CN1255168A - Invar alloy steel sheet material for shadow mask, method of production thereof, shadow mask and color picture tube - Google Patents
Invar alloy steel sheet material for shadow mask, method of production thereof, shadow mask and color picture tube Download PDFInfo
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- CN1255168A CN1255168A CN98804965A CN98804965A CN1255168A CN 1255168 A CN1255168 A CN 1255168A CN 98804965 A CN98804965 A CN 98804965A CN 98804965 A CN98804965 A CN 98804965A CN 1255168 A CN1255168 A CN 1255168A
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- shadow mask
- invar alloy
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- 229910001374 Invar Inorganic materials 0.000 title claims abstract description 78
- 229910000851 Alloy steel Inorganic materials 0.000 title claims abstract description 37
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 23
- 239000000463 material Substances 0.000 title claims description 56
- 238000000034 method Methods 0.000 title abstract description 12
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 49
- 239000000956 alloy Substances 0.000 claims abstract description 49
- 238000005097 cold rolling Methods 0.000 claims abstract description 23
- 238000000137 annealing Methods 0.000 claims abstract description 16
- 238000007906 compression Methods 0.000 claims description 22
- 230000006835 compression Effects 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 9
- 238000005096 rolling process Methods 0.000 abstract description 6
- 238000005530 etching Methods 0.000 abstract description 3
- 230000010354 integration Effects 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 description 20
- 238000005260 corrosion Methods 0.000 description 20
- 229910000831 Steel Inorganic materials 0.000 description 13
- 239000010959 steel Substances 0.000 description 13
- 238000005516 engineering process Methods 0.000 description 7
- 230000001788 irregular Effects 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 238000010894 electron beam technology Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 238000005098 hot rolling Methods 0.000 description 4
- 238000005482 strain hardening Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 3
- 238000005554 pickling Methods 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 238000005242 forging Methods 0.000 description 2
- 238000009776 industrial production Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000004445 quantitative analysis Methods 0.000 description 2
- 229910000655 Killed steel Inorganic materials 0.000 description 1
- 208000003351 Melanosis Diseases 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 240000005373 Panax quinquefolius Species 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229910000963 austenitic stainless steel Inorganic materials 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000001259 photo etching Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910001256 stainless steel alloy Inorganic materials 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J9/00—Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
- H01J9/02—Manufacture of electrodes or electrode systems
- H01J9/14—Manufacture of electrodes or electrode systems of non-emitting electrodes
- H01J9/142—Manufacture of electrodes or electrode systems of non-emitting electrodes of shadow-masks for colour television tubes
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/004—Very low carbon steels, i.e. having a carbon content of less than 0,01%
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F1/00—Etching metallic material by chemical means
- C23F1/02—Local etching
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0236—Cold rolling
Abstract
An invar alloy steel sheet for a shadow mask having improved etching characteristics, an economical method of production thereof, a shadow mask made from the invar alloy steel sheet, and a color picture tube incorporating the shadow mask. The production method is characterized by hot working a slab of an alloy consisting of 33 to 40 wt.% of Ni and the balance of Fe, applying primary cold rolling at a rolling reduction of not higher than 80 %, annealing the sheet at a temperature not lower than 550 DEG C, and applying further secondary cold rolling at a rolling reduction of not higher than 50 %, so that a planar integration of the {100} plane of the rolled surface is 60 to 80 %.
Description
Technical field
The present invention relates to a kind of shadow mask that is used for making invar alloy steel sheet material for the shadow mask of colour picture tube (hereinafter referred to as CRT) use, its production method, makes by above-mentioned invar alloy steel sheet material and the colour picture tube that above-mentioned shadow mask is housed.More particularly, the present invention relates to a kind of steel sheet that is used for shadow mask, this shadow mask is made by have superior corrosive Invar alloy when forming the some hole (small smooth hole) of shadow mask, relates to the method for producing above-mentioned invar alloy steel sheet material, above-mentioned shadow mask and the colour picture tube of shadow mask is housed.
Prior art
As the material of the shadow mask that uses for colour picture tube, adopt the steel sheet of making by Invar alloy or aluminium killed steel.The production process that is used for the thin plate of the shadow mask that Invar alloy makes is: the fusing Invar alloy, the Invar alloy of casting fusing forges and the above-mentioned alloy of hot rolling, carries out pickling subsequently and grinds de-scaling, after this carries out cold rolling again and annealing.The invar alloy steel sheet material that utilizes photoetching technique to obtain is thus got a hole, can produce plain bonnet like this.After plain bonnet is annealed, pressure forming is desired shape, melanism handles, just can be installed in the colour picture tube.
Shadow mask can serve as the anode of the electron beam of launching from electron beam gun, also can be used as iris, and this moment, its allowed to be launched on the point of the fluorescence coating that spreads on the panel by the electron beam in a hole.About a kind of effect in back, the some hole directly influences sharpness, irregular color or the irregular brightness of the image of colour picture tube demonstration, so they are very high to the requirement of dimensional precision.The point hole constitutes (through hole is hereinafter referred to as Br Th hole) by small-bore part (hereinafter referred to as aperture), wide aperture part (hereinafter referred to as macropore) and connection hole portions.Wherein aperture is positioned at the surface of cover thin plate like the thin dish, and faces cathode is promptly over against electron beam gun; Macropore is positioned at another surface of cover thin plate, and is relative with panel; The two meets aperture and macropore at place, Br Th hole.The function of Br Th hole energy remarkably influenced electron beam iris.
Usually, for the shadow mask of high definition, the thickness that is used for the invar alloy steel sheet material of shadow mask is 100～250 μ m, and the spacing between the center in 2 holes is about 250 μ m.Br Th bore dia respectively is about 120 μ m, and they should rounded and diameter homogeneous.In addition, in view of this function of iris, invar alloy steel sheet material is strict with corrosion surface and is had level and smooth and uniform surfaceness.Thus, be starved of and improve corrosive property, the promptly this corrodibility that is used for the invar alloy steel sheet material of shadow mask.
As improving the corrosive method of invar alloy steel sheet material, in such as Japanese patent application publication No. Hei-2-51973 and disclosed Japanese Patent No. Sho-61-190023, some technology have been proposed, these technology are used for reducing the Invar alloy unavoidable impurities, and these open strictnesses have limited the amount such as C, O and these unavoidable impurities of N.Really, for the high precision corrosion technology that is used to form shadow mask etc., these technology of proposition are very crucial, but only reducing unavoidable impurities can not solve the corrosive all problems of Invar alloy.In addition,, in such as disclosed Japanese Patent Hei-61-39343, Japanese patent gazette Hei-2-9655 and Hei-6-279946, some technology have been proposed, these technology strict control grain-size or crystalline orientation as the method for improving the Invar alloy metallographic structure.These technology have been well-known and also have been important for the corrodibility of improving Invar alloy.For polycrystalline material, crystal grain is thin more, and with regard to crystalline orientation, the chance that produces difference between the grain attack rate can be more little, thereby can make the erosion rate uniformity.In addition, Invar alloy has centroid cubic lattice structure, and it has with austenitic stainless steel is the identical structure of Stainless Steel Alloy in the steel field.As everyone knows, the material of centroid cubic lattice structure, along high atomic density such as { 111} face and { more even when the 100} face corrodes than other face.
Therefore, above-mentioned prior art simply being made up the corrodibility that is not sufficient to make as the Invar alloy of the material for shadow mask of high definition improves.In addition, the Invar alloy that industrial production is this to have fine grain tissue and a crystalline orientation needs complicated Controlling System, and this system runs through processes such as whole cold rolling, annealing, and they have constituted an expensive principal element.Today, strong just day by day for the demand of shadow mask cheaply.From now on, people will seek higher-grade shadow mask and material for shadow mask cheaply.
The problem that the present invention will solve
The object of the present invention is to provide the invar alloy steel sheet material of industrial economy, it can be used as has better corrosive material for shadow mask, the method for producing above-mentioned invar alloy steel sheet material, shadow mask that Invar alloy is made is provided and the colour picture tube of above-mentioned shadow mask is housed.
The method of dealing with problems
Claims 1 are described to be used for basic composition is of invar alloy steel sheet material of material for shadow mask: 33～40%Ni (weight), all the other are Fe, and invar alloy steel sheet material has 60～80% { 110} texture ratio at its rolled surface.
Claims 2 described production methods that are used for the invar alloy steel sheet material material of shadow mask, may further comprise the steps: first hot rolling Invar alloy slab, basic composition is of this slab: 33～40%Ni (weight), all the other are Fe, then the Invar alloy slab after the hot-work is carried out cold rollingly for the first time, its cold-rolled compression ratio is no more than 80%, then anneals under 550 ℃ or higher temperature, subsequently it is carried out secondary cold-rolling, its cold-rolled compression ratio is no more than 50%.
The above-mentioned production method that is used for the invar alloy steel sheet material material of shadow mask, first cold-rolled compression is than preferred 50～80% (as described in claims 3), annealing temperature can preferred 650～950 ℃ (as described in claims 4), and the secondary cold-rolling compression ratio can preferred 0.05～40% (as described in claims 5).
The shadow mask that uses for colour picture tube described in claims 6 has adopted above-mentioned invar alloy steel sheet material.
Claims 7 described colour picture tubes are equipped with above-mentioned shadow mask.
Embodiment preferred
At first, the Ni content in the Invar alloy is restricted to 33～40% (weight).When the Ni content in the Invar alloy is in above-mentioned scope, the thermal expansivity of Invar alloy will significantly reduce.When the shadow mask of being made by this Invar alloy is installed on the colour picture tube like this, even temperature variation does not exist such as problem such as pattern distortion or color be irregular yet.On the contrary, when Ni content less than 33% (weight) or when being higher than 40% (weight), the thermal expansivity of Invar alloy increases, so produce such as problems such as above-mentioned pattern distortion or color are irregular.When invar alloy steel sheet material was used to produce the shadow mask that uses for colour picture tube, its technical problem was how to improve the corrodibility of Invar alloy.Yet when paying the utmost attention to the characteristic of improving the Invar alloy thin plate, it is harsh that the condition of industrial production shadow mask becomes, and production process becomes more complicated.Therefore Industrial processes can access Invar alloy its rolled surface have 60%～80% { in the scope of 110} texture, be necessary to improve its corrodibility.When { when 110} texture surpassed 80%, the corrodibility of Invar alloy improved quite for a short time.At this moment, will increase the cold-rolled compression ratio on the contrary, so just need this Invar alloy of repeat-rolling, thereby prolonged cold rolling cycle time, and delay to produce.In addition, roll is often destroyed owing to the work hardening of Invar alloy, makes production cost strengthen.In addition, the etching system of producing shadow mask has had remarkable improvement recently, and can under high pressure spray high temperature corrosion liquid.That is, mainly by the what is called of in the solubilizing reaction of Invar alloy, carrying out " mechanical erosion " by pressure injection.Therefore, provide the more superior corrosive environment of producing shadow mask.So, in view of the price that will produce shadow mask is reduced to a certain degree requirement, with Invar alloy { 100} texture ratio is restricted to and the highlyest is about 80% and is necessary.Otherwise, when Invar alloy { 100} texture ratio is less than 60% the time, and its corrodibility reduces, so is defined as 60% under it.
According to above-mentioned viewpoint, explain to have 60～80% { production method of the invar alloy steel sheet material of 100} texture ratio below.The Invar alloy of fusing basic composition is: 33～40%Ni (weight), all the other are Fe, and it is cast into steel ingot and forging, or adopt continuous casting to produce slab, are thermally processed into the hot rolling slab subsequently, eliminate segregation simultaneously.By pickling and shredder grinding steel slab surface is carried out de-scaling.After this, slab becomes steel sheet after first cold working, annealing and secondary cold working.This once cold rolling is usually by carrying out cold rolling with roll.For the cost of the rolling surface tissue of Invar alloy and cold-rolled process, compression ratio all is an important factor.From the result of different experiments of the present invention, first cold-rolled compression ratio is preferably 80% or less than this value, and more preferably 50～80%.When compression ratio less than 50% the time, can not obtain at rolled surface that enough { 100} texture ratio only is less than 60% described ratio, is lower than the described { lower limit of 100} texture ratio.Otherwise, even when compression ratio was higher than 80%, { ratio of 100} texture did not obviously increase yet.At this moment, not only increased the load that acts in the operation of rolling in rain, and the destruction of significantly having strengthened breaker roll.Therefore the upper limit of compression ratio is defined as 80%.The annealing of carrying out in temperature more than 550 ℃ or 550 ℃ subsequently its objective is in order to recover the rolling surface tissue and to make its recrystallize.This annealing is to { improvement of 100} texture ratio has effect.When annealing temperature was lower than 550 ℃, recrystallize can not reach required degree and { ratio of 100} texture will significantly reduce.Otherwise, when annealing temperature is higher than 950 ℃, significantly quickened recrystallize, and the crystal grain change being big, this can make Invar alloy thin plate corrodibility reduce.Therefore, preferred annealing temperature is 650～950 ℃.Adopt the purpose of secondary cold-rolling to be to improve hardness and intensity by the work hardening of Invar alloy, like this by annealing obtain a high proportion of { 100} texture can keep getting off, and can give invar alloy steel sheet material required hardness.Therefore, the compression ratio of secondary cold-rolling is defined as 50% or be lower than 50%.When this compression ratio is higher than 50%, by annealing obtain a high proportion of 100} texture can reduce, thus forfeiture annealed effect.Therefore the compression ratio of secondary cold-rolling is preferably 50% or less than 50%, and more preferably 0.05～40%.When compression ratio less than 0.05% the time, the invar alloy steel sheet material behind annealing back and the secondary cold-rolling does not have difference aspect hardness, that is to say, secondary cold-rolling does not have remarkable influence to Invar alloy at this moment.The invar alloy steel sheet material of Sheng Chaning does not have enough hardness and intensity thus, makes the transmission workpiece have problems owing to steel plate distortion or suchlike reason in corrosion process like this.Usually, the hardness that Invar alloy requires is Hv (Vickers' hardness) 130 or is higher than this value, and the hardness of invar alloy steel sheet material of the present invention is Hv130～250.
In addition, the thus obtained invar alloy steel sheet material that is used for shadow mask carries out quantitative analysis { 100} texture ratio by X-ray diffraction method.This analytical procedure comprised for two steps: the first step determine 111}, 100}, 110} and the diffracted intensity of each texture of 311}, and second step by following given formula calculate the ratio of 100} texture:
100} texture ratio (%)=100 * 100}/[111}+{100}+{110}+{311}] (1)
{ 111}, { 100}, { 110} and { 311} represents the corresponding diffracted intensity of each texture herein.
In addition, can adopt corrosion factor to come the corrodibility of quantitative analysis invar alloy steel sheet material.The method of determining corrosion factor comprises: corrode side surface of steel-sheet, calculate the ratio of depth of corrosion and sideetching then.
Corrosion factor=(depth of corrosion)/(sideetching) (2)
By top formula (2), for depth of corrosion (obtaining corrosion length) at the steel sheet thickness direction by jet etching liquid, little sideetching (the corrosion length on the thin sheet surface direction) shows that the material steel sheet has superior corrodibility, that is to say, corrosion factor is high value; Otherwise big sideetching shows that material plate has poor corrodibility, and promptly corrosion factor is a low value.
Compare by the hardness of measuring sheet of material, can determine its mechanical property.Can utilize the Vickers hardness tester that has 100 gram load to measure hardness.
Example
Explain the present invention in more detail with reference to example below.Invar alloy steel sheet material contains the composition of the Sample A that table 1 provides, and with this alloy melting, casting, forging, carries out uniform heating treatment, hot rolling and pickling then, by this order heat production in next life volume steel sheet.Table 2 has provided the production standard of first cold rolling, annealing and secondary cold-rolling respectively.Table 3 has provided the measurement result of the sheet of material characteristic of producing.Hardness is represented with Vickers' hardness (Hv-100).If the hardness of sample thin plate is Hv130 or higher value, evaluation result is labeled as " possibility ".Because generally speaking, steel sheet passes the corrosion service line with the form of band steel, if therefore steel-sheet hardness does not reach Hv130 or the value higher than Hv130, steel sheet can not be normally by the corrosion service line usually.Per-cent is that { per-cent of 100} texture is if { ratio of 100} texture is 50～80%, and evaluation result is labeled as " possibility ".{ ratio of 100} texture is determined by above-mentioned X-ray diffraction method.For corrosion factor, if the value of corrosion factor is 2.6 or higher value, its evaluation result is labeled as " possibility ".In table 3, zero representative " possibility ", * representative " impossible ".The composition of table 1 invar alloy steel sheet material sample
The production standard of table 2 invar alloy steel sheet material
The evaluation result of table 3 sample performance
| Test piece number (Test pc No.) | Composition (weight %) | |||||||||
| ?????C | ?????Si | ???Mn | ?????P | ????????S | ?????N | ????Al | ????Cu | ????Cr | ???Ni | |
| ????A | ??0.0014 | ????0.020 | ??0.23 | ???0.001 | ??????0.0007 | ???0.0025 | ??0.001 | ??0.014 | ??0.013 | ??36.4 |
| Test piece number (Test pc No.) | The production standard | ||||||
| Cold rolling for the first time | Annealing | Secondary cold-rolling | |||||
| Ingoing ga(u)ge | Outgoing gauge | Compression ratio | Temperature | Time | Outgoing gauge | Compression ratio | |
| ?????(mm) | ?????(mm) | ????(％) | ????(℃) | (minute) | ?????(mm) | ?????(％) | |
| ????1 | ?????0.49 | ?????0.230 | ?????53.0 | ????800 | ????5 | ?????0.200 | ?????13.3 |
| ????2 | ?????0.70 | ?????0.150 | ?????78.5 | ????800 | ????5 | ?????0.130 | ?????13.3 |
| ????3 | ?????1.02 | ?????0.203 | ?????80.0 | ????800 | ????5 | ?????0.130 | ?????36.0 |
| ????4 | ?????0.65 | ?????0.131 | ?????80.0 | ????800 | ????5 | ?????0.130 | ?????0.2 |
| ????5 | ?????0.70 | ?????0.150 | ?????78.5 | ????670 | ????5 | ?????0.130 | ?????13.3 |
| ????6 | ?????0.70 | ?????0.150 | ?????78.5 | ????940 | ????5 | ?????0.130 | ?????13.3 |
| ????7 | ?????2.60 | ?????0.130 | ?????95.0 | ????1000 | ????5 | ???????- | ???????- |
| ????8 | ?????1.73 | ?????0.260 | ?????85.0 | ????1000 | ????5 | ?????0.130 | ?????50.0 |
| ????9 | ?????0.70 | ?????0.150 | ?????78.5 | ????500 | ????5 | ?????0.130 | ?????13.3 |
| ????10 | ?????0.31 | ?????0.186 | ?????40.0 | ????800 | ????5 | ?????0.130 | ?????30.0 |
| Test piece number (Test pc No.) | Measurement result | Classification | |||
| Vickers' hardness (Hv-100) | { the per-cent of 100} fabric | Corrosion factor | |||
| ????1 | ??????151 | ????????60 | ?????2.8 | ??????○ | Example |
| ????2 | ??????150 | ????????68 | ?????2.7 | ??????○ | Example |
| ????3 | ??????189 | ????????62 | ?????2.7 | ??????○ | Example |
| ????4 | ??????145 | ????????79 | ?????2.8 | ??????○ | Example |
| ????5 | ??????172 | ????????67 | ?????2.7 | ??????○ | Example |
| ????6 | ??????139 | ????????71 | ?????2.7 | ??????○ | Example |
| ????7 | ??????116 | ????????98 | ?????2.6 | ??????× | Comparative Examples |
| ????8 | ??????196 | ????????58 | ?????2.4 | ??????× | Comparative Examples |
| ????9 | ??????179 | ????????52 | ?????2.5 | ??????× | Comparative Examples |
| ????10 | ??????180 | ????????46 | ?????2.4 | ??????× | Comparative Examples |
Obviously, any in 1～No. 6 Invar alloy sample of the present invention, its material behavior is enough to satisfy standard value separately, and other 7～No. 10 Invar alloy Comparative Examples samples do not satisfy the standard value of one of characteristics such as hardness, per-cent and corrosion factor at least.
The effect of invention
The invar alloy steel-sheet production process that the present invention is used for the shadow mask material is: first hot-working alloy slab in the following order, basic composition is of this alloy slab: 33～40%Ni (weight), all the other are Fe, then carry out the alloy slab after the hot-working cold rolling for the first time, its cold-rolled compression ratio is no more than 80%, then anneal under 550 ℃ or higher temperature, again cold rolling subsequently, its cold-rolled compression ratio is no more than 50%. Therefore, can produce economically the superior corrosive invar alloy sheet metal that has of the present invention. When color picture tube is equipped with the shadow mask that above-mentioned invar alloy sheet metal material makes, have hardly irregular color and irregular brightness, and the definition of the image of screen display is fairly good. A word used in place name
Claims (7)
1, be used for the invar alloy steel sheet material material of shadow mask, it basic composition is: 33～40%Ni (weight), and all the other are Fe, above-mentioned invar alloy steel sheet material has 60～80% { 100} texture ratio at its rolled surface.
2, the production method that is used for the invar alloy steel sheet material material of shadow mask, comprise: first hot-work Invar alloy slab, basic composition is of this alloy slab: 33～40%Ni (weight), all the other are Fe, then the alloy slab after the hot-work is carried out cold rollingly for the first time, its cold-rolled compression ratio is no more than 80%, then under 550 ℃ or higher temperature it is annealed, cold rolling once more subsequently, its cold-rolled compression ratio is no more than 50%.
3, claims 2 described production methods that are used for the invar alloy steel sheet material material of shadow mask, wherein first cold rolling described in compression ratio be 50～80%.
4, claims 2 described production methods that are used for the invar alloy steel sheet material material of shadow mask, wherein said annealing temperature is 650～950 ℃.
5, claims 2 described production methods that are used for the invar alloy steel sheet material material of shadow mask, wherein cold rolling once more described in compression ratio be 0.05～40%.
6, the shadow mask that uses for colour picture tube, it is made by claims 1 described invar alloy steel sheet material material.
7, colour picture tube has wherein been installed claims 6 described shadow masks.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP134473/1997 | 1997-05-09 | ||
| JP13447397 | 1997-05-09 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN01137189A Division CN1132956C (en) | 1997-05-09 | 2001-10-24 | Color kinescope |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1255168A true CN1255168A (en) | 2000-05-31 |
| CN1083495C CN1083495C (en) | 2002-04-24 |
Family
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Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN988049651A Expired - Fee Related CN1083495C (en) | 1997-05-09 | 1998-05-08 | Invar alloy steel sheet material for shadow mask, method of production thereof, shadow mask and color picture tube |
| CN01137189A Expired - Fee Related CN1132956C (en) | 1997-05-09 | 2001-10-24 | Color kinescope |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN01137189A Expired - Fee Related CN1132956C (en) | 1997-05-09 | 2001-10-24 | Color kinescope |
Country Status (6)
| Country | Link |
|---|---|
| KR (1) | KR100519520B1 (en) |
| CN (2) | CN1083495C (en) |
| AU (1) | AU7234898A (en) |
| DE (1) | DE19882379T1 (en) |
| MY (1) | MY123398A (en) |
| WO (1) | WO1998051833A1 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100449025C (en) * | 2003-12-26 | 2009-01-07 | 松下电器产业株式会社 | Material of case for storage cell |
| CN102978361A (en) * | 2012-11-29 | 2013-03-20 | 深圳市欣天科技有限公司 | Thermal treatment process of Invar alloy |
| CN104775077A (en) * | 2015-03-23 | 2015-07-15 | 河北钢铁股份有限公司 | Ultrafine grained invar alloy ribbon and preparation method thereof |
| US20180010231A1 (en) * | 2013-10-15 | 2018-01-11 | Dai Nippon Printing Co., Ltd. | Metal plate |
| CN110499491A (en) * | 2013-09-13 | 2019-11-26 | 大日本印刷株式会社 | The preparation method of coiling body and the manufacturing method of deposition mask |
| US10570498B2 (en) | 2015-02-10 | 2020-02-25 | Dai Nippon Printing Co., Ltd. | Manufacturing method for deposition mask, metal plate used for producing deposition mask, and manufacturing method for said metal sheet |
| US10600963B2 (en) | 2014-05-13 | 2020-03-24 | Dai Nippon Printing Co., Ltd. | Metal plate, method of manufacturing metal plate, and method of manufacturing mask by using metal plate |
| CN111842527A (en) * | 2020-06-24 | 2020-10-30 | 江苏圣珀新材料科技有限公司 | Cold rolling process for LNG liquefied injection ship plate 4J36 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3740105B2 (en) * | 2001-11-20 | 2006-02-01 | 日鉱金属加工株式会社 | Fe-Ni and Fe-Ni-Co alloy strips for shadow mask |
| CN100451156C (en) * | 2007-04-27 | 2009-01-14 | 上海工程技术大学 | RE Invar alloy and its production process |
