CN1203196C - End point controlling process for smelting low carbon steel in electric furnace - Google Patents

End point controlling process for smelting low carbon steel in electric furnace Download PDF

Info

Publication number
CN1203196C
CN1203196C CNB02115094XA CN02115094A CN1203196C CN 1203196 C CN1203196 C CN 1203196C CN B02115094X A CNB02115094X A CN B02115094XA CN 02115094 A CN02115094 A CN 02115094A CN 1203196 C CN1203196 C CN 1203196C
Authority
CN
China
Prior art keywords
electric furnace
end point
carbon
controlling process
carbon steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB02115094XA
Other languages
Chinese (zh)
Other versions
CN1451767A (en
Inventor
王中丙
李烈军
付杰
柴毅忠
李绍康
陈学文
钟志永
刘蘅
赵剑峰
张金星
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHUJIANG IRON AND STEEL CO Ltd GUANGZHOU
Original Assignee
ZHUJIANG IRON AND STEEL CO Ltd GUANGZHOU
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ZHUJIANG IRON AND STEEL CO Ltd GUANGZHOU filed Critical ZHUJIANG IRON AND STEEL CO Ltd GUANGZHOU
Priority to CNB02115094XA priority Critical patent/CN1203196C/en
Publication of CN1451767A publication Critical patent/CN1451767A/en
Application granted granted Critical
Publication of CN1203196C publication Critical patent/CN1203196C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)

Abstract

The present invention discloses an end point controlling process for smelting low-carbon steel in an electric furnace, which orderly comprises the following steps: (a) compounding: conventional carbon compounding raw materials are adopted, and the carbon compounding quantity is controlled by 1.0% to 1.8%; (b) the control over C/O ratio: the C/O is controlled through a C-O gun manipulator of a furnace door as follows: at the prior period of smelting, namely that when the temperature is less than 1520 DEG C, the C/O ratio is 1:2; at the intermediate period of smelting, namely that when the temperature is from 1520 DEG C to 1580 DEG C, the C/O ration is 1:1; at the later period of smelting, namely that the temperature is higher than 1580 DEG C, the C/O ratio is 2:1, wherein the unit of C is kg/min, and the unit of O is NM<3>/min; (c) the control over the typical components of foamed slag: CaO/SiO2 is from 2.1 to 3.0, and FeO is from 25% to 30%; (d) tapping: when the a<o> is from 750 to 900 ppm and the temperature is from 1620 DEG C to 1640 DEG C, the tapping can be carried out. The present invention enriches the producing method of low-carbon steel, fills the blank of low-carbon molten steel required by an electric furnace to smelt hot rolling steel coils, provides more process selections for the production of the low-carbon steel and has the advantages of stabile end point controlling process, short smelting time and corresponding reduction of production energy consumption and cost.

Description

The end point controlling process of smelting low carbon steel in electric furnace
Affiliated technical field
The present invention relates to the end point controlling process of smelting low carbon steel in electric furnace, particularly relate to the electrosmelting carbon content below 0.08%, the end point controlling process of the required soft steel of heat supply steel rolling volume.
Background technology
Traditional electrosmelting generally is applicable to carbon content at carbon steel more than 0.1% or steel alloy, adopts converter process to smelt for carbon content usually at the soft steel below 0.08%.
Traditional electric furnace owing to can not accurately control the oxidisability of molten steel, thereby causes the peroxidation of molten steel when the smelting low carbon steel, directly produce following bad result: (1) iron and steel stock recovery rate is low; (2) alloy consumption is big.
Percentage ratio related in this specification sheets is weight percentage.
Summary of the invention
The end point controlling process that the purpose of this invention is to provide a kind of smelting low carbon steel in electric furnace, this technology can adopt electrosmelting go out carbon content below 0.08%, the required low-carbon (LC) molten steel of heat supply steel rolling volume.
In order to achieve the above object, the present invention adopts modern electric furnace to smelt, and can reach high-level efficiency under high oxygen supply intensity, and its oxygen supply intensity is usually at 30NM 3More than/the t, its technical process is: molten steel is molten clear → quantitatively control C/O ratio → foamy slag → decide a [o], C → thermometric → tapping, the key of this flow process is a [o]Control.The present invention is by the blowing oxygen quantity and the C/O ratio of quantitative control molten steel, and a of detection by quantitative molten steel [o]And temperature, to realize the terminal point control of smelting low carbon steel in electric furnace.
The end point controlling process of smelting low carbon steel in electric furnace of the present invention may further comprise the steps successively:
(a) batching: select conventional mixed carbon raw material for use, make mixed carbon comtent be controlled at 1.0~1.8%.
(b) control C/O ratio: C/O is carried out following control by fire door C-O rifle mechanical manipulator:
In melting early stage, promptly temperature below 1520 ℃ the time, C/O=1: 2.
In melting mid-term, promptly temperature in the time of 1520 ℃~1580 ℃, C/O=1: 1.
In the melting later stage, promptly temperature more than 1580 ℃ the time, C/O=2: 1.
Wherein, the unit of C is kg/min, and the unit of O is NM 3/ min.
(c) typical composition of foamy slag is controlled to be: CaO/SiO 2=2.1~3.0, FeO:25%~30%.
(d) tapping: work as a [o]=750~900ppm, temperature can be tapped in the time of 1620 ℃~1640 ℃.
Mixed carbon raw material in the described step (a) mainly contains: conventional raw materials such as the pig iron, molten iron, HBI, and mixed carbon comtent is 1.0~1.5% preferably, when using HBI, generally it joins C content between 1.2~1.8%.Because the CSP production technique is had relatively high expectations to steel quality, must control the residual element of molten steel, especially, reach specified requirement in order to make the copper content in the molten steel to the control of Cu content in the molten steel, except utilizing 15~25% high duty pig iron, also can use direct-reduced iron DRI/HBI.The main purpose that height is joined carbon is: for high oxygen supply intensity provides condition, and for taking off S, taking off P good power is provided.
In described step (b), the carbon amount abundance in the melting molten bath in early stage, so the C/O ratio should be less; Carbon amount in the melting later stage molten bath is limited, for guaranteeing the carbon of surplus, makes the molten bath that peroxidation not take place, and the C/O ratio should be bigger.
In described step (c), because influencing the factor of foamy slag mainly contains: the surface tension of slag, slag viscosity, basicity, FeO content and gas supply etc., the present invention is by the furnace door carbon oxygen lance mechanical manipulator, control the C/O ratio of different smelt stage and the angle of carbon-oxygen gun, to obtain good foamy slag.
In described step (d), because temperature one is regularly, [C] in the molten bath, [O] is long-pending is a constant, works as a [o]=750~900ppm, temperature is in the time of 1620 ℃~1640 ℃, and C content is 0.035~0.05%.
The present invention compared with prior art has the following advantages: the present invention changes the traditional technology of being produced soft steel by converter, enriched the production method of soft steel, filled up the blank of the required low-carbon (LC) molten steel of electrosmelting coils of hot-rolled steel, provide more process choice for producing soft steel.End point controlling process of the present invention is stable, and tap to tap time is short, the also corresponding decline of its production energy consumption and cost.
Embodiment
Present embodiment employing capacity is 150 tons a uhp electric arc furnace (UHP electric furnace), be characterized in using in a large number oxygen, promptly adopt carbon-oxygen gun and oxygen oil burner, electric furnace is furnished with a water-cooled furnace door carbon oxygen lance, wherein have two oxygen spray orifices and a carbon spray orifice, total amount is 2 * 2000Nm 3/ h, 6 furnace wall oxygen oil burners; Carbon-oxygen gun is used to cut steel scrap, improves thermal source, decarburization, making foamed slag.
Present embodiment may further comprise the steps successively:
(a) batching: the mixed carbon raw material of present embodiment is as follows:
The 15t broken material
The 20t pig iron
Useless among the 20t
The 10t pig iron
The 20t broken material
The 15t broken material
The 10t pig iron
Useless among the 20t
The 10t pig iron
The 20t broken material
Be broken material 70t, in useless 40t, pig iron 50t, its mixed carbon comtent is 1.38%.
(b) control C/O ratio: C/O is controlled by the furnace door carbon oxygen lance mechanical manipulator.
In melting early stage, promptly temperature below 1520 ℃ the time, C/O=1: 2, wherein the unit of C is kg/min, the unit of O is NM 3/ min; In melting mid-term, promptly temperature in the time of 1520 ℃~1580 ℃, C/O=1: 1; In the melting later stage, promptly temperature more than 1580 ℃ the time, C/O=2: 1.
Carbon-oxygen gun should keep its rifle head oblique cutting in slag, and from about the 30mm of molten bath.
(c) Composition Control of foamy slag:
The typical composition of foamy slag is: CaO:36%, SiO 2: 17%, MgO:10%, MnO:5%, FeO:25%, Al 2O 3: 5%, P:0.5%, S:0.5%.
The light dolomite that has added the 2.2t/ stove in the present embodiment, wherein contain the MgO about 30%, not only help improving electric furnace furnace life, and help the formation of electric furnace foamy slag and stable, the content of CaO in the light dolomite is 50~55%, the effect that can play P, remove S.CaO/SiO in the present embodiment 2=2.5FeO:26%.
(d) tapping:
Present embodiment is at a [o]=750~900ppm, temperature can be tapped in the time of 1620 ℃~1640 ℃.A wherein [o]Employing is decided oxygen fast, carbometer is controlled.Wherein, P content is lower than 0.015%, and carbon content is 0.03~0.06%.
Higher mixed carbon comtent is to avoid or the low excessively basis of the clear carbon of minimizing in the present embodiment, and the clear carbon of suitable change helps to shorten the heat, reduce melting electric consumption, and the present invention controls mixed carbon comtent by the ratio of adjusting oxygen and carbon dust.For smelting low carbon steel series (carbon content is lower than 0.07%), change clear carbon and be controlled at 0.1%, as change clear carbon height, then control blowing oxygen quantity well according to decarbonization rate; As it is low to change clear carbon, reduces oxygen blast, to realize that end point carbon is between 0.03~0.04%.

Claims (6)

1. the end point controlling process of smelting low carbon steel in electric furnace may further comprise the steps successively:
(a) batching: select conventional mixed carbon raw material for use, make mixed carbon comtent be controlled at 1.0~1.8%;
(b) control C/O ratio:
Carbon-oxygen gun should keep its rifle head oblique cutting in slag, and from about the 30mm of molten bath, by fire door C-O rifle mechanical manipulator C/O is carried out following control:
In melting early stage, promptly temperature below 1520 ℃ the time, C/O=1: 2;
In melting mid-term, promptly temperature in the time of 1520 ℃~1580 ℃, C/O=1: 1;
In the melting later stage, promptly temperature more than 1580 ℃ the time, C/O=2: 1;
Wherein, the unit of C is kg/min, and the unit of O is NM 3/ min;
(c) typical composition of foamy slag is controlled to be: CaO/SiO 2=2.1~3.0, FeO:25%~30%;
(d) tapping: work as a [o]=750~900ppm, temperature can be tapped in the time of 1620 ℃~1640 ℃;
All percentage ratios are weight percentage.
2. the end point controlling process of smelting low carbon steel in electric furnace according to claim 1, it is characterized in that: in described step (a), described mixed carbon comtent is 1.0~1.5%.
3. the end point controlling process of smelting low carbon steel in electric furnace according to claim 2, it is characterized in that: described mixed carbon comtent is 1.38%.
4. the end point controlling process of smelting low carbon steel in electric furnace according to claim 1, it is characterized in that: in described step (c), the typical composition of foamy slag is controlled to be: CaO/SiO 2=2.5, FeO:26%.
5. the end point controlling process of smelting low carbon steel in electric furnace according to claim 1, it is characterized in that: in described step (c), the typical composition of foamy slag is: CaO:36%, SiO 2: 17%, MgO:10%, MnO:5%, FeO:25%, Al 2O 3: 5%, P:0.5%, S:0.5%.
6. the end point controlling process of smelting low carbon steel in electric furnace according to claim 1, it is characterized in that: in described step (d), P content is lower than 0.015% during tapping, and carbon content is 0.03~0.06%.
CNB02115094XA 2002-04-17 2002-04-17 End point controlling process for smelting low carbon steel in electric furnace Expired - Fee Related CN1203196C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB02115094XA CN1203196C (en) 2002-04-17 2002-04-17 End point controlling process for smelting low carbon steel in electric furnace

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB02115094XA CN1203196C (en) 2002-04-17 2002-04-17 End point controlling process for smelting low carbon steel in electric furnace

Publications (2)

Publication Number Publication Date
CN1451767A CN1451767A (en) 2003-10-29
CN1203196C true CN1203196C (en) 2005-05-25

Family

ID=29220945

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB02115094XA Expired - Fee Related CN1203196C (en) 2002-04-17 2002-04-17 End point controlling process for smelting low carbon steel in electric furnace

Country Status (1)

Country Link
CN (1) CN1203196C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100345992C (en) * 2005-12-15 2007-10-31 广州珠江钢铁有限责任公司 Technology of improving and stabilizing titanium recorery rate in titanium micro-alloyed high strength weether resistant sinelting and continuous casting process

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102127691B (en) * 2011-02-21 2012-07-25 宁波钢铁有限公司 Method for producing hot rolled steel coil
CN106244827B (en) * 2016-09-05 2018-06-19 重庆大学 A kind of smelting endpoint of smelting titanium slag with electric stove judges system and method
CN107419056A (en) * 2017-07-28 2017-12-01 攀钢集团研究院有限公司 Stainless steel EAF foaming slag and its application method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100345992C (en) * 2005-12-15 2007-10-31 广州珠江钢铁有限责任公司 Technology of improving and stabilizing titanium recorery rate in titanium micro-alloyed high strength weether resistant sinelting and continuous casting process

Also Published As

Publication number Publication date
CN1451767A (en) 2003-10-29

Similar Documents

Publication Publication Date Title
CN100363508C (en) Electric furnace to converter steel making production process
CN102424886B (en) Furnace protection process for decarburization converter less slag splashing
CN102080136B (en) Converter smelting technique
CN105525055B (en) A kind of control method of converter less-slag melting carbon period splash
CN109022675B (en) Energy supply method by using chemical energy for smelting of full-scrap steel electric arc furnace
CN107760823A (en) A kind of quasi-continuous steelmaking system of steel scrap electric arc furnaces entirely and technique
CN111647714A (en) Smelting method for improving service life of electric furnace
CN101660019A (en) Electric furnace burden process with high efficiency and low cost
CN1088112C (en) Flux and process for forming slag of converter
CN108754062A (en) A kind of method of the interior gasification dephosphorization steel-making of converter steel slag hearth
CN1195079C (en) Method for smelting stainless steel with waste steel by frequency-conversion electric induction furnace
CN1203196C (en) End point controlling process for smelting low carbon steel in electric furnace
CN1057134C (en) Production method for medium- and low-carbon manganese iron
CN1434133A (en) Method for controlling rising splash slag in battom of converter
CN111893247B (en) Steelmaking method with high-efficiency refining function
CN113337669B (en) Method for strengthening electric furnace smelting by bottom blowing hydrogen
CN100335669C (en) Method for smelting phosphor-containing steel
CN100335659C (en) Smelting method of phosphorus containing steel
KR100363608B1 (en) Method of low-carbon ferromanganese(LCFeMn) manufacturing by recycling dust containing manganese
CA2224039A1 (en) Foamy slag process using multi-circuit lance
CN114107599A (en) Full scrap steel electric furnace smelting method
CN106086287A (en) Semi-steel making improves the method for aim carbon rear converter terminal residue adjustment
JPS6063307A (en) Converter steel making method of dead soft steel
CN1223694A (en) Method for making steel in a liquid melt-fed electric furnace
CN111218538B (en) Method for efficiently utilizing high-manganese pig iron

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20050525

Termination date: 20140417