CN1195576A - Emulsifying viscosity-reducing agent for superthick emulsified oil combustion - Google Patents

Emulsifying viscosity-reducing agent for superthick emulsified oil combustion Download PDF

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Publication number
CN1195576A
CN1195576A CN98113740A CN98113740A CN1195576A CN 1195576 A CN1195576 A CN 1195576A CN 98113740 A CN98113740 A CN 98113740A CN 98113740 A CN98113740 A CN 98113740A CN 1195576 A CN1195576 A CN 1195576A
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China
Prior art keywords
emulsifying
surfactant
viscosity
sodium
reducing agent
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Granted
Application number
CN98113740A
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Chinese (zh)
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CN1101255C (en
Inventor
盖军
宁甲清
宋迎来
王树学
郭鹏宇
李泽勤
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Prospecting Design Institute Of Liaohe Petroleum Exploration Bureau
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Prospecting Design Institute Of Liaohe Petroleum Exploration Bureau
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Priority to CN98113740A priority Critical patent/CN1101255C/en
Publication of CN1195576A publication Critical patent/CN1195576A/en
Application granted granted Critical
Publication of CN1101255C publication Critical patent/CN1101255C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

The present invention relates to an emulsifying viscosity-reducing agent for emulsifying combustion of ultraheavy crude for oil-field hot injection and heating boiler. Said emulsifying viscosity-reducing agent is made up by using three kinds or more than three kinds of surfactants and catalytic combustion adjuvant, stabilizing agent and solvent through such steps as proportioning, stirring, uniformly mixing and dilution by adding water. Said invented product has good emulsifying and viscosity-reducing properties, can greatly improve fluidity of ultraheavy crude and its combustion effect, and its raw material source is extensive and cost is low.

Description

A kind of emulsifying pour depressor that is used for super emulsified viscous oil burning
The present invention relates to a kind of emulsifying pour depressor that oil field heat is annotated, the super emulsified viscous oil of heating boiler is burnt that is used for.
Super viscous crude occupies certain ratio on part oilfield reserve, the output structure at home and abroad.Yet, because this kind crude oil with poor quality oil property extreme difference makes its utilization be subjected to limiting greatly, even also have certain difficulty when utilizing it as boiler oil.At present, demand urgently seeking, develop some and can reduce super viscosity of thickened oil significantly, improves super viscous crude combustion efficiency, enable to obtain the more chemical agent of good utilisation, to solve super viscous crude production, to utilize the institute of technology scarce.
The object of the present invention is to provide a kind of super emulsified viscous oil burning emulsifying pour depressor that can improve super viscous crude flowability and combustion efficiency.
The present invention realizes like this.Emulsifying pour depressor provided by the present invention adopts following prescription:
Component Percentage by weight (%)
Surfactant catalysis burning-rate accelerator stabilizing agent solvent ??????50--90 ??????0--10 ??????15--50 ??????0--20
Wherein: surfactant can adopt sodium alkyl sulfonate, sodium alkyl benzene sulfonate, alkylsurfuric acid ester sodium salt, alkylol polyoxyethylene groups ether, alkyl phenol polyoxyethylene base ether (NP15--100), fatty acid polyglycol chlorovinyl ether, tween--and N (N=20--85), sodium soap, polyoxyethylene groups polyoxypropylene base ether, each preparation are to select wherein that surfactant is used more than 3 kinds or 3 kinds for use; Catalysis burning-rate accelerator adopts alkyl nitrate; Stabilizing agent can adopt alkaline matters such as polyethylene glycol and ammonia, alkylamine, potassium hydroxide, NaOH, sodium carbonate; Solvent can adopt water or methyl alcohol, ethanol, propyl alcohol, butanols etc.
During preparation, add various components according to above-mentioned formula rate, thin up is the emulsifying pour depressor aqueous solution of concentration 10--20% behind the stirring and evenly mixing, uses for the super thick oil and emulsified oil of preparation.When the preparation oil emulsion, the dose that adds of this kind emulsifying pour depressor is 1--3 ‰, and the water mixing rate is 15--30%, and the viscosity break ratio of oil emulsion is more than 90% under 80 ℃ of temperature, and its heat endurance can keep more than 30 days.
Super emulsified viscous oil burning provided by the invention has good emulsifying, viscosity-reducing performance with emulsifying pour depressor, its cheap raw is wide, and compatibility is good, prepares convenient for production, utilize it can improve the flowability and the combustion efficiency of super viscous crude greatly, super viscous crude resource is fully used.
Embodiment 1: get 25kgNP--50,20kg tween--20 and 25kg polyoxyethylene groups polyoxypropylene base ether make surfactant, the just own ester of 10kg nitric acid is made catalysis burning-rate accelerator, 20kg polyethylene glycol used as stabilizers behind the stirring and evenly mixing, can obtain super emulsifying and viscosity-reducing agent for condensed oil 100kg.After should super emulsifying and viscosity-reducing agent for condensed oil adding the aqueous solution that water is made into concentration 10--20%, add dose by 2.5 ‰ and prepare oil emulsion and can make fuel usefulness by boiler of feeding.
Embodiment 2: press the super emulsifying and viscosity-reducing agent for condensed oil of following formulation 100kg:
Surfactant: NP--25 30kg
Tween--40 20kg
Sodium stearate 20kg
Stabilizing agent: NaOH 20kg
Solvent: methyl alcohol 10kg
Embodiment 3: press the super emulsifying and viscosity-reducing agent for condensed oil of following formulation 100kg:
Surfactant: NP--30 20kg
Tween--20 20kg
Ten sodium hisbenzene sulfonate 10kg
Stabilizing agent: NaOH 50kg
Embodiment 4: press the super emulsifying and viscosity-reducing agent for condensed oil of following formulation 100kg:
Surfactant: NP--30 30kg
Tween--40 30kg
Polyoxyethylene groups polyoxypropylene base ether 20kg
Stabilizing agent: NaOH 20kg

Claims (1)

1. an emulsifying pour depressor that is used for super emulsified viscous oil burning is characterized in that, this kind emulsifying pour depressor adopts following prescription: Component Percentage by weight (%) Surfactant catalysis burning-rate accelerator stabilizing agent solvent ???????50--90 ???????0--10 ???????15--5 ???????0--20
Wherein: surfactant can adopt sodium alkyl sulfonate, sodium alkyl benzene sulfonate, alkylsurfuric acid ester sodium salt, alkylol polyoxyethylene groups ether, alkyl phenol polyoxyethylene base ether (NP15--100), aliphatic acid polyethenoxy base ether, tween--and N (N=20--8 5), sodium soap, polyoxyethylene groups polyoxypropylene base ether, each preparation are to select wherein that surfactant is used more than 3 kinds or 3 kinds for use; Catalysis burning-rate accelerator adopts alkyl nitrate; Stabilizing agent can adopt alkaline matters such as polyethylene glycol and ammonia, alkylamine, potassium hydroxide, NaOH, sodium carbonate; Solvent can adopt water or methyl alcohol, ethanol, propyl alcohol, butanols etc.
During preparation, add various components according to above-mentioned formula rate, after stirring, thin up is the emulsifying pour depressor aqueous solution of concentration 10--20%.
CN98113740A 1998-01-21 1998-01-21 Emulsifying viscosity-reducing agent for superthick emulsified oil combustion Expired - Fee Related CN1101255C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN98113740A CN1101255C (en) 1998-01-21 1998-01-21 Emulsifying viscosity-reducing agent for superthick emulsified oil combustion

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN98113740A CN1101255C (en) 1998-01-21 1998-01-21 Emulsifying viscosity-reducing agent for superthick emulsified oil combustion

Publications (2)

Publication Number Publication Date
CN1195576A true CN1195576A (en) 1998-10-14
CN1101255C CN1101255C (en) 2003-02-12

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101735115B (en) * 2008-11-18 2013-06-05 长江大学 Salt resistance and calcium resistant deep extra-heavy oil emulsifier and viscosity dropping agent
CN105802601A (en) * 2016-05-16 2016-07-27 赵月 Viscosity reducer for crude oil
CN108913114A (en) * 2018-06-29 2018-11-30 河南妙天控股有限公司 A kind of oil exploitation crude oil lysate and preparation method thereof
CN110272727A (en) * 2018-03-14 2019-09-24 中国石油天然气股份有限公司 Thinner and preparation method thereof
CN110566816A (en) * 2019-09-25 2019-12-13 威海翔泽新材料科技有限公司 preparation method of tar viscosity reducer for reducing viscosity of tar

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101418213B (en) * 2007-10-24 2011-01-12 中国石油化工股份有限公司河南油田分公司石油工程技术研究院 Cracking and catalytic viscosity reducer for heavy oil production by steam injection and preparation method thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8521968D0 (en) * 1985-09-04 1985-10-09 British Petroleum Co Plc Preparation of emulsions
FR2588012B1 (en) * 1985-10-01 1988-01-08 Sodecim PROCESS FOR HOMOGENEIZING A MIXTURE OF AQUEOUS RESIDUAL LIQUIDS AND LIQUID OR SOLID FUELS
FR2680983B1 (en) * 1991-09-10 1993-10-29 Institut Francais Petrole CONTINUOUS MIXER DEVICE, METHOD AND USE IN A PUMP INSTALLATION OF A HIGH VISCOSITY FLUID.
CN1068359A (en) * 1992-02-11 1993-01-27 辽河石油学校 Emulsifying and viscosity-reducing agent for condensed oil
CN1025680C (en) * 1992-04-03 1994-08-17 山东大学 Viscosity decreasing ayent for high-consistency crude oil

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101735115B (en) * 2008-11-18 2013-06-05 长江大学 Salt resistance and calcium resistant deep extra-heavy oil emulsifier and viscosity dropping agent
CN105802601A (en) * 2016-05-16 2016-07-27 赵月 Viscosity reducer for crude oil
CN110272727A (en) * 2018-03-14 2019-09-24 中国石油天然气股份有限公司 Thinner and preparation method thereof
CN108913114A (en) * 2018-06-29 2018-11-30 河南妙天控股有限公司 A kind of oil exploitation crude oil lysate and preparation method thereof
CN110566816A (en) * 2019-09-25 2019-12-13 威海翔泽新材料科技有限公司 preparation method of tar viscosity reducer for reducing viscosity of tar

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