CN118293520A - Water anion air conditioner and water anion generating device thereof - Google Patents

Water anion air conditioner and water anion generating device thereof Download PDF

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Publication number
CN118293520A
CN118293520A CN202310243428.8A CN202310243428A CN118293520A CN 118293520 A CN118293520 A CN 118293520A CN 202310243428 A CN202310243428 A CN 202310243428A CN 118293520 A CN118293520 A CN 118293520A
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China
Prior art keywords
water
charging
water mist
mist
charging needle
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Pending
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CN202310243428.8A
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Chinese (zh)
Inventor
厉亚
陈黎俊
周刚
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Zhejiang Shuilichi Health Technology Co ltd
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Zhejiang Shuilichi Health Technology Co ltd
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Priority to CN202310243428.8A priority Critical patent/CN118293520A/en
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Abstract

The water anion air conditioner comprises an air conditioner main rest and a water anion generating device, wherein the water anion generating device comprises a water mist generating device and a high-voltage charging device, the water mist generating device comprises a liquid storage cavity and a water mist generator, the water mist generator atomizes liquid from the liquid storage cavity to generate water mist, and the high-voltage charging device is used for charging the water mist generated by the water mist generating device to generate water anions beneficial to human health and purified air.

Description

Water anion air conditioner and water anion generating device thereof
Technical Field
The invention relates to the technical field of anions, in particular to a water anion air conditioner and a device for generating water anions by discharging atomized liquid drops.
Background
With the importance of people on ambient air and healthy respiration, negative ion series products begin to appear on the market. Conventional negative ion generating devices generally generate negative ions by corona discharge. Specifically, electrons are generated in the corona process, and oxygen molecules O 2 in the air have more electrophilicity than molecules such as CO 2,N2, so that the oxygen molecules can preferentially obtain electrons to form air anions, and the oxygen molecules in the air anions are more occupied, so that the air anions are also commonly called air negative oxygen ions.
The negative oxygen ions in the air generated by the high-voltage static electricity rise to several kilovolts through a transformer booster circuit, and electrons are released into the air through the tip. On the one hand, the technical characteristics are that a large amount of electrons can be generated, when a large amount of electrons are generated, the electrons do not have carriers, the carriers can be searched at the fastest speed, besides being combined with oxygen molecules, the electrons can be combined on the surface of metal, an insulating material shell, and flow to the ground at the fastest speed, so that air negative oxygen ions generated by the traditional negative ion generating equipment are caused, the migration distance of the air negative oxygen ions is limited, and the radiation area of the negative oxygen ions generated in the environment is smaller. And in the dry condition these electrons attach to form static electricity around the device. The environment surface is blackened due to a large amount of static electricity in the vicinity of the device. At the same time, secondary pollution is caused by ionizing air, for example, ozone is generated by ionizing oxygen in the air.
In addition, the existing air conditioner can adjust the air state in the indoor environment, but does not have a function of providing negative ions.
Disclosure of Invention
In order to solve the above technical problems, the present invention provides a water anion generating apparatus for generating water anions by discharging atomized droplets, comprising:
A mist generating device comprising a liquid storage chamber and a mist generator, wherein the mist generator atomizes liquid from the liquid storage chamber to generate a mist; and
And the high-voltage charging device is used for charging the water mist generated by the water mist generating device so as to generate water anions.
Preferably, the water mist generator is selected from one of a venturi-type atomizer, an ultrasonic vibration atomizer, and a heating atomizer.
Preferably, the high-voltage charging device comprises a charging needle capable of charging the water mist generated by the water mist generating device, and the working voltage of the charging needle is above-4 kv.
Preferably, when the working voltage of the charging needle is between-4 kv and-6 kv, the distance between the position of the charging needle and the center position of the adjacent water mist generator is greater than 10mm.
Preferably, when the working voltage of the charging needle is between-6 kv and-8 kv, the distance between the position of the charging needle and the center position of the adjacent water mist generator is greater than 15mm.
Preferably, when the working voltage of the charging needle is between-8 kv and-11 kv, the distance between the position of the charging needle and the center position of the adjacent water mist generator is greater than 20mm.
Preferably, the working voltage of the charging needle is between-4 kv and-11 kv, and the distance between the position of the charging needle and the central position of the adjacent water mist generator is between 20mm and 30 mm.
Preferably, the water mist generating device comprises a plurality of rows of water mist generators which are arranged at intervals, each row of water mist generator comprises one or more water mist generators, and one or more charging needles are arranged between two adjacent rows of water mist generators.
Preferably, the water mist generating device comprises a plurality of water mist generators arranged around one charging needle, and the distances between the plurality of water mist generators and the charging needle are equal.
Preferably, the water anion generating device further comprises an air flow pushing device, which comprises a pushing fan and a filter screen, wherein under the action of the pushing fan, air is blown to the water mist generator of the water mist generating device and the charging needle of the high-voltage charging device after being filtered by the filter screen.
Preferably, the high-voltage charging device comprises an air guide cavity, and the charging needle is mounted at the opening end of the air guide cavity, so that the pushing air flow generated by the pushing fan reaches the charging needle through the air guide cavity to be ionized.
The invention also provides a water anion air conditioner which comprises an air conditioner main body and the water anion generating device assembled on the air conditioner main body.
The invention also provides a water anion generating method, which comprises the following steps:
Generating water mist through a water mist generator of the water mist generating device; and
And charging the water mist generated by the water mist generator through a charging needle head of the high-voltage charging device so as to generate water anions.
Preferably, in the above method, when the operating voltage of the charging needle is between-4 kv and-6 kv, a distance between the position of the charging needle and a center position of the adjacent water mist generator is greater than 10mm; when the working voltage of the charging needle head is between minus 6kv and minus 8kv, the distance between the position of the charging needle head and the center position of the adjacent water mist generator is more than 15mm; when the working voltage of the charging needle head is between-8 kv and-11 kv, the distance between the position of the charging needle head and the center position of the adjacent water mist generator is more than 20mm.
Preferably, a plurality of the mist generators are periodically operated in batches to generate mist.
Preferably, the air flow pushing device generates pushing air flow to flow through the water mist generator and the charging needle, so that water anions are carried to migrate to the environment.
The invention has the beneficial effects that:
(1) The water mist generating device generates water mist and the high-voltage charging device charges the water mist so that the water mist absorbs negative ions to generate water negative ions beneficial to human health and air purification.
(2) Negative ions generated during the operation of the high-voltage charging device are timely absorbed by the water mist, so that the water negative ion generating device avoids generating static electricity and ozone relative to generating air negative ions through high-voltage ionization.
(3) The negative ion generating device generates various water anions such as water anions containing O 2 -negative molecular groups [ O 2-(H2 O) n, H+ negative molecular groups [ H 302-(H2 O) n, HO-negative molecular groups OH- (H 2 O) n, negative water molecules- (H 2 O) n and the like by discharging the water mist, so that the generated water anions are more beneficial to the sanatorium health care of human bodies.
(4) The water mist generating device can also be configured to generate negative ions, namely, the water mist generating device generates water mist with negative ions and further absorbs the negative ions generated by the high-voltage charging device, so that the negative ion generating device of the invention can obviously increase the concentration of the generated water negative ions.
(5) The water anions generated by the anion generating device are far away from the diffusion distance in the environment under the action of the airflow pushing device, so that the functions of recuperating and health care of human bodies and purifying air can be achieved in a large range.
(6) When the water anion air conditioner is used for adjusting and controlling parameters such as temperature, humidity, flow rate and the like in the environment, water anions can be released into the environment, so that the environment air is purified and the medical bond-protecting function is realized for a human body.
Drawings
Fig. 1 is a block diagram schematically illustrating a water anion air conditioner according to an embodiment of the present invention.
Fig. 2 is a perspective view illustrating a water anion air conditioner of the above embodiment of the present invention.
Fig. 3 is a schematic structural view showing the arrangement relationship of the water mist generating device and the high-voltage charging device of the water anion generating device of the above embodiment of the present invention.
Detailed Description
The terms and words used in the following description are not limited to literal meanings, but are used only by the inventors to enable a clear and consistent understanding of the application. It will be apparent to those skilled in the art, therefore, that the following description of the various embodiments of the application is provided for illustration only and not for the purpose of limiting the application as defined by the appended claims and their equivalents.
Although ordinal numbers such as "first," "second," etc., will be used to describe various components, those components are not limited herein. The term is used merely to distinguish one component from another. For example, a first component may be referred to as a second component, and likewise, a second component may be referred to as a first component, without departing from the teachings of the present inventive concept. The term "and/or" as used herein includes any and all combinations of one or more of the associated listed items.
The terminology used herein is for the purpose of describing various embodiments only and is not intended to be limiting. As used herein, the singular is intended to include the plural as well, unless the context clearly indicates otherwise. It will be further understood that the terms "comprises" and/or "comprising," when used in this specification, specify the presence of stated features, integers, steps, operations, elements, or groups thereof, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, or groups thereof.
As shown in fig. 1 to 3, a water anion air conditioner 1000 and a water anion generating apparatus 100 thereof according to an embodiment of the present invention, the water anion generating apparatus 100 includes a water mist generating apparatus 10, a high voltage charging apparatus 20 and an air current pushing apparatus 30, wherein the water mist generating apparatus 10, the high voltage charging apparatus 20 and the air current pushing apparatus 30 may be assembled in a case, the water mist generating apparatus 10 is used to generate water mist, the high voltage charging apparatus 30 charges the water mist generated by the water mist generating apparatus 10 to generate water anions, and the air current pushing apparatus 30 blows the water anions to the environment outside the case for increasing the concentration of anions in the environment, thereby purifying air and being beneficial to the health care of the human body.
The water anion air conditioner 1000 includes an air conditioner main body 100 and the water anion generating apparatus 100, and the water anion generating apparatus 100 is installed at the air conditioner main body 1001 so as to add a function of providing water anions to the water anion air conditioner 1000. The air conditioner body 1001 has a structure of a general air conditioner, which may include a structure such as a box, a cooling system and/or a warm air system, a wind path system, a humidifying system, an electric system, etc., so that the air conditioner operates normally. It is to be understood that the air conditioner body 1001 may be a central air conditioner, an indoor wall-mounted air conditioner, a floor air conditioner, a vehicle air conditioner, or the like.
The water anion generating apparatus 100 may be used alone or may be assembled in other air conditioning devices such as an air cleaner, a fresh air system, etc.
More specifically, the water mist generating device 10 includes a liquid storage chamber 11 and one or more water mist generators 12, wherein the liquid storage chamber 11 is used for storing liquid for the water mist generators 12 to generate water mist, and the liquid stored in the liquid storage chamber 11 can be various suitable liquid water, such as purified drinking water, conductive negative ion drinking liquid, mineral drinking water, and the like.
The mist generator 12 is a variety of devices capable of generating mist from the liquid storage chamber 11, and as in one embodiment may be embodied as a venturi-type atomizer, which may include a constriction tube, a throat, a water spraying device and a diffuser tube, wherein the relative flow rates of the gas and liquid phases in the constriction tube and throat are large, and the droplets ejected from the nozzles are further atomized into finer droplets under the impact of high-velocity air flow. In another embodiment, the mist generator 12 may have a heating device for heating the liquid to generate a mist. Alternatively, in another embodiment, the water mist generator 12 may be an ultrasonic vibration atomizer, which breaks up the liquid water molecular structure to generate water mist by high frequency resonance of the ceramic atomizing plate.
The high-voltage charging device 20 comprises one or more charging needles 21 and a booster circuit 22, the booster circuit 22 boosts the voltage to above-4 kv, and the charging needles 21 are electrically connected to the booster circuit 22 to charge the water mist generated by the water mist generator 12, i.e. electrons generated by the charging needles 21 are timely absorbed by the water mist generated by the water mist generator 12, so that negative ion water mist rich in negative ions is generated. The high-voltage charging device 20 may share the power supply 14 with the mist generator 12, or may be configured with a power supply separately.
In the present invention, the mist generator 12 is driven to vibrate at a high frequency by a voltage of a predetermined frequency and a peak value, and the center position 121 thereof is a center position for converting the liquid into droplets, which is required to be kept at a predetermined distance D from the charging needle 21, so that the mist droplets generated by the mist generator 12 are prevented from adhering to the charging needle 21 due to the too close distance, and further, an arc is prevented from occurring between the charging needle 21 and the mist generator 12, resulting in high-voltage discharge of the entire water anion generating device 100 by the charging needle 21. The charging needle 21 is made of a corrosion-resistant material, preferably 316L stainless steel.
In the present invention, it is found from experimental data that it is preferable that the distance D between the position of the charging needle 21 and the center position 121 of the mist generator 12 of the mist generating means 10 is as follows:
When the operating voltage of the charging needle 21 is between-4 kv and-6 kv, the distance D between the position of the charging needle 21 and the center position 121 of the water mist generator 12 of the water mist generating device 10 is greater than 10mm.
When the operating voltage of the charging needle 21 is between-6 kv and-8 kv, the distance D between the position of the charging needle 21 and the center position 121 of the water mist generator 12 of the water mist generating device 10 is greater than 15mm.
When the working voltage of the charging needle 21 is between-8 kv and-11 kv, the distance D between the position of the charging needle 21 and the center position 121 of the water mist generator 12 of the water mist generating device 10 is greater than 20mm.
Preferably, for example, in a specific example, the distance D between the position of the charging needle 21 and the central position 121 of the mist generating device 10 may be chosen to be 30mm, the voltage of the charging needle 21 being preferably-10 kv.
It will be appreciated that in the example shown in fig. 3, the central positions 121 of the plurality of said mist generators 12 around each said charging needle 21 are equal to the distance D between them, and that in other variant embodiments the central positions 121 of these said mist generators 12 may also be different from the positions of the corresponding said charging needles 21, but the distance D suffices to be greater than 10mm.
It will be appreciated by those skilled in the art that the arrangement of the charging needles 21 and the mist generator 12 may be varied according to design requirements, so long as the distance D between each charging needle 21 and the central position 121 of the corresponding mist generator 12 is ensured to satisfy the above-mentioned condition.
For example, in the example shown in fig. 3, the water anion generating apparatus 100 includes one of the charging needles 21 and a plurality of the mist generators 12 arranged in an annular direction, for example, six of the mist generators 12 are circumferentially arranged around the charging needle 21, so that the charging needle 21 charges the mist generated by the surrounding six of the mist generators 12 to form a water anion mist. And preferably, as shown in fig. 3, the distance D between the center position 121 of each of the mist generators 12 and the center charging needle 121 is equal.
In this example, the line connecting the central locations 121 of six of the mist generators 12 may form a circle, i.e. six of the mist generators 12 are arranged on a circle. In other variant embodiments, the line connecting the central locations 121 of the plurality of mist generators 12 may form other shapes, such as triangles, pentagons, hexagons, octagons, etc., the polygonal shape of which may be regular or irregular, and the plurality of mist generators 12 surround one of the charging pins 12 to capture and absorb electrons ionized by the charging pins 12.
Of the water mist generators 12 in the annular arrangement shown in fig. 3, these water mist generators 12 may be operated together to generate water mist at the same time or alternately to generate water mist, for example, three groups of two water mist generators 12 each, and the two water mist generators 12 of each group may be two adjacent water mist generators 12, two water mist generators 12 located at both ends of the diameter, or two water mist generators 12 may be selected with one water mist generator 12 in between, and only one group of water mist generators 12 may be in operation. In other examples, the water mist generators 12 may be divided into two groups of three water mist generators 12, and the three water mist generators 12 of each group may be adjacent consecutive three water mist generators 12, or an odd number of water mist generators 12 may be one group, an even number of water mist generators 12 may be another group, and the two water mist generators 12 may alternately operate.
In further implementations, the water anion generating apparatus 100 may include a plurality of columns of the water mist generators 12 arranged at intervals from each other, each column of the water mist generators 12 including one or more of the water mist generators 12, e.g., each column of the water mist generators 12 including a plurality of the water mist generators 12, wherein the water anion generating apparatus includes a plurality of the charging needles 21, each of the charging needles 21 being located between two adjacent columns of the water mist generators 12.
Each charging needle 21 is located at a central position of a plurality of the mist generators 12, and a distance D between each charging needle 21 and a central position 121 of a plurality of the mist generators 12 is equal, for example, 30mm. In this way, when the charging needles 21 each ionize to generate electrons, the plurality of mesh atomizing sheets 121 located therearound generate water mist and absorb electrons generated by ionization of the charging needle 21 located at the center thereof to form water negative ion water mist.
The tip of the charging needle 21 may or may not be coplanar with the water mist generating surface of the water mist generator 12, and the charging needle 21 may be positioned near the front or near the rear of the water mist generating surface of the water mist generator 12.
It will be appreciated that these mist generators 12 may be driven to operate simultaneously or periodically in batches. For example, a plurality of rows of said mist generators 12 may be operated alternately in sequence, or a plurality of rows of said mist generators 12 may be operated alternately, or in some other manner. Preferably, when the water mist generators 12 are periodically activated to operate, at least one water mist generator 12 around each charging needle 21 is in an operating state to generate water mist during the same period of time, so as to absorb electrons ionized by the corresponding charging needle 21.
The air flow pushing device 30 comprises a pushing fan 31 and one or more filter screens 32, wherein the pushing fan 31 rotates to generate air flow, and a turbine fan is adopted as a fan preferred scheme. The filter screen 32 serves to filter air so that relatively clean air is sent by the push fan 31 to the water mist generating device 10 and the charging needle 21 of the high voltage charging device 20. More specifically, the box further has an air inlet, wherein air is blown to the charging needles 21 of the mist generating device 10 and the high-voltage charging device 20 after entering the box from the air inlet of the box and being filtered by the filter screen 32 under the action of the pushing fan 31, so that the water negative ion mist generated by the cooperation of the mist generating device 10 and the high-voltage charging device 20 is blown to the environment outside the box, so as to increase the migration distance of the water negative ion mist.
In this embodiment, the air flow propelling device 30 may comprise three layers of filter screens 32, which are, in order of the air flow path, a primary filter screen for blocking large particles such as hair and filtering dust of 5 μm or more, a resident electrode cleaning filter screen formed of interlaced fibers, in which particles and microorganisms suspended therein are blocked on the surface of the fiber material as the air flow passes through the filter, for sterilization and dust accumulation, and a High efficiency particulate filter screen (Hepa, high-EFFICIENCY PARTICULATE ARRESTANCE) for removing PM2.5 particles, respectively.
The high voltage charging device 20 further comprises an air guiding cavity 23, the charging needle 21 is mounted at an opening end 231 of the air guiding cavity 23, so that the pushing air flow generated by the pushing fan 31 reaches the charging needle 21 via the air guiding cavity 23 to be ionized, and the air guiding cavity 23 is used for guiding the air flow to increase the wind speed at the position of the charging needle 21, so that the water mist generated by the water mist generating device 10 is not easy to adhere to the charging needle 21.
While the basic principles of the present application have been described above in connection with specific embodiments, it should be noted that the advantages, benefits, effects, etc. mentioned in this application are merely examples and are not to be considered as limiting, and these advantages, benefits, effects, etc. are essential to the various embodiments of the present application. Furthermore, the foregoing detailed description has been given for illustrative purposes only and for ease of understanding, and is not intended to limit the application to the specific details described.
The block diagrams of the devices, apparatuses, devices, systems referred to in the present application are only illustrative examples and are not intended to require or imply that the connections, arrangements, configurations must be made in the manner shown in the block diagrams. As will be appreciated by one of skill in the art, the devices, apparatuses, devices, systems may be connected, arranged, configured in any manner. Words such as "including," "comprising," "having," and the like are words of openness and mean "including but not limited to," and are used interchangeably therewith. The terms "or" and "as used herein refer to and are used interchangeably with the term" and/or "unless the context clearly indicates otherwise. The term "such as" as used herein refers to, and is used interchangeably with, the phrase "such as, but not limited to.
It is also noted that in the apparatus, devices and methods of the present application, the components or steps may be disassembled and/or assembled. Such decomposition and/or recombination should be considered as equivalent aspects of the present application.
The previous description of the disclosed aspects is provided to enable any person skilled in the art to make or use the present application. Various modifications to these aspects will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other aspects without departing from the scope of the application. Thus, the present application is not intended to be limited to the aspects shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.
The foregoing description has been presented for purposes of illustration and description. Furthermore, this description is not intended to limit embodiments of the application to the form disclosed herein. Although a number of example aspects and embodiments have been discussed above, a person of ordinary skill in the art will recognize certain variations, modifications, alterations, additions, and subcombinations thereof.

Claims (15)

1. A water anion generating apparatus, comprising:
A mist generating device comprising a liquid storage chamber and a mist generator, wherein the mist generator atomizes liquid from the liquid storage chamber to generate a mist; and
And the high-voltage charging device is used for charging the water mist generated by the water mist generating device so as to generate water anions.
2. The water anion generating apparatus of claim 1, wherein the water mist generator is selected from one of a venturi-type atomizer, an ultrasonic vibration atomizer, and a heating atomizer.
3. The water anion generating apparatus of any one of claims 1 to 2, wherein the high voltage charging apparatus comprises a charging needle capable of charging the water mist generated by the water mist generating apparatus, the charging needle operating voltage being-4 kv or more.
4. A water anion generating device as claimed in claim 3, wherein when the operating voltage of the charging needle is between-4 kv and-6 kv, the distance between the position of the charging needle and the center position of the adjacent water mist generator is greater than 10mm.
5. A water anion generating device as claimed in claim 3, wherein when the operating voltage of the charging needle is between-6 kv and-8 kv, the distance between the position of the charging needle and the center position of the adjacent water mist generator is greater than 15mm.
6. A water anion generating device as claimed in claim 3, wherein the distance between the position of the charging needle and the center position of the adjacent water mist generator is greater than 20mm when the operating voltage of the charging needle is between-8 kv and-11 kv.
7. A water anion generating device as claimed in claim 3, wherein the operating voltage of the charging needle is between-4 kv and-11 kv, and the distance between the position of the charging needle and the central position of the adjacent water mist generator is between 20mm and 30 mm.
8. A water anion generating device as claimed in claim 3, wherein the water mist generating device comprises a plurality of rows of the water mist generators arranged at intervals, each row of the water mist generators comprising one or more of the water mist generators, wherein one or more of the charging needles are arranged between two adjacent rows of the water mist generators.
9. A water anion generating device as claimed in claim 3, wherein said mist generating device comprises a plurality of said mist generators disposed around one of said charging needles, the distances between a plurality of said mist generators and said charging needle being equal.
10. A water anion generating device as claimed in claim 3, further comprising an air flow pushing device comprising a pushing fan and a filter screen, wherein air is blown to said water mist generator of said water mist generating device and said charging needle of said high voltage charging device after being filtered by said filter screen by said pushing fan.
11. The apparatus of claim 10, wherein the high voltage charging device comprises a wind-guiding chamber, and the charging needle is mounted at an opening end of the wind-guiding chamber, such that the pushing air flow generated by the pushing fan reaches the charging needle via the wind-guiding chamber to be ionized.
12. A method for generating negative ions in water, comprising the steps of:
Generating water mist through a water mist generator of the water mist generating device; and
And charging the water mist generated by the water mist generator through a charging needle head of the high-voltage charging device so as to generate water anions.
13. The method of generating negative ions of water according to claim 12, wherein when the operating voltage of the charging needle is-4 kv to-6 kv, the distance between the position of the charging needle and the center position of the adjacent water mist generator is greater than 10mm; when the working voltage of the charging needle head is between minus 6kv and minus 8kv, the distance between the position of the charging needle head and the center position of the adjacent water mist generator is more than 15mm; when the working voltage of the charging needle head is between-8 kv and-11 kv, the distance between the position of the charging needle head and the center position of the adjacent water mist generator is more than 20mm.
14. A water anion generating method as claimed in claim 12 or 13, characterized in that the mist generator is operated periodically in batches to generate mist.
15. A method of generating negative ions in water according to claim 12 or 13, wherein the pushing air flow is generated by an air flow pushing means to flow through the mist generator and the charging needle, thereby carrying negative ions in water to migrate into the environment.
CN202310243428.8A 2023-03-14 2023-03-14 Water anion air conditioner and water anion generating device thereof Pending CN118293520A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202310243428.8A CN118293520A (en) 2023-03-14 2023-03-14 Water anion air conditioner and water anion generating device thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202310243428.8A CN118293520A (en) 2023-03-14 2023-03-14 Water anion air conditioner and water anion generating device thereof

Publications (1)

Publication Number Publication Date
CN118293520A true CN118293520A (en) 2024-07-05

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN202310243428.8A Pending CN118293520A (en) 2023-03-14 2023-03-14 Water anion air conditioner and water anion generating device thereof

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