CN1254515C - Brightening aqueous ink composition - Google Patents
Brightening aqueous ink composition Download PDFInfo
- Publication number
- CN1254515C CN1254515C CNB011226617A CN01122661A CN1254515C CN 1254515 C CN1254515 C CN 1254515C CN B011226617 A CNB011226617 A CN B011226617A CN 01122661 A CN01122661 A CN 01122661A CN 1254515 C CN1254515 C CN 1254515C
- Authority
- CN
- China
- Prior art keywords
- water
- weight
- aluminium powder
- ink composition
- printing ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 45
- 238000005282 brightening Methods 0.000 title 1
- 239000000049 pigment Substances 0.000 claims abstract description 130
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 96
- 239000000839 emulsion Substances 0.000 claims abstract description 47
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 43
- 239000000057 synthetic resin Substances 0.000 claims abstract description 43
- 239000003960 organic solvent Substances 0.000 claims abstract description 20
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 17
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 17
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000005642 Oleic acid Substances 0.000 claims abstract description 17
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 17
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 17
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 17
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 17
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 17
- 239000008117 stearic acid Substances 0.000 claims abstract description 17
- 239000007787 solid Substances 0.000 claims abstract description 9
- 150000004676 glycans Chemical class 0.000 claims abstract description 7
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 7
- 239000005017 polysaccharide Substances 0.000 claims abstract description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 102
- 239000004411 aluminium Substances 0.000 claims description 93
- 239000000843 powder Substances 0.000 claims description 93
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 61
- 229920005989 resin Polymers 0.000 claims description 56
- 239000011347 resin Substances 0.000 claims description 56
- 239000000463 material Substances 0.000 claims description 40
- 238000000034 method Methods 0.000 claims description 23
- 238000000227 grinding Methods 0.000 claims description 17
- 238000010298 pulverizing process Methods 0.000 claims description 14
- 239000002131 composite material Substances 0.000 claims description 12
- 239000004033 plastic Substances 0.000 claims description 6
- 229920003023 plastic Polymers 0.000 claims description 6
- 229920002310 Welan gum Polymers 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 239000011230 binding agent Substances 0.000 claims description 5
- 239000000470 constituent Substances 0.000 claims description 5
- YARNEMCKJLFQHG-UHFFFAOYSA-N prop-1-ene;styrene Chemical compound CC=C.C=CC1=CC=CC=C1 YARNEMCKJLFQHG-UHFFFAOYSA-N 0.000 claims description 5
- 239000002966 varnish Substances 0.000 claims description 5
- XEKOWRVHYACXOJ-UHFFFAOYSA-N ethyl acetate Substances CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 230000033444 hydroxylation Effects 0.000 claims 2
- 238000005805 hydroxylation reaction Methods 0.000 claims 2
- -1 acryl Chemical group 0.000 abstract description 11
- 150000001875 compounds Chemical class 0.000 abstract description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002245 particle Substances 0.000 description 48
- 239000000047 product Substances 0.000 description 19
- 239000002585 base Substances 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 9
- 239000006185 dispersion Substances 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- 239000000975 dye Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000003292 glue Substances 0.000 description 6
- 239000000123 paper Substances 0.000 description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 125000000129 anionic group Chemical group 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000001055 blue pigment Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 239000000314 lubricant Substances 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- RQAKESSLMFZVMC-UHFFFAOYSA-N n-ethenylacetamide Chemical compound CC(=O)NC=C RQAKESSLMFZVMC-UHFFFAOYSA-N 0.000 description 3
- 150000003014 phosphoric acid esters Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229920006186 water-soluble synthetic resin Polymers 0.000 description 3
- 239000012866 water-soluble synthetic resin Substances 0.000 description 3
- 229920002307 Dextran Polymers 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001398 aluminium Chemical class 0.000 description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 2
- 239000012964 benzotriazole Substances 0.000 description 2
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 210000000282 nail Anatomy 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000011342 resin composition Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- CSNIZNHTOVFARY-UHFFFAOYSA-N 1,2-benzothiazole Chemical class C1=CC=C2C=NSC2=C1 CSNIZNHTOVFARY-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- QCAHUFWKIQLBNB-UHFFFAOYSA-N 3-(3-methoxypropoxy)propan-1-ol Chemical compound COCCCOCCCO QCAHUFWKIQLBNB-UHFFFAOYSA-N 0.000 description 1
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- 229920000945 Amylopectin Polymers 0.000 description 1
- OAEXPGQVOUEDAC-UHFFFAOYSA-N C1(=CC=CC=C1)O.ClC=1C(=C(C(=C(C1)Cl)Cl)Cl)Cl Chemical class C1(=CC=CC=C1)O.ClC=1C(=C(C(=C(C1)Cl)Cl)Cl)Cl OAEXPGQVOUEDAC-UHFFFAOYSA-N 0.000 description 1
- 235000007627 Caesalpinia Nutrition 0.000 description 1
- 241000522234 Caesalpinia Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 108010076119 Caseins Proteins 0.000 description 1
- 241000065610 Cotinus Species 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- 241000446313 Lamella Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000004218 Orcein Substances 0.000 description 1
- 244000090599 Plantago psyllium Species 0.000 description 1
- 235000010451 Plantago psyllium Nutrition 0.000 description 1
- 241000011547 Plebejus idas Species 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- 229920013701 VORANOL™ Polymers 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000001118 alkylidene group Chemical group 0.000 description 1
- 239000000420 anogeissus latifolia wall. gum Substances 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000011013 aquamarine Substances 0.000 description 1
- 239000000305 astragalus gummifer gum Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 150000001896 cresols Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- XBPCUCUWBYBCDP-UHFFFAOYSA-O dicyclohexylazanium Chemical compound C1CCCCC1[NH2+]C1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-O 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 210000004709 eyebrow Anatomy 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 235000019314 gum ghatti Nutrition 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052816 inorganic phosphate Inorganic materials 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 235000019248 orcein Nutrition 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011085 pressure filtration Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 210000004906 toe nail Anatomy 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
- C09D11/17—Writing inks characterised by colouring agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B43—WRITING OR DRAWING IMPLEMENTS; BUREAU ACCESSORIES
- B43K—IMPLEMENTS FOR WRITING OR DRAWING
- B43K7/00—Ball-point pens
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
- C09D11/18—Writing inks specially adapted for ball-point writing instruments
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention provides the aqueous glittering ink composition comprising the following compounds shown as a to e with respect to the total amount of the ink composition (a) about 0.01 to about 20% by weight of aluminum powder pigments whose median diameter is not less than about 15 mum compounded with oleic acid and/or stearic acid; (b) about 0.1 to about 40% by weight (in solids) of synthetic resin emulsions selected from acryl based synthetic resin emulsions, styrene-acryl based synthetic resin emulsions and vinyl acetate based synthetic resin emulsions; (c) about 0.01 to about 40% by weight of polysaccharide selected from whelan gum, succinoglycan, and rhamsan gum; (d) about 1 to about 40% by weight of water-soluble organic solvent; and (e) about 0.05 to about 15% by weight of colored pigment.
