CN1230348A - Composite pesticide - Google Patents
Composite pesticide Download PDFInfo
- Publication number
- CN1230348A CN1230348A CN 98124396 CN98124396A CN1230348A CN 1230348 A CN1230348 A CN 1230348A CN 98124396 CN98124396 CN 98124396 CN 98124396 A CN98124396 A CN 98124396A CN 1230348 A CN1230348 A CN 1230348A
- Authority
- CN
- China
- Prior art keywords
- consumption
- insecticide
- usually
- agent
- alkylphenol polyoxyethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a field of farm chemical and is specially a composition pesticide containing pyridine pesticide and biological pesticide. The composite pesticide of the present invention is prepared by compounding the said pesticides and well known assistants including solvent, filling, synergist, etc. It has obvious synergistic effect.
Description
The invention belongs to pesticide field, relate in particular to a kind of pyridines and biological species insecticide composition of containing.
The insecticide of present common use generally is pyridines insecticide or biological species insecticide, the former the desinsection scope of pyridines insecticide is less, its usage degree is limited, and latter's biological species insecticide such as avermectins production cost are higher, composite insecticide of the present invention contains pyridines insecticide and biological species insecticide, it is wide both to have had biological species insecticide insecticidal spectrum, has the low advantage of pyridines insecticide cost again.
The objective of the invention is to practical problem, proposed a kind of new insecticides at the supply and demand on the pattern of farming in the agricultural production of present China.
Composite insecticide of the present invention includes as the pyridines insecticide of active component and biological species insecticide, and the pyridines insecticide of indication of the present invention can be Imidacloprid, pyrrole worm clear (Mo Bilang) and other pyridines insecticide.The biological species insecticide of indication of the present invention can be similar biological insecticides such as Avermectin, methyl Avermectin.Furtherly, composite insecticide of the present invention includes the cleer and peaceful Avermectin of active component pyrrole worm, and furtherly, it is clear that composite insecticide of the present invention includes the pyrrole worm of the Avermectin of 0.01-99% and 0.1-99%.
Composite insecticide of the present invention can also with other agricultural chemicals such as weed killer herbicide, insecticide, bactericide and safener, fertilizer, growth regulator are mixed with into preparation or primary and secondary packaged form.
Utilize the said insecticide of the invention described above, be equipped with the composite insecticide that the known auxiliary agent of those skilled in that art (solvent, filler, synergist etc.) can prepare multiple formulation of the present invention, the formulation that can process has:
A: wetting powder (WP)
B: dry suspending agent (DF)
C: missible oil (EC)
D: aqueous suspension emulsion
E: finish
F: pulvis
G: emulsifiable concentrate
H: aqua
The content range of the Avermectin in the formulation is 0.01-99%, and the clear content range of pyrrole worm is 0.1-99%, and Avermectin and pyrrole worm clearly can arbitrary proportions composite (Avermectin 0.01-99%, the clear 0.1-99% of pyrrole worm).
The auxiliary agent that uses in preparation of the present invention can be: the combination of OP-10,0201,8901,0203, farming breast 500,1600,1601,2201,0208, neopelex--calcium, sodium lignin sulfonate--any one or the multiple material among calcium, the SOPA.
The synergist that uses in preparation of the present invention can be: any one material in the agricultural bleeding agent A of penetrant t benefit, B, C, the azone or the combination of multiple material.
The solvent that uses in preparation of the present invention can be: one or more combination such as pentane, ether, methyl alcohol, ethyl acetate, chloroform, chloromethanes, dimethyl sulfoxide (DMSO), dimethylbenzene, toluene, chlorobenzene.
Embodiment 1
The preparation of the composite insecticide of wetting powder form
Wetting powder is can homodisperse preparation in water; except being added with white carbon black; precipitated calcium carbonate; potter's clay; beyond diatomite thinner or the inert substance; it also contains ionic or nonionic surface active agent (wetting agent; dispersant); comprise fatty alcohol polyglycol ether sulphate; fatty acid amide N methyl taurine sodium salt; sodium sulfate of polyethenoxy ether of fatty alcohol; alkylphenol polyoxyethylene sulphate, alkylphenol polyoxyethylene, neopelex one calcium; sodium lignin sulfonate-calcium; one or more above-mentioned substances such as SPOA are formed, and concrete above-mentioned substance content proportioning 0.1-30% also includes penetrant t; the agricultural powder of benefit; one or more above-mentioned substance combinations such as azone, concrete above-mentioned substance content proportioning 0.1-30% makes 50% wetting powder through grinding and processing.
Embodiment 2
Do the preparation of the composite insecticide of outstanding agent form
With active component, wetting agent, disintegrant, dispersant and the adhesive of former medicine, by forming with the water mixing granulation.Described wetting agent comprises anionic surfactant such as sodium alkyl sulfate, alkylbenzene sodium iodate and benzene sulfonic acid sodium salt, its consumption 0.1-10%.Disintegrant commonly used comprises starch and derivative, alginic acid and salt and clay etc., and consumption is 0.1-20%.Dispersant and adhesive have the formaldehyde condensation products of lignosulfonates, alkylbenzenesulfonate, Fluhyzon hydrochlorate and polycarboxylic acid surfactant etc.Common consumption 5-30%.
Embodiment 3
The preparation of the composite insecticide of missible oil form
Active component is dissolved in one or more organic solvents following pentane, ether, methyl alcohol, ethyl acetate, chloroform, carrene, dimethyl sulfoxide (DMSO), dimethylbenzene increases one or more ionics in the toluene, chlorobenzene etc. or nonionic surface active agent (emulsifier) is made.Described emulsifier comprises: fatty alcohol polyglycol ether sulphate; fatty acid amide N methyl taurine sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, alkylphenol polyoxyethylene sulphate; alkylphenol polyoxyethylene; alkyl benzene calcium sulfonate, consumption is 0.1-30% usually, also includes penetrant t; common consumption 0.1-10%; benefit farming oil, azone, consumption 0.1-20% usually.
The optimum ratio of missible oil of the present invention is (percentage by weight):
Avermectin 0.01-99%
The clear 0.1-99% of pyrrole worm
Auxiliary agent 1-30%.
Synergist 0.1-30%.
The solvent surplus
Embodiment 4
The preparation of the composite insecticide of aqueous suspension agent form
With the pyrrole worm clear with Avermectin by after adding synergist, auxiliary agent, pass through ball milling, sand milling is made.Described auxiliary agent comprises fatty alcohol polyglycol ether sulphate, fatty acid amide N methyl taurine sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol; alkylphenol polyoxyethylene sulphate, alkylphenol polyoxyethylene, triphen ethyl-phenol polyoxyethylene; common consumption 0.1-30%, penetrant t, consumption 0.1-10% usually; ethylene glycol, common consumption 0.1-10%, CMC; common consumption 0.1-10%, xanthans, 0.1-10%; tributyl phosphate, 0.1-20%.
Embodiment 5
The preparation of the composite insecticide of finish form
Finish is made by former medicine, surfactant adding mineral oil or vegetable oil.Surfactant comprises dioctyl phthalate, alcohol, fatty acid, the liquid ester class of alicyclic ring alcohol, as repefral, butyl ester, diisobutyl ester, two laruyl alcohol esters, two ring pentyl esters, two cyclohexyls and two ring monooctyl esters etc., also available C6-C10 carboxylic acid such as positive acetate, capric acid, n-nonanoic acid, benzoic acid and ester are as benzylacetic acid ester, ethyl acetate, ethyl pelargonate, methyl benzoate or ethyl ester etc., consumption 0.1-30% usually.Can having: fatty alcohol polyglycol ether sulphate as emulsifier; fatty acid amide N methyl taurine sodium salt; sodium sulfate of polyethenoxy ether of fatty alcohol; alkylphenol polyoxyethylene sulphate; alkylphenol polyoxyethylene; sodium alkyl benzene sulfonate--calcium, sodium lignin sulfonate--calcium, consumption 0.1-30% usually.
Embodiment 6
The preparation of the composite insecticide of powder form
By with active ingredient and finely divided property solid matter such as talcum, natural clay such as kaolin, precipitated calcium carbonate and pyrophyllite or diatomite, white carbon black grind together to be made, and supplies 100%.
Embodiment 7
The preparation of the composite insecticide of emulsifiable concentrate form
Emulsification forms through high-speed stirred with former medicine, surfactant, water, synergist, solvent.Surfactant comprises fatty alcohol polyglycol ether sulphate, fatty acid amide N methyl taurine sodium salt, and sodium sulfate of polyethenoxy ether of fatty alcohol, alkylphenol polyoxyethylene sulphate, alkylphenol polyoxyethylene, alkyl benzene calcium sulfonate, consumption is 1-30% usually.Solvent comprises pentane, ether, and methyl alcohol, ethyl acetate, chloroform, carrene, dimethyl sulfoxide (DMSO), dimethylbenzene, toluene, chlorobenzene, consumption is 1-50% usually.Synergist comprises nitrogen copper, beneficial agricultural liquid, and consumption is 1-30% usually.
Embodiment 8
The preparation of the composite insecticide of aqua form
With soluble in water behind the former medicine salify.
Evidence, insecticide provided by the present invention has the advantages that insecticidal spectrum is wide, effective, cost is low.
Embodiment 9
The synergism test report one of Mo Bilang and abamectin compounded control cigarette aphid, test objective: high-efficient low-toxicity compound medicament two, the test medicine of screening control cigarette aphid:
3% than bright (Mospilarn): Tso Tat Co., Ltd., Japan's product
1.8% Avermectin (Avermectin): Guilin Jiqi Pharmaceutical Industry Co., Ltd.'s product three, test material and method
Pick up from Institute of Plant Protection, eastern suburb, Baoding tobacco experimental field, laboratory test chamber condition for examination cigarette aphid (Myzus perisicae Sulzer): 24 ± 1 ℃ of temperature, illumination in 14 hours, relative moisture 70%.
Test method: immersion method.Be ready to diameter earlier and be 8 centimetres foster worm ware, get moist filter paper of the same area be put in the bottom preserve moisture, to have the worm blade to soak for 5 seconds in the different disposal soup, and inhale with filter paper and remove unnecessary soup, each handles the examination worm is the 50-130 head, repeat 3 times, after 24 hours, check the polypide death condition, and calculate the insect population lethality, with the computational methods of Sun and Johnson, calculate the toxicity correlation coefficient.
Three, test results and analysis
3% does not see Table 1 than the lethal concentration of 50 and the toxicity regression linear equation of bright, 1.8% Avermectin and compound drug thereof.The actual Relative Toxicity index that is calculated composite dose of X by table 1 result of the present invention is 85.48, and theoretical Relative Toxicity index is 31.33, is 272.2＞100 thereby calculate the toxicity correlation coefficient.Mo Bilang and abamectin compounded notable synergistic are described.Table 2 is handled the result of the test of control cigarette aphid for variable concentrations.Table 1, Mo Bilang, Avermectin and compound drug X thereof are to the toxicity test result of cigarette aphid
Table 2, variable concentrations are handled the result of the test of control cigarette aphid
| Test medicine | Regression equation | The lethal concentration of 50 (PPM) |
| Mo Bilang | ????Y=4.70+2.43X | ?????1.327 |
| Avermectin | ????Y=7.31+2.56X | ?????0.124 |
| ????X | ????Y=6.98+2.03X | ?????0.106 |
| Test is handled | Concentration of treatment (PPM) | The examination borer population | 24 hours dead borer populations |
| 1.8% Avermectin | ????0.750 | ?????87 | ??????86 |
| 1.8 Avermectin | ????0.375 | ?????85 | ??????76 |
| 1.8 Avermectin | ????0.188 | ?????89 | ??????59 |
| 1.8 Avermectin | ????0.094 | ?????76 | ??????34 |
| 1.8 Avermectin | ????0.047 | ?????83 | ??????18 |
| 3% than not bright | ????5.000 | ?????90 | ??????83 |
| 3% than not bright | ????2.500 | ?????96 | ??????72 |
| 3% than not bright | ????1.250 | ?????111 | ??????59 |
| 3% than not bright | ????0.625 | ?????118 | ??????36 |
| 3% than not bright | ????0.313 | ?????97 | ??????11 |
| 0.78% medicament of the present invention | ????0.650 | ?????62 | ??????58 |
| 0.78% medicament of the present invention | ????0.325 | ?????73 | ??????63 |
| 0.78% medicament of the present invention | ????0.163 | ?????78 | ??????50 |
| 0.78% medicament of the present invention | ????0.081 | ?????86 | ??????47 |
| 0.78% medicament of the present invention | ????0.041 | ?????73 | ??????15 |
| CK | ?????88 | ??????7 |
Claims (17)
1. a composite insecticide is characterized in that containing active component pyridines insecticide and biological species insecticide.
2. insecticide according to claim 1, wherein the pyridines insecticide can be clear or other the pyridines insecticide of Imidacloprid, pyrrole worm.
3. insecticide according to claim 1, wherein the biological species insecticide can be Avermectin, methyl Avermectin or other biological insecticides.
4. insecticide according to claim 1, it contains the cleer and peaceful Avermectin of pyrrole worm.
5. according to claim 1,2,3 or 4 described insecticides, it also contains auxiliary agent, synergist or solvent.
6. insecticide according to claim 4, wherein auxiliary agent is: OP-10,0201,8901,0203, farming breast 500,1600,1601,2201,0208, neopelex--calcium, sodium lignin sulfonate--any one or the multiple composition of matter among calcium, the SOPA.
7. insecticide according to claim 4, wherein synergist is: any one material or multiple composition of matter in the agricultural bleeding agent A of penetrant t benefit, B, C, the azone.
8. insecticide according to claim 4, wherein solvent is: one or more compositions such as pentane, ether, methyl alcohol, ethyl acetate, chloroform, chloromethanes, dimethyl sulfoxide (DMSO), dimethylbenzene, toluene, chlorobenzene.
9. insecticide according to claim 4, it can be formulated as wetting powder, does outstanding agent, missible oil, aqueous suspension agent, finish, pulvis, emulsifiable concentrate or aqua form.
10. according to claim 5,6,7 or 8 described insecticides, it can be the missible oil form, the proportioning of each composition is (percentage by weight):
Avermectin: 0.01-99%
The pyrrole worm is clear: 0.1-99%
Auxiliary agent: 1-30%
The above-mentioned substance content proportioning 0.1-30% that synergist: 0.1-30% is concrete, 50% wetting powder of making through grinding and processing.
11. according to claim 5,6,7 or 8 described insecticides, it can be to do outstanding agent form, it is the active component with former medicine, wetting agent, disintegrant, dispersant and adhesive, by forming with the water mixing granulation, described wetting agent is a sodium alkyl sulfate, anionic surfactant such as alkylbenzene sodium iodate or benzene sulfonic acid sodium salt, its consumption 0.1-10%, disintegrant commonly used has starch and derivative thereof, alginic acid and salt and clay etc., consumption is 0.1-20%, dispersant and adhesive have lignosulfonates, alkylbenzenesulfonate, the formaldehyde condensation products of Fluhyzon hydrochlorate and polycarboxylic acid surfactant etc., consumption 5-30% usually.
12. according to claim 5,6,7 or 8 described insecticides; it can be the missible oil form, is by active component being dissolved in one or more organic solvents following pentane; ether; methyl alcohol, ethyl acetate, chloroform; carrene; dimethyl sulfoxide (DMSO), dimethylbenzene, toluene; one or more ionics of increase or nonionic surface active agent (emulsifier) are made in the chlorobenzenes etc.; described emulsifier is a fatty alcohol polyglycol ether sulphate, fatty acid amide N methyl taurine sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol; alkylphenol polyoxyethylene sulphate; alkylphenol polyoxyethylene or alkyl benzene calcium sulfonate, consumption is 0.1-30% usually, also includes penetrant t; common consumption 0.1-10%; benefit farming oil, azone, consumption 0.1-20% usually.
13. according to claim 5,6,7 or 8 described insecticides; it is the aqueous suspension agent form, be with the pyrrole worm clear with Avermectin by the adding synergist; behind the auxiliary agent, through ball milling; the preparation that sand milling is made; described auxiliary agent comprises fatty alcohol polyglycol ether sulphate, fatty acid amide N methyl taurine sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol; alkylphenol polyoxyethylene sulphate; alkylphenol polyoxyethylene, triphen ethyl-phenol polyoxyethylene, consumption 0.1-30% usually; penetrant t; common consumption 0.1-10%, ethylene glycol, consumption 0.1-10% usually; CMC; common consumption 0.1-10%, xanthans, 0.1-10%; tributyl phosphate, 0.1-20%.
14. according to claim 5,6,7 or 8 described insecticides; it is the finish form, is by former medicine; surfactant adds mineral oil or vegetable oil is made, and described surfactant comprises dioctyl phthalate; alcohol, fatty acid, the liquid ester class of alicyclic ring alcohol; as repefral; butyl ester, diisobutyl ester, two laruyl alcohol esters; two ring pentyl esters; two cyclohexyls and two ring monooctyl esters etc., also available C6-C10 carboxylic acid such as positive acetate, capric acid; n-nonanoic acid; benzoic acid and ester are as benzylacetic acid ester, ethyl acetate; ethyl pelargonate; methyl benzoate or ethyl ester etc., common consumption 0.1-30%, described emulsifier is a fatty alcohol polyglycol ether sulphate; fatty acid amide N methyl taurine sodium salt; sodium sulfate of polyethenoxy ether of fatty alcohol, alkylphenol polyoxyethylene sulphate, alkylphenol polyoxyethylene; sodium alkyl benzene sulfonate---calcium or sodium lignin sulfonate---calcium, consumption 0.1-30% usually.
15. according to claim 5,6,7 or 8 described insecticides, it is a powder form, is by with active ingredient and finely divided property solid matter such as talcum, natural clay such as kaolin, precipitated calcium carbonate and pyrophyllite or diatomite, white carbon black grind together to be made, and content supplies 100%.
16. according to claim 5,6,7 or 8 described insecticides; it is the emulsifiable concentrate form; be with former medicine; surfactant; water; synergist; emulsification forms solvent through high-speed stirred, and described surfactant comprises fatty alcohol polyglycol ether sulphate, fatty acid amide N methyl taurine sodium salt; sodium sulfate of polyethenoxy ether of fatty alcohol; alkylphenol polyoxyethylene sulphate, alkylphenol polyoxyethylene, alkyl benzene calcium sulfonate; usually consumption is 1-30%; described solvent comprises pentane, ether, methyl alcohol; ethyl acetate; chloroform, carrene, dimethyl sulfoxide (DMSO) emulsifiable concentrate; dimethylbenzene; toluene, chlorobenzene, consumption is 1-50% usually; described synergist comprises nitrogen copper; the agricultural liquid of benefit, consumption is 1-30% usually.
17. according to claim 5,6,7 or 8 described insecticides, it is the aqua form, is with soluble in water behind the former medicine salify.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 98124396 CN1199568C (en) | 1998-11-09 | 1998-11-09 | Composite pesticide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 98124396 CN1199568C (en) | 1998-11-09 | 1998-11-09 | Composite pesticide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1230348A true CN1230348A (en) | 1999-10-06 |
| CN1199568C CN1199568C (en) | 2005-05-04 |
Family
ID=5228614
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 98124396 Expired - Fee Related CN1199568C (en) | 1998-11-09 | 1998-11-09 | Composite pesticide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1199568C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101911955A (en) * | 2010-08-13 | 2010-12-15 | 云南省农业科学院农业环境资源研究所 | Biogenic acaricidal water suspension composition and preparation method thereof |
| CN105532736A (en) * | 2015-12-21 | 2016-05-04 | 合肥星宇化学有限责任公司 | Pesticide composition and application thereof |
| CN106962371A (en) * | 2017-03-16 | 2017-07-21 | 中化化工科学技术研究总院 | For flying anti-emamectin benzoate dry suspending agent and preparation method thereof |
| CN107751221A (en) * | 2017-09-30 | 2018-03-06 | 无为县龙口花卉苗木有限公司 | One kind covers shrimp soft-shelled turtle efficient germicide of breeding fish |
| CN109744031A (en) * | 2017-11-02 | 2019-05-14 | 中国医学科学院药用植物研究所 | A kind of composition and application thereof for preventing and treating micro pest |
-
1998
- 1998-11-09 CN CN 98124396 patent/CN1199568C/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101911955A (en) * | 2010-08-13 | 2010-12-15 | 云南省农业科学院农业环境资源研究所 | Biogenic acaricidal water suspension composition and preparation method thereof |
| CN101911955B (en) * | 2010-08-13 | 2014-11-26 | 云南省农业科学院农业环境资源研究所 | Biogenic acaricidal water suspension composition and preparation method thereof |
| CN105532736A (en) * | 2015-12-21 | 2016-05-04 | 合肥星宇化学有限责任公司 | Pesticide composition and application thereof |
| CN105532736B (en) * | 2015-12-21 | 2018-03-06 | 合肥星宇化学有限责任公司 | A kind of composition pesticide and its application |
| CN106962371A (en) * | 2017-03-16 | 2017-07-21 | 中化化工科学技术研究总院 | For flying anti-emamectin benzoate dry suspending agent and preparation method thereof |
| CN106962371B (en) * | 2017-03-16 | 2018-06-29 | 中化化工科学技术研究总院 | For flying anti-emamectin benzoate dry suspending agent and preparation method thereof |
| CN107751221A (en) * | 2017-09-30 | 2018-03-06 | 无为县龙口花卉苗木有限公司 | One kind covers shrimp soft-shelled turtle efficient germicide of breeding fish |
| CN109744031A (en) * | 2017-11-02 | 2019-05-14 | 中国医学科学院药用植物研究所 | A kind of composition and application thereof for preventing and treating micro pest |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1199568C (en) | 2005-05-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101107934B (en) | Fungicide containing nutgall extractive and composition thereof | |
| CN1098032C (en) | Fungicidal composition and method of controlling fungus infestation | |
| CN104663670A (en) | Synergistic miticidal composition | |
| CN101352167B (en) | Pesticide composition based on nitenpyram | |
| CN1199568C (en) | Composite pesticide | |
| CN101366386A (en) | Agricultural chemical composition based on Pymetrozine | |
| CN103250732A (en) | Synergistic pesticide composition for killing scale insects | |
| CN109221140A (en) | A kind of Pesticidal combination containing (R)-4-isopropenyl-1-methyl-1-cyclohexene and pyridine quinazoline | |
| CN102228056B (en) | Pesticide composition containing sulfur-fluorine oxime ether and part of organophosphorus pesticides | |
| CN1124074C (en) | Herbicide | |
| CN101971860A (en) | Insecticidal composition containing dinotefuran and triazophos | |
| CN102217633B (en) | Pesticide composition containing sulfoxaflor | |
| CN109247332A (en) | A kind of composition pesticide and its application containing difenoconazole and Fluoxastrobin | |
| WO2018032889A1 (en) | Insecticidal composition having synergistic effect | |
| CN101779661B (en) | Compound insecticide prepared from emamectin benzoate and pyridaphethione | |
| CN100399900C (en) | Pesticide composition containing avermectin and butyl ether urea and its application | |
| CN1047503C (en) | Emulsion oil of angulatin | |
| CN1565182A (en) | Bactericidal compositions of flumorph and enostroburin and synergist | |
| CN1080997C (en) | Herbicide composition of acyl aniline and sulfonylurea | |
| CN103250713B (en) | Synergistic pesticide composition for killing gall midge insects | |
| CN1918994A (en) | Pesticides composition comprising methylamino avermectin benzoate and fipronil and uses thereof | |
| CN101180964A (en) | Insecticidal composition | |
| CN101263824A (en) | Insecticidal composition | |
| CN104026146A (en) | Binary pesticide composition and its use | |
| CN108651514A (en) | A kind of composition pesticide containing fosthiazate and fluxapyroxad |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20050524 Pledge (preservation): Preservation |
|
| PD01 | Discharge of preservation of patent |
Date of registration: 20060525 Pledge (preservation): Preservation |
|
| C56 | Change in the name or address of the patentee |
Owner name: XUANHUA AGRICULTURE CHEMICALS CO., LTD., HEBEI Free format text: FORMER NAME OR ADDRESS: XUANHUA PESTICIDE FACTORY, ZHANGJIAKOU |
|
| CP03 | Change of name, title or address |
Address after: 075100 Xuanhua pesticide factory, Hebei, Zhangjiakou Patentee after: Hebei Xuanhua Pesticide Co., Ltd. Address before: 075100 Xuanhua pesticide factory, Hebei, Zhangjiakou Patentee before: Xuanhua Pesticide Factory, Zhangjiakou City |
|
| ASS | Succession or assignment of patent right |
Owner name: HEBEI XUANHUA YIA PESTICIDES CO., LTD. Free format text: FORMER OWNER: XUANHUA AGRICULTURE CHEMICALS CO., LTD., HEBEI Effective date: 20071019 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20071019 Address after: 075100 Xuanhua pesticide factory, Hebei, Zhangjiakou Patentee after: Hebei Xuanhua Yi'a Pesticides Co., Ltd. Address before: 075100 Xuanhua pesticide factory, Hebei, Zhangjiakou Patentee before: Hebei Xuanhua Pesticide Co., Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20050504 Termination date: 20151109 |
|
| EXPY | Termination of patent right or utility model |