CN1219339C - Recycling battery - Google Patents
Recycling battery Download PDFInfo
- Publication number
- CN1219339C CN1219339C CNB018074863A CN01807486A CN1219339C CN 1219339 C CN1219339 C CN 1219339C CN B018074863 A CNB018074863 A CN B018074863A CN 01807486 A CN01807486 A CN 01807486A CN 1219339 C CN1219339 C CN 1219339C
- Authority
- CN
- China
- Prior art keywords
- battery
- recycling battery
- cell
- reservoir
- described recycling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
- H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
- H01M12/065—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode with plate-like electrodes or stacks of plate-like electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/50—Methods or arrangements for servicing or maintenance, e.g. for maintaining operating temperature
- H01M6/5077—Regeneration of reactants or electrolyte
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Secondary Cells (AREA)
- Hybrid Cells (AREA)
- Fuel Cell (AREA)
Abstract
The present invention relates to a recycling battery which comprises a feeding device, a battery pack and a discharging device, wherein the feeding device is used for quantitatively adding metallic granules and an electrolytic solution in each single battery to make the battery normally work. When the voltage output or the current output of the battery is lower than a rated value, a waste liquid is discharged by a discharging device, a new electrolytic solution and metallic granules are supplemented, and the battery can work again. In this way, the present invention realizes the circulation of charging, discharging and charging and has the advantages of fast charging, long discharging duration and large capacity, and the recovered waste electrolyte can be reused by reducing reaction, namely no pollution. The present invention is a new environmental protection type energy resource.
Description
Technical field
The present invention relates to a kind of battery, particularly relate to a kind of battery that can recycle.
Background technology
At present, the dry cell of selling on the market, rechargeable battery have a variety of, and still, all there is the problem that battery capacity is little, the continuous discharge time is short, manufacturing cost is high in they.In addition,, also exist and must use alternating current to charge for rechargeable battery, and long shortcoming of charging stand-by period, this brings inconvenience with regard to the use for no alternating current areas such as rural area, fields.
Summary of the invention
At the problems referred to above, the present inventor has finished the present invention finally through concentrated research.
Of the present inventionly provide a kind of recycling battery, comprised feeding device, battery pack and discharging device, wherein, described feeding device comprises for the charge door that adds clipped wire, the overflow pipe that is used to add the filling opening of electrolyte and unnecessary electrolyte is discharged; Described battery pack comprises at least one cell; Described discharging device is located at the battery bottom.This battery is by adding clipped wire, electrolyte at random or at regular time and quantity, make the battery operate as normal, when cell output voltage or electric current are lower than rated value, discharge the waste liquid in the battery, replenish new electrolyte through the liquid feeding storehouse and add new clipped wire through adding feed bin, battery can be reworked, if liquid level of electrolyte surpasses quantitatively, then flow out by overflow pipe.The waste electrolyte that reclaims also can reuse by reduction reaction, can realize recycling of battery like this.
Recycling battery provided by the invention based on electrochemical theory, under above-mentioned guiding theory, can have different structural designs to realize according to the operating position of reality.
According to technical scheme of the present invention, be provided with at least one positive plate and a negative pole currect collecting net in the described cell, be provided with barrier film between this positive plate and the negative pole currect collecting net, clipped wire contacts with negative pole currect collecting net, and each cell is assembled by battery box.
Described positive plate is made according to the order of catalyst layer, black bisque, anode collection net, black bisque from inside to outside, and outer black bisque contacts with air or oxygen.
Recycling battery provided by the invention can comprise two types product according to the overall structure and the course of work, and in first type, positive plate, barrier film and negative pole currect collecting net are plane contact successively and are pressed into one; Below clipped wire, be provided with screen cloth, and this screen cloth is positioned at discharging device top.Clipped wire and electrolyte add each cell respectively from add feed bin and liquid feeding storehouse, the reaction beginning, powered battery, when output voltage or electric current are lower than the standard definite value, according to of the by-pass valve control effluent discharge of prompting elder generation from drain hole, change simultaneously or interpolation electrolyte or clipped wire, battery can be reworked, and realizes the circulation discharge.
