CN1216109C - Water-repellent breathable nano coating for outer wall - Google Patents
Water-repellent breathable nano coating for outer wall Download PDFInfo
- Publication number
- CN1216109C CN1216109C CN 01127384 CN01127384A CN1216109C CN 1216109 C CN1216109 C CN 1216109C CN 01127384 CN01127384 CN 01127384 CN 01127384 A CN01127384 A CN 01127384A CN 1216109 C CN1216109 C CN 1216109C
- Authority
- CN
- China
- Prior art keywords
- parts
- nano
- product
- obtains
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000005871 repellent Substances 0.000 title abstract 2
- 239000002103 nanocoating Substances 0.000 title 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000002086 nanomaterial Substances 0.000 claims abstract description 15
- 239000000839 emulsion Substances 0.000 claims abstract description 12
- 239000002131 composite material Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000002270 dispersing agent Substances 0.000 claims abstract description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000010456 wollastonite Substances 0.000 claims abstract description 5
- 229910052882 wollastonite Inorganic materials 0.000 claims abstract description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 13
- 239000003973 paint Substances 0.000 claims description 11
- 230000002209 hydrophobic effect Effects 0.000 claims description 9
- 239000013530 defoamer Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 5
- -1 acrylic ester Chemical class 0.000 claims description 5
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims description 5
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 5
- 238000004581 coalescence Methods 0.000 claims description 5
- 239000003112 inhibitor Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 125000005375 organosiloxane group Chemical group 0.000 claims description 5
- 230000008719 thickening Effects 0.000 claims description 5
- 238000009736 wetting Methods 0.000 claims description 5
- 241000276489 Merlangius merlangus Species 0.000 claims description 4
- 239000005543 nano-size silicon particle Substances 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- 229940043430 calcium compound Drugs 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 235000014347 soups Nutrition 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- 238000001132 ultrasonic dispersion Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 abstract description 12
- 238000000576 coating method Methods 0.000 abstract description 12
- 238000002360 preparation method Methods 0.000 abstract description 7
- 230000032683 aging Effects 0.000 abstract description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 238000005054 agglomeration Methods 0.000 abstract 1
- 230000002776 aggregation Effects 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 230000035699 permeability Effects 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 235000010215 titanium dioxide Nutrition 0.000 description 3
- 230000000295 complement effect Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- 241001417490 Sillaginidae Species 0.000 description 1
- 238000005703 Whiting synthesis reaction Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 235000001968 nicotinic acid Nutrition 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention provides a nano exterior wall coating with strong water-repellent and air-permeable capacity and a preparation method thereof, wherein the nano exterior wall coating comprises, by mass, 10-25 parts of pure water, 2-4 parts of ethylene glycol, 8-10 parts of heavy calcium carbonate, 3-6 parts of aluminum silicate, 3-6 parts of talcum powder, 6-12 parts of wollastonite, 9-30 parts of acrylate emulsion, 5-20 parts of organic siloxane emulsion, 0.5-3 parts of composite nano material, a dispersing agent, an antifoaming agent, a film-forming aid, a thickening agent, a flatting agent and the like. The preparation method mainly overcomes the agglomeration of the nano material, enhances the dispersion effect and gives full play to the properties of the nano material, and the coating has the advantages of stronger water repellency and air permeability, capability of absorbing ultraviolet rays, high adhesive force, stain resistance and aging resistance and better comprehensive performance.
Description
Technical field
The present invention relates to a kind of building coating and preparation method thereof, particularly a kind of exterior wall nano paint and preparation method with hydrophobic permeable function.
Background technology
Traditional building coating because contain toxic substance or easily stain, easily go mouldy, adhesion strength and ageing resistance be relatively poor, incompatibility is in the world to requirement on environmental protection.In recent years, the coating material to superior performance has carried out extensive studies and exploration both at home and abroad, and wherein nano paint is an important research direction.China is owing to the theoretical investigation of nanotechnology is taken its place in the front ranks of the world, its applied research, comprise nano paint, many gratifying achievements have also been obtained, as Chinese patent CN1287144A, CN1287145A provide contain nano silicon-based oxide in, exterior coating and preparation method, Chinese patent CN1277234A provides a kind of oxygen debt silicon-base oxide has been inserted existing coating to improve the method for performance, but in general, the development of nano paint also is in initial stage, and performance index can't be satisfied the demand, with regard to exterior coating, the hydrophobic permeable ability is not high, and over-all properties is not good enough.Therefore, no matter be composition proportion or technology, all await further optimizing and improving.
Summary of the invention
The purpose of this invention is to provide a kind of exterior wall nano paint with strong hydrophobic permeable ability.
Another object of the present invention provides the method that a kind of preparation has the exterior wall nano paint of aforementioned capabilities.
The objective of the invention is to be achieved through the following technical solutions: a kind of exterior wall nano paint with hydrophobic permeable ability, its essentially consist comprises following composition, its mass component:
(1) pure water 10-25
(2) ethylene glycol 2-4
(3) wetting dispersing agent 0.6-2
(4) defoamer 0.1-0.3
(5) mould inhibitor 0.1-0.25
(6) titanium dioxide 12-25
(7) coarse whiting 8-10
(8) wollastonite 6-12
(9) talcum powder 3-6
(10) pure aluminium silicate 3-6
(11) film coalescence aid 0.5-1.5
(12) organo-siloxane emulsion 5-20
(13) acrylic ester emulsion 9-30
(14) composite nano materials 0.5-2.5
(15) thickening material 0.3-1
(16) flow agent 0.1-0.5
Another object of the present invention is achieved through the following technical solutions: a kind of preparation has the method for the nano paint of hydrophobic permeable ability, may further comprise the steps:
A. the pure water in the mentioned component, ethylene glycol, wetting dispersing agent, defoamer, mould inhibitor, titanium dioxide, coarse whiting, wollastonite, talcum powder, pure aluminium silicate are put into rotating speed and be in 1500-2000 rev/min the high speed dispersor, jitter time is 40-60 minute;
B. will grind by shredder through the product that steps A obtains, survey fineness;
C. the product that will obtain after will grinding adds stirrer, under 200-400 rev/min stirring velocity, slowly add film coalescence aid, organo-siloxane emulsion, acrylic ester emulsion, composite nano materials, thickening material, flow agent in the mentioned component, mix;
D. will sieve through the product that step C obtains, get product.
Said composite nano materials is nano silicon, nano titanium oxide and nano-calcium carbonate calcium compounds and coats the soup compound obtain at water through ultra-sonic dispersion and surface in the technique scheme, and the particle diameter of nano material is the 30-60 nanometer.
In the technique scheme, owing to contain composite nano materials in its component, it and rational filmogen are complementary, formed the concavo-convex alternate complementary interface structure of nano level, adsorbable gas molecule stable existence, being equivalent to the surface on the macroscopic view has the stable gas membrane of one deck, makes the You Heshui can't be in surface attachment, present extraordinary two thin property, and the moisture of matrix still can be by the microtexture volatilization of filming.The characteristics of lotus leaf are thought similarly in this performance and the plant, can regard the embodiment of bionics in building coating as.
Coating with hydrophobic permeable ability provided by the present invention has the following advantages: owing to have ultraviolet radiation absorption function and stronger hydrophobic permeable ability, thereby higher contamination resistance, stronger sticking power and ageing resistance are arranged, over-all properties is better, be the very superior new coating of a kind of ratio of performance to price, be specially adapted to Highrise buildings and environmental pollution serious area.
Embodiment
One embodiment of the present of invention are:
With 19.2 parts of (mass parts, water down together), 3 parts of ethylene glycol, 1.4 the wetting dispersing agent of part, 0.15 the defoamer of part, 0.2 the mould inhibitor of part, 20 parts of rutile titanium dioxides, 10 parts of coarse whitings, 8 parts of wollastonites, 4 parts of talcum powder, it is 2000 rev/mins high speed dispersor that 6 parts of pure aluminium silicate are put into rotating speed, jitter time is 40 minutes, then product is put into shredder, mesh-of-grind is 50 μ m, product after grinding is put into stirrer, under 300 rev/mins mixing speed, slowly add 12 parts of organo-siloxane emulsions, 9.5 part acrylic ester emulsion, 2.45 part composite nano materials colloid, 1 part of film coalescence aid, 0.15 part defoamer, 0.5 part thickening material and 0.2 part of flow agent, after mixing, cross 120 mesh sieves at last, promptly obtain finished product.
The composite nano materials that present embodiment uses is that nano silicon, nano titanium oxide and nano-calcium carbonate calcium compounds coat the soup compound that obtains at water through ultra-sonic dispersion and surface, and the particle diameter of nano material is the 30-60 nanometer.
Claims (2)
1, a kind of hydrophobic permeable exterior wall nano paint is characterized in that essentially consist comprises following composition, and its mass component is:
(1) pure water 10-25
(2) ethylene glycol 2-4
(3) wetting dispersing agent 0.6-2
(4) defoamer 0.1-0.3
(5) mould inhibitor 0.1-0.25
(6) titanium dioxide 12-25
(7) coarse whiting 8-10
(8) wollastonite 6-12
(9) talcum powder 3-6
(10) pure aluminium silicate 3-6
(11) film coalescence aid 0.5-1.5
(12) organo-siloxane emulsion 5-20
(13) acrylic ester emulsion 9-30
(14) composite nano materials 0.5-2.5
(15) thickening material 0.3-1
(16) flow agent 0.1-0.5
Composite nano materials recited above is that nano silicon, nano titanium oxide and nano-calcium carbonate calcium compounds coat the soup compound that obtains at water through ultra-sonic dispersion and surface, and the particle diameter of nano material is the 30-60 nanometer.
2, a kind of described method with nano paint of hydrophobic permeable ability of claim 1 for preparing is characterized in that may further comprise the steps;
It is that jitter time is 40-60 minute in 1500-2000 rev/min the high speed dispersor that A, the pure water with in the mentioned component, ethylene glycol, wetting dispersing agent, defoamer, mould inhibitor, titanium dioxide, coarse whiting, wollastonite, talcum powder, pure aluminium silicate are put rotating speed into;
B, will grind by shredder, survey fineness through the product that steps A obtains;
C, the product that obtains after will grinding add stirrer, under 200-400 rev/min stirring velocity, slowly add film coalescence aid, organo-siloxane emulsion, acrylic ester emulsion, composite nano materials, thickening material, flow agent in the mentioned component, mix;
D, will sieve, get product through the product that step C obtains.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01127384 CN1216109C (en) | 2001-09-04 | 2001-09-04 | Water-repellent breathable nano coating for outer wall |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01127384 CN1216109C (en) | 2001-09-04 | 2001-09-04 | Water-repellent breathable nano coating for outer wall |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1485383A CN1485383A (en) | 2004-03-31 |
| CN1216109C true CN1216109C (en) | 2005-08-24 |
Family
ID=34141393
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 01127384 Expired - Fee Related CN1216109C (en) | 2001-09-04 | 2001-09-04 | Water-repellent breathable nano coating for outer wall |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1216109C (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105482592A (en) * | 2015-12-29 | 2016-04-13 | 浙江名匠实业股份有限公司 | Water-based nano exterior wall coating with super weatherability and preparation method thereof |
| CN106752569A (en) * | 2016-12-01 | 2017-05-31 | 姚均甫 | A kind of exterior wall hydrophobic permeable adsorbs UV nano coating |
| CN107099208A (en) * | 2017-07-07 | 2017-08-29 | 佛山领新信息科技有限公司 | A kind of antifouling and easy cleaning interior wall coating and preparation method thereof |
| CN107459889A (en) * | 2017-09-21 | 2017-12-12 | 罗洪梅 | A kind of abrasion-resistance water can breathe building Nano waterproof paint and preparation method thereof |
| CN107573772B (en) * | 2017-09-21 | 2020-06-19 | 佛山市顺德区业基建筑材料有限公司 | Water-based antibacterial breathable building waterproof coating and preparation method thereof |
-
2001
- 2001-09-04 CN CN 01127384 patent/CN1216109C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1485383A (en) | 2004-03-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101307210B (en) | Ultra-discharging water-soluble fluor-silicon-acrylic coatings with nano particles | |
| CN1235992C (en) | Water high-weatherability nano external wall paint and its preparation method | |
| CN1354211A (en) | Water propyl fluorosilicate nano sol weatherability pollution-resisting coating material | |
| CN1245465C (en) | Weatherability self-cleaning external wall coating material and its preparation method | |
| CN1923913A (en) | Self-cleaning nona composite environment-friendly type emulsion paint and preparation method thereof | |
| CN106634078B (en) | A kind of nuclear case structure hybridization colloidal sol and its preparation and application with photocatalysis characteristic | |
| CN108822604A (en) | A kind of coating composition, automatically cleaning water nano coating and structural body | |
| CN1903961A (en) | Lotus leaf effect self cleaning fluorocarbon paint | |
| CN101517010A (en) | Photocatalytically active coating | |
| CN1392210A (en) | High weather resistant water-thinned wall paint and its preparing method | |
| CN1441015A (en) | Nano modified polymer-based roof waterproof paint and its production process | |
| CN107141936B (en) | A kind of super-hydrophobic stain resistant multicolor finish and preparation method thereof | |
| CN1850914A (en) | Method for producing high covering power titanium dioxide pigment | |
| CN110330839A (en) | Efficient non-sticky hydrophobic coating and preparation method thereof for timber, metal and frosting | |
| CN1216109C (en) | Water-repellent breathable nano coating for outer wall | |
| EP2271595A2 (en) | Finishing compound suitable for an acoustic support | |
| CN115960496A (en) | Weather-resistant corrosion-resistant metal fluorocarbon coating and preparation method thereof | |
| CN109535865A (en) | A kind of nano combined stone protectant and preparation method thereof | |
| CN111362641A (en) | Efficient environment-friendly antibacterial mildew-proof nano film-forming agent-containing coating and preparation method thereof | |
| CN106752260B (en) | Preparation method of nano hydrophobic calcium oxalate powder for stone cultural relic protection coating | |
| CN106007559A (en) | Environment-friendly diatom ooze decorative wall material | |
| CN1488688A (en) | Negative ion type internal-wall later paint for health-care building and preparing method thereof | |
| CN102964961B (en) | Nanometer-reflection thermal insulation coating and preparation method thereof | |
| CN1485382A (en) | Antibacterial purifying nano coating for interior wall | |
| CN109266148A (en) | A kind of energy conservation and environmental protection building coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |