CN1256074A - Pesticide composition - Google Patents
Pesticide composition Download PDFInfo
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- CN1256074A CN1256074A CN 99124758 CN99124758A CN1256074A CN 1256074 A CN1256074 A CN 1256074A CN 99124758 CN99124758 CN 99124758 CN 99124758 A CN99124758 A CN 99124758A CN 1256074 A CN1256074 A CN 1256074A
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Abstract
To obtain an insecticidal composition or an insecticidal aerosol agent having excellent immediate effect and insecticidal activity against insect pests. This insecticidal composition comprises 2-methyl-4-oxo-3-(2- propenyl)cyclopent-2-enyl 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate and a petroleum-based solvent having at least one of 11-17C saturated hydrocarbons ands 2:3-4:1 ratio of alicyclic hydrocarbons.
Description
The present invention relates to the method for composition pesticide and control pest.
BP GB-2055822A has narrated 2-methyl-4-oxygen-3-(2-propynyl) ring penta-2-thiazolinyl 3-(2 as pesticide active ingredient, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester, but 2-methyl-4-oxygen-3-(2-propynyl) ring penta-2-thiazolinyl 3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester is used in the composition pesticide, in the time of particularly in the aerosol composition pesticide, usually can not provide enough quick-acting.For the desired quick-acting of this composition, should make said composition pesticide be used for promptly preventing and treating pest behind one or more pests.
The invention provides a kind of method with composition pesticide and control pest of excellent pesticide activity.In this respect, composition pesticide of the present invention encircles penta-2-thiazolinyl 3-(2, the 2-dichloroethylene)-2 with containing 2-methyl-4-oxygen-3-(2-propynyl), and the known compositions of 2-dimethyl cyclopropane carboxylic acid ester is compared, and has unexpected excellent pesticide activity.For example, the pesticide activity in composition pesticide provides excellent quick-acting, and therefore, after said pest was exposed to said composition pesticide, the composition pesticide that is provided just can be prevented and treated pest apace.
Composition pesticide provided by the invention contains 0.01～1% weight meter, 2-methyl-4-oxygen-3-(2-propynyl) ring penta-2-thiazolinyl 3-(2 as active ingredient, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester and 90～99.99% weight meters contains at least a saturated C
11-17Alicyclic and at least a saturated C
11-17The saturated fat hydrocarbon mixture of aliphatic hydrocarbon.In composition pesticide of the present invention, the weight ratio of saturated alicyclic hydrocarbon and aliphatic saturated hydrocarbon is 2: 3～4: 1.The present invention also provides aerosol combination, and it consists of above-mentioned composition pesticide and propellant.The present invention and providing comprises the method for using composition pesticide of the present invention or aerosol combination control pest.
Composition pesticide of the present invention includes 2-methyl-4-oxygen-3-(2-propynyl) ring penta-2-thiazolinyl 3-(2 as active ingredient, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester, in with its said composition pesticide as active ingredient, can there be 2-methyl-4-oxygen-3-(2-propynyl) ring penta-2-thiazolinyl 3-(2, the 2-dichloroethylene)-2, the isomer various optics of 2-dimethyl cyclopropane carboxylic acid ester or how much, condition are that said optics in composition pesticide or how much isomer have pesticide activity.2-methyl-4-oxygen-3-(2-propynyl) ring penta-2-thiazolinyl 3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester can prepare according to the narration in GB2055822A.
Saturated hydrocarbon mixtures in composition pesticide of the present invention is made up of saturated alicyclic hydrocarbon and aliphatic saturated hydrocarbon, and its weight ratio is 2: 3～4: 1.Aliphatic saturated hydrocarbon in said composition pesticide and saturated alicyclic hydrocarbon contain 11～17 carbon, preferably contain 11～15 carbon.
Composition pesticide of the present invention is by 2-methyl-4-oxygen-3-(2-propynyl) ring penta-2-thiazolinyl 3-(2, the 2-dichloroethylene)-2 of 0.01～1% weight, and the saturated hydrocarbon mixtures of 2-dimethyl cyclopropane carboxylic acid ester and 90～99.99% weight meters is formed.This composition pesticide is processed into finish usually.
Under the situation that composition pesticide of the present invention uses as aerosol combination, the classical group of aerosol combination becomes said composition pesticide and the propellant in the aerosol cylinder, in said aerosol combination, composition pesticide is 3: 7～7: 3 with the typical weight ratio of propellant.Can in said aerosol combination, use, comprise liquefied petroleum gas as illustration and nonrestrictive propellant example, dimethyl ether, carbonic acid gas etc., and composition thereof.In addition, if desired, said aerosol combination also can contain solid carrier, for example SiO 2 powder.
Composition pesticide of the present invention also can select to contain other pesticide activity component, synergist, spices or cosolvent arbitrarily.
The example of other pesticide activity component that can use in composition pesticide of the present invention comprises allethrin, tetramethrin, prallethrin, phenothrin, Chryson, cyphenothrin, permethrin, cypermethrin, decis, cyfloxylate, prothrin, miaow alkynes chrysanthemum ester, ether chrysanthemum ester, dichlorvos, Folithion, unden, pyriproxyfen, Entocon ZR 515, Entocon ZR 512, TH-6040, fly eradication amine etc., but is not limited to this.
The example of the synergist that can use in composition pesticide of the present invention comprises Butacide, MGK264, S421 etc., but is not limited to this.
The example of the cosolvent that can use in composition pesticide of the present invention comprises alkylbenzene for example trimethylbenzene and detergent alkylate; Diphenyl alkane is phenyl xylyl ethane for example; Ester is isopropyl myristin, diisobutyl adipate, di-n-octyl sebacate and dioctyl succinate for example; Alcohol is ethanol, isopropyl alcohol, benzylalcohol and 3-methoxyl group-3-methyl isophthalic acid-butanols for example; Other saturated hydrocarbon is C for example
10Or lower alkane and C
18Or higher alkane, the unsaturation hydrocarbon is aromatic hydrocarbons etc. for example, but be not limited to this.If composition pesticide contains aromatic hydrocarbons as cosolvent, so preferred composition pesticide contains the less aromatic hydrocarbons of scent of.For example, when in composition pesticide, having aromatic hydrocarbons, can be that carbon number is 10 or more aromatic hydrocarbons.
The method of producing composition pesticide of the present invention comprises that forming 2-methyl-4-oxygen-3-(2-propynyl) encircles penta-2-thiazolinyl 3-(2, the 2-dichloroethylene)-2, the processing method of the composition of 2-dimethyl cyclopropane carboxylic acid ester and said saturated hydrocarbon mixtures.Preferred this composition comprises 2-methyl-4-oxygen-3-(2-propynyl) ring penta-2-thiazolinyl 3-(2, the 2-dichloroethylene)-2, and 2-dimethyl cyclopropane carboxylic acid ester and saturated hydrocarbon mixtures are dissolved in mixture wherein., this composition can comprise that also all components does not dissolve or not exclusively is dissolved in wherein, emulsion for example, mixtures such as suspending agent.Said composition can form in room temperature or under the temperature of heating, if desired, also can contain a kind or multiple other above-mentioned pesticide activity component, synergist, and spices or cosolvent mix wherein.
The method of control pest typically comprises uses said composition pesticide or aerosol combination.The method of preferred control pest can comprise composition pesticide of the present invention or aerosol combination are applied to the place that maybe needs to prevent and treat pest on the pest.The example in the place that composition pesticide can be used comprises the habitat of pest, the place of pest contact etc.
In order to prevent and treat various pests, typical insect and mite, flying insect for example, the insect that creeps, the insect of harm timber etc., the method for control pest of the present invention can be used composition pesticide.The limiting examples of enumerating of these insects and mite comprises Lepidoptera, diptera, and Lian mantis suborder, Hymenoptera, Isoptera, hard tick section, dermatophagoides pteronyssinus etc., but be not limited to this.The lepidopterous example that more refers in particular to comprises a bag rain moth, curtain rain moth etc., and the dipterous example that more refers in particular to comprises Culex for example northern house and Culex tritaeniorhynchus, Aedes is Aedes aegypti and Aedes alpopictus for example, Anopheles is Anopheles sinensis for example, Chironomidae, and Nuscidae is housefly and false stable fly for example, Calliphoridae, Flesh flies, Anthomyiidae is Fannia canicularis for example, and fly is planted on delia platura and green onion ground, Tephritidae, Drosophilidae, Moth files, Tabanidae, buffalo gnat worm section, sting fly subfamily etc., the example that more refers in particular to of Lian mantis suborder comprises Groton bug, Peroplaneta fluligginosa, American cockroach, the big Lian of foxiness, oriental cockroach etc.The hymenopteran example that more refers in particular to comprises Formicidae, Vespidae, and swaflies is yellow-winged cabbage sawfly etc. for example.The example that more refers in particular to of Isoptera comprises eastern subterranean termite, Taiwan formosanes etc., and the example that more refers in particular to of hard tick section comprises boophilus microplus.The example that more refers in particular to of dermatophagoides pteronyssinus comprises Tyroglyphidae, Pyroglyphidae, cheyletidae, ornithonyssus bacoti etc.
The method of the present invention of control pest is typically used composition pesticide and the aerosol combination of preventing and treating the pest effective dose.For example, at the insect eastern subterranean termite of control harm timber, during Taiwan formosanes etc., the pest control method preferably is applied to said composition pesticide timber, and soil etc. are located, and consumption is the about 0.001～100mg/m of active ingredient that is used
2When pest control method of the present invention was used for resident family, flying insect is mosquito for example, and fly etc. can be prevented and treated effectively by applying pesticides composition or aerosol combination, and its consumption is the active ingredient 0.001～10mg/m that is used
3Similarly, creep insect for example during cockroach etc. when the family expenses purpose of composition pesticide comprises control, said pest control method also can comprise uses this composition pesticide, and its consumption is the about 0.001～100mg/m of active ingredient that is used
2
Embodiment
Below, explain the present invention in further detail by following example, but the present invention is not limited to these examples.
Formulation Example 1
In order to produce composition pesticide, with the Exxsol D 130 (C of about 67% weight meter
15-17The C of saturated alicyclic hydrocarbon and 31% weight meter
15-17Aliphatic saturated hydrocarbon, wherein the percetage by weight of said hydrocarbon is based on the total weight of Exxsol D 130; Make by Exxon ChemicalCompany) be added to (S)-2-methyl-4-oxygen-3-(2-propynyl) ring penta-2-thiazolinyl (1R)-anti--3-(2 of 0.06 part of weight meter, the 2-dichloroethylene)-2, in the 2-dimethyl cyclopropane carboxylic acid ester, its amount reaches 100 parts of weight meters, then in mixed at room temperature.The composition pesticide that is produced is designated as " composition 1 ".
Formulation Example 2～5
Except adopting Exxsol D 110, Exxsol D 80, Naphthezol M or Naphthezol H replace outside the said Exxsol D 130, are similar to formulation Example 1 and produce composition pesticide, are listed in the table below 1.Each prescription of listing in the table 1 all gives the composition number of appointment.
Exxsol D 110 and Exxsol D 80 are made by Exxon Chemical Company, and Naphthezol M and Naphthezol H are made by Nippon Petrochemicals Company.The classical group of Exxsol D 110 becomes the C of about 47% weight meter
15The C of saturated alicyclic hydrocarbon and 51% weight meter
15Aliphatic saturated hydrocarbon.The classical group of Exxsol D 80 becomes the C of about 48% weight meter
11-13The C of saturated alicyclic hydrocarbon and 52% weight meter
11-13Aliphatic saturated hydrocarbon.The classical group of Naphthezol M becomes the C of about 75% weight meter
12-13The C of saturated alicyclic hydrocarbon and 25% weight meter
12-13Aliphatic saturated hydrocarbon.The classical group of Naphthezol H becomes the C of about 70% weight meter
13-14The C of saturated alicyclic hydrocarbon and 30% weight meter
13-14Aliphatic saturated hydrocarbon.The Exxsol D 110 that is provided is provided the percetage by weight of said hydrocarbon, Exxsol D 80, the total weight of Naphthezol M or Naphthezol H.
Table 1
Formulation Example compositions of hydrocarbons composition number
Formulation Example 2 Exxsol D 110 2
Formulation Example 3 Exxsol D 80 3
Formulation Example 4 Naphthezol M 4
Formulation Example 5 Naphthezol H 5
The formulation Example 1～6 of contrast
Except employing Exxsol D 30, Exxsol D 40, Exxsol D 160, Isopar M, the compositions of hydrocarbons of Isopar V or Isopar L replace outside the said Exxsol D 130, are similar to formulation Example 1 and produce the composition pesticide of contrast, are listed in the table below 2.Be listed in the letter that each comparative formula in the table 2 all gives the composition of appointment.
Table 2
The formulation Example compositions of hydrocarbons composition letter of contrast
Formulation Example 1 Exxsol D 30 A of contrast
Formulation Example 2 Exxsol D 40 B of contrast
Formulation Example 3 Exxsol D 160 C of contrast
The formulation Example 4 Isopar M D of contrast
The formulation Example 5 Isopar V E of contrast
The formulation Example 6 Isopar L F of contrast
Exxsol D 30, Exxsol D 40, Exxsol D 160, Isopar M, Isopar V and Isopar L are made by Exxon Chemical Company, and the classical group of Exxsol D 30 becomes the C of about 46% weight meter
8-10The C of saturated alicyclic hydrocarbon and 54% weight meter
8-10Aliphatic saturated hydrocarbon.The classical group of Exxsol D 40 becomes the C of about 46% weight meter
9-11The C of saturated alicyclic hydrocarbon and 54% weight meter
9-11Aliphatic saturated hydrocarbon.C wherein
11The total amount of saturated hydrocarbon is approximately 20% weight meter.The classical group of Exxsol D 160 becomes the C of about 42% weight meter
18-19The C of saturated alicyclic hydrocarbon and 58% weight meter
18-19Aliphatic saturated hydrocarbon.The classical group of Isopar M becomes the C of about 21% weight meter
12-15The C of saturated alicyclic hydrocarbon and 79% weight meter
12-15Aliphatic saturated hydrocarbon.The classical group of Isopar V becomes the C of about 20% weight meter
15-17The C of saturated alicyclic hydrocarbon and 80% weight meter
15-17Aliphatic saturated hydrocarbon.The classical group of Isopar L becomes the C of about 12% weight meter
11-13The C of saturated alicyclic hydrocarbon and 88% weight meter
11-13Aliphatic saturated hydrocarbon.The Exxsol D 30 that is provided is provided the percetage by weight of said hydrocarbon, Exxsol D 40, Exxsol D 160, Isopar M, the total weight of Isopar V or Isopar L.
Formulation Example 6～10 and comparative formula embodiment 7～12
Enter in the aerosol cylinder of the liquefied petroleum gas that contains 50% weight meter by the composition 1～6 of can 50% weight meter respectively, produce aerosol combination of the present invention.
Enter in the aerosol cylinder of the liquefied petroleum gas that contains 50% weight meter by the Comparative composition A～F of can 50% weight meter respectively, produce the aerosol combination of contrast.
Each aerosol formulations that is produced and the aerosol formulations of contrast all give the composition number or the letter of appointment, and be as shown in table 3 below.
The composition of the composition appointment that the formulation Example of table 3 prescription and contrast is number contained number
Formulation Example 616
Formulation Example 727
Formulation Example 838
Formulation Example 949
Formulation Example 10 5 10
The formulation Example 7 A G of contrast
The formulation Example 8 B H of contrast
The formulation Example 9 C I of contrast
The formulation Example 10 D J of contrast
The formulation Example 11 E K of contrast
The formulation Example 12 F L of contrast
Experimental example 1
Place diameter respectively and be the glass garden pipe of 30cm and high 50cm, have the garden of the diameter of a 15cm to describe device in each said garden pipe, the Groton bug of 5 male and female sex-healths is wherein respectively arranged.Then, be sprayed onto on the Groton bug from the composition G～I of pipe top, said glass garden respectively about 0.4g composition 6～8 and contrast.After the spray composition, on the pipe of glass garden, close the lid, after 30 seconds, shift out the garden of 15cm diameter and describe device, after each minute, the Groton bug number that number goes out to knock down.
Above program repeats 3 times.
Measure the composition G～I of every kind of composition 6～8 and contrast then, said composition (is KT to knocking down 50% Groton bug required average time from spraying
50).The KT of gained
50Value is listed in the table below 4.
Table 4
Composition KT
50(minute)
Composition 6 1.3
Composition 7 1.1
Composition 8 1.1
The composition G of contrast is greater than 10
The composition H 2.2 of contrast
The composition I 3.1 of contrast
Experimental example 2
Place diameter respectively and be the glass garden shape pipe of 30cm and high 50cm, have the garden of a 15cm diameter to describe device in each said garden pipe, the Groton bug of 5 male and female sex-healths is wherein respectively arranged.Then, respectively from pipe top, said glass garden, with about 1.2g composition 9 and 10 and the composition J and the K of contrast be sprayed onto on the Groton bug.Behind the spray composite, on the pipe of glass garden, close the lid, after 30 seconds, shift out the garden of 15cm diameter and describe device, then Groton bug is transferred in the cup, give water and feed.After 3 days, observation is for the lethality of the Groton bug of every kind of composition.