In second type, increased electrolyte circulation means, electrolyte is circulated in power supply process, the cleaning of the replenishing of complexed metal grain and electrolyte, waste liquid and residue, thus obtain constant discharge power, realize circulating discharge.
Detailed Description Of The Invention
According to recycling battery provided by the invention, comprise feeding device, battery pack and discharging device, wherein, described feeding device comprises the charge door that supplies to add clipped wire, the overflow pipe that is used to add the filling opening of electrolyte and unnecessary electrolyte is discharged; Described battery pack comprises at least one cell; Described discharging device is located at the battery bottom.
Be provided with at least one positive plate and a negative pole currect collecting net in the described cell, be provided with barrier film between this positive plate and the negative pole currect collecting net, clipped wire contacts with negative pole currect collecting net, each cell is assembled by battery box, the positive and negative electrode in the cell outside is in series or in parallel with each other, becomes battery pack.
Positive plate in the cell is made according to the order of catalyst layer, black bisque, anode collection net, black bisque from inside to outside, and outer black bisque contacts with air or oxygen.
Clipped wire in the battery of the present invention can be made by lithium, sodium, calcium, aluminium, magnesium, zinc, iron, cadmium, and be regular solid or irregular geometries such as bigger granular, the sheet of surface area, as hollow or solid cylinder, hollow or filled circles cone, hollow or solid sphere, hollow or solid cuboid, and wood shavings shape roll film shape etc.
Described anode collection net, negative pole currect collecting net are made by electric conducting material, and preferred negative pole currect collecting net is cellular, circular, prismatic, bar shaped, rectangle or other is irregularly shaped.
According to a kind of scheme of the present invention, positive plate, barrier film and negative pole currect collecting net are plane contact successively and are pressed into one or this negative pole currect collecting net and pack in the cell the inboard gas block panel that is provided with may command by the air mass flow of positive plate about cell with bar shaped into.In feeding device, be provided be combined as a whole add feed bin, big cap and housing, cell connects to form battery pack by adding feed bin, big cap and housing, adds the charge door and the quantitative control device that are provided with clipped wire below the feed bin.
Wherein, but described quantitative control device is the pumping board of a pull, and this pumping board is provided with corresponding to the hole of cell or groove, or is a whole plate.
Perhaps, this quantitative control device is the revolving door by the control of elasticity hinge.
According to this preferred version of the present invention, discharging device comprises battery discard solution discharge port and tapping groove, and this discard solution discharge port comprises a waste liquid storage tank, and its pipe joint place, lower end is provided with by-pass valve control.When needing to change reaction mass, the battery waste liquid that arrives in the waste liquid storage tank can be expelled in the tapping groove by by-pass valve control.This by-pass valve control can be manual type valve or electrodynamic type valve, perhaps is made of U type chuck and the holder that matches with it.
According to second type of recycling battery of the present invention, increased electrolyte circulation means, it is by the circulating pump that can utilize self electric energy work, woven hose, form to the shower of cell spray electrolyte and the reservoir that stores electrolyte, this circulating pump is located on the reservoir, woven hose is drawn from reservoir with shower and is linked to each other, negative pole currect collecting net is located in the cell and positive plate and the perpendicular face of barrier film, and part inserts in the clipped wire, but and the bottom be the screen cloth of barrier metal grain.
According to the embodiment of the present invention, electrolyte is sent to the shower on battery top and sprays in the battery through woven hose under the driving of circulating pump, and realizes circulating.
Wherein, overflow pipe communicates with reservoir, and unnecessary electrolyte is sent back to reservoir.
Optionally, can be provided with the valve that the control waste liquid is discharged at the bottom of battery liquid outlet, be preferably the porcelain valve, or reservoir is located at battery one side, battery bottom is provided with liquid back pipe and communicates with reservoir.
According to above-mentioned principle, by adopting technique scheme, recycling battery of the present invention can be at random or adding electrolyte and clipped wire regularly, can waste liquid be discharged by valve simultaneously, thereby realize the power supply-charging-power cycles of battery.
In addition, recycling battery of the present invention since clipped wire and electrolyte can add at random or regularly, thereby realized that the battery continuous discharge time is long, capacity is big, the purpose of discharging voltage balance, and the charging interval is short, has brought convenience for the use in no alternating current areas such as rural area, field.
In addition, the recyclable regeneration of the waste liquid of cycle battery of the present invention makes clipped wire reach reusable purpose, has saved the energy, has protected environment, has reduced cost.
Result relatively is as shown in table 1 for recycling battery of the present invention and existing battery relevant parameter.
Table 1
| Battery string | Theoretical specific energy Wh/Kg | Actual specific energy Wh/Kg | Open circuit voltage (V) | Operating voltage (V) | Price ($/Kwh) |
| Lead-acid | 170 | 25～35 | 2.1 | 1.5～1.8 | 60～100 |
| Cadmium-nickel | 200 | 30～45 | 1.3 | 1.0～1.2 | 600～1000 |
| Iron-nickel | 267 | 35～45 | 1.07 | 1.2～1.6 | 500～1200 |
| Zinc-nickel | 345 | 60～70 | 1.73 | 1.2～1.6 | 180～320 |
| Nickel-hydrogen | 50～60 | 1.3 | 1.0～1.2 | 2400～5500 | |
| Zinc- | 20～35 | 1.5 | 1.2～1.0 | ||
| Battery of the present invention | 1350 | 400～1000 | 1.5 | 1.0～1.2 | 25～40 |
Description of drawings
Fig. 1 is the structural representation of cell in first type of battery of the present invention.
Fig. 2 is the A-A cutaway view of Fig. 1.
Fig. 3 be first type of battery of the present invention battery pack (12 groups) embodiment partly cut open structural representation.
Fig. 4 is the B-B cutaway view of Fig. 3.
Fig. 5 is the vertical view of Fig. 4.
Fig. 6 is the enlarged diagram of C portion among Fig. 3.
Fig. 7 be first type of battery of the present invention battery pack another kind of specific embodiment partly cut open structural representation.
Fig. 8 is the D-D cutaway view of Fig. 7.
Fig. 9 is the enlarged diagram of E portion among Fig. 7.
Figure 10 is the structural representation of battery discharging device embodiment of the present invention.
Figure 11 is the enlarged diagram of H portion among Fig. 2.
Figure 12 is second type of the present invention's a battery structure schematic diagram.
Figure 13 is the structure principle chart of the present invention's battery cell shown in Figure 12.
Figure 14 is the enlarged diagram of I portion among Figure 12.
Figure 15 is the battery structure schematic diagram of second type of another embodiment of the present invention.
Figure 16 is the enlarged diagram of Q portion among Figure 15.
Figure 17 is the structure principle chart of cell embodiment illustrated in fig. 15.
Figure 18 is the vertical view of battery embodiment illustrated in fig. 15.
Figure 19 is the battery structure schematic diagram of second type of another embodiment of the present invention.
Figure 20 is the enlarged diagram of Z portion among Figure 19.
Figure 21 is the monomer structure schematic diagram of Figure 19 embodiment battery.
Figure 22 is battery discharge curve chart of the present invention (showing the discharge with 17A, voltage and time relation).
The best mode that carries out an invention
Referring to the recycling battery of the present invention shown in Fig. 1-6, by the feeding device on top, the battery pack at middle part and the discharging device of bottom are formed.Wherein, feeding device comprises charge door 29, filling opening 30 and overflow pipe 18, and charge door 29 is used for quantitatively or non-quantitative adds clipped wire 17, and filling opening 30 is used for quantitatively or non-quantitative adds electrolyte, overflow pipe 18 can make unnecessary electrolyte overflow, and flows in the flash groove 28.
Can comprise one or more cell 6 in the battery pack, each cell 6 is by battery box 13 assembling, the positive and negative electrode in cell 6 outsides one-tenth battery pack in series or in parallel with each other, and by add feed bin 3, big cap 4 is connected with housing 5.
In the structure chart shown in Figure 1, the right is the view that has clipped wire 17, the left side is the view that removes behind the clipped wire 17, clipped wire 17 can be made by metals such as lithium, sodium, calcium, aluminium, magnesium, zinc, iron, cadmiums, regular solid or irregular geometries such as long-pending bigger granular, the sheet of its shape preferred surface, as hollow or solid cylinder, hollow or filled circles cone, hollow or solid sphere, hollow or solid cuboid, and wood shavings shape roll film shape etc.As shown in Figure 1 and Figure 2, on battery box 13, be equiped with symmetrical positive plate 14, barrier film 15, negative pole currect collecting net 16, the centre is a clipped wire 17, clipped wire 17 bottoms are provided with screen cloth 21, positive plate 14 is formed by catalyst layer, black bisque, anode collection net 27, black bisque plane contact compacting successively, and outer field black bisque outwards contacts with air (oxygen), and the anode collection net is made with the electric conductor of various metals.Lifting one's head of positive plate 14 is connected with the positive pole 33 of box body 13, and the negative pole currect collecting net 16 that is the bar palisade is connected with negative pole 32.Illustrated in figures 1 and 2 is the structure of cell, and according to actual conditions, the battery that itself also can be used as single group uses.
The enlarged diagram of Figure 11 shows that positive plate 14, barrier film 15 and negative pole currect collecting net 16 contact, for through colding pressing or hot pressing is integral.
Discharging device comprises waste liquid storage tank 34 and valve 11, and waste liquid storage tank 34 is positioned at the bottom of battery box 13, is funnel-form, and trench bottom is provided with pipe joint 22 and controllable valve 11, the corresponding tapping groove 31 of pipe joint 22 outlets.
Fig. 3, Fig. 4, Fig. 5 and Figure 6 shows that the specific embodiment of the battery of being made up of 12 cells, it comprises feeding device, battery pack and discharging device.
Wherein, in the feeding device, adding feed bin 3, cap 4 and housing 5 is connected as a single entity, add and be provided with feeding cover 1 above the feed bin 3, but be provided with the pumping board 7 of a pull below, correspondence is provided with hole or groove on the pumping board 7, as shown in Figure 6, when pumping board 7 moves a certain distance, add clipped wire 7 in the feed bin 3 and can fall into separately cell 6; In addition, pumping board 7 also can be a whole plate, all extracts out and equally also can realize quantifying feed.The battery right side is provided with liquid feeding storehouse 2, can be quantitatively or non-quantitative add electrolyte.The battery left side is provided with overflow pipe 18, unnecessary electrolyte can be flowed out.The inboard is provided with gas block panel 26 about battery, can control air (oxygen) flow by positive plate 14, thereby reaches the heat dispersion of regulating discharge battery inside, perhaps closes air (oxygen) to stop discharge.
Add feed bin 3, cap 4 and housing 5 and be connected a plurality of cells 6, as shown in Figure 3, the left side is the view that removes behind the clipped wire 17, and the right is the view that has clipped wire 17.Clipped wire 17 is a hollow cylinder, that negative pole currect collecting net 16 is is cellular (or be regular shapes such as circle, prismatic, bar shaped, rectangle, or irregular netted, strip etc.).Can connect between the cell 6, also can be in parallel.
In the discharging device, be storage waste liquid tank 34 lower end pipe joints 22 places of funnel type, be provided with electric control valve 10, pipe joint 22 lower ends connect discharging tube 9.
Fig. 7, Fig. 8 show is that structure and the above-mentioned battery of recycling battery embodiment of the present invention is basic identical, difference is: feed bin 3 following each charging place that add in the feeding device are equipped with revolving door 19, it is controlled by elasticity hinge 20, thereby can quantitatively add clipped wire 17 (as shown in Figure 9); In the discharging device, valve 11 uses manual type valve or electrodynamic type valve, in the battery pack, with the contact amount of gas block panel 26 control positive plates 14 with air (oxygen), thereby reaches the purpose that control is discharged.
Figure 10 shows that the structural representation of alternative valve 11, connect flexible pipe 23 on pipe joint 22, the flexible pipe both sides are provided with U type chuck 25 and corresponding removable holder 24, by the cooperation of U type chuck 25 and holder 24, flexible pipe 23 are formed clamping, thus cutout.Also can holder 24 is fixing, by mobile chuck 25, realize cutout or emit the purpose of waste liquid.In addition, chuck 25 and holder 24 also can plane clamping flexible pipes 23, thereby play the effect of valve.
Figure 12, the battery structure that the present invention that Figure 13 shows is second type has increased electrolyte circulation means with noted earlier comparing, it is by the circulating pump 36 that can utilize self electric energy work, woven hose 37, form to the shower 38 of cell 6 spray electrolyte and the reservoir 39 of storage electrolyte, this circulating pump 36 is located on the reservoir 39, woven hose 37 is drawn from reservoir 39 with shower 38 and is linked to each other, negative pole currect collecting net 16 is located in the cell 6 face perpendicular with positive plate and barrier film 15, and part is inserted (this part is a strip) in the clipped wire 17, and but the bottom is the screen cloth of barrier metal grain, the electrolyte that flows is separated unlikely resulting in blockage with clipped wire.The embodiment battery cited with the front compares, and removed to add feed bin 3 and gas block panel 26, increased pump 36, woven hose 37, shower 38 and reservoir 39.
The pump 36 that battery itself has, utilize self electric energy, can deliver to shower 38 (as shown in figure 14) to the electrolyte in the reservoir 39 by woven hose 37, spray to cell 6 by shower 38, electrolyte circulates in battery under the driving of pump 36, flow direction flows back to reservoir 39 by overflow pipe 18 as shown in figure 13 at last.Be admitted in the battery through woven hose 37 and shower 38, circulation so repeatedly is till output voltage or electric current are lower than rated value again.But effluent discharge this moment replenishes new electrolyte and new clipped wire.In addition, in use, can be regularly or not timing ground in cell 6, replenish clipped wire, thereby obtain constant discharge power because electrolyte is mobile in battery, help the equilibrium of heat to derive.In addition, the battery bottom also is provided with the valve that is used for effluent discharge, and preferred in the present embodiment this valve is a porcelain valve 35, like this, regularly opens the porcelain threshold switch 35 of battery bottom, removes the residue in the cell 6, can guarantee that electrolyte can unimpededly flow.
Referring again to Figure 15, Figure 16, Figure 17, another kind of embodiment shown in Figure 180, overflow pipe 18 communicates with reservoir 39 by the adapter 41 of peripheral hardware.Electrolyte flows to adapter 41 through overflow pipe 18 in cyclic process, flow back to reservoir 39 by adapter 41 then, finishes once circulation, like this can overflow pipe 18 is hidden.
Figure 19, Figure 20, Figure 21 have then shown another embodiment design of this battery types, and reservoir 39 has been located at battery one side, and battery bottom is provided with liquid back pipe 40 and communicates with reservoir 39.Electrolyte sprays to cell 6 from shower 38, from top to bottom directly flow to tapping groove 31, flow back to reservoir 39 by liquid back pipe 40 again, this reservoir 39 is positioned at battery one side, owing to removed valve 11, electrolyte in the battery and the electrolyte in the reservoir are in connected state all the time.
Experimental example
The battery pack of using 12 cells to form, rated power 200W.Add self-control zinc granule 200～250g, 45% potassium hydroxide (KOH) solution, 200～230ml to each cell inner chamber.The employing inverter power is 80% inverter, service load is one group of the resistive load (altogether 170W) of inductive load and the 100W of 70W, at first measure the floating voltage of battery, loading is communicated with the battery circuit then, and every single cycle was measured voltage, the electric current of battery pack and cell, record data respectively at interval in 1 hour, with time is abscissa, output voltage is an ordinate, draws discharge curve, as Figure 22.Experimental result is as follows:
Weight: 7Kg
Floating voltage: 17.5V
Rated voltage: 12.5V
Capacity: 〉=1800Wh
Rated power:＞200W
Discharge time:＞8h
Charging interval: 10min
From above experimental result as can be seen, the continuous discharge time of recycling battery of the present invention is long, capacity is big, discharging voltage balance, and the charging interval is short.
Claims (26)
1, a kind of recycling battery, inside is provided with positive pole and negative pole, and clipped wire is housed, it is characterized in that: comprise feeding device, battery pack and discharging device, wherein, described feeding device comprises the charge door for the adding clipped wire, the overflow pipe that is used to add the filling opening of electrolyte and unnecessary electrolyte is discharged; Described battery pack comprises at least one cell; Described discharging device is located at the battery bottom, comprises battery discard solution discharge port and tapping groove.
2, recycling battery as claimed in claim 1, it is characterized in that: be provided with at least one positive plate and negative pole currect collecting net or collector bar in the described cell, be provided with barrier film between this positive plate and negative pole currect collecting net or the collector bar, and clipped wire contacts with negative pole currect collecting net or collector bar, and each cell is assembled by battery box.
3, the described recycling battery of claim 2, its spy is: described positive plate is made according to the order of catalyst layer, black bisque, anode collection net, black bisque from inside to outside, and outer black bisque contacts with air or oxygen.
4, the described recycling battery of claim 2, it is characterized in that: positive plate, barrier film and negative pole currect collecting net or collector bar are plane contact successively and are pressed into one.
5, the described recycling battery of claim 4 is characterized in that: be provided with screen cloth below clipped wire, and this screen cloth is positioned at discharging device top.
6, each described recycling battery of claim 1-5, it is characterized in that: in feeding device, be provided be combined as a whole add feed bin, big cap and housing, cell connects to form battery pack by adding feed bin, big cap and housing, adds the charge door and the quantitative control device that are provided with clipped wire below the feed bin.
7, the described recycling battery of claim 6 is characterized in that: but described quantitative control device is the pumping board of a pull, and this pumping board is provided with corresponding to the hole of cell or groove, or is a whole plate.
8, the described recycling battery of claim 6 is characterized in that: described quantitative control device is the revolving door by the control of elasticity hinge.
9, the described recycling battery of claim 6 is characterized in that: the discard solution discharge port of described discharging device comprises a waste liquid storage tank, and its pipe joint place, lower end is provided with by-pass valve control.
10, the described recycling battery of claim 9 is characterized in that: described by-pass valve control is manual type valve or electrodynamic type valve.
11, recycling battery as claimed in claim 9 is characterized in that: described valve is made of U type chuck and the holder that matches with it.
12, the described recycling battery of claim 6 is characterized in that: the inboard gas block panel that is provided with may command by the air mass flow of positive plate about cell.
13, each described recycling battery of claim 1-3, it is characterized in that: described recycling battery also is provided with an electrolyte circulation means, it is by the circulating pump that can utilize self electric energy work, woven hose, form to the shower of cell spray electrolyte and the reservoir that stores electrolyte, this circulating pump is located on the reservoir, and woven hose is drawn from reservoir with shower and linked to each other.
14, the described recycling battery of claim 13 is characterized in that: negative pole currect collecting net is located in the cell and positive plate and the perpendicular face of barrier film, and part inserts in the clipped wire, but and the bottom be the screen cloth of barrier metal grain.
15, the described recycling battery of claim 13, it is characterized in that: overflow pipe communicates with reservoir.
16, the described recycling battery of claim 14, it is characterized in that: overflow pipe communicates with reservoir.
17, the described recycling battery of claim 15 is characterized in that: overflow pipe communicates with reservoir by the adapter of peripheral hardware.
18, the described recycling battery of claim 16 is characterized in that: overflow pipe communicates with reservoir by the adapter of peripheral hardware.
19, the described recycling battery of claim 13 is characterized in that: the bottom liquid outlet of battery is provided with the valve that the control waste liquid is discharged.
20, the described recycling battery of claim 14 is characterized in that: the bottom liquid outlet of battery is provided with the valve that the control waste liquid is discharged.
21, the described recycling battery of claim 19 is characterized in that: this valve is the porcelain valve.
22, the described recycling battery of claim 20 is characterized in that: this valve is the porcelain valve.23, the described recycling battery of claim 13 is characterized in that: reservoir is located at battery one side, and battery bottom is provided with liquid back pipe and communicates with reservoir.
24, the described recycling battery of claim 1, it is characterized in that: described clipped wire is made by lithium, sodium, calcium, aluminium, magnesium, zinc, iron, cadmium.
25, recycling battery as claimed in claim 2 is characterized in that: described anode collection net, negative pole currect collecting net are made by electric conducting material.
26, as claim 2 or 25 described recycling batteries, it is characterized in that: described negative pole currect collecting net is cellular, circular, prismatic, bar shaped, rectangle or irregularly shaped.
27, recycling battery as claimed in claim 1 is characterized in that: serial or parallel connection between a plurality of cells.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN00113785 | 2000-04-12 | ||
| CN00113785.9 | 2000-04-12 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1421056A CN1421056A (en) | 2003-05-28 |
| CN1219339C true CN1219339C (en) | 2005-09-14 |
Family
ID=4583541
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB018074863A Expired - Fee Related CN1219339C (en) | 2000-04-12 | 2001-04-10 | Recycling battery |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN1219339C (en) |
| AU (1) | AU2001267264A1 (en) |
| WO (1) | WO2001095422A1 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103531865B (en) * | 2013-10-08 | 2017-01-25 | 刘甲祥 | Household magnesium air battery system |
| CN104577033B (en) * | 2014-10-31 | 2017-09-29 | 浙江吉利控股集团有限公司 | Metal fuel battery electrolyte charging method |
| CN105914430B (en) * | 2016-06-23 | 2018-08-17 | 河北工业大学 | A kind of electrolyte vertical circulation zinc and air cell group |
| CN107658419B (en) * | 2017-08-04 | 2024-04-30 | 苏州讴德新能源发展有限公司 | Battery with open bottom and circulating electrolyte |
| CN113488690A (en) * | 2021-07-30 | 2021-10-08 | 徐杨 | Metal fuel oxygen power generation and reduction device |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5418080A (en) * | 1994-07-01 | 1995-05-23 | Electric Fuel (E.F.L.) Ltd. | Mechanically rechargeable, electrochemical metal-air battery |
| CN2266199Y (en) * | 1996-07-24 | 1997-10-29 | 张素诚 | Metal powder-air cell |
| CN1199936A (en) * | 1997-05-20 | 1998-11-25 | 李广文 | Aluminium air battery |
-
2001
- 2001-04-10 WO PCT/CN2001/000552 patent/WO2001095422A1/en active Application Filing
- 2001-04-10 AU AU2001267264A patent/AU2001267264A1/en not_active Abandoned
- 2001-04-10 CN CNB018074863A patent/CN1219339C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| WO2001095422A1 (en) | 2001-12-13 |
| WO2001095422A8 (en) | 2002-11-14 |
| AU2001267264A1 (en) | 2001-12-17 |
| CN1421056A (en) | 2003-05-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US10826143B2 (en) | Refuelable electrochemical battery | |
| KR100905939B1 (en) | Metallic fuel cell system | |
| US3359136A (en) | Rechargeable energy conversion system | |
| CN1219339C (en) | Recycling battery | |
| CN101030664A (en) | Directly chargeable zinc-air battery for electric vehicle | |
| CN100347888C (en) | Battery grid and casting method thereof | |
| CN209298300U (en) | A kind of waste and old pole plate recyclable device | |
| CN218306505U (en) | Solid-liquid separation device for battery anode slurry | |
| CN208014765U (en) | A kind of battery pack device with high-energy density | |
| CN100505412C (en) | Energy supplementing system of zinc air battery | |
| CN202150719U (en) | Mutual charging type energy saving charging circuit of storage battery | |
| CN218223531U (en) | Sorting device for recycling waste dry batteries | |
| CN214830712U (en) | Novel environment-friendly and energy-saving titanium anode net device | |
| CN110589936A (en) | Photovoltaic purifying instrument based on electrolytic purification | |
| CN211839156U (en) | Solar panel washing and brushing equipment for solar street lamp | |
| CN216094587U (en) | Feeding system of conductive paste | |
| CN2764000Y (en) | Mechanical block-plug in type zinc-air battery | |
| CN108855249A (en) | A kind of novel high polymer ionization sub-exchange resin regenerating unit | |
| CN112018448B (en) | Long-life lithium battery | |
| JPH0351890Y2 (en) | ||
| CN212182388U (en) | New concept battery | |
| CN213184426U (en) | Solar cell with deep-cycle formula | |
| CN213124690U (en) | Novel lithium battery | |
| CN219580671U (en) | Preliminary crushing equipment for battery recovery | |
| CN209476471U (en) | Brine separating device is used in a kind of processing of waste lithium cell |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |