CN1245085A - Corrosion-resistant high-strength mullite filtering material and manufacturing method thereof - Google Patents

Corrosion-resistant high-strength mullite filtering material and manufacturing method thereof Download PDF

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Publication number
CN1245085A
CN1245085A CN 98116576 CN98116576A CN1245085A CN 1245085 A CN1245085 A CN 1245085A CN 98116576 CN98116576 CN 98116576 CN 98116576 A CN98116576 A CN 98116576A CN 1245085 A CN1245085 A CN 1245085A
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oxide
contain
mullite
amount
sand
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CN 98116576
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李海
刘启发
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Abstract

The present invention discloses a corrosion-resistant high-strength mullite filtering material and its preparation method, and its chemical composition includes (by wt%) 50-70% of aluminium oxide, 20-35% of silicon dioxide, 0.3-1.5% of ferric oxide, 0.5-2.2% of potassium oxide, 0.2-1.8% of sodium oxide, 1-2.5% of calcium oxide, 0.5-1% of magnesium oxide, 1-8% of zirconium oxide, 0.7-1.5% of chromium oxide and 0.1-0.4% of titanium dioxide. The material is a-Al2O3Mullite sand, corundum sand, Guangxi black soil, potash feldspar,The raw materials of zirconia, chromium oxide and industrial paste are mixed according to a certain proportion, and the mixture is prepared by crushing, ball milling, drying, granulating, forming and calcining. The filter material of the invention has the advantages of corrosion resistance, high strength, large filtration capacity, back flushing, suitability for filtering and separating coal ash and water generated by various types of coal-fired boilers, and long service life of 15-20 years.

Description

A kind of high-strength anticorrosion filtering material of mullite and manufacture method thereof
The present invention relates to a kind of filtering material, particularly relate to a kind of high-strength anticorrosion filtering material of mullite and manufacture method thereof.
The steam that present most of industrial production all takes place from the stove that boils, and the coal combusting boiler accounts for more than 80%.Coal combusting boiler coal ash water treatment commonly used generally adopts river sand, sea sand, quartz sand, porcelain ball and handstone to carry out coarse filtration, thick coal smoke ash and suspended substance can filter out, but the water muddiness of discharge do not clarify, and can not reach the standard of discharge water, water resource waste is big, the productive expense height.
The present invention aims to provide a kind of requirement that can not only reach general coarse filtration, the objectionable impurities less than 0.5 μ m in the coal ash water can also be filtered out, and reaches the discharge water standard fully, and the energy back flushing, the filtering material of life-time service and manufacture method thereof.
High-strength anticorrosion filtering material of mullite of the present invention, the weight percent of its chemical constitution is:
Aluminium sesquioxide 50--70; Silicon-dioxide 20--35; Ferric oxide 0.3--1.5;
Potassium oxide 0.5--2.2; Sodium oxide 0.2--1.8; Calcium oxide 1.0--2.5;
Magnesium oxide 0.5--1.0; Zirconium white 1--8; Chromium sesquioxide 0.7--1.5;
Titanium dioxide 0.1--0.4
Its porosity of this material is 30--50%, micro-pore diameter 0.5--80 μ m, tap density 1--1.2t/m 3, ultimate compression strength 1500--2000Kg/cm 2, acid-alkali-resistant degree 95--99%.
The manufacture method of high-strength anticorrosion filtering material of mullite of the present invention, its raw material comprises the a--AL of aluminum content>99% 2O 3, contain AL 2O 3Measure>50%, contain SIO 2The mullite sand of amount>42% contains a--AL 2O 3Emergy, Guangxi black earth, potassium felspar sand, zirconium white, chromium sesquioxide, the industrial paste of amount>90%, its raw material weight per-cent is:
A--AL 2O 330--40; Mullite sand 25--45; Emergy 5--15;
Guangxi black earth 2--10; Potassium felspar sand 3--10; Zirconium white 2--10;
Chromium sesquioxide 0.5--2.5; Industry paste 0.5--1.5.
Its technical process is: with the a--AL of aluminum content>99% 2O 3Be crushed between the 20--80 order, contain AL 2O 3Measure>50%, contain SIO 2Amount>42% mullite sand is crushed between the 80--100 order, contains a--AL 2O 3Amount>90% emergy is crushed between the 40--60 order, and three kinds of aggregates are mixed in proportion and knead evenly, and are stand-by.Guangxi black earth, potassium felspar sand, zirconium white, chromium sesquioxide, five kinds of raw materials of industrial paste are mixed in proportion and are crushed to 325 orders, add the water wet ball grinding 8 hours of 10--12% in the ball mill of packing into.Again the aggregate of spy's usefulness is packed into and continue ball milling half an hour in the ball mill, blowing.Dehydrate with slip drying press, make the batching water content between 15--18%.Hole sizer with diameter 0.5--2.5mm sieves dried batching with sieve, and carries out granulation; Make the metal punching block by product specification, particle is inserted in hydropress, be pressed into brick, plate in the metal punching block.The work in-process that suppress are at 80 °--and under 100 ° of conditions, carry out oven dry in 24 hours, make water content less than 2%.Dried work in-process are packed in the garden of falling cigarette kiln and other general kiln, and temperature is controlled at 1100 °--and 1200 °, calcine 4 hours, kiln discharge, inspection after construction is packed.
Filtering material of the present invention is a kind of corrosion-resistant, the intensity height, and filtration yield is big, can back flushing, use repeatedly, the conserve water resource, easy for installation simple, be applicable to the coal combusting boiler coal ash water filtration separating treatment of various models to reach 15--20 work-ing life.
Below in conjunction with embodiment, the present invention is further described: embodiment 1:
High-strength anticorrosion filtering material of mullite of the present invention, the weight percent of chemical constitution is:
Chromium sesquioxide 50; Silicon-dioxide 35; Ferric oxide 1.0; Potassium oxide 1.4
Sodium oxide 0.2; Calcium oxide 1.7; Magnesium oxide 0.8; Zirconium white 8;
Chromium sesquioxide 1.5; Titanium dioxide 0.4.Embodiment 2:
High-strength anticorrosion filtering material of mullite of the present invention, the weight percent of chemical constitution is:
Aluminium sesquioxide 60; Silicon-dioxide 29; Ferric oxide 0.3; Potassium oxide 0.5;
Sodium oxide 1.8; Calcium oxide 1.0; Magnesium oxide 0.5; Zirconium white 6;
Chromium sesquioxide 0.7; Titanium dioxide 0.2.Embodiment 3:
High-strength anticorrosion filtering material of mullite of the present invention, the weight percent of chemical constitution is:
Aluminium sesquioxide 70; Silicon-dioxide 20; Ferric oxide 1.5; Potassium oxide 2.2;
Sodium oxide 0.7; Calcium oxide 2.5; Magnesium oxide 1.0; Zirconium white 1.0;
Chromium sesquioxide 1.0; Titanium dioxide 0.1.Embodiment 4:
The manufacture method of high-strength anticorrosion filtering material of mullite of the present invention, each raw material weight per-cent is:
The a--AL of aluminum content>99% 2O 330;
Contain a--AL 2O 3Measure>50%, contain SIO 2The mullite sand 45 of amount>42%;
Contain a--AL 2O 3The emergy 15 of amount>90%;
Guangxi black earth 2; Potassium felspar sand 3; Zirconium white 2; Chromium sesquioxide 1.8;
Industry paste 1.2.
Its technical process is with of the present invention identical.Embodiment 5:
The manufacture method of high-strength anticorrosion filtering material of mullite of the present invention, each raw material weight per-cent is:
The a--AL of aluminum content>99% 2O 335;
Contain a--AL 2O 3Measure>50%, contain SIO 2The mullite sand 30 of amount>42%;
Contain a--AL 2O 3The emergy 10 of amount>90%;
Guangxi black earth 10; Potassium felspar sand 7; Zirconium white 6; Chromium sesquioxide 0.5;
Industry paste 1.5.
Its technical process is with of the present invention identical.Embodiment 6:
The manufacture method of high-strength anticorrosion filtering material of mullite of the present invention, each raw material weight per-cent is:
The a--AL of aluminum content>99% 2O 340;
Contain a--AL 2O 3Measure>50%, contain SIO 2The mullite sand 25 of amount>42%;
Contain a--AL 2O 3The emergy 5 of amount>90%;
Guangxi black earth 7; Potassium felspar sand 10; Zirconium white 10; Chromium sesquioxide 2.5;
Industry paste 0.5.
Its technical process is with of the present invention identical.

Claims (8)

1, a kind of high-strength anticorrosion filtering material of mullite is characterized in that the weight percent that this materials chemistry is formed is:
Aluminium sesquioxide 50--70; Silicon-dioxide 20--35; Ferric oxide 0.3--1.5;
Potassium oxide 0.5--2.2; Sodium oxide 0.2--1.8; Calcium oxide 1--2.5;
Magnesium oxide 0.5--1; Zirconium white 1--8; Chromium sesquioxide 0.7--1.5;
Titanium dioxide 0.1--0.4;
This material porosity is 30--50%, micro-pore diameter 0.5--80 μ m, tap density 1--1.2t/m 3, ultimate compression strength 1500--2000Kg/cm 2, acid-alkali-resistant degree 95--99%.
2, filtering material according to claim 1 is characterized in that the weight percent that this materials chemistry is formed is:
Aluminium sesquioxide 50; Silicon-dioxide 35; Ferric oxide 1.0; Potassium oxide 1.4;
Sodium oxide 0.2; Calcium oxide 1.7; Magnesium oxide 0.8; Zirconium white 8;
Chromium sesquioxide 1.5; Titanium dioxide 0.4.
3, filtering material according to claim 1 is characterized in that the weight percent that this materials chemistry is formed is:
Aluminium sesquioxide 60; Silicon-dioxide 29; Ferric oxide 0.3 potassium oxide 0.5;
Sodium oxide 1.8; Calcium oxide 1.0 magnesium oxide 0.5; Zirconium white 6;
Chromium sesquioxide 0.7; Titanium dioxide 0.2.
4, filtering material according to claim 1 is characterized in that the weight percent that this materials chemistry is formed is:
Aluminium sesquioxide 70; Silicon-dioxide 20; Ferric oxide 1.5; Potassium oxide 2.2;
Sodium oxide 0.7; Calcium oxide 2.5; Magnesium oxide 1.0; Zirconium white 1.0;
Chromium sesquioxide 1.0; Titanium dioxide 0.1.
5, a kind of manufacture method of high-strength anticorrosion filtering material of mullite, its raw material comprises the a--AL of aluminum content>99% 2O 3, contain AL 2O 3Measure>50%, contain SiO 2The mullite sand of amount>42% contains α--AL 2O 3The emergy of amount>90%, Guangxi black earth, potassium felspar sand, zirconium white, chromium sesquioxide, industrial paste is characterized in that the above-mentioned raw materials weight percent is:
A--AL 2O 330--40; Mullite sand 25--45; Emergy 5--15;
Guangxi black earth 2--10; Potassium felspar sand 3--10; Zirconium white 2--10;
Chromium sesquioxide 0.5--2.5; Industry paste 0.5--1.5.
Its technical process is: with the a--AL of aluminum content>99% 2O 3Be crushed between the 20--80 order, contain AL 2O 3Measure>50%, contain SIO 2The mullite sand of amount>42% is crushed between the 80--100, contains a--AL 2O 3Amount>90% emergy is crushed between the 40--60 order, and three kinds of aggregates are mixed in proportion and knead evenly, and are stand-by; Guangxi black earth, potassium felspar sand, zirconium white, chromium sesquioxide, five kinds of raw materials of industrial paste are mixed in proportion and are crushed to 325 orders, and wet ball grinding is 8 hours in the ball mill of packing into; Stand-by aggregate is packed into again and continue ball milling half an hour in the ball mill, blowing, dehydration, drying make the batching water content between 15--18%, with the hole sizer of diameter 0.5--2.5mm dried batching are sieved with sieve, carry out granulation; Make the metal punching block by product specification, particle is inserted in the metal punching block in hydropress, suppress; The work in-process that suppress through air-dry or oven dry, make water content less than 2% again, reinstall in the kiln at 1100 °--and calcination is 4 hours in 1200 ° of temperature, and kiln discharge gets material requested.
6, the manufacture method of filtering material according to claim 5 is characterized in that described raw material weight per-cent is:
The a--AL of aluminum content>99% 2O 330;
Contain AL 2O 3Measure>50%, contain SIO 2The mullite sand 45 of amount>42%;
Contain a--AL 2O 3The emergy 15 of amount>90%;
Guangxi black earth 2; Potassium felspar sand 3; Zirconium white 2; Chromium sesquioxide 1.8;
Industry paste 1.2.
7, the manufacture method of filtering material according to claim 5 is characterized in that described raw material weight per-cent is:
The a--AL of aluminum content>99% 2O 335;
Contain AL 2O 3>50%, contains SIO 2The mullite sand 30 of amount>42%;
Contain a--AL 2O 3The emergy 10 of amount>90%;
Guangxi black earth 10; Potassium felspar sand 7; Zirconium white 6; Chromium sesquioxide 0.5;
Industry paste 1.5.
8, the manufacture method of filtering material according to claim 5 is characterized in that described raw material weight per-cent is:
The a--AL of aluminum content>99% 2O 340;
Contain AL 2O 3Measure>50%, contain SIO 2The mullite sand 25 of amount>42%;
Contain a--AL 2O 3The emergy 5 of amount>90%;
Guangxi black earth 7; Potassium felspar sand 10; Zirconium white 10; Chromium sesquioxide 2.5;
Industry paste 0.5.
CN 98116576 1998-08-13 1998-08-13 Corrosion-resistant high-strength mullite filtering material and manufacturing method thereof Pending CN1245085A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 98116576 CN1245085A (en) 1998-08-13 1998-08-13 Corrosion-resistant high-strength mullite filtering material and manufacturing method thereof

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Application Number Priority Date Filing Date Title
CN 98116576 CN1245085A (en) 1998-08-13 1998-08-13 Corrosion-resistant high-strength mullite filtering material and manufacturing method thereof

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Publication Number Publication Date
CN1245085A true CN1245085A (en) 2000-02-23

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102173857A (en) * 2010-12-20 2011-09-07 中钢集团洛阳耐火材料研究院有限公司 Preparation method of mullite mesh ceramic foam filter
CN101415477B (en) * 2006-03-31 2011-09-07 博韦尔公开有限公司 Low expansion corrosion resistant ceramic foam filters for molten aluminum filtration
CN102173856A (en) * 2010-12-20 2011-09-07 中钢集团洛阳耐火材料研究院有限公司 Mullite ceramic foam filter for casting and preparation method thereof
CN105964055A (en) * 2016-06-24 2016-09-28 马鞍山市顺达环保设备有限公司 Filter material for industrial dedusting device and preparation method of filter material

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101415477B (en) * 2006-03-31 2011-09-07 博韦尔公开有限公司 Low expansion corrosion resistant ceramic foam filters for molten aluminum filtration
CN102173857A (en) * 2010-12-20 2011-09-07 中钢集团洛阳耐火材料研究院有限公司 Preparation method of mullite mesh ceramic foam filter
CN102173856A (en) * 2010-12-20 2011-09-07 中钢集团洛阳耐火材料研究院有限公司 Mullite ceramic foam filter for casting and preparation method thereof
CN105964055A (en) * 2016-06-24 2016-09-28 马鞍山市顺达环保设备有限公司 Filter material for industrial dedusting device and preparation method of filter material

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