CN1242105C - Human body fluid dissoluble inorganic ceramic fiber textile material and process of production - Google Patents
Human body fluid dissoluble inorganic ceramic fiber textile material and process of production Download PDFInfo
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- CN1242105C CN1242105C CN 200310105705 CN200310105705A CN1242105C CN 1242105 C CN1242105 C CN 1242105C CN 200310105705 CN200310105705 CN 200310105705 CN 200310105705 A CN200310105705 A CN 200310105705A CN 1242105 C CN1242105 C CN 1242105C
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- fiber
- soluble fibre
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- body fluid
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- 239000000835 fiber Substances 0.000 title claims abstract description 177
- 239000004753 textile Substances 0.000 title claims abstract description 53
- 238000000034 method Methods 0.000 title claims abstract description 23
- 210000001124 body fluid Anatomy 0.000 title claims description 17
- 239000010839 body fluid Substances 0.000 title claims description 17
- 239000000919 ceramic Substances 0.000 title abstract description 18
- 239000000463 material Substances 0.000 title description 29
- 238000004519 manufacturing process Methods 0.000 title description 16
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 26
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 239000004744 fabric Substances 0.000 claims abstract description 12
- 238000009941 weaving Methods 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 36
- 238000009987 spinning Methods 0.000 claims description 33
- 239000010779 crude oil Substances 0.000 claims description 32
- 239000000654 additive Substances 0.000 claims description 28
- 230000000996 additive effect Effects 0.000 claims description 28
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 22
- 229910052909 inorganic silicate Inorganic materials 0.000 claims description 18
- 239000003921 oil Substances 0.000 claims description 18
- 229920000297 Rayon Polymers 0.000 claims description 17
- 210000002268 wool Anatomy 0.000 claims description 14
- 238000009960 carding Methods 0.000 claims description 13
- 210000004209 hair Anatomy 0.000 claims description 5
- 238000010790 dilution Methods 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000004615 ingredient Substances 0.000 abstract 2
- 238000002360 preparation method Methods 0.000 abstract 2
- 229910011255 B2O3 Inorganic materials 0.000 abstract 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 210000003746 feather Anatomy 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 238000005406 washing Methods 0.000 description 17
- 230000015572 biosynthetic process Effects 0.000 description 16
- 239000002893 slag Substances 0.000 description 16
- 230000004927 fusion Effects 0.000 description 15
- 230000003750 conditioning effect Effects 0.000 description 14
- DSCFFEYYQKSRSV-FEPQRWDDSA-N (1s,2s,4s,5r)-6-methoxycyclohexane-1,2,3,4,5-pentol Chemical compound COC1[C@@H](O)[C@@H](O)C(O)[C@H](O)[C@H]1O DSCFFEYYQKSRSV-FEPQRWDDSA-N 0.000 description 4
- 235000013351 cheese Nutrition 0.000 description 4
- 239000011521 glass Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 238000009954 braiding Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 231100000003 human carcinogen Toxicity 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 206010028980 Neoplasm Diseases 0.000 description 1
- 231100000766 Possible carcinogen Toxicity 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
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- Glass Compositions (AREA)
Abstract
The present invention relates to an inorganic ceramic fiber textile capable of dissolving in body liquid of human bodies and a preparation method thereof. The fiber textile comprises the main components by weight percentage: 85 to 95% of soluble fiber, 3 to 12% of organic fiber and 0.1 to 3% of auxiliary agents. The preparation method comprises the steps: mixing the soluble fiber and the organic fiber according to the proportion; respectively producing soluble fiber cloth products, soluble fiber rope products and soluble fiber band products by procedures of feather mixture, combing, spun yarn, twisting, stranding, spooling and weaving. On the basis of ceramic fiber, an ingredient system with SiO2 as the main body is developed, and CaO, MgO, B2O3, Fe2O3, Na2O and/or K2O are introduced; simultaneously, the content of Al2O3 in ingredients is strictly controlled; the soluble inorganic ceramic fiber with the pH value of 7.35 to 7.45 is prepared. The present invention has the advantages of easy obtainment of the raw material and low cost, which is favorable to the popularization and the application of the present invention and the update and the replacement of the ceramic fiber products.
Description
Technical field
The invention belongs to refractory thermal insulating material and method for making thereof, be specifically related to a kind of inorganic silicate fiber (hereinafter to be referred as soluble fibre) textiles and method for making thereof that dissolves in human body fluid.
Background technology
Traditional ceramics fiber (aluminosilicate refractory fiber) textile product (comprising cloth, band, rope), its main component is Al
2O
3And SiO
2(its Al
2O
3+ SiO
2Generally greater than 94%).The ceramic fibre of this composition is being manufactured, and makes in the process that other heat-insulating material uses, and exists critical defect: because of the diameter of ceramic fibre tiny mostly below 6 μ m; Self property is crisp in addition, and fracture produces fibre dust easily, very easily is inhaled in the human body, thereby influences health.
Recent decades, the many scientific research institutions in the world have carried out a large amount of research to the safety issue of ceramic fibre, comprise the research to the human carcinogen.There have been some tissues or mechanism that ceramic fibre is divided into 2B class (possible carcinogen) at present, such as: IARC's (International Agency for Research on Cancer is called for short IARC).Their foundation is: normal human's body fluid pH value is 7.35～7.45 (neutral alkali partially), and with Al
2O
3And SiO
2For the ceramic fibre of main component not dissolved after being sucked by human body, so harmful.
At present, though ceramic fibre is still insufficient to the evidence of human carcinogen's effect, some countries such as Europe, the United States have listed common alumina-silicate ceramic fibre in the product that control is used, and require to print additional on product package material the mark of disporduct.
Summary of the invention
Purpose of the present invention, be by adopting soluble fibre to replace traditional ceramic fibre, develop a kind of inorganic silicate fiber textile and method for making thereof that dissolves in human body fluid, produce ceramic fiber spun product (cloth, band, rope), the inorganic silicate fiber is reduced to the infringement of human body minimum, thereby make the soluble fibre textiles become the product that does not harm human body.
Technical scheme of the present invention is: develop a kind of inorganic silicate fiber textile that dissolves in human body fluid, it is characterized in that this fiber textile predominant quantity percentage composition is: soluble fibre 85～95%; Organic fiber 3～12%; Auxiliary agent 0.1～3%.
Soluble fibre described in the above-mentioned inorganic silicate fiber textile that dissolves in human body fluid is the inorganic silicate fiber that dissolves in human body fluid, and the weight percent of this fiber consists of:
SiO
2 50.5～85％
CaO 5.5～35％
MgO 1～10％
B
2O
3 1～2％
Al
2O
3 0～1％
Fe
2O
3 0～0.5％
Na
2O 0～0.5％
K
2O 0～0.5％。
Above-mentioned organic fiber is viscose, fire resistance fibre and/or string; Above-mentioned auxiliary agent is and crude oil, antistatic additive and/or spinning conditioner.
The present invention also provides a kind of method for making that dissolves in the inorganic silicate fiber textile of human body fluid, it is characterized in that described soluble fibre mixes by proportioning with organic fiber, warp and hair, carding, spun yarn, twisting, plying, winder and weaving process are produced soluble fibre cloth, soluble fibre rope, soluble fibre alternate product respectively;
The auxiliary agent of above-mentioned wool blending step will adopt 30～50 ℃ warm water to dilute, and dilution ratio is an oil: water=1: 5～15; Be sprayed on uniformly then on the soluble fibre and organic fiber that shredding finishes: for guaranteeing that auxiliary agent fully immerses in the fiber, the mixed raw material of starting shooting will enter operation down in 8～24 hours in vexed storehouse in wool bin.
Above-mentioned carding process will with hair after fiber carry out combing by carding equipment and form the wool top of certain rule.
Above-mentioned spinning process is that the wool top twisting formation line density that carding is formed is the silvalin of 150～1500Tex (Tekes), and this operation need be added line feeder to improve the brute force of silvalin, and per share yarn generally adds 1～2 reinforced wire.Institute's line feeder is generally a kind of or compound use of glass yarn, copper wire, high temperature resistant stainless steel silk kind.
The plying operation that the present invention introduced is that wool top twisting is formed line density is that the silvalin of 150～1500Tex forms fiber yarn by twisting, plying, and the fiber yarn that this operation the forms normal line density of uniting is 300～3000Tex.
The winder that the present invention introduced is doubled yarn to be formed by bobbin winder produce needed cheese.
The weaving process that the present invention introduced is to utilize equipment such as loom, braiding machine, inkle loom to produce goods such as soluble fibre cloth, soluble fibre rope, soluble fibre band respectively.
The soluble fibre cloth thickness that the present invention produced is 1～6mm, and its fabric width is 501～3000mm, and during the producd fibers band, its width is 10～500mm.
The soluble fibre rope that the present invention produced can be square sennit or circle sennit, and its specifications and models can be produced according to customer requirement.
The quality index of the soluble fibre textiles that the present invention produces is:
Bulk density: 450～700Kg/m
3
Igloss: 4～10%
Moisture content: 1～2%
Washing shrinkage :≤0.5%
Solubility: 100～250mg/L
Compare with traditional inorganic silicate fiber textile, the invention has the advantages that:
1, on the basis of ceramic fibre, developed with SiO
2Be the batching system of main body, introduced CaO, MgO, B
2O
3, Fe
2O
3, Na
2O and/or K
2O; Al in the batching has been controlled in strictness simultaneously
2O
3Content; Made the inorganic silicate fiber that dissolves in PH 7.35～7.45.
2, raw material is easy to get, and is with low cost, helps the update of applying with ceramic fiber products of the present invention.
The present invention is further elaborated below in conjunction with embodiment for the specific embodiment
Embodiment 1
One, soluble fibre part
Proportioning raw materials (kg); SiO
270 parts, 15.5 parts of CaO, 10 parts of MgO, B
2O
32 parts, Al
2O
31 part, Fe
2O
30.5 part, Na
20.5 part of O, K
20.5 part of O.
After the technical process above-mentioned raw materials mixed, 1500～1800 ℃ were melt into liquid state in special resistance furnace (or electric arc furnaces, glass have a rest stove), utilized blowing process or got rid of a method (0.3～0.6Mpa blast) and carry out fiber production.
Existing resistance furnace is set up 3 groups of electrodes, because raw material changes, resistance is increased, and conductance reduces, and causes the fusing difficulty, for this increases by 3 groups of electrodes to existing resistance furnace, becomes 6 groups of electrodes, to improve the conductance of raw material.
The inorganic silicate fiber that dissolves in human body fluid that the present invention produces, softness and high resilience, average fibre diameter 1～5 μ m, fibre length is 30～150mm, slag ball content is 5～10%.
In PH7.3～7.5, soak 24h in the meta-alkalescence solution that temperature is 37 ± 0.5 ℃, use atomic absorption spectrometry, its solubility is 170～250mg/L.And the conventional ceramic fibrolysis degree of contrast is 0mg/L.
Two, solvable textiles part
Proportioning raw materials (kg): soluble fibre 95%; Organic fiber (viscose) 3%; Auxiliary agent (and crude oil, antistatic additive and spinning conditioner) 2%.
Method for making: soluble fibre mixes by proportioning with organic fiber, and warp and hair, carding, spun yarn, twisting, plying, winder and weaving process are produced soluble fibre cloth, soluble fibre rope, soluble fibre alternate product respectively;
Wherein the auxiliary agent of wool blending step will adopt 30～50 ℃ warm water to dilute, and dilution ratio is an oil: water=1: 5～15; Be sprayed on uniformly then on the soluble fibre and organic fiber that shredding finishes; For guaranteeing that auxiliary agent fully immerses in the fiber, the mixed raw material of starting shooting will enter operation down by vexed storehouse 24h in wool bin.
Carding process will carry out combing by carding equipment with the fiber behind the hair and form the wool top of certain rule.
It is the silvalin of 150～1500Tex (Tekes) that the wool top twisting that spinning process forms carding forms line density, and this operation need be added line feeder to improve the brute force of silvalin, and per share yarn generally adds 1～2 reinforced wire.Institute's line feeder is generally glass yarn, copper wire and/or high temperature resistant stainless steel silk.
The plying operation is that wool top twisting is formed line density is the silvalin of 150～1500Tex, forms fiber yarn by twisting, plying; The common line density of fiber yarn that this operation forms is 300～3000Tex.
Winder is doubled yarn to be formed by bobbin winder produce needed cheese.
The weaving process that the present invention introduced is to utilize equipment such as loom, braiding machine, inkle loom to produce goods such as soluble fibre cloth, soluble fibre rope, soluble fibre band respectively.
The soluble fibre cloth thickness that the present invention produced is 1～6mm, and its fabric width is 501～3000mm, and during the producd fibers band, its width is 10～500mm.
The soluble fibre rope that the present invention produced can be square sennit or circle sennit, and its specifications and models can be produced according to customer requirement.
The quality index of the soluble fibre textiles that makes is: bulk density: 450～700Kg/m
3Igloss: 4～10%; Moisture content: 1～2%; Washing shrinkage :≤0.5%; Solubility: 100～250mg/L.(press the determination method of soluble fibre, down together.)
Embodiment 2
The soluble fibre part
Proportioning raw materials (kg):
SiO
270 parts, 26 parts of CaO, 1 part of MgO, B
2O
31 part, Al
2O
31 part, Fe
2O
30.5 part, Na
2O0.5 part;
Technology: 1800～2000 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 5～10 μ m; Length 90～250mm; Slag ball content 5～10%; Solubility 100～250mg/L;
Two, solvable textiles part
Proportioning raw materials (kg): soluble fibre 85%; Organic fiber (viscose) 12%; Auxiliary agent 3% (with 1.5 parts of crude oils, 1 part in antistatic additive, 0.5 part of conditioner of spinning, and will put into 35 ℃ warm water in oil with crude oil, antistatic additive, spinning conditioning: the ratio of water=1: 8 is diluted).The mixed raw material of starting shooting will enter operation down by vexed storehouse 8h in wool bin.
After finish in vexed storehouse fiber is sent into combing machine for fur and carry out carding, carry out spun yarn after carding is finished, pass through the silvalin that twisting forms 600Tex (Tekes) this moment, the fiber yarn of twisted and plied then formation 1200Tex, and through doff machine formation cheese.The yarn that forms is weaved by loom, and the textiles bulk density of production is 550Kg/m
3, product igloss is 8%, and moisture content is 1.5%, and washing shrinkage is 0.1%.All the other are with example 1.
Embodiment 3
Soluble fibre part material proportioning (kg): SiO
260 parts, 26.5 parts of CaO, 10 parts of MgO, B
2O
32 parts, Fe
2O
30.5 part, Na
20.5 part of O, K
20.5 part of O; 1800～2000 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 1～6 μ m; Length 100～250mm; Slag ball content 5～8%; Solubility 190～250mg/L.
Solvable textiles part material proportioning (kg): soluble fibre 95%; Organic fiber (fire resistance fibre) 4.9%; Auxiliary agent 0.1% (with 0.1 part of crude oil, the warm water of putting into 30 ℃ is in oil: the ratio of water=1: 15 is diluted).The mixed raw material of starting shooting will enter operation down by vexed storehouse 18h in wool bin.
After finish in vexed storehouse fiber is sent into combing machine for fur and carry out carding, carry out spun yarn after carding is finished, pass through the silvalin that twisting forms 1000Tex (Tekes) this moment, the fiber yarn of twisted and plied then formation 1200～1500Tex, and process doff machine forms cheese.The yarn that forms is weaved by loom, and the textiles bulk density of production is 450Kg/m
3, product igloss is 4%, and moisture content is 2%, and washing shrinkage is 0.15%.All the other are with example 1.
Embodiment 4
Soluble fibre part material proportioning (kg): SiO
258 parts, 35 parts of CaO, 5 parts of MgO, B
2O
31 part, Fe
2O
30.5 part, K
20.5 part of O; 1800～2000 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 4～7 μ m; Length 70～250mm; Slag ball content 5～8%: solubility 200～250mg/L.
Solvable textiles part material proportioning (kg): soluble fibre 95%; Organic fiber (viscose) 3%; Auxiliary agent 2% (with 1.0 parts of crude oils, 0.5 part in antistatic additive, 0.5 part of conditioner of spinning, and will put into 35 ℃ warm water in oil with crude oil, antistatic additive, spinning conditioning: the ratio of water=1: 13 is diluted).Vexed storehouse 14h; Yarn twisting forms the silvalin of 150～300Tex (Tekes); The fiber yarn of twisted and plied formation 600～800Tex, the textiles bulk density of production is 700Kg/m
3, product igloss is 5%, and moisture content is 0.5%, and washing shrinkage is 0.5%.All the other are with example 1.
