CN1246197C - Package and/or applicating device for cosmetic and care product, and preparation method for fiber thereof - Google Patents

Package and/or applicating device for cosmetic and care product, and preparation method for fiber thereof Download PDF

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Publication number
CN1246197C
CN1246197C CN02122482.XA CN02122482A CN1246197C CN 1246197 C CN1246197 C CN 1246197C CN 02122482 A CN02122482 A CN 02122482A CN 1246197 C CN1246197 C CN 1246197C
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CN
China
Prior art keywords
fiber
particulate
liquid
bristle
spreader
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Expired - Fee Related
Application number
CN02122482.XA
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Chinese (zh)
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CN1389379A (en
Inventor
琼·路易·盖雷
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LOreal SA
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LOreal SA
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Publication of CN1389379A publication Critical patent/CN1389379A/en
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Publication of CN1246197C publication Critical patent/CN1246197C/en
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    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • A46D1/02Bristles details
    • A46D1/023Bristles with at least a core and at least a partial sheath
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B13/00Brushes with driven brush bodies or carriers
    • A46B13/001Cylindrical or annular brush bodies
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B2200/00Brushes characterized by their functions, uses or applications
    • A46B2200/10For human or animal care
    • A46B2200/1046Brush used for applying cosmetics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2933Coated or with bond, impregnation or core

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  • Cosmetics (AREA)
  • Brushes (AREA)
  • Coating Apparatus (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Closures For Containers (AREA)

Abstract

The invention relates to a package and/or applicating device for cosmetic and care product, which consists of fibers provided with filler particles. The particles are capable of absorbing liquid and/or compound in liquid solution, and/or capable of dissolving in liquid.

Description

The method for making of the packing of cosmetics or nursing product and/or apparatus for coating and fiber thereof, fiber
Technical field
The present invention relates to a kind of material, especially be coated on cosmetics or nursing product on the skin, on the hair or on finger or the toe nail.These cosmetics are a kind of products of knowing, as are limited on the Directive 93/95/CEE of Counsel on June 14th, 1993.
The invention particularly relates to the fiber of the filler that is used for coating substance or material.
Background technology
Need a kind of fiber, in particular for constituting the fiber of brush or flocking, this fiber can absorb the material of relatively large amount, for example in case make spreader can long-term use for a long time.
Also need a kind of bristle that is used for the mascara brush, this bristle can be caught eyelash, for example so that can remove the material on eyelashes surface or make the eyelashes bending.
Also need to improve the preservation of cosmetics or nursing product.
Also need to produce by fiber the new state of coating cosmetics or nursing product, this is suitable for producing new dressing effect.
At last, need to reduce cosmetics or the exsiccation speed of nursing product on spreader, especially in this spreader is not inserted into its container apace again or need under the seal cap body, remain in the wet condition time.
Summary of the invention
Purpose of the present invention is especially in order to satisfy the part of all these requirements or these requirements.
The present invention realizes this purpose by a kind of packing and/or apparatus for coating that is used for cosmetics or nursing product, this device is characterised in that: it comprises the fiber that contains particulate, and this particulate can absorb the liquid that is included at least five ten times of its weight in the product or the cmpd in liquid solution.
In the present invention, term " fiber " is used to represent common slender body arbitrarily, for example be used for constituting the bristle of bristle that eyelashes cover with paint or varnish, flocking coating, the bristle in covering with paint or varnish, put on powder in particular for being coated with nail polish or being used to, perhaps be actually the fiber that is used to constitute filler, this filler is included in the material that is used to be coated on the eyelash, for example so that elongate eyelash.This fiber can be relative flexibility, perhaps elastically deformable in fact, and they can be made by synthetic material.
Aforesaid liquid can be that beauty and make-up is acceptable, for example, can be applied to the oily or moisture ethanol or the oil solution of water of human body, but not be subjected to cited restriction.
This liquid can be to be contained in the product of coating.
Therefore, the objective of the invention is to be used for the device of coated product, this device comprises:
Be used for many fibers of coated product, it is characterized in that: at least a fiber comprises the particulate of a plurality of shapings, and one of them kind can absorb one of following:
Has the amount of liquid that weight equals the weight of particulate; With
Cmpd in the liquid solution; With
Be dissolved in liquid.Described a plurality of particulate can not have cotton.
At least a described fiber can have substantially invariable cross-sectional plane, for example by by one or more thermoplastic materials and/or elastomeric material is extruded or coextrusion forms.This fiber can be formed by two kinds of synthetic material coextrusion, and wherein a kind of synthetic material for example is filled with above-mentioned particulate.This particulate can be at least on the surface of at least a portion of fiber, and can only maybe can select from the teeth outwards to be dispersed in the whole plastic material.
In a specific embodiments, this particulate is suitable for when contacting with the material that will be coated with increasing volume, for example they can be contained in the expansion when contact of solvent in will the material of coating, described solvent for example can be a water.Such volume increases can play the effect that produces surface irregularity on fiber surface, this uneven zone that can be formed for keeping material, this is used for being coated with purpose and is immersed in cosmetics that supply is housed or very favourable during the container of nursing product at this fiber.
