CN1211060C - Cosmetics for skin - Google Patents

Abstract

The present invention relates to a skin care cosmetic which comprises one or more kinds of powders (A). After the powders (A) have been homogeneously coated on a black synthetic leather by an amount of 8 mg/100 cm<SP>2</SP>, the color difference ([Delta]E) calculated by the following formula: color difference ([Delta]E)=((L45.45*-L45.20*)<SP>2</SP>+(a45.45*-a45.20*)<SP>2</SP>+(b45.45*-b45.20*)<SP>2</SP>)<SP>0.5</SP> is in a range of 7 to 40 on using two interference colors (L45.45*, a45.45*, b45.45*) and (L45.20*, a45.20*, b45.20*) specified by the CIE 1976 L*a*b color specification system and determined under the colorimetric conditions of incident light angle 45 DEG and receiving light angle -45 DEG and -20 DEG. When the composition of the present invention is applied on the skin, the color will not change though the observation direction is changed. Besides, the completed make-up is natural and transparent; furthermore, the hue feeling of the skin can be changed.

Description

Cosmetics for skin

The present invention relates to a kind ofly can keep transparent feel, can make the color and luster of skin feel the cosmetics for skin that changes simultaneously again.

Traditional makeup applies some make up, and uses the back to change in order to make skin produce texture, mixes the strong powder of diffuse-reflectance therein and finishes matt makeup, mixes the strong powder realization gloss makeups of direct reflection such as Muscovitum simultaneously.And, in order to hide skin colour gloomy (state that refers to gloomy skin, the flavescence) phenomenon that causes owing to poor circulation and age increase etc., the pigment of strong covering powers such as mixed oxidization titanium, ferrum oxide therein, add red pigments such as iron oxide red, mordant pigment and organic pigment simultaneously, utilize this method to make the color and luster of skin feel to change.

In addition, in order to hide red and red vestige, using a kind of is the viridine green of red complementary color, uses cyan and violet pigment in order to give transparent feel simultaneously, utilizes this quadrat method to make the color and luster of skin feel to change.

Yet when using the pigment of strong covering power, produce the problem of nature anesthesia.And when adopting the complementary color principle, the material chroma that can cover color is low, and this occurs the problem of colour of skin deepening again.These problems are that this method utilizes subtractive colour mixture (Subtractive color mixing) to carry out control color and cause that its reason is that the color superposition must be many more, and chroma reduces severely more, thereby makes it to be bordering on Lycoperdon polymorphum Vitt.

For this reason, traditional makeup applies some make up, and is difficult to both keep transparent feel, makes the color and luster of skin feel to change again.

Based on this, the object of the invention is to provide a kind of skin cosmetic, and this cosmetics color on different observed directions is constant, has both kept transparent feel, can make skin colour produce visual variation again.

In view of the situation, the inventor etc. further investigate, found that: when the preparation cosmetics, do not adopt the subtractive colour mixture principle, and adopt addition mixture (additive color mixing) principle, promptly adopt the colour mixture of light, use has the powder of specific aberration (Δ E), by means of the surperficial interference colours that this powder produces, and can be when keeping transparent feel, make skin colour feel to change, thereby finished the present invention.

That is to say, the invention provides a kind of cosmetics for skin, it is characterized in that wherein containing the powder (A) that aberration (Δ E) equals 7～40, said aberration is obtained in accordance with the following methods: evenly be coated with 8mg/100cm on the black synthetic leather ²Powder, when 45 ° of angle of incidence and-45 ° and-20 ° are subjected to the firing angle colour examining, with regard to CIE 1976 L ^*a ^*b ^*Color specification system (L ^*a ^*b ^*Color measuring system) two interference colours (L of regulation _45.45*, a _45.45*, b _45.45*) and (L _45.20*, a _45.20*, b _45.20*), calculate according to following formula:

Aberration (Δ E)=((L _45.45*-L _45.20*) ²+ (a _45.45*-a _45.20*) ²+

(b _45.45*-b _45.20*) ²)0.5

Past, in foundation cream etc., mix Margarita powder, produce unique gloss of Margarita and dazzling outward appearance (glaring appearance) in this case, the appearance poor of fixing, and also pearlescent appearance and interference tone change along with the variation of observation angle.This is because the Margarita powder interference colours that use in the past have the cause of directivity with respect to the angle of incidence of light, promptly observes strong interference colours near normal reflection, and does not almost observe in other direction.

In contrast to this, the present invention uses powder (A), and its tone variations changes along with the change of observation angle hardly, that is to say not only to produce interference colours near normal reflection, and in very large range can both observe this interference colours.

The powder (A) that the present invention uses is to obtain aberration (Δ E) according to above-mentioned formula to equal 7～40 powder.Wherein, in order to obtain aberration, earlier powder is placed on the black synthetic leather,, make and evenly be coated with 8mg/100cm it on sponge wiping synthetic leather gently ²Powder.For example use angle spectral photometry system (color technical research institute system in the village, GCMS-3 type), be subjected to the firing angle colour examining with 45 ° of angle of incidence and-45 ° and-20 °.Two interference colours of this moment according to CIE 1976 L*a*b* color specification systems regulation, use (L when being in when 45 ° of angle of incidence are subjected to firing angle with-45 ° _45.45*, a _45.45*, b _45.45*), when being subjected to firing angle with-20 °, use by 45 ° of angle of incidence (L when being in _45.20*, a _45.20*, _B45.20*), use these interference lights to obtain aberration (Δ E) according to above-mentioned formula.In addition, obtain the aberration (Δ E) of the employed black synthetic leather of this mensuration below 7 by the same manner.

The powder (A) that the present invention uses, the aberration of obtaining according to the method (Δ E) equals 7～40, preferably equals 10～35.Be lower than at 7 o'clock, though the color and luster of skin is felt to change, transparent feel disappears; And when surpassing 40, great changes have taken place along with the variation of viewing angle for the color and luster of skin sensation, and outward appearance is inharmonious.

There is no particular restriction for the particle diameter of the powder (A) with this aberration (Δ E), but be to use mean diameter below 12 μ m, and especially outward appearance is good during the powder of 3～12 μ m, and can reduce dazzling vision, thereby preferred.

In addition, preferably utilize and be coated with metal oxide microparticle on the powder (A) and produce interference colours.Wherein,, for example can enumerate Muscovitum, lamellar titanium oxide, flake ferric oxide, tabular alumina, lamellar silicon oxide, guanin, hydroxyl bismuth chloride etc., preferred Muscovitum as the precursor powder that is coated.And, for example can enumerate titanium oxide, ferrum oxide, zirconium oxide, aluminium oxide etc. as metal-oxide, can use a kind of in them or more than one and usefulness, wherein especially preferred titanium oxide, ferrum oxide or its mixture.In addition, when using the mixture coating of titanium oxide or titanium oxide and ferrum oxide, titanium oxide preferably uses Titanium Dioxide Rutile Top grade, and preferably not stanniferous.

In these powder (A), preferably use mica surface to be coated with the particularly powder of titanium oxide, ferrum oxide or its mixture of metal-oxide.

Wherein, there is no particular restriction for the method for using metal oxide microparticle coating precursor powder, can carry out according to usual method.

In addition, by being controlled at the optical thickness of the metal oxide microparticle that coats on the precursor powder surface, can produce various tones.For example the powder (first order optics thickness is about 300m μ) of interference colours demonstration blueness～purple is given skin with transparent appearance, the green powder (first order optics thickness is 390～400m μ) of interference colours demonstration is not dark-coloured and can suppresses the redness of skin, interference colours show, and orange～red powder (first order optics thickness is about 250-290m μ) can make skin seem healthy, and can cover the ash dead color of skin.Wherein, optical thickness defines with following formula: (powder thickness) * (refractive index).

And two or more powder (A) are used in combination, and also can produce various tones.

Wherein two or more powder (A) are when being used in combination, and the preferred Δ E that mixes the back powder of using reaches 7～40.

The powder that uses among the present invention (A), from light resistance angle preferred surface through hydrophobic treatment.E changes if hydrophobic treatment makes Δ, then can use to handle back Δ E and reach 7～40.

Said hydrophobic treatment uses the hydrophobic treatment agent to carry out, this hydrophobic treatment agent for example can enumerate silicone, fatty acid metal salts, alkyl phosphoric acid, alkyl phosphoric acid alkali metal salt or amine salt, single long-chain (8～22 carbon atoms) the aliphatic acyl radical basic amino acid of N-, have the fluorochemical of perfluoroalkyl etc.

Silicone for example can be enumerated dimethyl polysiloxane, cyclic dimethyl polysiloxane, methyl phenyl silicone, methylhydrogenpolysi,oxane, ring-type methylhydrogenpolysi,oxane, polyether-modified polysiloxanes, alkyl-modified polysiloxanes, methyl polysiloxane emulsion, high-grade aliphatic ester modified polyorganosiloxane, senior alkoxy-modified polysiloxanes, phenol-modified polysiloxanes etc. if use then not having especially of common used for cosmetic to limit.

Fatty acid metal salts especially preferably has 12～18 carbon atoms, and these salt can be enumerated for example salt such as its calcium, magnesium, zinc, aluminum, wherein preferred especially aluminum salt.

Alkyl phosphoric acid or its alkali metal salt or amine salt, can enumerate with the salt shown in the general formula (1) or (2), for example sodium salt, potassium salt or the amine salt of double hexadecyl phosphoric acid, single lauryl phosphoric acid, single lauryl phosphoric acid, the sodium salt of double hexadecyl phosphoric acid, potassium salt or amine salt etc.

(in the formula, R ¹Expression has the saturated or unsaturated straight or branched alkyl of 1～45 carbon atom, X ¹And X ²Expression hydrogen, alkali metal or amine)

(in the formula, R ²And R ³Expression has the saturated or unsaturated straight or branched alkyl of 1～45 carbon atom, X ³Expression hydrogen, alkali metal or amine.)

In above-mentioned formula (1) and (2), R ¹～R ³Though shown alkyl is 1～45 carbon atom, preferred carbon number is greater than 8.If carbon number is lower than 8, its alkyl phosphoric acid slaine presents viscosity, and slickness, ductility are low.In above-mentioned formula (1) and (2), X ¹～X ³Shown alkali metal can be enumerated potassium, sodium etc.; X ¹～X ³Shown amine can be enumerated for example ethanolamine, diethanolamine, triethanolamine, triisopropanolamine, morpholine and arginine etc.

Constitute the basic amino acid of single long-chain (8～22 carbon atoms) the aliphatic acyl radical basic amino acid of N-, can enumerate alpha, gamma-diaminourea butyric acid, ornithine, lysine, arginine, histidine etc.These promptly can be optically active, also can be racemic modifications.Said long-chain fat family acyl group is the saturated or undersaturated straight or branched aliphatic acyl radical of 8～22 carbon atoms, both can be single chain length, also can be to mix chain length.

As fluorine compounds, for example can enumerate by formula with perfluoroalkyl

[C _mF _2m+1CnH _2nO] _yPO (OH) _3y(wherein m is 4～14 integer, n is 1～12 integer, and y is 1～3 integer) perfluoroalkyl phosphoric acid (US-3632744), fluoro-alkyl two (ethoxy) amine phosphate ester (spy opens clear 62-250074), the resin (spy opens clear 55-197209) of expression, TFE, perfluoro alcohol, perfluoro epoxide, sulfonamide type fluoro phosphoric acid, perfluoro sulfate, perfluorinated substituted carboxylic acids's salt, perfluoroalkyl silane (spy opens flat 2-218603) etc. with perfluoroalkyl.

Powder is carried out the hydrophobic treatment agent use amount of hydrophobic treatment, preferred 0.05～20 weight %, more preferably 2～10 weight %.In this scope, can access sufficient hydrophobicity and good sense of touch and light resistance.And said hydrophobic treatment can be carried out according to known method.

Equal the combined amount of 7～40 powder (A) there is no particular restriction about above-mentioned aberration (Δ E), but the preferred combined amount of using is greater than 0.1 weight % in make-up composition, more preferably 0.1～90 weight % is preferably 0.5～80 weight %, and its concrete numerical value is different according to the form of cosmetics.For example, for astringent, preferably in full the composition, account for 0.1～10 weight %, particularly 0.5～5 weight %; For emulsion and cream, mix 0.1～10 weight %, particularly 0.5～7 weight %; For foundation cream white lead, solid white lead dough-making powder powder, preferred 0.1～80 weight %, particularly 1～50 weight %; For the foundation cream and the oil end, preferred 0.1～80 weight %, particularly 1～25 weight %; For at the bottom of the frost end, the liquid and covering agent (concealer), preferred 0.1～10 weight %, particularly 0.5～7 weight %; For lipstick and lip pomade, preferred 0.1～20 weight %, particularly 0.5～10 weight %; For rouge and eye shadow, preferred 0.1～40 weight %, particularly 0.5～25 weight %; For informer and Lan eye shadow, preferred 0.1～30 weight %, particularly 0.5～20 weight %.

In addition, in cosmetics of the present invention, except above-mentioned powder (A), by adding volume cumulative mean particle diameter is the monodisperse spherical powder (B) of 0.01～2 μ m, not only can keep above-mentioned transparent feel, the color and luster of skin is changed, and can access the good tack of a kind of energy maintenance and significantly improve ductility, do not have the cosmetics for skin of the works very well of fixing of a sense of slightly making and a powder sense again.

The above-mentioned monodisperse spherical powder (B) that can use in the present invention for example can be enumerated metal-oxides such as ball-aluminium oxide, spherical silica, spherical zircite, spherical titanium oxide, spherical zinc oxide; Plastics such as polyester, polyethylene, polystyrene, polymethyl methacrylate resin, styrene and acrylic acid copolymer, polypropylene, acrylic acid pearl, polyolefin, nylon; Silicon oxide system complex oxide, silicones, aluminium silicate, cellulose etc.Wherein so-called " monodisperse spherical powder " is meant that powder is the powder of proper sphere shape and narrow particle size distribution, its coefficient of variation (standard deviation/mean diameter) should be below 10%, particularly preferably in below 5%.And powder (B) though volume cumulative mean particle diameter should be 0.01～2 μ m, preferred 0.1～1 μ m's.Wherein so-called " volume cumulative mean particle diameter " is meant the sphere diameter meansigma methods suitable with the volume of tested powder.Use after the hydrophobic treatment that powder (B) preferably carries out and powder (A) is same.

The combined amount of powder (B) in cosmetics of the present invention should be 0.5～50 weight %, preferred especially 1～20 weight %.

In cosmetics of the present invention, except above-mentioned powder (A), if the adding specific surface area is 10～100m ²The zinc oxide of/g (C) then not only can keep above-mentioned transparent feel and skin colour is changed, and has the effect that can not fall woman's persona because of sebum in addition.

The zinc oxide that can use in the present invention (C), its specific surface area should be 10～100m ²/ g especially preferably uses 20～80m ²/ g's.

For zinc oxide (C), preferably also carry out using after the same hydrophobic treatment with powder (A) with (B); If but use fluorochemical to carry out surface treatment, then bad owing to be insoluble to sebum.In addition, zinc oxide (C) is allocated into after also can improving tactile other powder mixes with spherical powder etc.

The mixed proportion of this zinc oxide (C) in cosmetics for skin of the present invention should be in 0.1～99 weight % scope preferred especially 2～90 weight %.

In addition.In the cosmetics of the present invention, except above-mentioned powder (A), blending iron oxide-titanium oxide sintering colored pigment (D) therein is except producing above-mentioned effect, can obtain a kind of woman's persona that causes because of sebum and lack, especially the little cosmetics of the change color that causes because of sebum.

This ferrum oxide that can use in the present invention-titanium oxide sintering colored pigment (D) can utilize agglomerating method manufacturing behind the uniform mixing ferrum oxide in titanium oxide.In this case, by kind, mixed proportion, heating-up temperature, heat time heating time and the sintering environmental gas etc. that are chosen in blending iron oxide in the titanium oxide, can access and a kind ofly have from red, yellow, black, brown up to the color gamut of skin color sintering colored pigment wide and certain tinting strength, tinting power.What have the greatest impact for the color of sintering pigment is the kind of the ferrum oxide of sneaking in titanium oxide.For example, obtain the pigment of Yellow series, should be in titanium oxide the red iron oxide of mixed zone blue cast; Obtain the pigment of red series, should be in titanium oxide the red iron oxide of mixed zone yellow hue; Obtain the pigment of black series, should be in titanium oxide the ferrum oxide of mixed zone black tone.In this case, add a small amount of iron powder again and can further improve color.

About the mixed proportion of titanium oxide and ferrum oxide, usually the quantity with titanium oxide mostly is, and preferably is in 20: 1～1: 1 the scope.Sintering temperature is 600 ℃～1300 ℃, heat time heating time be 1～24 hour for good, and sintering atmosphere should adopt under the medium state of oxidation of atmosphere, perhaps behind the evacuation with under the anaerobic state of nitrogen replacement, or with under the metathetical reducing condition of hydrogen.The above condition of appropriate combination, any color in the middle of can freely obtaining from primary colors such as red, Huangs to brown, the colour of skin etc. the color.

The oxygen that obtains like this is with ferrum-titanium oxide sintering colored pigment (D), compare with simple hybrid pigment, has visibly different physical property between the two, for example in x-ray diffraction pattern, the peak that occurs titanium oxide (Detitanium-ore-type) and ferrum oxide for hybrid pigment brand-new peak occurs owing to titanium oxide is transformed into rutile-type by comparison under the situation of sintering pigment.

Colored pigment (D) preferably also uses the same hydrophobic treatment of process and powder (A).

The mixing ratio of colored pigment (D) in cosmetics for skin of the present invention should be in 0.1～99 weight % scope preferred especially 1～90 weight %.

In the cosmetics for skin of the present invention; except above-mentioned powder (A)～(D); in case of necessity in the scope of not damaging effect of the present invention; can also mix in the cosmetics blended all compositions usually, for example various oil, surfactant, water soluble polymer, other powder, wetting agent, antiseptic, medicament, UV absorbent, pigment, inorganic salt or organic salt, spice, chelating cut open, pH regulator agent, water etc.

Said oil can use liquid paraffin for example, vaseline, paraffin, zamene, Cera Flava, olive oil, lanoline, higher alcohol, fatty acid, higher fatty acids, ester oil, cured, microcrystalline wax, candelilla wax, diglyceride, triglyceride, silicone, perfluoro polyether, perfluoro decahydronaphthalenes, perfluoro octane, Jojoba oil (ホ ホ バ oil), tetradecanoic acid octyl group dodecyl ester, two octanesulfonic acid DOPCP etc. are widely used in the oils in the cosmetics in vain.

Said surfactant can use nonionic surfactant, anionic surfactant and cationic surface active agent, amphoteric surfactant etc. to be widely used in surfactant in the cosmetics.

Said water soluble polymer, can use the methylcellulose that for example contracts, methylcellulose, hydroxy methocel, polyvinyl alcohol, polyvinylpyridine, tragacanth gum, carrageenan (カ ラ ギ one Na Application), locust bean gum, dextrin, dextrin fatty acid ester, CVP Carbopol ETD2050, xanthene glue, gelatin, sodium alginate, Radix Acaciae senegalis etc. are widely used in the water soluble polymer in the cosmetics.

Said other powder can use the inorganic powder such as tungstates, hydroxyapatite, moisture silicic acid, anhydrous silicic acid, magnesium oxide, bentonite, zeolite, ceramics, aluminium hydroxide of for example Talcum, Muscovitum, Kaolin, sericite, white mica, synthetic mica, phlogopite, rubellan, biotite, lithium oxide Muscovitum, Vermiculitum, magnesium carbonate, calcium carbonate, kieselguhr, magnesium silicate, calcium silicates, aluminium silicate, barium silicate, strontium silicate, metal; Organic dusts such as nylon powder, polyethylene powder, polymethyl-benzene and guanamine powder, polymethyl methacrylate powder, tetrafluoroethene powder-microcrystalline Cellulose, rice starch lauroyl lysine; The metal salt powder of surfactants such as calcium stearate, zinc stearate, magnesium stearate, nutmeg acid magnesium, calcium palmitate, Hexadecanoic acid, zinc salt sodium; Titanium oxide, zinc oxide, zirconium oxide, ferrum oxide (iron oxide red), iron titanate, hydrated ferric oxide., loess, ferroso-ferric oxide, white carbon black, Fructus Mangifera Indicae purple, cobalt violet, chromium oxide, chromic oxide gel, cobalt titanium, ultramarine, inorganic coloring powder such as dark purple; Be coated with titanium oxide Muscovitum, be coated with titanium oxide hydroxyl bismuth, guanin, be coated with painted titanium oxide Muscovitum, etc. pearl pigment; Metal dusts such as aluminium powder, stainless steel powder, copper powder etc. are widely used in the powder in the cosmetics, and the powder that uses silicon compound or fluorine compounds to handle.

Said wetting agent can use for example Sorbitol, xylitol, glycerol, mannitol, propylene glycol, 1,3 butylene glycol, 1, and 4-butanediol, picolinic acid sodium, lactic acid, sodium lactate, Polyethylene Glycol etc. are widely used in the wetting agent in the cosmetics.Said antiseptic for example can use alkyl paraben, sodium benzoate, potassium sorbate etc. to be widely used in antiseptic in the cosmetics.Said medicament can use for example vitamins, crude drug class, antibiotic medicine, antibacterial etc. to be widely used in medicament in the cosmetics.Said UV absorbent can use for example salicylic acid UV absorbent, cinnamic acid UV absorbent, benzophenone UV absorbent etc. to be widely used in UV absorbent in the cosmetics.

Said pigment can use tar colorant, natural pigment etc. to be widely used in pigment in the cosmetics.

Said inorganic salt or organic salt can be enumerated the salt of mineral acids such as hydrochloric acid, sulphuric acid, nitric acid; Hydroxy carboxylic acid such as citric acid, tartaric acid, lactic acid, malic acid, the salt of carboxylic acids such as formic acid, acetic acid, sorbic acid, the perhaps alkali metal salt of aromatic carboxylic acid such as salicylic acid, benzoic acid, alkaline-earth metal or aluminum salt.

These inorganic salts or organic salt both can be sneaked in the cosmetics composition with the state of salt, also can add stoichiometric respective acids material or alkaloid substance according to giving birth to salifiable requirement when making cosmetics.

The water that can mix in addition, any amount.

Cosmetics for skin of the present invention can also for example can be made basic cosmetics such as astringent, emulsion, cream according to the conventional method manufacturing except adopting the method manufacturing of mixing as the powder of above-mentioned neccessary composition; White lead, solid white lead, face with powder, foundation cream, the oil end, the frost end, liquid at the bottom of, makeups such as covering agent, lipstick, lip pomade, rouge, informer, eye shadow, blue eye shadow apply some make up etc.

Below enumerate embodiment the present invention is further elaborated, but the present invention is not subjected to the restriction of these embodiment.In following embodiment, the numerical value that mean diameter is to use SK Laser Particle degree meter (セ イ シ Application enterprise system) wet method to measure, volume cumulative mean particle diameter are to measure the numerical value that mean diameter is obtained by calculating afterwards.

Test example 1

On the black synthetic leather, evenly be coated with 8mg/100cm ²Powder, use angle spectral photometry system (color technical research institute system in the village, GCMS-3 type) to be subjected to the firing angle colour examining along 45 ° of angle of incidence and-45 ° and-20 °.Obtain two interference colours (L according to above-mentioned formula _45.45*, a _45.45*, b _45.45*) and (L _45.20*, a _45.20*, b _45.20*) aberration (Δ E).The results are shown among the table 1.

Table 1

The powder title	Manufacturer	Mean diameter (μ m)	ΔE
				Timiron super copper Timiron super violet Timiron super blue Timiron super green Timiron super red Duocrome YG Duocrome BR Flamenco blue Flamenco violet Flamenco satin blue Flamenco satin violet Flamenco satin green Flamenco satin red	The メ Le Network メ of the society Le Network メ of the society Le Network メ of the society Le Network メ of the society Le Network マ of the society-マ of Le society-マ of Le society-マ of Le society-マ of Le society-マ of Le society-マ of the Le society-マ of Le society-Le society	23.2 23.0 23.8 23.0 23.2 21.1 20.7 20.3 20.6 7.5 7.5 7.8 7.4	63.4 61.6 60.2 56.4 53.5 56.8 47.7 61.0 58.3 32.3 27.5 20.3 28.1

Embodiment 1 (foundation cream)

(composition) (% when weighing)

(1) Muscovitum 41.45

(2) nylon powder 10

(3) the red pearling agent (マ-system Flamenco of Le society

SATIN Orange，ΔE＝31.7) 5

(4) Pulvis Talci 20

(5) titanium oxide 10

(6) iron oxide red 0.8

(7) yellow ferric oxide 2.5

(8) ferroso-ferric oxide 0.1

(9) liquid paraffin 8

(10) Cera Flava 2

(11) antiseptic 0.05

(12) spice 0.1

Add up to 100.00

(method for making)

After the mixing pulverizing of composition (1)～(8), transfer in the high-speed mixer, be incorporated in the material that 80 ℃ of following mixed dissolution compositions (9)～(11) obtain afterwards again, uniform mixing.In this mixture, add composition (12), pulverize it again after the mixing, sieve.In metalware with its compression molding.

Reference examples 1 (foundation cream)

Among the embodiment 1, replace outside the composition (3) except using red pearling agent (the system Timiron Super Red of メ Le Network society, Δ E=53.5), all the other are operated equally, have made foundation cream.

Embodiment 2 (the frost end)

(composition) (weight %)

(1) stearic acid 5.5

(2) the lipophilic glyceryl monostearate 2.5

(3) cetostearyl alcohol 1

(4) single lauryl propylene glycol 3

(5) three decanes 7

(6) olive oil 8

(7) Purified Water surplus

(8) antiseptic 0.4

(9) triethanolamine 1.2

(10) Sorbitol 3

(11) titanium oxide 10

(12) Pulvis Talci 5

(13) coloring pigment (ferroso-ferric oxide-iron oxide red-yellow ferric oxide) 8

(14) blueness through hydrophobic treatment is pearling agent (マ-Le society system, Flamenco

The product that SATIN Blue handles through dimethyl polysiloxane,

ΔE＝26.5) 5

(15) spice 0.1

Add up to 100.0

(method for making)

Pulverizing is mixed in composition (11)～(14).Preparation is mixed with the solution of water-phase component (7)～(10) in addition, add after pulverizing the pigment redispersion it, in 75 ℃ of heating down.To join previously prepared aqueous phase while stirring in oil-phase component (1)～(6) of 80 ℃ of following heating for dissolving and make it emulsifying.Cooling under agitation, 50 ℃ add composition (15) down, and cooling obtains finished product while stirring.

Reference examples 2 (the frost end)

Among the embodiment 2, be that pearling agent (メ Le Network society system, TimironSuperBlue handles through dimethyl polysiloxane, Δ E=55.7) replaces outside the composition (14) except using the blueness through hydrophobic treatment, all the other are operated equally, have made the white end.

Embodiment 3 (foundation cream white lead)

(composition) (weight %)

(1) Muscovitum 51.04

(2) violet pearling agent (マ-Le society system, Flamenco

SATIN Violet，ΔE＝27.5) 8

(3) Pulvis Talci 30

(4) titanium oxide 0.5

(5) iron oxide red 0.1

(6) yellow ferric oxide 0.1

(7) ferroso-ferric oxide 0.01

(8) magnesium stearate 10

(9) antiseptic 0.2

(10) spice 0.05

Add up to 100.00

(method for making)

After the mixing pulverizing of composition (1)～(8), transfer in the high-speed mixer, be incorporated in the material that 80 ℃ of following mixed dissolution compositions (9)～(10) obtain afterwards again, pulverize it again behind the uniform mixing, sieve, obtain finished product.

Reference examples 3 (foundation cream white lead)

Except using violet pearling agent (マ-Le society system, Flamenco purple, Δ E=58.3) to replace having made the foundation cream white lead equally outside the composition (2) among the embodiment 3.

Test example 2

Estimated the cosmetics for skin that obtains in embodiment 1～3 and the reference examples 1～3, be coated on it on skin after, estimate its transparent feel, the colour of skin size with the variation of mirror viewing angle, the good situation of color, dazzling degree and covering power.By 14 special judges by the marking of following standard rating: good 5 minutes, better 4 minutes, general 3 minutes, differed from bad 1 minute, and calculate the meansigma methods of 14 marking slightly 2 fens.The result is as shown in table 2.

Table 2

Assessment item	Embodiment			Comparative example
							1	2	3	1	2	3
	The transparent feel colour of skin is with the dazzling sense degree of the variation color situation covering power of mirror viewing angle	4.1 4.7 4.8 4.7 4.0	4.8 4.5 3.0 4.8 4.0	4.8 4.7 3.0 4.7 4.0	1.5 1.6 1.3 0.9 3.5	1.5 1.0 1.5 0.7 3.2							1.5 1.2 1.5 0.9 3.4

The result of table 2 shows no matter be coated with which kind of cosmetics of the present invention, has transparent feel height, color do not change and can bring into play various light with observed direction color characteristic.In addition, can fix naturally, (covering property) is also good for covering power.

Embodiment 4 (solid white lead)

(composition) (weight %)

(1) Muscovitum 19.04

(2) through pearling agent (マ-Le society system, the Flamenco of hydrophobic treatment

The product that SATIN Violet handles through dimethyl polysiloxane and

マ-Le society system, FlamenoSATIN Green is through dimethyl

The equal amount of mixture of the product that polysiloxanes is handled, Δ E=26.0) 50

(3) Pulvis Talci 20

(4) titanium oxide 0.5

(5) iron oxide red 0.1

(6) yellow ferric oxide 0.1

(7) ferroso-ferric oxide 0.01

(8) liquid paraffin 8

(9) Cera Flava 2

(10) antiseptic 0.2

(11) spice 0.05

Add up to 100.00

(method for making)

After composition (1)～(7) mix are pulverized, transfer in the high-speed mixer, be incorporated in the material that 80 ℃ of following mixed dissolution compositions (8)～(10) obtain afterwards again, uniform mixing it.In this mixture, add composition (11), pulverize again after the mixing, sieve.With its compression molding in the metal ware.

Embodiment 5 (rouge)

(composition) (weight %)

(1) Muscovitum 39.75

(2) through pearling agent (マ-Le society system, the Flamenco of hydrophobic treatment

The product that SATIN Red handles through N-lauroyl lysine and

マ-Le society system, FlamenoSATIN Orange is through the N-lauroyl

The amount mixture of the product that base lysine is handled, Δ E=20.0) 20

(3) Pulvis Talci 20

(4) titanium oxide 4

(5) zinc stearate 5

(6) rice starch 5

(7) coloured material 3

(8) liquid paraffin 3

(9) antiseptic 0.2

(10) spice 0.05

Add up to 100.00

(method for making)

Composition (1)～(7) are mixed color development.Add composition (8)～(10) and mix homogeneously with spray pattern then in high-speed mixer, the back of sieving uses press to compress curing in the metal ware.

Embodiment 6 (eye shadow)

(composition) (weight %)

(1) Muscovitum 44.27

(2) through the royal purple colour system pearling agent of hydrophobic treatment (マ-Le society system,

The product that Flamenco SATIN Blue handles through dimethyl polysiloxane

And マ-Le society system, FlamenoSATIN Violet is through dimethyl

The equal amount of mixture of the product that polysiloxanes is handled, Δ E=24.3) 20

(3) Pulvis Talci 5

(4) mica titanium 5

(5) zinc stearate 5

(6) Dodecanoic acid, zinc salt 3

(7) coloring pigment (ferroso-ferric oxide, iron oxide red, yellow ferric oxide) 10

(8) liquid paraffin 7.5

(9) antiseptic 0.2

(10) spice 0.03

Add up to 100.00

(method for making)

Composition (1)～(7) are mixed color development.Add composition (8)～(10) and mix homogeneously with spray pattern then in mixer, the back of sieving uses press to compress curing in the metal ware.

Embodiment 7 (lipstick)

(composition) (weight %)

(1) titanium oxide 1.71

(2) red No. 201 1

(3) red No. 202 2

(4) yellow No. 4 aluminates 1

(5) red No. 223 0.1

(6) through red colour system pearling agent (マ-Le society system, the Flamenco of hydrophobic treatment

SATIN Orange handles through dimethyl polysiloxane, Δ E=27.5) 5

(7) Oleum Ricini 46.9

(8) octyldodecanol 15

(9) lanoline 5

(10) liquid lanolin 5

(11) Cera Flava 5

(12) ceresine 4

(13) candelilla wax 7

(14) Brazil wax 1

(15) antioxidant 0.05

(16) antiseptic 0.2

(17) spice 0.04

Add up to 100.00

(method for making)

With mix homogeneously behind composition (7)～(14) heating and melting.To wherein add (1)～(6), in three-stage roll mill, knead make it to be uniformly dispersed after, make it to melt again, and then add (15)～(17), inject mould behind the froth breaking and make it quenching and solidify.From mould, take out solidfied material and place container.After then putting the charge bar outward appearance in order, in flame, pass through, make its surface evenly.

Embodiment 8 (informer)

(composition) (weight %)

(1) Brazil wax 5

(2) Cera Flava 1

(3) microwax 10

(4) white vaseline 1

(5) the mobile isoparaffin 67.48 of lightweight

(6) organobentonite 0.5

(7) blueness through hydrophobic treatment is pearling agent (マ-Le society system, Flamenco

SATIN Blue handles through N-lauroyl lysine, Δ E=31.9) 10

(8) titanium oxide 3

(9) white carbon black 2

(10) antioxidant 0.02

Add up to 100.00

(method for making)

In part composition (5), add (6), use colloid mill to make it dispersion, gelation.In addition composition (1)～(4) are mixed with composition (10), heating makes it to melt, and adds composition (7)～(9), the cooling back uses three-stage roll mill to knead, in the process that heating makes it to melt, add bentonite gel and remaining composition (5) once more, cool off while stir.

Embodiment 9 (oil/water-type cream)

(composition) (weight %)

(1) Cera Flava 5.5

(2) hexadecanol 4.5

(3) the hydrogenation lanoline 7

(4) three decanes 33

(5) tristerin 3.5

(6) the lipophilic glyceryl monostearate 2

(7) Tween-20 (20E.O.) 2

(8) royal purple colour system pearling agent (マ-Le society system, Flamenco SATIN Blue

Through the product and the マ-Le society system of dimethyl polysiloxane processing,

The product that FlamenoSATIN Violet handles through dimethyl polysiloxane

Equal amount of mixture, Δ E=24.3) 2

(9) spice 0.1

(10) antiseptic 0.2

(11) antioxidant 0.1

(12) propylene glycol 10

(13) Purified Water surplus

Add up to 100.00

(method for making)

Composition (8), (10), (12) and (13) are mixed, remain under 80 ℃.Mix other compositions then, heating for dissolving makes it to be under 80 ℃.In this oil phase part, add above-mentioned water and make it emulsifying in advance, after the emulsifying evenly of use homogenizer, be cooled to 30 ℃, obtain finished product.

The cosmetics for skin that obtains in embodiment 4～9 all is strong the fixing naturally of transparent feel, and any its color does not change with observed direction, and can both make the color and luster of skin feel to change.

Embodiment 10～13 (foundation cream)

Method has been made the foundation cream of forming shown in the table 3 similarly to Example 1.

Table 3

Composition (weight %)	Embodiment 10	Embodiment 11	Embodiment 12	Embodiment 13
					(1) Muscovitum	36.5	36.5	36.5	36.5
(2) nylon powder	10	10	10	10
					(3) violet pearling agent (マ-ル She System, Flamenco satin violet; Δ E=27.5)	10	0	0	0
(4) the violet pearling agent of hydrophobization processing (handling the product that (3) obtain, Δ E=26.0) with dimethyl polysiloxane	0	10	0	0
					(5) red colour system pearling agent (マ-ル She System, Flamenco satin red; Δ E=28.1	0	0	10	0
(6) the red colour system pearling agent of hydrophobization processing (is handled the product that (4.) obtain, Δ E=27.4 with N-lauroyl lysine	0	0	0	10
					(7) Pulvis Talci	20	20	20	20
(8) titanium oxide	10	10	10	10
					(9) iron oxide red	0.8	0.8	0.8	0.8
(10) yellow ferric oxide	2.5	2.5	2.5	2.5
					(11) ferroso-ferric oxide	0.1	0.1	0.1	0.1
(12) liquid paraffin	8	8	8	8
					(13) Cera Flava	2	2	2	2
(14) antiseptic	0.1	0.1	0.1	0.1
					Total amount	100	100	100	100
Aberration before and after the exposure	1.3	0.8	1.2	0.7

Test example 3 (light exposure test)

The pearling agent that uses among the foundation cream of embodiment 10～13 preparation and the embodiment 10～13 is pressurizeed in the metal ware of 5 centimetres of diameters respectively, and use colour difference meter (CM-1000 type, ミ ノ Le society system) to measure (condition determination d-0 ℃) outward appearance color.Use natural light to be exposed to accumulation illumination 100,000 J/m then ²(confirming) through the accumulation illumination meter, and then use same colour difference meter colour examining, calculate the aberration of exposure front and back.The results are shown among table 3 and 4.

Table 4

The pearling agent substance	Aberration before and after the substance exposure
		Violet pearling agent (real is executed example 10)	9.0
The violet pearling agent (real that hydrophobization is handled is executed example 11)	7.0
		Red colour system pearling agent (real is executed example 12)	6.5
The red colour system pearling agent (real that hydrophobization is handled is executed example 13)	5.0

From table 3 and 4 as can be known, and without the comparing of hydrophobic treatment, all being difficult to variation through the powder of hydrophobic treatment or the foundation cream appearance color that is mixed with through the hydrophobic treatment powder, and light resistance is good.

Embodiment 14 (foundation cream)

Made shown in the table 5 foundation cream of forming in accordance with the following methods, and estimated the situation of fixing and cosmetic maintenance situation when using these foundation creams according to following method.These results are shown among the table 5 together.

(method for making)

Blending constituent (1)～(5) make it to pulverize by pulverizer.It is moved in high-speed mixer the added 80 ℃ of following mixed dissolutions again mixture of composition (16)～(19), mix homogeneously.In this mixture, add composition (20), pulverize once more after the mixing, sieve.Make it press molding in the metal ware.

(evaluation methodology)

According to following standard, by 10 special assessment officers, just the use feeling when being coated with foundation cream on the face (harsh feeling, rough sense, whether the tack and ductility on dry linting, the skin) and makeup (makeup have transparent feel, skin color with minute surface viewing angle different become, the fineness of the having or not of color situation, dazzling sensation, covering power and makeup) situation, carry out sensory evaluation.

Evaluation criterion:

◎: answer good more than 7

Answer good for zero: 4～6

△: answer good for 2～3

*: answer good below 1.

Embodiment 15 (foundation cream white lead)

Prepared the white lead of forming shown in the table 5 in accordance with the following methods, use feeling and makeup situation during for these white lead of use have been carried out the evaluation of mode similarly to Example 14.These results are shown among the table 5 together.

(method for making)

Mix whole compositions, use pulverizer to pulverize, obtain product after sieving.

Table 5

(weight %)

* 1: マ-Le society system, the product that Flamenco SATIN Orange handles through dimethyl polysiloxane

* 2: the product that the system Timiron Super Red of メ Le Network society handles through dimethyl polysiloxane

* 3: マ-Le society system, the product that Flamenco SATIN Violet handles through dimethyl polysiloxane

* 4: the system Timiron Super Violet of メ Le Network society handles the product that obtains through dimethyl polysiloxane.

Implement system 16 (solid white lead)

Make the solid white lead of following composition as follows.

(composition) (weight %)

(1) Muscovitum 13.04 of silicone covering

(2) the mixed bead photo etching (Δ E=26.0) crossed of hydrophobic treatment ^{* 1}50.0

(3) the monodisperse spherical powder of volume cumulative mean particle diameter 0.5 μ m

(polymethyl methacrylate, PMMA, coefficient of variation 4%) 6.0

(4) Pulvis Talci 20.0 of silicone covering

(5) titanium oxide 0.5 of silicone covering

(6) iron oxide red 0.1 of silicone covering

(7) yellow ferric oxide 0.1 of silicone covering

(8) ferroso-ferric oxide 0.01 of silicone covering

(9) liquid paraffin 8.0

(10) Cera Flava 2.0

(11) antiseptic 0.2

(12) spice 0.05

Add up to 100.00

* 1: the equal amount of mixture of the product that マ-system Flamenco SATIN Violet of Le society and FlamenoSATIN Green handled through dimethyl polysiloxane respectively.

(method for making)

Composition (1)～(8) are mixed, use pulverizer to pulverize.It is moved in high-speed mixer the added 80 ℃ of following mixed dissolutions again mixture of composition (9)～(11), mix homogeneously.In this mixture, add after composition (12) mixes, again crushing screening.Make its compression molding in the metal ware.

Embodiment 17 (rouge)

Utilize following method to make rouge with following composition.

(composition) (weight %)

(1) Muscovitum 32.75 of silicone covering

(2) the mixture of red colour system pearling agent (Δ E=20.0) crossed of hydrophobic treatment ^{* 1}20.0

(3) Pulvis Talci 20.0 of silicone covering

(4) the monodisperse spherical powder of volume cumulative mean particle diameter 0.5 μ m

(silicon oxide, coefficient of variation 4%) 7.0

(5) titanium oxide 4.0 of silicone covering

(6) zinc stearate 5.0 of silicone covering

(7) rice starch 5.0

(8) coloured material 3.0

(9) liquid paraffin 3.0

(10) antiseptic 0.2

(11) spice 0.05

Add up to 100.00

* 1: the equal amount of mixture of the product that マ-system Flamenco SATIN Red of Le society and FlamenoSATIN Orange handled through N-lauroyl lysine respectively.

(method for making)

Composition (1)～(8) are mixed color development.After then in mixer, adding composition (9)～(11) with spray pattern, mix homogeneously.The back use press that sieves compresses curing in the metal ware.

Embodiment 18 (eye shadow)

Utilize following method to make eye shadow with following composition.

(composition) (weight %)

(1) Muscovitum of handling through fluorine compounds 37.75

(2) the livid purple colour system pearling agent of mixing (Δ E=20.0) crossed of hydrophobic treatment ^{* 1}20.0

(3) Pulvis Talci of handling through fluorine compounds 5.0

(4) the monodisperse spherical powder of volume cumulative mean particle diameter 0.5 μ m

(silicon oxide system complex oxide, coefficient of variation 4%) 7.0

(5) mica titanium of handling through fluorine compounds ^{* 2}5.0

(6) through fluorine compounds handle zinc stearate ^{* 2}5.0

(7) Dodecanoic acid, zinc salt of handling through fluorine compounds ^{* 2}3.0

(8) coloring pigment (ferroso-ferric oxide, iron oxide red, yellow ferric oxide) 10.0

(9) liquid paraffin 7.0

(10) antiseptic 0.2

(11) spice 0.05

Add up to 100.00

* 1: the equal amount of mixture of the product that マ-system Flamenco SATIN Blue of Le society and FlamenoSATIN Violet handled through dimethyl polysiloxane respectively

* 2: open the material that the Production Example 1 in flat 5-58841 number was handled equally with the spy.

The cosmetics for skin that obtains in embodiment 16～18 all is strong the fixing naturally of transparent feel, and any its color does not change with observed direction, and can both make the color and luster of skin feel to change.In addition, tack on skin and ductility are also all splendid.

Embodiment 19 (foundation cream)

Made shown in the table 6 foundation cream of forming according to the method for following record, the makeup when using these foundation creams and hold the woman's persona situation adopts following evaluation methodology to estimate.Its result is shown among the table 6 in the lump.

(method for making)

Composition (1)～(11) are mixed, use pulverizer to pulverize.It is moved in high-speed mixer the added 80 ℃ of following mixed dissolutions again mixture of composition (12)～(14), mix homogeneously.In this mixture, add after composition (15) mixes, again crushing screening.With its compression molding in the metal ware.

(evaluation methodology)

The good situation of transparent feel when coating various foundation creams on the skin, situation that skin color changes with the minute surface observation angle, color, whether dazzling, covering power and the woman's persona situation of holding after 4 hours have been estimated.Said evaluation is undertaken by special assessment officer, projects all " well " be chosen as 5 fens, " good slightly " be chosen as 4 fens, " generally " be chosen as 3 fens, " poor slightly " be chosen as 2 fens, " poor " be chosen as 1 fen, and show its meansigma methods.

Table 6

(weight %)

		Embodiment	Reference examples
						19	8	9	10
		Form	(1) Muscovitum (2) nylon powder (3) red colour system pearling agent (Δ E=31.7) *1(4) red colour system pearling agent (Δ E=53.5) *2(5) Pulvis Talci (6) zinc oxide (specific surface area 50m 2/g) *3(7) zinc oxide (specific surface area 43m 2/g) *4(8) titanium oxide (9) (10) iron oxide red (11) yellow ferric oxide (12) atoleine (13) beeswax (14) anticorrisive agent (15) spices	37.35 10.0 5.0 - 20.0 4.0 - 10.0 0.8 2.5 0.1 8.0 2.0 0.2 0.05	37.35 10.0 - 5.0 20.0 4.0 - 10.0 0.8 2.5 0.1 8.0 2.0 0.2 0.05					37.35 10.0 5.0 - 20.0 - 4.0 10.0 0.8 2.5 0.1 8.0 2.0 0.2 0.05	37.35 10.0 - 5.0 20.0 - 4.0 10.0 0.8 2.5 0.1 8.0 2.0 0.2 0.05
Estimate	The transparent feel colour of skin is insisted on woman's persona with the covering that has or not of the dazzling sense of variation color situation of mirror viewing angle					4.1 4.7 4.8 4.7 4.0 4.5	1.5 1.6 1.3 0.9 3.5 4.2	4.1 4.5 4.7 4.5 3.8 2.5	1.5 1.8 1.5 1.2 4.0 2.0

* 1: マ-Le society system, the product that Flamenco SATIN Orange handles through dimethyl polysiloxane

* 2: メ Le Network society system, the product that Timiron Super Red handles through dimethyl polysiloxane

* 3: Sakai chemical industry society system, FINEX-50

* 4: Sakai chemical industry society system, Pharmacopeia of Japan records product.

As table 6 show, be coated with under the situation of cosmetics for skin of the present invention, any all have a color characteristic that transparent feel is strong, color does not change and can bring into play various light with observed direction.In addition, be a kind of natural makeup that does not have dazzling sense, and covering power and to hold woman's persona property also good.

Embodiment 20 (the frost end)

(composition) (weight %)

(1) stearic acid 5.5

(2) the lipophilic glyceryl monostearate 2.5

(3) cetostearyl alcohol 1.0

(4) single lauryl propylene glycol 3.0

(5) three decanes 7.0

(6) olive oil 8.0

(7) Purified Water surplus

(8) antiseptic 0.4

(9) triethanolamine 1.2

(10) Sorbitol 3.0

(11) titanium oxide 8.0

(12) Pulvis Talci 5.0

(13) coloring pigment (ferroso-ferric oxide-iron oxide red-yellow ferric oxide) 8.0

(14) zinc oxide (specific surface area 25m ²/ g) ^{* 1}4.0

(15) blueness of hydrophobic treatment is pearling agent (Δ E=26.5) ^{* 2}5.0

(16) spice 0.1

Add up to 100.0

* 1: Sakai chemical industry society system, FINEX-50

* 2: マ-Le society system, the product that Flamenco SATIN Blue handles through dimethyl polysiloxane.

(method for making)

Composition (11)～(15) are mixed, pulverize with pulverizer.Preparation is mixed with the solution of water-phase component (7)～(10) in addition, add after pulverizing the pigment redispersion it, in 75 ℃ of heating down.To join previously prepared aqueous phase while stirring in oil-phase component (1)～(6) that 80 ℃ of following heating are dissolved and make it emulsifying.Cooling under agitation, 50 ℃ add composition (16) down, and cooling obtains finished product while stirring.

Embodiment 21 (foundation cream white lead)

Make the foundation cream white lead of following composition as follows.

(composition) (weight %)

(1) Muscovitum 46.09

(2) violet pearling agent (Δ E=27.5) ^{* 1}8.0

(3) zinc oxide (specific surface area 75m ²/ g) ^{* 2}5.0

(4) Pulvis Talci 30.0

(5) titanium oxide 0.5

(6) iron oxide red 0.1

(7) yellow ferric oxide 0.1

(8) ferroso-ferric oxide 0.01

(9) magnesium stearate 10.0

(10) antiseptic 0.2

Add up to 100.00

* 1: マ-Le society system, Flamenco SATIN Violet

* 2: Sakai chemical industry society system, FINEX-75

(method for making)

Whole compositions are mixed, use the pulverizer grinding and sieving, obtain finished product.

Embodiment 22 (solid white lead)

The solid white lead that has prepared following composition according to following method.

(composition) (weight %)

(1) Muscovitum 13.04

(2) through the mixed bead photo etching (Δ E=26.0) of hydrophobic treatment ^{* 1}50.0

(3) zinc oxide (specific surface area 50m ²/ g) ^{* 2}6.0

(4) Pulvis Talci 20.0

(5) titanium oxide 0.5

(6) iron oxide red 0.1

(7) yellow ferric oxide 0.1

(8) ferroso-ferric oxide 0.01

(9) liquid paraffin 8.0

(10) Cera Flava 2.0

(11) antiseptic 0.2

(12) spice 0.05

Add up to 100.00

* 1: the equal amount of mixture of the product that マ-system Flamenco SATIN Violet of Le society and FlamenoSATIN Green handle through dimethyl polysiloxane respectively,

* 2: Sakai chemical industry society system, FINEX-50.

(method for making)

Composition (1)～(8) are mixed, after pulverizing with pulverizer, transfer in the high-speed mixer, be incorporated in the mixture that 80 ℃ of following mixed dissolution compositions (9)～(11) obtain afterwards again, uniform mixing it.In this mixture, add composition (12), pulverize again after the mixing, sieve.With its compression molding in the metal ware.

Embodiment 23 (rouge)

Utilize following method to make rouge with following composition.

(composition) (weight %)

(1) Muscovitum 32.75

(2) the different photo etching of mixture of red colour system (Δ E=20.0) of hydrophobic treatment ^{* 1}20.0

(3) Pulvis Talci 20.0

(4) zinc oxide (specific surface area 25m ²/ g) ^{* 2}7.0

(5) titanium oxide 4.0

(6) zinc stearate 5.0

(7) rice starch 5.0

(8) coloured material 3.0

(9) liquid paraffin 3.0

(10) antiseptic 0.2

(11) spice 0.05

Add up to 100.00

* 1: the equal amount of mixture of the product that マ-system Flamenco SATIN Red of Le society and FlamenoSATIN Orange handled through N-lauroyl lysine respectively

* 2: Sakai chemical industry society system, FINEX-25.

(method for making)

Composition (1)～(8) are mixed color development.Then in mixer, add back, composition (9)～(11) mix homogeneously with spray pattern.After sieving, use press in the metal ware, its compression to be solidified.

Embodiment 24 (eye shadow)

Utilize following method to make eye shadow with following composition.

(composition) (weight %)

(1) Muscovitum 37.75

(2) the mixing royal purple colour system pearling agent (Δ E=24.3) crossed of hydrophobic treatment ^{* 1}20.0

(3) Pulvis Talci 5.0

(4) zinc oxide (specific surface area 75m ²/ g) ^{* 2}7.0

(5) mica titanium 5.0

(6) zinc stearate 5.0

(7) Dodecanoic acid, zinc salt 3.0

(8) coloring pigment (ferroso-ferric oxide, iron oxide red, yellow ferric oxide) 10.0

(9) liquid paraffin 7.0

(10) antiseptic 0.2

(11) spice 0.05

Add up to 100.00

* 1: the equal amount of mixture of the product that マ-system Flamenco SATIN Blue of Le society and FlamenoSATIN Violet handled through dimethyl polysiloxane respectively

* 2: Sakai chemical industry society system, FINEX-75.

(method for making)

Made the purpose eye shadow according to method similarly to Example 23.

Embodiment 25 (lipstick)

Made lipstick in accordance with the following methods with following composition.

(composition) (weight %)

(1) titanium oxide surplus

(2) red No. 201 1.0

(3) red No. 202 2.0

(4) yellow No. 4 aluminates 1.0

(5) red No. 223 0.1

(6) through the red colour system pearling agent (Δ E=27.5) of hydrophobic treatment ^{* 1}5.0

(7) through zinc oxide (the specific surface area 25m of hydrophobic treatment ²/ g) ^{* 2}4.0

(8) Oleum Ricini 44.0

(9) octyldodecanol 15.0

(10) lanoline 5.0

(11) liquid paraffin 5.0

(12) Cera Flava 5.0

(13) ceresine 4.0

(14) candelilla wax 7.0

(15) Brazil wax 1.0

(16) antioxidant is an amount of

(17) antiseptic is an amount of

(18) spice trace

Add up to 100.0

* 1: the product that マ-the system Flamenco SATIN Orange of Le society handles through dimethyl polysiloxane

* 2: the product that the system FINEX-25 of Sakai chemical industry society handles through dimethyl polysiloxane.

(method for making)

With mix homogeneously behind composition (8)～(15) heating and melting.To wherein add (1)～(7), in three-stage roll mill, knead make it to be uniformly dispersed after, make it to melt again, and then add (16)～(18), inject mould behind the froth breaking and make it quenching and solidify.Taking out solidfied material from mould is filled in the container.After then putting the charge bar outward appearance in order, in flame, pass through, make its surface evenly.

Embodiment 26 (informer)

Made the informer of following composition in accordance with the following methods.

(composition) (weight %)

(1) Brazil wax 5.0

(2) Cera Flava 1.0

(3) microwax 10.0

(4) white vaseline 1.0

(5) organobentonite 0.5

(6) the mobile isoparaffin 62.48 of lightweight

(7) blueness through hydrophobic treatment is pearling agent (Δ E=31.9) ^{* 1}10.0

(8) zinc oxide (the specific surface area 50m of hydrophobic treatment ²/ g) ^{* 2}5.0

(9) titanium oxide 3.0

(10) white carbon black 2.0

(11) antioxidant 0.002

Add up to 100.00

* 1: the product that マ-the system Flamenco SATIN Blue of Le society handles through dimethyl polysiloxane

* 2: the product that the system ZnO-350 of Sumitomo, Osaka cement society handles through dimethyl polysiloxane.

(method for making)

In part composition (6), add (5), use colloid mill to make it dispersion, gelation.In addition composition (1)～(4) are mixed with composition (11), heating makes it to melt, and adds composition (7)～(10), the cooling back uses three-stage roll mill to knead, in the process that heating makes it to melt, add bentonite gel and remaining composition (6) once more, cool off while stir.

Embodiment 27 (oil/water type cream)

Made the oil/water type cream of following composition in accordance with the following methods.

(composition) (weight %)

(1) Cera Flava 5.5

(2) hexadecanol 4.5

(3) the hydrogenation lanoline 7.0

(4) three decanes 33.0

(5) fatty glyceride 3.5

(6) the lipophilic glyceryl monostearate 2.0

(7) polyoxyethylene (20) Span-20 2.0

(8) through the mixing royal purple colour system pearling agent (Δ E=24.3) of hydrophobic treatment ^{* 1}4.0

(9) zinc oxide (specific surface area 50m ²/ g) ^{* 2}4.0

(10) spice 0.1

(11) antiseptic 0.2

(12) antioxidant 0.1

(13) propylene glycol 10.0

(14) Purified Water surplus

Add up to 100.00

* 1: the equal amount of mixture of the product that マ-system Flamenco SATIN Blue of Le society and FlamenoSATIN Violet handle through dimethyl polysiloxane

* 2: the system ZnO-350 of Sumitomo, Osaka cement society.

(method for making)

Composition (8), (9), (11), (12) and (14) are mixed, remain under 80 ℃.Mix other compositions then, heating is dissolved, and makes it to be under 80 ℃.In this oil phase part, add above-mentioned water and make it pre-emulsifying, after the emulsifying evenly of use homogenizer, be cooled to 30 ℃, obtain finished product.

The cosmetics for skin that obtains among the embodiment 20～27, any all is the strong natural makeup of transparent feel, color does not change with observed direction, and the color and luster of skin is changed.And it is also good to hold woman's persona property.

Production Example 1

Ferrum oxide and titanium oxide are pressed 3: 7 weight ratio mix homogeneously, and 700 ℃ of sintering temperatures were pulverized after 2 hours in atmosphere, had obtained a kind of red pigment.

Production Example 2

Ferrum oxide and titanium oxide are pressed 2: 8 weight ratio mix homogeneously, and 800 ℃ of sintering temperatures were pulverized after 10 hours in atmosphere, had obtained a kind of pigment of skin color.

Production Example 3

Ferrous oxide, titanium oxide and iron powder by 9: 10: 1 weight ratio mix homogeneously, are pulverized after 16 hours in the atmosphere behind the nitrogen replacement and 1100 ℃ of sintering temperatures, obtained a kind of black pigment.

Embodiment 28 (foundation cream)

Made in accordance with the following methods and had shown in the table 7 foundation cream of forming, the makeup when using these foundation creams and hold the woman's persona situation and evaluate according to following method, evaluation result is shown among the table 7 in the lump.

(method for making)

Blending constituent (1)～(10), and make it to pulverize by pulverizer.It is moved in high-speed mixer, be incorporated in the mixture that 80 ℃ of following mixed melting compositions (11)～(13) obtain, and uniform mixing in addition.In this mixture, add composition (14), pulverize it again after the mixing, sieve, make its compression molding in the metal ware.

(evaluation methodology)

Various foundation creams are coated on the skin, estimate its transparent feel, skin color with the having or not of the variation of minute surface viewing angle, the good degree of color, dazzling sense, covering power with hold woman's persona after 4 hours.Evaluation is undertaken by 14 special judges, and projects are all by following standard marking: " well " 5 minutes, and " better " 4 minutes, " generally " 3 minutes, " poor slightly " 2 minutes and " poor " 1 minute, shown in the table is its meansigma methods.

Table 7

(weight %)

		Embodiment	Reference examples
						28	11	12	13
		Form	(1) Muscovitum (2) nylon powder (3) red colour system pearling agent (Δ E=31.7) *1(4) red colour system pearling agent (Δ E=53.5) *2(5) red sintering pigment (7) titanium oxide (8) iron oxide red (9) yellow ferric oxide (10) tri-iron tetroxide (11) atoleine (12) beeswax (13) anticorrisive agent (14) spices of talcum powder (6) Production Example 1	40.15 10.0 5.0 - 20.0 2.0 10.0 - 2.5 0.1 8.0 2.0 0.2 0.05	40.15 10.0 - 5.0 20.0 2.0 10.0 - 2.5 0.1 8.0 2.0 0.2 0.05					41.35 10.0 5.0 - 20.0 - 10.0 0.8 2.5 0.1 8.0 2.0 0.2 0.05	41.35 10.0 - 5.0 20.0 - 10.0 0.8 2.5 0.1 8.0 2.0 0.2 0.05
Estimate	The transparent feel colour of skin is insisted on woman's persona with the covering that has or not of the dazzling sense of variation color situation of mirror viewing angle					4.1 4.7 4.8 4.7 4.0 4.5	1.5 1.6 1.3 0.9 3.5 4.2	4.1 4.5 4.7 4.5 3.8 2.5	1.5 1.8 1.5 1.2 4.0 2.0

* 1: the マ-system Flamenco SATIN Orange of Le society

* 2: the system Timiron Super Red of メ Le Network society.

Feature indicated as table 7, after the cosmetics for skin of the present invention coating, anyly have all that transparent feel is strong, color does not change and can bring into play the color of various light with the change of minute surface viewing angle.And be a kind of natural makeup of not having dazzling sense, its covering power and to hold woman's persona property also good.

Embodiment 29 (foundation cream white lead)

Made a kind of white lead in accordance with the following methods with following composition.

(composition) (weight %)

(1) Muscovitum 43.09

(2) violet pearling agent (Δ E=27.5) ^{* 1}8.0

(3) the skin color sintering pigment 8.0 of Production Example 2

(4) Pulvis Talci 30.0

(5) titanium oxide 0.5

(6) iron oxide red 0.1

(7) yellow ferric oxide 0.1

(8) ferroso-ferric oxide 0.01

(9) magnesium stearate 10.0

(10) antiseptic 0.2

Add up to 100.00

* 1: マ-Le society system, Flamenco SATIN Violet

(method for making)

Whole compositions are mixed, use the pulverizer grinding and sieving, obtain finished product.

Embodiment 30 (solid white lead)

The solid white lead that has prepared following composition according to following method.

(composition) (weight %)

(1) Muscovitum 13.04

(2) through the mixed bead photo etching (Δ E=26.0) of hydrophobic treatment ^{* 1}50.0

(3) the skin color sintering pigment 6.0 of Production Example 2

(4) Pulvis Talci 20.0

(5) titanium oxide 0.5

(6) the red sintering pigment 0.1 of Production Example 1

(7) yellow ferric oxide 0.1

(8) ferroso-ferric oxide 0.01

(9) liquid paraffin 8.0

(10) Cera Flava 2.0

(11) antiseptic 0.2

(12) spice 0.05

Add up to 100.00

* 1: the equal amount of mixture of the product that マ-system Flamenco SATIN Violet of Le society and FlamenoSATIN Green handle through dimethyl polysiloxane respectively.

(method for making)

Composition (1)～(8) are mixed, after pulverizing with pulverizer, transfer in the high-speed mixer, be incorporated in the mixture that 80 ℃ of following mixed dissolution compositions (9)～(11) obtain afterwards again, uniform mixing it.In this mixture, add composition (12), pulverize again after the mixing, sieve.With its compression molding in the metal ware.

Embodiment 31 (rouge)

Utilize following method to make rouge with following composition.

(composition) (weight %)

(1) Muscovitum 32.75

(2) the mixture of red colour system pearling agent (Δ E=20.0) of hydrophobic treatment ^{* 1}20.0

(3) Pulvis Talci 20.0

(4) the skin color sintering pigment 7.0 of Production Example 2

(5) titanium oxide 4.0

(6) zinc stearate 5.0

(7) rice starch 5.0

(8) coloured material 3.0

(9) liquid paraffin 3.0

(10) antiseptic 0.2

(11) spice 0.05

Add up to 100.00

* 1: the equal amount of mixture of the product that マ-system Flamenco SATIN Red of Le society and FlamenoSATIN Orange handled through N-lauroyl lysine respectively.

(method for making)

Composition (1)～(8) are mixed color development.Then in mixer, add back, composition (9)～(11) mix homogeneously with spray pattern.After sieving, use press in the metal ware, its compression to be solidified.

Embodiment 32 (eye shadow)

Utilize following method to make eye shadow with following composition.

(composition) (weight %)

(1) Muscovitum 37.75

(2) the mixing royal purple colour system pearling agent (Δ E=24.3) crossed of hydrophobic treatment ^{* 1}20.0

(3) Pulvis Talci 5.0

(4) the skin color sintering pigment 7.0 of Production Example 2

(5) mica titanium 5.0

(6) zinc stearate 5.0

(7) Dodecanoic acid, zinc salt 3.0

(8) coloring pigment (ferroso-ferric oxide, iron oxide red, yellow ferric oxide) 10.0

(9) liquid paraffin 7.0

(10) antiseptic 0.2

(11) spice 0.05

Add up to 100.00

* 1: the equal amount of mixture of the product that マ-system Flamenco SATIN Blue of Le society and FlamenoSATIN Violet handled through dimethyl polysiloxane respectively

(method for making)

According to having made the purpose eye shadow with quadrat method with embodiment 31.

The cosmetics for skin that obtains among the embodiment 29～32, any all is the strong natural makeup of transparent feel, color does not change with observed direction, and the color and luster of skin is changed.And it is also good to hold woman's persona property.

Cosmetics for skin of the present invention, color do not change with observed direction, and the makeup nature has transparent feel, and can make the color and luster of skin feel to change.

Claims (15)

1. a cosmetics for skin is characterized in that wherein containing the powder (A) that aberration (Δ E) equals 7～40, and said aberration is obtained in accordance with the following methods: evenly be coated with 8mg/100cm on the black synthetic leather ²Said powder, when 45 ° of angle of incidence and-45 ° and-20 ° are subjected to the firing angle colour examining, with regard to two interference colours (L of CIE 1976 L*a*b* color specification systems regulation _45.45 ^*, a _45.45 ^*, b _45.45 ^*) and (L _45.20 ^*, a _45.20 ^*, b _45.20 ^*), calculate according to following formula:

Aberration (Δ E)=((L _45.45*-L _45.20*) ²+ (a _45.45*-a _45.20*) ²+

(b _45.45*-b _45.20*) ²) ^0.5；

Wherein powder (A) is the mixture powder coating of mica surface by titanium oxide and ferrum oxide, and the mean diameter of powder (A) is below the 12 μ m.

2. the described cosmetics for skin of claim 1, wherein the mean diameter of powder (A) is 3～12 μ m.

3. the described cosmetics for skin of claim 1, wherein hydrophobic treatment is also passed through on the surface of powder (A).

4. any one described cosmetics for skin in the claim 1～3 is wherein more than the content 0.1 weight % of powder (A).

5. the described cosmetics for skin of claim 1, wherein also containing volume cumulative mean particle diameter is the monodisperse spherical powder (B) of 0.1～2 μ m.

6. the described cosmetics for skin of claim 5, wherein the coefficient of variation of the particle size distribution of powder (B) is below 10%, this coefficient of variation is standard deviation/mean diameter.

7. claim 5 or 6 described cosmetics for skin, wherein the refractive index of powder (B) is 1.0～2.0.

8. any one described cosmetics for skin in the claim 5～7, wherein powder (B) is to handle through surface hydrophobicity.

9. any one described cosmetics for skin in the claim 5～8, wherein the content of powder (B) in cosmetics is 0.5～50 weight %.

10. the described cosmetics for skin of claim 1, wherein also containing specific surface area is 10～100m ²The zinc oxide of/g (C).

11. the described cosmetics for skin of claim 10, wherein said zinc oxide (C) are to handle through surface hydrophobicity.

12. claim 10 or 11 described cosmetics for skin, the content of wherein said zinc oxide (C) in cosmetics is 0.1～99 weight %.

13. the described cosmetics for skin of claim 1 wherein also contains ferrum oxide-titanium oxide sintering colored pigment (D).

14. the described cosmetics for skin of claim 13, wherein said colored pigment (D) are to handle through surface hydrophobicity.

15. claim 13 or 14 described cosmetics for skin, the content of wherein said colored pigment (D) in cosmetics is 0.1～99 weight %.