol (C7) PO₁ 2,4-dimethyl-1,4-Wu glycol (C7) n-BO_2-4 The 2-methyl isophthalic acid, 4-Wu glycol (C6) (Me-E_1-6); The 2-methyl isophthalic acid, 4-Wu glycol (C6) PO_2-3 The 2-methyl isophthalic acid, 4-Wu glycol (C6) BO₁ 3,3-dimethyl-1,4-Wu glycol (C7) (Me-E₁); 3,3-dimethyl-1,4-Wu glycol (C7) PO₁ 3,3-dimethyl-1,4-Wu glycol (C7) n-BO_2-4 3,4-dimethyl-1,4-Wu glycol (C7) (Me-E₁); 3,4-dimethyl-1,4-Wu glycol (C7) PO₁ 3,4-dimethyl-1,4-Wu glycol (C7) n-BO_2-4 The 3-methyl isophthalic acid, 4-Wu glycol (C6) 2 (Me-E_1-6); The 3-methyl isophthalic acid, 4-Wu glycol (C6) PO_2-3 3-methyl-1,4-Wu glycol (C6) BO₁ The 4-methyl isophthalic acid, 4-Wu glycol (C6) 2 (Me-E_1-6); The 4-methyl isophthalic acid, 4-Wu glycol (C6) PO_2-3 The 4-methyl isophthalic acid, 4-Wu glycol (C6) BO₁ 1,5-Wu glycol (C5) (Me-E_4-10); 1,5-Wu glycol (C5), 2 (Me-E₁); 1,5-Wu glycol (C5) PO₃ 2,2-dimethyl-1,5-Wu glycol (C7) E_1-7 2,2-dimethyl-1,5-Wu glycol (C7) PO₁ 2,2-dimethyl-1,5-Wu glycol (C7) n-BO_1-2 2,3-dimethyl-1,5-Wu glycol (C7) E_1-7 2,3-dimethyl-1,5-Wu glycol (C7) PO₁ 2,3-dimethyl-1,5-Wu glycol (C7) n-BO_1-2 2,4-dimethyl-1,5-Wu glycol (C7) E_1-7 2,4-dimethyl-1,5-Wu glycol (C7) PO₁ 2,4-dimethyl-1,5-Wu glycol (C7) n-BO_1-2 2-Yi base-1,5-Wu glycol (C7) E_1-5 2-Yi base-1,5-Wu glycol (C7) n-BO_1-2 The 2-methyl isophthalic acid, 5-Wu glycol (C6) (Me-E_1-4); The 2-methyl isophthalic acid, 5-Wu glycol (C6) PO₂ 3,3-dimethyl-1,5-Wu glycol (C7) E_1-7 3,3-dimethyl-1,5-Wu glycol (C7) PO₁ 3,3-dimethyl-1,5-Wu glycol (C7) n-BO_1-2 The 3-methyl isophthalic acid, 5-Wu glycol (C6) (Me-E_1-4); The 3-methyl isophthalic acid, 5-Wu glycol (C6) PO₂ 2,3-Wu glycol (C5) (Me-E_1-3); 2,3-Wu glycol (C5) PO₂ 2-methyl-2,3-Wu glycol (C6) E_1-7 2-methyl-2,3-Wu glycol (C6) PO₁ 2-methyl-2,3-Wu glycol (C6) n-BO_1-2 3-methyl-2,3-Wu glycol (C6) E_1-7 3-methyl-2,3-Wu glycol (C6) PO₁ 3-methyl-2,3-Wu glycol (C6) n-BO_1-2 4-methyl-2,3-Wu glycol (C6) E_1-7 4-methyl-2,3-Wu glycol (C6) PO₁ 4-methyl-2,3-Wu glycol (C6) n-BO_1-2 2,4-Wu glycol (C5), 2 (Me-E_1-4); 2,4-Wu glycol (C5) PO₄ 2,3-dimethyl-2,4-Wu glycol (C7) (Me-E_1-4); 2,3-dimethyl-2,4-Wu glycol (C7) PO₂ 2,4-dimethyl-2,4-Wu glycol (C7) (Me-E_1-4); 2,4-dimethyl-2,4-Wu glycol (C7) PO₂ 2-methyl-2,4-Wu glycol (C7) (Me-E_5-10); 2-methyl-2,4-Wu glycol (C7) PO₃ 3,3-dimethyl-2,4-Wu glycol (C7) (Me-E_1-4); 3,3-dimethyl-2,4-Wu glycol (C7) PO₂ 3-methyl-2,4-Wu glycol (C6) (Me-E_5-10); 3-methyl-2,4-Wu glycol (C6) PO₃；

(4) .1,3-hexylene glycol (C6) (Me-E _1-5); 1,3-hexylene glycol (C6) PO ₂1,3-hexylene glycol (C6) BO ₁The 2-methyl isophthalic acid, 3-hexylene glycol (C7) E _2-9The 2-methyl isophthalic acid, 3-hexylene glycol (C7) PO ₁The 2-methyl isophthalic acid, 3-hexylene glycol (C7) n-BO _1-3The 2-methyl isophthalic acid, 3-hexylene glycol (C7)-BO ₁The 3-methyl isophthalic acid, 3-hexylene glycol (C7) E _2-9The 3-methyl isophthalic acid, 3-hexylene glycol (C7) PO ₁The 3-methyl isophthalic acid, 3-hexylene glycol (C7) n-BO _1-3The 4-methyl isophthalic acid, 3-hexylene glycol (C7) E _2-9The 4-methyl isophthalic acid, 3-hexylene glycol (C7) PO ₁The 4-methyl isophthalic acid, 3-hexylene glycol (C7) n-BO _1-3The 5-methyl isophthalic acid, 3-hexylene glycol (C7) E _2-9The 5-methyl isophthalic acid, 3-hexylene glycol (C7) PO ₁The 5-methyl isophthalic acid, 3-hexylene glycol (C7) n-BO _1-31,4-hexylene glycol (C6) (Me-E _1-5); 1,4-hexylene glycol (C6) PO ₂1,4-hexylene glycol (C6) BO ₁The 2-methyl isophthalic acid, 4-hexylene glycol (C7) E _2-9The 2-methyl isophthalic acid, 4-hexylene glycol (C7) PO ₁The 2-methyl isophthalic acid, 4-hexylene glycol (C7) n-BO _1-3The 3-methyl isophthalic acid, 4-hexylene glycol (C7) E _2-9The 3-methyl isophthalic acid, 4-hexylene glycol (C7) PO ₁The 3-methyl isophthalic acid, 4-hexylene glycol (C7) n-BO _1-3The 4-methyl isophthalic acid, 4-hexylene glycol (C7) E _2-9The 4-methyl isophthalic acid, 4-hexylene glycol (C7) PO ₁The 4-methyl isophthalic acid, 4-hexylene glycol (C7) n-BO _1-3The 5-methyl isophthalic acid, 4-hexylene glycol (C7) E _2-9The 5-methyl isophthalic acid, 4-hexylene glycol (C7) PO ₁The 5-methyl isophthalic acid, 4-hexylene glycol (C7) n-BO _1-31,5-hexylene glycol (C6) (Me-E _1-5); 1,5-hexylene glycol (C6) PO ₂1,5-hexylene glycol (C6) BO ₁The 2-methyl isophthalic acid, 5-hexylene glycol (C7) E _2-9The 2-methyl isophthalic acid, 5-hexylene glycol (C7) PO ₁The 2-methyl isophthalic acid, 5-hexylene glycol (C7) n-BO _1-3The 3-methyl isophthalic acid, 5-hexylene glycol (C7) E _2-9The 3-methyl isophthalic acid, 5-hexylene glycol (C7) PO ₁The 3-methyl isophthalic acid, 5-hexylene glycol (C7) n-BO _1-3The 4-methyl isophthalic acid, 5-hexylene glycol (C7) E _2-9The 4-methyl isophthalic acid, 5-hexylene glycol (C7) PO ₁The 4-methyl isophthalic acid, 5-hexylene glycol (C7) n-BO _1-3The 5-methyl isophthalic acid, 5-hexylene glycol (C7) E _2-9The 5-methyl isophthalic acid, 5-hexylene glycol (C7) PO ₁The 5-methyl isophthalic acid, 5-hexylene glycol (C7) n-BO _1-31,6-hexylene glycol (C6) (Me-E _1-2); 1,6-hexylene glycol (C6) PO _1-21,6-hexylene glycol (C6) n-BO ₄The 2-methyl isophthalic acid, 6-hexylene glycol (C7) E _1-5The 2-methyl isophthalic acid, 6-hexylene glycol (C7) n-BO ₁The 3-methyl isophthalic acid, 6-hexylene glycol (C7) E _1-5The 3-methyl isophthalic acid, 6-hexylene glycol (C7) n-BO ₁2,3-hexylene glycol (C6) E _1-52,3-hexylene glycol (C6) n-BO ₁2,3-hexylene glycol (C6) BO ₁2,4-hexylene glycol (C6) (Me-E _3-8); 2,4-hexylene glycol (C6) PO ₃2-methyl-2,4-hexylene glycol (C7) (MeE _1-2); 2-methyl-2,4-hexylene glycol (C7) PO _1-23-methyl-2,4-hexylene glycol (C7) (Me-E _1-2); 3-methyl-2,4-hexylene glycol (C7) PO _1-24-methyl-2,4-hexylene glycol (C7) (Me-E _1-2); 4-methyl-2,4-hexylene glycol (C7) PO _1-25-methyl-2,4-hexylene glycol (C7) (Me-E _1-2); 5-methyl-2,4-hexylene glycol (C7) PO _1-22,5-hexylene glycol (C6) (Me-E _3-8); 2,5-hexylene glycol (C6) PO ₃2-methyl-2,5-hexylene glycol (C7) (Me-E _1-2); 2-methyl-2,5-hexylene glycol (C7) PO _1-23-methyl-2,5-hexylene glycol (C7) (Me-E _1-2); 3-methyl-2,5-hexylene glycol (C7) PO _1-23,4-hexylene glycol (C6) E _1-53,4-hexylene glycol (C6) n-BO ₁3,4-hexylene glycol (C6) BO ₁

