CN1236037C - Detergent for equipment for producing and processing synthetic fibre - Google Patents

Detergent for equipment for producing and processing synthetic fibre Download PDF

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Publication number
CN1236037C
CN1236037C CN 200410014057 CN200410014057A CN1236037C CN 1236037 C CN1236037 C CN 1236037C CN 200410014057 CN200410014057 CN 200410014057 CN 200410014057 A CN200410014057 A CN 200410014057A CN 1236037 C CN1236037 C CN 1236037C
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poe
ether
amine
salt
clean
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CN1557927A (en
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长谷昌浩
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ZHUBEN OIL (SUZHOU) CO Ltd
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ZHUBEN OIL (SUZHOU) CO Ltd
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Abstract

The present invention relates to a detergent used on equipment for producing and processing synthetic fibers. The present invention is characterized in that the detergent comprises water solutions with the following and contents: 10 to 30 wt% of trialkylamine oxide (A), 2 to 10 wt% of alkyl phosphoric acid ester salt (B) and 5 to 20 wt% of polyether compound (C) whose molecular weight is 200 to 800. A cleaning agent which is more easy in use can be obtained after the constituent (C) is added on the basis of constituents (A), (B). The detergent of the present invention is composed of the mixture of the water solutions with surface activity. The pH value of the present invention is 6 to 9 which is an optimum value for a special yarn path washing detergent used on equipment for producing and processing synthetic fibers.

Description

Synthon are made the processing units clean-out system
Technical field
The present invention relates to a kind of clean-out system, particularly a kind ofly be applicable to that synthon are made and remove the cast piled up in the road and the scavenger specially of thing inferior on the processing units.
Background technology
In recent years, the synthon with high-quality characteristic and nominal price were used widely, and output is also increasing.And aspect the manufacturing of synthon, for fully representing its high-quality characteristic, the use of heating process is more and more, such as, for obtaining the drafting process that intensity adopted, for the curling operation that makes synthon curl and be adopted, for allowing the bulk twisting manufacturing procedure that adopts of synthon etc.In these heating processes, coming off after having silk itself softening also has the polymkeric substance and the various additive that contain on the silk to come off from the silk road, and for improving phenomenon generation such as coming off of treatment agent that processibility is used.Because it is roasting that these casts are shone by high temperature for a long time, become the thing inferior of coking shape and solid state on the silk road.These things inferior are stayed the obstacle that becomes the silk operation in the road easily, cause broken end, bad generation phenomenon such as lousiness.Therefore under this situation, for keeping good operability and quality product, the silk road of routine cleaning equipment has become to make essential operation steps in the processing.Yet, down roasting in the high temperature solarization, above-mentioned thing inferior is very difficult to cleaning because time and temperature action become, especially in the operation of heat silk, cotton, cast goes bad into coking shape thing and carbide after being baked by the long-time solarization of pyritous heat, is difficult to more clean.Therefore in such operation, clean-out operation is arranged in cast than carrying out under the state that is easier to remove as far as possible, processes but carry out the necessary again manufacturing of interrupting synthon of clean-out operation, if clean-out operation too much must make productivity descend.So for boosting productivity, a kind of mode of production that long-time continuous operation and the clean-out operation of short period of time combine is expected by manufacturerss, wherein, effectively clean-out system has just become the key that addresses this problem.
Usually, the special clean-out system of needs all is so that constantly the coking and the carbide of generation are the scrubbing object after the cast heat damaging.These dirts become jelly owing to add the thermogenesis crosslinking reaction, water insoluble and solvent, and also the general physical operation also is difficult to remove.Once try several clean-out systems in the past, but all do not reach gratifying effect.Now, the clean-out operation great majority use the aqueous solution of alkaline inorganic compound, specifically be that the aqueous solution after the dilution of alkaline inorganic compounds such as sodium hydroxide, sodium bicarbonate, yellow soda ash, potassium hydroxide is spread upon on the dirt, if possible preferably promote the reaction of it and dirt, then it is wiped by heating.From present present situation, this purging method is the most practical, but the alkalescence of this detergent solution is very strong, in case contact skin and mucous membrane, can bring grievous injury to human body, and cause environmental pollution easily, therefore wish to have the appearance of the more weak clean-out system of a kind of corrodibility.
The objective of the invention is: in the operation, particularly this operation that wherein need heat of making the processing synthon, provide can be abundant and safe clean and remove clean-out system that adds the thermal degradation when thing and the purging method that comes off on the equipment such as a road.
Summary of the invention
For achieving the above object, the technical solution used in the present invention is: a kind of synthon are made the processing units clean-out system, and it contains the aqueous solution of following active constituent and content:
(A): tertiary amino oxides 10～30% weight;
(B): alkyl phosphate salt 2～10% weight.
The related content and the change interpretation of technique scheme are as follows:
1, about clean-out system (A) active constituent---tertiary amino oxides.As clean-out system composition of the present invention (A), tertiary amino oxides can use the oxide compound of various amine, specifically comprises:
Fats oxidn tertiary amines such as octyl group amine oxide, lauryl alcohol amine oxide, hexadecyl amine oxide, butyl amine oxide, trimethylammonium amine oxide, second dimethyl oxidation amine, triethyl amine oxide, tripropyl amine oxide, the third dimethyl oxidation amine, fourth dimethyl oxidation amine, hot dimethyl oxidation amine, 2-ethylhexyl diformazan amine oxide, laurel tallow dimethyl oxidation amine, CH3-(CH2)13N(CH3)2-O, cetyl dimethyl amine oxide, vaccenic acid base dimethyl oxidation amine;
Aromatic series oxidation amines such as dimethylbenzene oxidation amine, diethylbenzene amine oxide.
In the above tertiary amino oxides, contain the alkyl of carbon number 8 to 18 or have better with the alkenyl of carbon number.
2, about clean-out system (B) active constituent---alkyl phosphate salt.As the composition (B) of clean-out system of the present invention, alkyl phosphate salt can use various phosphoric acid ester.
Specifically include: basic metal, amine, the salt in season of alkyl phosphates such as butyl phosphoric acid ester sylvite, butyl phosphoric acid ester sodium salt, octyl phosphate sodium salt, octyl phosphate sylvite, ethylhexyl dihydrogen phosphate front three amine salt, laurel tallow phosphate kalium salt, laurel tallow phosphoric acid ester tetramethyl amine salt, hexadecanyl phosphate sylvite, POE (15) hexadecanyl phosphate sodium salt, stearic phosphoric acid ester triethanolamine salt;
On butanols, add the phosphoric acid ester sodium of the alkane ether thing (being called for short POE (4), as follows) of 4 oxyethane, POE (2) Octyl Ether phosphate kalium salt, { POP (2)/POE (3) } Octyl Ether phosphate kalium salt, { POP (3)/POE (3) } Octyl Ether phosphoric acid ester sodium, POE (5) ethylhexyl dihydrogen phosphate front three amine salt, POE (5) lauryl alcohol phosphoric acid ester tetramethyl amine salt, { POP (2)/POE (4) } lauryl alcohol phosphate kalium salt, lauryl alcohol phosphoric acid ester tetramethyl amine salt, POE (3) hexadecyl ether phosphate triethanolamine salt, the salt identical of polyoxy allylic alkylation ether phosphates such as POE (5) octadecane ether phosphate sylvite with preceding note.Wherein contain the alkyl of carbon number 8 to 18 or alkenyl for well, its general formula is as follows:
In the formula:
R: the alkyl of expression carbon number 8 to 18 or with the alkenyl of carbon number;
A: the alkylidene group of representing carbon number 2 or 3;
M: expression hydrogen or basic metal, organic amine, organic;
M: expression 1 or 2;
N: the integer of expression 0 to 10;
O: expression oxygen;
P: expression phosphorus.
The occasion carbon number of alkyl phosphate salt be 8 to 14 better.
More than in the expression: " POE ": polyoxyethylene; " POP ": polyoxypropylene; " (numeral) ": numeral is for containing the oxy alkylene number; It in " { } " containing oxygen ethene, containing oxypropylene of adding at random.Such as the material of having represented to add group in { } according to the order of POP, POE.
The cationic moiety of these compounds is fatty amines such as basic metals such as lithium, sodium, potassium, dimethylamine, Trimethylamine 99, diethylamine, triethylamine, butylamine, dibutylamine, Tributylamine, octylame; Alkanolamine such as thanomin, diethanolamine, trolamine, methyldiethanolamine, ethyldiethanolamine, butyl diethanolamine, octyl group diethanolamine; Formations such as tetramethylammonium, Tetrylammonium, ethyl TMA (TriMethylAmine), butyl TMA (TriMethylAmine), front three phosphorus, three second phosphorus etc. are organic.In amine, organic class, water-soluble high for well, in the molecule of cationic moiety total carbon number add up to 8 below better.
3, in the such scheme, contain composition (A) and (B), just can reach the purpose at initial stage, can access the clean-out system that is more prone to use but add composition (C) on this basis.Composition (C) can use the various polyether compounds of molecular weight 200 to 800, and its content is 5～20% weight.
Specifically include: the oxyalkylene group polyethers that adds carbon number 2 to 3 on the 1 valency alcohols such as methyl alcohol, ethanol, butanols, octanol, 2-Ethylhexyl Alcohol, bay lipidol, different tridecanol, hexadecyl alcohol, oleyl alcohol; Glycol, glycol ether, propylene glycol, 1, the polyethers of adding the oxyalkylene of carbon number 2 to 3 on the divalent alcohols such as 6-hexyl glycol; Add the polyethers of the oxyalkylene of carbon number 2 to 3 on the multivalence alcohols such as glycol, glycerine, TriMethylolPropane(TMP), Sorbitol Powder; Add the polyethers of the oxyalkylene of carbon number 2 to 3 on the phenol such as phenol, butylphenol, octyl phenol, nonylbenzene phenol.Wherein use the divalent alcohols and contain the alkyl of carbon number 1 to 18 or 1 valency alcohols of alkenyl for well, its general formula is as follows:
R’O-(A’O)qH
In the formula:
R ': the alkyl of expression hydrogen or carbon number 1 to 18 or with the alkenyl of carbon number;
A ': the industry alkyl of representing carbon number 2 or 3;
Q: the integer of expression 4 to 18;
O: expression oxygen;
H: expression hydrogen.
4, about the content problem of each component.Clean-out system of the present invention is made of mentioned component, in order to produce effect, contains in clean-out system:
(A): tertiary amino oxides 10～30% weight ranges;
(B): alkyl phosphate salt 2～10% weight ranges.
(A)+(B) total must reach 12～40% weight ranges.Break away from this scope, can not get desirable effect or be difficult to using.It is better to amount to 15～40% weight ranges.
In addition, when using composition (C):
(A): tertiary amino oxides 10～30% weight ranges;
(B): alkyl phosphate salt 2～10% weight ranges;
(C): polyether compound 5～20% weight ranges.
And (A), the Meter that closes of (B), (C) is 17～60% weight ranges, breaks away from this scope, can not get desirable effect or be difficult to using.
Wherein,
(A): tertiary amino oxides 10～25% weight ranges;
(B): alkyl phosphate salt 2～10% weight ranges;
(C): polyether compound 5～20% weight ranges of molecular weight 200 to 800;
And (A), the Meter that closes of (B), (C) is 20～40% weight range better effects if.
5, for making the safer more convenient use of clean-out system of the present invention, that pH is approaching neutral, the scope 6 to 9.Specifically be after mentioned component is in harmonious proportion, to use a little acid or alkali if necessary in right amount, the pH value that just can adjust clean-out system is in above-mentioned scope.If pH does not meet this when requiring, the aspects such as corrodibility in the time of will be in the stability of product and with skin contact are affected, and our desirable characteristic just may be not easy embodiment.
6, clean-out system of the present invention also can add other compositions of use by mentioned component (A) and (B) and better composition (A) and (B) and (C) constituting under the prerequisite that does not influence effect of the present invention, for example, and defoamer, sanitas or the like.
7, clean-out system of the present invention is constituted by having surface-active mixture aqueous solution, scavenger specially as synthon manufacturing processing units cleaning silk road in specific pH scope is only, its purging method is: directly or after aqueous solution dilution, be coated onto the necessary part of equipment, and such as the silk road.Though this method of smearing is not special, generally is with smearing methods such as spraying process or brushings.Hot spots can be smeared under original temperature when smearing in addition.Under the too high situation of temperature, can reduce the temperature to possible temperature and smear.The amount of smearing must be able to state that the deterioration thing is covered fully.Smearing the back according to the situation of deterioration thing uses cloth to wipe with just passable under simple situation.Use when using cloth to wipe with to fall simple utensil as far as possible not injury equipment carry out wiping, it is dried to use cloth to wipe with after major part is wiped again.
Clean-out system of the present invention can be used for each fibrid, synthon as object are polyester series fiber, nylon-6s such as polyethylene terephthalate (terylene), polybutylene terephthalate, Poly(Trimethylene Terephthalate), poly-lactic acid ester, various fibers such as polyolefin fibers, polyacrylonitrile fibre such as polymeric amide such as nylon-66 series fiber, polyethylene, polypropylene, be particularly suitable for the polyester series fiber, the polymeric amide series fiber that are used for heating process are made, the equipment of processing can be brought into play good effect.
Embodiment
Below in conjunction with embodiment the present invention is further described:
Below, for formation of the present invention and effect is more specific, be illustrated with embodiment and comparative example.The present invention only is limited in these examples of implementation.
Table 1～table 5 has shown the clean-out system composition of embodiment 1～92, and table 6 has shown the clean-out system composition of comparative example 1～7.In the table:
POE: expression polyoxyethylene
POP: expression polyoxypropylene
(numeral): numeral is for containing the oxy alkylene number
{ } b: the expression group is paid and is added body
{ } r: expression is paid at random and is added body
Estimate product stability and the detergency that this clean-out system is formed according to following method.
1, the evaluation method of product stability
The clean-out system 300ml that adjusts is put in the beaker of 500ml, and lid is not at 20 degree, and the state of humidity 65% is placed the evaluation of opening stability after 3 days down.According to macroscopic various results with following method evaluation.
◎: fully during with adjustment not become
Zero: visible a little tackify in surface
△: tackify can be clearly seen on the surface
*: can see layering
2, the evaluation method of detergency
With polyester filament continuous spinning fortnight under the condition of GR1=90 degree, GR2=135 degree (godet roller abbreviates GR as), winding speed 4600m/min in hole, SD 75 dawn/36, obtain adhering to the GR test portion (going up the GR2 of note) of dirt.With this GR surface, as the test portion of estimating usefulness.Use the treatment agent that demonstration is formed in the table 1, remain on and remember on the various piece of GR test portion before 80 degree spread upon with hairbrush down, placed 15 minutes.With cloth the surface is wiped then.The surface that detects by an unaided eye, following note evaluation.
Detergency:
◎: the not residual dirt of major part
Zero: residual dirt area is below 10%
△: residual dirt area is 10 to 25%
*: residual dirt area is more than 25%
The result who draws is in li demonstration of table 1～table 6.
Show as can be known that by table 1～table 6 clean-out system of the present invention is being very outstanding aspect clean effect and the product stability.
Table 1 Treatment agent composition, concentration and effect Embodiment
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19
Composition (A) The octyl group amine oxide 24 15 24 24 24 24 24 20 20 20
The lauryl alcohol amine oxide 20 20 20 20
The hexadecyl amine oxide 24
The butyl amine oxide 24 20 20 20
The trimethylammonium amine oxide
Second dimethyl oxidation amine
The tripropyl amine oxide
The triethyl amine oxide
The third dimethyl oxidation amine
Fourth dimethyl oxidation amine
Hot dimethyl oxidation amine
2-ethylhexyl diformazan amine oxide
Laurel tallow dimethyl oxidation amine
CH3-(CH2)13N(CH3)2-O
Cetyl dimethyl amine oxide
Vaccenic acid base dimethyl oxidation amine
Dimethylbenzene oxidation amine
The diethylbenzene amine oxide
Composition (B) Butyl phosphoric acid ester sylvite 6
The butyl phosphoric acid ester sodium salt
The octyl phosphate sodium salt 6 4 6 6 5 5
Octyl phosphate sylvite 5
Ethylhexyl dihydrogen phosphate front three amine salt 5
The laurel tallow phosphate kalium salt 5
Laurel tallow phosphoric acid ester tetramethyl amine salt 5
Hexadecanyl phosphate sylvite
POE (15) hexadecanyl phosphate sodium salt 6
Stearic phosphoric acid ester triethanolamine salt
POE (2) Octyl Ether phosphate kalium salt 5
{ POP (2)/POE (3) } Octyl Ether phosphate kalium salt
POE (4) phosphoric acid ester sodium
{ POP (3)/POE (3) } b Octyl Ether phosphoric acid ester sodium 6 5 5 5
POE (5) ethylhexyl dihydrogen phosphate front three amine salt
POE (5) lauryl alcohol phosphoric acid ester tetramethyl amine salt
{ POP (2)/POE (4) } r lauryl alcohol phosphoric acid ester potassium 6
Lauryl alcohol phosphoric acid ester tetramethyl amine salt 6
POE (3) hexadecyl ether phosphate triethanolamine salt
POE (5) octadecane ether phosphate sylvite
Composition (C) POE (10) methanol-ethers 10 10 10 10 10 10 10
POE (5) ethanol ether
{ POP (3)/POE (10) } b butanols ether 10
{ POP (2)/POE (8) } r octanol ether 10
POE (5) 2-Ethylhexyl Alcohol ether
POE (5) laurel tallow alcohol ether
{ POP (1)/POE (4) } different tridecanol ether of b
{ POP (2)/POE (6) } r hexadecyl alcohol ether
POE (5) oleyl alcohol ether
Polyethylene glycol (molecular weight 400) 10
POE (5) glycol ether ether
POE (8) propylene glycol
{ POP (2)/POE (5) } b 1,6-hexyl glycol ethers
POE (10) glycol ether
POE (5) glyceryl ether
POE (6) TriMethylolPropane(TMP) ether
POE (5) sorbose alcohol ether
POE (7) phenol ether
POE (5) butylbenzene phenolic ether
POE (4) octyl phenol ether
POE (4) nonylbenzene phenolic ether
Concentration (weight %) 30 19 30 30 30 30 30 30 30 35 35 35 35 35 35 35 35 35 35
Product stability ○ ○ ○ ○ ○ ○ ○ ○ ○ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎
Detergency ◎ ◎ ◎ ○ ◎ ○ ◎ ○ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎
Table 2 Treatment agent composition, concentration and effect Embodiment
20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38
Composition (A) The octyl group amine oxide
The lauryl alcohol amine oxide 20
The hexadecyl amine oxide
The butyl amine oxide 20
The trimethylammonium amine oxide 20 20 20 20 20
Second dimethyl oxidation amine 20 20 20 20 20
The tripropyl amine oxide 20 20 20 20
The triethyl amine oxide 20
The third dimethyl oxidation amine 20
Fourth dimethyl oxidation amine 20
Hot dimethyl oxidation amine
2-ethylhexyl diformazan amine oxide
Laurel tallow dimethyl oxidation amine
CH3-(CH2)13N(CH3)2-O
Cetyl dimethyl amine oxide
Vaccenic acid base dimethyl oxidation amine
Dimethylbenzene oxidation amine
The diethylbenzene amine oxide
Composition (B) Butyl phosphoric acid ester sylvite
The butyl phosphoric acid ester sodium salt
The octyl phosphate sodium salt 5 5 5 5 5 5
Octyl phosphate sylvite
Ethylhexyl dihydrogen phosphate front three amine salt
The laurel tallow phosphate kalium salt
Laurel tallow phosphoric acid ester tetramethyl amine salt
Hexadecanyl phosphate sylvite 5
POE (15) hexadecanyl phosphate sodium salt 5
Stearic phosphoric acid ester triethanolamine salt 5
POE (2) Octyl Ether phosphate kalium salt 5
{ POP (2)/POE (3) } Octyl Ether phosphate kalium salt 5
POE (4) phosphoric acid ester sodium 5
{ POP (3)/POE (3) } b Octyl Ether phosphoric acid ester sodium 5
POE (5) ethylhexyl dihydrogen phosphate front three amine salt 5
POE (5) lauryl alcohol phosphoric acid ester tetramethyl amine salt 5
{ POP (2)/POE (4) } r lauryl alcohol phosphoric acid ester potassium 5
Lauryl alcohol phosphoric acid ester tetramethyl amine salt 5
POE (3) hexadecyl ether phosphate triethanolamine salt 5
POE (5) octadecane ether phosphate sylvite 5
Composition (C) POE (10) methanol-ethers 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10
POE (5) ethanol ether
{ POP (3)/POE (10) } b butanols ether
{ POP (2)/POE (8) } r octanol ether
POE (5) 2-Ethylhexyl Alcohol ether
POE (5) laurel tallow alcohol ether
{ POP (1)/POE (4) } different tridecanol ether of b
{ POP (2)/POE (6) } r hexadecyl alcohol ether
POE (5) oleyl alcohol ether
Polyethylene glycol (molecular weight 400)
POE (5) glycol ether ether
POE (8) propylene glycol
{ POP (2)/POE (5) } b 1,6-hexyl glycol ethers
POE (10) glycol ether
POE (5) glyceryl ether
POE (6) TriMethylolPropane(TMP) ether
POE (5) sorbose alcohol ether
POE (7) phenol ether
POE (5) butylbenzene phenolic ether
POE (4) octyl phenol ether
POE (4) nonylbenzene phenolic ether
Concentration (weight %) 35 35 35 35 35 35 35 35 35 35 35 35 35 35 35 35 35 35 35
Product stability ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎
Detergency ◎ ◎ ◎ ○ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎
Table 3 Treatment agent composition, concentration and effect Embodiment
39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57
Composition (A) The octyl group amine oxide 20 20 20 20 20 20 20 20 20
The lauryl alcohol amine oxide
The hexadecyl amine oxide
The butyl amine oxide
The trimethylammonium amine oxide
Second dimethyl oxidation amine
The tripropyl amine oxide
The triethyl amine oxide
The third dimethyl oxidation amine
Fourth dimethyl oxidation amine
Hot dimethyl oxidation amine 20
2-ethylhexyl diformazan amine oxide 20
Laurel tallow dimethyl oxidation amine 20
CH3-(CH2)13N(CH3)2-O 20
Cetyl dimethyl amine oxide 20
Vaccenic acid base dimethyl oxidation amine 20
Dimethylbenzene oxidation amine 20
The diethylbenzene amine oxide 20
Composition (B) Butyl phosphoric acid ester sylvite 20
The butyl phosphoric acid ester sodium salt 20
The octyl phosphate sodium salt 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5
Octyl phosphate sylvite
Ethylhexyl dihydrogen phosphate front three amine salt
The laurel tallow phosphate kalium salt
Laurel tallow phosphoric acid ester tetramethyl amine salt
Hexadecanyl phosphate sylvite
POE (15) hexadecanyl phosphate sodium salt
Stearic phosphoric acid ester triethanolamine salt
POE (2) Octyl Ether phosphate kalium salt
{ POP (2)/POE (3) } Octyl Ether phosphate kalium salt
POE (4) phosphoric acid ester sodium
{ POP (3)/POE (3) } b Octyl Ether phosphoric acid ester sodium
POE (5) ethylhexyl dihydrogen phosphate front three amine salt
POE (5) lauryl alcohol phosphoric acid ester tetramethyl amine salt
{ POP (2)/POE (4) } r lauryl alcohol phosphoric acid ester potassium
Lauryl alcohol phosphoric acid ester tetramethyl amine salt
POE (3) hexadecyl ether phosphate triethanolamine salt
POE (5) octadecane ether phosphate sylvite
Composition (C) POE (10) methanol-ethers 10 10 10 10 10 10 10 10 10 10
POE (5) ethanol ether 10
{ POP (3)/POE (10) } b butanols ether 10
{ POP (2)/POE (8) } r octanol ether 10
POE (5) 2-Ethylhexyl Alcohol ether 10
POE (5) laurel tallow alcohol ether 10
{ POP (1)/POE (4) } different tridecanol ether of b 10
{ POP (2)/POE (6) } r hexadecyl alcohol ether 10
POE (5) oleyl alcohol ether 10
Polyethylene glycol (molecular weight 400) 10
POE (5) glycol ether ether
POE (8) propylene glycol
{ POP (2)/POE (5) } b 1,6-hexyl glycol ethers
POE (10) glycol ether
POE (5) glyceryl ether
POE (6) TriMethylolPropane(TMP) ether
POE (5) sorbose alcohol ether
POE (7) phenol ether
POE (5) butylbenzene phenolic ether
POE (4) octyl phenol ether
POE (4) nonylbenzene phenolic ether
Concentration (weight %) 35 35 35 35 35 35 35 35 35 35 35 35 35 35 35 35 35 35 35
Product stability ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎
Detergency ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎
Table 4 Treatment agent composition, concentration and effect Embodiment
58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76
Composition (A) The octyl group amine oxide 20 20 20 20 20 20 20 20 20 20 20 15
The lauryl alcohol amine oxide 15
The hexadecyl amine oxide 15
The butyl amine oxide 15
The trimethylammonium amine oxide 15
Second dimethyl oxidation amine 15
The tripropyl amine oxide 15
The triethyl amine oxide 15
The third dimethyl oxidation amine
Fourth dimethyl oxidation amine
Hot dimethyl oxidation amine
2-ethylhexyl diformazan amine oxide
Laurel tallow dimethyl oxidation amine
CH3-(CH2)13N(CH3)2-O
Cetyl dimethyl amine oxide
Vaccenic acid base dimethyl oxidation amine
Dimethylbenzene oxidation amine
The diethylbenzene amine oxide
Composition (B) Butyl phosphoric acid ester sylvite 3
The butyl phosphoric acid ester sodium salt
The octyl phosphate sodium salt 5 5 5 5 5 5 5 5 5 5 5 3 3
Octyl phosphate sylvite
Ethylhexyl dihydrogen phosphate front three amine salt 3
The laurel tallow phosphate kalium salt
Laurel tallow phosphoric acid ester tetramethyl amine salt 3
Hexadecanyl phosphate sylvite
POE (15) hexadecanyl phosphate sodium salt 3
Stearic phosphoric acid ester triethanolamine salt
POE (2) Octyl Ether phosphate kalium salt 3
{ POP (2)/POE (3) } Octyl Ether phosphate kalium salt
POE (4) phosphoric acid ester sodium
{ POP (3)/POE (3) } b Octyl Ether phosphoric acid ester sodium
POE (5) ethylhexyl dihydrogen phosphate front three amine salt
POE (5) lauryl alcohol phosphoric acid ester tetramethyl amine salt
{ POP (2)/POE (4) } r lauryl alcohol phosphoric acid ester potassium
Lauryl alcohol phosphoric acid ester tetramethyl amine salt
POE (3) hexadecyl ether phosphate triethanolamine salt
POE (5) octadecane ether phosphate sylvite
Composition (C POE (10) methanol-ethers
POE (5) ethanol ether 7
{ POP (3)/POE (10) } b butanols ether
{ POP (2)/POE (8) } r octanol ether
POE (5) 2-Ethylhexyl Alcohol ether 7
POE (5) laurel tallow alcohol ether
{ POP (1)/POE (4) } different tridecanol ether of b
{ POP (2)/POE (6) } r hexadecyl alcohol ether 7
POE (5) oleyl alcohol ether
Polyethylene glycol (molecular weight 400)
POE (5) glycol ether ether 10 7
POE (8) propylene glycol 10
{ POP (2)/POE (5) } b 1,6-hexyl glycol ethers 10
POE (10) glycol ether 10 7
POE (5) glyceryl ether 10
POE (6) TriMethylolPropane(TMP) ether 10
POE (5) sorbose alcohol ether 10 7
POE (7) phenol ether 10
POE (5) butylbenzene phenolic ether 10
POE (4) octyl phenol ether 10 7
POE (4) nonylbenzene phenolic ether 10 7
Concentration (weight %) 35 35 35 35 35 35 35 35 35 35 35 25 25 25 25 25 25 25 25
Product stability ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎
Detergency ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ○ ◎ ○ ◎ ○ ◎ ◎
Table 5 Treatment agent composition, concentration and effect Embodiment
77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92
Composition (A) The octyl group amine oxide 15 15 96 97 98 99
The lauryl alcohol amine oxide 15 15 15 5
The hexadecyl amine oxide
The butyl amine oxide
The trimethylammonium amine oxide
Second dimethyl oxidation amine
The tripropyl amine oxide
The triethyl amine oxide
The third dimethyl oxidation amine 15
Fourth dimethyl oxidation amine 15
Hot dimethyl oxidation amine 15
2-ethylhexyl diformazan amine oxide 15
Laurel tallow dimethyl oxidation amine 15
CH3-(CH2)13N(CH3)2-O 15
Cetyl dimethyl amine oxide 15
Vaccenic acid base dimethyl oxidation amine 15
Dimethylbenzene oxidation amine 15
The diethylbenzene amine oxide 15
Composition (B) Butyl phosphoric acid ester sylvite
The butyl phosphoric acid ester sodium salt 3
The octyl phosphate sodium salt
Octyl phosphate sylvite 3 3 3 3 1
Ethylhexyl dihydrogen phosphate front three amine salt
The laurel tallow phosphate kalium salt 3
Laurel tallow phosphoric acid ester tetramethyl amine salt
Hexadecanyl phosphate sylvite 3
POE (15) hexadecanyl phosphate sodium salt
Stearic phosphoric acid ester triethanolamine salt 3
POE (2) Octyl Ether phosphate kalium salt
{ POP (2)/POE (3) } Octyl Ether phosphate kalium salt
POE (4) phosphoric acid ester sodium
{ POP (3)/POE (3) } b Octyl Ether phosphoric acid ester sodium 3
POE (5) ethylhexyl dihydrogen phosphate front three amine salt 3
POE (5) lauryl alcohol phosphoric acid ester tetramethyl amine salt 3
{ POP (2)/POE (4) } r lauryl alcohol phosphoric acid ester potassium 3
Lauryl alcohol phosphoric acid ester tetramethyl amine salt 3
POE (3) hexadecyl ether phosphate triethanolamine salt 3
POE (5) octadecane ether phosphate sylvite 3
Composition (C) POE (10) methanol-ethers 2
POE (5) ethanol ether
{ POP (3)/POE (10) } b butanols ether 7
{ POP (2)/POE (8) } r octanol ether 7
POE (5) 2-Ethylhexyl Alcohol ether
POE (5) laurel tallow alcohol ether 7
{ POP (1)/POE (4) } different tridecanol ether of b 7
{ POP (2)/POE (6) } r hexadecyl alcohol ether
POE (5) oleyl alcohol ether 7
Polyethylene glycol (molecular weight 400) 7
POE (5) glycol ether ether
POE (8) propylene glycol 7
{ POP (2)/POE (5) } b 1,6-hexyl glycol ethers 7
POE (10) glycol ether
POE (5) glyceryl ether 7
POE (6) TriMethylolPropane(TMP) ether 7
POE (5) sorbose alcohol ether
POE (7) phenol ether 7
POE (5) butylbenzene phenolic ether 7
POE (4) octyl phenol ether 7
POE (4) nonylbenzene phenolic ether 7 7
Concentration (weight %) 25 25 25 25 25 25 25 25 25 25 25 25 25 25 25 8
Product stability ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎
Detergency ◎ ◎ ◎ ○ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ○
Table 6 Treatment agent composition, concentration and effect Comparative example
1 2 3 4 5 6 7
Composition (A) The octyl group amine oxide 20 20 10 25
The lauryl alcohol amine oxide
The hexadecyl amine oxide
The butyl amine oxide
The trimethylammonium amine oxide
Second dimethyl oxidation amine
The tripropyl amine oxide
The triethyl amine oxide
The third dimethyl oxidation amine
Fourth dimethyl oxidation amine
Hot dimethyl oxidation amine
2-ethylhexyl diformazan amine oxide
Laurel tallow dimethyl oxidation amine
CH3-(CH2)13N(CH3)2-O
Cetyl dimethyl amine oxide
Vaccenic acid base dimethyl oxidation amine
Dimethylbenzene oxidation amine
The diethylbenzene amine oxide
Composition (B) Butyl phosphoric acid ester sylvite 2 10
The butyl phosphoric acid ester sodium salt
The octyl phosphate sodium salt 20 20
Octyl phosphate sylvite
Ethylhexyl dihydrogen phosphate front three amine salt
The laurel tallow phosphate kalium salt
Laurel tallow phosphoric acid ester tetramethyl amine salt
Hexadecanyl phosphate sylvite
POE (15) hexadecanyl phosphate sodium salt
Stearic phosphoric acid ester triethanolamine salt
POE (2) Octyl Ether phosphate kalium salt
{ POP (2)/POE (3) } Octyl Ether phosphate kalium salt
POE (4) phosphoric acid ester sodium
{ POP (3)/POE (3) } b Octyl Ether phosphoric acid ester sodium
POE (5) ethylhexyl dihydrogen phosphate front three amine salt
POE (5) lauryl alcohol phosphoric acid ester tetramethyl amine salt
{ POP (2)/POE (4) } r lauryl alcohol phosphoric acid ester potassium
Lauryl alcohol phosphoric acid ester tetramethyl amine salt
POE (3) hexadecyl ether phosphate triethanolamine salt
POE (5) octadecane ether phosphate sylvite
Composition (C) POE (10) methanol-ethers 20 10 10
POE (5) ethanol ether
{ POP (3)/POE (10) } b butanols ether
{ POP (2)/POE (8) } r octanol ether
POE (5) 2-Ethylhexyl Alcohol ether
POE (5) laurel tallow alcohol ether
{ POP (1)/POE (4) } different tridecanol ether of b
{ POP (2)/POE (6) } r hexadecyl alcohol ether
POE (5) oleyl alcohol ether
Polyethylene glycol (molecular weight 400)
POE (5) glycol ether ether
POE (8) propylene glycol
{ POP (2)/POE (5) } b 1,6-hexyl glycol ethers
POE (10) glycol ether
POE (5) glyceryl ether
POE (6) TriMethylolPropane(TMP) ether
POE (5) sorbose alcohol ether
POE (7) phenol ether
POE (5) butylbenzene phenolic ether
POE (4) octyl phenol ether
POE (4) nonylbenzene phenolic ether
Concentration (weight %) 20 20 20 30 30 12 45
Product stability ○ ○ ○ ○ ○ ×
Detergency △ × × △ × △ ◎

Claims (7)

1, a kind of synthon are made the processing units clean-out system, it is characterized in that containing the aqueous solution of following active constituent and content:
(A): tertiary amino oxides 10～30% weight;
(B): alkyl phosphate salt 2～10% weight.
2, clean-out system according to claim 1 is characterized in that: contain the alkyl of carbon number 8～18 in the described tertiary amino oxides or have alkenyl with carbon number.
3, clean-out system according to claim 1 is characterized in that: the general formula of described alkyl phosphate salt is as follows:
Figure C2004100140570002C1
In the formula:
R: the alkyl of expression carbon number 8 to 18 or with the alkenyl of carbon number;
A: the alkylidene group of representing carbon number 2 or 3;
M: expression hydrogen or basic metal, organic amine, organic;
M: expression 1 or 2;
N: the integer of expression 0 to 10;
O: expression oxygen;
P: expression phosphorus.
4, clean-out system according to claim 1 is characterized in that: also contain in the described clean-out system:
(C): molecular weight is 200 to 800 polyether compound 5～20% weight.
5, clean-out system according to claim 4 is characterized in that: described polyether compound general formula is as follows:
R’O-(A’O)qH
In the formula:
R ': the alkyl of expression hydrogen or carbon number 1 to 18 or with the alkenyl of carbon number;
A ': the alkylidene group of representing carbon number 2 or 3;
Q: the integer of expression 4 to 18;
O: expression oxygen;
H: expression hydrogen.
6, clean-out system according to claim 4 is characterized in that: the content of described (A)+(B)+(C) is controlled at 20～40% weight ranges.
7, according to any described clean-out system in the claim 1 to 6, it is characterized in that: the pH value of described clean-out system is in 6～9 scopes.
CN 200410014057 2004-02-12 2004-02-12 Detergent for equipment for producing and processing synthetic fibre Expired - Lifetime CN1236037C (en)

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