Embodiment 5
The proportioning raw materials of soluble fibre (kg): SiO
250.5 part, 35 parts of CaO, 10 parts of MgO, B
2O
32 parts, Fe
2O
30.5 part, K
20.5 part of O; 1800～2000 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 2～5 μ m; Length 30～200mm; Slag ball content 5～15%; Solubility 100～200mg/L.
Solvable textiles part material proportioning (kg): soluble fibre 94%; Organic fiber (viscose) 3%; Auxiliary agent 3% (with 1.0 parts of crude oils, 0.5 part in antistatic additive, 1.5 parts of conditioners of spinning, and will put into 50 ℃ warm water in oil with crude oil, antistatic additive, spinning conditioning: the ratio of water=1: 15 is diluted).Vexed storehouse 12h; Yarn twisting forms the silvalin of 150～300Tex (Tekes); The fiber yarn of twisted and plied formation 600～800Tex, the textiles bulk density of production is 700Kg/m
3, product igloss is 5%, and moisture content is 1%, and washing shrinkage is 0.5%.All the other are with example 1.
Embodiment 6
Soluble fibre part material proportioning (kg): SiO
254.5 part, 35 parts of CaO, 8 parts of MgO, B
2O
32 parts, Na
20.5 part of O; 1500～1900 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 2～5 μ m; Length 90～250mm; Slag ball content 5～13%; Solubility 100～200mg/L.
Solvable textiles part material proportioning (kg): soluble fibre 85%; Organic fiber (viscose) 12%; Auxiliary agent 3% (with 1.0 parts of crude oils, 1.5 parts in antistatic additive, 0.5 part of conditioner of spinning, and will put into 45 ℃ warm water in oil with crude oil, antistatic additive, spinning conditioning: the ratio of water=1: 5 is diluted).Vexed storehouse 24h; Yarn twisting forms the silvalin of 1250～1500Tex (Tekes); The fiber yarn of twisted and plied formation 2600～3000Tex, the textiles bulk density of production is 650Kg/m
3, product igloss is 5%, and moisture content is 0.5%, and washing shrinkage is 0.5%.All the other are with example 1.
Embodiment 7
Soluble fibre part material proportioning (kg): SiO
258 parts, 35 parts of CaO, 5 parts of MgO, B
2O
31 part, Fe
2O
30.5 part, K
20.5 part of O; 1800～2000 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 4～7 μ m; Length 70～250mm; Slag ball content 5～8%; Solubility 200～250mg/L;
Solvable textiles part material proportioning (kg): soluble fibre 91%; Organic fiber (viscose or string) 7%; Auxiliary agent 2% (with 1.0 parts of crude oils, 0.5 part in antistatic additive, 0.5 part of conditioner of spinning, and will put into 30 ℃ warm water in oil with crude oil, antistatic additive, spinning conditioning: the ratio of water=1: 15 is diluted).Vexed storehouse 12h; Yarn twisting forms the silvalin of 850～1000Tex (Tekes); The fiber yarn of twisted and plied formation 2600～3000Tex, the textiles bulk density of production is 700Kg/m
3, product igloss is 5%, and moisture content is 0.5%, and washing shrinkage is 0.5%.All the other are with example 1.
Embodiment 8
Soluble fibre part material proportioning (kg): SiO
253.5 part, 34 parts of CaO, 10 parts of MgO, B
2O
31 part, Al
2O
30.4 part, Fe
2O
30.5 part, Na
20.2 part of O, K
20.4 part of O; 1800～2000 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 4～8 μ m; Length 30～200mm; Slag ball content 5～10%; Solubility 200～250mg/L;
Solvable textiles part material proportioning (kg): soluble fibre 87%; Organic fiber (viscose) 10%; Auxiliary agent 3% (with 1.0 parts of crude oils, 0.5 part in antistatic additive, 1.5 parts of conditioners of spinning, and will put into 40 ℃ warm water in oil with crude oil, antistatic additive, spinning conditioning: water=ratio was diluted in 1: 5).Vexed storehouse 8h; Yarn twisting forms the silvalin of 1250～1500Tex (Tekes); The fiber yarn of twisted and plied formation 2600～3000Tex, the textiles bulk density of production is 600Kg/m
3, product igloss is 10%, and moisture content is 2%, and washing shrinkage is 0.5%.All the other are with example 1.
Embodiment 9
Soluble fibre part material proportioning (kg): SiO
270 parts, 26 parts of CaO, 1 part of MgO, B
2O
32 parts, Al
2O
30.3 part, Fe
2O
30.3 part, Na
20.4 part of O; 1900～2000 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 6～10 μ m; Length 150～250mm; Slag ball content 5～12%; Solubility 150～250mg/L;
Solvable textiles part material proportioning (kg): soluble fibre 90%; Organic fiber (viscose or string) 9.2%; Auxiliary agent 0.8% (with 0.5 part of crude oil, 0.1 part in antistatic additive, 0.2 part of conditioner of spinning, and will put into 45 ℃ warm water in oil with crude oil, antistatic additive, spinning conditioning: the ratio of water=1: 10 is diluted).Vexed storehouse 164h; Yarn twisting forms the silvalin of 250～400Tex (Tekes); The fiber yarn of twisted and plied formation 600～800Tex, the textiles bulk density of production is 700Kg/m
3, product igloss is 5%, and moisture content is 0.5%, and washing shrinkage is 0.5%.All the other are with example 1.
Embodiment 10
Soluble fibre part material proportioning (kg): SiO
280 parts, 12 parts of CaO, 5 parts of MgO, B
2O
32 parts, Fe
2O
30.5 part, K
20.5 part of O; 1900～2000 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 3～6 μ m; Length 100～250mm; Slag ball content 5～14%; Solubility 100～240mg/L;
Solvable textiles part material proportioning (kg): soluble fibre 95%; Organic fiber (viscose and/or fire resistance fibre) 3%; Auxiliary agent 2% (with 1.0 parts of crude oils, 0.5 part in antistatic additive, 0.5 part of conditioner of spinning, and will put into 45 ℃ warm water in oil with crude oil, antistatic additive, spinning conditioning: the ratio of water=1: 13 is diluted).Vexed storehouse 14h; Yarn twisting forms the silvalin of 250～400Tex (Tekes); The fiber yarn of twisted and plied formation 600～800Tex, the textiles bulk density of production is 700Kg/m
3, product igloss is 5%, and moisture content is 0.5%, and washing shrinkage is 0.5%.All the other are with example 1.
Embodiment 11
Soluble fibre part material proportioning (kg): SiO
280 parts, 12 parts of CaO, 5 parts of MgO, B
2O
32 parts, Fe
2O
30.5 part, K
20.5 part of O; 1900～2000 ℃ of fusions: 0.3～0.6Mpa blast; Diameter 3～6 μ m; Length 100～250mm; Slag ball content 5～14%; Solubility 100～240mg/L;
Solvable textiles part material proportioning (kg): soluble fibre 95%; Organic fiber (viscose and/or fire resistance fibre) 4.8%; Auxiliary agent 0.2% (with 0.1 part of crude oil, 0.1 part of conditioner of spinning, and will put into 45 ℃ warm water in oil with crude oil, antistatic additive, spinning conditioning: the ratio of water=1: 15 is diluted).Vexed storehouse 12h; Yarn twisting forms the silvalin of 250～400Tex (Tekes); The fiber yarn of twisted and plied formation 600～800Tex, the textiles bulk density of production is 700kg/m
3, product igloss is 5%, and moisture content is 0.5%, and washing shrinkage is 0.5%.All the other are with example 1.
Embodiment 12
Soluble fibre part material proportioning (kg): SiO
285 parts, 6 parts of CaO, 5 parts of MgO, B
2O
32 parts, Al
2O
31 part, Fe
2O
30.5 part, Na
20.5 part of O; 1500～1900 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 4～8 μ m; Long 120～250mm; Slag ball content 5～8%; Solubility 100～200mg/L;
Solvable textiles part material proportioning (kg): soluble fibre 94%; Organic fiber (viscose) 3%; Auxiliary agent 3% (with 1 part of crude oil, 1 part in antistatic additive, 1 part of conditioner of spinning, and will put into 45 ℃ warm water in oil with crude oil, antistatic additive, spinning conditioning: the ratio of water=1: 13 is diluted).Vexed storehouse 14h; Yarn twisting forms the silvalin of 650～800Tex (Tekes); The fiber yarn of twisted and plied formation 1600～1800Tex, the textiles bulk density of production is 700Kg/m
3, product igloss is 5%, and moisture content is 0.5%, and washing shrinkage is 0.5%.All the other are with example 1.
Embodiment 13
Soluble fibre part material proportioning (kg): SiO
285 parts, 7 parts of CaO, 5 parts of MgO, B
2O
32 parts, Al
2O
35 parts, K
20.5 part of O; 1700～2000 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 5～10 μ m; Length 80～250mm; Slag ball content 5～10%; Solubility 200～250mg/L;
Solvable textiles part material proportioning (kg): soluble fibre 85%; Organic fiber (viscose or string) 13%; Auxiliary agent 2% (with 1.0 parts of crude oils, 0.5 part in antistatic additive, 0.5 part of conditioner of spinning, and will put into 40 ℃ warm water in oil with crude oil, antistatic additive, spinning conditioning: the ratio of water=1: 15 is diluted).Vexed storehouse 24h; Yarn twisting forms the silvalin of 250～400Tex (Tekes); The fiber yarn of twisted and plied formation 2600～2800Tex, the textiles bulk density of production is 700Kg/m
3, product igloss is 5%, and moisture content is 0.5%, and washing shrinkage is 0.5%.All the other are with example 1.
Embodiment 14
Soluble fibre part material proportioning (kg): SiO
251.5 part, 35 parts of CaO, 10 parts of MgO, B
2O
32 parts, Al
2O
30.5 part, Fe
2O
30.5 part, K
20.5 part of O; 1500～1900 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 1～5 μ m; Length 130～250mm; Slag ball content 5～15%; Solubility 200～250mg/L;
Solvable textiles part material proportioning (kg): soluble fibre 86%; Organic fiber (viscose) 12%; Auxiliary agent 2% (with 1.0 parts of crude oils, 0.5 part in antistatic additive, 0.5 part of conditioner of spinning, and will put into 45 ℃ warm water in oil with crude oil, antistatic additive, spinning conditioning: the ratio of water=1: 13 is diluted).Vexed storehouse 16h; Yarn twisting forms the silvalin of 250～400Tex (Tekes); The fiber yarn of twisted and plied formation 600～800Tex, the textiles bulk density of production is 700Kg/m
3, product igloss is 5%, and moisture content is 0.5%, and washing shrinkage is 0.5%.All the other are with example 1.
Embodiment 15
Soluble fibre part material proportioning (kg): SiO
282.5 part, 9 parts of CaO, 5 parts of MgO, B
2O
32 parts, Fe
2O
30.5 part, Na
20.5 part of O, K
20.5 part of O; 1700～2000 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 5～10 μ m; Length 150～250mm; Slag ball content 5～15%; Solubility 150～250mg/L;
Solvable textiles part material proportioning (kg): soluble fibre 95%; Organic fiber (viscose or fire resistance fibre) 3%; Auxiliary agent 2% (with 1 part of crude oil, 1 part of conditioner of spinning, and will put into 45 ℃ warm water in oil with crude oil, spinning conditioning: the ratio of water=1: 15 is diluted).Vexed storehouse 12h; Yarn twisting forms the silvalin of 250～400Tex (Tekes); The fiber yarn of twisted and plied formation 600～800Tex, the textiles bulk density of production is 700Kg/m
3, product igloss is 5%, and moisture content is 0.5%, and washing shrinkage is 0.5%.All the other are with example 1.
Embodiment 16
Soluble fibre part material proportioning (kg): SiO
250.5 part, 35 parts of CaO, 10 parts of MgO, B
2O
32 parts, Al
2O
31 part, Fe
2O
30.5 part, Na
20.5 part of O, K
20.5 part of O; 1800～2000 ℃ of fusions; 0.3～0.6Mpa blast; Diameter 6～10 μ m; Length 150～250mm; Slag ball content 5～14%; Solubility 180～250mg/L.Solvable textiles part material proportioning (kg): soluble fibre 88%; Organic fiber (viscose) 10%; Auxiliary agent 2% (with 0.5 part of crude oil, 1 part in antistatic additive, 0.5 part of conditioner of spinning, and will put into 40 ℃ warm water in oil with crude oil, antistatic additive, spinning conditioning: the ratio of water=1: 11 is diluted).Vexed storehouse 18h; Yarn twisting forms the silvalin of 250～400Tex (Tekes): the twisting Taiwan stocks form the fiber yarn of 600～800Tex, and the textiles bulk density of production is 700Kg/m
3, product igloss is 10%, and moisture content is 0.5%, and washing shrinkage is 0.5%.All the other are with example 1.
Claims (6)
1. an inorganic silicate fiber textile that dissolves in human body fluid is characterized in that this fiber textile predominant quantity percentage composition is: soluble fibre 85-95%; Organic fiber 3-12%; Auxiliary agent 0.1-3%.
2. according to the described inorganic silicate fiber textile that dissolves in human body fluid of claim 1, it is characterized in that wherein said soluble fibre, is the inorganic silicate fiber that dissolves in human body fluid, and the weight percent of this fiber consists of:
SiO
2 50.5～85％
CaO 5.5～35％
MgO 1～10％
B
2O
3 1～2％
Al
2O
3 0～1％
Fe
2O
3 0～0.5％
Na
2O 0～0.5％
K
2O 0～0.5％。
3. according to the described inorganic silicate fiber textile that dissolves in human body fluid of claim 1, it is characterized in that wherein said organic fiber is viscose, fire resistance fibre and/or string.
4. according to the described inorganic silicate fiber textile that dissolves in human body fluid of claim 1, it is characterized in that wherein said auxiliary agent is and crude oil, antistatic additive and/or spinning conditioner.
5. according to the described method for making that dissolves in the inorganic silicate fiber textile of human body fluid of claim 1, it is characterized in that described soluble fibre mixes by proportioning with organic fiber, warp and hair, carding, spun yarn, twisting, plying, winder and weaving process are produced soluble fibre cloth, soluble fibre rope, soluble fibre alternate product respectively;
6. according to the described method for making that dissolves in the inorganic silicate fiber textile of human body fluid of claim 1, it is characterized in that the auxiliary agent of described wool blending step will adopt 30～50 ℃ warm water to dilute, dilution ratio is an oil: water=1: 5～15; Be sprayed on uniformly then on the soluble fibre and organic fiber that shredding finishes; The mixed raw material of starting shooting will enter operation down in 8～24 hours in vexed storehouse in wool bin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310105705 CN1242105C (en) | 2003-11-24 | 2003-11-24 | Human body fluid dissoluble inorganic ceramic fiber textile material and process of production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310105705 CN1242105C (en) | 2003-11-24 | 2003-11-24 | Human body fluid dissoluble inorganic ceramic fiber textile material and process of production |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1544730A CN1544730A (en) | 2004-11-10 |
| CN1242105C true CN1242105C (en) | 2006-02-15 |
Family
ID=34333870
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|---|---|---|---|
| CN 200310105705 Expired - Lifetime CN1242105C (en) | 2003-11-24 | 2003-11-24 | Human body fluid dissoluble inorganic ceramic fiber textile material and process of production |
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|---|---|
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101654865B (en) * | 2009-09-17 | 2012-09-26 | 江阴市华晓纺织有限公司 | Pretreatment method of viscose fibers and processing method of terylene-viscose blended knitting yarn |
| JP6212040B2 (en) * | 2012-06-29 | 2017-10-11 | ニチアス株式会社 | Heat resistant inorganic fiber |
| CN108656657A (en) * | 2018-03-26 | 2018-10-16 | 相里海霞 | A kind of cashmere cotton face fabric |
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2003
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|---|---|
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Address after: 256120 Shandong city of Zibo province Yiyuan County Yi River Road No. 11 Patentee after: LUYANG ENERGY-SAVING MATERIALS Co.,Ltd. Address before: 256120 Shandong city of Zibo province Yiyuan County Yi River Road No. 11 Patentee before: Shandong Luyang Share Co.,Ltd. |
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