CN1183445A - Water expansion fire-proof adhesive - Google Patents
Water expansion fire-proof adhesive Download PDFInfo
- Publication number
- CN1183445A CN1183445A CN 97125834 CN97125834A CN1183445A CN 1183445 A CN1183445 A CN 1183445A CN 97125834 CN97125834 CN 97125834 CN 97125834 A CN97125834 A CN 97125834A CN 1183445 A CN1183445 A CN 1183445A
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- CN
- China
- Prior art keywords
- fire
- melamine
- water
- tetramethylolmethane
- ammonium polyphosphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
An expanding water fire-proof adhesive is prepared from filmforming substance of poly(vinylacetate) emulsion, or acrylic polymer and adhesive 107, or adhesive 107 and poly(vinylacetate) emulsion, ammonium polyphosphate, pentaerythrite and melamine through heating, synthesis, dispersion, grinding and addition of assistant, and features expanding nature when it meets fire, excellent fire-proof and physical properties, and use of water as diluent. It can be used to make fire-proof board or sprayed onto surface for flame-retarding.
Description
The present invention relates to a kind of caking agent, particularly a kind of water expansion fire-proof adhesive, can be widely used in the bonding manufacturing of fire-proof product.
Traditional product---the caking agent of making wadding plank, fiberboard, veneer sheet use is not all prevented fires, and after China on October 1 nineteen ninety-five " Building Fire Protection standard " issue, all kinds of fire prevention series products all arise at the historic moment, yet only make one of main raw material of PLASTIC LAMINATED again---high-performance fire prevention glue, still need from external import, cost is too high, and is flammable with the product of non-fire prevention glue manufacturing, do not prevent fires.The substitute products of present domestic development then because the standard of performance that can reach is low, according to the requirement of " standard ", also can only deserve to be called the glue based flame retardant at most, and desired fire-protection rating also has a segment distance in " standard ".
The objective of the invention is to overcome above-mentioned the deficiencies in the prior art, is that thinner, chance fire can be formed into the blocking-up of carbon expander flame, fire resistance and the good water expansion fire-proof adhesive of physicals with water and provide a kind of.
Provided by the present invention is that thinner, chance fire can be formed into the blocking-up of carbon expander flame, fire resistance and the good water expansion fire-proof adhesive of physicals with water, it can with the poly-rare ester emulsion of acetate second be main film forming matter with raw materials such as ammonium polyphosphate, tetramethylolmethane, melamine through heating, synthetic, disperse, add effective auxiliary agent after the grinding and make each component material consumption: (weight unit is identical)
The poly-rare ester emulsion 170~260 of acetate second
Ammonium polyphosphate 160~230
Tetramethylolmethane 100~140
Melamine 100~140
Auxiliary agent 95~125
Water 130~500.
Provided by the present invention is that thinner, chance fire can be formed into the blocking-up of carbon expander flame, fire resistance and the good water expansion fire-proof adhesive of physicals with water, it also can with vinylformic acid styrene polymer and 107 glue be raw materials such as main film forming matter and ammonium polyphosphate, tetramethylolmethane, melamine through heating, synthetic, add effective auxiliary agent after disperseing, grinding and make each component material consumption: (weight unit is identical)
Vinylformic acid styrene polymer 119~182
107 glue 51~78
Ammonium polyphosphate 160~230
Tetramethylolmethane 100~140
Melamine 100~140
Auxiliary agent 95~125
Water 130~500.
Provided by the present invention is that thinner, chance fire can be formed into the blocking-up of carbon expander flame, fire resistance and the good water expansion fire-proof adhesive of physicals with water, it can also with vinylformic acid styrene polymer and 107 glue and the poly-rare ester emulsion of acetate second be main film forming matter with raw materials such as ammonium polyphosphate, tetramethylolmethane, melamine through heating, synthetic, disperse, add effective auxiliary agent after the grinding and make each component material consumption: (weight unit is identical)
Vinylformic acid styrene polymer 119~182
107 glue 0~60
The poly-rare ester emulsion 0~78 of acetate second
Ammonium polyphosphate 160~230
Tetramethylolmethane 100~140
Melamine 100~140
Auxiliary agent 95~125
Water 130~500.
Water expansion fire-proof adhesive LSZH provided by the present invention, translucent, it is good that the chance fire can be formed into carbon expander blocking-up flame, fire resistance and physicals, with water is the thinner dilution, can replace PLASTIC LAMINATED such as non-fire prevention glue manufacturing fire prevention wadding plank, fiberboard, veneer sheet, as the bonding compound of back-fire relief of product of rubber and plastic, can also be sprayed on some needs fire-retardant material surface or uses as undercoat.
The present invention is described in further detail below in conjunction with example:
What the embodiment of the invention 1 was provided is that thinner, chance fire can be formed into the blocking-up of carbon expander flame, fire resistance and the good water expansion fire-proof adhesive of physicals with water, it with the poly-rare ester emulsion of acetate second be main film forming matter with raw materials such as ammonium polyphosphate, tetramethylolmethane, melamine through heating, synthetic, disperse, add effective auxiliary agent after the grinding and make, adjuvant used is formaldehyde, clorafin, Sodium hexametaphosphate 99 and methylcellulose gum, each component material consumption: (weight unit is identical)
The poly-rare ester emulsion 210 of acetate second
Ammonium polyphosphate 210
Tetramethylolmethane 130
Melamine 130
Formaldehyde 30
Clorafin 60
Sodium hexametaphosphate 99 10
Methylcellulose gum 20
Water 400.
What the embodiment of the invention 2 was provided is that thinner, chance fire can be formed into the blocking-up of carbon expander flame, fire resistance and the good water expansion fire-proof adhesive of physicals with water, it with vinylformic acid styrene polymer and 107 glue be raw materials such as main film forming matter and ammonium polyphosphate, tetramethylolmethane, melamine through heating, synthetic, add effective auxiliary agent after disperseing, grinding and make, adjuvant used is formaldehyde, clorafin, Sodium hexametaphosphate 99 and methylcellulose gum, each component material consumption: (weight unit is identical)
Vinylformic acid styrene polymer 147
107 glue 63
Ammonium polyphosphate 210
Tetramethylolmethane 130
Melamine 130
Formaldehyde 30
Clorafin 60
Sodium hexametaphosphate 99 10
Methylcellulose gum 20
Water 400.
What the embodiment of the invention 3 was provided is that thinner, chance fire can be formed into the blocking-up of carbon expander flame, fire resistance and the good water expansion fire-proof adhesive of physicals with water, it with vinylformic acid styrene polymer and 107 glue and the poly-rare ester emulsion of acetate second be main film forming matter with raw materials such as ammonium polyphosphate, tetramethylolmethane, melamine through heating, synthetic, disperse, add effective auxiliary agent after the grinding and make, adjuvant used is formaldehyde, clorafin, Sodium hexametaphosphate 99 and methylcellulose gum, each component material consumption: (weight unit is identical)
Vinylformic acid styrene polymer 147
107 glue 33
The poly-rare ester emulsion 30 of acetate second
Ammonium polyphosphate 210
Tetramethylolmethane 130
Melamine 130
Formaldehyde 30
Clorafin 60
Sodium hexametaphosphate 99 10
Methylcellulose gum 20
Water 400.
Claims (3)
1, a kind of water expansion fire-proof adhesive, it is characterized in that: it with the poly-rare ester emulsion of acetate second be main film forming matter with raw materials such as ammonium polyphosphate, tetramethylolmethane, melamine through heating, synthetic, disperse, add effective auxiliary agent after the grinding and make each component material consumption: (weight unit is identical)
The poly-rare ester emulsion 170~260 of acetate second
Ammonium polyphosphate 160~230
Tetramethylolmethane 100~140
Melamine 100~140
Auxiliary agent 95~125
Water 130~500.
2, a kind of water expansion fire-proof adhesive, it is characterized in that: it with vinylformic acid styrene polymer and 107 glue be raw materials such as main film forming matter and ammonium polyphosphate, tetramethylolmethane, melamine through heating, synthetic, add effective auxiliary agent after disperseing, grinding and make each component material consumption: (weight unit is identical)
Vinylformic acid styrene polymer 119~182
107 glue 51~78
Ammonium polyphosphate 160~230
Tetramethylolmethane 100~140
Melamine 100~140
Auxiliary agent 95~125
Water 130~500.
3, a kind of water expansion fire-proof adhesive, it is characterized in that: it with vinylformic acid styrene polymer and 107 glue and the poly-rare ester emulsion of acetate second be main film forming matter with raw materials such as ammonium polyphosphate, tetramethylolmethane, melamine through heating, synthetic, disperse, add effective auxiliary agent after the grinding and make each component material consumption: (weight unit is identical)
Vinylformic acid styrene polymer 119~182
107 glue 0~60
The poly-rare ester emulsion 0~78 of acetate second
Ammonium polyphosphate 160~230
Tetramethylolmethane 100~140
Melamine 100~140
Auxiliary agent 95~125
Water 130~500.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 97125834 CN1183445A (en) | 1997-12-25 | 1997-12-25 | Water expansion fire-proof adhesive |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 97125834 CN1183445A (en) | 1997-12-25 | 1997-12-25 | Water expansion fire-proof adhesive |
Publications (1)
Publication Number | Publication Date |
---|---|
CN1183445A true CN1183445A (en) | 1998-06-03 |
Family
ID=5177426
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 97125834 Pending CN1183445A (en) | 1997-12-25 | 1997-12-25 | Water expansion fire-proof adhesive |
Country Status (1)
Country | Link |
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CN (1) | CN1183445A (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1460119A1 (en) * | 2003-03-18 | 2004-09-22 | tesa AG | Flameproof adhesive, its production as well as its use in the production of adhesive tape |
CN1315938C (en) * | 2004-08-03 | 2007-05-16 | 李树志 | Terpolymerized redispersable emulsion powder and its producing method |
CN100368487C (en) * | 2002-12-20 | 2008-02-13 | 亿立欧公司 | Polymer binder for intumescent coatings |
WO2010062438A3 (en) * | 2008-11-26 | 2010-09-16 | Avery Dennison Corporation | Printable flame retardant polymeric film |
CN101838517A (en) * | 2009-03-18 | 2010-09-22 | 河北天海纵横科技有限责任公司 | Water-based fireproof sealant with low total smoke release during combustion |
CN101955710A (en) * | 2010-05-14 | 2011-01-26 | 袁雪祥 | Water-borne nano ultra-thin steel structure fire retardant coating and preparation method thereof |
CN102492344A (en) * | 2011-12-13 | 2012-06-13 | 深圳市嘉卓成科技发展有限公司 | Plastic veneer type thermoplastic acrylic environment-friendly fireproof paint and method for preparing and using same |
CN102533009A (en) * | 2011-12-30 | 2012-07-04 | 深圳市嘉卓成科技发展有限公司 | Monocomponent aqueous environmentally-friendly fireproof paint for plastic as well as preparation and use methods thereof |
CN105602364A (en) * | 2016-03-27 | 2016-05-25 | 张耀忠 | Intumescent fire-retardant coating |
CN106189426A (en) * | 2016-08-17 | 2016-12-07 | 张娟 | A kind of fire-resistant gluing |
CN107903849A (en) * | 2017-11-03 | 2018-04-13 | 常州市雄泰纺织品有限公司 | A kind of preparation method of high temperature resistant type fireproof foam adhesive |
-
1997
- 1997-12-25 CN CN 97125834 patent/CN1183445A/en active Pending
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100368487C (en) * | 2002-12-20 | 2008-02-13 | 亿立欧公司 | Polymer binder for intumescent coatings |
EP1460119A1 (en) * | 2003-03-18 | 2004-09-22 | tesa AG | Flameproof adhesive, its production as well as its use in the production of adhesive tape |
CN1315938C (en) * | 2004-08-03 | 2007-05-16 | 李树志 | Terpolymerized redispersable emulsion powder and its producing method |
WO2010062438A3 (en) * | 2008-11-26 | 2010-09-16 | Avery Dennison Corporation | Printable flame retardant polymeric film |
CN101838517A (en) * | 2009-03-18 | 2010-09-22 | 河北天海纵横科技有限责任公司 | Water-based fireproof sealant with low total smoke release during combustion |
CN101955710A (en) * | 2010-05-14 | 2011-01-26 | 袁雪祥 | Water-borne nano ultra-thin steel structure fire retardant coating and preparation method thereof |
CN101955710B (en) * | 2010-05-14 | 2012-10-24 | 袁雪祥 | Water-borne nano ultra-thin steel structure fire retardant coating and preparation method thereof |
CN102492344A (en) * | 2011-12-13 | 2012-06-13 | 深圳市嘉卓成科技发展有限公司 | Plastic veneer type thermoplastic acrylic environment-friendly fireproof paint and method for preparing and using same |
CN102533009A (en) * | 2011-12-30 | 2012-07-04 | 深圳市嘉卓成科技发展有限公司 | Monocomponent aqueous environmentally-friendly fireproof paint for plastic as well as preparation and use methods thereof |
CN105602364A (en) * | 2016-03-27 | 2016-05-25 | 张耀忠 | Intumescent fire-retardant coating |
CN106189426A (en) * | 2016-08-17 | 2016-12-07 | 张娟 | A kind of fire-resistant gluing |
CN107903849A (en) * | 2017-11-03 | 2018-04-13 | 常州市雄泰纺织品有限公司 | A kind of preparation method of high temperature resistant type fireproof foam adhesive |
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C06 | Publication | ||
PB01 | Publication | ||
C01 | Deemed withdrawal of patent application (patent law 1993) | ||
WD01 | Invention patent application deemed withdrawn after publication |