CN105858984A - Device and method for treating vessel oily sewage by ultrasonic strengthening membrane with combination of photo-electrocatalytic technology - Google Patents
Device and method for treating vessel oily sewage by ultrasonic strengthening membrane with combination of photo-electrocatalytic technology Download PDFInfo
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- CN105858984A CN105858984A CN201610356540.2A CN201610356540A CN105858984A CN 105858984 A CN105858984 A CN 105858984A CN 201610356540 A CN201610356540 A CN 201610356540A CN 105858984 A CN105858984 A CN 105858984A
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- Prior art keywords
- photoelectrocatalysioxidization oxidization
- ultrasonic
- membrane
- negative electrode
- oil
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- 238000000034 method Methods 0.000 title claims abstract description 52
- 239000012528 membrane Substances 0.000 title claims abstract description 35
- 239000010865 sewage Substances 0.000 title claims abstract description 31
- 238000005516 engineering process Methods 0.000 title claims abstract description 26
- 238000005728 strengthening Methods 0.000 title abstract 3
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 73
- 230000003647 oxidation Effects 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 57
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 48
- 239000000839 emulsion Substances 0.000 claims description 45
- 239000002071 nanotube Substances 0.000 claims description 36
- 230000008569 process Effects 0.000 claims description 30
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 28
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 23
- 238000002604 ultrasonography Methods 0.000 claims description 20
- 238000001914 filtration Methods 0.000 claims description 19
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 17
- 239000010936 titanium Substances 0.000 claims description 17
- 229910052719 titanium Inorganic materials 0.000 claims description 17
- 239000003792 electrolyte Substances 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims description 14
- 239000000523 sample Substances 0.000 claims description 12
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 10
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 239000002131 composite material Substances 0.000 claims description 9
- 229940079593 drug Drugs 0.000 claims description 8
- 239000003814 drug Substances 0.000 claims description 8
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 8
- 238000005276 aerator Methods 0.000 claims description 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 7
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 7
- 238000007790 scraping Methods 0.000 claims description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
- 239000007832 Na2SO4 Substances 0.000 claims description 6
- 239000002033 PVDF binder Substances 0.000 claims description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 5
- 229920001661 Chitosan Polymers 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 229910021536 Zeolite Inorganic materials 0.000 claims description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims description 5
- 238000007743 anodising Methods 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 239000012510 hollow fiber Substances 0.000 claims description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 5
- 229910052697 platinum Inorganic materials 0.000 claims description 5
- 239000011780 sodium chloride Substances 0.000 claims description 5
- 229910001488 sodium perchlorate Inorganic materials 0.000 claims description 5
- 239000010457 zeolite Substances 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 239000004927 clay Substances 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910001220 stainless steel Inorganic materials 0.000 claims description 4
- 239000010935 stainless steel Substances 0.000 claims description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 3
- 238000000137 annealing Methods 0.000 claims description 3
- 230000005611 electricity Effects 0.000 claims description 3
- 238000004070 electrodeposition Methods 0.000 claims description 3
- 238000007667 floating Methods 0.000 claims description 3
- 239000006260 foam Substances 0.000 claims description 3
- 230000036571 hydration Effects 0.000 claims description 3
- 238000006703 hydration reaction Methods 0.000 claims description 3
- MACBSXIPRLPFDJ-UHFFFAOYSA-N oxygen(2-) platinum(2+) titanium(4+) Chemical compound [O-2].[O-2].[Ti+4].[Pt+2] MACBSXIPRLPFDJ-UHFFFAOYSA-N 0.000 claims description 3
- 230000005622 photoelectricity Effects 0.000 claims description 3
- 239000002244 precipitate Substances 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- 238000000527 sonication Methods 0.000 claims description 3
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 claims description 2
- 238000005273 aeration Methods 0.000 claims description 2
- BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- 239000004744 fabric Substances 0.000 claims 1
- 238000009434 installation Methods 0.000 claims 1
- 230000008901 benefit Effects 0.000 abstract description 9
- 238000005374 membrane filtration Methods 0.000 abstract description 5
- 238000006555 catalytic reaction Methods 0.000 abstract description 4
- 238000004064 recycling Methods 0.000 abstract description 3
- 238000004134 energy conservation Methods 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 26
- 239000010408 film Substances 0.000 description 24
- 230000000694 effects Effects 0.000 description 7
- 238000000926 separation method Methods 0.000 description 6
- 230000015556 catabolic process Effects 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 230000018044 dehydration Effects 0.000 description 4
- 238000006297 dehydration reaction Methods 0.000 description 4
- 230000004907 flux Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 230000006798 recombination Effects 0.000 description 4
- 238000005215 recombination Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000007146 photocatalysis Methods 0.000 description 3
- 230000001699 photocatalysis Effects 0.000 description 3
- 239000010970 precious metal Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000003672 processing method Methods 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 206010002660 Anoxia Diseases 0.000 description 1
- 241000976983 Anoxia Species 0.000 description 1
- FMMWHPNWAFZXNH-UHFFFAOYSA-N Benz[a]pyrene Chemical compound C1=C2C3=CC=CC=C3C=C(C=C3)C2=C2C3=CC=CC2=C1 FMMWHPNWAFZXNH-UHFFFAOYSA-N 0.000 description 1
- 206010021143 Hypoxia Diseases 0.000 description 1
- QYSYEILYXGRUOM-UHFFFAOYSA-N [Cl].[Pt] Chemical compound [Cl].[Pt] QYSYEILYXGRUOM-UHFFFAOYSA-N 0.000 description 1
- 238000009303 advanced oxidation process reaction Methods 0.000 description 1
- 230000007953 anoxia Effects 0.000 description 1
- 230000001458 anti-acid effect Effects 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 238000011953 bioanalysis Methods 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000010727 cylinder oil Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000012458 free base Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000010720 hydraulic oil Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- -1 hydroxyl radical free radical Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/34—Treatment of water, waste water, or sewage with mechanical oscillations
- C02F1/36—Treatment of water, waste water, or sewage with mechanical oscillations ultrasonic vibrations
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/40—Devices for separating or removing fatty or oily substances or similar floating material
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/444—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
- C02F1/4672—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/727—Treatment of water, waste water, or sewage by oxidation using pure oxygen or oxygen rich gas
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/008—Originating from marine vessels, ships and boats, e.g. bilge water or ballast water
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
Abstract
The invention aims to provide a device and a method for treating vessel oily sewage by an ultrasonic strengthening membrane with the combination of the photo-electrocatalytic technology. The vessel oily sewage passes by a grid by a collection pipeline, enters an ultrasonic demulsification device and then enters a membrane filtration device, the membrane filtration device comprises an oil wiper and a modified membrane, and the vessel oily sewage enters a photoelectric catalysis and oxidation device and is exhausted and recycled when it is tested by a detector that all indexes meet the requirements. The device and the method for treating the vessel oily sewage by the ultrasonic strengthening membrane with the combination of the photo-electrocatalytic technology have the advantages that the structure is simple and compact, the occupied area is small, and the use and operation management is convenient, at the same time, recycling of oil and sewage after treatment is realized, and the purposes of energy conservation and emission reduction are realized.
Description
Technical field
The present invention relates to a kind of sewage-treatment plant and method thereof, specifically ship sewage treatment dress
Put and method.
Background technology
Ship sewage treatment is an important content in vessel pollution control field, oil-containing in vessel oily water
Polytype oil, its source includes: lubricating oil, steam cylinder oil and hydraulic oil, cleaning agent, foaming agent (AFFF),
Paint and solvent etc..In vessel oily water a part oil in water in emulsified state, it is difficult to separate.If
These vessel oily waters do not do and effectively process and directly discharge, and can cause the pollution of ocean and river environment.
The decomposition of oils can produce the noxious substance such as benzopyrene and other polycyclic aromatic hydrocarbon, the on the one hand meeting of these catabolites
Be there is direct toxic action in biology；On the other hand, when the water containing micro oil is used for cultivating or irrigating, quilt
Bio-absorbable and be enriched with, by food chain enter human body, be detrimental to health.IMO data shows, the world
Cabin bilge oil-polluted water amount discharged every year by average single ship is the 1/10 of this ship gross tonnage, it has been found that illegal row
The oil content of the cabin biloge water gone out is up to 50000ppm.There is up to ten million ton oils the most every year by each
Kind of approach enters water body, and oil can form monolayer oil film and cover the water surface, makes water body and air exclusion and anoxia,
Produce stench, affect aquatile growth even dead.Within 2004, IMO makes rule in MEPC107. (49)
Fixed, instead of old MEPC60. (33) pact, add in new execution standard containing oil emulsion " C "
The test requirements document of liquid, therefore the effective technology processing vessel oily water of exploitation is significant.
The processing method of the vessel sewage of research, mainly has Physical, physical-chemical process, life the most at present
Thing chemical method, electrochemical process, chemical demulsification method and advanced oxidation processes.Various methods have certain applicable bar
Part and pluses and minuses.Bioanalysis, owing to being limited by the cultivation of microorganism and growth conditions, is transported at actual boats and ships
Row operating process can produce various problems.Therefore, for having the biology of preferable treatment effect containing sewage
Processing method should not use.Use membrane technology oil-polluted water to be processed, in external boats and ships the most
Application, and studies in China and application are the most less.It addition, for ship sewage treatment effect that reuse can be reached
Really, the rarest research of domestic and international this respect.In order to process for biloge water in time on boats and ships,
If biloge water can reach the water quality requirement of reuse after certain process, it is achieved " zero-emission simultaneously
Put ", so can not only save the volume of sewage storage cabinet in boats and ships, reduce consumption of raw materials, also achieve
Being continuing with after the recycling of oils resource and sewage disposal, the reuse of sewage can be substantially reduced supply
Demand, reaches the purpose of energy-saving and emission-reduction.
Oil and water can form emulsion under certain condition, and this emulsion in most cases presents oil-in-water
(O/W) or the form of Water-In-Oil (W/O), there is relative stability under certain condition.Ultrasonic dehydration
Have low cost, effective, do not produce the outstanding advantages such as secondary pollution.Ultrasonic emulsion breaking utilizes ul-trasonic irradiation
The displacement effect produced in the fluid media (medium) that character is different realizes oil-water separation.Owing to ultrasound wave is at You Heshui
In be respectively provided with good conductivity, so ultrasonic dehydration is applicable to various types of emulsion.Ultrasound wave
Breakdown of emulsion can reduce the temperature of breakdown of emulsion, the most just thus can reduce heating set with breakdown of emulsion
Standby and energy consumption, can also cancel the high-tension electricity dehydration equipment of complexity simultaneously.Ultrasound wave and demulsifier have good
Synergism, it can improve the functioning efficiency of demulsifier, reduce the consumption of demulsifier.Ultrasound wave and chemistry
Demulsifier combines has good development prospect for emulsification crude oil demulsification dehydration, particularly to those with conventional
Dewatering type is difficult to the crude oil emulsion breaking emulsion and dewatering proved effective.
Kynoar PVDF ultrafiltration membrane is the macromolecular material of a kind of function admirable, steady with the chemistry that it is good
Qualitative, radiation resistance and thermostability, mechanical strength are big, high tenacity, antiacid caustic corrosion, preparation technology are simple,
The plurality of advantages such as cost is relatively low, apply widely in fields such as waste water process and reuses.But due to tool itself
Have strong-hydrophobicity, surface energy is low, wettability is poor, particularly applies in aqueous phase system separation process, is passing
Making flux depression due to Adsorption of solute and Pore Blocking during matter, separation process needs bigger driving
Power, in separation process, membrane flux and two main Separation Indexes of interception capacity constantly decline, and clean very
Difficulty, shortens the service life of film.In order to decelerating membrane pollution, film surface can be carried out hydrophilic modifying,
Pollutant are made to be difficult to deposit on the surface of the film and just can make the pollution on film surface under less effect power
Thing is removed.Along with the hydrophilic improvement of pvdf membrane, permeability of the membrane, resistance tocrocking and stability are the most available
Preferably improving, the overall performance of film is promoted, and has significantly expanded its range of application.Modification for film
Being divided into two big classes one is film matrix modification, and including being blended, copolymerization process, another kind is membrane surface modification.
Photoelectro-catalytic oxidation technology is a kind of high-level oxidation technology, has equipment simple, easily controllable, and
The advantages such as secondary pollution will not be brought, be described as the water technology of " environmental friendliness ".Photoelectrocatalysioxidization oxidization
Technology is the technology of a kind of oil-polluted water of can effectively degrading, and the speed of photoelectrocatalysioxidization oxidization degradation of organic substances is bright
The aobvious independent role speed sum higher than photochemical catalytic oxidation with electrocatalysis oxidation reaction, thus light and electric process tool
There is significant synergism.TiO2 is one of catalysis material the most of greatest concern, but applies in reality
In there is the problem that electron-hole pair recombination rate is high.TiO2 nanotube have even structure, high-sequential,
Specific surface area is big, stable chemical nature and advantage, precious metals pt and SnO2 and TiO2 such as reusable receive
Mitron can reduce electron-hole pair recombination rate after mixing, improves photocatalysis efficiency.
Summary of the invention
It is an object of the invention to provide and be capable of the ultrasound-enhanced film of reusing sewage purpose and combine photoelectrocatalysis
The device and method of technical finesse vessel oily water
The object of the present invention is achieved like this:
The ultrasound-enhanced film of the present invention combines photo-electrocatalytic technology and processes the device of vessel oily water, it is characterized in that:
Including grid, ultrasonic emulsion breaking device, membrane-filtering unit, photoelectrocatalysioxidization oxidization device, set in ultrasonic emulsion breaking device
Putting ultrasonic probe, drug feeding device is installed at the top of ultrasonic emulsion breaking device, and the bottom of ultrasonic emulsion breaking device is swash plate knot
Structure, arranges sewage draining exit below swash plate structure, be respectively provided with modified filter membranes and oil wiper, membrane filtration in membrane-filtering unit
Blow-off pipe is set on device, DC source, ultraviolet lamp tube, aerator is set in photoelectrocatalysioxidization oxidization device,
DC source includes anode and negative electrode, and negative electrode is arranged on the middle part of photoelectrocatalysioxidization oxidization device, and anode is cylinder
Shape to be arranged on the inwall of photoelectrocatalysioxidization oxidization device inboard, ultraviolet lamp tube is arranged in the outside of negative electrode, photoelectricity
Drain pipe is set on catalytic oxidizing equipment, is filled with electrolyte in photoelectrocatalysioxidization oxidization device, containing from boats and ships
Oily water passes sequentially through grid, ultrasonic emulsion breaking device, oil wiper, modified filter membranes and photoelectrocatalysioxidization oxidization dress
Put and discharged by drain pipe.
The ultrasound-enhanced film of the present invention combines the device of photo-electrocatalytic technology process vessel oily water and can also wrap
Include:
1, described ultrasonic probe is evenly distributed on the inwall of ultrasonic emulsion breaking device.
2, described modified filter membranes uses PVC Yu PVDF blend hollow fiber membrane, and the surface of blend film is coated with
Covering hydroaropic substance, described hydroaropic substance includes modified powdered zeolite, Kaolin, clay, kieselguhr
And chitosan.
3, the anode of photoelectrocatalysioxidization oxidization device is the SnO that Pt modifies2/TiO2Nanotube electrode, electrocatalytic oxidation
The negative electrode of gasifying device is stainless steel bar or copper rod, light source ultraviolet lamp tube be distributed in the shape of a spiral cathode outer side or by
Four straight fluorescent tubes are distributed in around negative electrode；Described electrolyte is NaCl, Na2SO4、NaClO4In one
Or several, electrolyte concentration is 0.1-0.5mol/L.
The ultrasound-enhanced film of the present invention combines the method that photo-electrocatalytic technology processes vessel oily water, it is characterized in that:
The following device processing vessel oily water of employing:
Including grid, ultrasonic emulsion breaking device, membrane-filtering unit, photoelectrocatalysioxidization oxidization device, ultrasonic emulsion breaking device
In ultrasonic probe is set, drug feeding device is installed at the top of ultrasonic emulsion breaking device, and the bottom of ultrasonic emulsion breaking device is oblique
Plate structure, arranges sewage draining exit below swash plate structure, be respectively provided with modified filter membranes and oil wiper in membrane-filtering unit,
Arrange on membrane-filtering unit and DC source, ultraviolet lamp tube, aeration dress are set in blow-off pipe photoelectrocatalysioxidization oxidization device
Putting, DC source includes anode and negative electrode, and negative electrode is arranged on the middle part of photoelectrocatalysioxidization oxidization device, anode in
Cylindric and to be arranged on the inwall of photoelectrocatalysioxidization oxidization device inboard, ultraviolet lamp tube is arranged in the outside of negative electrode,
Drain pipe is set on photoelectrocatalysioxidization oxidization device, in photoelectrocatalysioxidization oxidization device, is filled with electrolyte；
(1) vessel oily water is entered in ultrasonic emulsion breaking device through grid by collecting, by adding
Medicine device adds AP type demulsifier in ultrasonic emulsion breaking device, and demulsifier concentration is 10-1000mg/L, enables super
Sonic probe, supersonic frequency 15-30kHz of ultrasonic probe, ultrasonic power 50-500w, sonication treatment time
10-30min, proportion is discharged by sewage draining exit more than the precipitate of water；
(2) oil-polluted water after sonicated enters in the oil wiper of membrane-filtering unit, stands in oil wiper
Scraped off the floating greasy dirt in upper strata by oil scraping plate after 10-30min, blow-off pipe discharge greasy dirt；
(3) sewage scraping off upper strata greasy dirt enters photoelectrocatalysioxidization oxidization device, to power supply after modified filter membranes
Energising, voltage range is 1-10V, is passed through ozone, oxygen or air in aerator, and dosage is 5-30
Mg/L, ultraviolet lamp tube is energized thus completes photoelectrocatalysioxidization oxidization process, the dirt processed by photoelectrocatalysioxidization oxidization
Water detects through verifying attachment, when its index reaches pre-provisioning request, discharges with crossing drain pipe.
The ultrasound-enhanced film of the present invention combines the method for photo-electrocatalytic technology process vessel oily water and can also wrap
Include:
1, the anode of photoelectrocatalysioxidization oxidization device is the SnO that Pt modifies2/TiO2Nanotube electrode, Pt modifies
SnO2/TiO2The preparation process of nanotube is:
(1) anodizing is used to prepare TiO with titanium plate2Nano-tube array: with platinized platinum as negative electrode, titanium plate
For anode, the most gradually applying 0-30V voltage, increase 1V per minute, magnetic stirrer is slow
Take out titanium plate after the lower oxidation 30min of stirring, then carry out anodic oxidation and prepare TiO2Nanotube array；
(2) SnO is prepared2/TiO2Nanotube array composite material: prepared by pulse electrodeposition method
SnO2/TiO2Nanotube array composite material；
(3) hydrothermal synthesis method is used to prepare the SnO that Pt modifies2/TiO2Nanotube electrode: in hydrothermal reaction kettle
Add six hydration platinum acid chloride solutions, formalin and sodium lauryl sulphate, stir, then evacuation,
Add the SnO prepared2/TiO2The hydrothermal reaction kettle of nanotube array composite material good seal is placed in Muffle furnace
In 180 DEG C reaction 10h, be cooled to room temperature, loads platinum titanium dioxide nanotube electrode is transferred to lead to N2Protection
Tube furnace in 250 DEG C annealing 2h.
2, anodizing is used to prepare TiO2Array during nanotube, replaces titanium plate by titanium net or titanium foam.
Present invention have an advantage that vessel oily water through grid laggard enter ultrasonic breaking device, by super
Sound wave and demulsifier have good synergism, make oil or fat particles in water be gathered into bigger elaioleucite, are conducive to
Improving the separation efficiency of oil water separator, ultrasound wave can also improve the functioning efficiency of demulsifier simultaneously, reduces
The consumption of demulsifier, it is not necessary to add other coagulant.Water outlet is filtered by modified filter membranes, it is achieved returning of oil point
Receive and utilize, be purified further to realize recycling by the water outlet after membrane filtration.Use PVC and PVDF
Blend hollow fiber membrane, at the surface coating modified powdery zeolite of blend film, Kaolin, clay, kieselguhr
With hydroaropic substances such as chitosans.Improve the hydrophilic of film, effectively prevent fouling membrane.TiO2 nanotube profit
With having that even structure, high-sequential, specific surface area be big, stable chemical nature and the advantage such as reusable,
Precious metals pt and SnO2 and TiO2 nanotube can reduce electron-hole pair recombination rate after mixing, improve light
Catalytic efficiency.The speed of photoelectrocatalysioxidization oxidization degradation of organic substances is apparently higher than photochemical catalytic oxidation and electrocatalytic oxidation
The independent role speed sum of reaction, utilizes the synergism of photocatalysis and electro-catalysis can improve organic
Removal efficiency, it is also possible to by being passed through air, oxygen or ozone in photoelectrocatalysioxidization oxidization device, electrolysis
During the ozone that produces or the ozone that is passed through in system can decompose generation high active substance hydroxyl free
Base, reaches oxidation and the effect of sterilization, finally realizes the purpose of reusing sewage, it is achieved the zero-emission of sewage.
This reaction unit not only remove pollutant usefulness height also have simple and compact for structure, floor space is little, use and
The convenient advantage of operational management.
Accompanying drawing explanation
Fig. 1 is the schematic flow sheet of method for separating polluted particles of the present invention；
Fig. 2 is assembly of the invention figure；
Fig. 3 is ultrasonic emulsion breaking device top view；
Fig. 4 be light source be the photoelectrocatalysioxidization oxidization reaction unit top view of spiral ultraviolet lamp tube；
Fig. 5 be light source be the photoelectrocatalysioxidization oxidization reaction unit top view of uviol lamp straight tube.
Detailed description of the invention
Illustrate below in conjunction with the accompanying drawings and the present invention be described in more detail:
In conjunction with Fig. 1-5, the ultrasound-enhanced film of the present invention combines photo-electrocatalytic technology and processes the dress of vessel oily water
Put and specifically include that grid 1, ultrasonic emulsion breaking device 2, membrane-filtering unit 10, photoelectrocatalysioxidization oxidization device 13.
The wherein inner ultrasonic probe 3 that arranges of ultrasonic emulsion breaking device 2, ultrasonic probe 3 is many, and is uniformly distributed
In the inwall surrounding of ultrasonic emulsion breaking device 2.Drug feeding device 4 is installed at the top of ultrasonic emulsion breaking device 2, passes through
Drug feeding device 4 adds demulsifier in ultrasonic emulsion breaking device, and the type of demulsifier can be with AP type, SP type, AE
Type or AR type non-ionic demulsifier one of which, concentration is 10-1000mg/L, ultrasonic emulsion breaking device 2
Bottom be swash plate structure 6, sewage draining exit 5 is set below swash plate structure.
Modified filter membranes 11 and oil wiper 8, the row of also setting up on membrane-filtering unit 10 it is respectively provided with in membrane-filtering unit 10
Dirty pipe 9 and back purge system 12.
Photoelectrocatalysioxidization oxidization device 13 is inner arranges DC source, ultraviolet lamp tube 14, aerator 17, direct current
Power supply includes anode 15 and negative electrode 16, and negative electrode 16 is arranged on the middle part of photoelectrocatalysioxidization oxidization device 13, sun
Pole 15 cylindrically and is arranged near the inwall of photoelectrocatalysioxidization oxidization device 13, and ultraviolet lamp tube 14 is helically
Shape is distributed in around negative electrode 16 or is distributed in around negative electrode 16 by four straight fluorescent tubes, photoelectrocatalysioxidization oxidization device
Arranging drain pipe 19 on 13, be filled with electrolyte in photoelectrocatalysioxidization oxidization device 13, anode 15 is modified for Pt
SnO2/TiO2Nanotube, TiO2Nanotube is passed through anodic oxidation legal system by titanium plate, titanium net or titanium foam
, negative electrode 16 is stainless steel bar or copper rod, and electrolyte is NaCl, Na2SO4、NaClO4In one
Or it is several.
Oil-polluted water from boats and ships is discharged after the process of this device by main line, and main line connects successively
Logical ultrasonic emulsion breaking device 2, membrane-filtering unit 10 and photoelectrocatalysioxidization oxidization device 13.
The method for separating polluted particles following steps of the present invention: collecting collects vessel oily water, through grid 1,
Entering in ultrasonic emulsion breaking device 2, add AP type demulsifier in breaking device 2, demulsifier concentration is
10-1000mg/L, supersonic frequency 15-30kHz, ultrasonic power 50-500w, sonication treatment time 10-30min.
Ultrasonic emulsion breaking bottom of device is swash plate structure, and proportion precipitates, by blowdown more than the silt of water, rust etc.
Mouth 5 is discharged, and the oil-polluted water after ultrasonic emulsion breaking processes enters membrane-filtering unit 10, and membrane-filtering unit 10 includes scraping
Oil device 7, modified filter membranes 11, oil-polluted water is scraped off by oil scraping plate after standing 10-30min in oil wiper 7
The floating greasy dirt of layer, is discharged greasy dirt by blow-off pipe 8, blow-off pipe 8 can weigh after being dehydrated further after discharging
Multiple utilization, the sewage scraping off upper strata greasy dirt passes through modified filter membranes 11, subsequently into photoelectrocatalysioxidization oxidization device 13,
Power supply is DC source, and voltage range is 1-10V, and anode is cylindrically.Electrolyte is Na2SO4, concentration
For 0.1-0.5mol/L, being passed through ozone in aerator 17, ozone dosage is 5-30mg/L, when passing through
The oil-polluted water device 18 after testing that photoelectrocatalysioxidization oxidization processes detects indices when reaching requirement, by draining
Pipe 19 is discharged, reuse.Back purge system 12 periodically carries out backwash to ultrafilter membrane.Light source is ultraviolet lamp tube,
It is distributed in closing twist shape outside negative electrode 16 or is distributed in around negative electrode 16 by four straight fluorescent tubes.
Demulsifier used is in addition to AP type demulsifier, it is also possible to be SP type, AE type, AR type nonionic
Demulsifier, concentration is 10-1000mg/L.Electrolyte is in addition to Na2SO4, it is also possible to for NaCl, NaClO4,
Concentration is 0.1-0.5mol/L.
The SnO that the anode 15 of photoelectrocatalysioxidization oxidization device 13 is modified for Pt2/TiO2Nanotube electrode, photoelectricity
Catalysis oxidation depth processes the SnO2/TiO2 electrode using Pt to modify, and the preparation process of this electrode is:
(1) TiO2 nanotube uses anodizing to prepare: with platinized platinum as negative electrode, the titanium plate processed is
Anode, the most gradually applies 0-30V voltage, and increase 1V per minute, magnetic stirrer slowly stirs
Take out titanium plate after mixing lower oxidation 30min, then carry out anodic oxidation and prepare TiO2 nanotube array.
(2) preparation of SnO2/TiO2 nanotube array composite material: pulse electrodeposition method prepares SnO2/TiO2
Nanotube array composite material.
(3) preparation of the SnO2/TiO2 nanotube that Pt modifies: add six hydration chlorine platinum in hydrothermal reaction kettle
Acid solution, formalin and sodium lauryl sulphate, stir, then evacuation, and addition prepares
The hydrothermal reaction kettle of SnO2/TiO2 nanotube array composite material good seal is placed in 180 DEG C of reactions in Muffle furnace
10h, is cooled to room temperature, transfers to carrying platinum titanium dioxide nanotube electrode in the tube furnace that logical N2 protects
250 DEG C of annealing 2h.
TiO2 nanotube has that even structure, high-sequential, specific surface area be big, stable chemical nature and can weighing
Advantage, precious metals pt and SnO2 and the TiO2 nanotubes such as multiple use can reduce electron-hole pair after mixing
Recombination rate, improves photocatalysis efficiency.
Use PVC Yu PVDF blend hollow fiber membrane, it can the performance of two kinds of polymers compositionss of aggregative equilibrium,
Effectively expand the range of choice of membrane material, it is thus achieved that the membrane material that combination property is ideal.PVC and PVDF
Blend hollow fiber membrane water flux and hot strength are preferable.
The parents such as surface coating modified powdery zeolite, Kaolin, clay, kieselguhr and the chitosan in blend film
Aqueous substance.Modified zeolite, Kaolin, kieselguhr are all the hydroaropic substances that surface is electronegative, make film
Antifouling property increase.It addition, surface is weak electronegative modified zeolite can be formed loosely organized,
The cake layer that hole is bigger, is easily rinsed during backwash, and membrane flux can be recovered very well.Zeolite
Modified through acid system, specific surface area increases, and surface elecrtonegativity reduces.Chitosan both can overlay on film surface,
Can also enter in fenestra, thus improve the hydrophilic of film, can effectively prevent the protein contamination of film.
The strong adsorptivity of powder activated carbon can also be utilized to have at blend film surface-coated Powdered Activated Carbon
Effect removes the organic pollution in water.
In photoelectrocatalysioxidization oxidization device 13, aerator 17 is in addition to being passed through ozone, it is also possible to be passed through air or
Oxygen, dosage is 5-30mg/L, the ozone produced in electrolytic process or the ozone being passed through in system
Generation high active substance hydroxyl radical free radical can be decomposed.Water outlet after making by membrane filtration is purified further, reaches
To oxidation and the effect of sterilization.
Claims (8)
- The most ultrasound-enhanced film combines photo-electrocatalytic technology and processes the device of vessel oily water, it is characterized in that: bag Include grid, ultrasonic emulsion breaking device, membrane-filtering unit, photoelectrocatalysioxidization oxidization device, arrange in ultrasonic emulsion breaking device Ultrasonic probe, the top installation drug feeding device of ultrasonic emulsion breaking device, the bottom of ultrasonic emulsion breaking device is swash plate structure, Sewage draining exit is set below swash plate structure, in membrane-filtering unit, is respectively provided with modified filter membranes and oil wiper, membrane-filtering unit On blow-off pipe is set, DC source, ultraviolet lamp tube, aerator are set in photoelectrocatalysioxidization oxidization device, directly Stream power supply includes anode and negative electrode, and negative electrode is arranged on the middle part of photoelectrocatalysioxidization oxidization device, and anode is cylindrically And the inwall that is arranged on photoelectrocatalysioxidization oxidization device is inboard, ultraviolet lamp tube is arranged in the outside of negative electrode, and photoelectricity is urged Change and on oxidation unit, drain pipe is set, be filled with electrolyte in photoelectrocatalysioxidization oxidization device, from the oil-containing of boats and ships Sewage passes sequentially through grid, ultrasonic emulsion breaking device, oil wiper, modified filter membranes and photoelectrocatalysioxidization oxidization device And discharged by drain pipe.
- Ultrasound-enhanced film the most according to claim 1 combines photo-electrocatalytic technology and processes vessel oily water Device, it is characterized in that: described ultrasonic probe is evenly distributed on the inwall of ultrasonic emulsion breaking device.
- Ultrasound-enhanced film the most according to claim 1 and 2 combines photo-electrocatalytic technology and processes boats and ships oil-containing The device of sewage, is characterized in that: described modified filter membranes uses PVC Yu PVDF blend hollow fiber membrane, The surface-coated hydroaropic substance of blend film, described hydroaropic substance include modified powdered zeolite, Kaolin, Clay, kieselguhr and chitosan.
- Ultrasound-enhanced film the most according to claim 1 and 2 combines photo-electrocatalytic technology and processes boats and ships oil-containing The device of sewage, is characterized in that: the anode of photoelectrocatalysioxidization oxidization device is the SnO that Pt modifies2/TiO2Nanometer Pipe electrode, the negative electrode of electrocatalysis oxidation apparatus is stainless steel bar or copper rod, and light source ultraviolet lamp tube divides in the shape of a spiral Cloth is distributed in around negative electrode at cathode outer side or by four straight fluorescent tubes；Described electrolyte is NaCl, Na2SO4、 NaClO4In one or more, electrolyte concentration is 0.1-0.5mol/L.
- Ultrasound-enhanced film the most according to claim 3 combines photo-electrocatalytic technology and processes vessel oily water Device, it is characterized in that: the anode of photoelectrocatalysioxidization oxidization device be Pt modify SnO2/TiO2Nanotube electricity Pole, the negative electrode of electrocatalysis oxidation apparatus is stainless steel bar or copper rod, and light source ultraviolet lamp tube is distributed in the shape of a spiral Cathode outer side or be distributed in around negative electrode by four straight fluorescent tubes；Described electrolyte is NaCl, Na2SO4、NaClO4 In one or more, electrolyte concentration is 0.1-0.5mol/L.
- The most ultrasound-enhanced film combines the method that photo-electrocatalytic technology processes vessel oily water, it is characterized in that: adopt Device with following process vessel oily water:Including grid, ultrasonic emulsion breaking device, membrane-filtering unit, photoelectrocatalysioxidization oxidization device, ultrasonic emulsion breaking device In ultrasonic probe is set, drug feeding device is installed at the top of ultrasonic emulsion breaking device, and the bottom of ultrasonic emulsion breaking device is oblique Plate structure, arranges sewage draining exit below swash plate structure, be respectively provided with modified filter membranes and oil wiper in membrane-filtering unit, Arrange on membrane-filtering unit and DC source, ultraviolet lamp tube, aeration dress are set in blow-off pipe photoelectrocatalysioxidization oxidization device Putting, DC source includes anode and negative electrode, and negative electrode is arranged on the middle part of photoelectrocatalysioxidization oxidization device, anode in Cylindric and to be arranged on the inwall of photoelectrocatalysioxidization oxidization device inboard, ultraviolet lamp tube is arranged in the outside of negative electrode, Drain pipe is set on photoelectrocatalysioxidization oxidization device, in photoelectrocatalysioxidization oxidization device, is filled with electrolyte；(1) vessel oily water is entered in ultrasonic emulsion breaking device through grid by collecting, by adding Medicine device adds AP type demulsifier in ultrasonic emulsion breaking device, and demulsifier concentration is 10-1000mg/L, enables super Sonic probe, supersonic frequency 15-30kHz of ultrasonic probe, ultrasonic power 50-500w, sonication treatment time 10-30min, proportion is discharged by sewage draining exit more than the precipitate of water；(2) oil-polluted water after sonicated enters in the oil wiper of membrane-filtering unit, stands in oil wiper Scraped off the floating greasy dirt in upper strata by oil scraping plate after 10-30min, blow-off pipe discharge greasy dirt；(3) sewage scraping off upper strata greasy dirt enters photoelectrocatalysioxidization oxidization device, to power supply after modified filter membranes Energising, voltage range is 1-10V, is passed through ozone, oxygen or air in aerator, and dosage is 5-30 Mg/L, ultraviolet lamp tube is energized thus completes photoelectrocatalysioxidization oxidization process, the dirt processed by photoelectrocatalysioxidization oxidization Water detects through verifying attachment, when its index reaches pre-provisioning request, discharges with crossing drain pipe.
- Ultrasound-enhanced film the most according to claim 6 combines photo-electrocatalytic technology and processes vessel oily water Method, it is characterized in that: the anode of photoelectrocatalysioxidization oxidization device be Pt modify SnO2/TiO2Nanotube electricity Pole, the SnO that Pt modifies2/TiO2The preparation process of nanotube is:(1) anodizing is used to prepare TiO with titanium plate2Nano-tube array: with platinized platinum as negative electrode, titanium plate For anode, the most gradually applying 0-30V voltage, increase 1V per minute, magnetic stirrer is slow Take out titanium plate after the lower oxidation 30min of stirring, then carry out anodic oxidation and prepare TiO2Nanotube array；(2) SnO is prepared2/TiO2Nanotube array composite material: prepared by pulse electrodeposition method SnO2/TiO2Nanotube array composite material；(3) hydrothermal synthesis method is used to prepare the SnO that Pt modifies2/TiO2Nanotube electrode: in hydrothermal reaction kettle Add six hydration platinum acid chloride solutions, formalin and sodium lauryl sulphate, stir, then evacuation, Add the SnO prepared2/TiO2The hydrothermal reaction kettle of nanotube array composite material good seal is placed in Muffle furnace In 180 DEG C reaction 10h, be cooled to room temperature, loads platinum titanium dioxide nanotube electrode is transferred to lead to N2Protection Tube furnace in 250 DEG C annealing 2h.
- Ultrasound-enhanced film the most according to claim 7 combines photo-electrocatalytic technology and processes vessel oily water Method, it is characterized in that: use anodizing prepare TiO2Array during nanotube, with titanium net or foam Titanium replaces titanium plate.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106430821A (en) * | 2016-09-30 | 2017-02-22 | 哈尔滨工程大学 | Ship black water and ash water treatment device and method |
| CN109502703A (en) * | 2018-12-17 | 2019-03-22 | 长江水利委员会长江科学院 | The suppressing method and device of a kind of pair of bed mud provenance cyanobacteria recovery |
| CN110015749A (en) * | 2019-04-03 | 2019-07-16 | 上海海事大学 | One kind being used for emulsified waste liquid sterilization process device and technique |
| CN110787799A (en) * | 2019-08-16 | 2020-02-14 | 浙江工业大学 | Preparation method of foamed copper oxide/TNTs photoelectric composite material |
| CN111252970A (en) * | 2020-02-13 | 2020-06-09 | 湛江远通高新技术有限公司 | Oil-water separation method for oily sewage of ship |
| CN113415937A (en) * | 2021-06-15 | 2021-09-21 | 盐城海德能水处理环保工程有限公司 | Oil field exploitation wastewater treatment equipment and method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1429773A (en) * | 2001-12-31 | 2003-07-16 | 中国科学院大连化学物理研究所 | Method of treating oil field waste water by electric-multiphase catalytic reaction and its special equipment |
| CN101492200A (en) * | 2009-03-04 | 2009-07-29 | 广东工业大学 | Method for photoelectrocatalysis oxidization of organic waste water with ozone |
| CN102826694A (en) * | 2012-09-14 | 2012-12-19 | 西北有色金属研究院 | Method for processing industrial wastewater by membrane separation/catalytic degradation composite process |
| CN103523971A (en) * | 2013-10-22 | 2014-01-22 | 中国海洋石油总公司 | Combined treatment method and combined treatment system for offshore platform domestic sewage |
-
2016
- 2016-05-25 CN CN201610356540.2A patent/CN105858984A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1429773A (en) * | 2001-12-31 | 2003-07-16 | 中国科学院大连化学物理研究所 | Method of treating oil field waste water by electric-multiphase catalytic reaction and its special equipment |
| CN101492200A (en) * | 2009-03-04 | 2009-07-29 | 广东工业大学 | Method for photoelectrocatalysis oxidization of organic waste water with ozone |
| CN102826694A (en) * | 2012-09-14 | 2012-12-19 | 西北有色金属研究院 | Method for processing industrial wastewater by membrane separation/catalytic degradation composite process |
| CN103523971A (en) * | 2013-10-22 | 2014-01-22 | 中国海洋石油总公司 | Combined treatment method and combined treatment system for offshore platform domestic sewage |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106430821A (en) * | 2016-09-30 | 2017-02-22 | 哈尔滨工程大学 | Ship black water and ash water treatment device and method |
| CN106430821B (en) * | 2016-09-30 | 2019-09-27 | 哈尔滨工程大学 | A kind of ship Heisui River and waste water treatment device and method |
| CN109502703A (en) * | 2018-12-17 | 2019-03-22 | 长江水利委员会长江科学院 | The suppressing method and device of a kind of pair of bed mud provenance cyanobacteria recovery |
| CN110015749A (en) * | 2019-04-03 | 2019-07-16 | 上海海事大学 | One kind being used for emulsified waste liquid sterilization process device and technique |
| CN110787799A (en) * | 2019-08-16 | 2020-02-14 | 浙江工业大学 | Preparation method of foamed copper oxide/TNTs photoelectric composite material |
| CN110787799B (en) * | 2019-08-16 | 2022-08-23 | 浙江工业大学 | Preparation method of foamed copper oxide/TNTs photoelectric composite material |
| CN111252970A (en) * | 2020-02-13 | 2020-06-09 | 湛江远通高新技术有限公司 | Oil-water separation method for oily sewage of ship |
| CN113415937A (en) * | 2021-06-15 | 2021-09-21 | 盐城海德能水处理环保工程有限公司 | Oil field exploitation wastewater treatment equipment and method |
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Application publication date: 20160817 |