Use can absorb liquid and can expand when contacting with liquid, perhaps the particulate of dissolving can play the effect that produces special anchorage zone on the fiber that is being used to be coated with cosmetics or nursing product when contacting with liquid, especially since this particulate for being contained in the wetting ability in the material or the compatibility of lipophilic compound.Therefore, material can be better attached on this fiber, and spreader can have more substantial material.
Exist the particulate be suitable for absorbing liquid and can select to be suitable for expansion when contacting can also be used to postpone the cosmetics on fiber surface or the exsiccation of nursing product with this liquid; because the solvent in being contained in cosmetics or nursing product is water when evaporation for example, these particulates that have been absorbed with described liquid are discharged into this liquid in the material around this fiber again.Make to postpone very favourablely in the exsiccation of the lip-deep material of spreader, because it can not only make this spreader use the longer time, and when it does not use and be not immersed in this material, can postpone its exsiccation, for example when it is only protected by tin hat.
Particulate is crystalline when dried for example, when be contained in applied product in liquid can be deliquescing when contacting.
After absorbing liquid, make fiber more soft like this.By the characteristic of selection particulate and the amount of adding, make fiber have desirable flexibility.
Particulate can absorb the liquid of its weight, for example water at least.
For can make particulate with material that will coating when contact, the especially material that volume increases when contact with water, can be as described below, but to exemplify not be that conduct limits: the poly-mer that expands when water or liquid are arranged for this; The netted polyacrylates that superabsorbent is arranged, this netted polyacrylates has very high coefficient of expansion in water; Polyvinyl alcohol; Carboxyl vinyl polymer; Semisynthetic by the cellulose derivation; Starch; Xanthan gum; Biological carbohydrate; Scleroglucan (sclero-glucanes); Casein; Vegetable gum is alginates, gel, glue connection polysaccharide (gellan), xanthans (Xanthan) for example; LAPONITE; Silica, especially gluey silica; And their compound.
Superabsorbent material can absorb the liquid of 100 times of its weight at least, for example can use polyacrylates.
Before expanding, the grain size of this particulate for example can be at 0.1 micron (μ m) to the scope of 300 μ m, perhaps at 5 microns (μ m) to the scope of 200 μ m, perhaps at 10 microns (μ m) to the scope of 150 μ m.
The grain size of these particulates will be selected along with the variation of the desirable roughness in back that expands.
With respect to the total weight of the fiber before expanding, the dry weight weight ratio of described particulate can preferably be less than or equal to 6% in 0 to 20% scope.
In order to make fiber, material therefor can be chosen as when contacting with the material that will be coated with and can expand, and for example can make volume increase 15% relatively.
The plastic material that is used for making at least a fiber can exemplify selection from below: polyamide; Polyethylene terephthalate (PET); Acetate, polyethylene (PE); Polypropylene (PP); Polyvinylchloride (PVC); Amide polyesters (amide block polyester); Plasticising Rilsan Elastic body, especially polyester elastomer, PE elastic body, silicone elastomer, nitrile elastic body; And these mixtures of material.
In a specific embodiments, at least a fiber comprise be suitable for liquid soluble particulate when for example water contacts.This particulate can be water-soluble or fat-soluble.The dissolving of this particulate makes and presents rough surface on the fiber, preferably even make this fiber multihole.The primary particle size of these particulates can be in the scope of 0.1 μ m to 300 μ m.
At least a fiber can comprise and is suitable for absorption liquid style such as water, expands simultaneously or non-bloating particulate.Use the advantage of this particulate to be, it can be sent into one or more cmpds in the fiber, for example kills biological characteristic, the characteristic of especially sterilizing for it is had.Especially, this fiber can contain and is suitable in the absorption liquid liquid solution, especially the particulate of the maintenance material in the aqueous system.
The concentration that is suitable for the particulate of liquid in the absorption liquid liquid solution or cmpd can be, with before described liquid contacts, with respect to the total weight of fiber, the percentage by weight of this particulate can be in 0 to 20% scope, perhaps in 0 to 6% scope at fiber.
This fiber can have a variety of cross-sectional planes, and for example its shape of cross section can be selected as follows: circular symmetry or asymmetric; Circular; Solid or hollow is square; Plate-like also can have been selected groove; Solid or hollow triangle; Solid or hollow star; U-shaped; V-arrangement; I shape; T shape: Z-shaped;-font; + font; Kidney shape shape; Three branches are arranged; Hollow; The perhaps combination of these shapes.This fiber can twisting.
Adopt the packing and the apparatus for coating of fiber of the present invention can select to comprise polishing piece.
Fiber of the present invention can belong to the spreader that is suitable for absorbing material, as mentioned above.
This spreader can be that eyelashes are covered with paint or varnish, and at least a bristle of this brush is made of fiber of the present invention.
As mentioned above, existence can absorb liquid and/or expand when contacting with liquid or dissolve in particulate in the liquid, can make the bristle of brush that to a certain degree roughness or porosity are arranged, thereby promote the adhesion of mascara and postpone its exsiccation.Especially when this particulate was suitable for producing film, this particulate also can deposit a skim on the eyelash surface, thereby improved ciliary stability or outward appearance, perhaps helped the slip of this spreader.
In a kind of version, also can select, spreader is made of the type spreader of covering with paint or varnish, and at least a bristle of this brush is made of a kind of described fiber.
This packing and/or apparatus for coating can have the flocking coating, and in this flocking coating, at least a bristle is made of a kind of described fiber.This flocking coating can cover from least a portion of a following selected assembly: the tooth of comb; The bristle of brush; Wiper; Foamed materials; Sponge; The selectivity membrana perforata; Rigidity or flexible end piece, especially elastic body end piece; Textile fibres; And non-woven fibre.
The diameter of fiber for example can be in the scope of 0.5 μ m to 500 μ m, and perhaps in 50 μ m to 500 mu m ranges, this depends on its purposes, and the length of this fiber for example can be in the scope of 0.5mm to 50mm.
Also can select, this fiber can constitute the filler in cosmetics or the nursing product, mascara especially, and at this moment, this fiber helps to elongate eyelash.Be included in the particulate that absorbs liquid and/or expansion when contacting with liquid in fiber, this will for example help making fiber to remain on the eyelash.
Also preferably, comprise in this fiber and magnetizing or magnetizable particulate.
Magnetized or magnetizable particulate can be introduced to have contained can absorb liquid or expansion when contacting with liquid, perhaps dissolve in the fiber of the particulate in the liquid, perhaps in a version, packing and/or apparatus for coating can only contain some fiber of magnetic particle, and other fiber contains can absorb liquid or expansion when contacting with liquid, perhaps dissolves in the particulate in the liquid.This magnetic particle can be the particulate by resin-coating, cyanoacrylate for example, and perhaps they can be formed by the magnetic material that is deposited on the non-magnetic media, and this non-magnetic media for example is micro glass bead or wood fiber.
Fiber is magnetic and can helps the absorption of material, and can improve its coating to the nursing surface, perhaps can produce novel dressing effect.
This magnetic can also promote the infiltration of activating agent by promoting microcirculation.
Fiber can be static or motion.
Fiber can comprise a plurality of particulates, and this particulate can not have clay and do not have silica.
At least a fiber does not have tapering basically.
The method that the present invention also provides a kind of manufacturing to be applicable to the fiber in above-mentioned packing and/or the apparatus for coating is characterized in that having the following steps:
Extrude or coextrusion contains the plastic material fiber of particulate, this particulate can absorb the liquid of at least five ten times of its weight or the cmpd in liquid solution, perhaps dissolves in the liquid; And
This fiber is contacted with described liquid.
In the specific implementations of this method, use to be suitable for the particulate that when contact, expands, and the grain size of particulate is chosen as and makes fiber after described particulate expansion predetermined roughness be arranged with described liquid.
In a specific implementations also, the maintenance material in particulate can the absorption liquid liquid solution, this fiber contacts with described liquid, and makes this fiber be filled with the maintenance material.Described liquid can be used to cool off the fiber that leaves extruder.
The present invention also provides the fiber that is applicable to the bristle in the brush, perhaps as the fiber of the flocking that is used for the packing of cosmetics or nursing materials and/or apparatus for coating, this fiber is characterised in that: it is except synthetic material, also comprise the liquid that can absorb at least five ten times of its weight or the particulate of the cmpd in liquid solution, perhaps dissolve in the particulate in the liquid.
The present invention also provides porous or the rough wearing fiber that obtains by said method, and in particular for the fiber of coated product device, this fiber comprises:
Synthetic material; With
The a plurality of particulates relevant with synthetic material, a plurality of particulates of this shaping one of them plant can absorb one of following:
Liquid and
Cmpd in the liquid solution, and be dissolved in the liquid.
A plurality of particles wherein can absorb the amount of the liquid that equals its weight at least.
Description of drawings
By to the detailed description of non-limiting examples and with reference to the accompanying drawings (this accompanying drawing is an integral part of this specification sheets) below reading, can understand other features and advantages of the present invention, in institute's drawings attached, for drawings clear, the relative scale of each assembly may distortion.In the accompanying drawing:
Figure 1A and 1B are expression includes the fiber of the particulate that is suitable for expanding in liquid axial schematic sectional views;
Fig. 2 A and 2B are the axial schematic sectional views that expression comprises the fiber that dissolves in the particulate in the liquid;
Fig. 3 has represented the gel that forms on fiber surface;
Fig. 4 has represented the only embodiment on fiber surface of particulate;
Fig. 5 A to 7 is that expression comprises the fiber of magnetic particle respectively at the similar view of Figure 1A to 3;
Fig. 8 A to 8C is the cross-sectional figure of signal of the different instances that distributes in fiber of expression magnetic particle;
Fig. 9 A to 9R is the cross-sectional figure of signal in the various possibilities cross section of expression fiber;
Figure 10 represents that fiber is by extruding manufacturing;
Figure 11 represents that this fiber extruding back magnetization;
The various examples of Figure 12 to 26 expression packing and/or apparatus for coating;
Figure 27 represents the bristle made with the magnetisable fiber orientation in flocking under the magnetic field line effect that is produced by magnet;
Figure 28 A and 28B are illustrated in the deflection of brush bristles under the influence of magnetic interaction;
Figure 29 A and 29B are illustrated in the deflection of covering with paint or varnish bristle under the influence of magnetic interaction;
Figure 30 represents to comprise the spreader of coating assembly, and this coating assembly is loaded in the tin hat when not using;
Figure 31 represents the magnetic particle that is coated with; And
Figure 32 represents the magnetic particle that forms on the non-magnetic material by magnetic is deposited on.
The specific embodiment
Figure 1A to 9R has represented fiber of the present invention, and this fiber for example is applicable to as packing and/or the apparatus for coating shown among Figure 12 to 26 any one.
In described example, fiber is made by extruding the thermoplastic material 11 that comprises particulate filler, and this particulate can absorb liquid or the cmpd in liquid solution, perhaps can be dissolved in the liquid, can select to make simultaneously this particulate filler to be magnetic.
Figure 1A has represented at fiber to comprise the fiber of the filler of particulate 30 cmpds before for example water contacts with liquid, the cmpd of this particulate 30 can expand in water, and Figure 1B represented this identical fibre with situation after liquid contacts.
In the example shown, fiber is solid, and circular cross section is arranged, but it also can have other cross section, as hereinafter described.
For example, this fiber passes through device manufacturing as shown in figure 10, and this device comprises an extruder 20 and a cooling liquid bath 21, and fiber is immersed in after leaving extruder in this groove.
The expansion of particulate 30 is used for forming the fluctuating effect on the surface of fiber, and by utilizing this fluctuating effect, fiber especially can absorb more substantial material, perhaps can catch eyelash better when the bristle that this fiber is for example covered with paint or varnish as eyelashes.
Particulate 30 also can be used in one or more materials is absorbed in the fiber, and this material is for example for having the protective agent or the reagent of beauty treatment or skin activity effect.
Especially, the groove 21 that is used for cooling off the fiber that leaves extruder can comprise one or more cmpds that are dissolved in tank liquor, and protective agent for example, described cmpd are absorbed by particulate 30 when fiber immerses in this groove 21.Like this, the fiber that leaves groove 21 is filled with the cmpd of being drawn by the particulate 30 that is contained in the fiber.These cmpds for example discharge when contacting with cosmetics or nursing product more gradually, so that improve their preservation.This fiber can dewater after leaving groove 21.
Also can select, except can having selected particulate 30, fiber can also comprise particulate 40, and this particulate 40 dissolves in the liquid, for example the water that is used to cool off the fiber that leaves extruder of groove 21.These particulates 40 for example can be made of the salt, the sugar that dissolve in the used liquid, perhaps are made of gel when this liquid is water.Fig. 2 A has represented to be included in the fiber of dissolving this particulate 40 before, and promptly for example this fiber has just left extruder 20, and Fig. 2 B has represented the situation of identical fibre after process groove 21.Can see that the solvable particulate 40 on fiber surface is dissolved by the liquid in the groove 21, thereby make fiber surface produce roughening, even can make this fiber multihole.This roughening or porosity for example can be used to increase the absorbent amount of substance of fiber.Roughening that is obtained or porous size depend on the primary particle size of particulate 40.When fiber leaves groove 21, only need make 40 dissolvings of part particulate, like this, particulate continues to dissolve when contact with in its surface cosmetics or nursing product.Particulate 40 can be made of one or more materials with cosmetic or skin effect.In this case, the dissolving of particulate 40 when contacting with cosmetics or nursing product can be accompanied by described material is discharged on the nursing surface.Preferably, fiber can be vibrated, so that or make particulate 40 from the teeth outwards leave.
Also can select, particulate 40 by and the material that is insoluble in the water of groove 21 make, and in this material only is dissolved in gradually with this fiber contacts the cosmetics or nursing product.
Particulate 50 can also be introduced in the fiber, this fiber is suitable for forming gel when contacting with liquid, thereby forms layer of gel 51 on fiber surface, as shown in Figure 3.Layer of gel 51 for example can change the compatibility of fiber for cosmetics that are in contact with it or nursing materials like this.This gel can also be deposited on the nursing surface, for example on the eyelash, thereby improves its stability and outward appearance, perhaps improves the sliding that spreader is in contact with it.
Employing can absorb liquid, and especially the particulate of water also has such advantage, and promptly working as the liquid that is absorbed by this particulate can discharge gradually, so that compensate when being contained in the evaporation of the solvent in the composition, can postpone cosmetics or the exsiccation of nursing composition on fiber surface.
Use particulate 30,40 or 50 can also play, for example owing to the compatibility of used particulate for lipophilicity that is comprised in the material or hydrophilic compounds in the effect that is used for producing on the fiber surface of material special anchorage zone.This material can be water/oil emulsion, and this fiber can only absorb water or only absorb oil, perhaps more generally is that they are with a kind of cmpd in the selected mode absorbing material.
Preferably, particulate 30,40 or 50 can only be present on the fiber surface, as shown in Figure 4.
For example, particulate 30,40 or 50 primary particle size are between scope 1 μ m to 300 μ m, perhaps between 5 μ m to 200 μ m, perhaps between 10 μ m to 150 μ m.Particulate 30,40 or 50 concentration can be to be 0 to 20% weight range when dry, perhaps are 0 to 6% weight range.
This fiber can also comprise magnetic particle 12, and this magnetic particle 12 is dispersed in the plastic material 11 in basic mode uniformly.
Also can select, magnetic material 12 can only be deposited on fiber surface by appropriate method, and for example by the coat shown in Fig. 8 A, perhaps they can be limited to fibrous inside, shown in Fig. 8 B.Can also replace magnetic particle by nucleus 14, shown in Fig. 8 C.
For example, the weight ratio of magnetic particle is in 0.2% to 30% scope.
Preferably, used magnetic material selection from following exemplifying: soft magnetic material; Retentive material; Ferrite is especially based on the ferrite of zinc, nickel or manganese; Rare earth; Barium sulfate; Silicon alloy; Ferro-cobalt especially has the molybdenum filler; And these mixtures of material.Magnetic particle 12 can be broken or go up and make by magnetic M being deposited on non-magnetic material C by making magnetic, for example miniature globule or wood fiber as shown in figure 31.Also can select, this magnetic particle can comprise magnetic core M and nonmagnetic outer R, for example one deck resin, especially cyanoacrylate, shown in figure 32.
Fig. 5 A and 5B have represented a kind of fiber, and this fiber is different with the fiber among Figure 1A and the 1B, within it portion's particulate 12 that is magnetic.
Fig. 6 A is different with the fiber among Fig. 2 A and the 2B with the fiber shown in the 6B, wherein has magnetic particle 12.
Fig. 7 has represented that the fiber of Fig. 3 has the magnetic particle 12 that scatters in its whole volume.
The cross-sectional plane of fiber can also have much more very variations except solid circles, as following with reference to as described in the figure 9A to 9R.
Fiber can be extruded into flat cross section, shown in Fig. 9 A, star section is arranged perhaps, shown in Fig. 9 B, the cross section of the star shape with three branches is arranged perhaps, shown in Fig. 9 C.Fiber can have hollow section, shown in Fig. 9 D, or the solid section of capillary channel is arranged, shown in Fig. 9 E.This fiber can also have the U-shaped cross section, shown in Fig. 9 F; The I tee section is shown in Fig. 9 H; T section is shown in Fig. 9 I; The V-arrangement cross section, shown in Fig. 9 J, Z-section, shown in Fig. 9 K, the perhaps combination of above-mentioned given shape, for example shown in Fig. 9 G, the combination of the shape among Fig. 9 B and the 9C.Fig. 9 L has represented fiber hollow, the square-section; Fig. 9 M has represented fiber solid, the square-section; Fig. 9 N has represented fiber hollow, the star cross section; Fig. 9 P has represented fiber hollow, the triangular-section; Fig. 9 Q has represented that the cross section is formed with the fiber of circumferential groove; Fig. 9 R represents the fiber of kidney shape tee section.
When fiber comprised magnetic particle, this fiber can be exposed in the magnetic field, so that magnetize, for example had predetermined polarity for fiber is magnetized into.This can carry out when fiber leaves groove 21, for example by magnetizing equipment 60, as shown in figure 11.Preferably, the magnetization of fiber can also be undertaken by magnetic field being added on this device or being added on a collection of such device after fiber is packed packing and/or apparatus for coating into.The magnetization of fiber only is can make manufacturing easier by the danger together of restriction fibril aggregation when in place in order to arrange in packing and/or apparatus for coating when them.
This fiber can be used for multiple spreader and packing device, as hereinafter described.
Figure 12 has represented a kind of packing and spreader device 100, and this packing and apparatus for coating 100 comprise: a container 101, and this container 101 holds the Substance P that is used to be coated with, for example mascara; Also has a spreader 102.This container 101 has polishing piece 106, and in a unshowned version, this polishing piece 106 can be covered by suede.Spreader 102 comprises a bar 103, and this bar 103 at one end has a handle 104, and this handle 104 also is configured for sealing the seal cap of this container 101, and this bar has a brush 105 at its other end.This brush comprises the core of being made by the metal filament of twisting, and this core is equipped with the bristle that is made of above-mentioned fiber again, and this fiber can select to comprise magnetic particle.
When fiber comprises magnetic particle, the magnetic pole of this brush for example is oriented along the axis of this bar 103 or perpendicular to the axis of this bar 103.The core of this twisting can be made by for example nonmagnetic corrosion-resistant steel of non-magnetic material, and perhaps in a kind of version, it can be made by the material with magnetic.Like this, this core and the mutual magnetic action of this bristle.The bristle of this brush 105 can magnetize, and like this, the magnetizabillty of brush bristles acts on the adjacent bristle, and the effect that makes the bristle appropriate location is for example played in the magnetic interaction between the bristle.According to the direction of brush magnetic pole, can change the effect of bristle orientation.For example, Figure 28 A and 28B have represented when the horizontal expansion of magnetic field the lateral deflection effect to the bristle of brush.Also can select, when being coated on material on the eyelash, use bristle separately, so that useful magnetic field is applied on the part of eyelash or face, for example on the eyelid.The magnetic field that is applied by the bristle of brush is easy to change at any time, especially when the changing of design of brush, for example extracts out or during when coating substance when spreader.Substance P can be magnetic, and for example it can contain magnetisable or magnetized particulate.When Substance P was magnetic, also magnetic brush bristles can strengthen the ability of this brush draws substance, for example by the magnetic attracting force between material and the brush bristles.Also can select, material can contain fiber or the thin slice with magnetic, and spreader can with these thin slice magnetic interaction so that they were alignd with specific direction in when coating, thereby for example help the slip of spreader.
Figure 13 has represented to be used to pack and be coated with the device 110 of nail polish, this device comprises a container 111 and a spreader 112, this spreader comprises a bar 113, this bar 113 has Handleset 114 at the one end, this Handleset 114 also is configured for sealing the cap body of this container, this bar 113 covers with paint or varnish 115 at its other end, and this is covered with paint or varnish 115 and comprises the clumps of bristles that closely ties together relatively.This bristle utilizes fiber of the present invention to make, and they can select to be magnetic, and this magnetic can be used for making in use the bristle of brush 115 to form predetermined direction, thereby makes brush 115 be easier to draws substance or act on the nursing surface.When between the bristle at brush magnetic interaction being arranged, according to the polarity of the magnetic field of each bristle, this magnetic interaction can help with the bristle pack together, and is perhaps opposite, and they are opened.For example, Figure 29 A and 29B have very roughly represented bristle because the magnetic interaction between them and open effect.Substance P can be chosen as the magnetic of himself.
Figure 14 has represented a kind of packing and apparatus for coating 120, this packing and apparatus for coating 120 comprise a container 121, this container 121 is equipped with Substance P, liquid lipstick for example, this device 120 also has a spreader 122, this spreader 122 comprises a bar 123, this bar 123 at one end has cap body 124, be used for closed container 121 and as handle, and the other end at this bar has a spreader end piece 124, this spreader end piece 124 is covered by the flocking of adopting fiber of the present invention to make, and this fiber can be selected to be magnetic.This device 120 also has the polishing piece that is made of block of foam material 125.This block of foam material also can be selected to be magnetic.Particularly, this block of foam material 125 can be magnetized into to a certain degree by comprising magnetic particle therein.The magnetization of wiping test specimen for example can the flocking of magnetization on end piece 124 when extracting spreader 122 out.
Figure 15 has represented to be used to pack the device 130 with coating substance P, and this Substance P is the liquid lipstick especially, and this device comprises an end piece 131, and this end piece is covered by the flocking 132 that utilizes fiber of the present invention to make, and this fiber can be selected to be magnetic.
What Figure 16 had represented to be used to put on powder covers with paint or varnish 140, and the bristle of this brush is made by fiber of the present invention, and this fiber can be selected to be magnetic.
Figure 17 has represented spreader 150, and this spreader 150 comprises a foamed materials 151, and the surface of this foamed materials 151 is covered by the flocking 152 that utilizes fiber of the present invention to make, and this fiber can be selected to be magnetic.This spreader for example can be used for kermes (blush) is coated in skin.
Figure 18 A has represented a kind of liquid lipstick spreader 160, and this liquid lipstick spreader 160 comprises an elastomeric end piece 161 of flocking, and Figure 18 B has represented eyeliner 160 ', and this eyeliner 160 ' comprises an elastomeric end piece 161 ' of flocking equally.In both of these case, the bristle that is used for flocking is made by fiber of the present invention, and this fiber can be selected to be magnetic.
Fiber of the present invention can also be used for powder puff 170 flocking, as shown in figure 19, and perhaps to 180 flocking of makeup removing sponge, as shown in figure 20.
The flocking coating can also extend on the film 191 that is fixed on the block of foam material 192, and the spreader 190 of this situation as shown in figure 21.
Can also adopt fiber of the present invention in disk 200 or towelette, this fiber can be selected to be magnetic, and this disk 200 or towelette comprise that one deck 201 at least comprises the non-woven fibre or the textile fibres of described fiber, as shown in figure 22.
Figure 23 has represented the comb 210 to the eyelash coating substance, and this comb has the tooth 211 of flocking.The bristle of flocking can be made by fiber of the present invention, and this fiber can be selected to be magnetic.
Except fiber was magnetic, this spreader can also select to comprise one or more single-piece magnets.
For example, Figure 24 has represented a kind of spreader 220, and this spreader 220 comprises handle 221, is fixed with magnet 222 on this handle.This magnet is covered by block of foam material 223, and this block of foam material is covered by flocking 224 in its outside certainly, and this flocking is made of the fiber with magnetic.The bristle that the existence of magnet 222 is subjected to flocking 224 is subjected to the magnetic field effect.Especially, the bristle that is basically perpendicular to the flocking of bottom dielectric bonded assembly extends along magnetic field line M, as shown in figure 27.This bristle will stand upright on the surface of coater assembly, perhaps according to them with respect to the position of magnet 222 and stretch out along other direction, thereby make this spreader can absorb more substantial material or make that the coating of this spreader is softer.In addition, when material is with powder that spreader contacts the time, and when spreader is magnetic, the particulate of powder will be deposited on the spreader, especially on its fiber, dispel everywhere and will cause the danger of sneezing thereby reduced this powder.
In device shown in Figure 25 230, material is loaded in the flexible pouch 231, and pump 232 is contained on this flexible pouch top.Spreader comprises a foamed materials 234, and the surface of this foamed materials 234 is covered by flocking 235, and this foamed materials 234 is fixed on the cap body 236.Magnet 237 is loaded in the foamed materials 234, and is installed on the cap body 236.The bristle of flocking 235 utilizes fiber of the present invention to make, and this fiber is magnetic, and this bristle is subjected to the influence in the magnetic field of magnet 237, as described in the embodiment of front.
Figure 30 has represented the part of spreader 280, and this spreader 280 comprises an end piece 282 that flocking is arranged, and this end piece 282 is loaded in the cap body 281 when not using.Contain the fiber of suction or the reagent that expands by employing when water is arranged, can make it keep moist in the cap body, thereby postpone the exsiccation of this end piece, this end piece also can be by other coater assembly replacement, for example brush.
Nature, the present invention is not limited to the foregoing description.
Especially, at spreader be loaded between the material in the container screen 240 is arranged, as shown in figure 26.At this moment, Substance P can contain magnetic particle 241, and spreader can be magnetic, and for example this spreader is made of the end piece with flocking coating, and this flocking coating is made of magnetic fiber of the present invention.This end piece 242 can adsorb the magnetic particle 241 that is contained in the material.By the aperture of suitable selection screen 240, can guarantee this screen 240 of magnetic particle 241 impassabititys by 242 attractions of this end piece, making the effect of Substance P but play, thereby improving the ability that this end piece 242 absorbs these materials towards end piece 242 motions.In a kind of version, self is magnetic Substance P, for example contains the coating magnetic particle, and this Substance P can be by the hole of screen 240.
This fiber can only magnetize on the part of its length.
Above-mentioned packing and apparatus for coating can comprise magnetic fibre, and be mixed with non magnetic fiber, this fiber is filled with the cmpd particulate, and this cmpd particulate can absorb liquid and/or be suitable for expanding when contacting with liquid, perhaps can dissolve when contacting with liquid, this liquid for example can be water.

Claims (44)

1. the packing and/or the apparatus for coating of cosmetics or nursing product, this device is characterised in that: it comprises contains particulate (30; 40; 50) fiber, this particulate can absorb the liquid that is included at least five ten times of its weight in the product or the cmpd in liquid solution.
2. device according to claim 1 is characterized in that: this fiber is made by synthetic material.
3. device according to claim 1 is characterized in that: at least a described fiber has substantially invariable cross-sectional plane.
4. device according to claim 2 is characterized in that: at least a described fiber is by by one or more thermoplastic materials and/or elastomeric material is extruded or coextrusion forms.
5. device according to claim 1 is characterized in that: described particulate is at least on the surface of at least a portion of fiber.
6. device according to claim 1 is characterized in that: at least a portion of fiber, described particulate is only on the surface of this fiber.
7. device according to claim 1 is characterized in that: at least a described fiber, particulate is dispersed in the whole plastic material.
8. device according to claim 1 is characterized in that: described particulate (30) is suitable for increasing volume when contacting with the material that will be coated with.
9. device according to claim 8 is characterized in that: at least a described fiber, particulate is made by at least a material that is selected from following the exemplifying: the poly-mer that expands when water or liquid are arranged; The netted polyacrylates that superabsorbent is arranged, this netted polyacrylates has very high coefficient of expansion in water; Polyvinyl alcohol; Carboxyl vinyl polymer; Semisynthetic by the cellulose derivation; Starch; Xanthan gum; Biological carbohydrate; Scleroglucan; Casein; Vegetable gum; LAPONITE; Silica; And their compound.
10. device according to claim 9 is characterized in that: described vegetable gum is selected from alginates, gel, glue connection polysaccharide, xanthans.
11. device according to claim 9 is characterized in that: described silica comprises gluey silica.
12. device according to claim 8 is characterized in that: at least a described fiber, the grain size of particulate (30) before expanding is in the scope of 0.1 μ m to 300 μ m.
13. device according to claim 8 is characterized in that: at least a described fiber, described particulate (30) before expanding with respect to the weight ratio of total weight of fiber in 0 to 6% scope.
14. device according to claim 1 is characterized in that: the material of at least a described fiber (11) is suitable for expanding when contacting with the material that will be coated with.
15. device according to claim 1 is characterized in that: at least a described fiber comprises the particulate (40) that is suitable for dissolving when contacting with liquid.
16. device according to claim 1 is characterized in that: described particulate does not have cotton.
17. device according to claim 1 is characterized in that: at least a described fiber contains the particulate (50) that is suitable for forming at fiber surface gel.
18. device according to claim 1 is characterized in that: this device comprises at least a fiber, and this fiber contains the particulate (30: 50) of the maintenance material that is suitable for absorption in the liquid solution.
19. device according to claim 1 is characterized in that: be suitable for absorbing this particle of liquid or the cmpd in described liquid solution, with before described liquid contacts with respect to the weight ratio of the total weight of fiber between 0 to 6%.
20. device according to claim 1 is characterized in that: at least a described fiber is made by plastic material (11), and this plastic material is from following selection: polyamide; PET; Acetate; PE; PP; PVC; Amide polyesters; Plasticising Rilsan Elastic body; And these mixtures of material.
21. device according to claim 20 is characterized in that: described elastic body is selected from polyester elastomer, PE elastic body, silicone elastomer, nitrile elastic body.
22. device according to claim 1 is characterized in that: the shape of cross section of at least a described fiber is from following selection: circular symmetry or asymmetric; Circular; Solid or hollow is square; Plate-like also can have been selected groove; Solid or hollow triangle; Solid or hollow star; U-shaped; V-arrangement; I shape; T shape: Z-shaped;-font; + font; Kidney shape shape; Three branches are arranged; Hollow; The perhaps combination of these shapes, this fiber can select to carry out twisting.
23. device according to claim 1 is characterized in that: this device comprises polishing piece (106; 125).
24. device according to claim 1 is characterized in that: at least a described fiber belongs to spreader (102; 112; 122; 140; 160; 170; 180; 190; 200; 210; 220; 234; 240), this spreader is suitable for charging into material.
25. device according to claim 24 is characterized in that: this spreader is that eyelashes are covered with paint or varnish, and at least a bristle of this brush is made of a kind of described fiber.
26. device according to claim 24 is characterized in that: this spreader constitutes by covering with paint or varnish, and this at least a bristle of covering with paint or varnish is made of a kind of described fiber.
27. device according to claim 1 is characterized in that: this device has the flocking coating, and in this flocking coating, at least a bristle is made of a kind of described fiber.
28. device according to claim 27 is characterized in that: this flocking coating can cover from least a portion of a following selected assembly: the tooth of comb; The bristle of brush; Polishing piece; Foamed materials; Sponge; The selectivity membrana perforata; Rigidity or flexible end piece; Textile fibres; And non-woven fibre.
29. device according to claim 28 is characterized in that: this end piece is the elastic body end piece.
30. device according to claim 1 is characterized in that: the diameter of at least a described fiber is in the scope of 0.5 μ m to 500 μ m
31. device according to claim 1 is characterized in that: the length of at least a described fiber is in 0.5mm to 50mm scope.
32. device according to claim 1 is characterized in that: this device has and comprises at least a the magnetization or magnetizable body (12; 14) fiber.
33. device according to claim 1 is characterized in that: at least a described fiber contains the magnetization or the magnetizable particles of 0.2% to 30% weight.
34. device according to claim 1 is characterized in that: particulate can absorb the liquid of at least one hundred times of its weight.
35. device according to claim 1 is characterized in that: particulate does not have clay and silica.
36. a manufacturing is used for the method for the fiber of described packing of claim 1 and/or apparatus for coating, it is characterized in that having the following steps:
Extrude or coextrusion contains particulate (30; 40; 50) plastic material fiber, this particulate can absorb the liquid of at least five ten times of its weight or the cmpd in liquid solution; And
This fiber is contacted with described liquid.
37. method according to claim 36 is characterized in that: described particulate does not have cotton.
38. method according to claim 36 is characterized in that: described particulate (30) expands when contacting with described liquid, and the grain size of this particulate is chosen as and makes fiber have predetermined roughness after described particulate expands.
39. according to the described method of claim 38, it is characterized in that: described liquid is used to cool off the fiber that leaves extruder.
40. method according to claim 36 is characterized in that: described particulate (30; 50) can absorb maintenance material in this liquid solution because of contacting with described liquid.
41. according to the described method of claim 40, it is characterized in that: described liquid is cosmetics or nursing materials.
42. method according to claim 36 is characterized in that: before coated article is made, make this fiber.
43. fiber that is applicable to the bristle in the brush, perhaps be suitable as the fiber of the flocking bristle of the packing that is used for cosmetics or nursing product and/or apparatus for coating, this fiber is characterised in that: except synthetic material (11), it also comprises the liquid that can absorb at least five ten times of its weight or the particulate (30 of the cmpd in liquid solution; 40; 50).
44. according to the described fiber of claim 43, it is characterized in that: described particulate does not have cotton.
CN02122482.XA 2001-06-05 2002-06-05 Package and/or applicating device for cosmetic and care product, and preparation method for fiber thereof Expired - Fee Related CN1246197C (en)

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FR0107308A FR2825246B1 (en) 2001-06-05 2001-06-05 PACKAGING AND/OR APPLICATION DEVICE COMPRISING FIBERS COMPRISING PARTICLES CAPABLE OF ABSORBING A LIQUID OR A COMPOUND IN SOLUTION IN THIS LIQUID OR OF DISSOLVING IN A LIQUID
FR0107308 2001-06-05

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US (1) US20020182409A1 (en)
EP (1) EP1264562A1 (en)
JP (2) JP2003125846A (en)
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CA (1) CA2389556C (en)
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FR2825246A1 (en) 2002-12-06
CA2389556C (en) 2008-09-30
JP2006271983A (en) 2006-10-12
CA2389556A1 (en) 2002-12-05
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CN1389379A (en) 2003-01-08
EP1264562A1 (en) 2002-12-11
US20020182409A1 (en) 2002-12-05
BR0202112A (en) 2003-05-20
MXPA02005565A (en) 2004-07-16
FR2825246B1 (en) 2004-06-04

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