CN1247851C - Knitting fabric releasing negative ion - Google Patents

Abstract

The present invention relates to a knitting fabric capable of releasing negative ions, which uses a dye containing the component of opal with the unique property of releasing negative ions to print and dye. The present invention is characterized in that the knitting fabric is formed from 15% to 20% of Ciba-adhesive acoine PB-NF, 1% to 3% of protein powder, 1.5% to 5.5% of paint, 1% to 2% of Ciba-softener PSC, 2.5% to 3% of Ciba-thickening agent acoine PT-CP and water as rest through the steps of circular-net printing, drying, softener feeding and shaping. The releasing concentration of the negative ions is equivalent to the concentration of people walking in city parks, negative ion textiles can be accompanied beside people at any moment so that people hourly live in the space of the negative ions, the released negative ions are more than 2500/cm<3>, and can be stabilized to be more than 2000/cm<3> through water washing, and the basic requirement of healthy guarantee is achieved.

Description

A kind of knit fabric that discharges anion

Technical field

The present invention relates to the knit fabric that can discharge anion that a kind of usefulness contains the coating dye printing of the opal composition that can discharge the anion special performance.

Background technology

Opal shale is composed and is stored in Cretaceous System Nenjiang group (k ₂N) among mud stone, shale and the siltstone stratum, ore porosity height, water imbibition is strong, excellent adsorption, poisonous and harmful substance or elements such as adsorbable formaldehyde, benzene and derivative, chloride, nitrite, cyanide, Pb, Hg, As, and have decolouring and bleachability preferably.Its chemical composition is SiO ₂, H ₂O, moisture is about 1-14%, also contains a spot of Fe ₂O ₃, Al ₂O ₃, Mn, Cu etc., the opaline chemical analysis in Nenjiang is as shown in table 1.Ore has a large amount of poriforms micropore, and specific area is big especially, can reach 277.3cm ²/ g, water absorption rate is 74.4%, the aperture is between 5-20nm.

The opaline chemistry in table 1 Nenjiang becomes

SiO 2	Al 2O 3	Fe 2O 3	CaO	MgO	K 2O	Na 2O	P 2O 5	H 2O +	H 2O -	FeO	TiO 2	Mn
													81.01	7.84	1.68	6.60	0.589	1.13	0.20	0.01	0.10	2.42	0.21	0.20	0.01

Tridymite all is tiny scale aggregate, and forms a bobbles body, is often overlapping a circle christobalite in the foreign country of these spheroids, and its size of also wrapping a christobalite shell at some independent opal ball peripheries is measured as 0.1-0.3 μ m under Electronic Speculum.

It is nanometer level microporous to find that by electron-microscope scanning opal inside has, and absorption property is good especially, can adsorb poisonous, pernicious gas and element.The opal micro mist of super-refinement and modification can be preferably and synthetic fats such as polyacrylonitrile, polyethers, polyester, polyurethane, polyethylene, polypropylene and second third, butyronitrile, butylbenzene, natural various rubber combined, polymer/Nano-Opal Composite has toughening effect to ABS resin, can also be used to directly joining in printing ink, paint, coating, weaving, the rubber-plastics material, also can be used for working out fiber, because it is nanometer level microporous that opal has, and can be used for preparing nanocomposite.

Anion is exactly electronegative particulate, the charged particulate that wherein swims in air is air ion, ion has positive and negative branch, positively charged ion constantly worsens the quality of air, anion is then opposite, anion to people's health, and ecological ground ghost image ring and verify by clinical practice for domestic and international medical circle expert.The place of containing a large amount of negative aeroions, people can feel to breathe happy, relaxed and joyful.Anion also has good sterilizing function, wherein negative oxygen ion has higher activity, can brokenly encircle the cell membrane of bacterium or the activity of cellular plasm organized enzyme, and anion is with bacterium with after combining, can make bacterial virus produce the change of structure or the conversion of energy, cause the death of bacterial virus, no longer form new bacterial classification, thereby reach the purpose of antibiotic and sterilizing.

The relation of table 2 anion concentration and health

Environment	Content (anion number/cm	Degree of relationship
			Forest, waterfall district	100000-500000	Has the spontaneous recovery ability
High mountain, seashore	50000-100000	Sterilization reduces disease propagation
			Countryside, seashore	5000-50000	Strengthen body immunity and antimicrbial power
In the town park	1000-2000	Keep healthy basic need
			The street greening district	100-200	Bring out the physiological barrier edge
Dwelling house enclosed area, city	40-50	Bring out physiological barrier such as headache, insomnia, neurasthenia, burnout etc.
			Adorn the indoor of air-conditioning	0-25	Cause " air conditioner disease " symptom

Human comfortable in order to guarantee to live, also at the source of seeking to discharge anion, the occurring in nature negative aeroion is created in three big mechanism: the one, and what atmosphere was subjected to factors such as ultraviolet ray, cosmic ray, radioactive material thunder and lightning, storm influences generation ionization, produces anion; The 2nd, the Lenard effect of water, promptly at the impact of waterfall, the water that falls natural processes such as mistake that pushes away volume and heavy rain of wave, from top to down, flow at high speed under the effect of gravity makes the hydrone cracking, produces the spray tube electrical effect that a large amount of anions also is water; The 3rd, the photoelectric effect that the photosynthetic use of the trees of forest, the point discharge of branches and leaves and green plants forms also can make air ionization, produces negative aeroion.

The test of fiber product inspection center of the Chinese chemical fibre industry of process association finds that the coating, the coating that contain the opal composition have particular performances, can discharge anion, reaches 3000-5000/cm ³Not second to the people in the countryside, in the environment of the Nature in field, this environment and health relation are very close, can play health, health-care function, can strengthen body immunity and antimicrbial power, if it is added in paint, the coating, can develop the environmentally friendly machine of promising green, health, be a kind of natural green environment friendly materials, directly indoor, modern people just can easily have a taste of the environment of the comfortable anion atmosphere of the Nature.

Summary of the invention

The knit fabric that can discharge anion of the coating dye printing of the opal composition that the object of the present invention is to provide a kind of usefulness to contain to discharge the anion special performance.

The present invention takes following design: the coating that the knit fabric of release anion is disposed by weight percentage by following prescription, slurry, auxiliary agent and technology printing and dyeing form,

Paste formula:

Vapour crust adhesive acoin PB-NF 15-20%

Albumen stone flour 1-3%

Coating 1.5-5.5%

Qiba softener PSC 1-2%

Vapour crust thickener acoin PT-CP 2.5-3%

All the other are water.

Print:

ROTARY SCREAM PRINTING:

Online, debugging, starching, start stamp

Oven dry:

Net formula dryer: 130～140 ℃, 3 minutes

Cross softener:

Add 1 grams per liter softener with dying machine, 35～40 ℃, went out jar in 10 minutes

Typing: 140 ℃, 3 minutes.

After the ultra-fine grinding of opal shale, further grind again, add in the dyestuff of textiles, can change natural performance, discharge anion, and do not influence other performance of textiles, people's health is highly profitable.The negative ion concentration of anion lining is about 2.5 * 10 ³Individual, forest, waterfall district negative from concentration be about ten thousand/cm of 10-15 ³, the concentration of anion is about 100-200/cm in the street greening district ³, the negative of Urban Parks is about 1000-2000/cm from concentration ³, dwelling house closed zone, city negative ion concentration is red to be 40-50/cm ³, long-time back, room conditioning room negative ion concentration is about 0-25/cm ³The effect of the nature of anion textile fabric just is equivalent to the concentration of people in Urban Parks stroll, and the anion textiles can be followed the people at one's side at any time, very extensively, as clothing and household textiles, as underwear pants, bedding, towel etc.; Indoor ornament is as the wallpaper, carpet, slip cover, mat etc. of decoration usefulness; Medical woven cloths is as operating coat, nursing clothes, sick bed articles for use etc.; Filtering material is as air-conditioning filter net, material for water treatment etc.; Other fabric.Like this, just can make the people natural space that is enclosed in anion constantly, play the mankind have been brought into the colory living space of following that anion is arranged constantly.

The anion that the different fabric of table 3 discharges several/cm ³

The polypropylene fibre spun filament	3900
		Polypropylene fibre undrawn yarn 600m/min acrylic fibers as-spun fibre 800m/min polyester-cotton blend calico blended cloth arrangement blended cloth stamp	3300 3300 3600 (1) 1800 (2) 2500 (2)

Annotate: (1) Shanghai China fiber product inspection center measures;

(2) Beijing China Textile Academy measures

Table 4 washing is to the influence of negative ion concentration

Washing times	0	10	20	30	40	50
							Red calico	4800	2940	2870	2610	2740	2430
The purple calico	3180	2660	2510	2610	2600	2050

By the said determination result as seen: the textiles through arrangement can reach the anion level that guarantees health of people, formulates successful negative-ion fiber at 2000 cm ³More than, by table 4 as seen: washing can be stabilized in 2000 cm ³More than, be to guarantee healthy basic need.

The specific embodiment

Embodiment 1

The mill base prescription:

Deep blue:

Vapour crust adhesive acoin PB-NF 20%

Albumen stone flour 3%

Coating blue 8,301 4%

Coating pake purpke 8,701 0.7%

Coating black 8,503 0.35%

Qiba softener PSC 2%

Vapour crust thickener acoin PT-CP 2.5%

All the other are water;

Print:

ROTARY SCREAM PRINTING:

Online, debugging, starching, start stamp

Oven dry:

Net formula dryer: 130～140 ℃, 3 minutes

Cross softener:

Add 1 grams per liter softener with dying machine, 35～40 ℃, went out jar in 10 minutes

Typing

140 ℃, 3 minutes.

Embodiment 2

The mill base prescription:

Red:

Vapour crust adhesive acoin PB-NF 15%

Albumen stone flour 3%

Coating pieces red 8,119 2.5%

Coating yellow 8,202 1.5%

Qiba softener PSC 1.5%

Vapour crust thickener acoin PT-CP 2.5%

All the other are water;

Print:

ROTARY SCREAM PRINTING:

Online, debugging, starching, start stamp

Oven dry:

Net formula dryer: 130～140 ℃, 3 minutes

Cross softener:

Add 1 grams per liter softener with dying machine, 35～40 ℃, went out jar in 10 minutes

Typing

140 ℃, 3 minutes.

Embodiment 3

The mill base prescription:

Dark brown:

Vapour crust adhesive acoin PB-NF 15%

Albumen stone flour 3%

Coating palm fibre 8,801 1.5%

Coating yellow 8,202 0.17%

Coating black 8,503 0.18%

Qiba softener PSC 1%

Vapour crust thickener acoin PT-CP 3%

All the other are water;

Print:

ROTARY SCREAM PRINTING:

Online, debugging, starching, start stamp

Oven dry:

Net formula dryer: 130～140 ℃, 3 minutes

Cross softener:

Add 1 grams per liter softener with dying machine, 35～40 ℃, went out jar in 10 minutes

Typing

140 ℃, 3 minutes.

Claims (1)

1. knit fabric that discharges anion is characterized in that: the mill base and the technology printing and dyeing of being disposed by weight percentage by following prescription form,

Paste formula:

Vapour crust adhesive acoin PB-NF 15-20%

Albumen stone flour 1-3%

Coating 1.5-5.5%

Qiba softener PSC 1-2%

Vapour crust thickener acoin PT-CP 2.5-3%

All the other are water;

Print:

ROTARY SCREAM PRINTING:

Online, debugging, starching, start stamp

Oven dry:

Net formula dryer: 130～140 ℃, 3 minutes

Cross softener:

Add 1 grams per liter softener with dying machine, 35～40 ℃, went out jar in 10 minutes

Typing:

140 ℃, 3 minutes.