CN1200059C - Offset on-line water-based roll-coating glazing oil and preparation method thereof - Google Patents
Offset on-line water-based roll-coating glazing oil and preparation method thereof Download PDFInfo
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- CN1200059C CN1200059C CN 02135083 CN02135083A CN1200059C CN 1200059 C CN1200059 C CN 1200059C CN 02135083 CN02135083 CN 02135083 CN 02135083 A CN02135083 A CN 02135083A CN 1200059 C CN1200059 C CN 1200059C
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- Prior art keywords
- agent
- water
- offset
- added
- based roll
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 239000011248 coating agent Substances 0.000 title claims abstract description 19
- 238000000576 coating method Methods 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 36
- 238000003756 stirring Methods 0.000 claims abstract description 15
- 230000003472 neutralizing effect Effects 0.000 claims abstract description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 239000000080 wetting agent Substances 0.000 claims abstract description 11
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 10
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 10
- 239000000839 emulsion Substances 0.000 claims abstract description 8
- 239000011347 resin Substances 0.000 claims description 13
- 229920005989 resin Polymers 0.000 claims description 13
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 claims description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 8
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 claims description 8
- 229930016911 cinnamic acid Natural products 0.000 claims description 8
- 235000013985 cinnamic acid Nutrition 0.000 claims description 8
- 239000013530 defoamer Substances 0.000 claims description 8
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 claims description 8
- 125000003368 amide group Chemical group 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 4
- 239000013543 active substance Substances 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 2
- 239000008367 deionised water Substances 0.000 claims description 2
- 229910021641 deionized water Inorganic materials 0.000 claims description 2
- -1 polyethylene Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 238000001035 drying Methods 0.000 abstract description 6
- 238000007645 offset printing Methods 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000002518 antifoaming agent Substances 0.000 abstract 2
- ALJHHTHBYJROOG-UHFFFAOYSA-N 7-(dimethylamino)phenothiazin-3-one Chemical compound C1=CC(=O)C=C2SC3=CC(N(C)C)=CC=C3N=C21 ALJHHTHBYJROOG-UHFFFAOYSA-N 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 238000007639 printing Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
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- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention relates to offset printing on-line water-based roll-coating glazing oil which comprises components of the following percentage content: 4.84 to 12.92% of acrylic resin, 50.30 to 72.82% of acrylic emulsion, 0.92 to 2.72% of wetting agent, 0.18 to 0.41% of slipping agent, 0.46 to 1.10% of wax, 0.46 to 1.37% of levelling agent, 10.06 to 24.27% of water, 5.03 to 18.20% of neutralizing agent and 0.18 to 0.41% of defoaming agent. In a preparation method, the water and the neutralizing agent are added into a stirrer where the acrylic resin is slowly added, and the neutralizing agent is added into the stirrer after the acrylic resin is dissolved to regulate a pH value to 8.5 to 9.5; the acrylic emulsion, the wax and the levelling agent are sequentially added into the stirrer, and the slipping agent is singly added to the wetting agent along with stirring; afterwards, the slipping agent and the wetting agent are added to mixtures of the former components, and the defoaming agent is added to the mixtures along with stirring; water is replenished to regulate viscidity to 55 to 65 seconds (a Methylene Violet NO. 2 cup at 25 DEG C). The present invention has the advantages of novel composition, scientific compounding, simple preparation, low cost and high surface gloss of more than 90% when tested by a glossmeter; the present invention can obtain drying properties especially suitable for offset printing on-line production and can also effectively avoid the phenomena of back sticking and cracks.
Description
It is the coating composition of feature that technical field the present invention relates to its physical properties or the effect that produced, relates in particular to a kind of offset on-line water-based roll-coating glazing oil and preparation method thereof.
The water lustering oil of the existing press of background technology, be subjected to the restriction of its surface wettability performance and drying property, can only on the exsiccant ink lay, be coated with, promptly can only carry out the glazing of gravure mode or the glazing at intermittence of offset printing mode, can not carry out the on line glazing of offset printing mode, and the solvent borne oil polish has the solvent evaporates that is unfavorable for HUMAN HEALTH, pollution of ecological environment in printing process.
Summary of the invention is to remedy the defective that prior art exists, and the present invention proposes a kind of offset on-line water-based roll-coating glazing oil and preparation method thereof.The technical scheme that adopts is as follows:
This offset on-line water-based roll-coating glazing oil is characterized in that each component and degree are respectively:
The polyfunctional group acrylic resin 4.84～12.92% that contains hydroxyl and amide group except that pure acrylic acid or cinnamic acid resin;
Be selected from the ACRYLIC EMULSION 50.30～72.82% of pure acrylic acid or cinnamic acid resin;
Wetting agent 0.92～2.72%;
Smooth agent 0.18～0.41%;
Wax 0.46～1.10%;
Flow agent 0.46～1.37%;
Water 10.06～24.27%;
Neutralizing agent 5.03～18.20%;
Defoamer 0.18～0.41%.
The further feature of this offset on-line water-based roll-coating glazing oil is:
Wetting agent can be a tensio-active agent;
Smooth agent, flow agent, defoamer can be silicone based;
Wax can be polyethylene wax;
Water can be deionized water;
Neutralizing agent can be an ammoniacal liquor, also can be organic amine.
This offset on-line water-based roll-coating glazing oil and preparation method thereof is characterized in that following operation is arranged successively:
(1) water, neutralizing agent are added in the agitator, stirring velocity is remained on 600 rev/mins, slowly add the polyfunctional group acrylic resin that contains hydroxyl and amide group except that pure acrylic acid or cinnamic acid resin, after it all dissolves, add neutralizing agent, regulate pH value to 8.5～9.5;
(2) ACRYLIC EMULSION, wax and the flow agent that will be selected from pure acrylic acid or cinnamic acid resin adds in the above-mentioned resin liquid successively, mixes;
(3) in another agitator, smooth agent is added in the wetting agent, stir after 30 minutes, add again in the said mixture, stirring velocity remains on 600 rev/mins, stirs 1 hour;
(4) defoamer is added in the said mixture, stirred 10 minutes, make up water is regulated viscosity to 60 ± 5 second (Zan Shi 2# cup, 25 ℃) then.
The present invention's beneficial effect against existing technologies is, the component novelty, and the batching science, preparation is simple, and cost is lower, and solvent flashing is a water, helps safety in production and environment protection.Owing to selected appropriate resin and flow agent for use, high surface luster is arranged, the glossometer test can reach more than 90%.Owing to adopted the tensio-active agent of strong penetrating quality, reduce the diagram of system surface tension again, can when the oily gum printing ink is dried, not adhere to, soaked into fully, be convenient on line production, separately oil polish.Also owing to suitably introduce hydroxyl, amido, increased water-soluble, reduce the water miscible viscosity of resin and obtained high solids content, make the gloss oil rete thickening of final printed matter, and introducing functional group, reduced the release property of water, by acrylic resin and the ACRYLIC EMULSION collocation of finish-drying fast, can obtain to be particularly suitable for the drying property that the offset printing on line is produced, be surface drying rapidly and the internal layer rate of drying is consistent with printing ink, avoid taking place the sticking back of the body and crack performance effectively, save printing cost significantly.
Embodiment
A kind of offset on-line water-based roll-coating glazing oil
This offset on-line water-based roll-coating glazing oil, each component and degree are respectively acrylic resin 7.0% (pH=9.0), vinylformic acid water miscible liquid 55.0%, wetting agent 2.0%, smooth agent 0.3%, wax 0.6%, flow agent 1.0%, water 27.8%[viscosity 58 seconds (Zan Shi 2# cup, 25 ℃)], neutralizing agent 6.0% and defoamer 0.3%.
A kind of preparation method of offset on-line water-based roll-coating glazing oil
The preparation method of this offset on-line water-based roll-coating glazing oil has following operation successively:
(1) water, neutralizing agent are added in the agitator, stirring velocity is remained on 600 rev/mins, slowly add acrylic resin, after it all dissolves, add neutralizing agent, regulate pH value to 9.0;
(2) ACRYLIC EMULSION, wax and flow agent are added in the above-mentioned resin liquid successively, mix;
(3) in another agitator, smooth agent is added in the wetting agent, stir after 30 minutes, add again in the said mixture, stirring velocity remains on 600 rev/mins, stirs 1 hour;
(4) defoamer is added in the said mixture, stirred 10 minutes, make up water is regulated viscosity to 58 second (Zan Shi 2# cup, 25 ℃) then.
Claims (7)
1, a kind of offset on-line water-based roll-coating glazing oil, it is characterized in that each component and degree are respectively the polyfunctional group acrylic resins 4.84～12.92% that contains hydroxyl and amide group except that pure acrylic acid or cinnamic acid resin, be selected from the ACRYLIC EMULSION 50.30～72.82% of pure acrylic acid or cinnamic acid resin, wetting agent 0.92～2.72%, smooth agent 0.18～0.41%, wax 0.46～1.10%, flow agent 0.46～1.37%, water 10.06～24.27%, neutralizing agent 5.03～18.20% and defoamer 0.18～0.41%.
2, offset on-line water-based roll-coating glazing oil as claimed in claim 1 is characterized in that wetting agent is a tensio-active agent.
3, offset on-line water-based roll-coating glazing oil as claimed in claim 1 is characterized in that smooth agent, flow agent, defoamer are silicone based.
4, offset on-line water-based roll-coating glazing oil as claimed in claim 1 is characterized in that wax is polyethylene wax.
5, offset on-line water-based roll-coating glazing oil as claimed in claim 1 is characterized in that water is deionized water.
6, offset on-line water-based roll-coating glazing oil as claimed in claim 1 is characterized in that neutralizing agent is an ammoniacal liquor, or organic amine.
7, a kind of preparation method of offset on-line water-based roll-coating glazing oil has following operation successively:
71 with in water, the neutralizing agent adding agitator, stirring velocity is remained on 600 rev/mins, slowly add the polyfunctional group acrylic resin that contains hydroxyl and amide group except that pure acrylic acid or cinnamic acid resin, after it all dissolves, add neutralizing agent, regulate pH value to 8.5～9.5;
72 ACRYLIC EMULSION, wax and the flow agents that will be selected from pure acrylic acid or cinnamic acid resin add in the above-mentioned resin liquid successively, mix;
73 in another agitator, and smooth agent is added in the wetting agent, stirs after 30 minutes, adds in the said mixture again, and stirring velocity remains on 600 rev/mins, stirs 1 hour;
74 add defoamer in the said mixture, stir 10 minutes, regulate viscosity to 60 ± 5 second with Zan Shi 2# cup make up water under 25 ℃ temperature condition then.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02135083 CN1200059C (en) | 2002-10-31 | 2002-10-31 | Offset on-line water-based roll-coating glazing oil and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02135083 CN1200059C (en) | 2002-10-31 | 2002-10-31 | Offset on-line water-based roll-coating glazing oil and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1405249A CN1405249A (en) | 2003-03-26 |
| CN1200059C true CN1200059C (en) | 2005-05-04 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02135083 Expired - Lifetime CN1200059C (en) | 2002-10-31 | 2002-10-31 | Offset on-line water-based roll-coating glazing oil and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN1200059C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104293030A (en) * | 2014-09-24 | 2015-01-21 | 安徽省中彩印务有限公司 | Environment-friendly type water-based oil polish and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101812256B (en) * | 2009-02-24 | 2012-07-04 | 东莞市英科水墨有限公司 | Preprinted oil polish for high-temperature resistant carton |
| CN101798775B (en) * | 2010-03-05 | 2011-12-28 | 北京高盟新材料股份有限公司 | Water-borne ultraviolet cured gloss oil and preparation method thereof |
| CN102154941A (en) * | 2011-03-18 | 2011-08-17 | 上海理工大学 | Preparation method of waterproof printing polishing oil for paper presswork |
| CN103029473B (en) * | 2012-12-27 | 2015-08-12 | 山东泰宝防伪制品有限公司 | A kind of typography realizing local the calendaring effect |
| CN104151920B (en) * | 2014-07-04 | 2016-08-24 | 上海应用技术学院 | A kind of on line glazing printing water glazing ink and preparation method |
| CN104893485B (en) * | 2015-06-26 | 2018-05-01 | 中荣印刷（昆山）有限公司 | A kind of highlight water-based oil polish of environment-friendly type and preparation method thereof |
| CN106221479A (en) * | 2016-08-29 | 2016-12-14 | 宁波江东甬风工业设计有限公司 | A kind of preparation method of durability water-based gloss oil |
| CN106519815A (en) * | 2016-10-13 | 2017-03-22 | 常州创索新材料科技有限公司 | Preparing method for environment-friendly living creature adhesion preventing gloss oil |
| CN107600614A (en) * | 2017-09-28 | 2018-01-19 | 珠海正业包装有限公司 | A kind of high-precision flexible printing corrugated case of green |
| CN110028820A (en) * | 2018-01-12 | 2019-07-19 | 上海荟百精细化工有限公司 | A kind of water-based gloss oil and preparation method thereof suitable for the online coding of high speed |
| CN110551418A (en) * | 2019-09-12 | 2019-12-10 | 中山市中益油墨涂料有限公司 | water-based glitter gloss oil and preparation method thereof |
-
2002
- 2002-10-31 CN CN 02135083 patent/CN1200059C/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104293030A (en) * | 2014-09-24 | 2015-01-21 | 安徽省中彩印务有限公司 | Environment-friendly type water-based oil polish and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN1405249A (en) | 2003-03-26 |
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Owner name: SHANTOU DONGFENG PRINTING CO., LTD. Free format text: FORMER NAME: DONGFENG PRINTING PLANT CO. LTD., SHANTOU CITY |
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| CP01 | Change in the name or title of a patent holder |
Address after: 515064 Industrial Zone, North Chaoshan Road, Guangdong, Shantou Patentee after: SHANTOU DONGFENG PRINTING Co.,Ltd. Address before: 515064 Industrial Zone, North Chaoshan Road, Guangdong, Shantou Patentee before: Shantou Dongfeng Printing Co.,Ltd. |
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| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20030326 Assignee: ANHUI SANLIAN WOODEN ART PACKAGE CO.,LTD. Assignor: SHANTOU DONGFENG PRINTING Co.,Ltd. Contract record no.: 2014340000135 Denomination of invention: Offset on-line water-based roll-coating glazing oil and preparation method thereof Granted publication date: 20050504 License type: Exclusive License Record date: 20140703 |
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