CN1194063C - Multicomponent mixed work medium throttling refrigerant applicable to 200-204K refrigerating temperature zone - Google Patents
Multicomponent mixed work medium throttling refrigerant applicable to 200-204K refrigerating temperature zone Download PDFInfo
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- CN1194063C CN1194063C CN 03121466 CN03121466A CN1194063C CN 1194063 C CN1194063 C CN 1194063C CN 03121466 CN03121466 CN 03121466 CN 03121466 A CN03121466 A CN 03121466A CN 1194063 C CN1194063 C CN 1194063C
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- 239000003507 refrigerant Substances 0.000 title description 3
- 239000000463 material Substances 0.000 claims abstract description 112
- 239000000203 mixture Substances 0.000 claims abstract description 65
- 238000005057 refrigeration Methods 0.000 claims abstract description 48
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims abstract description 30
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 22
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 claims abstract description 20
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 claims abstract description 15
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims abstract description 14
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims abstract description 14
- QYSGYZVSCZSLHT-UHFFFAOYSA-N octafluoropropane Chemical compound FC(F)(F)C(F)(F)C(F)(F)F QYSGYZVSCZSLHT-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229960004065 perflutren Drugs 0.000 claims abstract description 13
- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical compound FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 claims abstract description 12
- AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical compound CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims abstract description 11
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims abstract description 10
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 claims abstract description 9
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims abstract description 8
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims abstract description 8
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims abstract description 7
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 7
- UHCBBWUQDAVSMS-UHFFFAOYSA-N fluoroethane Chemical compound CCF UHCBBWUQDAVSMS-UHFFFAOYSA-N 0.000 claims abstract description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 6
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229960004692 perflenapent Drugs 0.000 claims abstract description 6
- NJCBUSHGCBERSK-UHFFFAOYSA-N perfluoropentane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F NJCBUSHGCBERSK-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052724 xenon Inorganic materials 0.000 claims abstract description 6
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 claims abstract description 6
- LVZWSLJZHVFIQJ-UHFFFAOYSA-N Cyclopropane Chemical compound C1CC1 LVZWSLJZHVFIQJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- IYABWNGZIDDRAK-UHFFFAOYSA-N allene Chemical compound C=C=C IYABWNGZIDDRAK-UHFFFAOYSA-N 0.000 claims abstract description 5
- WMIYKQLTONQJES-UHFFFAOYSA-N hexafluoroethane Chemical compound FC(F)(F)C(F)(F)F WMIYKQLTONQJES-UHFFFAOYSA-N 0.000 claims abstract description 5
- QKCGXXHCELUCKW-UHFFFAOYSA-N n-[4-[4-(dinaphthalen-2-ylamino)phenyl]phenyl]-n-naphthalen-2-ylnaphthalen-2-amine Chemical compound C1=CC=CC2=CC(N(C=3C=CC(=CC=3)C=3C=CC(=CC=3)N(C=3C=C4C=CC=CC4=CC=3)C=3C=C4C=CC=CC4=CC=3)C3=CC4=CC=CC=C4C=C3)=CC=C21 QKCGXXHCELUCKW-UHFFFAOYSA-N 0.000 claims abstract description 5
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims description 20
- 239000001294 propane Substances 0.000 claims description 13
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims description 13
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 claims description 4
- 229960003132 halothane Drugs 0.000 claims description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 4
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 abstract 4
- UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 abstract 2
- PMPVIKIVABFJJI-UHFFFAOYSA-N Cyclobutane Chemical compound C1CCC1 PMPVIKIVABFJJI-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- 239000001282 iso-butane Substances 0.000 abstract 2
- KAVGMUDTWQVPDF-UHFFFAOYSA-N perflubutane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)F KAVGMUDTWQVPDF-UHFFFAOYSA-N 0.000 abstract 2
- 229950003332 perflubutane Drugs 0.000 abstract 2
- 238000000034 method Methods 0.000 description 12
- GVGCUCJTUSOZKP-UHFFFAOYSA-N nitrogen trifluoride Chemical class FN(F)F GVGCUCJTUSOZKP-UHFFFAOYSA-N 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- 238000007906 compression Methods 0.000 description 7
- 230000006835 compression Effects 0.000 description 6
- 239000000470 constituent Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 235000013844 butane Nutrition 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 239000006200 vaporizer Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000013256 coordination polymer Substances 0.000 description 3
- JKTORXLUQLQJCM-UHFFFAOYSA-N 4-phosphonobutylphosphonic acid Chemical compound OP(O)(=O)CCCCP(O)(O)=O JKTORXLUQLQJCM-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- -1 1,2-butylene Chemical group 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical group [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
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Abstract
Description
Project | Mixture 1 volumetric molar concentration % | Mixture 2 volumetric molar concentration % | Mixture 3 volumetric molar concentration % |
The 1st group | 35 (tetrafluoromethane 25, nitrogen trifluorides 10) | 40 (tetrafluoromethanes) | 50 (nitrogen trifluorides) |
The 2nd group | 35 (ethane) | 25 (perfluoro-ethylenes) | 20 (methylene fluoride) |
The 3rd group | 25 (propane) | 25 (propane 10, perfluoropropane 15) | 15 (perfluoropropane) |
The 4th group | 5 (2-methylbutanes) | 10 (1-butylene 2, Trimethylmethane 3,2-methylbutanes 5) | 15 (2-methylbutane 10, normal butanes 5) |
High voltage/low voltage | 1.8/0.3(MPa) | 1.8/0.4(MPa) | 2.2/0.5(MPa) |
COP | 0.356 | 0.647 | 1.04 |
CEF% | 17.8 | 32.4 | 52 |
Project | Mixture 1 volumetric molar concentration % | Mixture 2 volumetric molar concentration % | Mixture 3 volumetric molar concentration % |
The 1st group | 30 (tetrafluoromethane 25, nitrogen trifluorides 5) | 35 (tetrafluoromethanes) | 45 (nitrogen trifluorides) |
The 2nd group | 40 (ethene 5, ethane 5, trifluoromethane 5, xenon 5, methyl fuoride 5, perfluoro-ethylene 5, vinyl fluoride 5, R 116s 5) | 30 (perfluoro-ethylenes) | 25 (methylene fluoride) |
The 3rd group | 20 (propane) | 20 (propane 10, perfluoropropane 10) | 10 (perfluoropropane) |
The 4th group | 10 (2-methylbutanes) | 15 (1-butylene 4, Trimethylmethane 3,2-methylbutanes 8) | 20 (2-methylbutane 10, normal butanes 10) |
High voltage/low voltage | 1.8/0.6(MPa) | 2.0/0.4(MPa) | 2.2/0.5(MPa) |
COP | 0.726 | 1.03 | 1.24 |
CEF% | 31.1 | 44.1 | 53.1 |
Project | Mixture 1 volumetric molar concentration % | Mixture 2 volumetric molar concentration % | Mixture 3 volumetric molar concentration % |
The 1st group | 25 (tetrafluoromethane 20, nitrogen trifluorides 5) | 30 (tetrafluoromethanes) | 40 (nitrogen trifluorides) |
The 2nd group | 45 (methyl fuoride 10, perfluoro-ethylene 10, vinyl fluoride 10, R 116s 15) | 35 (perfluoro-ethylenes) | 30 (methylene fluoride) |
The 3rd group | 15 (propane) | 15 (propane 5, perfluoropropane 10) | 5 (perfluoropropane) |
The 4th group | 15 (Trimethylmethane 5,2-methylbutanes 10) | 20 (1-butylene 5, Trimethylmethane 5,2-methylbutanes 10) | 25 (2-methylbutane 10, normal butanes 15) |
High voltage/low voltage | 1.8/0.6(MPa) | 2.0/0.5(MPa) | 2.2/0.6(MPa) |
COP | 1.13 | 1.11 | 1.43 |
CEF% | 41.1 | 40.2 | 52.1 |
Project | Mixture 1 volumetric molar concentration % | Mixture 2 volumetric molar concentration % | Mixture 3 volumetric molar concentration % |
The 1st group | 20 (tetrafluoromethane 15, nitrogen trifluorides 5) | 25 (tetrafluoromethanes) | 35 (nitrogen trifluorides) |
The 2nd group | 50 (methyl fuoride 15, perfluoro-ethylene 10, vinyl fluoride 10, R 116s 15) | 40 (perfluoro-ethylenes) | 35 (methylene fluoride) |
The 3rd group | 10 (propane) | 10 (propane 5, perfluoropropane 5) | 0 |
The 4th group | 20 (1-butylene 2, Trimethylmethane 2,2-methylbutane 2,1-amylene 2,3-methyl-1-butene 2,2-methylpentane 1,2-butylene (cis) 1,2-butylene (trans) 1, tetramethylene 1, iso-butylene 1, normal butane 1, perfluorinated butane 1, Skellysolve A 1, perflenapent 2) | 25 (1-butylene 5, Trimethylmethane 10,2-methylbutanes 10) | 30 (2-methylbutane 10, normal butane 10, Trimethylmethanes 10) |
High voltage/low voltage | 1.8/0.6(MPa) | 2.0/0.5(MPa) | 2.2/0.7(MPa) |
COP | 1.562 | 1.433 | 1.67 |
CEF% | 47.5 | 43.6 | 50.8 |
Project | Mixture 1 volumetric molar concentration % | Mixture 2 volumetric molar concentration % | Mixture 3 volumetric molar concentration % |
The 1st group | 15 (tetrafluoromethane 10, nitrogen trifluorides 5) | 18 (tetrafluoromethanes) | 30 (nitrogen trifluorides) |
The 2nd group | 55 (methyl fuoride 15, perfluoro-ethylene 15, vinyl fluoride 10, R 116s 15) | 45 (perfluoro-ethylenes) | 40 (methylene fluoride) |
The 3rd group | 2 (propane) | 2 (propane) | 5 (perfluoropropane) |
The 4th group | 28 (Trimethylmethane 18,2-methylbutanes 10) | 35 (1-butylene 15, Trimethylmethane 10,2-methylbutanes 10) | 25 (2-methylbutane 10, normal butanes 15) |
High voltage/low voltage | 2.0/0.6(MPa) | 2.0/0.5(MPa) | 2.1/0.7(MPa) |
COP | 1.778 | 1.52 | 1.91 |
CEF% | 44.5 | 38.2 | 47.8 |
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 03121466 CN1194063C (en) | 2002-05-17 | 2003-03-28 | Multicomponent mixed work medium throttling refrigerant applicable to 200-204K refrigerating temperature zone |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN02117335.4 | 2002-05-17 | ||
CN02117335 | 2002-05-17 | ||
CN 03121466 CN1194063C (en) | 2002-05-17 | 2003-03-28 | Multicomponent mixed work medium throttling refrigerant applicable to 200-204K refrigerating temperature zone |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1460703A CN1460703A (en) | 2003-12-10 |
CN1194063C true CN1194063C (en) | 2005-03-23 |
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Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 03121466 Expired - Lifetime CN1194063C (en) | 2002-05-17 | 2003-03-28 | Multicomponent mixed work medium throttling refrigerant applicable to 200-204K refrigerating temperature zone |
Country Status (1)
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CN (1) | CN1194063C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105885798A (en) * | 2014-12-23 | 2016-08-24 | 张永康 | Non-combustible mixed refrigerant suitable for refrigeration temperature region at temperature of -135 DEG C to -105 DEG C |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100547050C (en) * | 2007-04-13 | 2009-10-07 | 中国科学院理化技术研究所 | A kind of mix refrigerant that is applicable to low temperature level in the two-stage multiplex refrigerating system |
CN101608860B (en) * | 2008-06-17 | 2011-08-17 | 北京安瑞科新能能源科技有限公司 | Gas liquefying process for mixed refrigerant and mixed refrigerant |
CN102559146B (en) * | 2010-12-17 | 2014-05-07 | 中科赛凌(北京)科技有限公司 | Non-combustible mixing refrigerant suitable for deep refrigeration temperature of minus 80 DEG C to minus 100 DEG C |
CN105586009A (en) * | 2014-10-29 | 2016-05-18 | 张永康 | Inflammable mixture refrigerant being suitable at refrigerating temperature zone of -75 - -105 DEG C |
CN108531135B (en) * | 2018-04-10 | 2021-05-07 | 龙志刚 | Mixed refrigerant suitable for cryogenic temperature zone and preparation method and application method thereof |
CN112778976A (en) * | 2020-12-24 | 2021-05-11 | 青岛营上电器有限公司 | Low-temperature refrigerant and preparation method and application thereof |
CN116606632B (en) * | 2023-07-19 | 2023-10-20 | 中科美菱低温科技股份有限公司 | Refrigerant and method for producing the same |
-
2003
- 2003-03-28 CN CN 03121466 patent/CN1194063C/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105885798A (en) * | 2014-12-23 | 2016-08-24 | 张永康 | Non-combustible mixed refrigerant suitable for refrigeration temperature region at temperature of -135 DEG C to -105 DEG C |
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CN1460703A (en) | 2003-12-10 |
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Owner name: CHINA-SCICOOLING (BEIJING) SCIENCE + TECHNOLOGY CO Free format text: FORMER OWNER: TECHNICAL INSTITUTE OF PHYSICS AND CHEMISTRY Effective date: 20121026 |
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Effective date of registration: 20121026 Address after: 102211 Beijing city Changping District town of Xiaotangshan Lin village before 386 Patentee after: CHINA-SCICOOLING (BEIJING) SCIENCE & TECHNOLOGY CO.,LTD. Address before: 100080 No. 2, north of Haidian District, Beijing, Zhongguancun Patentee before: Technical Institute of Physics and Chemistry Chinese Academy of Sciences |
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Application publication date: 20031210 Assignee: ZHONGKE MEILING CRYOGENICS Ltd. Assignor: CHINA-SCICOOLING (BEIJING) SCIENCE & TECHNOLOGY CO.,LTD. Contract record no.: 2015340000122 Denomination of invention: Multicomponent mixed work medium throttling refrigerant applicable to 200-204K refrigerating temperature zone Granted publication date: 20050323 License type: Exclusive License Record date: 20150820 |
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