CN1218026C - Solid dispersible abrasive compositions - Google Patents
Solid dispersible abrasive compositions Download PDFInfo
- Publication number
- CN1218026C CN1218026C CN01807818.4A CN01807818A CN1218026C CN 1218026 C CN1218026 C CN 1218026C CN 01807818 A CN01807818 A CN 01807818A CN 1218026 C CN1218026 C CN 1218026C
- Authority
- CN
- China
- Prior art keywords
- composition
- abrasive material
- water
- consumption
- abrasive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 99
- 239000007787 solid Substances 0.000 title claims abstract description 31
- 239000007788 liquid Substances 0.000 claims abstract description 44
- 239000000725 suspension Substances 0.000 claims abstract description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000004094 surface-active agent Substances 0.000 claims abstract description 18
- 238000002156 mixing Methods 0.000 claims abstract description 11
- 230000008719 thickening Effects 0.000 claims abstract description 4
- 239000003082 abrasive agent Substances 0.000 claims description 61
- 239000013543 active substance Substances 0.000 claims description 20
- -1 anion sulfate Chemical class 0.000 claims description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 229920000642 polymer Polymers 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 6
- 125000000129 anionic group Chemical group 0.000 claims description 5
- 239000006185 dispersion Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 150000001298 alcohols Chemical class 0.000 claims description 4
- 238000005187 foaming Methods 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 2
- 239000002736 nonionic surfactant Substances 0.000 claims 1
- 230000003019 stabilising effect Effects 0.000 claims 1
- 239000000693 micelle Substances 0.000 abstract description 2
- 239000000843 powder Substances 0.000 description 17
- 239000003599 detergent Substances 0.000 description 14
- 239000000047 product Substances 0.000 description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- 238000009837 dry grinding Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 229910021532 Calcite Inorganic materials 0.000 description 7
- 125000000217 alkyl group Chemical group 0.000 description 7
- 239000003945 anionic surfactant Substances 0.000 description 7
- 229920002125 Sokalan® Polymers 0.000 description 6
- 235000013599 spices Nutrition 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 230000002209 hydrophobic effect Effects 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- 239000000344 soap Substances 0.000 description 5
- 239000006061 abrasive grain Substances 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 150000004996 alkyl benzenes Chemical class 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 150000001721 carbon Chemical group 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 4
- 150000002632 lipids Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 238000010008 shearing Methods 0.000 description 4
- 235000017550 sodium carbonate Nutrition 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 3
- 239000007844 bleaching agent Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 229920000945 Amylopectin Polymers 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 2
- 235000018936 Vitellaria paradoxa Nutrition 0.000 description 2
- 241001135917 Vitellaria paradoxa Species 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 229940096386 coconut alcohol Drugs 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 239000010431 corundum Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000010433 feldspar Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- ILHIHKRJJMKBEE-UHFFFAOYSA-N hydroperoxyethane Chemical compound CCOO ILHIHKRJJMKBEE-UHFFFAOYSA-N 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N n-propyl alcohol Natural products CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 229940057910 shea butter Drugs 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000007790 solid phase Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229920003179 starch-based polymer Polymers 0.000 description 2
- 239000004628 starch-based polymer Substances 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- SIDULKZCBGMXJL-UHFFFAOYSA-N 1-dimethylphosphoryldodecane Chemical compound CCCCCCCCCCCCP(C)(C)=O SIDULKZCBGMXJL-UHFFFAOYSA-N 0.000 description 1
- KRUABTDBQQLWLS-UHFFFAOYSA-N 1-methylsulfinyltetradecane Chemical compound CCCCCCCCCCCCCCS(C)=O KRUABTDBQQLWLS-UHFFFAOYSA-N 0.000 description 1
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 1
- JCBPETKZIGVZRE-UHFFFAOYSA-N 2-aminobutan-1-ol Chemical compound CCC(N)CO JCBPETKZIGVZRE-UHFFFAOYSA-N 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- 229910000632 Alusil Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000640882 Condea Species 0.000 description 1
- 208000006558 Dental Calculus Diseases 0.000 description 1
- 101100117236 Drosophila melanogaster speck gene Proteins 0.000 description 1
- 239000004908 Emulsion polymer Substances 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000283986 Lepus Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- ATTZFSUZZUNHBP-UHFFFAOYSA-N Piperonyl sulfoxide Chemical compound CCCCCCCCS(=O)C(C)CC1=CC=C2OCOC2=C1 ATTZFSUZZUNHBP-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 230000021736 acetylation Effects 0.000 description 1
- 238000006640 acetylation reaction Methods 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 229920006318 anionic polymer Polymers 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000000305 astragalus gummifer gum Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000005908 glyceryl ester group Chemical group 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229910052588 hydroxylapatite Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000000266 injurious effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229940045996 isethionic acid Drugs 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- 229960001708 magnesium carbonate Drugs 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 150000004028 organic sulfates Chemical class 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 150000003008 phosphonic acid esters Chemical class 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000008698 shear stress Effects 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
- C11D11/0094—Process for making liquid detergent compositions, e.g. slurries, pastes or gels
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0013—Liquid compositions with insoluble particles in suspension
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
Abstract
The invention provides dry compositions comprising a solid abrasive (preferably at least 65 %) and a suspending system (preferably at least 0.1 %) suitable to obtain a stable suspension on mixing with a liquid medium. Suitable suspending systems are based on a surfactants or surfactant mixtures which are able to form a lamellar micelle phase after mixing with the liquid medium or on polymeric thickening systems. The preferred liquid medium is water. The dry abrasive compositions are free flowing and easily dispersible in water by the consumer to obtain a ready-to-use liquid abrasive cleaner.
Description
Invention field
The present invention relates to contain abrasive material and be suitable in water disperseing and obtain a kind of confession and clean the solids composition that liquid abrasive material that crust uses is cleaned composition.
Background of invention
It is well-known in the art that the liquid abrasive material of crust is cleaned composition, generally comprises the combination of detersive surfactant, the especially combination of negatively charged ion and nonionogenic tenside, and they form the stratiform micellar phase jointly and make this liquid retrogradation whereby.This lamellar phase plays a kind of suspension system, and solid abrasive is remained in stable suspended state.Ionogen and/or polymer viscosifier have usually also been added, with the further stability of improving this suspension.
For example, WO 91/08283 discloses, the liquid abrasive material is cleaned composition and is comprised the stain remover of 0.02-20%, the abrasive material particles of 1-70% and the thickened mixt of 0.01-10%, comprises the non-starch based polymers of a kind of straight chain and a kind of amylopectin base polymer (amylopectin).Non-starch based polymers comprises various natural gums and synthetic polymkeric substance.By comparison, especially with the partial acetylation xanthan gum for well.In fact the consumption that requires of thickened mixt is about 3% of said composition gross weight, and the consumption of regulation nonionogenic tenside is 1.5% in all examples.
WO 95/08619 discloses, and the liquid abrasive material is cleaned combination, a kind of pH regulator agent and a kind of lime carbonate abrasive material that composition comprises a kind of crosslinked polyacrylic ester, at least a nonionogenic tenside or a kind of anion surfactant and a kind of nonionogenic tenside.This grade compound allegedly contain polyacrylic ester, the 0.1-10% of 0.1-2% nonionic, be up to 10% negatively charged ion and the abrasive material of 5-60%.According to example, in fact they contain the polymkeric substance, 0.5% or the abrasive material of more nonionic and 40% of 0.25-0.4%.Requiring nonionogenic tenside is in order to keep appropriate viscosity characteristics.Disclose similar compositions in EP 649898, but extra collateral condition is, they contain hypochlorite and its tensio-active agent to bleach stable.
EP-A-0 857 557 has described a kind of moisture thickener composition that is fit to multiple terminal applies, it comprises that at least two kinds of its hydrophile-lipophile balance values of 0.04-30 weight % differ tensio-active agent mixture according to a certain percentage and a kind of associative thickeners of 0.01-5 weight % of a unit at least, and it is selected from hydrophobic modified Natvosol, hydrophobic modified nonionic polyol and the hydrophobic modified solvable emulsion polymer of alkali.In fact, the consumption of associative thickeners is 1-2%, and the consumption of surfactant mixture is 1-10%.
Crust liquid abrasive material is cleaned composition and is sold with available form at any time usually, and it contains 10-50%, in most cases is the solid abrasive of 30-45%.Such composition can not be diluted to such as 10-20% solid abrasive content and not lose its precipitating stability.Though quoted the abrasive material content up to 70% in the patent documentation, such content generally be can't see in commercial product.
Liquid abrasive material detergent become popular before, general custom is in using the powder abrasive composition to clean crust, and in some countries so far still like this.Such composition is almost all by powder abrasive material promptly 95% or above and a spot of (＜5%) lathering surfactant formation.This composition is directly put on crust to be washed and uses a spot of water, as a piece of cloth is got wet.This tensio-active agent is assisted the effect of cleaning by improving on the crust wetting property of water/abrasive mixt, and relies on and form foam and clean signal directly perceived is provided.For example, PL153680 has described solid abrasive and has cleaned composition, and they contain levigate quartz, feldspar or the glass of 45-95%; The synthetic anionic of 1.5-23% or nonionogenic tenside (the especially multipolymer of linear alkylbenzene sulphonic acid and alkylene oxide); A kind of chlorine bleaching compound; Phosphoric acid/the urea complex of 0.1-50% and the sodium sulfate of 0.1-25%.GB1,339,274 have described similar compositions, and they comprise a kind of hot compound that produces when mixing with water in addition in cleaning operating process.RU 2106376 has described a kind of powder abrasive material detergent, and it contains levigate quartz and as the sodium polyacrylate of tensio-active agent.This product is intended as classical powder abrasive material and uses.JP-A-02029497 has described the abrasive material detergent, and they can have the form of powder or liquid, and contains hydroxyapatite and a kind of tensio-active agent as abrasive material.EP-A-0 821 721 has described ready-to-use abrasive powders, and they contain as the mixture of the yellow soda ash of water-soluble abrasive material and sodium bicarbonate, a kind of anionic detergent and a kind of solid hypochlorite bleaching.
Only by adding an amount of water, can not make the clean composition of powder abrasive material of prior art be transformed into the clean composition of liquid abrasive material, because the tensio-active agent that exists in this powdered mixture is not to be intended to nor may to form desired lamellar micelle phase, to keep solid abrasive in stable suspended state.Thereby this abrasive material can separate and be sink to the bottom of its container rapidly.
But, form with powder or particle, it is useful still to obtain a kind of dry mixture with the form of other suitable solid, it plays a kind of liquid abrasive material detergent that gets when adding an amount of water, promptly can be transformed into a kind of available and stable at any time liquid abrasive material detergent.Like this, just can save shipment big water gaging related packing and trucking costs, and can avoid the harmful effect of storage requirement the stability of getting liquid system ready.
Dry grinding material soap powder also is good for removing the stain that is difficult to remove on the skin.Just such product is described such as US 4786432 and US 4786369.They comprise the abrasive grain with a kind of anion surfactant coating of most of fatty acid soaps.Soap powder generally contains less than 80% abrasive material and is not more than about 50% as a rule.EP-B-0 796 318 has described and has been intended to the free-pouring preparation of solid that is used to wash one's hands.This preparation can by a kind of stain remover of fluidised bed drying stick with paste with the mixture of abrasive material and in addition pelletization treatment obtain, abrasive material then is selected from float stone, wood meal, levigate nutshell or vegetable fibers.Such powder is not really wanted to mix with water before use, and wherein used soap system does not have any suspension characteristic to its abrasive material.
WO 94/25563 has described sheet, piece or the analogous shape particle that comprises tensio-active agent and optional abrasive material.They are to be used for cleaning mechanical means, and obviously are not suitable for converting to steady suspension.Here mention, the needs to suspension system have been avoided in piece material and use thereof.
Yet, whether have in the above-mentioned solid phase prod to be transformed into steady suspension person, but do not point out.
The invention summary
The invention provides dried solids composition, they can mix and form stable, ready-to-use crust liquid abrasive material and clean composition with liquid medium.Therefore, this dry composition comprise a kind of solid abrasive and a kind of with make this abrasive material remain in the suspension system of stable suspersion state after liquid medium mixes.
The present invention also provides a kind of preparation liquid abrasive material to clean method for compositions, comprises making a kind of dry composition and a kind of liquid medium blended step that comprises solid abrasive and suspension system, and need not further to be mixed into any other component.
In addition, the invention provides the liquid abrasive material that obtains according to aforesaid method and clean composition.
Detailed Description Of The Invention
Except as otherwise noted, all percentage compositions given here are all according to the weight of whole composition.
Basal component according to dry grinding feed composition of the present invention comprises: a kind of solid abrasive as its main component, preferable amount is at least 55%, with a kind of suspension system that is suitable for obtaining stable suspension when mixing with liquid medium, preferable amount is at least 0.1%.In addition, said composition comprises that also a kind of very hope has but the lathering surfactant of optional member, and preferable amount is at least 0.1%.
This dry composition is fit to the human consumer and mixes it with liquid medium at home, and obtains ready-to-use liquid abrasive material detergent.On the other hand, can be with this dry composition shipment to a tame factory, the simple mixing equipment of factory just is enough to dry composition is transformed into ready-to-use liquid abrasive composition, in order to packing and transporting to the human consumer.
This liquid medium can be any liquid, and it is suitable and safety for human consumer's use.Therefore, it should not harm health, and is preferably non-flammable.Significantly selecting is water, but some organic solvents or these solvents also can be fit to the mixture of water.Preferably, this medium comprises at least 85% water.
In this dry composition, the preferable amount of abrasive material is at least 65%, even more preferably be at least 70% 75%.This abrasive material can be any fine particle solid that is suitable as abrasives as known in the art.This known materials major part is insoluble in water, still, suitable water-soluble material is arranged also.Preferred abrasive material has to be 6 or to be lower than 6 Mohs' hardness, although can use the abrasive material of higher hardness for special application.In general, the hardness of abrasives is low more, and it is just more little to the damage on surface, but, render a service for producing to clean fully, and should be 1 or with hardness greater than 1.
The soluble abrasive material of water that is fit to can be selected from synthetic and naturally occurring material (mineral), its example comprises: zeolite, silica, silicate, carbonate, corundum and organic polymer abrasive material, such as polyethylene, polycarbonate, polyurethane(s), polystyrene, polypropylene, polyethylene terephthalate, poly-methyl iso-butylene ester and nylon with and composition thereof.Preferred abrasive material is: mixture (as rhombspar), zeolite, corundum, hydrated aluminum oxide, feldspar, talcum and the silica of lime carbonate (as calcite), lime carbonate and magnesiumcarbonate.By comparison, especially with calcite and rhombspar and with the mixture of silica, particularly the non-crystalline state silica of low consumption for well good again because its cost hangs down the abrasive material characteristic.
The water-soluble abrasive material that is fit to comprises yellow soda ash, sodium bicarbonate, tripoly phosphate sodium STPP, Sodium Tetraborate and vitriolate of tartar.A kind of water-soluble abrasive material produces the saturated aqueous solution of this abrasive material and is suspended in the solid phase of not dissolving abrasive grain in this aqueous solution when mixing with water.Be described such as in EP-A-0 193 375, this class I liquid I abrasive material being cleaned composition.
Preferred abrasive grain weighted mean granularity is the 0.5-500 micron, especially with the about 10-100 micron of granularity for well.In this scope, can reach between a kind of good washing (-)off properties and the low matrix damage can accept compromise.But, as silica is used in conjunction with calcite or rhombspar, then the average grain granularity is that the 200-500 micron also is fit closely.
Suspension system can be any suspension system of the abrasive grain in the suspension liquid abrasive material detergent as known in the art.The gratifying available at any time liquid abrasive material detergent that obtains by the dry grinding feed composition according to the present invention, should have such fluid flow characteristics, so that in that they are not to be steady suspension simultaneously, but rarely do not present dense inadequately and many water to pouring out from container and intersperse among completely on the dirty surface.Therefore, the suspension that obtains after will making water with equivalent mix with dry composition to the selection of the type of suspension system and consumption has following flow characteristics:
η
0Be 2500Pas at least
σ
cBe 2.5-25
η
21For 0.1Pas at least wherein, η
0Viscosity when being zero shearing rate; σ
cFor viscosity is 0.1 η
0The time shear-stress; And η
21For shearing rate is 21s
-1The time viscosity.η preferably
21Being 0.3-5.0, is 0.6-1.8 more preferably, is most preferably 1.0-1.5Pas.
Measure: measuring from stress (σ) with the CSL100 (TA instrument company) with impeller and gondola measuring apparatus (gondola internal diameter 48mm, impeller diameter 38mm and height 24.5mm) is that shearing rate is 1s for 0.01Pa
-1The viscosity of the stress that is required.Measure shearing rate 0.1 and 389s to have Haake RV20 that M5 measuring head and SV2P measure geometry
-1Between viscosity.All measurements are all carried out at 20 ℃.
Well-known suspension system comprises a kind of tensio-active agent or surfactant mixtures, preferably makes up with a kind of ionogen with such consumption and ratio, can form the stratiform micellar phase to cause whole combination.This tensio-active agent, perhaps one or more these tensio-active agents can be a kind of lathering surfactant, in this case, just needn't add other optional lathering surfactant again in order to obtain desirable bubbling character.Preferably, this tensio-active agent, perhaps one or more these tensio-active agents are anionic.By making a kind of anion surfactant, can obtain most suitable suspension system with a kind of ionogen, a kind of nonionogenic tenside or the combination of a kind of cats product.Specially suitable system comprises a kind of anion surfactant and a kind of nonionogenic tenside, also adds a kind of ionogen if desired again and makes it more perfect.
The such suspension system that preferably is included in the dry grinding feed composition is:
The 0.5-30% anion surfactant is preferably 1.5-25%, more preferably is 2.5-20%.
The 0.2-20% nonionogenic tenside is preferably 1.0-15%, more preferably is 1.5-12%.
Suitable anion surfactant is the water-soluble salt of organo-sulfate and sulfonic acid, and they have a kind of aliphatic group that contains 8 to 22 carbon atoms in its molecular structure.
Its suitable example is following water-soluble salt:
-long chain aliphatic alcohol sulfate, particularly those salt that obtain with the vitriolization higher alcohols, and these higher alcohols are to make by the glyceryl ester that reduces in vegetables or animal oil or the fat, such as shea butter or Oleum Cocois;
-alkylbenzene sulfonate contains those alkylbenzene sulfonates of 6 to 20 carbon atoms such as alkyl wherein;
-the second and first sulfonated alkane;
Those ethers of-alkyl glyceryl ether sulfate, the particularly higher alcohols of from shea butter and Oleum Cocois, obtaining;
-fatty mono glyceride vitriol;
The sulfuric ester of-ethoxylized fatty alcohol contains 1-6 oxyethane (EO unit) in its molecule;
-sulfated ethoxylated alkylphenol, its molecule contain 1-8 oxyethane, and wherein alkyl contains 4-14 carbon atom;
The reaction product of-lipid acid, for example from Oleum Cocois resulting those, come esterification and neutralize with isethionic acid with sodium hydroxide;
With and composition thereof.
A kind of most suitable water-soluble synthetic anion surface active agent composition of suspension system is: the alkylbenzene sulfonate of sodium, potassium and magnesium, olefin sulfonate, alkyl-sulphate and glycerin fatty acid ester vitriol.These tensio-active agents also are suitable as lathering surfactant.
When no calcium ion (such as calcite or rhombspar) was originated, fatty acid soaps also was suitable as anion surfactant.Even having under the situation of calcium ion, perhaps still need add a spot of lipid acid (＜4.5%), be beneficial to improve the stability of dilution rear suspension liquid.
The nonionogenic tenside that one class is fit to can briefly be described as such compound, they by hydrophilic alkylene oxide base in essence with a kind of perhaps be the organic compound condensation of aliphatic cpd or alkyl aromatics and making in essence.The hydrophilic group that connects with any specific hydrophobic group or the length of polyoxyalkylenes can easily be regulated, to produce a kind of equilibrated water-soluble cpds that has between desirable hydrophilic and hydrophobic composition.So just, can select nonionogenic tenside with suitable HLB.
Specific example comprises:
-in its straight or branched structure, have the condenses of the fatty alcohol of 8 to 22 carbon atoms, such as coconut alcohol ethylene oxide condensate with every mole of coconut alcohol 2 to 15 moles of ethylene oxide with oxyethane.
-its alkyl contains the condenses of 6 to 12 alkylphenols that carbon is former with every mole of alkylphenol 2 to 25 moles of ethylene oxide;
The reaction product of-quadrol and propylene oxide is with the condenses of oxyethane, and this condenses contains the vinyloxy group of 40-80 weight %, and 5000 to 11,000 molecular weight is arranged.
The nonionogenic tenside of other kind is:
-general structure is the tertiary amino oxides of RRRNO, aliphatic group that R is 8 to 18 carbon atoms here, and each then is the alkyl or the hydroxyalkyl of 1 to 3 carbon atom, for example dimethyl dodecyl amine oxide for other R;
-structure is the phosphine oxides of RRRPO, and here, a R is the aliphatic group of 8 to 18 carbon atoms, and each then is the alkyl or the hydroxyalkyl of 1 to 3 carbon atom, for example dimethyl dodecyl phosphine oxide for other R;
-structure is the dialkyl sulphoxide of RRSO, alkyl that R is a 10-18 carbon atom here, and another R then is methyl or ethyl, for example methyl tetradecyl sulfoxide;
-fatty acid alkyl alcohol amide;
The alkylene oxide condensate of-Fatty Alcohol(C12-C14 and C12-C18) alkylol amide;
-alkyl sulfhydryl.
Fatty alcohol ethylene oxide condensate and amine oxide are the particularly suitable compositions of suspension system.Amine oxide also is suitable as lathering surfactant.
Other well-known suspension system comprises one or more polymer viscosifiers.Polymkeric substance in this system can be natural or synthetic.Suitable polymers often is an anionic type.They can emulsoid and solid form acquisition.In addition, they also can be hydrophobic modified and/or crosslinked in addition.Such polymkeric substance comprises polycarboxylate type polymkeric substance, such as carboxymethyl cellulose, Natvosol, Vltra tears, carrageenin, alginate, tragacanth gum, Viscogum BE, guar gum etc.This polymkeric substance will easily be dissolved in the cold water and retrogradation and not luming.
The examples of polymers that is fit to comprises:
ACUSDL HASE and ASE series product are such as 820,823 and 842;
The POLYGEL/NEUTRAGEL series product are such as W30, DA, DS, DR and DB;
RHEOVIS series product such as CRX;
The CARBOPOL series product are such as Aqua30, ETD2690, ETD2691, ETD2623, EZ-1, EZ-2, EP-1, LNP-3,663,664 and 674;
PEMULEN series product such as TR1 and TR2;
STRUCTURE 2001、3001；
ALCOGUM SL-70 and SL-78.
ACUSOL is Rohm ﹠amp; The trade mark of Haas company;
CARBOPOL and PEMULEN are the trade marks of B F Goodrich company;
POLYGEL and NEUTRAGEL are the trade marks of Sigma 3V Inc.;
RHEOVIS is the trade mark of the extraordinary Products Co., Ltd of Ciba;
STRUCTURE is the trade mark of national starch and chemical company;
ALCOGUM is the trade mark of Alco company.
In dry grinding feed composition according to the present invention, polymer suspension system consumption will be selected like this, so that the viscosity of the suspension that obtains when waiting water gaging dilution is within the scope of above defined.This consumption is at least 0.1%, and generally will be no more than 10%.
Also can use the tensio-active agent and the polymer suspension system of combination.Particularly, by in the dry grinding feed composition, adding a small amount of thickening polymer in addition, can further improve stability based on a kind of suspension of tensio-active agent.
If be not to have had lathering surfactant in a kind of tensio-active agent suspension system, then can from known foaming negatively charged ion, nonionic, positively charged ion, zwitter-ion or amphoterics, choose it wantonly, they do not have injurious effects to this suspension system.
The pH of ready-to-use liquid abrasive material detergent preferably should be between 5 and 14.When the pH of detergent was alkalescence, clean performance just improved, be preferably to be higher than 9, and more preferably for being lower than 12.If desired, the dry grinding feed composition should contain another pH regulator system, such as a kind of suitable alkali, so that the pH of liquid detergent is in desirable scope.Suitable alkali is such as alkali metal hydroxide or carbonate, volatile salt, organic bases, such as triethylamine, amino methyl propyl alcohol (AMP), amino butanol, list, two or trolamine, monoisopropylamine or amino methyl propanediol.
Dry grinding feed composition according to the present invention can contain the optional member that improves its performance.Its example is a solid bleaching, especially goes up halogen bleaching agent.Under one situation of back, other composition of dry composition, particularly its tensio-active agent and suspension system obviously should be bleach stables.Other example is an organic solvent, such as hydrocarbon and terpene, alkanolamine, (gathering) ethylene glycol and (gathering) propylene glycol with and C
1-C
6Alkyl or phenyl ether.Such solvent load should not hinder the free-flowing character of dry composition, generally is to be lower than 6% therefore.
In addition, it is well-known other optional member that this dry composition can contain for the liquid abrasive material detergent in this area, such as:
For increasing its magnetism to the human consumer, as colorant, brightening agent and so on, and spices especially;
For preventing the speck pollution or giving its product with anti-anti-microbiological property, for example sanitas and sterilant;
Use character for improving it, for example: prevent free-flow agents (the layering agent of dry composition caking,＜10%) (the Alusil ET that example: J.Crosfield sells, a kind of porous pure aluminium silicate, Socal P2V with the Solvay sale), make dry composition easier dispersion and/or give dispersion agent (example: molecular weight＜100 with the freeze-thaw-stable property of the suspension that obtains in water, the oil that 000 anionic polymer, science are handled and/or the phosphoric acid salt or the phosphonic acid ester of other organic or inorganic), prevent the antifoams (example: lipid acid) of excess foam formation.Free-flow agents and dispersion agent are especially preferred other compositions.
Can have according to dry composition of the present invention to be suitable for dispersive Any shape in water easily, such as powder, particle, bead or even small pieces.Powder, particle and bead preferably should be free-pouring.Spraying drying as known in the art, fluidised bed drying, granulation and similarly method all be very suitable for obtaining these products, they are unrestricted flow and disperse easily and do not lump.For granulation, then adding a kind of auxiliary agent of granulating is that perhaps the polyoxyethylene glycol of 1500-4000 is useful such as molecular weight.
By being pushed, the above-mentioned product of a predetermined amount can make small pieces.They can contain the division auxiliary agent, to improve the dispersion in water.Such division auxiliary agent is well-known in laundry and dishwasher stain remover sheet field.
At any time available liquid abrasive material detergent dry composition thus adds an amount of water and obtains.Usually the consumption of water should make this product liquid contain the solid abrasive between 10% and 65%, is preferably 10%-60%, more preferably be 15-50%, and this liquid has viscosities il
21Being 0.4-3.0Passec, being preferably 0.8-2.5Passec, more preferably is 1.0-2.0Passec.
Preferred compositions
The preferred dry composition that contains based on a kind of suspension system of tensio-active agent will have following composition usually:
| Preferably | Preferred | Composition |
| 65-95％ | 70-90％ | The powder abrasive material |
| 1.5-10％ | 2.0-8.0％ | Anion sulfate or sulfosalt surfactant |
| 1.5-7.0％ | 2.0-6.0％ | The ethoxy alcohol nonionogenic tenside |
| 1.0-10％ | 1.5-8.0％ | The alkaline pH conditioning agent preferably includes a kind of alkaline carbonate or supercarbonate |
| 0-2.0％ | 0.1-1.5％ | Lipid acid |
The preferred dry composition that contains based on a kind of suspension system of polymer viscosifier generally will have following composition:
| Preferably | Preferred | Composition |
| 85-99％ | 90-98％ | The powder abrasive material |
| 0.1-2.0％ | 0.15-1.0％ | Negatively charged ion or nonionic lathering surfactant, preferably amine oxide |
| 0.1-2.0％ | 0.15-1.0％ | The anionic thickening polymer agent |
| 0.2-5.0％ | 0.5-4％ | The alkaline pH conditioning agent is preferably alkali metal hydroxide and/or alkanolamine |
| Add to 100% | Water |
Embodiment
Embodiment 1
Prepare a kind of solid abrasive composition that contains based on a kind of suspension system of tensio-active agent, it is composed as follows:
Linear alkyl benzene sulphonic acid 5.97
Lialet 111-5.5 1) 3.13
Omyacarb 30AV 2) 79.57
Yellow soda ash 7.22
Prifac 7901 3) 0.90
Acusol 823 4) 0.036
Spices 0.72
Proxel GXL 5) 0.028
Socal P2V 6) 1.00
Alusil 7) 0.75
Water 0.67
1) the ethoxy alcohol nonionogenic tenside of Condea chimica DAC sale
2) calcite of Omya sale it is said that the average grain granularity is 30 microns
3) fatty acid mixt of UniQema sale
4) Rohm ﹠amp; The polyacrylic ester that Haas sells
5) sanitas of Zeneca Biocides supply
6)
7) pure aluminium silicate of J Crosfield sale
At RotoJunior 10L type super mixer/granulator (Italian Zenchetta ﹠amp; C.S.r.1. company) in the groove, make Omyacarb and yellow soda ash be heated to about 50 ℃ linear alkyl benzene sulphonic acid, and it is scattered in this solid mixture.In case after scattering, just nonionic/lipid acid/polymkeric substance/a small amount of mixture of ingredients (except free-flow agents and the spices) is added in the groove.Carry out lentamente when the adding of linear alkyl benzene sulphonic acid and nonionic mixture will be rotated (300rpm) at stirrer, add the required time and be about 2 minutes.
Finish when adding this liquid, the stirrer of RotoJunior, knife mill (1400rpm) remain in operation, and continue reheat (65 ℃) 10 minutes.Afterwards, turn off stirrer and knife mill, and make its product cooling with water cooling RotoJunior.Start stirrer again every 5 minutes and mix several seconds.Then free-flow agents is added (Socal U2) and discharging.Use spray gun and keg to add spices outside then.
Embodiment 2
Prepare a kind of solid abrasive composition that contains based on a kind of suspension system of polymer viscosifier, it is composed as follows:
Calcite 95
(arbopol ETD 2623 1) 0.36
(C16-18) alkyl dimethyl amine oxide 0.42
AMP (amino methyl propyl alcohol) 0.38
NaOH 1.00
Spices 0.84
Water etc. reach 100%
1) polyacrylic ester of BF Goodrich sale
Mixture operation carries out with the Kenwood Chef mixing tank that uses " K " shape to connect, and its step is as follows:
1. calcite is added in the tempering tank.
2. add polymer powder and mixed about 5 minutes, for avoiding any loss of powder, mixing velocity fixes on and is low to moderate middling speed.Remaining composition is a liquid, adds by means of dropper.
3. when mixing, add the AMP that is scattered in advance in about 1% water.
4. add NaOH (10% solution), mixed about 5 minutes.
5. adding amine oxide.
6. adding spices; Mixed about 20 minutes, until forming a kind of gratifying homogeneous mixture.
Claims (7)
1. one kind is suitable for mixing to obtain the dried solids composition of the clean composition of stabilising liq abrasive material with water, and it comprises solid water-insoluble abrasive material, it is characterized in that said composition comprises:
I. at least 65% solid abrasive;
Ii. at least 0.1% suspension system is selected from:
A) one or more can form the tensio-active agent of stratiform micellar phase when mixing with water, or
B) one or more polymer viscosifiers,
Or its composition;
Iii. at least 0.1% foaming surfactant;
Iv. a free-flow agents and/or a kind of dispersion agent.
2. according to the dried solids composition of claim 1, it is characterized in that this dry composition with wait water gaging to mix after, resulting suspension has following flow characteristics:
η
0Be 2500Pas at least
σ
cBe 2.5-25
η
21Be 0.1Pas at least.
3. according to the dried solids composition of claim 1, it is characterized in that the consumption of its abrasive material is at least 70%.
4. according to the dried solids composition of claim 3, the consumption that it is characterized in that abrasive material is 85-99%, and the consumption of foaming surfactant is 0.1-2%, and suspension system comprises the anionic thickening polymer agent that consumption is 0.1-2.0%.
5. according to the dried solids composition of claim 3, the consumption that it is characterized in that abrasive material is 70-95%, and suspension system comprises the ethoxylated alcohol nonionic surfactant of anion sulfate or sulfosalt surfactant and the 1.5-7% of 1.5-10%.
6. according to each the dried solids composition of claim 1-5, it is characterized in that described composition handles already making it unrestricted flow and to disperse easily, described treatment process is selected from spraying drying, fluidised bed drying and granulation.
7. one kind prepares the clean method for compositions of available at any time liquid abrasive material, comprise that each the composition that makes claim 1-6 mixes with a kind of liquid medium, this liquid medium contains consumption and is at least 85% water, so that the liquid abrasive material is cleaned the η that composition contains the solid abrasive of 10-60% and has 0.4-3.0Pas
21
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00302869.3 | 2000-04-05 | ||
| EP00302869 | 2000-04-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1422328A CN1422328A (en) | 2003-06-04 |
| CN1218026C true CN1218026C (en) | 2005-09-07 |
Family
ID=8172888
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN01807818.4A Expired - Fee Related CN1218026C (en) | 2000-04-05 | 2001-03-09 | Solid dispersible abrasive compositions |
Country Status (10)
| Country | Link |
|---|---|
| CN (1) | CN1218026C (en) |
| AR (1) | AR027766A1 (en) |
| AU (1) | AU2001262090A1 (en) |
| BR (1) | BR0109752A (en) |
| HU (1) | HUP0300292A3 (en) |
| MX (1) | MXPA02009578A (en) |
| PL (1) | PL357997A1 (en) |
| RU (1) | RU2256699C2 (en) |
| WO (1) | WO2001077273A1 (en) |
| ZA (1) | ZA200206780B (en) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2434586A (en) * | 2006-01-24 | 2007-08-01 | Henkel Uk | Structured liquid abrasive composition |
| PT2281853E (en) * | 2009-08-05 | 2012-07-23 | Omya Development Ag | Use of 2-amino-2-methyl-1-propanol as additive in aqueous suspensions of calcium carbonate comprising materials |
| SI2392622T1 (en) * | 2010-06-07 | 2013-07-31 | Omya Development Ag | Use of 2-aminoethanol as additive in aqueous suspensions of calcium carbonate comprising materials |
| PT2402167E (en) | 2010-07-02 | 2013-12-11 | Omya Int Ag | Paper for inkjet recording |
| DE102012217139A1 (en) * | 2012-09-24 | 2014-03-27 | Henkel Ag & Co. Kgaa | Pasty hand dishwashing detergent |
| US9688948B2 (en) | 2012-09-25 | 2017-06-27 | Conopco, Inc. | Laundry detergent particles |
| WO2016096328A1 (en) | 2014-12-18 | 2016-06-23 | Unilever N.V. | Powder composition for hard surface cleaning |
| RU2601303C1 (en) * | 2015-08-25 | 2016-11-10 | федеральное государственное бюджетное образовательное учреждение высшего образования "Пермский национальный исследовательский политехнический университет" | Cleaning powder |
| SI3561002T1 (en) * | 2018-04-23 | 2021-01-29 | Omya International Ag | Use of additives containing primary alkanolamines in aqueous mineral suspensions |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1339274A (en) * | 1970-11-18 | 1973-11-28 | Unilever Ltd | Cleaning composition |
| US4581042A (en) * | 1984-06-22 | 1986-04-08 | Pro-Strength, Inc. | Composition for removing hard-water build-up |
| CA2144065C (en) * | 1992-09-09 | 2003-11-11 | Alexander Allan | Improvements to hard surface cleaners |
| GB9708500D0 (en) * | 1997-04-25 | 1997-06-18 | Unilever Plc | Abrasive cleaning composition |
-
2001
- 2001-03-09 MX MXPA02009578A patent/MXPA02009578A/en not_active Application Discontinuation
- 2001-03-09 CN CN01807818.4A patent/CN1218026C/en not_active Expired - Fee Related
- 2001-03-09 AU AU2001262090A patent/AU2001262090A1/en not_active Abandoned
- 2001-03-09 HU HU0300292A patent/HUP0300292A3/en not_active Application Discontinuation
- 2001-03-09 BR BR0109752-0A patent/BR0109752A/en not_active IP Right Cessation
- 2001-03-09 PL PL01357997A patent/PL357997A1/en not_active Application Discontinuation
- 2001-03-09 RU RU2002129360/04A patent/RU2256699C2/en not_active IP Right Cessation
- 2001-03-09 WO PCT/EP2001/002763 patent/WO2001077273A1/en active Application Filing
- 2001-04-04 AR ARP010101592A patent/AR027766A1/en unknown
-
2002
- 2002-08-23 ZA ZA200206780A patent/ZA200206780B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| HUP0300292A3 (en) | 2006-07-28 |
| RU2002129360A (en) | 2004-03-27 |
| CN1422328A (en) | 2003-06-04 |
| AR027766A1 (en) | 2003-04-09 |
| HUP0300292A2 (en) | 2003-06-28 |
| PL357997A1 (en) | 2004-08-09 |
| AU2001262090A1 (en) | 2001-10-23 |
| RU2256699C2 (en) | 2005-07-20 |
| BR0109752A (en) | 2003-02-04 |
| ZA200206780B (en) | 2003-10-29 |
| MXPA02009578A (en) | 2003-03-10 |
| WO2001077273A1 (en) | 2001-10-18 |
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