CN101067292A - Drying and softening antistatic paper for household fiber fabric and its preparation method - Google Patents
Drying and softening antistatic paper for household fiber fabric and its preparation method Download PDFInfo
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- CN101067292A CN101067292A CN 200710023025 CN200710023025A CN101067292A CN 101067292 A CN101067292 A CN 101067292A CN 200710023025 CN200710023025 CN 200710023025 CN 200710023025 A CN200710023025 A CN 200710023025A CN 101067292 A CN101067292 A CN 101067292A
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- fabric
- drying
- quaternary ammonium
- ammonium salt
- stir
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- 238000001035 drying Methods 0.000 title claims abstract description 66
- 239000004744 fabric Substances 0.000 title claims abstract description 48
- 238000002360 preparation method Methods 0.000 title claims description 14
- 239000000835 fiber Substances 0.000 title description 9
- -1 ester quaternary ammonium salt Chemical class 0.000 claims abstract description 44
- 239000004745 nonwoven fabric Substances 0.000 claims abstract description 31
- 239000004094 surface-active agent Substances 0.000 claims abstract description 15
- 239000002270 dispersing agent Substances 0.000 claims abstract description 12
- 239000002979 fabric softener Substances 0.000 claims abstract description 12
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 11
- 239000000440 bentonite Substances 0.000 claims abstract description 11
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims description 28
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 15
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 11
- 239000011149 active material Substances 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 239000000194 fatty acid Substances 0.000 claims description 11
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 10
- 229930195729 fatty acid Natural products 0.000 claims description 10
- 239000004034 viscosity adjusting agent Substances 0.000 claims description 10
- 239000002202 Polyethylene glycol Substances 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 9
- 229920001223 polyethylene glycol Polymers 0.000 claims description 9
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 9
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 9
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 241000220317 Rosa Species 0.000 claims description 6
- 239000003205 fragrance Substances 0.000 claims description 6
- 150000002191 fatty alcohols Chemical class 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 244000178870 Lavandula angustifolia Species 0.000 claims description 4
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 4
- 239000004927 clay Substances 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
- 239000001102 lavandula vera Substances 0.000 claims description 4
- 235000018219 lavender Nutrition 0.000 claims description 4
- 239000011707 mineral Substances 0.000 claims description 4
- 150000005846 sugar alcohols Polymers 0.000 claims description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 150000003077 polyols Chemical class 0.000 claims description 2
- 239000000600 sorbitol Substances 0.000 claims description 2
- 239000013543 active substance Substances 0.000 claims 1
- 150000004665 fatty acids Chemical class 0.000 claims 1
- 229940075507 glyceryl monostearate Drugs 0.000 claims 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 claims 1
- 229940029614 triethanolamine stearate Drugs 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 abstract description 7
- 238000001816 cooling Methods 0.000 abstract description 5
- 239000000306 component Substances 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 238000010422 painting Methods 0.000 abstract 1
- 238000002791 soaking Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 16
- 239000000203 mixture Substances 0.000 description 15
- 230000003068 static effect Effects 0.000 description 13
- 238000009472 formulation Methods 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 229920000742 Cotton Polymers 0.000 description 7
- 229940092782 bentonite Drugs 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 239000005020 polyethylene terephthalate Substances 0.000 description 6
- 229920004934 Dacron® Polymers 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- 150000003863 ammonium salts Chemical class 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229940080314 sodium bentonite Drugs 0.000 description 4
- 229910000280 sodium bentonite Inorganic materials 0.000 description 4
- 238000005303 weighing Methods 0.000 description 4
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 239000004567 concrete Substances 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- ONCZQWJXONKSMM-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] ONCZQWJXONKSMM-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229940070765 laurate Drugs 0.000 description 2
- 239000004669 nonionic softener Substances 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- QATWBUATYXURHE-UHFFFAOYSA-M sodium;octadecanoate;propane-1,2,3-triol Chemical compound [Na+].OCC(O)CO.CCCCCCCCCCCCCCCCCC([O-])=O QATWBUATYXURHE-UHFFFAOYSA-M 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- ODIGIKRIUKFKHP-UHFFFAOYSA-N (n-propan-2-yloxycarbonylanilino) acetate Chemical compound CC(C)OC(=O)N(OC(C)=O)C1=CC=CC=C1 ODIGIKRIUKFKHP-UHFFFAOYSA-N 0.000 description 1
- NVLHGZIXTRYOKT-UHFFFAOYSA-N 1-chloro-2,3-dimethylbenzene Chemical compound CC1=CC=CC(Cl)=C1C NVLHGZIXTRYOKT-UHFFFAOYSA-N 0.000 description 1
- SPFVNQBOHYXSMM-UHFFFAOYSA-M 1-decylpyridin-1-ium;bromide Chemical compound [Br-].CCCCCCCCCC[N+]1=CC=CC=C1 SPFVNQBOHYXSMM-UHFFFAOYSA-M 0.000 description 1
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 1
- VIRHYTOAKDLCIQ-UHFFFAOYSA-N 2-ethyl-n,n-dimethylaniline;hydrochloride Chemical compound Cl.CCC1=CC=CC=C1N(C)C VIRHYTOAKDLCIQ-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Polymers SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000004368 Modified starch Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000004668 anionic fabric softener Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000004663 anionic softener Substances 0.000 description 1
- 229940006460 bromide ion Drugs 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 239000004665 cationic fabric softener Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- FKOPCVJGLLMUNP-UHFFFAOYSA-N decylazanium;acetate Chemical compound CC(O)=O.CCCCCCCCCCN FKOPCVJGLLMUNP-UHFFFAOYSA-N 0.000 description 1
- 150000001470 diamides Chemical class 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- XHFGWHUWQXTGAT-UHFFFAOYSA-N dimethylamine hydrochloride Natural products CNC(C)C XHFGWHUWQXTGAT-UHFFFAOYSA-N 0.000 description 1
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 150000003840 hydrochlorides Chemical group 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 1
- 229940006461 iodide ion Drugs 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229920001427 mPEG Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- VIKNJXKGJWUCNN-XGXHKTLJSA-N norethisterone Chemical compound O=C1CC[C@@H]2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1 VIKNJXKGJWUCNN-XGXHKTLJSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Paper (AREA)
Abstract
The present invention discloses one kind of household fabric softening and antistatic paper and its making process. The household fabric softening and antistatic paper is used in drying fabric to make the fabric flexible and antistatic. The paper has active matter comprising fabric softener with ester quaternary ammonium salt as main component, dispersant, surfactant, viscosity regulator, bentonite and aromatic in certain weight proportion. The paper is made through compounding the active matter, applying the active matter through painting or soaking onto non-woven fabric as the carrier, and cooling.
Description
One, technical field
The present invention has prepared a kind of domestic fiber fabric dry soft anti-electro static paper (being called for short drying paper).This drying paper is made up of the flaky material and the coating activity prescription thereon thereof of softness, can obtain softness and antistatic effect with this paper processing when drying in dryer after clothes washing finishes.
Two, background technology
Along with the development of rotating cage fabric drying machine (dryer), can be increasing to the demand of the drying paper that uses in the dryer.Drying paper can be given fabric sofetening, comfortable, good antistatic performance and pleasant fragrance.From the seventies in 19th century at first since occurring on the American market, the clothing treatment product that is used for dryer inside has had very big development, the product that multiple different disposal mode occurred as load active material in flexible container, perhaps absorbs the product of active material with sponge.But up to the present, the simplest and effective product is to adopt the carrier of flaky material as active material.United States Patent (USP) (patent No. 5869410,5174911,5399271) has been introduced different product forms and finishing agent prescription.
That fabric sofetening that uses in the drying paper prescription and antistatic additive comprise is cationic, anionic, nonionic and silicone based softener.Cation quaternary ammonium salt type softener is a class softener that is most widely used, and can be adsorbed on efficiently on the fiber, reduces interfibrous friction and static.But along with the raising of environmental requirement, traditional relatively poor biodegradability of cationic quaternary ammonium salt softener has limited its application in the family expenses fabric softener.Recently the quaternary softener of esterification modification has the favorable biological degradability energy, can satisfy environmental protection requirement fully.Anionic fabric softener commonly used comprises hard soap and derivative thereof.The adsorptivity of anionic softener on fiber is poor, and soft effect is undesirable, with the composite effect that then can obtain of nonionic surface active agent.The nonionic softener comprises fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, aliphatic acid polyethenoxy ether, fatty alcohol carboxylic acid ester, the poly-polysaccharide of alkyl etc.Because nonionic softener itself is not charged, thus poor to the fiber absorption property, use seldom separately, can use jointly with CATION or ion softener.But water miscible nonionic surface active agent is owing to there is good hydrophily, in case be adsorbed onto the water absorbing properties that fabric face just can increase fabric, thus the performance of static dissipation increased, improved antistatic effect.
Three, summary of the invention
1, goal of the invention
The object of the present invention is to provide a kind of domestic fiber fabric dry soft anti-electro static paper, abbreviate drying paper as.This drying paper is used in the dryer drying stage behind the clothes washing.Together put drying paper and clothing into dryer and dry minimizing along with clothing moisture, the rising of temperature, the fabric softener on the drying paper is transferred on the clothing, gives good softness of fabric and antistatic effect.
Another object of the present invention provides a kind of preparation method of this antistatic paper.
2, technical scheme
A kind of domestic fabric dry soft anti-electro static paper is characterized in that increasing the soft effect of clothing, improves the antistatic property of clothing.
A kind of preparation method of domestic fabric dry soft anti-electro static paper, it is characterized in that drying paper of the present invention is to utilize synthetic nonwoven fabric sheet material as carrier, use novel ester based quaternary ammonium salt as main active, add other auxiliary composition simultaneously and bring into play best treatment effect.
1) carrier material
Spendable flexible sheet material can be natural among the present invention, also can be the nonwoven fabric of chemical synthesis, and wherein nonwoven fabric is comparatively desirable.The fiber of forming carrier can be a natural fabric, as wool, silk, tossa, cotton, flax etc., also can be synthetic fiber, as nylon, cellulose esters, polythene derivative, polyolefin, polyamide or polyester.Under the dryer maximum temperature that all suitable materials must guarantee (about 70 ℃) enough intensity is arranged.The nonwoven cloth material that uses among the present invention is 100% polyester non-woven fabric, has enough each to avoid tearing or disintegrating to intensity in the time of can guaranteeing to use in dryer.100% nylon or 100% polypropylene non-woven fabric also are preferable selections.
2) prescription of drying paper active material
A kind of domestic fabric dry soft anti-electro static paper (being called for short drying paper), it is characterized in that, as carrier, form the active matter formula coating or impregnated in carrier surface made with nonwoven fabric sheet material by fabric softener 5-80%, surfactant 2-40%, dispersant 0.1-25%, viscosity modifier 1-30%, Peng Run soil 0.01-2% and aromatic 0.1-2%.
Drying paper active material is formulated by following raw materials by weight percent:
1. fabric softener
This drying paper prescription comprises one or more fabric softener, accounts for the 5%-80% of total formulation weight.Cationic fabric softener is the first-selected type of drying paper prescription, and wherein quaternary ammonium salt is a big cationoid type fabric softener, and the static that can reduce fabric coheres with fine hair and adsorbs.Operable quaternary softener comprises Biester quarternary ammoniumsalt, monoesters based quaternary ammonium salt, monomethyl trialkyl quaternary ammonium salt, imidazoline quaternary ammonium salt, dialkyl dimethyl quaternary ammonium salt, methyl dialkoxy alkyl quaternary ammonium salts, diamides based quaternary ammonium salt and dialkyl methyl phenyl quaternary ammonium salt in the drying paper active matter formula, so-called alkyl is meant the alkyl of 8-24 carbon, and quaternary ammonium salt is hydrochloride or methylsulfuric acid ester salt.Biester quarternary ammoniumsalt comprises two (fatty-acid ethyl ester base) ethoxy methyl quaternary ammoniums, two ethyl stearte base ethoxy methylsulfuric acid ammonium methyls etc.; The monoesters based quaternary ammonium salt comprises Triethanolamine Esters of Stearic Acid quaternary ammonium salt etc.
The structural formula of the aliphatic quaternary ammonium salt that uses in the drying paper active matter formula is:
(R)(R
1)(R
2)(R
3)N
+X
-
In the following formula, R is phenyl or low-carbon alkyl phenyl; R
1Be 10-24 carbon atom, the alkyl of 12-22 carbon atom preferably; R
2Be C
10-C
24Or C
1-C
4Alkyl or C
2-C
3Alkoxyl; R
3Be C
1-C
4Alkyl or C
2-C
3Alkoxyl; X is chlorion, bromide ion, iodide ion, sulfate ion or methylsulfuric acid radical ion.Only aliphatic quaternary ammonium salt comprises C
12-C
24Alkyl dimethyl Phenyl chloride, C
12-C
14Alkyl dimethyl (ethylphenyl) ammonium chloride, xylyl ammonium chloride and their mixture.
Other effective aliphatic quaternary ammonium salt comprises that structural formula is:
[(A (C=O)-Y-)-N (R
1) (R
2) (R
3)]
+X
-Quaternary ammonium salt.Wherein, A is C
14-C
24The straight or branched alkyl; Y is ethene, propylene or butylene; R
1, R
2Be H, C
1-C
4Alkyl or C
1-C
3Alkoxyl; R
3With R
1Identical or [A (C=O)-Y-]; X is a kind of acylate.
Other effective ammonium salts are water miscible stearic acid-base ammonium salts, as stearic acid-base dimethyl amine hydrochloride, distearyl acidic group amine hydrochlorate, decyl pyridinium bromide, bay acidic group trimethyl ammonium chloride, decyl ammonium acetate.
The quaternary ammonium salt that uses among the present invention is characterised in that the biological degradability of novel ester based quaternary ammonium salt is better than other quaternary ammonium salt, is the developing direction of following quaternary ammonium salt.
2. surfactant
Use help fill a prescription the dispersion in dryer of one or more surfactant in this drying paper active matter formula.Nonionic surface active agent or amphoteric surfactant are preferable selection, because they can be compatible with cationic fabric-treating agent and can bring into play the effect of fabric softener simultaneously.Use the specific non-ionic surface active agent that to bring into play useful effect to improve the water-soluble and fast dispersibility in dryer of drying paper prescription among the present invention.
The nonionic surface active agent that uses among the present invention is fatty alcohol-polyoxyethylene ether, accounts for the 2-40% of total formulation weight, is preferably 5-25%.The length of fatty alcohol carbochain has determined the water-insoluble of fatty alcohol-polyoxyethylene ether.The polyoxyethylene part can increase the water-soluble of fatty alcohol-polyoxyethylene ether, and fatty alcohol-polyoxyethylene ether can keep the characteristic of its liquid when polyoxyethylene accounts for 50% left and right sides of total condensation product weight.
Best non-ionic surface active agent is C
8-C
22The condensation product of alkylol and 2-50 mole ethylene oxide/mol of alcohol.For example, the Neodol 23-6.5 of U.S. Shell Co. Ltd is C
12-C
13The condensation product of fatty alcohol and 7 mole ethylene oxides; Leveling agent o commonly used in the textile industry is C
12-C
18The condensation product of fatty alcohol and 15-30 mole ethylene oxide etc.Best non-ionic surface active agent also comprises C
8-C
24Fatty acid amine, polyxyethylated mercaptan ester, polyoxyethylene carboxylate (as polyethylene glycol laurate, methoxy poly (ethylene glycol) laurate), fatty acid amine polyoxyethylene ether, Polyoxyethylene Sorbitol Fatty Acid Esters, wherein ethylene oxide is 5-50 to the mol ratio of alcohol, amine, acid or phenol: 1.
3. dispersant
Use dispersant to improve the dispersiveness of finishing agent among the present invention.Dispersant can change the viscosity of prescription, changes speed and homogeneity that finishing agent shifts from drying principal direction fabric.Effectively dispersant comprises modified starch, modified cellulose (as CMC), aliphatic acid and soap, fatty alcohol, modified mineral clay, polyvinyl alcohol, polyacrylamide and the organic wax of polymerization.Effectively polymer wax comprises ethylene acrylic salt copolymer, ethylene acrylic acid co polymer and polyoxyethylene.The polyethylene glycol of selecting for use molecular weight to be about 200-2000 among the present invention is a dispersant.
The consumption of dispersant accounts for the 0.1-25% of total formulation weight, is preferably 2-20%.
4. viscosity modifier
The viscosity of using viscosity modifier to regulate prescription among the present invention, the transfer rate of control prescription, viscosity modifier also has the effect of fabric wetting agent, lubricant, antistatic additive etc. concurrently simultaneously.Satisfactory this analog assistant has the high-grade aliphatic ester or the mineral clay of non-ionic hydrophilic polymer, polyalcohol, as fatty alcohol-polyoxyethylene ether, CATION ammonium salt and higher polyol and polyoxyethylated polymer.
The viscosity modifier that uses among the present invention is as the high-grade aliphatic ester of polyalcohol, as glycerin monostearate.Also add the mineral clay bentonite simultaneously.The consumption of glycerin monostearate accounts for the 1-30% of total formulation weight, and bentonitic consumption accounts for the 0.01-2% of total formulation weight.
5. aromatic
Aromatic can be selected different fragrance according to client's needs, as rose scent, and lavender etc.
The consumption of aromatic accounts for the 0.1-2% of total formulation weight.
3) preparation of drying paper
A kind of domestic fabric dry soft anti-electro static paper is the preparation method of drying paper, and its preparation process is as follows:
A, take by weighing fabric softener 5-80% in there-necked flask, place 50-70 ℃ of water-bath, electric mixer mixing speed 300rpm stirs 10-20min;
B, adding surfactant 2-40% stir 15-30min;
C, adding dispersant 0.1-25% stir 10-20min;
D, adding viscosity modifier 1-30% stir 10-20min;
E, adding bentonite 0.01-2% stir 30-60min;
F, adding aromatic 0.1-2% stir 5-10min, make active matter formula, and be standby;
G, a nonwoven fabric is lain in the flat chassis, flat chassis is placed in 50-70 ℃ the thermostat;
H, the above-mentioned active matter formula for preparing is coated on the nonwoven fabric equably, takes out nonwoven fabric then, in being lower than 30 ℃ environment, cool off, or cool off with fan for cooling.
The effect of the drying paper that makes can be estimated by measuring antistatic property, softness and the moisture pick-up properties of handling the back fabric.
The antistatic property of fabric can be estimated by the surface resistivity of measuring fabric, and the instrument that uses is ZC36 type megger.
The softness of fabric can be estimated by the pliability of measuring fabric, and the instrument that uses is DC-RRY1000 type computer observing and controlling pliability instrument.
Hygroscopicity of fabric can adopt oven method measuring.Under 105 ℃ of conditions the oven dry fabric weigh after 4 hours the dry weight G of fabric
0
In the formula: G is that sample is through the weight in wet base of damping (23 ± 1 ℃ of temperature, humidity 50 ± 2%) after 24 hours; G
0Dry weight for sample.
The mensuration of above all properties is all carried out under constant temperature and humidity (23 ± 1 ℃ of temperature, humidity 50 ± 2%).
In order to estimate drying paper performance formula of the present invention, under identical condition, compare with external like product.The drying paper size is 230mm * 163mm.The about 1.05g of coating weight.Use cotton, polyester-cotton blend (50/50) and dacron as estimating fabric.
Below in conjunction with test result useful result of the present invention is described.
Fig. 1 is the regain comparison diagram.Improving regain can increase the electric conductivity of fabric, thereby improves antistatic property.Concerning COTTON FABRIC, because regain own is than higher, the hydrophobicity finishing agent combines with hydroxyl on the fiber and reduces its moisture pick-up properties certainly, but drying paper of the present invention reduces to such an extent that lack than external drying paper.And concerning dacron and contain the polyester cotton of dacron,, can increase its moisture pick-up properties after handling by drying paper because terylene itself does not have water absorbing properties, drying paper of the present invention is more few than external drying paper weak effect.
Fig. 2 is the surface resistivity comparison diagram.The surface resistivity that reduces fabric is exactly the electric conductivity that has improved fabric, thereby improves antistatic property.Wherein the surface resistivity of dacron reduces the amplitude maximum.Drying paper of the present invention is basic identical with the treatment effect of external sample drying paper.
Fig. 3 is the pliability comparison diagram.The unit of pliability is a milli ox (mN), and the low more explanation flexibility of numerical value is good more.Concerning three kinds of fabrics, use the flexibility after drying paper is handled all to have a more substantial increase.Concerning cotton and polyester-cotton fabric, drying paper of the present invention is suitable with external sample drying paper, but concerning dacron, the effect of drying paper of the present invention is better than external sample drying paper.
Useful result
To the comparison of drying paper of the present invention, can clearly be seen that drying paper of the present invention has reached the level of external product by above-mentioned with external sample drying paper performance.
The present invention prepares operating temperature (the highest 70 ℃) requirement that drying paper can satisfy dryer, and the fabric after the processing has soft anlistatig effect, can satisfy the requirement of domestic fabric drying fully.Its performance has reached the level of external equivalents.
Adopt novel ester based quaternary ammonium salt type active component among the present invention, add the prescription conditioning agent of property, the drying paper that uses nonwoven fabric to make does not still have patent report at home.
Four, description of drawings
Fig. 1 is the regain comparison diagram of fabric when not using drying paper, use drying paper of the present invention and sample paper.
Fig. 2 is the surface resistivity comparison diagram of fabric when not using drying paper, use drying paper of the present invention and sample paper.
Fig. 3 is the pliability comparison diagram of fabric when not using drying paper, use drying paper of the present invention and sample paper.
Five, the specific embodiment
1, the preparation of active matter formula
The composition of prescription sees the following form:
| Formulation | The component title | Consumption, % |
| Softener surfactant-dispersed agent viscosity modifier bentonite aromatic | Triethanolamine Esters of Stearic Acid quaternary ammonium salt aliphatic alcohol polyethenoxy, (10) ether polyethylene glycol, (1500) glycerin monostearate calcium-base bentonite lavender aromatic | 68.3 3.4 6.8 20.5 0.7 0.3 |
Take by weighing 100g Triethanolamine Esters of Stearic Acid quaternary ammonium salt quaternary ammonium salt in there-necked flask, place 60 ℃ of water-baths, electric mixer mixing speed 300r/min.After stirring 10min, add aliphatic alcohol polyethenoxy (10) ether 5g, stir 15min; Add polyethylene glycol (1500) 10g, stir 10min; The glycerin monostearate 30g that adds stirs 10min; Add bentonite 1g and stir 30min, add lavender 0.5g, make active matter formula, standby;
2, the prescription of drying paper coating
The active matter formula of preparation in above-mentioned is applied on the nonwoven fabric by dip coated, concrete steps are: at first a 20cm * 10cm nonwoven fabric is lain in the flat chassis, flat chassis is placed in 60 ℃ the thermostat, when the temperature of nonwoven fabric and flat chassis all reaches 60 ℃, the active matter formula for preparing is distributed in the flat chassis surface equably, treat after the active matter formula fusing nonwoven fabric to be immersed in the active material, with metal bar blade coating nonwoven fabric equably, make active material be evenly distributed on nonwoven surface then.At last in being lower than 30 ℃ environment, cool off nonwoven fabric, or cool off with fan for cooling.
Embodiment 2 domestic fabric dry soft anti-electro static paper and method for makings thereof:
1, the preparation of active matter formula
The composition of prescription sees the following form:
| Formulation | The component title | Consumption, % |
| Softener surfactant-dispersed agent viscosity modifier bentonite aromatic | The hard ester acid of two ethyl stearte base ethoxy methylsulfuric acid ammonium methyls polyoxyethylene, (20) ester polyethylene glycol, (800) glycerin monostearate sodium bentonite rose | 67.1 4.7 10.1 16.8 1.0 0.3 |
Take by weighing the two ethyl stearte base ethoxy methylsulfuric acid ammonium methyls of 100g in there-necked flask, place 60 ℃ of water-baths, electric mixer mixing speed 300r/min.After stirring 15min, add hard ester acid polyoxyethylene (20) ester 7g, stir 15min; Add polyethylene glycol (800) 15g, stir 10min; The glycerin monostearate 25g that adds stirs 10min; Add sodium bentonite 1.5g and stir 30min, add rose 0.5g, make active matter formula, standby;
2, the prescription of drying paper coating
The active matter formula of preparation in above-mentioned is applied on the nonwoven fabric by dip coated, concrete steps are: at first a 20cm * 10cm nonwoven fabric is lain in the flat chassis, flat chassis is placed in 60 ℃ the thermostat, when the temperature of nonwoven fabric and flat chassis all reaches 60 ℃, the active matter formula 2g for preparing is spilt in nonwoven surface, to fill a prescription with metal bar and to be coated on the nonwoven fabric equably, take out nonwoven fabric then, in being lower than 30 ℃ environment, cool off, or cool off with fan for cooling.
Embodiment 3 domestic fabric dry soft anti-electro static paper and method for makings thereof:
1, the preparation of active matter formula
Take by weighing two (fatty-acid ethyl ester base) the ethoxy methyl quaternary ammoniums of 100g in there-necked flask, place 60 ℃ of water-baths, electric mixer mixing speed 300r/min.After stirring 15min, add polyoxyethylene (80) Span 10g, stir 15min; Add polyethylene glycol (800) 15g, stir the glycerin monostearate 20g that 10min adds, stir 10min; Add sodium bentonite 1g and stir 30min, add rose 0.5g, make active matter formula, standby;
The composition of prescription sees the following form:
| Formulation | The component title | Consumption, % |
| Softener surfactant-dispersed agent viscosity modifier bentonite aromatic | Two, (fatty-acid ethyl ester base) ethoxy methyl quaternary ammonium polyoxyethylene, (80) Span polyethylene glycol, (800) glycerin monostearate sodium bentonite rose | 68.3 6.8 10.2 13.7 0.7 0.3 |
2, the prescription of drying paper coating
The active matter formula of preparation in above-mentioned is applied on the nonwoven fabric by dip coated, concrete steps are: at first a 20cm * 10cm nonwoven fabric is lain in the flat chassis, flat chassis is placed in 60 ℃ the thermostat, when the temperature of nonwoven fabric and flat chassis all reaches 60 ℃, the active matter formula for preparing is distributed in the flat chassis surface equably, treat after the active matter formula fusing nonwoven fabric to be immersed in the active material, with metal bar blade coating nonwoven fabric equably, make active material be evenly distributed on nonwoven surface then.At last in being lower than 30 ℃ environment, cool off nonwoven fabric, or cool off with fan for cooling.
Claims (10)
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| CN 200710023025 CN101067292A (en) | 2007-05-31 | 2007-05-31 | Drying and softening antistatic paper for household fiber fabric and its preparation method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
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| CN104480780A (en) * | 2014-11-13 | 2015-04-01 | 常熟市常隆包装有限公司 | Packaging paper with anti-static function |
| CN104452470A (en) * | 2014-11-13 | 2015-03-25 | 常熟市常隆包装有限公司 | Preparation method of packaging paper with anti-static function |
| CN110106699A (en) * | 2019-05-13 | 2019-08-09 | 广州洁生日化有限公司 | A kind of submissive fragrant garment piece of solid |
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