| EP2031082B1 (en) * | 2007-08-31 | 2014-09-03 | Aperam Alloys Imphy | Metal substrate with crystallographic texture, crystallographic texture device, photovoltaic cell and module comprising such a device and method of depositing fine layers |
| CN107119234B (en) * | 2017-05-11 | 2019-01-18 | 东北大学 | A kind of refined crystalline strengthening method of invar alloy band |
| KR102300029B1 (en) * | 2017-07-27 | 2021-09-09 | 삼성디스플레이 주식회사 | Mask frame assembly, method for manufacturing the same and method for manufacturing a display apparatus using the same |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6452022A (en) * | 1987-08-19 | 1989-02-28 | Nippon Mining Co | Production of shadow mask material |
| JPH06158229A (en) * | 1992-09-24 | 1994-06-07 | Nkk Corp | Fe-ni alloy thin sheet and fe-ni-co alloy thin sheet for shadow mask excellent in press formability |
-
1998
- 1998-05-07 MY MYPI98002039A patent/MY123398A/en unknown
- 1998-05-08 AU AU72348/98A patent/AU7234898A/en not_active Abandoned
- 1998-05-08 KR KR10-1999-7010362A patent/KR100519520B1/en not_active IP Right Cessation
- 1998-05-08 CN CN988049651A patent/CN1083495C/en not_active Expired - Fee Related
- 1998-05-08 DE DE19882379T patent/DE19882379T1/en not_active Ceased
- 1998-05-08 WO PCT/JP1998/002051 patent/WO1998051833A1/en active IP Right Grant
-
2001
- 2001-10-24 CN CN01137189A patent/CN1132956C/en not_active Expired - Fee Related
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7515395B2 (en) | 2003-12-26 | 2009-04-07 | Panasonic Corporation | Material of case for storage cell |
| CN100449025C (en) * | 2003-12-26 | 2009-01-07 | 松下电器产业株式会社 | Material of case for storage cell |
| CN102978361A (en) * | 2012-11-29 | 2013-03-20 | 深圳市欣天科技有限公司 | Thermal treatment process of Invar alloy |
| US10731261B2 (en) | 2013-09-13 | 2020-08-04 | Dai Nippon Printing Co., Ltd. | Metal plate, method of manufacturing metal plate, and method of manufacturing mask by use of metal plate |
| CN110499491A (en) * | 2013-09-13 | 2019-11-26 | 大日本印刷株式会社 | The preparation method of coiling body and the manufacturing method of deposition mask |
| US11486031B2 (en) | 2013-10-15 | 2022-11-01 | Dai Nippon Printing Co., Ltd. | Metal plate |
| US20180010231A1 (en) * | 2013-10-15 | 2018-01-11 | Dai Nippon Printing Co., Ltd. | Metal plate |
| US10600963B2 (en) | 2014-05-13 | 2020-03-24 | Dai Nippon Printing Co., Ltd. | Metal plate, method of manufacturing metal plate, and method of manufacturing mask by using metal plate |
| US11217750B2 (en) | 2014-05-13 | 2022-01-04 | Dai Nippon Printing Co., Ltd. | Metal plate, method of manufacturing metal plate, and method of manufacturing mask by using metal plate |
| US10570498B2 (en) | 2015-02-10 | 2020-02-25 | Dai Nippon Printing Co., Ltd. | Manufacturing method for deposition mask, metal plate used for producing deposition mask, and manufacturing method for said metal sheet |
| US10612124B2 (en) | 2015-02-10 | 2020-04-07 | Dai Nippon Printing Co., Ltd. | Manufacturing method for deposition mask, metal plate used for producing deposition mask, and manufacturing method for said metal sheet |
| CN104775077A (en) * | 2015-03-23 | 2015-07-15 | 河北钢铁股份有限公司 | Ultrafine grained invar alloy ribbon and preparation method thereof |
| CN111842527A (en) * | 2020-06-24 | 2020-10-30 | 江苏圣珀新材料科技有限公司 | Cold rolling process for LNG liquefied injection ship plate 4J36 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1132956C (en) | 2003-12-31 |
| CN1376807A (en) | 2002-10-30 |
| DE19882379T1 (en) | 2000-05-25 |
| KR100519520B1 (en) | 2005-10-05 |
| CN1083495C (en) | 2002-04-24 |
| WO1998051833A1 (en) | 1998-11-19 |
| KR20010012409A (en) | 2001-02-15 |
| MY123398A (en) | 2006-05-31 |
| AU7234898A (en) | 1998-12-08 |
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