CN1253732A - Natural marine fruit vegetable coating fresh-keeping agent - Google Patents
Natural marine fruit vegetable coating fresh-keeping agent Download PDFInfo
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- CN1253732A CN1253732A CN 98110567 CN98110567A CN1253732A CN 1253732 A CN1253732 A CN 1253732A CN 98110567 CN98110567 CN 98110567 CN 98110567 A CN98110567 A CN 98110567A CN 1253732 A CN1253732 A CN 1253732A
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- shitosan
- fruit
- sodium
- agent
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- Storage Of Fruits Or Vegetables (AREA)
Abstract
The present invention relates to a natural marine fruit and vegetable film-coating fresh-keeping agent and its preparation process. It is characterized by using chitin acylate prepared by using chitin as raw material as fruit and vegetable film-coating fresh-keeping agent or compounding it with other adjuvant to prepare fruit and vegetable film-coating fresh-keeping agent. It is pure natural and non-toxic, possesses good biological compatibility, good film-forming property, water-absorbing moisture-holding property, antimicrobial activity, antioxidant activity, acid-base balance and plant physiological regulation function, and is safe for human body, so that it can be extensively used for storage and fresh-keeping of various fruits and vegetables.
Description
The invention belongs to food or food additives field.
The seasonality of fruit, vegetable growth is stronger, the particularly continuous expansion and the expanding economy of Chinese Urbanization scale, and storage, the freight volume of fruit, vegetables increase day by day.According to investigations, during producing, the fruits and vegetables of China overstocks because of the improper part of accumulating, cause rotting of 20-30% and 30-40% every year respectively, this not only causes the waste of resource, the pollution of environment, and orchard worker and vegetable grower's interests have directly been damaged, seriously restricted expanding economy, therefore, at home and abroad the research of preserving fruit and vegetable utilizing is very active, wherein antistaling agent has become the focus of research, and the research of natural fruit and vegetables coating antistaling agent then becomes the direction of antistaling agent research and development, meanwhile, fruits and vegetables are produced, the development in accumulating market, to the raising of antistaling agent demand and functional requirement, also to the utmost antistaling agent research is pushed to depth, effectively promoted the development in antistaling agent market.
At present, Chang Yong fruit and vegetable coating antistaling agent has two classes substantially at home: a class is to be the antistaling agent of film forming matter or host with the synthetic organic polymer compound, and such antistaling agent is because of being synthetic, and it is residual to tend to toxigenicity after the use; Another kind of is to be the antistaling agent of film forming agent or host with the natural polymer, as shellac, algin, gum arabic, beeswax and carboxymethyl cellulose etc., the film forming matter of such antistaling agent is because its function is comparatively single, as only having film forming, water-retaining property or suppressing respiration, in antistaling agent prescription, often must add relatively large chemical agent such as anticorrosion, antibacterial and anti-oxidant, influence the natural sex of this type of antistaling agent.
The objective of the invention is to prepare shitosan acylated derivatives-Malaysia acyl shitosan sodium, as fruit and vegetable coating antistaling agent or composite making fruit and vegetable coating antistaling agent.
The object of the present invention is achieved like this: with butene dioic acid class antisepsis antistaling agent is guide's molecular model; with the natural marine shitosan with good film forming, plant physiology regulatory function is raw material; with the maleic anhydride is acylating agent, makes Malaysia acyl shitosan sodium.The Malaysia acyl shitosan sodium that makes therefrom is except that possessing the good film forming of shitosan, plant physiology regulatory function, because the introducing of maleoyl group, make it possess butene dioic acid class antisepsis antistaling agent α, the beta-unsaturated carbonyl structure, thereby its antibacterial and antioxidation activity improves greatly; Because the introducing of hydrophily carboxyl makes Malaysia acyl shitosan have good suction performance of keeping humidity; Simultaneously, Malaysia acyl shitosan is again a kind of poly-both sexes organic macromolecule, makes Malaysia acyl shitosan sodium become multi-functional efficient, natural marine fruit vegetable coating fresh-keeping agent, and its fresh-keeping usefulness of in addition composite back is more outstanding.
Embodiment:
The preparation of Malaysia acyl shitosan sodium: take by weighing shitosan 20g, put into the 1000ml there-necked flask that agitator is housed, add suitable quantity of water, take by weighing Na
2CO
342g and maleic anhydride 98g also are divided equally into four parts, under agitation, the two are alternately added, and add the back and continue reaction 1 hour.After stopping reaction, reactant is slowly poured in a large amount of acetone, shitosan acylate sodium salt precipitation is separated out, and filtration back cyclic washing is precipitated to filtrate and is neutral, will be deposited in 60 ℃ of vacuum drying and promptly get Malaysia acyl shitosan sodium.The preparation of chitose aquatic foods: take by weighing Malaysia acyl shitosan sodium 20Kg; SE-9 (sucrose ester) 5Kg; OA (sodium soap) 2Kg; CMC (carboxymethyl cellulose) 5Kg; GAP (gum arabic) 5Kg mixes, pulverizes, and crosses 60 mesh sieves, promptly gets natural marine fruit vegetable coating fresh-keeping agent-chitose aquatic foods.
During use, 1Kg chitose aquatic foods can add water 500-1000Kg, become preserving fruit and vegetable utilizing liquid after stirring, but the fruits and vegetables of 20,000 kilograms of coating-film fresh-keepings.When filming, fruits and vegetables are immersed 30-60 second in the fresh-keeping liquid, pull out, natural air drying or blower fan dry up, and the packing case of packing into can be put in storage fresh-keeping, and storehouse temperature 8-10 ℃, fresh-keeping more than 6 months, good fruits and vegetables rate is more than 95%.
Claims (8)
1 natural marine fruit vegetable coating fresh-keeping agent-chitose aquatic foods belong to food or food additives field, it is characterized in that: the chitose aquatic foods are to be that the shitosan acylate of feedstock production prepares fruit and vegetable coating antistaling agent and preparation technology thereof as fruit and vegetable coating antistaling agent or with other additive compound with the shitosan;
2 is described according to claim 1, it is characterized in that: with butene dioic acid class antisepsis antistaling agent is guide's molecular model, with natural marine shitosan with good film forming, plant physiology regulatory function is raw material, is acylating agent with the maleic anhydride, produces the preparation technology of Malaysia acyl shitosan sodium;
3 is described according to claim 1 or 2, it is characterized in that: Malaysia acyl shitosan sodium is as fruit and vegetable coating antistaling agent or the fruit and vegetable coating antistaling agent made with other additive compound;
4 is described according to claim 1 or 2, it is characterized in that: the acylating agent of shitosan acylate preparation is a maleic anhydride;
5 shells are described according to claim 1 or 2, it is characterized in that: the acid binding agent of shitosan acylate preparation can be sodium carbonate, sodium acid carbonate, NaOH, ammonium hydroxide etc., and wherein best is sodium carbonate;
6 is described according to claim 1 or 2, it is characterized in that: with Malaysia acyl shitosan sodium is that the auxiliary agent of the composite preparation chitose of host aquatic foods is SE-9 (sucrose ester), OA (sodium soap), CMC (carboxymethyl cellulose) and GAP (gum arabic);
7 is described according to claim 6, it is characterized in that: sucrose ester can be selected SE-9, SE-11, SE-13, SE-15 for use according to different fruit and vegetable varieties, wherein with SE-11 the best;
8 is described according to claim 6, it is characterized in that: OA can select odium stearate, sodium palmitate, enuatrol and linoleic acid sodium for use, wherein with linoleic acid sodium the best.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98110567A CN1091355C (en) | 1998-11-14 | 1998-11-14 | Natural marine fruit vegetable coating fresh-keeping agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98110567A CN1091355C (en) | 1998-11-14 | 1998-11-14 | Natural marine fruit vegetable coating fresh-keeping agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1253732A true CN1253732A (en) | 2000-05-24 |
| CN1091355C CN1091355C (en) | 2002-09-25 |
Family
ID=5220601
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN98110567A Expired - Fee Related CN1091355C (en) | 1998-11-14 | 1998-11-14 | Natural marine fruit vegetable coating fresh-keeping agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1091355C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104430837A (en) * | 2014-12-31 | 2015-03-25 | 青海康普生物科技股份有限公司 | Method for avoiding moisture absorption, caking, oxidation and color changing of dried wolfberry fruit |
| CN108822233A (en) * | 2018-07-05 | 2018-11-16 | 陕西科技大学 | A kind of hydroxypropyl sugar derivatives and preparation method thereof |
| CN113402631A (en) * | 2021-06-18 | 2021-09-17 | 青岛市农业科学研究院 | Preparation method and application of alkaline seed coating agent film-forming agent |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1060010A (en) * | 1990-09-19 | 1992-04-08 | 天津轻工业学院 | Fruit and vegetable coating fresh preserving agent and preparation method thereof |
| US5633025A (en) * | 1994-11-07 | 1997-05-27 | The United States Of America As Represented By The Secretary Of Agriculture | Bioactive coating for harvested commodities |
-
1998
- 1998-11-14 CN CN98110567A patent/CN1091355C/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104430837A (en) * | 2014-12-31 | 2015-03-25 | 青海康普生物科技股份有限公司 | Method for avoiding moisture absorption, caking, oxidation and color changing of dried wolfberry fruit |
| CN108822233A (en) * | 2018-07-05 | 2018-11-16 | 陕西科技大学 | A kind of hydroxypropyl sugar derivatives and preparation method thereof |
| CN113402631A (en) * | 2021-06-18 | 2021-09-17 | 青岛市农业科学研究院 | Preparation method and application of alkaline seed coating agent film-forming agent |
| CN113402631B (en) * | 2021-06-18 | 2023-02-28 | 青岛市农业科学研究院 | Preparation method and application of alkaline seed coating agent film-forming agent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1091355C (en) | 2002-09-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: QINGDAO HAOLIZHONG BIOTECHNOLOGY CO., LTD. Free format text: FORMER OWNER: QINGDAO LIZHONG CHITIN CO. Effective date: 20030117 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20030117 Address after: 266033 Fuhua building, No. 27, Wenzhou Road, Shandong, Qingdao Patentee after: Qingdao good China Biotechnology Co., Ltd. Address before: The mountain area of Jimo city in Shandong province Qingdao city 266200 Li Jia Xi Cheng Xi Patentee before: Qingdao Lizhong Chitin Co. |
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| ASS | Succession or assignment of patent right |
Owner name: QINGDAO LIZHONG CHITIN CO. Free format text: FORMER OWNER: QINGDAO HAOLIZHONG BIOTECHNOLOGY CO., LTD. Effective date: 20040210 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20040210 Address after: 266200 Shandong city of Qingdao province Jimo Huanxiu office Lee West Village Patentee after: Qingdao Lizhong Chitin Co. Address before: 266033 Fuhua building, 27 Wenzhou Road, Shandong, Qingdao, China Patentee before: Qingdao good China Biotechnology Co., Ltd. |
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| ASS | Succession or assignment of patent right |
Owner name: QINGDAO HAIKANGLIZHONG BIOISYSTECH CO., LTD. Free format text: FORMER OWNER: QINGDAO LIZHONG CHITIN CO. Effective date: 20040903 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20040903 Address after: 266101 No. 268 East Hongkong Road, hi tech Industrial Development Zone, Shandong, Qingdao Patentee after: Biological Technology Co., Ltd. Qingdao Haikang Liberia Address before: 266200 Shandong city of Qingdao province Jimo Huanxiu office Lee West Village Patentee before: Qingdao Lizhong Chitin Co. |
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| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |