CN1180986C - Method of treating oil field waste water by electric-multiphase catalytic reaction and its special equipment - Google Patents

Method of treating oil field waste water by electric-multiphase catalytic reaction and its special equipment Download PDF

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CN1180986C
CN1180986C CNB011389761A CN01138976A CN1180986C CN 1180986 C CN1180986 C CN 1180986C CN B011389761 A CNB011389761 A CN B011389761A CN 01138976 A CN01138976 A CN 01138976A CN 1180986 C CN1180986 C CN 1180986C
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waste water
catalyzer
oil field
carrier
catalyst
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CN1429773A (en
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旭 杨
杨旭
孙承林
谢茂松
徐桂芬
王贤高
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Dalian Institute of Chemical Physics of CAS
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Dalian Institute of Chemical Physics of CAS
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Abstract

The present invention provides an approach for treating industrial waste water, namely a method for treating waste water of an oil field by electric-multiphase catalytic reaction. Under the condition of the existence of an additional electric field, organic pollutants in waste water of an oil field are catalyzed and oxidated on the surface of a catalyst, wherein the catalyst is composed of active components and a carrier, one or a plurality of oxides of Fe, Co, Ni, Mn, Cu, Ti, W or Pb are used as the active components carried on SiO2, Al2O3, a zeolite molecular sieve or active carbon as the carrier, wherein the component metal is from 0.1 wt% to 10 wt%, the direct current voltage between the electrodes of the electric field is from 2 to 15V, and the current is from 50mA to 600 mA/square decimeter, wherein the catalyst can be added with one or a plurality of oxides of rare earth metal as an auxiliary agent, and is prepared by impregnating, drying and roasting. The method of the present invention can be used for effectively treating oily waste water and dinitrophenol waste water which are generated in the exploitation process of the oil field, waste water of fertilizer plants, waste water of cutting solutions, etc.; the experimental result indicates that the waste water of the oil field, which is treated by the technique, can directly reach the standard to be discharged, and the method of the present invention has the advantage of low operation cost.

Description

A kind of method and isolated plant of handling oil field waste with electric-multiphase catalytic reaction
Technical field
The present invention relates to Industrial Wastewater Treatment, specifically a kind of method and isolated plant of handling oil field waste with electric-multiphase catalytic reaction.
Background technology
Petroleum production wastewater (producing oily(waste)water in the oil extraction process) is main from different workshop sections such as drilling well, oil recovery, well-flushing, borehole operation, contains petroleum-type, COD in the waste water that these workshop sections discharge Cr, pollutent such as volatile phenol, sulfide, SS.These oil field wastes belong to organic wastewater with difficult degradation thereby, are difficult to administer with methods commonly used such as biochemistry; Biological degradation is the most frequently used process for the treatment of waste water, but as dinitrophenol(DNP) waste water, fertilizer plant's waste water, trade effluents such as cutting fluid waste water are difficult to handle with biodegradable method, must adopt new technology, and new technology is handled.
Catalytic oxidation mainly utilizes a large amount of OH free radicals that produce in the electrolysis treatment process, make organic pollutant obtain degraded (Song Weifeng etc., water technology, 27 (2001.2) 90-92).And an electric heterogeneous catalytic oxidation (Xie Maosong etc., Dalian Railway University's journal, 19 (1998.2) 35-37) different with catalytic oxidation, the size of current of the impressed voltage and the reactor of flowing through is the not significantly influence of effect to administering waste water in certain value scope; People such as Xie Maosong once proposed a kind of electricity-heterogeneous catalytic reaction process (ZL.92106153.6) in early days, this technology is that chemical catalysis and electrocatalysis process are combined, utilize catalyst activity component and electric activated acting in conjunction, make reaction molecular activation, can be than carrying out single reaction that can not take place under the mild reaction conditions with catalyzer.Utilize this technology can handle the waste water of brew-house (ZL.92106153.6), fertilizer plant's waste water (ZL.00122912) etc., and built up the industrialized unit of handling fertilizer waste water, treatment capacity is 200 tons/hour, has passed through two-stage environmental administration of provinces and cities and has checked and accepted.So far operation is more than 2 years, and the waste water of treated mistake can reuse, has saved a large amount of process waters; The electric-multiphase catalytic oxidation is at normal temperatures and pressures, under the synergy of electric field and catalyzer, makes larger molecular organics be converted into small molecules or CO 2And water, reduce content of harmful, thereby reach the emission standard of waste water.
Electric-multiphase catalytic oxidation and other water technology are compared, and many advantages are arranged: as the reaction conditions gentleness, carry out under the normal temperature and pressure; Water quality there is not special requirement; Working cost is low; Required equipment is simple, and floor space is little, and is easy and simple to handle; Do not produce secondary pollution; Be particularly suitable for handling the waste water of some intermediate concentration difficult degradations, big to the not high but toxicity of some concentration, as to be not suitable for biochemical treatment waste water, the also effect that can receive.
Containing in the organism trade effluent process with the electric-multiphase catalytic reaction processing, organic matter degradation is actually organism and is decomposed by catalyzed oxidation; Its reaction process is, on the one hand under the activation of extra electric field, can in the aqueous solution, cause the free radical that produces based on OH, because the non-selectivity that the OH free radical that generates has very strong oxidisability and organism is reacted makes the organism catalyzed oxidation at normal temperatures and pressures of bio-refractory become possibility; On the other hand, processed organism can selectively be carried out catalyzed oxidation at catalyst surface; Therefore, the electric-multiphase catalytic technology needs to realize organic degraded that under the synergy of electric field and catalyzer catalyzer and the current field condition selecting suitably to contain active ingredient just can carry out the reaction of catalyzed oxidation decomposing organic matter expeditiously.
Summary of the invention
What the object of the present invention is to provide a kind of catalyzer of suitable active ingredient and current field condition handles the method and the isolated plant of oil field waste with electric-multiphase catalytic reaction.
For achieving the above object, technical solution of the present invention is: under the condition that extra electric field exists, make in the oil field waste organic pollutant at the catalyst surface catalyzed oxidation, wherein said catalyzer is made up of active ingredient and carrier, is that active ingredient is supported on SiO with one or more oxide compound among Fe, Co, Ni, Mn, Cu, Ti, W or the Pb 2, Al 2O 3, on zeolite molecular sieve or the absorbent charcoal carrier, wherein the weight percentage of metal component is 1～10%, surplus is a carrier, in its electric field between electrode volts DS be 12～14V, current density is every square decimeter of 125mA～600mA;
Wherein: the oxide compound that can add in the rare earth metal one or more in the described catalyzer is as auxiliary agent, and weight percentage is 1/6～1/5 of a metal component gross weight; The weight percentage of metal component is preferably 1～5% in the described catalyzer;
Described catalyzer can adopt immersion process for preparing, with containing the soluble chloride or the nitrate aqueous solution of metal ion, behind the impregnated carrier, leaves standstill, and roasting 2～4 hours is carried out in oven dry again under 300～450 ℃, get final product finished product;
Soluble chloride in the described Preparation of Catalyst or nitrate aqueous solution concentration are 0.12～2.0mol/l, and solution is 0.8～1.5: 1 with the carrier bulk ratio; Described catalyzer leaves standstill and is meant under 25～30 ℃ of conditions and put 10～24 hours, and oven dry is to carry out in 110～130 ℃ of temperature ranges; Described catalyzer is when being carrier with the gac, and roasting is to carry out under nitrogen protection;
The isolated plant of described method for preparing catalyst is a slot type structural response device, mainly form by cell body, top cover, electrode, catalyzer, it is material that reactor adopts PVC, on the sidewall of its underpart, be provided with water inlet pipe, sidewall at an upper portion thereof is provided with rising pipe, be provided with aeration tube in its bottom, other is equipped with grid distributor in the aeration tube top, on grid distributor, place the parallel titanium electrode of one or more pairs of band diamond-mesh, area visual response device volume and deciding, for volume that electrode contains is 32～56% of a reactor volume, catalyzer is filled in around the electrode.
The present invention has following advantage:
1. the inventive method can effectively be handled trade effluents such as producing oily(waste)water, dinitrophenol(DNP) waste water, fertilizer plant's waste water and cutting fluid waste water in the oil extraction process; Pilot-scale experiment shows that this technical finesse oil field waste can directly reach emission standard, particularly makes to be difficult to biochemical oily(waste)water, reaches national grade one discharge standard, and handles COD in the prior art CrCan only drop to the 200mg/L method and compare, COD of the present invention CrCan drop to 92mg/L.
2. the inventive method is easy and simple to handle, and the reaction conditions gentleness is carried out at normal temperatures and pressures, is particularly suitable for handling some intermediate concentration used water difficult to degradate, and working cost is cheap, and equipment is simple, and non-secondary pollution produces.
3. the inventive method employing PVC is the slot type structural response device of material, places the parallel titanium electrode of one or more pairs of band diamond-mesh in reactor, and volume that electrode contains is 32～56% of a reactor volume, and treatment effect can reach the highest.
Description of drawings
Fig. 1 is the influence collection of illustrative plates of different electrode widths to the wastewater treatment result; B:L wherein Electrode width/ L The reactor width: below 32%, C:L Electrode width/ L The reactor width: between 32～56%, D:L Electrode width/ L The reactor width: more than 56%.(electrode width refers to plate width, and interelectrode distance and electrode height are constant)
Fig. 2 is electricity-catalytic multi-phase reactor synoptic diagram.
Embodiment
Embodiment 1
M/SiO 2Preparation of catalysts:
Get the Fe (NO of 0.18mol/L 3) 3Solution 100ml is with 100 grams, 40～60 order SiO 2Particle is poured in the steeping fluid and is stirred, and places 10 hours, dries 2 hours down in 110 ℃, again in 400 ℃ of following roastings 3 hours, naturally cools to room temperature and makes catalyst A.The weight of metal component is in the catalyst A: Fe:1%, all the other are carrier S iO 2
Embodiment 2
M/Al 2O 3Preparation with the M/ zeolite catalyst:
With Al 2O 3Or molecular sieve zeolites replaces the SiO among the embodiment 1 2Particle, all the other are identical with embodiment 1, are prepared into the M/Al that contains Fe:1% 2O 3Catalyst B or contain the M/ zeolite catalyst C of Fe:1%.
Embodiment 3
The preparation of M/ activated-carbon catalyst:
1. with the SiO among the mesopore activated carbon replacement embodiment 1 2Powder, and under nitrogen atmosphere, carry out roasting, all the other are identical with embodiment 1, are prepared into the M/ active carbon type catalyzer D1 that contains Fe:1%.
2. with the SiO among the mesopore activated carbon replacement embodiment 1 2Powder, and add the lanthanum nitrate hexahydrate 10ml of 0.18mol/L in the dipping solution in embodiment 1, and at N 2Roasting under the atmosphere, all the other conditions and step are with embodiment 1.Be prepared into the M/ active carbon type catalyzer D2 of La0.2%-Fel%.
Embodiment 4
Test for electricity-heterogeneous catalyst of oil field waste is static:
Used former water COD Cr: 503mg/l, BOD 5: 18mg/l, BOD 5/ COD Cr: 0.036, PH:7, light yellow.
Form by cell body (2), top cover (3), electrode (4), catalyzer (5) at the electricity-heterogeneous catalyst slot type structural response device that with PVC is material, on the sidewall of its underpart, be provided with water inlet pipe (1), sidewall is provided with rising pipe (6) at an upper portion thereof, be provided with aeration tube (8) in its bottom, other is equipped with grid distributor (7) in aeration tube (8) top, go up the parallel titanium electrode (4) of vertically placing 3 pairs of band diamond-mesh at grid distributor (7), its area is that volume that electrode contains is 56% of a reactor volume, and catalyzer (5) is filled in electrode (4) on every side; Static reaction is equipped with in the reactor of electrode in the former water adding of 400ml.Through the different treatment times, sampling analysis the results are shown in Table 1.(COD CrAdopt the mensuration dichromate titration (GB 11914-89) of hydrochemistry oxygen requirement to analyze)
Table 1. electricity-heterogeneous catalyst method is to oil field waste static treatment result
Treatment time (h) Voltage-to-current Reaction back COD Cr(mg/l)
1 12V-400mA 253
2 195
3 149
4 120
Seen that by table 1. experimental result electricity consumption-heterogeneous catalyst method is handled oil field waste, effect is better, and the waste water after the processing can reach national secondary discharge standard.
Embodiment 5
Electricity-heterogeneous catalyst for oil field waste is tested (I) continuously:
Be in the electricity-catalytic multi-phase reactor of material with PVC, the titanium electrode of two bands of parallel placement diamond-mesh, filling 100ml presses the catalyst A of embodiment 1 preparation, use the peristaltic pump continuous sample introduction, under certain impressed current condition, adopt different air speeds, handle.Each water sample is got numerical value after the complete equipilibrium.
25 ℃ of temperature of reaction, normal pressure, former water COD Cr: 506mg/, PH:6-7, light beige, water outlet is almost colourless, and reaction result is listed in table 2.
Table 2. catalyst A is to the result of oil field waste
Air speed (V Water∶V Catalyzer) 2.2 2.5 2.9 3.3 4.0
Reaction back COD Cr(mg/l) 65 78 97 115 137
Embodiment 6
Electricity-heterogeneous catalyst for oil field waste is tested (II) continuously:
Former water COD Cr: 504mg/l.Adopt the catalyst B of embodiment 2 preparations, all the other conditions and embodiment 5 are same, and reaction result is listed in table 3.
Table 3. catalyst B is handled the result of oil field waste
Air speed (V Water∶V Catalyzer) 2.2 2.5 2.9 3.3 4.0
Reaction back COD Cr(mg/l) 50 65 84 102 117
Embodiment 7
Electricity-heterogeneous catalyst for oil field waste is tested (III) continuously:
Former water COD Cr: 503mg/l.Adopt the catalyzer C of embodiment 3 preparations, all the other conditions and embodiment 5 are same, and reaction result is listed in table 4.
Table 4. catalyzer C handles the result of oil field waste
Air speed (V Water∶V Catalyzer) 2.2 2.5 2.9 3.3 4.0
Reaction back COD Cr(mg/l) 48 60 70 77 93
Embodiment 8
Electricity-heterogeneous continuous experiment (IV) for oil field waste:
Former water COD Cr: 506mg/L, adopt the 2. catalyzer D2 of middle preparation of embodiment 3, all the other conditions and embodiment 5 are same, and result is listed in table 5.
Table 5. catalyzer D2 handles the result of oil field waste
Air speed (V Water∶V Catalyzer) 2.2 2.5 2.9 3.3 4.0
Reaction back COD Cr(mg/l) 32 40 56 69 80
Embodiment 9
Electrode width is to the influence of treatment effect:
In same electricity-catalytic multi-phase reactor, use the catalyzer of equivalent, change electrode width, all the other conditions and embodiment 7 are same, and reaction result is listed in table 6.
The different electrode widths of table 6. are to the influence of waste water treatment efficiency
L Electrode width/ L The reactor width: below 32%
Air speed (V Water∶V Catalyzer) 2.9 3.3 3.7 4.0
Reaction back COD Cr(mg/l) 72 83 104 120
L Electrode width/ L The reactor width: between 32～56%
Air speed (V Water∶V Catalyzer) 2.9 3.3 3.7 4.0
Reaction back COD Cr(mg/l) 62 75 82 93
L Electrode width/ L The reactor width: more than 56%
Air speed (V Water∶V Catalyzer) 2.9 3.3 3.7 4.0
Reaction back COD Cr(mg/l) 80 89 99 112
Different electrode widths are seen Fig. 1 to wastewater treatment result's the collection of illustrative plates that influences, by Fig. 1. as can be known, when electrode width be the reactor width 32～56% the time, processing efficiency is the highest.
Embodiment 10
Electricity-heterogeneous catalyst pilot experiment for oil field waste:
Based on laboratory reaction result preferably, carry out pilot scale at the scene, oil field.Groove type reactor is adopted in pilot scale, uses catalyzer C, and electrode adopts the titanium electrode of band diamond-mesh, multi-group electrode, and interelectrode distance 20cm adds 400 liter catalyzer in reactive tank.With submersible pump water in the pond is extracted out, through entering reactive tank after the spinner-type flowmeter metering.The COD of oily(waste)water CrBe 200mg/L, flooding quantity is 800 liters/hour.Reaction back water outlet PH:6-7, very slight color, steady running 12 days.Pilot-scale experiment sees Table 7.
Table 7. electricity-heterogeneous catalyst method is handled the oil field waste pilot-scale experiment
Air speed (V Water∶V Catalyzer) Reaction back COD Cr(mg/l) Working cost *(unit/ton)
2.1 92 1.0
*Working cost includes only power consumption
Table 8. electricity-heterogeneous catalyst method is handled oil field waste pilot scale stability result
Days running 1 2 3 4 5 6 7 8 9 10 11 12
Handle back COD Cr (mg/L) 50 90 92 98 85 87 90 90 92 89 92 88
*V WaterWater: V Water:: catalyzer=2.1, voltage: 14V, current density: 125mA/ square decimeter
See by table 7,8 experimental result, adopt the low COD of electricity-heterogeneous catalytic oxidation technical finesse CrOily(waste)water, can reach national grade one discharge standard, be with a wide range of applications in the oil field.

Claims (7)

1. an electricity consumption-heterogeneous catalytic reaction is handled the method for oil field waste, it is characterized in that: under the condition that extra electric field exists, make in the oil field waste organic pollutant at the catalyst surface catalyzed oxidation, wherein said catalyzer is made up of active ingredient and carrier, is that active ingredient is supported on SiO with one or more oxide compound among Fe, Co, Ni, Mn, Cu, Ti, W or the Pb 2, Al 2O 3, on zeolite molecular sieve or the absorbent charcoal carrier, wherein the weight percentage of metal component is 1～10%, in its electric field between electrode volts DS be 12～14V, current density is every square decimeter of 125mA～600mA; Electrode width is 32～56% of a reactor width.
2. method according to claim 1 is characterized in that: the oxide compound that can add in the rare earth metal one or more in the wherein said catalyzer is as auxiliary agent, and weight percentage is 1/6～1/5 of a metal component gross weight.
3. method according to claim 1 and 2 is characterized in that: the weight percentage of metal component is 1～5% in the described catalyzer.
4. method according to claim 1 and 2, it is characterized in that: wherein said catalyzer can adopt immersion process for preparing, with soluble chloride that contains metal ion or nitrate aqueous solution, behind the impregnated carrier, leave standstill, roasting 2～4 hours is carried out in oven dry again under 300～450 ℃, can obtain finished catalyst.
5. method according to claim 4 is characterized in that: soluble chloride or nitrate aqueous solution concentration are 0.12～2.0mol/l in the wherein said catalyzer, and solution is 0.8～1.5: 1 with the carrier bulk ratio.
6. method according to claim 4 is characterized in that: wherein said catalyzer leaves standstill and is meant under 25～30 ℃ of conditions and put 10～24 hours, and oven dry is to carry out in 110～130 ℃ of temperature ranges.
7. method according to claim 4 is characterized in that: wherein said catalyzer is when being carrier with the gac, and roasting is to carry out under nitrogen protection.
CNB011389761A 2001-12-31 2001-12-31 Method of treating oil field waste water by electric-multiphase catalytic reaction and its special equipment Expired - Fee Related CN1180986C (en)

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