CN1218021C - Gasoline hydrogenation catalyst, its prep. and application in lowering olefin by desulfurization - Google Patents
Gasoline hydrogenation catalyst, its prep. and application in lowering olefin by desulfurization Download PDFInfo
- Publication number
- CN1218021C CN1218021C CN 02116267 CN02116267A CN1218021C CN 1218021 C CN1218021 C CN 1218021C CN 02116267 CN02116267 CN 02116267 CN 02116267 A CN02116267 A CN 02116267A CN 1218021 C CN1218021 C CN 1218021C
- Authority
- CN
- China
- Prior art keywords
- tio
- catalyst
- gasoline
- sio
- catalyzer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 39
- 238000005984 hydrogenation reaction Methods 0.000 title claims abstract description 23
- 150000001336 alkenes Chemical class 0.000 title abstract description 19
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract description 6
- 238000006477 desulfuration reaction Methods 0.000 title description 15
- 230000023556 desulfurization Effects 0.000 title description 13
- 239000011230 binding agent Substances 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims abstract description 5
- 239000000969 carrier Substances 0.000 claims abstract description 3
- 239000000843 powder Substances 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 22
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 17
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 16
- 239000004480 active ingredient Substances 0.000 claims description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 7
- 238000007598 dipping method Methods 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 230000003009 desulfurizing effect Effects 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 239000010937 tungsten Substances 0.000 claims description 2
- 238000005303 weighing Methods 0.000 claims description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 abstract description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 8
- 239000007788 liquid Substances 0.000 abstract description 8
- 229910044991 metal oxide Inorganic materials 0.000 abstract description 8
- 150000004706 metal oxides Chemical class 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 5
- 229910052717 sulfur Inorganic materials 0.000 abstract description 5
- 239000011593 sulfur Substances 0.000 abstract description 5
- 238000004073 vulcanization Methods 0.000 abstract 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 15
- 238000001035 drying Methods 0.000 description 14
- 238000004523 catalytic cracking Methods 0.000 description 13
- 206010013786 Dry skin Diseases 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 12
- 239000003292 glue Substances 0.000 description 12
- 239000004215 Carbon black (E152) Substances 0.000 description 9
- 229930195733 hydrocarbon Natural products 0.000 description 9
- 239000003921 oil Substances 0.000 description 9
- 229910017313 Mo—Co Inorganic materials 0.000 description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 8
- 150000002430 hydrocarbons Chemical class 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 239000010936 titanium Substances 0.000 description 8
- 229910052719 titanium Inorganic materials 0.000 description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 7
- 241000219793 Trifolium Species 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- 239000004411 aluminium Substances 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 238000005470 impregnation Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000004408 titanium dioxide Substances 0.000 description 5
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 238000004517 catalytic hydrocracking Methods 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910017318 Mo—Ni Inorganic materials 0.000 description 2
- 229910017709 Ni Co Inorganic materials 0.000 description 2
- 229910003267 Ni-Co Inorganic materials 0.000 description 2
- 229910003262 Ni‐Co Inorganic materials 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 238000004939 coking Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000003974 emollient agent Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000006317 isomerization reaction Methods 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- 229910003296 Ni-Mo Inorganic materials 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- UGACIEPFGXRWCH-UHFFFAOYSA-N [Si].[Ti] Chemical compound [Si].[Ti] UGACIEPFGXRWCH-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000019241 carbon black Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- -1 olefin hydrocarbon Chemical class 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 238000007363 ring formation reaction Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- PMTRSEDNJGMXLN-UHFFFAOYSA-N titanium zirconium Chemical compound [Ti].[Zr] PMTRSEDNJGMXLN-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Images
Landscapes
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Abstract
Description
Catalyzer | A1 | B1 | C1 | D1 | E1 | F1 |
Carrier | A | B | C | D | E | F |
Pore volume, ml/g | 0.38 | 0.38 | 0.38 | 0.36 | 0.43 | 0.42 |
Specific surface, m 2/g | 175 | 160 | 155 | 210 | 232 | 202 |
Intensity, N/ | 88 | 98 | 86 | 120 | 135 | 118 |
MoO 3,w% | 3.2 | 4.1 | 4.1 | 5.1 | 7.5 | 15.3 |
CoO,w% | 1.3 | 1.6 | 1.6 | 2.0 | 3.0 | 4.2 |
Density, g/ml | 0.7325 | Total sulfur, ppm | 1590 |
Total nitrogen, | 30 | Alkene, v% | 45.8 |
The bromine valency, gBr/100g | 84 | Aromatic hydrocarbons, v% | 23.0 |
Research octane number (RON) (RON) | 91.9 | Motor-method octane number (MON) | 79.1 |
Boiling range, ℃ | IBP 10% 30% 50% 70% 90% EP 28 49 77 110 145 179 210 |
Reaction pressure, Mpa | 1.6 | Temperature of reaction, | 290 |
Liquid air speed, h -1 | 4 | Hydrogen-oil ratio, v/v | 200 |
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 02116267 CN1218021C (en) | 2002-03-28 | 2002-03-28 | Gasoline hydrogenation catalyst, its prep. and application in lowering olefin by desulfurization |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 02116267 CN1218021C (en) | 2002-03-28 | 2002-03-28 | Gasoline hydrogenation catalyst, its prep. and application in lowering olefin by desulfurization |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1448471A CN1448471A (en) | 2003-10-15 |
CN1218021C true CN1218021C (en) | 2005-09-07 |
Family
ID=28680661
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 02116267 Expired - Fee Related CN1218021C (en) | 2002-03-28 | 2002-03-28 | Gasoline hydrogenation catalyst, its prep. and application in lowering olefin by desulfurization |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1218021C (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100345943C (en) * | 2004-10-29 | 2007-10-31 | 中国石油化工股份有限公司 | Process for hydrodesulphurization and olefin reduction of gasoline |
CN103131467B (en) * | 2011-12-01 | 2015-11-25 | 北京海顺德钛催化剂有限公司 | A kind of processing method of selectively hydrogenating and desulfurizing inferior gasoline and device |
CN104338565B (en) * | 2013-08-09 | 2016-08-10 | 中国石油天然气股份有限公司 | Method for presulfurizing catalytic gasoline hydrogenation catalyst |
CN106622358A (en) * | 2016-09-30 | 2017-05-10 | 过冬 | Composite support hydrodesulfurization catalyst |
CN114433118B (en) * | 2020-10-30 | 2023-06-02 | 中国科学院宁波材料技术与工程研究所 | Ebullated bed hydrogenation catalyst and method for processing coal tar full fraction |
CN114433119B (en) * | 2020-10-30 | 2023-06-02 | 中国科学院宁波材料技术与工程研究所 | Heavy aromatic oil hydrofining catalyst and method for producing BTX from heavy aromatic oil |
-
2002
- 2002-03-28 CN CN 02116267 patent/CN1218021C/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN1448471A (en) | 2003-10-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1021738C (en) | Hydrocarbon conversion catalysts | |
CN100531909C (en) | ZSM-5/SAPO-11 composite zeolite and catalytically cracked gasoline hydrogenation quality-improved catalyzer and the method for preparing the same | |
CN1036280C (en) | Hydrocarban coversion catalysts | |
EP2412785A1 (en) | Method for producing aromatic hydrocarbons | |
US10696910B2 (en) | Systems and methods for processing heavy oils by oil upgrading followed by distillation | |
CN1054150C (en) | Catalyst for hydrocracking diesel oil | |
CN1049679C (en) | Catalyst for hydrogenation conversion of diesel | |
CN109718867B (en) | Hydrofining catalyst system and application thereof, preparation method of hydrofining catalyst and hydrofining method of distillate oil | |
CN1218021C (en) | Gasoline hydrogenation catalyst, its prep. and application in lowering olefin by desulfurization | |
CN1769388A (en) | Hydrogenation and quality improvement method for reducing sulfur and olefin content of inferior gasoline | |
CZ2001582A3 (en) | Method for enhancing properties of a hydrocarbon mixture and catalyst for such process | |
RU2468864C1 (en) | Catalyst, method of its preparation and method of hydrorefining diesel distillates | |
CN103146420B (en) | Gasoline hydrotreating method | |
CN1124331C (en) | Hydrofining catalyst and preparation method thereof | |
CN1094967C (en) | Gasoline fraction hydrogenating and modifying method | |
CN1173010C (en) | Method and Catalyst for Selective Hydrofining of Cracked Gasoline | |
EP4141088A1 (en) | Method of producing lubricating base oil from atmospheric residue in pyrolysis oil derived from waste plastic | |
CN101440306A (en) | Hydro-upgrading method for FCC gasoline | |
CN1094968C (en) | Gasoline fraction hydrogenating and modifying catalyst containing zeolite | |
CN112619696B (en) | Composite bed hydrocracking catalyst system and preparation method and application thereof | |
CN1407066A (en) | Hydrogenation of distilled oil | |
CN102614889A (en) | Hydrotreatment catalyst and application thereof | |
CN1246519A (en) | Method for producing high cetane value and low sulfur content diesel oil | |
CN108421560B (en) | Hydrogenation modification catalyst, preparation method and application thereof, and method for producing monocyclic aromatic hydrocarbon | |
CN1966620A (en) | Catalytic dewaxing catalyst |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Gasoline hydrogenation catalyst, its prep. and application in lowering olefin by desulfurization Effective date of registration: 20150821 Granted publication date: 20050907 Pledgee: Beijing technology business factoring Ltd. Pledgor: Beijing Haishunde Titanium Catalyst Co., Ltd. Registration number: 2015990000703 |
|
PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20171108 Granted publication date: 20050907 Pledgee: Beijing technology business factoring Ltd. Pledgor: Beijing Haishunde Titanium Catalyst Co., Ltd. Registration number: 2015990000703 |
|
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20050907 Termination date: 20200328 |