(5) .1,3-heptanediol (C7) E _1-71,3-heptanediol (C7) PO ₁1,3-heptanediol (C7) n-BO _1-21,4-heptanediol (C7) E _1-71,4-heptanediol (C7) PO ₁1,4-heptanediol (C7) n-BO _1-21,5-heptanediol (C7) E _1-71,5-heptanediol (C7) PO ₁1,5-heptanediol (C7) n-BO _1-21,6-heptanediol (C7) E _1-71,6-heptanediol (C7) PO ₁1,6-heptanediol (C7) n-BO _1-21,7-heptanediol (C7) E _1-21,7-heptanediol (C7) n-BO ₂2,4-heptanediol (C7) E _3-102,4-heptanediol (C7) (Me-E ₁); 2,4-heptanediol (C7) PO ₁2,4-heptanediol (C7) n-BO ₃2,5-heptanediol (C7) E _3-102,5-heptanediol (C7) (Me-E ₁); 2,5-heptanediol (C7) PO ₁2,5-heptanediol (C7) n-BO ₃2,6-heptanediol (C7) E _3-102,6-heptanediol (C7) (Me-E ₁); 2,6-heptanediol (C7) PO ₁2,6-heptanediol (C7) n-BO ₃3,5-heptanediol (C7) E _3-103,5-heptanediol (C7) (Me-E ₁); 3,5-heptanediol (C7) PO ₁3,5-heptanediol (C7) n-BO ₃

(6) .3-methyl-2-sec.-propyl-1,3 butylene glycol (C8) PO ₁2,3,3-trimethylammonium-2,4-pentanediol (C8) PO ₁2,2-diethyl-1,3 butylene glycol (C8) E _2-52,3-dimethyl-2,4-hexylene glycol (C8) E _2-52,4-dimethyl-2,4-hexylene glycol (C8) E _2-52,5-dimethyl-2,4-hexylene glycol (C8) E _2-53,3-dimethyl-2,4-hexylene glycol (C8) E _2-53,4-dimethyl-2,4-hexylene glycol (C8) E _2-53,5-dimethyl-2,4-hexylene glycol (C8) E _2-54,5-dimethyl-2,4-hexylene glycol (C8) E _2-55,5-dimethyl-2,4-hexylene glycol (C8) E _2-52,3-dimethyl-2,5-hexylene glycol (C8) E _2-52,4-dimethyl-2,5-hexylene glycol (C8) E _2-52,5-dimethyl-2,5-hexylene glycol (C8) E _2-53,3-dimethyl-2,5-hexylene glycol (C8) E _2-53,4-dimethyl-2,5-hexylene glycol (C8) E _2-53-methyl-3,5-heptanediol (C8) E _2-52,2-diethyl-1,3 butylene glycol (C8) n-BO _1-22,3-dimethyl-2,4-hexylene glycol (C8) n-BO _1-22,4-dimethyl-2,4-hexylene glycol (C8) n-BO _1-22,5-dimethyl-2,4-hexylene glycol (C8) n-BO _1-23,3-dimethyl-2,4-hexylene glycol (C8) n-BO _1-23,4-dimethyl-2,4-hexylene glycol (C8) n-BO _1-23,5-dimethyl-2,4-hexylene glycol (C8) n-BO _1-24,5-dimethyl-2,4-hexylene glycol (C8) n-BO _1-25,5-dimethyl-2,4-hexylene glycol (C8) n-BO _1-22,3-dimethyl-2,5-hexylene glycol (C8) n-BO _1-22,4-dimethyl-2,5-hexylene glycol (C8) n-BO _1-22,5-dimethyl-2,5-hexylene glycol (C8) n-BO _1-23,3-dimethyl-2,5-hexylene glycol (C8) n-BO _1-23,4-dimethyl-2,5-hexylene glycol (C8) n-BO _1-23-methyl-3,5-heptanediol (C8) n-BO _1-22-(1, the 2-dimethyl propyl)-1, ammediol (C8) n-BO _1-22-ethyl-2,3-dimethyl-1,3 butylene glycol (C8) n-BO ₁2-methyl-2-sec.-propyl-1,3 butylene glycol (C8) n-BO ₁3-methyl-2-sec.-propyl-1,4-butyleneglycol (C8) n-BO ₁2,2,3-trimethylammonium-1,3-pentanediol (C8) n-BO ₁2,2,4-trimethylammonium-1,3-pentanediol (C8) n-BO ₁2,4,4-trimethylammonium-1,3-pentanediol (C8) n-BO ₁3,4,4-trimethylammonium-1,3-pentanediol (C8) n-BO ₁2,2,3-trimethylammonium-1,4-pentanediol (C8) n-BO ₁2,2,4-trimethylammonium-1,4-pentanediol (C8) n-BO ₁2,3,3-trimethylammonium-1,4-pentanediol (C8) n-BO ₁2,3,4-trimethylammonium-1,4-pentanediol (C8) n-BO ₁3,3,4-trimethylammonium-1,4-pentanediol (C8) n-BO ₁2,3,4-trimethylammonium-2,4-pentanediol (C8) n-BO ₁4-ethyl-2,4-hexylene glycol (C8) n-BO ₁2-methyl-2,4-heptanediol (C8) n-BO ₁3-methyl-2,4-heptanediol (C8) n-BO ₁4-methyl-2,4-heptanediol (C8) n-BO ₁5-methyl-2,4-heptanediol (C8) n-BO ₁6-methyl-2,4-heptanediol (C8) n-BO ₁2-methyl-2,5-heptanediol (C8) n-BO ₁3-methyl-2,5-heptanediol (C8) n-BO ₁4-methyl-2,5-heptanediol (C8) n-BO ₁5-methyl-2,5-heptanediol (C8) n-BO ₁6-methyl-2,5-heptanediol (C8) n-BO ₁2-methyl-2,6-heptanediol (C8) n-BO ₁3-methyl-2,6-heptanediol (C8) n-BO ₁4-methyl-2,6-heptanediol (C8) n-BO ₁2-methyl-3,5-heptanediol (C8) n-BO ₁2-(1, the 2-dimethyl propyl)-1, ammediol (C8) E _1-32-ethyl-2,3-dimethyl-1,3 butylene glycol (C8) E _1-32-methyl-2-sec.-propyl-1,3 butylene glycol (C8) E _1-33-methyl-2-sec.-propyl-1,4-butyleneglycol (C8) E _1-32,2,3-trimethylammonium-1,3-pentanediol (C8) E _1-32,2,4-trimethylammonium-1,3-pentanediol (C8) E _1-32,4,4-trimethylammonium-1,3-pentanediol (C8) E _1-33,4,4-trimethylammonium-1,3-pentanediol (C8) E _1-32,2,3-trimethylammonium-1,4-pentanediol (C8) E _1-32,2,4-trimethylammonium-1,4-pentanediol (C8) E _1-32,3,3-trimethylammonium-1,4-pentanediol (C8) E _1-32,3,4-trimethylammonium-1,4-pentanediol (C8) E _1-33,3,4-trimethylammonium-1,4-pentanediol (C8) E _1-32,3,4-trimethylammonium-2,4-pentanediol (C8) E _1-34-ethyl-2,4-hexylene glycol (C8) E _1-32-methyl-2,4-heptanediol (C8) E _1-33-methyl-2,4-heptanediol (C8) E _1-34-methyl-2,4-heptanediol (C8) E _1-35-methyl-2,4-heptanediol (C8) E _1-36-methyl-2,4-heptanediol (C8) E _1-32-methyl-2,5-heptanediol (C8) E _1-33-methyl-2,5-heptanediol (C8) E _1-34-methyl-2,5-heptanediol (C8) E _1-35-methyl-2,5-heptanediol (C8) E _1-36-methyl-2,5-heptanediol (C8) E _1-32-methyl-2,6-heptanediol (C8) E _1-33-methyl-2,6-heptanediol (C8) E _1-34-methyl-2,6-heptanediol (C8) E _1-3And/or 2-methyl-3,5-heptanediol (C8) E _1-3And

(7). their mixture.

IX. aromatic diol comprises: 1-phenyl-1; 1-phenyl-1, the 2-propylene glycol; 2-phenyl-1, the 2-propylene glycol; 3-phenyl-1, the 2-propylene glycol; 1-(3-aminomethyl phenyl)-1, ammediol; 1-(4-aminomethyl phenyl)-1, ammediol; 2-methyl isophthalic acid-phenyl-1, ammediol; 1-phenyl-1,3 butylene glycol; 3-phenyl-1,3 butylene glycol; 1-phenyl-1, the 4-butyleneglycol; 2-phenyl-1, the 4-butyleneglycol; And/or 1-phenyl-2, the 3-butyleneglycol;

X. the solvent that has the ClogP value of about 0.15-about 0.64, they are the homologue or the analogue of above structure, are wherein increasing one or more CH ₂In the time of group, for each CH that adds ₂Group, the adjacent carbons from molecule are removed two hydrogen atoms forming a carbon-to-carbon double bond, thereby keep the number of hydrogen atoms in the molecule constant, and these solvents comprise: 2, and 2-two-2-propenyl-1, ammediol; 2-(1-pentenyl)-1, ammediol; 2-(2-methyl-2-propenyl)-2-(2-propenyl)-1, ammediol; 2-(3-methyl-1-butene base)-1, ammediol; 2-(4-pentenyl)-1, ammediol; 2-ethyl-2-(2-methyl-2-propenyl)-1, ammediol; 2-ethyl-2-(2-propenyl)-1, ammediol; 2-methyl-2-(3-methyl-3-butenyl)-1, ammediol; 2,2-diallyl-1,3 butylene glycol; 2-(1-ethyl-1-propenyl)-1,3 butylene glycol; 2-(crotyl)-2-methyl isophthalic acid, the 3-butyleneglycol; 2-(3-methyl-2-butene base)-1,3 butylene glycol; 2-ethyl-2-(2-propenyl)-1,3 butylene glycol; 2-methyl-2-(1-methyl-2-propenyl)-1,3 butylene glycol; 2,3-two (1-methyl ethylidene)-1,4-butyleneglycol; 2-(3-methyl-2-butene base)-3-methylene radical-1, the 4-butyleneglycol; 2-(1,1-dimethyl propyl-2-butylene-1,4-glycol; 2-(1-methyl-propyl)-2-butylene-1, the 4-glycol; 2-butyl-2-butylene-1, the 4-glycol; 2-vinyl-3-ethyl-1, the 3-pentanediol; 2-vinyl-4,4-dimethyl-1,3-pentanediol; 3-methyl-2-(2-propenyl)-1, the 4-pentanediol; 2-(1-propenyl)-1, the 5-pentanediol; 2-(2-propenyl)-1, the 5-pentanediol; 2-ethylidene-3-methyl isophthalic acid, the 5-pentanediol; 2-propylidene-1, the 5-pentanediol; 3-ethylidene-2,4-dimethyl-2,4-pentanediol; 2-(1, the 1-dimethyl ethyl)-4-amylene-1, the 3-glycol; 2-ethyl-2,3-dimethyl-4-amylene-1,3-glycol; 4-ethyl-2-methylene radical-1, the 4-hexylene glycol; 2,3,5-trimethylammonium-1,5-hexadiene-3,4-glycol; 5-ethyl-3-methyl isophthalic acid, 5-hexadiene-3,4-glycol; 2-(1-methyl ethylene)-1, the 5-hexylene glycol; 2-vinyl-1, the 6-hexylene glycol; 5,5-dimethyl-1-hexene-3,4-glycol; 5,5-dimethyl-1-hexene-3,4-glycol; 4-vinyl-2,5-dimethyl-2-hexene-1,5-glycol; 2-vinyl-2,5-dimethyl-3-hexene-1,6-glycol; 2-ethyl-3-hexene-1, the 6-glycol; 3,4-dimethyl-3-hexene-1,6-glycol; 2,5-dimethyl-4-hexene-2,3-glycol; 3,4-dimethyl-4-hexene-2,3-glycol; 3-(2-propenyl)-5-hexene-1, the 3-glycol; 2,3-dimethyl-5-hexene-2,3-glycol; 3,4-dimethyl-5-hexene-2,3-glycol; 3,5-dimethyl-5-hexene-2,3-glycol; 3-vinyl-2,5-dimethyl-5-hexene-2,4-glycol; 6-methyl-5-methylene radical-1, the 4-heptanediol; 2,3-dimethyl-1,5-heptadiene-3,4-glycol; 2,5-dimethyl-1,5-heptadiene-3,4-glycol; 3,5-dimethyl-1,5-heptadiene-3,4-glycol; 2,6-two (methylene radical)-1,7-heptanediol; 4-methylene radical-1, the 7-heptanediol; 2,4-dimethyl-1-teracrylic acid, 5-glycol; 2,6-dimethyl-1-teracrylic acid, 5-glycol; 3-vinyl-5-methyl isophthalic acid-teracrylic acid, the 5-glycol; 6,6-dimethyl-1-teracrylic acid, 5-glycol; 4,6-dimethyl-2,4-heptadiene-2,6-glycol; 4,4-dimethyl-2,5-heptadiene-1,7-glycol; 2,5,5-trimethylammonium-2,6-heptadiene-1,4-glycol; 5,6-dimethyl-2-heptene-1,4-glycol; 5-ethyl-2-heptene-1, the 5-glycol; 2-methyl-2-heptene-1, the 7-glycol; 4,6-dimethyl-3-heptene-1,5-glycol; 3-methyl-6-methylene radical-3-heptene-1, the 7-glycol; 2,4-dimethyl-3-heptene-2,5-glycol; 2,5-dimethyl-3-heptene-2,5-glycol; 2,6-dimethyl-3-heptene-2,6-glycol; 4,6-dimethyl-3-heptene-2,6-glycol; 2,4-dimethyl-5-heptene-1,3-glycol; 3,6-dimethyl-5-heptene-1,3-glycol; 2,6-dimethyl-5-heptene-1,4-glycol; 3,6-methyl-5-heptene-1,4-glycol; 2,3-dimethyl-5-heptene-2,4-glycol; 2,2-dimethyl-6-heptene-1,3-glycol; 4-(2-propenyl)-6-heptene-1, the 4-glycol; 5,6-dimethyl-6-heptene-1,4-glycol; 2,4-dimethyl-6-heptene-1,5-glycol; 2-ethylidene-6-methyl-6-heptene-1, the 5-glycol; 4-(2-propenyl)-6-heptene-2, the 4-glycol; 5,5-dimethyl-6-heptene-2,4-glycol; 4,6-dimethyl-6-heptene-2,5-glycol; 5-vinyl-4-methyl-6-heptene-2, the 5-glycol; 2-methylene radical-1, the 3-ethohexadiol; 2,6-dimethyl-1,6-octadiene-3,5-glycol; 3,7-dimethyl-1,6-octadiene-3,5-glycol; 2,6-dimethyl-1,7-octadiene-3,6-glycol; 2,7-dimethyl-1,7-octadiene-3,6-glycol; 3,6-dimethyl-1,7-octadiene-3,6-glycol; 3-vinyl-1-octene-3, the 6-glycol; 2,7-dimethyl-2,4,6-sarohornene-1,8-glycol; 3,7-dimethyl-2,4-octadiene-1,7-glycol; 2,6-dimethyl-2,5-octadiene-1,7-glycol; 3,7-dimethyl-2,5-octadiene-1,7-glycol; 3,7-dimethyl-2,6-octadiene-1,4-glycol (Rosiridol); 2-methyl-2,6-octadiene-1,8-glycol; 3,7-dimethyl-2,7-octadiene-1,4-glycol; 2,6-dimethyl-2,7-octadiene-1,5-glycol; 2,6-dimethyl-2,7-octadiene-1,6-glycol (8-hydroxyl phantol); 2,7-dimethyl-2,7-octadiene-1,6-glycol; The 2-octene-1, the 4-glycol; The 2-octene-1, the 7-glycol; 2-methyl-6-methylene radical-2-octene-1, the 7-glycol; 3,7-dimethyl-3,5-octadiene-1,7-glycol; 2,7-dimethyl-3,5-octadiene-2,7-glycol; 4-methylene radical-3, the 5-ethohexadiol; 2,6-dimethyl-3,7-octadiene-1,6-glycol; 2,7-dimethyl-3,7-octadiene-2,5-glycol; 2,6-dimethyl-3,7-octadiene-2,6-glycol; 4-methyl-3-octene-1, the 5-glycol; 5-methyl-3-octene-1, the 5-glycol; 2,2-dimethyl-4,6-octadiene-1,3-glycol; 2,6-dimethyl-4,7-octadiene-2,3-glycol; 2,6-dimethyl-4,7-octadiene-2,6-glycol; 7-methyl-4-octene-1, the 6-glycol; 2,7-two (methylene radical); The 2-methylene radical-; 2,7-dimethyl-5,7-octadiene-1,4-glycol; 7-methyl-5,7-octadiene-1,4-glycol; The 5-octene-1, the 3-glycol; 7-methyl-6-octene-1, the 3-glycol; 7-methyl-6-octene-1, the 4-glycol; The 6-octene-1, the 5-glycol; 7-methyl-6-octene-1, the 5-glycol; 2-methyl-6-octene-3, the 5-glycol; 4-methyl-6-octene-3, the 5-glycol; 2-methyl-7-octene-1, the 3-glycol; 4-methyl-7-octene-1, the 3-glycol; 7-methyl-7-octene-1, the 3-glycol; The 7-octene-1, the 5-glycol; The 7-octene-1, the 6-glycol; 5-methyl-7-octene-1, the 6-glycol; 2-methyl-6-methylene radical-7-octene-2, the 4-glycol; 7-methyl-7-octene-2, the 5-glycol; 2-methyl-7-octene-3, the 5-glycol; 1-nonene-3, the 5-glycol; 1-nonene-3, the 7-glycol; 3-nonene-2, the 5-glycol; 8-methyl-4,6-nonadiene-1,3-glycol; 4-nonene-2, the 8-glycol; 6,8-nonadiene-1,5-glycol; 7-nonene-2, the 4-glycol; 8-nonene-2, the 4-glycol; 8-nonene-2, the 5-glycol; 1,9-decadiene-3,8-glycol; And/or 1,9-decadiene-4,6-glycol; And

XI. their mixture, this main solvent contain quantity not sufficient and are selected from 2,2,4-trimethylammonium-1,3-pentanediol, 2,2,4-trimethylammonium-1, the ethoxylate of 3-pentanediol, diethoxy thing or triethoxy compound derivative with what form water base stable prod; With and/or 2-ethylhexyl-1, the solvent of 3-glycol.

10. the fabric sofetening composition of stable aqueous based dispersions form wherein contains among the claim 1-4 of 2-50% each fabric softener active matter.

11. premix compositions wherein contains among the claim 1-4 each the fabric softener active matter and the effective spices of quantity.

12. premix compositions wherein contains component A, B and the C of each composition among the claim 5-9.

13. solid fabric softening agent composition wherein contains among the claim 1-4 of effective quantity each fabric softener active matter.

14. transparent water base fabric softener composition wherein contains the fabric softener active matter of the claim 1 of effective quantity.

15. prepare the method for fabric softener composition, add in the entry comprising pre-composition claim 12, regulate pH to 1.5-5, add the water-soluble calcium of effective quantity and/or magnesium salts to improve the viscosity and/or the transparency of composition.