CN1185490A - Method for making artificial fluorescent precious stone - Google Patents
Method for making artificial fluorescent precious stone Download PDFInfo
- Publication number
- CN1185490A CN1185490A CN 96122295 CN96122295A CN1185490A CN 1185490 A CN1185490 A CN 1185490A CN 96122295 CN96122295 CN 96122295 CN 96122295 A CN96122295 A CN 96122295A CN 1185490 A CN1185490 A CN 1185490A
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- China
- Prior art keywords
- power
- base material
- substrate material
- precious stone
- add
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
A method for making an artificial fluorescent precious stone, uses ZnS as base material, Au and Cu as activation agent which accounts for 1 X (10 to the power -6) - 5 X (10 to the power -6) (in wt.) of said base material, and adds Cu which accounts for (in wt.) 5 X (10 to the power -6) - 5 X (10 to the power -5) of said base material, said added materials can be AuCl3, CuCl2 and CuSO4 etc., common activation agent can be DyCl3, accounting for (in wt.) 1 X (10 to the power -6) - 1 X (10 to the power -5) of the base material, and CsCl as fluxing agent accounting for (in wt.) 0.5-1% of the base material. Said materials are passed through wet grinding by adding distilled water, baking, growing for 5-12 hours by gas-phase transport method at 1050-1200 degree C, HCl gas flow. The obtained precious stone is in hexagonal structure, transparent bright green, 5 hours in after glow and has no radioactivity.
Description
The invention belongs to the artificial crystal growth technology.
Hard mass is subjected to people with low basis, high quality and abundant colors to be liked, but the hard mass of fluorescent effect is not arranged at present as yet.
The making method that the purpose of this invention is to provide a kind of artificial fluorescent precious stone, this method technology is simple, the transparent bright green of the jewel of producing, it is also "dead" to reach 5 hours time of persistence.
For achieving the above object, the present invention adopts following technology:
Substrate material adopts ZnS, activator Au, Cu, and the add-on of Au is 1 * 10 of a substrate material weight
-6-5 * 10
-6, the add-on of Cu is 5 * 10 of a substrate material weight
-5* 10
-5, the adding form can be AuCl
3, CuCl
2, CuSO
4Deng, coactivator Dy, add-on is 1 * 10 of a substrate material weight
-6-1 * 10
-5, its effect can improve after-glow brightness, and the adding form can be DyCl
3, fusing assistant CsCl, add-on is the 0.5-1% of substrate material weight, can improve crystalline quality, prolongs time of persistence.Above-mentioned materials adds the distilled water wet grinding, oven dry, and 1050-1200 ℃ of following gas phase axle fortune method grown the HCl air-flow 5-12 hour.The jewel of making belongs to hexagonal structure, emmission spectrum 480-520nm, mohs hardness 4.5-5, refractive index 2.3-2.4, chromatic dispersion 0.157.
Below in conjunction with embodiment the present invention is specified.
Embodiment 1. takes by weighing substrate material ZnS 100g, activator CuSO
4Middle Cu concentration 8 * 10
-6, AuCl
3Middle Au concentration 3 * 10
-6, coactivator DyCl
3The concentration 1 * 10 of middle Dy
-6, fusing assistant CsCl 0.5g, adding distil water ground 48 hours, and silica tube is put in 120 ℃ of oven dry, 1100 ℃ of tube furnace temperature, HCl air-flow per minute 0.1L grew 8 hours.
Embodiment 2. takes by weighing substrate material ZnS 100g, activator CuSO
4Middle Cu concentration 5 * 10
-6, AuCl
3Middle Au concentration 5 * 10
-6, coactivator DyCl
3The concentration 2 * 10 of middle Dy
-6, fusing assistant CsCl 1g, all the other conditions are with embodiment 1.
Embodiment 3. takes by weighing substrate material ZnS 100g, activator CuSO
4Middle Cu concentration 1 * 10
-5, AuCl
3Middle Au concentration 2 * 10
-6, coactivator DyCl
3The concentration 1 * 10 of middle Dy
-5, fusing assistant CsCl 0.8g, all the other conditions are with embodiment 1.
Claims (1)
1, a kind of making method of artificial fluorescent precious stone is characterized in that substrate material adopts ZnS, activator Au, Cu, and the add-on of Au is 1 * 10 of a substrate material weight
-5* 10
-6, the add-on of Cu is 5 * 10 of a substrate material weight
-6-5 * 10
-5, the adding form can be AuCl
3, CuCl
2, CuSO
4Deng, coactivator Dy, add-on is 1 * 10 of a substrate material weight
-6-1 * 10
-5, the adding form can be DyCl
3, fusing assistant CsCl, add-on is the 0.5-1% of substrate material weight, wet grinding, oven dry, 1050-1200 ℃ of following gas phase transport method grown the HCl air-flow 5-12 hour.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 96122295 CN1185490A (en) | 1996-12-17 | 1996-12-17 | Method for making artificial fluorescent precious stone |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 96122295 CN1185490A (en) | 1996-12-17 | 1996-12-17 | Method for making artificial fluorescent precious stone |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1185490A true CN1185490A (en) | 1998-06-24 |
Family
ID=5127238
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 96122295 Pending CN1185490A (en) | 1996-12-17 | 1996-12-17 | Method for making artificial fluorescent precious stone |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1185490A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1330736C (en) * | 2002-09-30 | 2007-08-08 | 株式会社东芝 | Phosphor for display device, its production method, and color display device using the same |
-
1996
- 1996-12-17 CN CN 96122295 patent/CN1185490A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1330736C (en) * | 2002-09-30 | 2007-08-08 | 株式会社东芝 | Phosphor for display device, its production method, and color display device using the same |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |