CN104163544A - Ecological pond effluent deep treatment method and device - Google Patents
Ecological pond effluent deep treatment method and device Download PDFInfo
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Abstract
一种生态塘出水深度处理装置:一滚筒格栅机,其出水通过缩口进水管喷入生态塘内的底部;生态塘的出水进入扰流纳米曝气反冲筛滤池中,扰流纳米曝气反冲筛滤池处理后的出水自流至纳米曝气消融装置中,纳米曝气消融装置底部开设有排泥口,纳米曝气消融装置内部位于排泥口的上方设置有纳米曝气盘,纳米曝气盘连接纳米O3曝气机;纳米曝气消融装置安装有温度控制仪,该温度控制仪连接并控制安置在纳米曝气消融装置内部的感温控头和加热带。本发明还公开了利用上述装置进行污水处理的方法。
An ecological pond effluent advanced treatment device: a roller grille machine, the effluent of which is sprayed into the bottom of the ecological pond through the shrinkage inlet pipe; The effluent treated by the air recoil screen filter flows into the nano-aeration ablation device by itself. There is a mud discharge port at the bottom of the nano-aeration ablation device. The nano-aeration ablation device is located above the mud discharge port. The nano-aeration disk is connected to the nano-O 3 aerator; the nano-aeration ablation device is equipped with a temperature controller, which is connected to and controls the temperature-sensing head and the heating belt arranged inside the nano-aeration ablation device. The invention also discloses a sewage treatment method using the device.
Description
技术领域technical field
本发明涉及一种生态塘出水深度处理的组合工艺,具体地涉及一种生态塘出水深度处理装置。The invention relates to a combined process for advanced treatment of effluent from an ecological pond, in particular to a device for advanced treatment of effluent from an ecological pond.
本发明还涉及利用上述装置进行生态塘出水深度处理的方法。The present invention also relates to a method for advanced treatment of the effluent of the ecological pond by using the above-mentioned device.
背景技术Background technique
生态塘是利用天然水中存在的水生植物、水生动物对污水进行处理的一种稳定塘。稳定塘处理系统已在许多国家得到广泛应用,我国从上个世纪80年代开始至今在全国范围开展了研究。虽然与传统活性污泥法、A2/O法、氧化沟法、AB法以及近几年出现的ABC、SBR法、生物膜法、高压膜法等相比具有占地面积大的缺点,但其投资少、运行费用低、运行管理简单等优点是其他处理方法无法相匹敌的。目前,生态塘的处理工艺正在向着正规化、系统化、资源化、生态化、美学化的方向发展。筛选、培育高效水生净化植物(营建诸如水葫芦塘、芦苇塘、藕塘等水生植物塘),组合曝气、水生植物、水产养殖等多个生物处理单元的综合功能,营建生化一体化的水生动植物的复合生态体系,将成为生态塘处理工艺的发展方向。许多中小城市的污水处理长期以来没有受到应有的重视,有的只是经过了简单的处理就直接排入了自然水体,大部分处于放任自流的状态,据统计95%以上的生活污水被直接排放到地下或江河湖泊中,使环境不断恶化。在我国的中小城市土地资源丰富的地区稳定塘作为一种高效率、低能耗的污水处理方案具有广阔的应用前景。The ecological pond is a kind of stable pond that uses aquatic plants and aquatic animals existing in natural water to treat sewage. The stabilization pond treatment system has been widely used in many countries, and our country has carried out research on a national scale since the 1980s. Although compared with the traditional activated sludge method, A2/O method, oxidation ditch method, AB method, and ABC, SBR method, biofilm method, high-pressure membrane method that have appeared in recent years, it has the disadvantage of occupying a large area, but its The advantages of low investment, low operating costs, and simple operation and management are unmatched by other processing methods. At present, the treatment process of ecological ponds is developing in the direction of standardization, systematization, resource utilization, ecologicalization and aestheticization. Screen and cultivate high-efficiency aquatic purification plants (build aquatic plant ponds such as water hyacinth ponds, reed ponds, and lotus root ponds), combine the comprehensive functions of multiple biological treatment units such as aeration, aquatic plants, and aquaculture, and build biochemically integrated water The complex ecological system of animals and plants will become the development direction of ecological pond treatment technology. Sewage treatment in many small and medium-sized cities has not received due attention for a long time. Some of them are directly discharged into natural water bodies after simple treatment, and most of them are in a state of letting go. According to statistics, more than 95% of domestic sewage is directly discharged. To the ground or in rivers and lakes, the environment continues to deteriorate. As a high-efficiency and low-energy sewage treatment scheme, the stable pond has broad application prospects in the areas with rich land resources in small and medium-sized cities in my country.
由于氧化塘成本低廉,操作保养方便,在市政方面及私立开发公司拥有的小型废水处理系统中具有优越性,所以氧化塘在美国得到了广泛的应用。这种氧化塘1976年仅在南卡罗来纳州就有800多个。传统的生态塘直接作为二级处理单元用于处理污水,处理后的污水直接排入自然水体,容易引起自然水体的恶化。Oxidation ponds have been widely used in the United States due to their low cost, convenient operation and maintenance, and their superiority in municipal and small wastewater treatment systems owned by private development companies. In 1976, there were more than 800 such ponds in South Carolina alone. The traditional ecological pond is directly used as a secondary treatment unit to treat sewage, and the treated sewage is directly discharged into the natural water body, which is likely to cause the deterioration of the natural water body.
发明内容Contents of the invention
本发明的目的在于提供一种生态塘出水深度处理装置。The purpose of the present invention is to provide an ecological pond effluent advanced treatment device.
本发明的又一目的在于提供一种利用上述装置进行生态塘出水深度处理的方法。Another object of the present invention is to provide a method for advanced treatment of ecological pond effluent by using the above-mentioned device.
为实现上述目的,本发明提供的生态塘出水深度处理装置,其结构为:In order to achieve the above object, the ecological pond effluent advanced treatment device provided by the present invention has a structure of:
一滚筒格栅机,对不同密度的悬浮液进行沉降分层,其出水通过缩口进水管喷入生态塘内的底部;A roller screen machine, which settles and stratifies suspensions of different densities, and the outlet water is sprayed into the bottom of the ecological pond through the shrinkage inlet pipe;
生态塘中填充有对污染物质进行降解的碳素纤维填料;The ecological pond is filled with carbon fiber fillers that degrade pollutants;
流动填料上方设置有拦截碳素纤维填料的隔栏;A barrier to intercept carbon fiber packing is set above the flowing packing;
生态塘的上方设置有依靠漂浮载体漂浮在水面的太阳能动水除藻机,太阳能动水除藻机的上端设置有太阳能电池板,下端设置有以太阳能为动力的螺旋桨;The top of the ecological pond is equipped with a solar dynamic water algae removal machine that floats on the water surface by means of a floating carrier. The upper end of the solar dynamic water algae removal machine is equipped with a solar panel, and the lower end is equipped with a propeller powered by solar energy;
太阳能动水除藻机通过绳索连接生态浮床,生态浮床利用浮力漂浮在水面,上端设置孔洞用于栽种植物,生态浮床下面放置有重物,重物上悬挂有填料;The solar dynamic water algae removal machine is connected to the ecological floating bed through ropes. The ecological floating bed floats on the water surface by buoyancy. The upper end is provided with holes for planting plants. There are heavy objects placed under the ecological floating bed, and fillers are hung on the heavy objects;
生态塘的出水进入扰流纳米曝气反冲筛滤池中,扰流纳米曝气反冲筛滤池内部由多孔板分为上、下两部分;The effluent from the ecological pond enters the disturbed flow nano-aeration recoil screen filter tank, and the inside of the disturbed flow nano-aeration recoil screen filter tank is divided into upper and lower parts by a porous plate;
多孔板上方设置有连接纳米O2曝气机的纳米曝气头,纳米曝气头上铺设一层复合填料,复合填料上方设置有搅拌机,搅拌机的叶轮置于复合填料的上方;A nano - aerator head connected to a nano-O aerator is arranged above the porous plate, a layer of composite filler is laid on the nano-aerator head, a mixer is arranged above the composite filler, and the impeller of the mixer is placed above the composite filler;
复合填料上方的一侧设置有连接纳米O2曝气机的曝气头,曝气管设有多个细孔曝气孔,曝气孔垂直向上,曝气管上方设置有回流槽;The side above the composite filler is provided with an aeration head connected to a nano- O2 aerator, and the aeration pipe is provided with a plurality of fine aeration holes, the aeration holes are vertically upward, and a reflux tank is provided above the aeration pipe;
复合填料的上方安装有超声波发生仪;An ultrasonic generator is installed above the composite filler;
多孔板的下方为储水箱,其内壁均匀负载一层非金属掺杂光催化剂,底部安装有紫外灭菌灯,在紫外灭菌灯的空隙间设置纳米曝气头,储水箱内部剩余空间填充有半导体负载填料,在半导体负载填料的内部设有连接纳米O3曝气机的曝气头;Below the porous plate is the water storage tank, the inner wall of which is evenly loaded with a layer of non-metallic doped photocatalyst, the bottom is equipped with an ultraviolet sterilizing lamp, and a nano aeration head is installed in the gap between the ultraviolet sterilizing lamp, and the remaining space inside the water storage tank is filled with The semi-conductor-loaded filler is equipped with an aeration head connected to a nano- O3 aerator inside the semiconductor-loaded filler;
扰流纳米曝气反冲筛滤池的出水自流至纳米曝气消融装置中,纳米曝气消融装置底部开设有排泥口,纳米曝气消融装置内部位于排泥口的上方设置有纳米曝气盘,纳米曝气盘连接纳米O3曝气机;纳米曝气消融装置安装有温度控制仪,该温度控制仪连接并控制安置在纳米曝气消融装置内部的感温控头和加热带。The effluent of the disturbed flow nano-aeration recoil screen filter flows into the nano-aeration and ablation device by itself. The nano-aeration disk is connected to the nano-O 3 aerator; the nano-aeration ablation device is equipped with a temperature controller, which is connected to and controls the temperature-sensing head and the heating belt placed inside the nano-aeration ablation device.
所述的生态塘出水深度处理装置,其中,滚筒格栅机的转速为30-5000r/min。Said ecological pond effluent advanced treatment device, wherein, the rotating speed of the roller grill machine is 30-5000r/min.
所述的生态塘出水深度处理装置,其中,隔栏的栏杆呈上宽下窄形态。In the device for advanced treatment of effluent in ecological ponds, the railings of the partitions are wide at the top and narrow at the bottom.
所述的生态塘出水深度处理装置,其中,多孔板是由两层多孔板夹杂一层不锈钢纱网组成。In the advanced treatment device for the effluent of the ecological pond, the porous plate is composed of two layers of porous plates mixed with a layer of stainless steel gauze.
所述的生态塘出水深度处理装置,其中,生态浮床选用高强度聚苯乙烯浮床。In the advanced treatment device for the effluent of the ecological pond, the ecological floating bed is made of high-strength polystyrene floating bed.
所述的生态塘出水深度处理装置,其中,生态浮床上采用水面无土栽培水生植物的方式,利用这些植物来汲取动物产生的养分,处理富营养化水体。The device for advanced treatment of effluent in the ecological pond, wherein the ecological floating bed adopts the method of cultivating aquatic plants without soil on the water surface, and uses these plants to absorb nutrients produced by animals to treat eutrophic water bodies.
所述的生态塘出水深度处理装置,其中,生态浮床下面悬挂的填料为纳米级碳素纤维填料或组合填料,呈上下形式的设置,碳素纤维设置区域面积不小于水域面积的20%。Said ecological pond effluent advanced treatment device, wherein the filler suspended under the ecological floating bed is nano-scale carbon fiber filler or combined filler, which is set up and down, and the carbon fiber setting area is not less than 20% of the water area.
所述的生态塘出水深度处理装置,其中,扰流纳米曝气反冲筛滤池内部的复合填料采用粒径为0.5-1.0mm的天然沸石分子筛以及锰砂,填料配比为5:1。The ecological pond effluent advanced treatment device, wherein the composite filler inside the flow-disturbing nano-aeration recoil screen filter adopts natural zeolite molecular sieve with a particle size of 0.5-1.0mm and manganese sand, and the filler ratio is 5:1.
本发明提供的利用上述生态塘出水深度处理装置进行污水处理的方法:The method provided by the present invention utilizes the above-mentioned ecological pond effluent advanced treatment device to carry out sewage treatment:
通过一滚筒格栅机,利用悬浮液密度不同的各组分在离心力场中迅速沉降分层的原理,实现液-固或液-液分离;Through a roller grid machine, the liquid-solid or liquid-liquid separation is realized by using the principle of rapid sedimentation and stratification of components with different suspension densities in the centrifugal force field;
滚筒格栅机的出水通过增压泵增压,在缩口进水管的作用下高压喷入生态塘内下方,使生态塘中填充的碳素纤维流动填料在水流的作用下不断翻滚混合,在缺氧条件下对污染物质进行降解;经过生态塘处理的水流通过隔栏涌入生态塘上方的塘体,隔栏将碳素纤维填料拦截下来;The outlet water of the roller grill machine is pressurized by the booster pump, and under the action of the shrinkage inlet pipe, it is sprayed into the bottom of the ecological pond under high pressure, so that the carbon fiber flow filler filled in the ecological pond is continuously rolled and mixed under the action of the water flow, and the The pollutants are degraded under the condition of oxygen; the water treated by the ecological pond pours into the pond body above the ecological pond through the barrier, and the carbon fiber filler is intercepted by the barrier;
生态塘中的太阳能动水除藻机以太阳能为原动力,驱动叶片运转形成水流;自下而上运行时动水增氧,自上而下运行时把块状化的藻打碎分解,持续性地让水体产生上下层对流,使水体达到高效循环处理后进入扰流纳米曝气反冲筛滤池;The solar water dynamic algae removal machine in the ecological pond uses solar energy as the driving force to drive the blades to form water flow; when running from bottom to top, the dynamic water increases oxygen, and when running from top to bottom, it breaks and decomposes the massive algae. Let the water body generate upper and lower layer convection, so that the water body can reach the high-efficiency circulation treatment and then enter the disturbing nano-aeration recoil screen filter;
扰流纳米曝气反冲筛滤池内的纳米曝气头间歇工作,冲散复合填料和半导体负载填料上的致密污物层,污染物质层在曝气管的浮力作用下溢流至回流槽,使污染物集中排除与进水混合重新处理,以延长扰流纳米曝气反冲筛滤池的使用寿命及反洗周期;The nano-aeration head in the turbulent nano-aeration recoil screen filter works intermittently to disperse the dense dirt layer on the composite filler and semiconductor-loaded filler, and the pollutant layer overflows to the return tank under the buoyancy of the aeration tube , so that pollutants can be concentratedly removed and mixed with influent water for retreatment, so as to prolong the service life and backwashing cycle of the disturbed flow nano aeration backwashing screen filter;
扰流纳米曝气反冲筛滤池内半导体负载填料的曝气头采用O3曝气,由于纳米气泡具有庞大的数量、比表面积、缓慢的上升速度等特性,同时气泡在水中停留时间长,增加了气液接触面积、接触时间,利于臭氧溶于水中,克服了臭氧难溶于水的缺点;微气泡内部具有较大的压力且纳米气泡破裂时界面消失,周围环境剧烈改变产生的化学能促使产生更多的羟基自由基·OH,增强O3氧化分解有机物的能力;且纳米级别O3气泡与紫外灭菌灯、半导体负载填料共存于储水箱,提高高级氧化效果,可有效提高·OH产生率;装置中纳米二氧化钛晶体作为光触媒在紫外灯照射下激发极具氧化力的自由负离子,同时在纳米曝气过程中以及超声波发生过程激发的能量亦可发生并加强自由负离子的产生,达成光催化效果;而自由负离子以及其摆脱共价键的束缚后留下空位,与纳米气泡表面带有的电荷同时产生微电解效果。扰流纳米曝气反冲筛滤池的出水同时回流至生态塘进水,调节水质并刺激植物生长过程分泌次生物质。The aeration head of the semiconductor-loaded filler in the disturbed flow nano-aeration recoil screen filter adopts O 3 aeration. Because the nano-bubbles have characteristics such as a large number, specific surface area, and slow rising speed, and the bubbles stay in the water for a long time, Increase the gas-liquid contact area and contact time, which is conducive to the dissolution of ozone in water, and overcomes the shortcomings of ozone insoluble in water; there is a large pressure inside the microbubbles and the interface disappears when the nanobubbles break, and the chemical energy generated by the drastic changes in the surrounding environment Promote the production of more hydroxyl radicals OH, enhance the ability of O 3 to oxidize and decompose organic matter; and nano-scale O 3 bubbles coexist with ultraviolet sterilization lamps and semiconductor-loaded fillers in the water storage tank to improve the advanced oxidation effect and effectively increase OH Production rate: nano-titanium dioxide crystals in the device act as photocatalysts to excite highly oxidative free negative ions under the irradiation of ultraviolet lamps. At the same time, the energy excited during the process of nano-aeration and ultrasonic generation can also occur and strengthen the production of free negative ions to achieve light. Catalytic effect; while free negative ions and their vacancies after getting rid of the covalent bond, and the charge on the surface of nanobubbles produce micro-electrolysis effect at the same time. The effluent of the disturbed flow nano-aeration recoil screen filter returns to the ecological pond at the same time to adjust the water quality and stimulate the secretion of secondary substances in the process of plant growth.
扰流纳米曝气反冲筛滤池的出水同时回流至生态塘进水,调节水质并刺激植物生长过程分泌次生物质;The effluent of the disturbed flow nano-aeration recoil screen filter flows back to the ecological pond at the same time to adjust the water quality and stimulate the secretion of secondary substances during the growth of plants;
扰流纳米曝气反冲筛滤池出水自流至纳米曝气消融装置中进行纳米曝气处理,将污水中难降解有机化合物分解消融,病原菌和微生物被灭活。The effluent of the disturbed flow nano-aeration recoil screen filter flows into the nano-aeration and ablation device for nano-aeration treatment, which decomposes and ablates the refractory organic compounds in the sewage, and inactivates pathogenic bacteria and microorganisms.
所述的方法,其中,纳米曝气消融装置的温度为25-35℃。Said method, wherein the temperature of the nano-aeration ablation device is 25-35°C.
本发明采用离心机降低生态塘进水负荷,防止由于有机营养物过剩导致藻类疯长,同时采用太阳能动水除藻机曝气除藻,增加生态塘内溶解氧浓度,去除塘内藻类,使用生态浮床增强生态系统稳定性,并设计一种扰流纳米曝气反冲筛滤池对生态塘出水进行深度处理,提高出水透明度的同时进行高级氧化,氧化降解残留污染物质,最后采用纳米曝气消融装置深度进行最终处理。本发明利用太阳能作为电力补偿,利用流体力学动水效果好,水面放置施工维修简单,现行使用生态法处理污染物质,后续使用多功能筛滤降低污水浊度,高效降低污水中残留污染物、难降解痕量物质,提高污水水质,出水可作为中水回用或直接排放。The invention uses a centrifuge to reduce the water intake load of the ecological pond, prevents the excessive growth of algae due to excess organic nutrients, and at the same time uses a solar dynamic water algae removal machine to aerate and remove algae, increase the dissolved oxygen concentration in the ecological pond, remove algae in the pond, and use an ecological floating bed to enhance Ecosystem stability, and design a disruptive nano-aeration recoil screen filter for advanced treatment of ecological pond effluent, improve the transparency of effluent while performing advanced oxidation, oxidative degradation of residual pollutants, and finally adopt nano-aeration ablation device depth For final processing. The present invention utilizes solar energy as electric power compensation, utilizes hydrodynamic dynamics to achieve good hydrodynamic effects, and is easy to place on the water surface for construction and maintenance. Currently, ecological methods are used to treat pollutants, and multi-functional screening is used to reduce sewage turbidity, effectively reducing residual pollutants in sewage, difficult to Degrade trace substances, improve sewage water quality, and the effluent can be reused as reclaimed water or directly discharged.
附图说明Description of drawings
图1是本发明的生态塘出水深度处理装置的结构示意图。Fig. 1 is a schematic structural view of the ecological pond effluent advanced treatment device of the present invention.
附图中主要组件符号说明:Explanation of main component symbols in the attached drawings:
1滚筒格栅机;2太阳能动水除藻机;3太阳能电池板;4螺旋桨;5生态浮床;6生态塘;7填料;8植物;9曝气机;10重物;11扰流纳米曝气反冲筛滤池;12搅拌机;13叶轮;14纳米曝气消融装置;15纳米曝气机;16排泥口;17纳米曝气盘;18紫外灭菌灯;19多孔板;20纳米曝气头;21半导体负载填料;22储水箱;23液压泵;24碳素纤维流动填料;25隔栏;26缩口进水管;27增压泵;28超声波发生仪;29曝气管;30回流槽;31复合填料。1 Roller grid machine; 2 Solar dynamic water algae removal machine; 3 Solar panel; 4 Propeller; 5 Ecological floating bed; 6 Ecological pond; 7 Filling; 8 Plants; Air recoil sieve filter; 12 mixer; 13 impeller; 14 nanometer aeration and ablation device; 15 nanometer aerator; 16 mud discharge port; 17 nanometer aeration disc; 18 ultraviolet sterilization lamp; Gas head; 21 semiconductor load filler; 22 water storage tank; 23 hydraulic pump; 24 carbon fiber flow filler; slot; 31 composite filler.
具体实施方式Detailed ways
本发明提供的处理污水的一种生态塘出水深度处理的组合工艺,其主要结构如图1所示,包括:A kind of ecological pond effluent advanced treatment combined process for sewage treatment provided by the present invention, its main structure is as shown in Figure 1, including:
一滚筒格栅机1,利用悬浮液(或乳浊液)密度不同的各组分在离心力场中迅速沉降分层的原理,实现液-固(或液-液)分离。离心机出水通过增压泵27增压,在缩口进水管26的作用下高压喷入生态塘内6。滚筒格栅机的转速可以控制在30-5000r/min。A roller grid machine 1, which realizes liquid-solid (or liquid-liquid) separation by utilizing the principle that components with different densities of suspensions (or emulsions) rapidly settle and stratify in a centrifugal force field. The centrifuge outlet water is pressurized by the booster pump 27, and is sprayed into the ecological pond 6 at high pressure under the effect of the shrinkage inlet pipe 26. The rotating speed of the roller grill machine can be controlled at 30-5000r/min.
生态塘6,进水在压力作用下喷入生态塘6下方,碳素纤维流动填料24在水流的作用下不断翻滚混合,在缺氧条件下,污染物质得到降解,经过预处理的水流通过隔栏25涌入生态塘6上方的塘体,隔栏25的每条栏杆呈上宽下窄形态,流动填料24被有效拦截下来;太阳能动水除藻机2依靠漂浮载体漂浮在水面,利用绳索与生态塘6的塘体连接;为防止太阳能动水除藻机失衡,可以通过绳索将太阳能动水除藻机固定在水面。太阳能动水除藻机2上端设置有太阳能电池板3,下端设置有螺旋桨4,以太阳能为原动力驱动螺旋桨运转形成水流。自下而上运行时动水增氧,自上而下运行时把块状化的藻打碎、分解,持续性地让水体产生上下层对流,让水体达到高效循环。太阳能动水除藻机2通过绳索连接生态浮床5,生态浮床选用承载能力强、耐腐蚀性好的高强度聚苯乙烯浮床,生态浮床5利用浮力漂浮在水面,上端设置孔洞采用水面无土栽培水生植物的方式栽种植物8,利用这些植物来汲取动物产生的养分,处理富营养化水体。In the ecological pond 6, the influent water is sprayed into the bottom of the ecological pond 6 under the action of pressure, and the carbon fiber flow filler 24 is continuously rolled and mixed under the action of the water flow. The fence 25 pours into the pond body above the ecological pond 6, and each railing of the fence 25 is wide at the top and narrow at the bottom, and the flowing filler 24 is effectively intercepted; It is connected with the pond body of the ecological pond 6; in order to prevent the imbalance of the solar dynamic water algae remover, the solar dynamic water algae remover can be fixed on the water surface by ropes. The upper end of the solar powered water algae removal machine 2 is provided with a solar panel 3, and the lower end is provided with a propeller 4, and the propeller is driven by solar energy to form a water flow. When it runs from bottom to top, it moves water to increase oxygen, and when it runs from top to bottom, it breaks and decomposes the massive algae, and continuously creates convection between the upper and lower layers of the water body, so that the water body can achieve efficient circulation. The solar dynamic water algae removal machine 2 is connected to the ecological floating bed 5 through ropes. The ecological floating bed is made of high-strength polystyrene floating bed with strong bearing capacity and good corrosion resistance. The ecological floating bed 5 floats on the water surface by buoyancy, and the upper end is set with holes for soilless cultivation on the water surface. Plant 8 in the form of aquatic plants, use these plants to absorb nutrients produced by animals, and treat eutrophic water bodies.
生态浮床5下面依靠重物10悬挂一定量的填料7,该填料为纳米级碳素纤维填料或组合填料,呈上下形式的设置;碳素纤维设置区域面积不小于水域面积的20%,碳素纤维填料的表面形成的生物膜,其断面上由外及里形成了好氧、兼性厌氧和厌氧三种反应区。生态浮床5上设置有曝气机9,在太阳能不足的情况下作为曝气补偿。A certain amount of filler 7 is suspended under the ecological floating bed 5 by weights 10. The filler is nano-scale carbon fiber filler or composite filler, which is set up and down; the area where the carbon fiber is set is not less than 20% of the water area, and the carbon fiber The biofilm formed on the surface of the fiber filler forms three reaction zones, aerobic, facultative anaerobic and anaerobic, from the outside to the inside. The ecological floating bed 5 is provided with an aerator 9, which is used as aeration compensation in the case of insufficient solar energy.
生态塘6的出水通过液压泵23进入扰流纳米曝气反冲筛滤池11中。The effluent from the ecological pond 6 enters the disturbed flow nano-aeration recoil screen filter tank 11 through the hydraulic pump 23 .
扰流纳米曝气反冲筛滤池11由两层多孔板19夹杂一层不锈钢纱网分为上、下两部分。多孔板19上方设置一纳米曝气头20,纳米曝气头20上铺设一层复合填料31,该复合填料为粒径0.5-1.0mm的天然沸石分子筛以及锰砂,填料配比为5:1,用以去除重金属。复合填料31上方设置有搅拌机12,搅拌机的叶轮13置于复合填料31的上方。复合填料31上方的一侧设置有一曝气管29,曝气管29设有多个细孔曝气孔,曝气孔垂直向上,曝气管29上方设置有回流槽30;复合填料31的上方还安装有超声波发生仪28。多孔板19的下方为储水箱22,其内壁均匀负载一层非金属掺杂光催化剂(如纳米TiO2粉体),底部安装有紫外灭菌灯18,在紫外灭菌灯18的空隙间设置纳米曝气头,储水箱22内部剩余空间填充有半导体负载填料21(如纳米TiO2粉体负载在立体网状聚丙烯填料),本发明将填料固定在载体上,解决了常规光催化剂需要分散剂协同使用的弊端,减少了催化剂的流失现象,避免了反应结束后催化剂的分离步骤。The flow-disturbing nano-aeration recoil screen filter tank 11 is divided into upper and lower parts by two layers of perforated plates 19 mixed with a layer of stainless steel gauze. A nano-aeration head 20 is set above the porous plate 19, and a layer of composite filler 31 is laid on the nano-aeration head 20. The composite filler is natural zeolite molecular sieve and manganese sand with a particle size of 0.5-1.0 mm, and the filler ratio is 5:1. , to remove heavy metals. An agitator 12 is arranged above the composite filler 31 , and the impeller 13 of the agitator is placed above the composite filler 31 . One side above the composite filler 31 is provided with an aeration pipe 29, the aeration pipe 29 is provided with a plurality of micropore aeration holes, the aeration holes are vertically upward, and a return tank 30 is arranged above the aeration pipe 29; the top of the composite filler 31 Ultrasonic generator 28 is also installed. Below the perforated plate 19 is a water storage tank 22, and its inner wall evenly loads a layer of non-metallic doped photocatalyst (such as nanometer TiO 2 powder), and an ultraviolet sterilization lamp 18 is installed at the bottom, and is arranged between the gaps of the ultraviolet sterilization lamp 18. Nano-aeration head, the remaining space inside the water storage tank 22 is filled with semiconductor-loaded fillers 21 (such as nano- TiO2 powder loaded on three-dimensional network polypropylene fillers), the invention fixes the fillers on the carrier, which solves the need for conventional photocatalysts to disperse The disadvantages of the synergistic use of the catalyst reduce the loss of the catalyst and avoid the separation step of the catalyst after the reaction.
扰流纳米曝气反冲筛滤池11工作时,纳米曝气头不连续工作,空气自多孔板向上鼓起,分割成小气泡,间歇冲散复合填料31上的致密污物层,污染物质层破碎成片状浮起,在纳米曝气头20的浮力作用下,溢流至回流槽30,使复合填料31截留的污染物集中排出,与进水混合重新处理,以延长扰流纳米曝气反冲筛滤池11的使用寿命及反洗周期,对于进水浊度较低的情况,甚至可以无需反冲洗,不断运行净化污水。When the flow-disturbing nano-aeration recoil screen filter 11 is working, the nano-aeration head does not work continuously, and the air bulges upward from the porous plate and is divided into small air bubbles, which intermittently disperse the dense dirt layer on the composite packing 31. Pollutants The layer is broken into flakes and floats, under the buoyancy of the nano-aeration head 20, it overflows to the return tank 30, so that the pollutants trapped by the composite filler 31 are discharged in a concentrated manner, and mixed with the influent water for retreatment, so as to prolong the turbulent nano-aeration. The service life and the backwashing cycle of the air backwashing screen filter 11, for the situation that the turbidity of the influent is low, even the need for backwashing can be continuously operated to purify the sewage.
扰流纳米曝气反冲筛滤池11内的纳米曝气头采用O3曝气,由于纳米气泡具有庞大的数量、比表面积、缓慢的上升速度等特性,同时气泡在水中停留时间长,增加了气液接触面积、接触时间,利于臭氧溶于水中,克服了臭氧难溶于水的缺点;微气泡内部具有较大的压力且纳米气泡破裂时界面消失,周围环境剧烈改变产生的化学能促使产生更多的羟基自由基·OH,增强O3氧化分解有机物的能力;且纳米级别O3气泡与紫外灭菌灯、半导体负载填料共存于储水箱,提高高级氧化效果,可有效提高·OH产生率,紫外灭菌灯平均照射剂量在300J/m2以上。The nano-aeration head in the turbulent nano-aeration recoil screen filter tank 11 adopts O3 aeration, because the nano-bubbles have characteristics such as huge number, specific surface area, and slow rising speed, and at the same time, the bubbles stay in the water for a long time, increasing The gas-liquid contact area and contact time are improved, which is conducive to the dissolution of ozone in water and overcomes the shortcomings of ozone insoluble in water; there is a large pressure inside the microbubble and the interface disappears when the nanobubble breaks, and the chemical energy generated by the drastic change in the surrounding environment promotes Generate more hydroxyl radicals OH, enhance the ability of O 3 to oxidize and decompose organic matter; and nano-level O 3 bubbles coexist with ultraviolet sterilization lamps and semiconductor-loaded fillers in the water storage tank to improve the advanced oxidation effect and effectively increase OH generation rate, the average irradiation dose of ultraviolet germicidal lamps is above 300J/m 2 .
扰流纳米曝气反冲筛滤池11的出水自流至纳米曝气消融装置14中。纳米曝气消融装置14底部开设有排泥口16,纳米曝气消融装置14内部位于排泥口16的上方设置有纳米曝气盘17,纳米曝气盘17连接纳米曝气机15,进气为O3。纳米曝气盘17产生的气泡均匀混入污水中,通过纳米曝气大量获得羟基自由基,起强氧化作用在高温纳米曝气的情况下对污水进行纳米曝气处理,污水中难降解有机化合物分解、消融,病原菌和微生物被灭活,同时在去除有机物、降低COD的同时,污水的透明度、色度也有所提高。纳米曝气消融装置内安装有温度控制仪,该温度控制仪连接并控制安置在反应器内部的感温控头和加热带,温度通过温控装置控制在25-35℃。The effluent from the disturbed flow nano-aeration recoil screen filter 11 flows into the nano-aeration ablation device 14 by itself. The bottom of the nano-aeration and ablation device 14 is provided with a mud outlet 16, and the inside of the nano-aeration and ablation device 14 is located above the mud outlet 16. A nano-aeration disc 17 is provided. The nano-aeration disc 17 is connected to the nano-aerator 15, and the air intake is O 3 . The bubbles generated by the nano-aeration disc 17 are evenly mixed into the sewage, and a large amount of hydroxyl radicals are obtained through nano-aeration, which plays a strong oxidation role. Under the condition of high-temperature nano-aeration, the sewage is treated with nano-aeration, and the refractory organic compounds in the sewage are decomposed. , ablation, pathogenic bacteria and microorganisms are inactivated, while removing organic matter and reducing COD, the transparency and chroma of sewage are also improved. A temperature controller is installed in the nano-aeration ablation device, which is connected to and controls the temperature-sensing head and the heating belt installed inside the reactor, and the temperature is controlled at 25-35°C by the temperature control device.
本发明的非金属掺杂光催化剂(碳掺杂的纳米TiO2粉体)的制备:采用均匀沉淀法和水热法两步过程制备碳掺杂的纳米TiO2。以硫酸钛和尿素为前驱,葡萄糖为碳源,具体制备过程如下:取6.48g27硫酸钛和3.24g54尿素(硫酸钛与尿素的摩尔比为1:2)溶于去离子水中,再加入适量的葡萄糖0.6搅拌均匀,1:2:0.023在90℃的条件下反应2h。待反应结束后取出反应物干燥、反复水洗至中性,再次干燥,用球磨机研磨得到碳掺杂的纳米TiO2粉体。Preparation of the non-metallic doped photocatalyst (carbon-doped nano TiO 2 powder) of the present invention: the carbon-doped nano TiO 2 is prepared by a two-step process of a uniform precipitation method and a hydrothermal method. With titanium sulfate and urea as the precursor, glucose as the carbon source, the specific preparation process is as follows: take 6.48g27 titanium sulfate and 3.24g54 urea (the molar ratio of titanium sulfate and urea is 1:2) dissolved in deionized water, and then add an appropriate amount of Glucose 0.6 was stirred evenly, and 1:2:0.023 was reacted at 90°C for 2 hours. After the reaction is finished, the reactant is taken out and dried, repeatedly washed with water until neutral, dried again, and ground with a ball mill to obtain carbon-doped nano TiO 2 powder.
纳米TiO2粉体负载在填料上的方法:采用聚丙烯材质的立体网状结构填料,将纳米TiO2粉体与去离子水(粉体与水的质量比为1:20)混合,用超声波超声成乳浊液,将洁净的立体网状结构填料浸入与乙醇1:1混合的钛酸酯偶联剂,缓慢搅拌一段时间,然后将填料取出放入TiO2乳浊液中继续搅拌一段时间,取出后放入烘箱中干燥(85℃以下)2h,即制得负载纳米TiO2的聚丙烯悬浮填料,其外观呈淡黄色,膜层较均匀。The method of loading nano-TiO 2 powder on the filler: using a three-dimensional network structure filler made of polypropylene, mixing nano-TiO 2 powder with deionized water (the mass ratio of powder to water is 1:20), and ultrasonically Ultrasound to form an emulsion, immerse the clean three-dimensional network structure filler into the titanate coupling agent mixed with ethanol 1:1, stir slowly for a period of time, then take out the filler and put it into the TiO 2 emulsion to continue stirring for a period of time After taking it out, put it in an oven to dry (below 85°C) for 2 hours, and then the polypropylene suspension filler loaded with nano-TiO 2 is obtained. Its appearance is light yellow and the film layer is relatively uniform.
正常筛滤时,开启搅拌机,其转速为100r/min,随着筛滤过程中由于污染物质堆积,水流不能顺利通过填料。液位不断增高的过程,开启曝气管29并间歇开启多孔板下方纳米曝气机15,储水箱22内纳米曝气头不连续工作,空气自多孔板向上鼓起,分割成小气泡,协同搅拌机的转动冲散筛滤填料上的致密污物层,污染物质层破碎成片状浮起。在曝气管的浮力以及进水冲击向右推力的协同作用下产生波轮效果,大力清洗填料表层片状致密污染物,溢流至回流槽,使填料截留的污染物集中排除装置外,与进水混合重新处理,污水也可继续自分子筛空隙渗透下去。本筛滤装置可延长使用寿命及反洗周期,对于进水浊度较低的情况,甚至可以无需反冲洗,使装置不断运行净化污水。During normal sieving, turn on the agitator with a rotation speed of 100r/min. During the sieving process, due to the accumulation of pollutants, the water flow cannot pass through the filler smoothly. During the process of increasing the liquid level, open the aeration pipe 29 and intermittently open the nano-aerator 15 under the porous plate, the nano-aerator in the water storage tank 22 does not work continuously, the air bulges upward from the porous plate, and is divided into small bubbles, synergistically The rotation of the mixer washes away the dense dirt layer on the sieve filler, and the pollutant layer is broken into flakes and floated. Under the synergistic effect of the buoyancy of the aeration tube and the thrust to the right of the incoming water impact, a pulsator effect is produced, which vigorously cleans the flaky and dense pollutants on the surface of the packing, and overflows to the return tank, so that the pollutants trapped by the packing are discharged out of the device in a concentrated manner. The influent water is mixed and reprocessed, and the sewage can also continue to permeate through the gaps of the molecular sieve. The screening device can prolong the service life and the backwashing cycle. For the case of low influent turbidity, backwashing can even be unnecessary, so that the device can continue to operate to purify sewage.
二级反冲洗为空气脉冲反冲洗,由于污水浊度过高,导致污染物质在填料表面的大量堆积,仅仅靠一级反冲洗步骤仍不能达到继续筛滤的效果。此时停止进、出水,关闭液压泵23,启动两纳米曝气机15,并将出水池内出水导入储水箱中,当储水箱内液面接近多孔板时停止。在回水压力的作用下,储水箱中的全部空气受到快速挤压,沿分压仓上细孔上升,全部筛滤填料层在上升空气、旋转扰动的波轮作用及填料下纳米曝气头的冲击力作用下,填料间隙的污染物质破碎浮起,又在曝气管的浮力以及进水冲击挡流板向右推力的协同作用下,溢流至回流槽与初始进水混合,待水面快速下降。过滤速率重新稳定后,关闭两纳米曝气机15,开启液压泵23并恢复进出水,继续进行筛滤处理。The second-stage backwash is an air pulse backwash. Due to the high turbidity of the sewage, a large amount of pollutants accumulate on the surface of the filler. The effect of continuous screening cannot be achieved only by the first-stage backwash step. At this moment, stop the water inlet and outlet, close the hydraulic pump 23, start the two nanometer aerator 15, and import the water outlet in the water outlet tank in the water storage tank, and stop when the liquid level in the water storage tank is close to the perforated plate. Under the action of the return water pressure, all the air in the water storage tank is quickly squeezed and rises along the fine holes on the partial pressure chamber, and the entire filter packing layer is under the action of the rising air, the rotating and disturbing wave wheel and the nano aeration head under the packing. Under the action of the impact force, the pollutants in the packing gap are broken and floated, and under the synergistic effect of the buoyancy of the aeration tube and the rightward thrust of the water impact baffle, they overflow to the return tank and mix with the initial water, and wait for the water surface drop rapidly. After the filtration rate is stabilized again, close the two-nanometer aerator 15, open the hydraulic pump 23 and restore the water in and out, and continue the sieve treatment.
三级反冲洗为曝气湍流反冲洗,此时上文提及的两级反冲洗已经不足以解决污染物质对填料的覆盖、阻塞问题,污水大量积聚不得过滤。此时停止进、出水,关闭液压泵23,启动超声波发生仪28及两纳米曝气机15,并将出水池内出水大量导入储水箱中,当储水箱内液面接近多孔板时停止。⑴储水箱内部空气沿多孔板细孔上升搅拌,填料底部纳米曝气头开始曝气,填料上方涡轮不断转动;⑵利用纳米曝气技术冲击、氧化、气浮及高温作用协同清洗,上方填料呈现湍流状态,进行无规则高速运动状态,填料在水流旋涡的冲击力和气泡的剪切力作用下相互摩擦,填料上附着的有机污染物能够去除,得到较为纯净的填料;⑶利用超声波发生仪在液体介质中产生超声波,在筛滤填料表面产生空化效应,空化汽泡在闭合过程中破裂时形成的冲击波,会在其周围产生上千个气压的冲击压力,作用在填料表面上破坏污物之间粘性,并使它们迅速分散在反洗液中,从而达到填料表面洁净的效果。⑷空气排净后,出水池的出水继续导入,富含羟自由基的出水冲洗湍流状态的的填料颗粒表面及微孔,剥离污染物质,填料得到再生。⑸而污染物质在水流冲击力及右侧曝气管气浮作用下不断向上浮至水面,自左端进水堰及右端回流槽流出与初始进水混合。经过三级反冲洗,内部污染物被清洗排空殆尽。The three-stage backwash is an aeration turbulent backwash. At this time, the two-stage backwash mentioned above is not enough to solve the problem of covering and blocking the filler by pollutants, and a large amount of sewage accumulates and cannot be filtered. Now stop entering and leaving water, close hydraulic pump 23, start ultrasonic generator 28 and two nanometer aerators 15, and a large amount of water is imported in the water storage tank in the water outlet pool, and stop when the liquid level in the water storage tank is close to the perforated plate. ⑴The air inside the water storage tank rises and stirs along the pores of the porous plate, the nano-aeration head at the bottom of the filler starts to aerate, and the turbine above the filler keeps rotating; In the state of turbulent flow and irregular high-speed movement, the fillers rub against each other under the impact of the vortex of the water flow and the shear force of the air bubbles, and the organic pollutants attached to the fillers can be removed to obtain relatively pure fillers; Ultrasonic waves are generated in the liquid medium, and cavitation effects are generated on the surface of the sieve packing. The shock wave formed when the cavitation bubbles burst during the closing process will generate thousands of air pressure impact pressures around it, acting on the surface of the packing to destroy the dirt. The viscosity between the materials, and make them quickly dispersed in the backwash solution, so as to achieve the effect of cleaning the surface of the filler. ⑷After the air is exhausted, the effluent from the effluent tank continues to be introduced, and the effluent rich in hydroxyl radicals washes the surface and micropores of the filler particles in the turbulent state, strips off the pollutants, and the filler is regenerated. (5) The pollutants float upwards to the water surface continuously under the impact force of the water flow and the air flotation of the right aeration tube, and flow out from the left inlet weir and the right return trough to mix with the initial inlet water. After three-stage backwashing, the internal pollutants are cleaned and emptied.
常规砂滤通常采用压实填料、增加水压、砂上附加网格等手段改进砂滤过程,通常不扰动砂层,使水流从砂子细小缝隙之间流过,而污染物质停留在砂层的表层上,本发明则是利用搅拌机的旋转扰动填料表层,防止污染物质堆积对水流的顺利通过形成阻力。同时利用纳米曝气水流、气泡的冲击力和剪切力对填料进行反冲洗。Conventional sand filtration usually improves the sand filtration process by means of compacting packing, increasing water pressure, and attaching grids on the sand. Usually, the sand layer is not disturbed, and the water flows through the small gaps in the sand, while the pollutants stay on the surface of the sand layer. On the other hand, the present invention utilizes the rotation of the mixer to disturb the surface layer of the filler to prevent the accumulation of pollutants from forming resistance to the smooth passage of water flow. At the same time, the filler is backwashed by using the nano-aeration water flow, the impact force and the shear force of the air bubbles.
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