Above program repeats 4 times.
The lethality of every kind of composition is listed in the table below 5.
Table 5
Composition lethality (%)
Composition 9 95.0
Composition 10 100.
The composition J 75.0 of contrast
The composition HK 60.0 of contrast
Experimental example 3
Place diameter respectively and be the glass garden pipe of 30cm and high 50cm, have the garden of a diameter 15cm to describe device in each said garden pipe, the Groton bug of 5 male and female sex-healths is wherein respectively arranged.Then, from the top of said glass garden pipe, about 0.8g composition 8 is sprayed onto on the Groton bug with the composition L that contrasts.After the spray composition, on the pipe of glass garden, close the lid, after 30 seconds, shift out the garden of 15cm diameter and describe device, then Groton bug is transferred in the cup, and given water and feed.After 3 days, observation is for the lethality of the Groton bug of every kind of composition.
Above program repeats 4 times.
The average mortality of every kind of composition is listed in the table below 6.
Table 6
Composition lethality (%)
Composition 8 100.
The composition L 50.0 of contrast
Claims (5)
1. composition pesticide, 2-methyl-4-oxygen-3-(2-propynyl) ring penta-2-thiazolinyl 3-(2 that contains 0.01～1% weight meter, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester, as active ingredient, with the saturated hydrocarbon mixtures of 90～99.99% weight meters, wherein said saturated hydrocarbon mixtures contains a kind of C at least
11-17Saturated alicyclic hydrocarbon and at least a C
11-17Aliphatic saturated hydrocarbon, the weight ratio of saturated alicyclic hydrocarbon and aliphatic saturated hydrocarbon are 2: 3～4: 1.
2. aerosol combination contains the composition pesticide and the propellant of claim 1.
3. according to the aerosol combination of claim 2, wherein the weight ratio of composition pesticide and propellant is 3: 7～7: 3.
4. the method for control pest, the composition pesticide that comprises the claim 1 of using effective dose are on pest or the habitat of pest.
5. the method for control pest, the aerosol combination that comprises the claim 2 of using effective dose are on pest or the habitat of pest.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP35027398A JP4182239B2 (en) | 1998-12-09 | 1998-12-09 | Insecticidal composition and insecticidal aerosol |
| JP350273/98 | 1998-12-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1256074A true CN1256074A (en) | 2000-06-14 |
Family
ID=18409388
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99124758 Pending CN1256074A (en) | 1998-12-09 | 1999-12-09 | Pesticide composition |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP4182239B2 (en) |
| CN (1) | CN1256074A (en) |
| AR (1) | AR021432A1 (en) |
| BR (1) | BR9908655A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101548672A (en) * | 2008-03-31 | 2009-10-07 | 大日本除虫菊株式会社 | Flying insect control spray |
| CN105309468A (en) * | 2014-07-22 | 2016-02-10 | 江苏扬农化工股份有限公司 | Pesticide mother liquid, and preparation method and application thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4578833B2 (en) * | 2003-06-30 | 2010-11-10 | 大日本除蟲菊株式会社 | Aerosol composition |
-
1998
- 1998-12-09 JP JP35027398A patent/JP4182239B2/en not_active Expired - Fee Related
-
1999
- 1999-11-30 AR ARP990106073 patent/AR021432A1/en unknown
- 1999-12-08 BR BR9908655-7A patent/BR9908655A/en not_active Application Discontinuation
- 1999-12-09 CN CN 99124758 patent/CN1256074A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101548672A (en) * | 2008-03-31 | 2009-10-07 | 大日本除虫菊株式会社 | Flying insect control spray |
| CN101548672B (en) * | 2008-03-31 | 2013-06-19 | 大日本除虫菊株式会社 | Flying insect control spray |
| CN105309468A (en) * | 2014-07-22 | 2016-02-10 | 江苏扬农化工股份有限公司 | Pesticide mother liquid, and preparation method and application thereof |
| CN105309468B (en) * | 2014-07-22 | 2017-10-20 | 江苏扬农化工股份有限公司 | A kind of insecticide mother liquor and its preparation method and application |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2000169313A (en) | 2000-06-20 |
| BR9908655A (en) | 2000-12-19 |
| AR021432A1 (en) | 2002-07-17 |
| JP4182239B2 (en) | 2008-11-19 |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |