CN1261625C - 一种聚乙二醇用作纺丝添加剂的应用方法 - Google Patents
一种聚乙二醇用作纺丝添加剂的应用方法 Download PDFInfo
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- CN1261625C CN1261625C CN 200410046808 CN200410046808A CN1261625C CN 1261625 C CN1261625 C CN 1261625C CN 200410046808 CN200410046808 CN 200410046808 CN 200410046808 A CN200410046808 A CN 200410046808A CN 1261625 C CN1261625 C CN 1261625C
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- Prior art keywords
- polyethylene glycol
- spinning
- fiber
- diacetate
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002202 Polyethylene glycol Substances 0.000 title claims abstract description 59
- 229920001223 polyethylene glycol Polymers 0.000 title claims abstract description 59
- 238000009987 spinning Methods 0.000 title claims abstract description 46
- 239000000654 additive Substances 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 28
- 230000000996 additive effect Effects 0.000 title claims abstract description 19
- 229920006239 diacetate fiber Polymers 0.000 claims abstract description 31
- 239000000203 mixture Substances 0.000 claims abstract description 15
- 230000008569 process Effects 0.000 claims description 11
- 229920006221 acetate fiber Polymers 0.000 claims description 10
- 239000002002 slurry Substances 0.000 claims description 10
- 238000013459 approach Methods 0.000 claims description 9
- 230000015556 catabolic process Effects 0.000 abstract description 11
- 238000006731 degradation reaction Methods 0.000 abstract description 11
- 239000002657 fibrous material Substances 0.000 abstract description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 24
- 235000019504 cigarettes Nutrition 0.000 description 20
- 229920001747 Cellulose diacetate Polymers 0.000 description 19
- 239000000463 material Substances 0.000 description 18
- 239000000835 fiber Substances 0.000 description 13
- 239000000052 vinegar Substances 0.000 description 9
- 235000021419 vinegar Nutrition 0.000 description 9
- 239000003921 oil Substances 0.000 description 7
- 230000008859 change Effects 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000003546 flue gas Substances 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 230000000391 smoking effect Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 230000009187 flying Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920000151 polyglycol Polymers 0.000 description 2
- 239000010695 polyglycol Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- XOMKZKJEJBZBJJ-UHFFFAOYSA-N 1,2-dichloro-3-phenylbenzene Chemical group ClC1=CC=CC(C=2C=CC=CC=2)=C1Cl XOMKZKJEJBZBJJ-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 108010022355 Fibroins Proteins 0.000 description 1
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 1
- 230000021736 acetylation Effects 0.000 description 1
- 238000006640 acetylation reaction Methods 0.000 description 1
- 229940081735 acetylcellulose Drugs 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000000578 dry spinning Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005297 material degradation process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 239000012782 phase change material Substances 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229940113115 polyethylene glycol 200 Drugs 0.000 description 1
- 229940068918 polyethylene glycol 400 Drugs 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
Description
二醋酸纤维素∶聚乙二醇∶丙酮 | 粘度值(m pa.s) | 二醋酸纤维素∶聚乙二醇∶丙酮 | 粘度值(m pa.s) |
70∶30∶210 | 40291-40391 | 80∶20∶240 | 64186-64686 |
70∶30∶300 | 9598-9698 | 80∶20∶300 | 11500-11800 |
70∶30∶350 | 4699-4999 | 80∶20∶350 | 5999-6100 |
70∶30∶450 | 3000-3299 | 80∶20∶400 | 4000-4400 |
二醋酸纤维素∶聚乙二醇∶丙酮 | 粘度值(m pa.s) | 二醋酸纤维素∶聚乙二醇∶丙酮 | 粘度值(m pa.s) |
85∶15∶255 | 65700-68500 | 90∶10∶270 | 63386-64686 |
85∶15∶300 | 22600-22695 | 90∶10∶300 | 22600-22800 |
85∶15∶350 | 15900-16000 | 90∶10∶350 | 8898-19000 |
85∶15∶400 | 6600-6900 | 90∶10∶350 | 5099-48000 |
二醋酸纤维素∶聚乙二醇∶丙酮 | 粘度值(m pa.s) | 二醋酸纤维素∶聚乙二醇∶丙酮 | 粘度值(m pa.s) |
70∶30∶210 | 31590-31093 | 80∶20∶240 | 63586-64086 |
70∶30∶300 | 8000-8300 | 80∶20∶300 | 11897-12097 |
70∶30∶350 | 3900-4300 | 80∶20∶350 | 4800-5100 |
70∶30∶450 | 2100-2400 | 80∶20∶400 | 2500-2800 |
二醋酸纤维素∶聚乙二醇∶丙酮 | 粘度值(m pa.s) | 二醋酸纤维素∶聚乙二醇∶丙酮 | 粘度值(m pa.s) |
85∶15∶255 | 62312-62812 | 90∶10∶270 | 64569-65069 |
85∶15∶300 | 17300-17400 | 90∶10∶300 | 23000-24000 |
85∶15∶350 | 6299-6499 | 90∶10∶350 | 12200-12300 |
85∶15∶400 | 4599-4799 | 90∶10∶350 | 5600-5800 |
单旦Titer(den) | 断强Tenacity(CN/tex) | 延伸率Elong(%) | |
普通醋纤 | 2.68 | 12.2 | 27.2 |
加入添加剂醋纤 | 2.99 | 10.7 | 26.0 |
总旦(den) | 卷曲能(g.cm/cm) | 断强(CN/tex) | 飞花(mg/30min) | 外油(%) | |
普通醋纤 | 35.2 | 245 | 25.2 | 30 | 0.9 |
加入添加剂醋纤 | 35.6 | 246 | 26.1 | 31 | 1.0 |
硬度(%) | 重量(g) | 圆周(mm) | 吸阻(mm) | 焦油含量(mg) | 降解时间(天) | |
普通卷烟滤嘴 | 5.407 | 0.7481 | 24.025 | 401.4 | 15 | 30 |
加入添加剂卷烟滤嘴 | 5.324 | 0.7289 | 23.986 | 403.2 | 13.5 | 20 |
总旦(den) | 卷曲能(g.cm/cm) | 断强(CN/tex) | 飞花(mg/30min) | 外油(%) | |
普通醋纤 | 35.2 | 245 | 25.2 | 30 | 0.9 |
加入添加剂醋纤 | 35.6 | 256 | 26.6 | 35 | 1.1 |
硬度(%) | 重量(g) | 圆周(mm) | 吸阻(mm) | 焦油含量(mg) | 降解时间(天) | |
普通卷烟滤嘴 | 5.609 | 0.7868 | 24.080 | 369.3 | 15 | 30 |
加入添加剂卷烟滤嘴 | 5.561 | 0.7592 | 24.066 | 376.5 | 12.96 | 19 |
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200410046808 CN1261625C (zh) | 2004-09-30 | 2004-09-30 | 一种聚乙二醇用作纺丝添加剂的应用方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200410046808 CN1261625C (zh) | 2004-09-30 | 2004-09-30 | 一种聚乙二醇用作纺丝添加剂的应用方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1616726A CN1616726A (zh) | 2005-05-18 |
CN1261625C true CN1261625C (zh) | 2006-06-28 |
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Application Number | Title | Priority Date | Filing Date |
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CN 200410046808 Expired - Lifetime CN1261625C (zh) | 2004-09-30 | 2004-09-30 | 一种聚乙二醇用作纺丝添加剂的应用方法 |
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CN (1) | CN1261625C (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2474694B (en) * | 2009-10-23 | 2011-11-02 | Innovia Films Ltd | Biodegradable composites |
GB0922253D0 (en) * | 2009-12-21 | 2010-02-03 | British American Tobacco Co | Sheet filter materials with additives |
CN105088868B (zh) * | 2015-08-04 | 2017-10-17 | 浙江中烟工业有限责任公司 | 高界面粘附强度纳米纤维复合纸及其制备方法和应用 |
CN105088376B (zh) * | 2015-08-04 | 2017-11-17 | 浙江中烟工业有限责任公司 | 高界面粘附强度纳米纤维复合丝束及其制备方法和应用 |
CN110387625B (zh) * | 2019-07-10 | 2021-08-10 | 上海八达纺织印染服装有限公司 | 一种自动调温双层面料及其加工方法 |
-
2004
- 2004-09-30 CN CN 200410046808 patent/CN1261625C/zh not_active Expired - Lifetime
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Publication number | Publication date |
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CN1616726A (zh) | 2005-05-18 |
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C14 | Grant of patent or utility model | ||
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ASS | Succession or assignment of patent right |
Owner name: CHINA TOBACCO HUNAN INDUSTRIAL CORPORATION Free format text: FORMER OWNER: CHANGSHA CIGARETTE FACTORY Effective date: 20070706 |
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Effective date of registration: 20070706 Address after: 410001 Mars Development Zone, Hunan, Changsha seven Patentee after: CHINA TOBACCO HUNAN IND Corp. Address before: 410007 No. 426 middle labour Road, Changsha, Hunan Patentee before: Changsha Cigarette Factory |
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C56 | Change in the name or address of the patentee |
Owner name: HUNAN ZHONGYAN INDUSTRY CO., LTD. Free format text: FORMER NAME OR ADDRESS: CHINA TOBACCO HUNAN INDUSTRIAL CORPORATION |
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CP03 | Change of name, title or address |
Address after: Wanjiali Road, Yuhua District of Hunan province Changsha three No. 188 Patentee after: CHINA TOBACCO HUNAN INDUSTRIAL Co.,Ltd. Address before: Seven pieces of Mars Development Zone, Hunan, Changsha Patentee before: CHINA TOBACCO HUNAN IND Corp. |
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CX01 | Expiry of patent term |
Granted publication date: 20060628 |