Description
The present invention relates to a kind of bright water printing ink composition that is adapted at using in the ballpoint pen.
In the prior art, be useful on obtain having gold, the bright water printing ink composition of the person's handwriting of metalluster color such as silver color.For example, the open communique of Japan's special permission discloses the surface-treated aluminium powder pigment has been carried out in a kind of use with stearic acid aqueous ink composition 1996 No. 151547.The open communique of Japan special permission nineteen ninety-five discloses a kind of aqueous ink composition that uses pearl pigment No. 118592.
Yet existing these use the aqueous ink composition of aluminium powder pigment or pearl pigment to be difficult to obtain having the person's handwriting of strong light sense.
The objective of the invention is, a kind of like this bright water printing ink composition that is used for ballpoint pen etc. is provided, it is compared with in the past the use aluminium powder pigment or the aqueous ink composition of pearl pigment, can obtain having the more person's handwriting of the bright sense of high light.
For achieving the above object, the present inventor has carried out deep research, found that, when aluminium powder pigment through being that the pulverization process of grinding aid and its median size are when (being 30-60 μ m better) with oleic acid more than 15 μ m, to contain this aluminium powder pigment and water soluble resin, the bright water printing ink composition of water-miscible organic solvent and water is used for writing appliances such as ballpoint pen, its printing ink person's handwriting will manifest the sense of intensive light. and find, when aluminium powder pigment through being that the pulverization process of grinding aid and its median size are when (being 30-60 μ m better) with the stearic acid more than 15 μ m, to contain this aluminium powder pigment and water soluble resin, the bright water printing ink composition of water-miscible organic solvent and water is used for writing appliances such as ballpoint pen, and its printing ink person's handwriting also can manifest the sense of intensive light.
The aqueous ink composition of the present invention that will have an above-mentioned composition is used for writing appliance such as ballpoint pen to be write, and its person's handwriting can manifest the sense of intensive light.
Aluminium powder pigment
The aluminium powder pigment that uses among the present invention for example obtains as aluminum paste (being commonly called as aluminium paste) by the following method: oleic acid or stearic acid are mixed in the mineral spirits and with it as grinding aid disperse the back pulverize with ball mill. and in addition, for example preferably use by in above-mentioned aluminum paste, adding and the water-resisting type aluminum slice slurry (water-resisting type aluminium powder pigment or water-resisting type aluminum slice color compositions) that obtains such as in mixing tank, mix behind inorganic phosphate, fatty compounds, tensio-active agent, water, the pure and mild hydrocarbon ils of hydratability.Generally speaking, so long as the aluminium powder pigment of crossing as the grinding aid pulverization process with oleic acid or stearic acid then can be any.
If the aluminium powder pigment of pulverizing as grinding aid with oleic acid; then since oleic acid the absorption of aluminium powder pigment particle surface become thick and polarity also big; person's handwriting that forms or the right and wrong of filming (metal-powder) are floated (non-leafing) type; aluminium powder pigment is at person's handwriting or in filming; thus, each aluminium powder pigment exists with various angular orientation.On the other hand; if the aluminium powder pigment that replaces above-mentioned oleic acid to pulverize with stearic acid as grinding aid; then stearic acid the absorption of aluminium powder pigment particle surface become intensive and polarity little, like this, the person's handwriting of formation or to film be that (metal-powder) floats (leafing) type.In above-mentioned situation, because the surface that aluminium powder pigment concentrates on person's handwriting or films, therefore, the orientation of each aluminium powder pigment particle is parallel with person's handwriting or coated surface basically.But has polar resin (varnish resin) owing to contain; same with the above-mentioned aluminium powder pigment of pulverizing as grinding aid with oleic acid; become non-floating type person's handwriting or film and aluminium powder pigment at person's handwriting or in filming, therefore, each aluminium powder pigment exists with various angular orientation.That is, if the aluminium powder pigment of pulverizing as grinding aid with stearic acid, then contain make aluminium powder pigment not buoyant have polar or highly oxidized resin is very important.The useful alkaline neutraliser of the example of these resins has carried out electrolysis, has imported hydroxyl, ether, carried out water soluble resins such as hydroxylated Synolac, melmac.
In addition, in the present invention, for the person's handwriting that makes ballpoint pen etc. shows the sense of intensive light, the median size of aluminium powder pigment particle is more than 15 μ m, and the big particle diameter that is preferably 30-60 μ m also is very important.If less than 15 μ m, even then aluminium powder pigment is orientated with float state at person's handwriting or in filming, but owing to the person's handwriting as ball pen ink, its thin slice particle is too small, and therefore, light is poor.And if surpass 60 μ m, even then adjust the content and the ball diameter of above-mentioned aluminium powder pigment, when using as ball pen ink, be difficult for from nib flowing out, be unfavorable therefore.If the particle diameter of above-mentioned big particle diameter aluminium powder pigment is 30 μ m or surpasses 30 μ m, then can make more intensive light sense of person's handwriting.
15 μ m), " WXM7640 " that produce of japan Aluminum Co., Ltd (median size: 17 μ m), " WXM5422 " (median size: 19 μ m), " WXM1440 " (median size: 30 μ m), " WXM1415 " (median size: 51 μ m), " WXM7493 " (median size: 60 μ m) such aluminium powder pigment for example has following commodity: " AW7000R " that Asahi Kasei Corporation produces (median size:.The aluminium powder pigment that these median sizes are different can use separately, also can share more than two kinds.
In the present invention, " median size " is meant the diameter with the D50 value representation that gets with laser diffraction formula size-grade distribution instrumentation.
Above-mentioned big particle diameter aluminium powder pigment preferably accounts for the 0.01-2 weight % of ink composite gross weight.If less than 0.01 weight %, light deficiency then, and if surpass 20 weight %, then ink viscosity is excessive, mobile descends, writing property of influence.Consider that light and printing ink flow out property (outflow of printing ink between ball and the ball seat that is fixed), the optimal mixing amount of above-mentioned big particle diameter aluminium powder pigment is 0.05-10 weight %
Water soluble resin
As water soluble resin, importantly, use can be adjusted ink viscosity and can make big particle diameter aluminium powder pigment and tinting material disperses and prevents its settled water-soluble tackifying resin, especially can make printing ink have pseudoplastic fluid dynamic characteristic (thixotropy) water soluble resin.An one example is the polysaccharide and the derivative thereof of microorganisms producing.For example, amylopectin, xanthan gum, Welland (welan) glue, Lei Sang (rhamsan) glue, succinoglucan, dextran etc.Also can use water-soluble plant is polysaccharide and derivative thereof.For example, tragacanth gum, guar gum, Caesalpinia spinosaKuntze glue, Viscogum BE, ghatti gum, arabogalactan glue, gum arabic, smoke tree glue, pectin, starch, psyllium seed glue, carrageenan, Lalgine, agar etc.In addition, can use water soluble animal is polysaccharide and derivative thereof.For example, gelatin, casein, albumin.In addition, as tackifying resin, can use N-vinyl acetamide resin, crosslinked N-vinyl acetamide resins such as N-vinyl acetamide resin.
In the present invention, in above-mentioned water soluble resin, suitable especially is the polysaccharide and the derivative thereof of microorganisms producing.In addition, above-mentioned water soluble resin can use separately, also can share more than two kinds.
These water soluble resins preferably account for the 0.01-40% of total weight.As less than 0.01%, prevent that then the settled effect of big particle diameter aluminium powder pigment is not enough; And if surpass 40%, then ink viscosity is excessive, mobile decline.The optimal mixing amount of water soluble resin is according to its kind and slightly variant, but is generally 0.05-20 weight %.
In above-mentioned water soluble resin, especially the white acyl dextran of Welan gum, Leisang plastic and the amber big particle diameter aluminium powder pigment that can make median size (be preferably 30-60 μ m) more than 15 μ m disperses well, is stable in the printing ink, and makes the printing ink that contains big particle diameter aluminium powder pigment have good pseudoplastic fluid dynamic characteristic (thixotropy).
Water-miscible organic solvent
Used water-miscible organic solvent can prevent that preferably ballpoint tip drying and printing ink from freezing.Its example comprises glycols such as ethylene glycol, glycol ether, triglycol, propylene glycol, polyoxyethylene glycol, polyalcohols such as glycerol, gylcol ethers such as ethylene glycol monomethyl ether, diethylene glycol monomethyl ether, dipropylene glycol monomethyl ether, dipropylene glycol list propyl ether.These organic solvents can use separately, also can share more than two kinds.
Water-miscible organic solvent should account for the 1-40% of total weight.As less than 1%, then nib is easily dry, and the printing ink easy freezing; And if surpass 40%, then can the solvability of above-mentioned water soluble resin be exerted an influence, and person's handwriting is difficult to drying.The optimal mixing amount of water-miscible organic solvent is according to its kind and slightly variant, but is generally 5-20 weight %.
Tinting material
Tinting material does not preferably react and can not influence the light of these aluminium powder pigments with above-mentioned big particle diameter aluminium powder pigment.Specifically, except water-soluble dyes such as matching stain, substantive dyestuff and basic dyestuff, can use mineral dyes such as carbon black, copper phthalocyanine, intellectual circle's pigment, azo pigment, quinacridone pigment, anthraquinone pigment, diox pigment, indigo pigment, thioindigo color, scratch organic dye such as blue intellectual circle's pigment, pigment, Indolenone dyestuff, azomethine dyes, also can use fluorescence dye, pigmentary resin emulsion etc.In addition, also these pigment can be used as pigment dispersion.In the present invention, these pigment can use separately, also can share more than two kinds.In addition, light mix particles such as big particle diameter aluminium powder pigment of the present invention and pearl pigment can be used.Also can will have concealed titanium oxide, two trimeric cyanamide (alkylenebismelamine) derivatives of alkylidene group, disguised pigment such as various inorganic or organic white pigments such as the plastic pigments (synthetic resins particle pigment) of different shapes such as spherical, flats share.In addition, also the mineral dye of aluminium powder pigment with metallic cover can be used.
In aqueous ink composition of the present invention, be not to contain tinting material.Even the water color ink that does not contain tinting material but contain aluminium powder pigment also can make person's handwriting produce the sense of intensive light.But the above-mentioned aqueous ink composition that contains tinting material can be by tinting material tone etc. person's handwriting is produced and corresponding colored strong lights such as its tone, therefore, be very suitable.
Tinting material should account for the 0.05-15% of total weight.As less than 0.05%, then be difficult to find out the painted of this tinting material; And if surpass 15%, then ink viscosity is excessive, mobile decline.The optimal mixing amount of tinting material is according to its kind and slightly variant, but is generally 1-10 weight %.
Synthetic resin emulsion
As mentioned above, the present inventor is the person's handwriting that obtains having strong light sense, and discovery should be used the big particle diameter aluminium powder pigment of crossing as the grinding aid pulverization process with oleic acid and stearic acid in the ink composite that contains water-soluble tackifying resin, water-miscible organic solvent and water.Compare with pearl pigment with the small particle size aluminium powder pigment of crossing for the grinding aid pulverization process with other lipid acid or mineral acid, use above-mentioned big particle diameter aluminium powder pigment can make person's handwriting produce stronger light sense.
Yet, contain water soluble resin (especially water-soluble tackifying resin) though bright water-thinned printing ink can improve the adhesivity of above-mentioned big particle diameter aluminium powder pigment by water-soluble tackifying resin to a certain extent, but the present inventor finds, because the shape of above-mentioned big particle diameter aluminium powder pigment is big, therefore, be difficult to big particle diameter aluminium powder pigment be adhered on the base material securely with water-soluble tackifying resin.Therefore, after writing with the water color ink that contains above-mentioned big particle diameter aluminium powder pigment, above-mentioned big particle diameter aluminium powder pigment can be easily because friction waits peel off, be difficult to make person's handwriting to produce the sense of intensive light constantly, have the poor durability of the person's handwriting that light feels.
Given this, provide water color ink with following characteristic (especially writing appliance use, the bright water-thinned printing ink used of ballpoint pen specifically) become an important problem: this bright water-thinned printing ink can not make ink characteristics and write suitability and descend, and can not hinder the intensive light sense effect that produces by mixing above-mentioned big particle diameter aluminium powder pigment, can improve the adhesivity of above-mentioned big particle diameter aluminium powder pigment, make person's handwriting produce stronger light sense constantly base material.
For finishing above-mentioned problem, the present inventor has carried out deep research, found that, contain as above-mentioned big particle diameter aluminium powder pigment, water soluble resin, water-miscible organic solvent and water that must composition and also contain and make above-mentioned big particle diameter aluminium powder pigment adhere to paper applied things such as (as write and use paper) to finish above-mentioned problem with the bright water-thinned printing ink of the binder constituents (adhered resin composition) that is replicated base material such as thing.
On the other hand, adhere to applied thing securely, be replicated on the base materials such as thing, can consider to use water-soluble synthetic resin as binder constituents in order to make so big particle diameter aluminium powder pigment.But, if big particle diameter aluminium powder pigment is adhered to securely, improve its content according to the kind of water-soluble synthetic resin, then may produce detrimentally affect to the solvability of tackifying resin, the dispersiveness of tinting material.In addition, the visco-elasticity of printing ink is descended significantly, suitability is write in influence.In addition, even applied thing, the adhesivity that is replicated base materials such as thing are obtained performance, but if the intensive light sense of above-mentioned big particle diameter aluminium powder pigment in person's handwriting descended, then such water color ink remains unfavorable.
The present inventor further in depth studies, found that, if use synthetic resin emulsion as making above-mentioned big particle diameter aluminium powder pigment adhere to applied thing, being replicated the binder constituents on the base material such as thing, then can improve above-mentioned big particle diameter aluminium powder pigment to the adhesivity of for example paper base materials such as (as write and use paper) and can not make it lose light, and finish the present invention thus.
Therefore, with the above-mentioned aqueous ink composition of the present invention that contains big particle diameter aluminium powder pigment at applied thing, be replicated on the thing base materials such as (as paper, metal, plastics, fibre products etc.) write or be coated with, when duplicating, can improve big particle diameter aluminium powder pigment to applied thing, be replicated the adhesivity of base materials such as thing, make person's handwriting have weather resistance, and can make person's handwriting continue to produce the sense of intensive light.This is the big particle diameter aluminium powder pigment that the film sexual compatibility has big lamella shape of making owing to synthetic resin emulsion, can not hinder the intensive light sense that produces by mixing above-mentioned big particle diameter aluminium powder pigment, make big particle diameter aluminium powder pigment can adhere to applied thing securely, be replicated due to the base material such as thing.
And, because binder constituents of the present invention (adhered resin composition) is not a water-soluble synthetic resin, but synthetic resin emulsion, therefore, it is less that the characteristics such as visco-elasticity of the dispersiveness of the solvability of the water-soluble tackifying resin that mixes simultaneously, tinting material and printing ink are produced dysgenic situation.Thus, the color that printing ink of the present invention can not influence ink viscosity, write suitability and person's handwriting can improve the adhesivity of above-mentioned big particle diameter aluminium powder pigment.
According to above-mentioned situation, the bright water-thinned printing ink that contains above-mentioned big particle diameter aluminium powder pigment of the present invention can not make ink characteristics and write decline such as suitability, and can not hinder the height surface smoothness that glass has, compare with the aqueous ink composition of bright pigment such as existing use aluminium powder pigment, pearl pigment, can make person's handwriting continue to produce stronger light sense.
Synthetic resin emulsion of the present invention is not particularly limited, so long as the synthetic resin emulsion of water dispersible gets final product.But consider ink characteristics and write suitability that used synthetic resin emulsion should not influence solvability, the ink viscosity of water-soluble tackifying resin, the dispersiveness and the printing ink colour developing of tinting material.In addition, can not hinder the intensive light sense effect that produces by mixing big particle diameter aluminium powder pigment.
In addition, the minimum film temperature of making of synthetic resin emulsion should be below 20 ℃.If the minimum film temperature of making of synthetic resin emulsion is below 20 ℃, especially below 0 ℃, much less (about 25 ℃) are then at normal temperatures, even in the place of cold, also can form film, thereby can improve the adhesivity of person's handwriting to base material.
Also have, synthetic resin emulsion preferably has anionic property or nonionic.Synthetic resin emulsion with anionic property or nonionic for example can be by making synthetic resins by anionic property or non-ionic monomer or obtaining by use anionic property or non-ionic emulsifier.Use has the synthetic resin emulsion of anionic property or nonionic, can improve the stability of printing ink.
Have, synthetic resin emulsion should be worked as printing ink pH can not affect the dispersiveness of toner and the solvability of water-soluble tackifying resin when above 6 again.
Consider that from above-mentioned angle used synthetic resin emulsion for example can be acrylic acid or the like synthetic resin emulsion, styrene-propene acids synthetic resin emulsion, vinyl-acetic ester class synthetic resin emulsion.The suitable example of acrylic acid or the like synthetic resin emulsion has the acrylate copolymer synthetic resin emulsion.The suitable example of styrene-propene acids synthetic resin emulsion has the copolymer in cinnamic acrylic ester synthetic resin emulsion.In addition, for example vinyl-acetic ester synthetic resin emulsion, vinyl-acetic ester-acrylate copolymer synthetic resin emulsion are the vinyl-acetic ester class synthetic resin emulsions that suits.These synthetic resins can use separately, also can share more than two kinds.
Specifically, the example of acrylic acid or the like synthetic resin emulsion comprises the commodity " Nikasol FX336 " by name that Japanese Carbide Industrial Co., Ltd produces (minimum film temperature＜0 ℃ of making, pH 7.5,200mPas), commodity are called " Nikasol A-02 " (minimum film temperature＜0 ℃ of making, pH 7.0,500mPas), commodity are called " Nikasol FH-011A " (minimum film temperature＜0 ℃ of making, pH 7.0,150mPas) and the commodity " Mowinyl 231 " by name produced of ClariantPolymer company (minimum film temperature＜0 ℃ of making, pH 4.0, viscosity 500-1500mPas) synthetic resin emulsion etc.Above-mentioned viscosimetric analysis is at 25 ℃ of numerical value that record with Brookfield viscometer.
Content to synthetic resin emulsion does not have special restriction, for example, in solid content, should account for the 0.1-40% of total weight.As less than 0.1%, then above-mentioned big particle diameter aluminium powder pigment descends to the adhesivity of base material; And if surpass 40%, then solid content is excessive, can membranization etc. occur being coated with at nib, and suitability is write in influence.In addition, the easy whitening of person's handwriting.For further improving the adhesivity of above-mentioned big particle diameter aluminium powder pigment to base material, synthetic resin emulsion preferably accounts at least 0.3% of total weight (in solid content).In addition, write suitability for further improving, synthetic resin emulsion preferably accounts for 20% of total weight (in solid content).That is, the optimum content of synthetic resin emulsion is 0.3-20 weight %.
According to above-mentioned situation, according to the bright water printing ink composition of embodiment of the present invention with contain following composition a～e (its content is to account for the proportional meter of ink composite gross weight), viscosity is 1,000-10,000mPas (ELD type viscometer, 3 ° of R14 circular cones, 0.5rpm, 20 ℃) the water color ink of claim 1 be good.
A.0.01-20 weight %'s is the aluminium powder pigment of median size more than 15 μ m that the grinding aid pulverization process is crossed with oleic acid and/or stearic acid,
B.0.1-40 the synthetic resin emulsion that is selected from acrylic resin emulsion, styrene-propene acid resin emulsion and vinyl-acetic ester resin emulsion of weight % (solid content),
C.0.01-40 the polysaccharide that is selected from Welan gum, succinoglucan and Leisang plastic of weight %,
D.1-40 the water-miscible organic solvent of weight %,
E.0.05-15 the tinting pigment of weight %.
Other additives
In addition, in the present invention, optionally, can add lubricants such as polyoxyethylene an alkali metal salt, dicarboxylic acid acid amides, phosphoric acid ester, N-oleoyl sarcosinates, rust-preventive agent such as benzotriazole, nitric acid tolyl-triazole dicyclohexyl ammonium, Antisepticize and mildew preventives such as benzisothiazole class, pentachlorobenzene phenols, cresols have all ingredients of surfactivity effect etc. to above-mentioned big particle diameter aluminium powder pigment.
The preferred viscosity ranges of aqueous ink composition of the present invention is 1,000-10,000mPas.Ink composite of the present invention is adjusted according to above-mentioned range of viscosities.This viscosity is the numerical value that records with ELD type viscometer (3 ° of R14 circular cones, rotation number: 0.5rpm, 20 ℃).
The making method of printing ink
Can pass through making printing ink such as known dispersing method, defoaming method, filter method so far, but the method for stating below the input method is good.Promptly, after with turning circle disc type whipping up agent etc. water, water-miscible organic solvent, light aluminium powder pigment and tinting material being disperseed under the room temperature, drop into water soluble resin, adhered resin, optionally add various additives, and optionally adjust pH, the gained mixture is filtered by pressure filtration etc., and deaeration then obtains bright water-thinned printing ink.
Embodiment
Press shown in the table 1 and form and incorporation (weight %), after with above-mentioned manufacture method the big particle diameter aluminium powder pigment of water, water-miscible organic solvent, regulation and each composition such as tinting material or pigment base-material being mixed, stir, disperse, drop into water soluble resin, the gained mixture is filtered the back deaeration, obtain the bright water printing ink composition of embodiment.In addition, as shown in table 2, in order to compare, after each composition mixing such as water, water-miscible organic solvent, small particle size aluminium powder pigment and pearl pigment, stirring, disperse, drop into water soluble resin, the gained mixture is filtered the back deaeration, obtain the aqueous ink composition of comparative example.In embodiment and comparative example, dispersing method, defoaming method, filter method etc. all adopt known method so far.
Table 1 (weight %)
| Embodiment | ||||||||||||||||
| 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 | 12 | 13 | 14 | 15 | ||
| Aluminium powder pigment | I | 4.0 | 4.0 | 4.0 | 4.0 | |||||||||||
| II | 4.0 | 4.0 | 4.0 | 4.0 | ||||||||||||
| III | 4.0 | 4.0 | 4.0 | 4.0 | ||||||||||||
| IV | ||||||||||||||||
| V | 4.0 | 4.0 | 4.0 | |||||||||||||
| Pearl pigment | ||||||||||||||||
| Water soluble resin | I | 0.3 | 0.3 | 0.3 | 0.3 | 0.4 | 0.4 | 0.4 | ||||||||
| II | 0.4 | 0.4 | 0.4 | 0.4 | ||||||||||||
| III | 0.3 | 0.3 | 0.3 | 0.3 | ||||||||||||
| IV | 0.3 | 0.3 | 0.3 | |||||||||||||
| Adhered resin | I | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | ||||||
| II | 12.0 | 12.0 | 12.0 | |||||||||||||
| Water-miscible organic solvent | I | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 |
| II | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | |
| Tinting material | I | 2.0 | 2.0 | 2.0 | 2.0 | 2.0 | ||||||||||
| II | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | |||||||||||
| Antisepticize and mildew preventive | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | |
| The agent of anti-embroidery | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | |
| Lubricant | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
| The bright pigment dispersion agent | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | |
| Water | 56.4 | 54.4 | 55.6 | 54.3 | 55.5 | 56.3 | 55.6 | 56.4 | 54.4 | 56.4 | 54.3 | 55.6 | 71.3 | 69.3 | 70.5 | |
| Meter | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | |
| The light sense | ○ | ○ | ○ | ○ | ○ | ○ | ○ | ○ | ○ | ○ | ○ | ○ | ○ | ○ | ○ | |
Table 2 (weight %)
| Comparative example | |||||||||||||
| 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 | 12 | ||
| Aluminium powder pigment | I | ||||||||||||
| II | |||||||||||||
| III | |||||||||||||
| IV | 4.0 | 4.0 | 4.0 | 4.0 | |||||||||
| V | 8.0 | 8.0 | 8.0 | 4.0 | |||||||||
| Pearl pigment | 8.0 | 8.0 | 8.0 | 8.0 | |||||||||
| Water soluble resin | I | 0.3 | 0.3 | 0.3 | 0.4 | 0.4 | 0.5 | ||||||
| II | 0.4 | 0.4 | 0.4 | ||||||||||
| III | 0.3 | 0.3 | 0.3 | ||||||||||
| IV | 3.0 | ||||||||||||
| Adhered resin | I | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | ||||||
| II | 15.0 | 15.0 | 12.0 | ||||||||||
| Water-miscible organic solvent | I | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 | 7.0 |
| II | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | 15.0 | |
| Tinting material | I | 2.0 | 2.0 | 2.0 | 2.0 | ||||||||
| II | 0.8 | 0.8 | 0.8 | 0.8 | |||||||||
| Antisepticize and mildew preventive | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | |
| The agent of anti-embroidery | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | |
| Lubricant | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
| The bright pigment dispersion agent | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | |
| Water | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | |
| Meter | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | |
| The light sense | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | |
In the table, each raw material is composed as follows.
Aluminium powder pigment
I: the aluminium powder pigment that oleic acid was handled, trade(brand)name " WXM 5422 ", japan Aluminum Co., Ltd's product, median size 19 μ m
II. the aluminium powder pigment handled of oleic acid, trade(brand)name " WXM 1440 ", japan Aluminum Co., Ltd's product, median size 30 μ m
III. the aluminium powder pigment handled of oleic acid, trade(brand)name " WXM 1415 ", japan Aluminum Co., Ltd's product, median size 51 μ m
IV. the aluminium powder pigment handled of stearic acid, trade(brand)name " WXM 0630 ", japan Aluminum Co., Ltd's product, median size 7 μ m
V. the aluminium powder pigment handled of stearic acid, trade(brand)name " 1110W ", Showa Aluminium Corp's product, median size 15 μ m
Pearl pigment
Trade(brand)name " Iriodin302 ", Merck Japan Co., Ltd. product, the about 5-20 μ of median size m
Water soluble resin
I. Welan gum: trade(brand)name " K1C376 ", three brilliant Co., Ltd. products
II. succinoglucan: trade(brand)name " Reozan ", three brilliant Co., Ltd. products
III. Leisang plastic: trade(brand)name " K7C233 ", three brilliant Co., Ltd. products
IV. in the amine and the type Synolac, trade(brand)name " Watersol S-311 ", Dainippon Ink. ﹠ Chemicals Inc's product
Water-miscible organic solvent
I. glycerol
II. propylene glycol
Adhered resin
I: the acrylic acid or the like synthetic resin emulsion (trade(brand)name " Nikasol FH-011A ", Japanese Carbide Industrial Co., Ltd product, minimum film temperature＜0 ℃ of making, pH 7.0,150mPas (with Brookfield viscometer at 25 ℃ of numerical value that record))
II. acrylic acid or the like synthetic resin emulsion (pH 7.5 for trade(brand)name " Nikasol FX336 ", Japanese Carbide Industrial Co., Ltd product, minimum film temperature＜0 ℃ of making, 200mPas (with Brookfield viscometer at 25 ℃ of numerical value that record))
Tinting material
I. blue pigments base-material
The preparation method of the pigment dispersion of blue pigments base-material is as follows: following blue pigments and following colo(u)rant dispersion are added triethylamine with resin after by following mixed, the dissolving back disperses with ball mill, and obtaining median size is that 0.08 μ m, solid component concentration are the pigment water dispersion of 10 weight %.Wherein, used blue pigments is a phthalocyanine blue (trade(brand)name " Fastgen Blue TGR ", Dainippon Ink. ﹠ Chemicals Inc's product), used colo(u)rant dispersion resin is a styrene-propene acid copolymer (trade(brand)name " JohncrylJ683 ", Johnson Polymer company product, weight-average molecular weight: 8000).
Phthalocyanine blue 5 weight parts
Colo(u)rant dispersion resin 1 weight part
II. orchil (China and foreign countries change into Co., Ltd.'s product for Xylene Red 289, trade(brand)name " Chugai Aminol Pink R ")
Antisepticize and mildew preventive
1,2-benzisothiazole-3-ketone (trade(brand)name: " Proxell GXL ", the synthetic Co., Ltd. of Hoechst product)
The agent of anti-embroidery
Benzotriazole
Lubricant
Voranol EP 2001 phosphoric acid ester (phosphoric acid ester promoting agent, trade(brand)name " Phosphanol PE-510 ", Toho Chemical Industry Co., Ltd.'s product)
Bright pigment dispersion agents such as aluminium powder pigment
Polyoxyethylene nonylplenyl ether (nonionic surface active agent, HLB:13.2, trade(brand)name " EmulgenPI-20T ", Kao Corp's product)
The making of sample
Below, each ink composite of embodiment and comparative example shown in the table is filled to by an one end and stainless ball-point pen tip (pearl material: in the printing ink storage portion that the polypropylene beam barrel of the hollow that silicon carbide) is connected forms, make each ballpoint pen sample that above-mentioned printing ink storage portion is housed.
Evaluation test
Write on commercially available loose leaf paper with these ballpoint pens, the light sense of each printing ink of the embodiment of his-and-hers watches 1 and comparative example is estimated respectively.
The evaluation of light sense is write state by visual inspection and is carried out, and the strong usefulness zero of light sense is represented, light sense usefulness * expression little or that do not have the light sense.
As seen from table, use the printing ink of embodiment 1,6,8,10 and 13, all can obtain manifesting the person's handwriting of light as the diamond.Use the printing ink of embodiment 2,4,9,11 and 14, all can obtain manifesting the person's handwriting of light as the aquamarine.Use the printing ink of embodiment 3,5,7,12 and 15, all can obtain the person's handwriting of light as the pink colour pearl (pearl pink).And the printing ink of use comparative example, resulting person's handwriting all turns white, and does not manifest light.Especially no matter whether the ink composite of embodiment contain adhered resin, compares with 12 ink composite with the comparative example 7,10,11 that contains pearl pigment, and many glittering points that send dazzling light are arranged on its person's handwriting.
The foregoing description is the ink composite that is applicable to ballpoint pen, but if light ink composite of the present invention contains with oleic acid and/or stearic acid is the aluminium powder pigment of median size more than 15 μ m that the grinding aid pulverization process is crossed, then also applicable to other writing appliances.If to contain with oleic acid and/or stearic acid is the aluminium powder pigment of median size more than 15 μ m that the grinding aid pulverization process is crossed to light ink composite of the present invention, also can be used for cosmetic material such as the makeup that face applied some make up, modified nail, the makeup of modifying toenail, nail varnish, mascara, eyeliner, eye black pigment used by women in ancient times to paint their eyebrows, lipstick, foundation cream and hair cosmetic with the makeup association area of various uses such as material etc.
Because it is median size that the grinding aid pulverization process is crossed (is preferably 30-60 μ m) more than 15 μ m aluminium powder pigment and water soluble resin, water-miscible organic solvent and water that bright water printing ink composition of the present invention contains with oleic acid and/or stearic acid at least, therefore, compare with the aqueous ink composition of existing use bright pigment, can obtain having the person's handwriting of the stronger bright unexistent uniqueness of feeling in the past.Especially when above-mentioned light ink composite also contains tinting material except aluminium powder pigment, person's handwriting is produced and the corresponding strong light of the tone of this tinting material.
Claims (9)
1. bright water printing ink composition, it contains aluminium powder pigment and water soluble resin, water-miscible organic solvent and the water that the median size of crossing for the grinding aid pulverization process with the stearic acid is 30-60 μ m at least,
Described water soluble resin is to have the polar varnish resin.
2. bright water printing ink composition as claimed in claim 1, wherein, described to have the polar varnish resin be the Synolac that has neutralized with amine.
3. bright water printing ink composition as claimed in claim 1, wherein, described Synolac that to have the polar varnish resin be hydroxylation or hydroxylation melmac.
4. bright water printing ink composition as claimed in claim 1, wherein, described aluminium powder pigment accounts for the 0.01-20 weight % of total weight.
5. bright water printing ink composition as claimed in claim 1, it also contains as the synthetic resin emulsion that above-mentioned aluminium powder pigment is adhered to the binder constituents of base material.
6. bright water printing ink composition as claimed in claim 1, wherein, in solid content, the content of synthetic resin emulsion is 0.1-40 weight %.
7. bright water printing ink composition as claimed in claim 1, its viscosity is 1,000-10,000mPas, be under 3 ° of R14 circular cones, 0.5rpm, 20 ℃ condition, to record with ELD type viscometer, and contain following compositions a～e, the content of each composition is to account for the proportional meter of ink composite gross weight:
A.0.01-20 the aluminium powder pigment of the median size of crossing for the grinding aid pulverization process with the stearic acid of weight % more than 15 μ m,
B. in solid content, be the synthetic resin emulsion that is selected from acrylic resin emulsion, styrene-propene acid resin emulsion and vinyl-acetic ester resin emulsion of 0.1-40 weight %,
C.0.01-40 the polysaccharide that is selected from Welan gum, succinoglucan and Leisang plastic of weight %,
D.1-40 the water-miscible organic solvent of weight %,
E.0.05-15 the tinting pigment of weight %.
8. bright water printing ink composition as claimed in claim 1, wherein, described grinding aid also comprises oleic acid.
9. ballpoint pen, its filling as claimed in claim 1ly have a flow water color ink of property of pseudo-plasticity.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP215930/00 | 2000-07-17 | ||
| JP215930/2000 | 2000-07-17 | ||
| JP2000215930 | 2000-07-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1333313A CN1333313A (en) | 2002-01-30 |
| CN1254515C true CN1254515C (en) | 2006-05-03 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011226617A Expired - Fee Related CN1254515C (en) | 2000-07-17 | 2001-06-27 | Brightening aqueous ink composition |
Country Status (3)
| Country | Link |
|---|---|
| KR (1) | KR100463440B1 (en) |
| CN (1) | CN1254515C (en) |
| TW (1) | TW588095B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100498807B1 (en) * | 2001-12-04 | 2005-07-01 | 대한민국 | Restorating agents for deteriorated blue ink and its preparation method |
| US7365108B2 (en) * | 2004-07-14 | 2008-04-29 | Hewlett-Packard Development Company, L.P. | Pigmented ink-jet inks with improved print quality and reliability |
| KR101110196B1 (en) * | 2009-09-02 | 2012-03-13 | 한국세라믹기술원 | Ceramic ink for manufacturing alumina thick film by inkjet printing process |
| CN101705031B (en) * | 2009-07-08 | 2012-07-04 | 深圳市嘉卓成科技发展有限公司 | Mirror surface screen printed ink and preparation method thereof |
| CN101705030B (en) * | 2009-11-26 | 2011-10-26 | 杭州电子科技大学 | Preparation method of gravure water-based ink |
| CN105038404B (en) * | 2015-09-09 | 2018-06-15 | 上海纳诺微新材料科技有限公司 | A kind of composition for ink and writing implement |
| KR101795636B1 (en) * | 2015-10-19 | 2017-11-16 | 최수진 | Aqueous transferring ink for use of textile for aqueous gravure printing and textile transferring paper for the same |
| CN109575645B (en) * | 2018-12-27 | 2020-12-29 | 长沙族兴新材料股份有限公司 | Aluminum paste for alcohol-water type ink and preparation method thereof |
-
2001
- 2001-05-01 TW TW090110389A patent/TW588095B/en not_active IP Right Cessation
- 2001-06-27 CN CNB011226617A patent/CN1254515C/en not_active Expired - Fee Related
- 2001-07-12 KR KR10-2001-0041870A patent/KR100463440B1/en active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| CN1333313A (en) | 2002-01-30 |
| TW588095B (en) | 2004-05-21 |
| KR20020008006A (en) | 2002-01-29 |
| KR100463440B1 (en) | 2004-12-23 |
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