CN1211292A

CN1211292A - Particle-containing fibres

Info

Publication number: CN1211292A
Application number: CN97192216A
Authority: CN
Inventors: O·托米仁; O·T·图鲁仁; E·欣利希森; K·佩特森
Original assignee: Borealis AS; FiberVisions AS
Current assignee: Borealis AS; FiberVisions AS
Priority date: 1996-02-12
Filing date: 1997-02-06
Publication date: 1999-03-17
Anticipated expiration: 2017-02-06
Also published as: DK0880610T3; DE69707838D1; KR19990082626A; EP0880610A1; EP0880610B1; ES2166061T3; DE69707838T2; WO1997030199A1; ATE207982T1; JP2000504791A; BR9707421A; CN1079452C; AU1718497A

Abstract

Fibres of filaments suitable for the production of a nonwoven fabrics, the fibres or filaments consisting essentially of a polyolefin or a copolymer thereof and 0.01-20 % by weight of inorganic particles, substantially all of the particles having a Mohs hardness of less than about 5 and preferably less than about 2, at least 90 % by weight of the inorganic particles having a particle size of less than 10 mu m. Talc particles are particularly preferred. Particle-containing staple fibres according to the invention can be continuously formed into a web and thermobonded to a nonwoven fabric at high speeds, and they have a broad bonding window, reduced static electricity and a reduced friction coefficient.

Description

The fiber that contains particle

What the performance that the present invention relates to be used to make thermal non-woven fabric had an improvement contains particulate polyolefin fiber and long filament.The invention still further relates to and plant the non-weaving cloth that contains particulate polyolefin fiber or long filament making thus.

Background of invention

Non-weaving cloth is to be bonded together and the porous sheet made by fiber or long filament.They can be flat or fluffy, and according to the difference of its production method, performance also may vary.Nonwoven fabric has been applied in various fields, comprises the part as products such as clothes, building, house fitting, health care, engineering, industry and the consumer goods.An important purposes is used to produce sanitary absorbent article exactly, as the various parts of throw-away nappy, women sanitary articles and adult-incontinence articles.

As the basis of nonwoven fabric, bonding between fiber in the fiber web or the long filament given fibre web with intensity and have influence on its overall performance.A kind of adhesive bonding method that is widely used in this kind fibre web is to make thermoplasticly by heating, and as polyolefin or polyester, fiber or long filament are bonded together.The manufacture method of nonwoven fabric can be seen in various publications, as " non-woven handbook (" non-woven TIA ", 1988) and " polymer science and engineering complete works " the 10th volume, " non-weaving cloth " (John Wiley and Sons, 1987).

The growing people's faster production that forces of nonwoven products consumption figure is to increase production capacity.Yet problem has just been come, and for example when heat pressure adhesive speed improved, for keeping bonding quality, temperature also must improve.And this causes occurring nonwoven fabric and adheres to problem on the hot roll.

Generally speaking, inorganic particle is used for various purposes in plastics industry, and also is no lack of the example that contains the inorganic particle fiber that is used for nonwoven fabric in the fiber of prior art.

Such as, JP 4194026 and JP 4170463 disclose a kind of polyester fiber of inorganic inert particle such as talcum or silica that contains 0.01～3.0% (weight) as nucleator.

EP 569 860-A disclose a kind of nonwoven web that comprises as polypropylene or polyethylene and so on spunbond thermoplastic filament, and this kind long filament contains 0.1～0.3% (weight) is 1 micron to the maximum as the granularity of nucleator fumed silica.

EP 539 890-A disclose a kind of melting extruded thermoplastic polyolefin composition that comprises polysiloxanes and hydrophobicity fumed silica, but are used for preparation warm nature nonwoven web fiber.

JP 3069675 discloses a kind of synthetic fiber as polypropylene or polyethylene and so on, and it comprises the ceramic oxide particle that 3～30% (weight) are sent far ir ray.This kind particle for example is Al ₂O ₃, MgO, SiO ₂, ZrO ₂Or TiO ₂, granularity is preferably less than 1 micron.Handled with silicone compounds on the surface of this kind fiber.

JP 2169718 disclose a kind of be core with the polyester, be the core-skin composite fiber of skin with the polyolefin, the skin component comprises 0.3～10% (weight) TiO ₂Or talcum and so on particle mean size is 0.05～5 micron a inorganic particle.The purpose that adds inorganic particle is to improve the flexibility of fibre web and makes it opaque.

JP 1266216 discloses a kind of comprising as the high melting point component of polypropylene or polyester and so on and as the composite fibre of the low-melting component of polyethylene and so on, wherein high melting point component comprises 0.1～13% the inorganic filler as talcum, mica or alum clay and so on sheet-like particle form that accounts for high melting point component weight, and its granularity is 110 microns to the maximum.

JP 61155437 openly is used to produce the resin combination of continuous filament yarn nonwoven fabric, and this resin comprises polypropylene and 0.05～0.5% (weight) crystal nucleating agent, and this nucleator for example is alum clay or silica, and granularity is less than 5 microns.

Though, the above prior art document of quoting all be disclose various be used for nonwoven fabric contain particle fiber or long filament,, wherein neither one relates to provides the special high-speed production non-weaving cloth that is fit to, such as employed non-weaving cloth in hygienic material industry, want to accomplish to make all good nonwoven fabric of performances such as intensity and uniformity with up to for example 200～250 meters/minute or higher high-speed and continuous one-tenth net and heat pressure adhesive.

Now find unexpectedly, in based on the fiber of polyolefin or long filament, add the meticulous soft inorganic particle of relatively small amount, as talcum, can bring multiple advantage, be included in do not improve tack temperature, again keep intensity allow constant the time to improve fibre web is shaped and binding speed producing the ability of nonwoven fabric, and/or do not reduce that fibre web such as in the wrong is shaped and binding speed to obtain the ability of improved strength.

Summary of the invention

An object of the present invention is to provide the polyamide fiber or the long filament that contain particle, when it is configured as fibre web and hot sticky when being combined into nonwoven fabric with high-speed and continuous, the nonwoven fabric intensity (bondability index) that is obtained will be higher than with the corresponding fiber that does not contain described particle or the long filament nonwoven fabric intensity by the same manner preparation.

Another object of the present invention provide its bonding scope (bonding window) than the corresponding fiber that does not contain described particle or long filament wide contain particulate polyolefin fiber or long filament.

Another purpose of the present invention provides institute's static electrification and contains particulate polyolefin fiber or long filament than what the corresponding fiber that does not contain described particle or long filament lacked.

Further purpose of the present invention provides coefficient of friction than low the containing particle, contain polyolefinic fiber or long filament of the corresponding fiber that does not contain described particle or long filament.

Above-mentioned and other purpose of the present invention is just very clear after having studied carefully hereinafter.

Therefore, with regard to an aspect, the present invention relates to be fit to make the fiber or the long filament of nonwoven fabric, this fiber or long filament are made up of polyolefin or its copolymer and 0.01～10% (weight) inorganic particle basically, basically the Mohs' hardness of all these particles all less than the granularity of about 5, at least 90% (weight) inorganic particle less than 10 microns.

Detailed Description Of The Invention

In this specification and claims book, the definition of term " bondability index " is, along machine direction (vertically) (MD) with along the horizontal square root of the bonding strength product of (CD), centimetre be the value of unit representation with ox/5.

Bondability index is the sign of nonwoven fabric intensity.In view of being different from transverse strength usually along machine direction (being parallel to fibre web/nonwoven fabric moving direction) intensity, so bondability index is the function of these two variablees.Under best situation, the ratio between MD intensity and the CD intensity is close to one.

Term " bonding scope " is meant certain temperature range, can obtain qualified bondability index in this is interval.In this context, " bonding scope " is meant that the difference of bondability index and maximum bondability index (BImax) is no more than 15% the temperature range (is unit with K) of BImax.Be used as under the second best in quality typical nonwoven fabric situation of sanitary absorbent article, this interval is about 3N/5 centimetre corresponding to the difference of bondability index and BImax.

The tack temperature scope is wide more, and it is big more to make the producer of nonwoven fabric obtain the probability of even product, though when employed hot-pressing system when the hot roll surface temperature has fluctuation, perhaps as the same when adopting higher binding speed or reducing tack temperature.

What the invention provides novel, the improvement that is used to make nonwoven fabric contains polyamide fiber or long filament.This reaches by add inorganic particle in fiber or long filament, promptly because the adding of inorganic particle makes the physical property of fiber or long filament that unexpected change take place, demonstrate and help the variation that fiber or long filament are combined into heat bonding performance aspect between for example fiber of fibre web of nonwoven fabric or the long filament.Hereinafter,, should be appreciated that the present invention is applicable to fiber simultaneously, for example cut off staple fibre although usually for the sake of simplicity, only carry " fiber ", and long filament, for example continuous spun-bonded continuous yarn.

Particularly, when in fiber of the present invention and long filament, adding " soft " inorganic particle, during as talcum, kaolin (aluminium hydrosilicate), calcium carbonate, mica (physalite), wollastonite (calcium silicates), calcium sulfate, barium sulfate etc., they will obtain favourable performance.With regard to the hardness of particle, it is about 6 that the Mohs' hardness of particle (according to originally from the Mohs' hardness standard of 1～10 scope) should not surpass, and preferably is not more than approximately 5, especially is not more than approximately 4, particularly is not more than about 3.Because talcum and kaolin are particularly suitable for being incorporated in this fiber or the long filament, so Mohs' hardness usually can be also lower than this, for example is not more than 2, or or even 1, promptly corresponding to the hardness of talcum.Preferably, at least a portion inorganic particle is a talc particle; In making us interested embodiment especially, all particles all are talc particles basically.Though contain fiber than grit, for example contain silica, its Mohs' hardness is 7, also may possess the characteristic that some is fit to make nonwoven fabric, but still preferred soft inorganic particle, reason is that hard, abrasion particle tends to the damaged fiber production equipment.This also is to be the preferred inorganic particle kind that is used for the object of the invention by the softest mineral matter talcum of Mohs' hardness standard why.

Term " talcum " is meant that by usage of the present invention the high magnesium silicate content of a class is (as corresponding to greater than about 90%MgO+SiO ₂) the natural minerals of wide region.Most commercial talcum grade it is believed that and be fit to use of the present invention, and but, those granularities are little, then being of even particle size distribution preferred (discussion of the relevant preferred size that sees below).

Inorganic particle can be incorporated in the polymer masses before the polymer chips that preparation is generally used for the preparation fiber, and perhaps this particle also can directly join in the polymer melt.In order to regulate the content of inorganic particle, reaching particle simultaneously evenly distributes in fibrous finished product, usually advantageously, prepare high granule content, as 30%, 40% or 50% (weight), the polymer beads masterbatch, then the part masterbatch pellet is mixed mutually with the general polymer section that does not contain particle, be placed on again and be prepared into the granule density of melt in the extruder to obtain to require.

About containing the content of inorganic particle in the polyamide fiber, this content should be not low excessively, because should being arranged, the particle of q.s (considers that particle will be evenly distributed in the polymer melt basically near fiber surface, therefore just be evenly distributed in the whole fiber), and this content again should be not too high, because the fibre machinery performance should not suffer damage (with regard to most of purposes, fibre strength decline less than 10%, be acceptable for example less than 5%), and because granule content too much may cause the problem in the spinning process.Concerning the closest type of polymer of many and this respect relation, also will speak of below these polymer, it is believed that, the content of inorganic particle accounts for 0.01～20% (weight) of fiber, typical case accounts for 0.1～15% (weight), more typically accounts for 0.2～10% (weight), particularly 0.5～5% (weight) will be suitable as 1.0～2.5% (weight).This content can change along with various factors, (particle is thin more to comprise grain graininess and size distribution, the quantity that can add is many more), and fiber or long filament be gathered into nonwoven fabric speed (because, find again, the effect of particle is particularly remarkable when the nonwoven fabric speed of production is higher, is favourable so improve granule content under the speed of production condition with higher).

As for the quality of inorganic particle, according to guessing, granularity should adapt with the fiber cross sections size.Yet even if fiber is thicker, grain graininess should be not excessive yet, because the comparatively smooth fiber in Bi Jing surface is wished.Therefore, with regard to the industrial nonwoven fabric of hygienic articles is produced employed typical fibers fiber number, (be that fibre diameter is generally at about 0.5～7 dtex (dtex), also will further specify below), the preferred size of particle and size distribution should satisfy, and the size (full-size) of at least 90% (weight) particle is less than 10 microns.Particle is preferably as far as possible little, and the granularity that it is therefore preferable that at least 90% (weight) particle is more preferably less than 6 microns less than 8 microns, most preferably less than 4 microns.

Further preferably, size distribution is narrow, so that make the stability of fibre spinning process interference-free, avoids causing fiber to break end because of inhomogeneities is excessive.Therefore, particle size distribution preferably should satisfy, and makes the ratio of the granularity that granularity that 90% hundredths (percentile) (weight) locates and 10% hundredths (weight) locate be about 20: 1 to the maximum, more preferably is about 15: 1 to the maximum, most preferably be about 10: 1 to the maximum, particularly be too narrow to the most about 8: 1.

Polyolefin in fiber of the present invention and the long filament can comprise polyolefin homopolymer or copolymer.Suitable polyolefin, for example be the isotactic polypropylene homopolymers and with the random copolymer of ethene, 1-butylene, 4-methyl-1-pentene, 1-hexane etc., and the Hi-fax of different densities, as high density polyethylene (HDPE), low density polyethylene (LDPE) and linear low density polyethylene (LLDPE).Preferred polyolefin is Noblen or contains 10% (weight) other alhpa olefins at most, as the propylene copolymer of ethene, 1-butylene, 4-methylpentene or 1-hexene.As this kind polymer of the raw material of fiber production, suitable melt flow rate (MFR) (MFR) is lower than 500 grams/10 minutes, for example is lower than 25 grams/10 minutes.The melt that is used to produce based on polyolefinic fiber also can contain various traditional fiber additives, as calcium stearate, antioxidant, processing stabilizers and pigment, comprises brightening agent and colouring agent, as titanium dioxide etc.

As already pointed out, the present invention relates to two kinds of fibers, as be used for the staple fibre of the cut-out of carded web, also relate to continuous filament yarn, as spun-bonded continuous yarn.With regard to staple fibre, they both can be one pack systems, can be bi-components also, and the latter is sheath-core bicomponent fibre for example, and wherein core component can be eccentric (departing from the center) or concentric (substantially at the center).Core and skin that typical bicomponent fiber is comprised comprise polypropylene, polyethylene, high density polyethylene (HDPE)/linear low density polyethylene (LLDPE), polypropylene random copolymer/polyethylene or polypropylene/polypropylene random copolymer again respectively.They can also be is high melting point component with the polyester, be the bicomponent fiber of low-melting component with polypropylene or its copolymer or polyethylene.

In specification of the present invention, this low-melting component (skin component) comprises inorganic particle at least.

In order to make fiber and long filament be applicable to sanitary absorbent article with the making of nonwoven fabric, the typical fiber number that this fiber or long filament should have is in 0.5～7 dtex scope, and as 1～7 dtex, 1.5～5 dtexs more typically are as 1.7～3.3 dtexs.

Can adopt " compact spinning " method or adopt traditional melt spinning (also being referred to as " long spin ") according to the spinning of fiber of the present invention.This two classes spinning process is all known technically.The tradition spinning is two step process, and the first step is that melt is extruded and the actual of tow spins, and this step to be carrying out at a high speed, and second step was to spin the drawing-off of tow and curling subsequently, dry and be cut to staple fibre.Compact spinning is a step process, and wherein spinning and drawing-off are finished in single stepping simultaneously.This spinning technique can be seen in, for example Ahmed shows " polypropylene fibre-science and technology ", nineteen eighty-two publishes.Be used to produce sanitary absorbent article with the long spin technology of nonwoven fabric can be seen in, for example WO 89/10989, WO 93/01334, WO 94/20664, WO 95/19465 and WO 96/33303.Spun-bond process for example can be seen in " trend in modern spunbond technology 2-90 age ", Miller Freeman work, version in 1992.In this spinning process, tow is handled with suitable surfactant, antistatic additive etc.

From above discussion, can be clear that, the invention still further relates to and comprise the fiber of inorganic particle or the nonwoven fabric of long filament of containing described herein.

The invention further relates to the method that is prepared nonwoven fabric by staple fibre, this method may further comprise the steps: (a) shaping comprises the fiber web according to the staple fibre of this paper fiber dimensious, and (b) makes this fiber web bonding.Particularly, this adhesion process more preferably at least 200 meters/minutes, is most preferably finished under at least 250 meters/minutes speed preferably at least 150 meters/minutes.This bonding preferred employing heat bonding, bonding or hot-air is bonding as hot roll, and infrared bonding or ultrasonic bonds is finished.

The invention still further relates to the method that is prepared nonwoven fabric by long filament, this method may further comprise the steps: (a) being shaped comprises the fiber web that constitutes according to the long filament by this paper fiber dimensious, and (b) makes this fiber web bonding.The in question embodiment of a kind of method in relevant front (staple fibre) also is applicable to the method that adopts long filament.

Once pointed out above, found that novel fiber or the long filament that contains particle of the present invention can produce many-sided unexpected advantage, comprised that this fiber or long filament can be to be configured as fibre web and heat bonding than the higher speed of corresponding fiber that does not contain inorganic particle.Though do not intend being limited to any theory, the inventor believes that this is owing to the comprehensive function result of particle to the multiple favourable effect that fiber or long filament produced.One of major advantage it is believed that it is the improvement of fiber or long filament macroscopic property, especially the raising of thermal conductivity, this raising it is believed that it is to cause fiber to carry out bonding reason at a relatively high speed with for example hot roll, in other words, if this speed is used on the corresponding fiber or long filament that does not contain inorganic particle, thereby will cause the bonding quality difference and produce ropy nonwoven fabric.That is to say, find that fiber of the present invention can overlap one realizes the bonding of satisfaction under the given condition in wideer temperature range.Especially it is to be noted that this is for requiring the various conditions of more careful control so that produce, with regard to indexs such as intensity, the more high production speed of the nonwoven fabric that performance is satisfied is to be again important.

The minimizing that observed another advantage is a static from the fiber of the present invention, it makes fiber be able to carry out combing under higher speed, therefore helps the carrying out of carding process.Also further find, containing talcum at least, just on the fiber of the sort of particle at present preferred for this invention, can reach the effect that reduces friction.This can promote carding process equally, thereby helps the realization of high-speed production and do not cause finished product nonwoven fabric compromised quality.Find that in addition the hydrophobicity of talcose polyamide fiber decreases, this may be valuable for those nonwoven fabric that are intended to be used to drench.

The effect of particle is dual: at first, the improvement of static and attriting performance aspect makes staple fibre of the present invention be able to combing under fair speed and without detriment to the uniformity of fibre web, the second, the improvement of thermal property makes and for example to be able to carry out under higher speed with the bonding heat bonding of hot roll and needn't to seek help from the raising of tack temperature.Because the nonwoven fabric production process had both depended on the fibre web forming speed, for example combing speed, depend on binding speed again, the two must keep basically identical in tinuous production, therefore its effect is to have improved productivity ratio greatly, the fair speed that promptly keeps production line, and the while quality is without any remarkable loss.Yet, higher nonwoven fabric linear velocity and not exclusive possible advantage in fact also can obtain by the present invention, for example be not raising speed (perhaps, the two gets both probably), can the lower nonwoven fabric of production unit weight and do not reduce the advantage of intensity but get it.

As seen, concerning the producer of nonwoven fabric,, comprise widening and the improvement of bondability index of bonding scope according to above-mentioned every improved characteristics of fiber of the present invention, and the reduction of static and friction, will cause bringing the reduction of production cost owing to the modification of following manufacturing parameter:

● under the temperature-resistant situation of heat bonding, produce the constant nonwoven fabric of Unit Weight, keep nonwoven fabric intensity constant simultaneously with higher speed of production;

● do not change speed of production and heat bonding temperature, can produce the less nonwoven fabric of Unit Weight, keep nonwoven fabric intensity constant simultaneously;

● under the condition that does not change speed of production and heat bonding temperature, can adopt lower hot roll pressure to produce nonwoven fabric, keep nonwoven fabric intensity constant simultaneously;

● speed of production is constant, but can produce the identical nonwoven fabric of Unit Weight under than the low-heat tack temperature, keeps nonwoven fabric intensity constant simultaneously.

Under above-mentioned various situations, although all taked the measure that reduces cost, because employing of the present invention, it is constant to make that nonwoven fabric intensity and quality are maintained.

Therefore, in one embodiment of the invention, comprise polyolefin and contain the fiber of 0.1～20% (weight) inorganic particle, wherein the granularity of the particle of at least 90% (weight) is less than 10 microns, this fiber can be fibre web with 100 meters/minute speed progressive forming, and go out at least 10% in the bonding wide ranges of producing nonwoven fabric than the corresponding fiber that does not contain inorganic particle in the same manner with 100 meters/minute speed, preferably at least 20%, more preferably carry out bonding continuously with hot roll at least 30% the bonding scope, wherein the definition of bonding scope is a temperature range, does not exceed this scope of BImax ± 15% at this interval bondability index.

In another embodiment of the invention, comprise polyolefin and contain the fiber of 0.1～20% (weight) inorganic particle, wherein the granularity of the particle of at least 90% (weight) is less than 10 microns, this fiber can be fibre web with 100 meters/minute speed progressive forming, and with the speed of hot roll with 100 meters/minute, and exceed at least 10%, preferably at least 20% than the bondability index that the corresponding fiber that does not contain particle is produced nonwoven fabric in the same manner, more preferably at least 30% bondability index be bonded as continuously Unit Weight be 20 restrain/square metre nonwoven fabric.

In yet another embodiment of the present invention, this fiber comprises polyolefin and contains 0.1～20% (weight) inorganic particle, wherein the granularity of the particle of at least 90% (weight) is less than 10 microns, this fiber can be fibre web with 100 meters/minute speed progressive forming and carry out bonding with hot roll, produce Unit Weight and be 20 grams/square metre nonwoven fabric, wherein this nonwoven fabric roll up record on the nonwoven fabric that corresponding fiber that static numeric ratio that overhead 3 centimeters record never contains particle produces in the same manner low at least 20%, for example hang down at least 30%, preferably at least 40%, more preferably low by at least 50%, particularly hang down at least 70%.

As for selected polyolefin in above-mentioned (bonding scope, bondability index and static value) embodiment, preferably adopt polypropylene or its copolymer (as described above).Homofil or long filament are that general institute is preferred owing to its production cost is low, and still, under special circumstances, bicomponent fiber or long filament also can use, and perhaps use separately or with homofil or long filament and all can.

In more interesting embodiment of the present invention, all features such as above-mentioned relevant bonding scope, bondability index and static are even adopting higher speed, as 175 meters/minute or 200 meters/minute or 250 meters/minute, or even the situation of 300 meters/minute or 350 meters/minute under, still can obtain.

As mentioned above, the reduction of fiber or long filament friction can realize by adding soft inorganic particle.Obviously, this will reduce fiber or long filament production equipment and the wearing and tearing of producing the production equipment of nonwoven fabric with this fiber or long filament, therefore, relate to the replacing of machine parts and the consumption of the energy and will also have reduced with regard to corresponding.For this reason, in one embodiment of the invention, this contains the fiber of particle or the coefficient of friction of long filament has reduced at least 10% than the corresponding fiber or the long filament that do not contain particle, and for example at least 20%, preferably at least 30%, more preferably at least 40%, especially reduce by 50%.

Test method

Bondability index is measured

TENSILE STRENGTH (MD) reaches laterally according to EDANA 70.2-89 along machine direction (vertically), and (CD) measures.Bondability index (BI) centimetre is unit representation with ox/5, is to calculate under different tack temperature, and this bondability index is defined as vertically and the square root of transverse strength product.For extrapolate standard nonwoven fabric Unit Weight 20 gram/square metre under standard adhesion index (BI ₂₀-this paper is called for short BI), the bondability index calculated value of given sample is multiplied by 20, remove in order to the effective unit weight of gram/square metre be unit again, thereby eliminate the factor of nonwoven fabric intensity with the Unit Weight variation.Bimax is meant the maximum bondability index in the tack temperature scope.

Bonding scope is measured

Measure bondability index respectively under several temperature in the uniform temperature interval, the temperature upper limit of this temperature range is defined by the temperature that fiber or long filament begin to adhere on the hot roll, and its lowest temperature is then for bonding temperature no longer takes place.Then, determine maximum bondability index (BImax).Bonding scope (is unit with K) is that the deviation of bondability index and BImax is less than 15% pairing temperature range.

Particle size distribution

The granularity of inorganic particle can adopt automatic precipitation Particle Size Analyzer to measure, (Micromeritics company produces for example to adopt SediGraph 5000 Particle Size Analyzers, the Georgia, the U.S.), " this bears the recommend method of ground Na Weiya pulp " according to the paper and the cardboard test committee (the 4th edition suggestion of P 115 X, 1987) measured.

Static value is measured

It is after nonwoven fabric is collected rolling that the overhead static value of nonwoven fabric is measured, and adopts Electrostatic Meter Statiron M, and model 7204 (Haug company makes, Germany) is measured.

To further specify the present invention in the following embodiments.

Embodiment

Example 1～6

All polypropylene grades of using in the following example all are to be produced by Borealis OY company (Finland).

Adopt a dry method lapping nonwoven fabric production line to prepare nonwoven fabric.The most important equipment that is used for combing and hot pressing is: Hergeth Card Akg-1-5-FI-dl-R2 (1000 millimeters of working widths) and K ü sters Three-bowl Carlender 410.30.This hot-rolling mill has 2 rollers, 400 millimeters of body diameters, 600 millimeters of column part fabric widths, 500 millimeters of maximum rapidoprint fabric widths, bond area 21.8%.Maximal rate is 350 meters/minute.The Unit Weight of all nonwoven fabric be about 20 the gram/square metre.

Talc content in the material of being mentioned is 0.5～20% (weight), and content is 0% in the reference material.

Example 1

MFR is that (Finntalc M03, Finnminerals OY produces, Finland) is mixing together at melt stage and 0,5,10,15 and 20% talcum for 12 polypropylene.The size distribution of this talcum following (% (weight)):

＜10 micron 99%

＜5 micron 96%

＜2 micron 74%

＜1 micron 40%

On traditional experiment spinning production line, go out the fiber of fiber number 2.5 dtexs with the polymer spun that contains filler.Fiber through false twist texturing to about 12 curl/centimetre level and be cut to 40 millimeters staple fibre, with this staple fibre making nonwoven fabric.The highest intensity that contains the nonwoven fabric of 15% talc particle is in same level with not talcose contrast nonwoven fabric.But, the fiber that contains particle is carried out the bonding wideer bonding scope that adopts, also can adopt higher tack temperature and do not cause nonwoven fabric to adhere on the hot roll.

In this example, owing to the obstruction of filament spinning component fails to spin out the fiber that contains 20% talc particle.It is believed that this is because due to the employed grain graininess, thereby the inventor believes,, originally can spin granule content and be equal to or greater than 20% fiber and come if adopt thinner particle.

Example 2

MFR is that 8 polypropylene is mixing together at molten condition and 0,0.5 and 1.0% talcum (Micro-TalcI.T.Extra, Norway talcum company, Norway).The size distribution of this talcum following (% (weight)):

＜20 micron 100%

＜10 micron 99%

＜5 micron 85%

＜3 micron 60%

＜2 micron 43%

This whiter slightly talcum is to the not influence of color of fiber.(fibre spinning is difficulty slightly, because grain graininess is than the big slightly cause of example 1 employed talcum.)

With another kind of talcum grade, addition 1% has been done single test again, and this talcum is Luzenac Prever-M8 (Luzenac company, an Italy), and its granularity is less, and is specific as follows:

＜8 microns: 97.5%

＜5 microns: 85.4%

＜2 microns: 34.5%

＜1 micron: 12.8%

The result that this example obtained is roughly the same with employing Finntalc (example 1).

Example 3

MFR is that 18 polypropylene and 0,0.5,1.0% talcum (Finntalc M03, Finnminerals OY, Finland) are mixing together.Find that the bonding scope that contains 0.5 or 1% talcum is wideer than not talcose contrast fiber.

Example 4

With MFR is that 15 polypropylene and talcum (Finntalc M03, Finnminerals OY, Finland) are made female section.This masterbatch pellet comprises 40% (weight) talcum.Be spun into the fiber that comprises 0,0.5,1.0 and 1.5% (weight) talcum by as above method, and make nonwoven fabric with various different combing speed from 100～295 meters/minute with this fiber.Find that when low speed, no matter at maximum bondability index or aspect the bonding scope width, each sample does not all have marked difference, and (this scope width is defined as allowing to obtain the temperature range of given bondability index; In following table, having provided and having corresponded respectively to bondability index is 15 and 10 scope width at least).But under higher speed, the raising of talc content causes the two the raising of maximum bondability index and scope width.Result of the test is provided in the table below.

The result of table 1. embodiment 4

Talcum powder %	BI _max	Scope ℃, BI＞15	Width ℃, BI＞10	Speed m/min
Talcum powder %	BI _max	Scope ℃, BI＞15	Width ℃, BI＞10	Speed m/min	????0 ????0.5 ????1.0 ????1.5	????25 ????25 ????24 ????25	????15 ????15 ????16 ????15	????15 ????17 ????18 ????17	????100 ????100 ????100 ????100
????0 ????0.5 ????1.0 ????1.5	????14 ????17 ????15 ????17	????0 ????4 ????3 ????5	????7 ????14 ????13 ????15	????175 ????175 ????175 ????175	????0 ????0.5 ????1.0 ????1.5	????25 ????25 ????24 ????25	????15 ????15 ????16 ????15	????15 ????17 ????18 ????17	????100 ????100 ????100 ????100
????0 ????0.5 ????1.0 ????1.5	????14 ????17 ????15 ????17	????0 ????4 ????3 ????5	????7 ????14 ????13 ????15	????175 ????175 ????175 ????175	????0 ????0.5 ????1.0 ????1.5	????12 ????14 ????14 ????15	????0 ????0 ????0 ????1	????2 ????3 ????3 ????6	????250 ????250 ????250 ????250
????0 ????0.5 ????1.0 ????1.5	????6 ????9 ????10 ????10	????0 ????0 ????0 ????0	????0 ????0 ????1 ????2	????295 ????295 ????295 ????295	????0 ????0.5 ????1.0 ????1.5	????12 ????14 ????14 ????15	????0 ????0 ????0 ????1	????2 ????3 ????3 ????6	????250 ????250 ????250 ????250

Example 5

With the polypropylene that MFR equals 12, do not contain or contain 1.5% talcum, spinning has prepared fiber under 270 ℃ of conditions.This fiber is used to prepare nonwoven fabric subsequently, and adopting linear velocity is 30 meters/minute and various different heat pressure adhesive temperature.Even talcose nonwoven fabric its sensation when adopting high hot roll tack temperature to produce is also very soft.Maximum bondability index under the different tack temperature provides in following table 2, therefrom as can be seen, can't realize at the fiber that does not contain talc particle but can producing the fabulous nonwoven fabric of intensity with the fiber that contains particle under the high tack temperature of heat pressure adhesive.

The result of table 2 example 5

Temperature	The % talcum powder
Temperature	The % talcum powder		????℃	????0	????1.5
????130 ????133 ????136 ????139 ????142 ????145 ????148 ????151 ????154 ????156 ????159	????0 ????3 ????7 ????16 ????18 ????23 ????24 ????22 ????*) ????- ????-	????2 ????8 ????17 ????24 ????23 ????26 ????25 ????25 ????24 ????23 ????*)	????℃	????0	????1.5

* roll banding tube

Example 6

Equal 12 polypropylene with MFR and be spun into fiber, make nonwoven fabric under 100 meters/minute of on-line velocity, 149 ℃ of conditions of tack temperature then at 270 ℃.

For the nonwoven fabric of making of the fiber that does not contain inorganic particle, along nonwoven fabric roll up static value that overhead 3 centimeters measure between-5.0～-8.0kv (fluctuating range is big).

For the nonwoven fabric of making of the fiber that contains 1.0% (weight) Finntalc M03, static value is+2.0～+ 3.0kv (fluctuating range is little).

Example 7

Upward produce staple fibre with the difference product grade polypropylene that Borealis OY produces in the spinning that can buy and drawing-off testing equipment (Fourn , Germany) by traditional long spin program.This spinning process is corresponding to long spin described herein (traditional spinning).The result of example 7 is stated from table 3.

As can be seen from Table 3, compare with the fiber that does not contain particle, the fiber that contains particle has kept the fibre strength feature basically.

Analyze and to find out that contain the particle fiber and compare with not containing the particle fiber, its Δ T value has reduced from DSC (difference examination scanning calorimetric).Though do not intend being limited to any theory, still, this may be the sign that contains the thermodynamic property improvement of particle fiber.

Example 8～9

Employing has the Spinbau Random Card (carding machine) and the Ramisch-Kleinewerfers 2 Bowl Calender (two roller hot-rolling mills) of 2 doffers, and the two fabric width is 700 millimeters, produces nonwoven fabric.This hot-rolling mill has a smooth roll (diameter: 250 millimeters) and a scoring roller (240 millimeters of diameters).Texturing (NW 99 types) are finished by Casaretto company, corresponding to bond area 21.78% (every square centimeter 60,1 point).Line speed is 175 meters/minute.Result with two kinds of different materials (" HD350 J " reaches " HE 350 J ") test is stated from table 4 and 5

Can find out from the result of each example, adopt the bondability index of the nonwoven fabric that contains the talcum fiber, compare with the not talcose nonwoven fabric of fiber, the nonwoven fabric bondability index has improved.

Table 3: the fiber characteristics as a result and the dsc analysis of example 7

Tensile fiber

MFR talcum powder MFR fiber number intensity elongation numbering raw material grade g/10min % g/min dtex CN/dtex %1 HD350J 8 0.0 38.5 2.3 1.9 315.02 HD350J 8 2.5 46.3 2.4 1.7 362.03 HD350J 8 0.0 27.3 2.2 2.0 405.04 HD350J 8 2.0 26.3 2.3 1.9 387.05 HD350J 8 2.5 31.4 2.1 1.9 370.06 HD950K 8 CR 0.0 27.9 2.2 2.5 301.07 HD950K 8 CR 1.5 30.3 2.2 2.3 284.08 HD350J 12 0.0 39.3 2.3 1.8 387.09 HD350J 12 0.5 46.2 2.3 1.8 377.010 HD350J 12 1.0 46.1 2.4 1.8 392.011 HD350J 12 1.5 42.8 2.3 1.8 396.012 HD350J 12 0.0 42.3 2.3 1.8 401.013 HD350J 12 1.5 44.0 2.2 1.7 420.014 HD350J 12 2.0 44.0 2.3 1.7 411.015 HD350J 12 2.5 40.7 2.4 1.7 409.0

DSC ΔT H J/g T℃ H J/g T℃ H J/g T℃ ℃1 90.5 160.1 79.4 104.0--56.12 93.2 160.8 64.4 117.0 106.6 161.1 43.83 92.8 161.6 65.5 102.9 115.1 160.7 58.84 94.4 161.9 70.3 115.5 112.2 161.8 46.45 88.7 162.1 66.1 116.1 100.1 161.0 46.06 88.8 159.1 61.6 102.8 113.4 159.9 56.37 91.3 159.6 54.4 115.1 112.0 155.5 44.58 84.3 166.1 83.1 101.4 93.7 161.5 64.79 90.2 161.5 59.2 111.6 115.5 160.7 49.910 95.3 163.1 45.7 112.1--51.011 89.8 160.8 57.2 112.9 98.2 161.7 47.912 92.6 161.6 77.3 102.5 95.6 160.0 59.113 98.4 161.1 58.1 113.0 112.7 156.6 48.414 90.9 161.0 58.1 116.1 134.5 156.8 44.915 91.1 162.5 63.9 117.3 113.8 158.3 45.24：8

Fiber MD MD CD CD talcum powder MFR fiber number TENSILE STRENGTH elongation NW weight TENSILE STRENGTH elongation TENSILE STRENGTH elongation bondability index combing speed % g/mm dtex CN/dtex % g/m ²N/5cm ％ N/5cm ％ N/5cm m/min0.0 27.3 2.2 2.0 405 20.0 40.5 40.6 5.4 54.1 14.7 1751.5 30.8- -- 20.0 37.8 46.0 7.9 73.5 16.9 1752.5 31.4 2.1 1.9 370 20.0 37.7 37.0 8.2 77.4 15.5 175

Table 5: the result of example 8

Fiber MD MD CD CD talcum powder MFR fiber number TENSILE STRENGTH elongation NW weight TENSILE STRENGTH elongation TENSILE STRENGTH elongation bondability index combing speed % g/min dtex CN/dtex % g/m ²N/5cm ％ N/5cm ％ N/5cm m/min0.0 39.3 2.3 1.8 387 20.0 41.5 43.6 8.4 71.4 17.7 1550.5 46.2 2.3 1.8 377 20.0 41.2 37.8 7.7 72.0 17.8 1751.0 46.1 2.4 1.8 392 20.0 44.8 44.6 8.1 79.3 18.7 1751.5 42.8 2.3 1.8 396 20.0 44.1 49.4 8.8 83.7 19.7 175

Claims

1. one kind is applicable to fiber or the long filament of making non-weaving cloth, this fiber or long filament are basically by polyolefin or its copolymer, and 0.01～20% (weight) inorganic particle is formed, the Mohs' hardness of these particles basically all less than the granularity of the inorganic particle of about 5, at least 90% (weight) less than 10 microns.

2. according to the fiber or the long filament of claim 1, wherein inorganic particle is selected from talcum, kaolin, calcium carbonate, mica, wollastonite, calcium sulfate and barium sulfate.

3. according to the fiber or the long filament of claim 1, wherein the Mohs' hardness of all inorganic particles preferably less than about 3.0, is more preferably less than about 2.0 all less than about 4.0 basically.

3. according to the fiber or the long filament of claim 1, wherein inorganic particle comprises talc particle.

4. according to the fiber or the long filament of claim 1, wherein whole basically particles all are talc particles.

5. according to any one fiber or long filament in the above claim, it comprises 0.2～10% (weight) inorganic particle.

6. according to the fiber or the long filament of claim 5, it comprises 0.5～5% (weight) inorganic particle.

7. according to the fiber or the long filament of claim 6, it comprises 1.0～2.5% (weight) inorganic particle.

8. according to any one fiber or long filament in the above claim, wherein polyolefin or its copolymer are polypropylene or polypropylene copolymer.

9. according to the fiber or the long filament of claim 8, wherein polypropylene or its copolymer are Noblens, or contain the copolymer of 10% (weight) as another alhpa olefin of ethene, 1-butylene, 4-methylpentene or 1-hexene and so at most.

10. according to any one fiber or long filament in the above claim, it is selected from staple fibre or spun-bonded continuous yarn.

11. according to any one fiber or long filament in the above claim, wherein the granularity of 90% (weight) inorganic particle is more preferably less than 6 microns less than 8 microns, most preferably less than 4 microns.

12. according to any one fiber or long filament in the above claim, it is a homofil.

13. according to any one fiber or long filament in the claim 1～11, it is a bicomponent fiber, its high melting point component comprises polypropylene or its copolymer, and low-melting component comprises polyethylene or its copolymer, and low-melting component comprises inorganic particle at least.

14. according to any one fiber or long filament in the above claim, its fiber number is between 0.5～7 dtex, 1～7 dtex is typically 1.5～5 dtexs, for example 1.7～3.3 dtexs.

15. according in the above claim any one contain particle fiber or long filament, wherein the coefficient of friction of fiber or the long filament corresponding fiber or the long filament that more do not contain inorganic particle reduced at least 10%.

16. according to claim 15 contain particle fiber or long filament, wherein the coefficient of friction of fiber or the long filament corresponding fiber or the long filament that more do not contain inorganic particle reduces at least 20%.

17. one kind is applicable to the fiber of making non-weaving cloth, this fiber comprises polyolefin and comprises 0.1～20% (weight) inorganic particle, the granularity of the particle of at least 90% (weight) is less than 10 microns, this fiber can be fibre web with 100 meters/minute speed progressive forming, and carries out bonding with hot roll at least in the bonding wide ranges of producing nonwoven fabric than the corresponding fiber that does not contain inorganic particle in the same manner goes out 10% bonding scope with 100 meters/minute speed.

18. according to the fiber of claim 17, wherein polyolefin is made up of polypropylene or its copolymer.

19. one kind is applicable to the fiber of making nonwoven fabric, this fiber comprises polyolefin and contains the fiber of 0.1～20% (weight) inorganic particle, wherein the granularity of the particle of at least 90% (weight) is less than 10 microns, this fiber can be fibre web with 100 meters/minute speed progressive forming, and with the speed of hot roll with 100 meters/minute, and with the bondability index of producing nonwoven fabric than the corresponding fiber that does not contain inorganic particle in the same manner exceed at least 10% bondability index be bonded as continuously Unit Weight be 20 grams/square metre nonwoven fabric.

20. according to the fiber of claim 19, wherein polyolefin is made up of polypropylene or its copolymer.

21. fiber according to claim 20, it can be with 100 meters/minute speed progressive forming fibre web and with hot roll be bonded as Unit Weight be 20 the gram/square metre nonwoven fabric, the bondability index that its bondability index is produced nonwoven fabric in the same manner than the corresponding fiber that does not contain inorganic particle exceeds at least 20%.

22. fiber according to claim 21, it can be with 100 meters/minute speed progressive forming fibre web and with hot roll be bonded as Unit Weight be 20 the gram/square metre nonwoven fabric, the bondability index that its bondability index is produced nonwoven fabric in the same manner than the corresponding fiber that does not contain inorganic particle exceeds at least 30%.

23. be applicable to the fiber of making nonwoven fabric, this fiber comprises polyolefin and contains the fiber of 0.1～20% (weight) inorganic particle, wherein the granularity of the particle of at least 90% (weight) is less than 10 microns, this fiber can be fibre web with 100 meters/minute speed progressive forming, and with hot roll with 100 meters/minute speed be bonded as continuously Unit Weight be 20 grams/square metre nonwoven fabric, wherein this nonwoven fabric roll up nonwoven fabric volume that corresponding fiber that average static numeric ratio that overhead 3 centimeters record never contains inorganic particle produces in the same manner overhead record low at least 20%.

24. according to any one fiber in the claim 23, wherein polyolefin comprises polypropylene or its copolymer.

25. according to the fiber of claim 23 or 24, wherein nonwoven fabric roll up nonwoven fabric volume that corresponding fiber that average static numeric ratio that overhead 3 centimeters record never contains inorganic particle produces in the same manner overhead record low at least 30%.

26. according to the fiber of claim 25, wherein the nonwoven fabric volume produced in the same manner of the corresponding fiber that never contains inorganic particle at the overhead 3 centimetres of average static numeric ratios that record of nonwoven fabric volume overhead record low at least 40%.

27. comprise according to any one the non-weaving cloth that contains inorganic particle fiber or long filament in the claim 1～16.

28. a method for preparing non-weaving cloth, it comprises that shaping comprises the fibre web according to the staple fibre of claim 1～16, and this fibre web is bonding.

29. according to the method for claim 28, wherein fibre web carries out combing and then carries out bonding with at least 150 meters/minutes speed.

30. according to the method for claim 29, wherein this speed is 200 meters/minute at least, preferably 250 meters/minute.

31. according to the method for claim 29 or 30, wherein fibre web is to adopt heat bonding, and is bonding or hot-air is bonding, infrared ray is bonding or ultrasonic wave is bonding etc. that method is carried out bonding as hot roll.

32. a method that is used to prepare non-weaving cloth, it comprises that shaping comprises the spunbond fibre web according to the long filament of any one in the claim 1～16, and this fibre web is bonding.