CN1212180C - Granulating equipment for making molten liquid into spherical granule product - Google Patents

Granulating equipment for making molten liquid into spherical granule product Download PDF

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Publication number
CN1212180C
CN1212180C CN 03100011 CN03100011A CN1212180C CN 1212180 C CN1212180 C CN 1212180C CN 03100011 CN03100011 CN 03100011 CN 03100011 A CN03100011 A CN 03100011A CN 1212180 C CN1212180 C CN 1212180C
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China
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nozzle
distribution grid
tower body
fused solution
product
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Expired - Fee Related
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CN 03100011
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Chinese (zh)
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CN1515350A (en
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王亭杰
方九阳
奚元宙
魏飞
金涌
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Tsinghua University
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Tsinghua University
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Abstract

The present invention relates to a granulating device for making molten liquid into a spherical granule product, which belongs to the technical field of the shaping of molten liquid. The present invention is characterized in that when the density of the molten liquid is less than that of cooling liquid, the molten liquid comprises a molten liquid chamber for equalizing pressure, a distribution plate, a heat insulation plate, a tower body and a nozzle on-off component, wherein the distribution plate is positioned above the molten liquid comprises and is provided with a plurality of nozzles in the longitudinal direction; the heat insulation plate which is positioned above the distribution plate is provided with heat insulation holes which are correspondingly sheathed with the nozzles in the longitudinal direction, and is provided with heating medium channels alongside in the transverse direction; the tower body is connected with the heat insulation plate through a flange of the tower body and is communicated with the heat insulation holes; the nozzle on-off component is connected with the distribution plate. In addition, the nozzle on-off component penetrates through the lateral surface of the distribution plate in the transverse direction, and is a channel which can be controlled by a valve and can switch over cooling media and heating media. The nozzle on-off component can also be a mechanical switch which is arranged below the distribution plate. A cooling liquid inlet and a product discharge port are arranged above the tower body. When the density of the molten liquid is greater than that of the cooling liquid, the granulating device is provided with the molten liquid chamber, the distribution plate, the heat insulation plate, the tower body, a cooling liquid inlet distribution device and the product discharge device from top to bottom according to the installation sequence. The molten liquid downwards flows through a nozzle, and liquid drops downwards move in.

Description

Fused solution is made the prilling granulator of spheric granules product
Technical field
Fused solution is made the prilling granulator of spheric granules product, belong to the fused solution field shaping technique.
Background technology
The chemical products moulding is an important step in the Chemical Manufacture, numerous liquid chemical product needed are made the solid particle form, store, pack, transport and use with convenient, as organic products such as paraffin, sulphur, rosin, polymer, urea, and some intermediate states are the salt series products of fused solution, as salts such as chemical fertilizer, calcium chloride.The forming technique of fused solution has multiple, and concrete granulating raw material characteristic is depended in the design of its prilling process and selection, and different material has different prilling process, as oil cooling granulating technique, steel band granulating technique, tower granulation technology and other granulating technique etc.Now brief introductory section granulating technique related to the present invention.
The oil cooling granulating technique is that density is formed drop greater than the fused solution of cold oil density by nozzle, spread to cold oil from the top of cold oil liquid level, drop sedimentation in cold oil, cooling move heat, and drop solidifies the back discharges, remove cold oil by centrifugal method, realize the granulation of fused solution.This oil cooling granulating technique exists the granulation ability low, and the Granularity Distribution wide ranges is second-rate, the fine particle problems such as causing oil contamination that suspends in cold oil.
With paraffin is example, and background technology of the present invention is described.
The wax moulding technology has chain disc type piece was moulding technology and water-cooled steel band granulating technique at present.
Chain disc type piece was moulding technology comprises following basic processes, the paraffin fused solution is injected the stainless steel cake wax, cake wax enters the cold house by chain drive, move on parallel layer by layer, indoor liquefied ammonia evaporimeter and the air blast of being provided with is to keep cold house's temperature, the heat of liquid wax is shifted out by cold wind, liquid wax is cooled to wax stone gradually, through switching mechanism wax stone is come off, and obtaining every weight is the piece wax product of 5kg.This wax moulding technology is cooling medium with the air, is about 2 hours cool time, the energy consumption height, and production efficiency is low, and labour intensity is big, and the package unit complexity is huge, and mechanical moving element is many, and fault is frequent.
The basic process of the water-cooled steel band granulating technique of Sweden's Sandvik is via distributing rotary drum to form drop with the paraffin fused solution, be dropped in the steel band upper surface, the steel band lower surface is cooled off by spraying cooling water, the paraffin drop is cooled to solid grain wax, scrape the back by scraper plate and obtain hemispherical sheet grain wax, cooling water recycles.The long-time running meeting reduces the smoothness of steel strip surface, and paraffin adhesion steel band or grain wax are inter-adhesive on steel band.Because the cooling of liquid wax is to move heat indirectly through the steel band single face, and the paraffin thermal conductivity factor is low, therefore, it is low to move the thermal efficiency, needs very long steel band, and floor space is big, generally needs many Granulation Equipments to work simultaneously.
On " research of wax balling technique " (" petroleum refining and chemical industry " rolled up the 8th~12 page of the 8th phase in 1994 the 26th), reported a kind of technology, but do not reported concrete device with the balling-up of gunite realization wax.
Summary of the invention
The object of the present invention is to provide and a kind of fused solution is made the prilling granulator of spheric granules product, it can make the spherical particle that particle diameter is 1~10mm.
The invention is characterized in: when the density of fused solution during less than the density of cooling fluid, it contains the fusion liquid chamber of all pressing, be positioned at the flange top of above-mentioned fusion liquid chamber and the distribution grid of a plurality of nozzles vertically is housed, be positioned at above-mentioned distribution grid top and vertically have the corresponding a plurality of insulations hole that is nested and at the warming plate that laterally has the heat medium passage from the side with nozzle, through the tower body flange link to each other with warming plate and with it on the insulation above-mentioned tower body that communicates of hole and the nozzle break-make parts that link to each other with distribution grid, wherein, fusion liquid chamber flange, distribution grid, warming plate, the tower body flange closely connects by bolt, the tower body top is provided with the inlet of cooling fluid and the discharging opening of product, at distribution grid, the warming plate surface respectively scribbles heat insulating coating.Described nozzle break-make parts be lateral direction penetrating open in the distribution grid side and valve control arranged changeablely open with heat medium and close the passage of usefulness cooling medium.Described insulation hole and a plurality of nozzle are nested.Nozzle on the distribution grid stretches out in insulation hole direction.Described nozzle break-make parts are mechanical.In the described fusion liquid chamber of all pressing an equal pressure cap that communicates with voltage stabilizing material inlet pipe is arranged.
When the density of fused solution during greater than the density of cooling fluid, it contains from top to bottom: equal fusion liquid chambers of Yaing, be positioned at the flange below of above-mentioned fusion liquid chamber and the distribution grid of a plurality of nozzles vertically is housed, be positioned at above-mentioned distribution grid below and vertically have the corresponding a plurality of insulations hole that is nested and at the warming plate that laterally has the heat medium passage from the side with nozzle, through the tower body flange link to each other with warming plate and with it on the insulation above-mentioned tower body that communicates of hole and the nozzle break-make parts that link to each other with distribution grid, wherein, fusion liquid chamber flange, distribution grid, warming plate, the tower body flange closely connects by bolt, below tower body, be provided with cooling fluid inlet distribution apparatus, the product discharge device is at distribution grid, the warming plate surface respectively scribbles heat insulating coating.Described nozzle break-make parts be lateral direction penetrating open in the distribution grid side and valve control arranged changeablely open with heat medium and close the passage of usefulness cooling medium.Described insulation hole and a plurality of nozzle are nested.Nozzle on the distribution grid stretches out in insulation hole direction.Described nozzle break-make parts are mechanical.In the described fusion liquid chamber of all pressing an equal pressure cap that communicates with voltage stabilizing material inlet pipe is arranged.
Evidence: the present invention has granulation efficiency and moves thermal efficiency height, and reduced investment, energy consumption are low, the advantage of processing ease, good product quality.
Description of drawings
Fig. 1. the prilling granulator cutaway view that the present invention proposes (density of fused solution less than the density of cooling fluid time).
Fig. 2. the structure cutaway view of this prilling granulator built up nozzle and warming plate (density of fused solution less than the density of cooling fluid time).
Fig. 3. the prilling granulator cutaway view that the present invention proposes (density of fused solution greater than the density of cooling fluid time).
Fig. 4. the structure cutaway view of this prilling granulator built up nozzle and warming plate (density of fused solution greater than the density of cooling fluid time).
Fig. 5. the connection diagram of distribution grid mechanical switch in prilling granulator.
Fig. 6. distribution grid mechanical switch structure schematic diagram.
Fig. 7. the product photo (particle 2~3mm) of the embodiment of the invention one.
Fig. 8. the product photo (particle 5~8mm) of the embodiment of the invention one.
The specific embodiment
When the density of fused solution during, see Fig. 1, Fig. 2 less than the density of cooling fluid.After granulation fused solution 1 is stabilized in definite pressure by compression pump 2 pumpings and through stable-pressure device 3, enter fusion liquid chamber 6 through material pipe 4, equal pressure cap 5, the top of fusion liquid chamber 6 is provided with fusion liquid chamber flange 7a, the top of this flange 7a is provided with distribution grid 8, distribution grid 8 is provided with a plurality of nozzles 9, the side of distribution grid 8 is provided with switch cooling medium and heat medium passage 13, valve 11 is used to control shutoff with cooling medium or open with heat medium and enter from mouth 10 or mouthfuls 12, behind heat medium and coolant guiding channel 13, flow out from mouth 14.The top of distribution grid 8 is warming plates 15, and warming plate 15 has and the nozzle 9 corresponding insulation holes 16 that are nested, and has heat medium passage 18 in the side of warming plate 15, behind heat medium process inlet 17, the heat medium passage 18, flows out from exporting 19.Warming plate 15 tops connect tower body 20 by tower body flange 7b.Fusion liquid chamber flange 7a, distribution grid 8, warming plate 15, tower body flange 7b closely connect with bolt, all scribble heat insulating coating on the surface of distribution grid 8, warming plate 15, are provided with cooling fluid inlet 21 and outlet for product 22 above tower body 20.
The beginning of above-mentioned granulation and stopping to be to realize that by the break-make to nozzle 9 when feeding heat medium in the passage 13 of distribution grid 8, nozzle 9 is heated, and the coagulum in nozzle 9 passages melts, and nozzle 9 is open-minded, and fused solution flows out from nozzle 9, and granulation begins; Switch when feeding cooling medium in the passage 13 of distribution grid 8, nozzle 9 is cooled, and the fused solution in nozzle 9 passages solidifies, and nozzle 9 turn-offs, and granulation stops.
In addition, the break-make of nozzle 9 also can adopt mechanical means to realize.As: Fig. 5, Fig. 6, below distribution grid 8, be provided with Perforated decking 23, in order to close the built up nozzle of forming by a plurality of nozzles 9 effectively, bonding elastic weld wood 24 above cover plate 23, have the porous that staggers with nozzle 9 positions on the cover plate 23, guarantee that fused solution is through the even supply nozzle 9 of energy behind the cover plate 23, for guaranteeing that the parallel of cover plate 23 moves up and down, be provided with a plurality of parallel guide rails 25 on distribution grid 8, the parallel of cover plate 23 moves up and down dependence by comprising movable pin 26, connect pin 27, connecting rod 28a, 28b, the link mechanism that turning cylinder 29 and handle 31 are formed is realized.Between turning cylinder 29 and fusion liquid chamber 6, seal washer 30 is arranged.
When the density of fused solution during, see Fig. 3, Fig. 4 greater than the density of cooling fluid.After granulation fused solution 1 is stabilized in definite pressure by compression pump 2 pumpings and through stable-pressure device 3, through material pipe 4, equal pressure cap 5, enter fusion liquid chamber 6, the bottom of fusion liquid chamber 6 is provided with fusion liquid chamber flange 7a, the below of this flange 7a is provided with distribution grid 8, distribution grid 8 is provided with a plurality of nozzles 9, the side of distribution grid 8 is provided with switch cooling medium and heat medium passage 13, valve 11 is used to control shutoff with cooling medium or open with heat medium and enter from mouth 10 or mouthfuls 12, behind heat medium and coolant guiding channel 13, flow out from mouth 14.The below of distribution grid 8 is warming plates 15, and warming plate 15 has and the nozzle 9 corresponding insulation holes 16 that are nested, and has heat medium passage 18 in the side of warming plate 15, behind heat medium process inlet 17, the heat medium passage 18, flows out from exporting 19.Warming plate 15 belows connect tower body 20 by tower body flange 7b.Fusion liquid chamber flange 7a, distribution grid 8, warming plate 15, tower body flange 7b closely connect with bolt, surface at distribution grid 8, warming plate 15 all scribbles heat insulating coating, below tower body 20, be provided with cooling fluid inlet distribution grid 32, have a plurality of holes less than grain diameter on the distribution grid 32, the bottom is provided with cooling fluid pipeline 33.Cooled grain products is from discharge port 34, discharge product through discharge device 35.
The beginning of above-mentioned granulation and stopping to be to realize that by the break-make to nozzle 9 when feeding heat medium in the passage 13 of distribution grid 8, nozzle 9 is heated, and the coagulum in nozzle 9 passages melts, and nozzle 9 is open-minded, and fused solution flows out from nozzle 9, and granulation begins; Switch when feeding cooling medium in the passage 13 of distribution grid 8, nozzle 9 is cooled, and the fused solution in nozzle 9 passages solidifies, and nozzle 9 turn-offs, and granulation stops.
In addition, the break-make of nozzle 9 also can adopt mechanical means to realize.As: Fig. 5, Fig. 6, below distribution grid 8, be provided with Perforated decking 23, in order to close the built up nozzle of forming by a plurality of nozzles 9 effectively, bonding elastic weld wood 24 above cover plate 23, have the porous that staggers with nozzle 9 positions on the cover plate 23, guarantee that fused solution is through the even supply nozzle 9 of energy behind the cover plate 23, for guaranteeing that the parallel of cover plate 23 moves up and down, be provided with a plurality of parallel guide rails 25 on distribution grid 8, the parallel of cover plate 23 moves up and down dependence by comprising movable pin 26, connect pin 27, connecting rod 28a, 28b, the link mechanism that turning cylinder 29 and handle 31 are formed is realized.Between turning cylinder 29 and fusion liquid chamber 6, seal washer 30 is arranged.When being used for Fig. 3, Fig. 4 device, to relevant position in Fig. 1, Fig. 2 to be mounted to mirror image similar.
Embodiment one: the present invention implements in the granulation of paraffin fused solution, and the density of fused solution is less than the density of cooling fluid, and its basic parameter and implementation result are as follows:
Melting point of paraffin wax is 58 ℃, and the density of fused solution is about 776kg/m 3, the density of solid paraffin is about 916kg/m 3, the temperature of paraffin fused solution is 80 ℃, cooling fluid adopts cooling water.Adopt device shown in Figure 1.The warming plate heat medium adopts steam, and switch adopts steam with heat medium, and the cooling medium that switch is used is a cooling water.Cooling water recycles after lowering the temperature through refrigerating plant.
1. when nozzle diameter was 0.5mm, obtaining diameter was the spherical paraffin particles of 2~3mm, through draining with the centrifugal fluidized bed dehydration after, its water content is lower than 0.03%, product component does not have external other pollution components, reaches the product quality requirement, its granulation product such as Fig. 7.
2. when nozzle diameter was 1mm, obtaining diameter was the spherical paraffin particles of 5~8mm, through draining with the centrifugal fluidized bed dehydration after, its water content is lower than 0.03%, product component does not have external other pollution components, reaches the product quality requirement, its granulation product such as Fig. 8.
Embodiment two: the present invention to urea melting liquid granulation in atoleine implement, the density of fused solution is greater than the density of cooling fluid, its basic parameter and implementation result are as follows:
The fusing point of urea is 132.7 ℃, and the density of urea melting liquid is 1335kg/m 3, cooling fluid adopts atoleine, and the density of atoleine is about 845kg/m 3, adopt device shown in Figure 3.The warming plate heat medium adopts steam, and the heat medium that switch is used adopts steam, and the cooling medium that switch is used is an atoleine.Atoleine recycles after lowering the temperature through refrigerating plant.When nozzle diameter was 1.2mm, obtaining diameter was the spherical urea granules of 3~6mm, through draining with the centrifugal fluidized bed dewaxing after, good quality of product.

Claims (12)

1. fused solution is made the prilling granulator of spheric granules product, contain cooling fluid inlet and outlet for product, tower body, nozzle and break-make parts thereof, it is characterized in that, when the density of fused solution during less than the density of cooling fluid, it contains the fusion liquid chamber of all pressing, be positioned at the flange top of above-mentioned fusion liquid chamber and the distribution grid of a plurality of nozzles vertically is housed, be positioned at above-mentioned distribution grid top and vertically have the corresponding a plurality of insulations hole that is nested and at the warming plate that laterally has the heat medium passage from the side with nozzle, through the tower body flange link to each other with warming plate and with it on the insulation above-mentioned tower body that communicates of hole and the nozzle break-make parts that link to each other with distribution grid, wherein, fusion liquid chamber flange, distribution grid, warming plate, the tower body flange closely connects by bolt, the tower body top is provided with the inlet of cooling fluid and the discharging opening of product, at distribution grid, the warming plate surface respectively scribbles heat insulating coating.
2. fused solution is made the prilling granulator of spheric granules product, contain cooling fluid inlet and outlet for product, tower body, nozzle and break-make parts thereof, it is characterized in that, when the density of fused solution during greater than the density of cooling fluid, it contains from top to bottom: equal fusion liquid chambers of Yaing, be positioned at the flange below of above-mentioned fusion liquid chamber and the distribution grid of a plurality of nozzles vertically is housed, be positioned at above-mentioned distribution grid below and vertically have the corresponding a plurality of insulations hole that is nested and at the warming plate that laterally has the heat medium passage from the side with nozzle, through the tower body flange link to each other with warming plate and with it on the insulation above-mentioned tower body that communicates of hole and the nozzle break-make parts that link to each other with distribution grid, wherein, fusion liquid chamber flange, distribution grid, warming plate, the tower body flange closely connects by bolt, below tower body, be provided with cooling fluid inlet distribution apparatus, the discharge device of product is at distribution grid, the warming plate surface respectively scribbles heat insulating coating.
3. according to claim 1 fused solution is made the prilling granulator of spheric granules product, it is characterized in that: described nozzle break-make parts be lateral direction penetrating open in the distribution grid side and valve control arranged changeablely open with heat medium and close the passage of usefulness cooling medium.
4. according to claim 2 fused solution is made the prilling granulator of spheric granules product, it is characterized in that: described nozzle break-make parts be lateral direction penetrating open in the distribution grid side and valve control arranged changeablely open with heat medium and close the passage of usefulness cooling medium.
5. according to claim 1 fused solution is made the prilling granulator of spheric granules product, it is characterized in that: a plurality of nozzles of described insulation Kong Keyu are nested.
6. according to claim 2 fused solution is made the prilling granulator of spheric granules product, it is characterized in that: a plurality of nozzles of described insulation Kong Keyu are nested.
7. according to claim 1 fused solution is made the prilling granulator of spheric granules product, it is characterized in that: the nozzle on the distribution grid stretches out in insulation hole direction.
8. according to claim 2 fused solution is made the prilling granulator of spheric granules product, it is characterized in that: the nozzle on the distribution grid stretches out in insulation hole direction.
9. according to claim 1 fused solution is made the prilling granulator of spheric granules product, it is characterized in that: described nozzle break-make parts are mechanical.
10. according to claim 2 fused solution is made the prilling granulator of spheric granules product, it is characterized in that: described nozzle break-make parts are mechanical.
11. according to claim 1 fused solution is made the prilling granulator of spheric granules product, it is characterized in that: in the described fusion liquid chamber of all pressing an equal pressure cap that communicates with voltage stabilizing material inlet pipe is arranged.
12. according to claim 2 fused solution is made the prilling granulator of spheric granules product, it is characterized in that: in the described fusion liquid chamber of all pressing an equal pressure cap that communicates with voltage stabilizing material inlet pipe is arranged.
CN 03100011 2003-01-03 2003-01-03 Granulating equipment for making molten liquid into spherical granule product Expired - Fee Related CN1212180C (en)

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CN1212180C true CN1212180C (en) 2005-07-27

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101165086B (en) * 2006-10-17 2011-07-20 江苏圣奥化学科技有限公司 Spherical rubber auxiliary agent and preparation method thereof
IT201600119699A1 (en) * 2016-11-25 2018-05-25 Eurotecnica Melamine Luxemburg Zweigniederlassung In Ittigen PLANT AND PROCESS OF PRODUCTION OF SOLID UREA IN GRANULES
CN111073607B (en) * 2020-03-05 2023-12-12 郑州轻工业大学 Phase-change sphere preparation system and control method thereof
CN111054931B (en) * 2020-03-05 2023-09-29 郑州轻工业大学 Ball preparation system for ball bearing and control method thereof

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