CN1190464C - Environmental protection water encaustic tile coating and preparing method thereof - Google Patents

Abstract

The present invention relates to an environmental protection type encaustic tile coating which comprises the material proportioning: 15 to 40 portions of water, 0.2 to 0.7 portion of a dispersing agent, 0.1 to 0.2 portion of a foam control agent, 10 to 14 portions of pigment, 40 to 60 portions of emulsion, 3 to 10 portions of silica sol, 1.5 to 2.5 portions of a film forming auxiliary agent and 0.12 portion of a germicidal agent. The present invention also provides a preparing method of the environmental protection type encaustic tile coating, and the present invention has the following technical characteristics: 1. water is used as a solvent, and the proportion of the water is from 26 to 40%; compared with a toxic solvent in an oil encarpus tile coating, the method saves a large number of precious resources and simultaneously brings social benefits and environmental benefits; 2. The average cost of the present invention is 6 yuan/kg (material cost), but the average cost of an oil encarpus tile coating is 8 to 10 yuan/kg, so that the average cost is reduced by 30% more or less, and the product has the advantages of practicality and cheap price and consequentially has very large commercial value; 3. due to the advantages of no drug, no taste, no combustion and no explosion, the product of the present invention is very beneficial to both the safety and the production of producing environments and the collective health of users.

Description

A kind of environment-friendly type aqueous encaustic tile coating and preparation method thereof

Technical field

The invention belongs to the chemical building material field, is a kind of environment-friendly encaustic tile coating and preparation method thereof specifically.

Background technology

Clay shingle is a kind of destruction to the soil environment, and the tile kilning that fetches earth is in a large number forbidden that by country cement tile is promoted the use of in all parts of the country, thus a kind of new tiling is protected and finishing material----encaustic tile coating also just arises at the historic moment.But on the market, the known encaustic tile coating of cement tile tiling that is used for both at home and abroad is based on oiliness acrylate encaustic tile coating at present, its market requirement grows on a steady double-digit, and oiliness encaustic tile coating product generally contains toluene, dimethylbenzene, acetone equal solvent, and its ratio is up to 40-50%.As everyone knows, toluene, dimethylbenzene all are toxic substance, these materials only play carrier function aborning, finally all evaporate in the atmosphere, obviously there is contaminate environment, the waste resource, shortcomings such as cost height, the four E targets (energy, environment, efficient, economy) of this and modern humans's Sustainable development are incompatible.

Summary of the invention

The purpose of this invention is to provide a kind of environment-friendly type aqueous encaustic tile coating free from environmental pollution and preparation method thereof, to overcome the problem that the oiliness encaustic tile coating exists.

To achieve these goals, proportioning raw materials of the present invention is:

Water 15-40 part dispersion agent 0.2-0.7 part foam control agent 0.1-0.2 part pigment 10-14 part

0.12 part in emulsion 40-60 part silicon sol 3-10 part film coalescence aid 1.5-2.5 part sterilant

Also can add in the said ratio wetting agent and (or) defoamer;

Above-mentioned dispersion agent can be a kind of preparation, also can be that several formulations is mixed;

Above-mentioned pigment can be a kind of pigment, also can be that multiple pigment mixes;

Above-mentioned film coalescence aid can be a kind of auxiliary agent, also can be that multiple auxiliary agent mixes;

Above-mentioned emulsion is benzene emulsion, pure-acrylic emulsion, organosilicon crylic acid latex.

Preparation method of the present invention is:

1. the water of getting umber ready, dispersion agent, foam control agent and pigment through high speed dispersion, grinding;

2. in the mixture after the 1. step, add emulsion, and slowly add silicon sol and mix;

3. mix at a slow speed after in the mixture after the 2. step, adding film coalescence aid and sterilant;

4. will be 3. the gained mixture after filtration, packing gets product.

Key of the present invention is to utilize organic and characteristics separately inorganics, silicon sol for example, and it is when drying out, and monomer silicic acid aggregates into poly silicic acid gradually, and along with the evaporation of moisture, the colloid molecule increases, and forms Si-o-Si at last and films.Because the particle diameter of silicon sol is trickle, is molecularity, thereby strong to basic unit's seepage force, tack is good, and its inorganic polymer coating itself just has advantage acidproof, alkaline-resisting, high temperature resistant, good endurance.Si-o-Si films and does not produce static simultaneously, is difficult for the absorption dust, and stain resistance is good.The polymer organic polymer is (as benzene emulsion, pure-acrylic emulsion, organosilicon crylic acid latex etc.) the physicals characteristics of filming are that the degradation property of UV resistant is good, coating gloss height after the film forming, cohesive strength is big etc., the science collocation of this organism and inorganics, organic polymer is evenly distributed in the gap of Si-o-Si inorganic coating, remaining hydrophilic radical and when temperature Change colds and heat succeed each other in the shielded inorganic coating, the contraction of the slow coating of speeding, make coating have certain elasticity, the advantage of two kinds of materials just shows especially out, thereby obtain high-quality end product---water-based encarpus tile coating, what must remind is, add man-hour, order and speed that material adds also have certain influence to quality product.

The quality of product of the present invention all meets or exceeds corresponding national standards (country does not formulate the technical quality standard of water-based encarpus tile lacquer as yet at present, now adopts the GB/T9755-1995 standard), and detected result is as follows:

Test item	Standard-required	Measured result
			Application property	It is accessible to brush two roads	It is accessible to brush two roads
Appearance of film	Appearance of film is normal	Appearance of film is normal
			Alkali resistance (48h)	No abnormal	No abnormal
Abrasion resistance (inferior)	500 times	Do not have for 500 times damaged, show-through
			Coating heatproof degree (10 circulations)	No abnormal	No abnormal

At the ubiquitous wasting of resources of present oiliness encaustic tile coating, environmental pollution, expensive three big shortcomings, technical characterictic of the present invention is as follows:

1, with water as solvent, its ratio is 26-40%, this with the oiliness encaustic tile coating in about 35% noxious solvent---toluene, dimethylbenzene are compared, not only save a large amount of precious resources, social benefit that it brings simultaneously and environmental benefit are conspicuous;

2, the 6 yuan/kg of product cost average out to (raw materials cost) that produces with the present invention, and the production cost average out to 8-10 unit/kg (raw materials cost) of oiliness encaustic tile coating, average low about 30%, thereby the market value of water-based encarpus tile coating on average also hangs down about 30%, practical and cheap product must have great commercial value;

3, since the present invention selected be nontoxic or basic poisonous material, its product is nontoxic, tasteless, it is not quick-fried not fire, and all is very useful concerning safe, the production of production environment and user of service's collectivity health.

Description of drawings

Accompanying drawing is technological process of production figure of the present invention.

Embodiment

The present invention is further illustrated below in conjunction with embodiment, but should not be construed as limitation of the present invention.

Embodiment 1:

25.8 parts in water, 0.3 part of sodium hexametaphosphate dispersant, 0.18 part of foam control agent 681F, 0.1 part of wetting agent OP-10,12 parts of pigment (organic or inorganic pigment) iron oxide reds, through high speed dispersion (1500 rev/mins) 20 minutes, grind the back and add 50 parts of benzene emulsions (phenylethylene ethylene/propenoic acid ester copolymer emulsion), slowly add 10 parts of silicon sol, 1.5 parts of film coalescence aid lauryl alcohol esters, 0.12 part of sterilant YN-187 mixed (60 rev/mins) 20 minutes at a slow speed.Last bag filter is finished product.

Embodiment 2:

15.8 parts in water, 5,040 0.5 parts of dispersion agents, 0.18 part of foam control agent 681F, 4 parts of 3132 bright red mill bases, 9 parts of iron oxide reds are through high speed dispersion, grind the back and add benzene emulsion 55-60 part, slowly add 8 parts of silicon sol, 0.5 part of film coalescence aid propylene glycol (or ethylene glycol), 1.8 parts of film coalescence aid lauryl alcohol esters, 0.1 part of defoamer D309A, 0.12 part in sterilant mixes at a slow speed, filters and packages and is finished product.

Embodiment 3:

31.63 parts in water, 0.2 part of sodium hexametaphosphate dispersant, 0.2 part of foam control agent, 12 parts of iron oxide reds after high speed dispersion is ground, add 48 parts of pure-acrylic emulsions (acrylic ester polymerization emulsion), slowly add 6 parts of silicon sol, 1.7 parts of film coalescence aid lauryl alcohol esters, 0.12 part in sterilant, the hybrid filtering packing is finished product at a slow speed.

Embodiment 4:

26.63 parts in water, 0.15 part of sodium hexametaphosphate dispersant, 5,040 0.5 parts of dispersion agents, 0.2 part of foam control agent, 0.1 part of wetting agent DP-18,5 parts of 3132 bright red mill bases, 9 parts of iron oxide reds through high speed dispersion and after grinding, add 52 parts of pure-acrylic emulsions, slowly add 5 parts of silicon sol again, 0.5 part of film coalescence aid propylene glycol, 1.8 parts of lauryl alcohol esters, 0.12 part of anticorrosion and bactericidal agent MB-11, mix at a slow speed, filter and package and be finished product.

Embodiment 5:

38.78 parts in water, 0.3 part of sodium hexametaphosphate dispersant, 0.2 part of foam control agent, 12 parts of iron oxide reds, through high speed dispersion and grinding, add 44 parts of organosilicon crylic acid latexs (organosilicon modified acrylic ester copolymer emulsion), 1.6 parts of lauryl alcohol esters slowly add 3 parts of silicon sol again, 0.12 part in sterilant, uniform mixing stirred after 20 minutes, filtered and packaged and was finished product.

Embodiment 6:

28.58 parts in water, 0.2 part of sodium hexametaphosphate dispersant, 5,040 0.5 parts of dispersion agents, 0.2 part of foam control agent, 0.1 part of wetting agent DP-18,5 parts of 3132 bright red mill bases, 9 parts of iron oxide reds through high speed dispersion and after grinding, add 50 parts of organosilicon crylic acid latexs, slowly add 4 parts of silicon sol again, 0.5 part of film coalescence aid ethylene glycol, 1.8 parts of lauryl alcohol esters, 0.1 part of defoamer, 0.12 part in sterilant stirred at a slow speed 20 minutes, filtered and packaged and was finished product.

The foregoing description with its effect of order is: glossiness and hardness are more and more higher, but cost is more and more higher equally.

Claims (7)

1, a kind of environment-friendly encaustic tile coating, its proportioning raw materials is:

Water 15-40 part dispersion agent 0.2-0.7 part foam control agent 0.1-0.2 part pigment 10-14 part

0.12 part in emulsion 40-60 part silicon sol 3-10 part film coalescence aid 1.5-2.5 part sterilant

2, environment-friendly encaustic tile coating as claimed in claim 1, also can add in the proportioning wetting agent and (or) defoamer.

3, environment-friendly encaustic tile coating as claimed in claim 1, dispersion agent can be a kind of preparations, also can be that several formulations is mixed.

4, environment-friendly encaustic tile coating as claimed in claim 1, pigment can be a kind of pigment, also can be that multiple pigment mixes.

5, environment-friendly encaustic tile coating as claimed in claim 1, film coalescence aid can be a kind of auxiliary agents, also can be that multiple auxiliary agent mixes.

6, environment-friendly encaustic tile coating as claimed in claim 1, emulsion are benzene emulsion, pure-acrylic emulsion, organosilicon crylic acid latex.

7, the preparation method of environment-friendly encaustic tile coating as claimed in claim 1 is:

1. the water of getting umber ready, dispersion agent, foam control agent and pigment through high speed dispersion, grinding;

2. in the mixture after the 1. step, add emulsion, and slowly add silicon sol and mix;

3. mix at a slow speed after in the mixture after the 2. step, adding film coalescence aid and sterilant;

4. will be 3. the gained mixture after filtration, packing gets product.

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