CN117950210A - Anti-infrared and anti-ultraviolet optical lens and preparation method thereof - Google Patents
Anti-infrared and anti-ultraviolet optical lens and preparation method thereof Download PDFInfo
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- CN117950210A CN117950210A CN202311869768.8A CN202311869768A CN117950210A CN 117950210 A CN117950210 A CN 117950210A CN 202311869768 A CN202311869768 A CN 202311869768A CN 117950210 A CN117950210 A CN 117950210A
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- 230000003287 optical effect Effects 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title abstract description 7
- 239000010410 layer Substances 0.000 claims abstract description 219
- 238000010521 absorption reaction Methods 0.000 claims abstract description 97
- 239000000758 substrate Substances 0.000 claims abstract description 39
- 239000011241 protective layer Substances 0.000 claims description 16
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- 238000001704 evaporation Methods 0.000 claims description 6
- 239000007888 film coating Substances 0.000 claims description 6
- 238000009501 film coating Methods 0.000 claims description 6
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 5
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical group [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 235000012239 silicon dioxide Nutrition 0.000 claims description 5
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- 238000003756 stirring Methods 0.000 claims description 5
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- 238000009504 vacuum film coating Methods 0.000 claims description 5
- IRAGEBXSFXWYNX-UHFFFAOYSA-N 2-(1,3,5-triazinan-1-yl)ethanol Chemical compound OCCN1CNCNC1 IRAGEBXSFXWYNX-UHFFFAOYSA-N 0.000 claims description 4
- NJCDRURWJZAMBM-UHFFFAOYSA-N 6-phenyl-1h-1,3,5-triazin-2-one Chemical compound OC1=NC=NC(C=2C=CC=CC=2)=N1 NJCDRURWJZAMBM-UHFFFAOYSA-N 0.000 claims description 4
- AZCUJQOIQYJWQJ-UHFFFAOYSA-N oxygen(2-) titanium(4+) trihydrate Chemical compound [O-2].[O-2].[Ti+4].O.O.O AZCUJQOIQYJWQJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000002952 polymeric resin Substances 0.000 claims description 4
- 229920003002 synthetic resin Polymers 0.000 claims description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
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- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000006378 damage Effects 0.000 abstract description 6
- 238000002834 transmittance Methods 0.000 abstract description 6
- 239000011247 coating layer Substances 0.000 abstract description 2
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Abstract
The invention provides an infrared and ultraviolet resistant optical lens, comprising: a substrate; an anti-reflection layer arranged on the surface of the substrate; the infrared absorption layer is arranged on the surface of the anti-reflection layer and comprises a first infrared absorption layer and a second infrared absorption layer which are adjacently arranged, and a closed flat cavity is formed between the first infrared absorption layer and the second infrared absorption layer in a surrounding mode; an ultraviolet absorbing layer disposed inside the cavity; and a hardening layer provided on the surface of the infrared absorbing layer. The invention also provides a preparation method of the infrared and ultraviolet resistant optical lens. In the invention, the ultraviolet absorbing layer is restrained and limited by the cavity formed by the infrared absorbing layer, and the damage conditions such as deformation, displacement and the like caused by softening can be avoided. The ultraviolet absorption capacity is improved. The number of coating layers is reduced, and the problem that the light transmittance is affected is correspondingly improved.
Description
Technical Field
The invention relates to the technical field of optical lenses, in particular to an infrared and ultraviolet resistant optical lens and a preparation method thereof.
Background
As the eyeglass market has expanded, its lenses have also gained increased consumer attention. Thus, with the diversification of consumer demand, various aspects of lens performance and technology are continually improving and perfecting. At present, on the basis of hardened lenses, the coated lenses in the market are mainly coated with an antireflection film layer, a top waterproof layer and the like by a vacuum coating method. So as to achieve the effects of enhancing the transmittance and protecting the lens. Various lenses in life are used as daily carrying articles, so that the functions of vision correction, protection, fashion and the like are provided.
However, the common lens has simple raw materials and relatively simple structure, has no great effect on the absorption and reflection of infrared rays and ultraviolet rays, and can damage eyes after being worn for a long time. Recent studies have shown that infrared and ultraviolet rays cause damage to the eyes of a person, such as the eyes of a person may cause damage to the retina of the fundus, and the eyes of a person may cause cataracts if exposed to infrared rays for a long period of time; the ultraviolet rays can cause cataract, keratitis, retina damage, cataract, macular degeneration, snowblindness and other serious eye diseases. It is therefore desirable to have glasses that protect and correct vision while also avoiding eye injury. Thus, lenses having various functions of preventing infrared rays, ultraviolet rays and blue light are appeared in the market.
With the development of technology, most of the glasses have more or less infrared or ultraviolet blocking functions, and generally, films for blocking ultraviolet and infrared are formed on the lens body respectively to form the lens. Meanwhile, in order to improve the protection effect, a mode of overlapping multiple films is generally adopted, for example, an infrared ray-proof, blue light-proof and ultraviolet-proof lens and a preparation method thereof, which are mentioned in Chinese patent No. CN109655943A, are overlapped by more than 6 films. But this way, while blocking infrared rays and infrared rays, the transmittance of visible light is reduced, which is unfavorable for vision correction and vision protection. Meanwhile, the current uv protection layer generally adopts organic matters with uv absorption (UVA) effect, and the organic matters have low melting point and cannot be directly used as a film layer, so that the organic matters need to be prepared into polymers to raise the melting point, so that the organic matters are not damaged due to environmental temperature rise in daily use. However, the ultraviolet absorption capacity of the polymer is reduced after the polymer is prepared, and the prepared polymer usually has a certain color and further influences the light transmittance. There is therefore a need for a better optical lens that is resistant to infrared and ultraviolet light.
Disclosure of Invention
Aiming at the defects existing in the prior art, the invention provides an infrared and ultraviolet resistant optical lens and a preparation method thereof. The ultraviolet light-absorbing film solves the problems that the light transmittance is affected due to excessive coating layers in the prior art, and meanwhile, the organic film layer serving as the ultraviolet protective layer is required to be prepared into a polymer due to lower melting point, so that the absorbing capacity of the organic film layer is reduced.
According to an embodiment of the present invention, an optical lens resistant to infrared and ultraviolet rays includes:
A substrate;
The anti-reflection layer is arranged on the surface of the substrate;
the infrared absorption layer is arranged on the surface of the anti-reflection layer and comprises a first infrared absorption layer and a second infrared absorption layer which are adjacently arranged, and a closed flat cavity is formed between the first infrared absorption layer and the second infrared absorption layer in a surrounding mode;
an ultraviolet absorbing layer disposed inside the cavity;
And a hardening layer provided on the surface of the infrared absorbing layer.
Further, the substrate is a glass lens or a polymer resin material lens.
Further, the material of the anti-reflection layer is titanium dioxide, and the thickness of the anti-reflection layer is 40-60nm.
Further, the first infrared absorption layer and the second infrared absorption layer are of symmetrical structures, and concave parts are respectively arranged on opposite surfaces of the first infrared absorption layer and the second infrared absorption layer, so that a closed cavity is formed when the first infrared absorption layer and the second infrared absorption layer are surrounded by the edge connecting part.
Further, the thickness of the first infrared absorption layer and the second infrared absorption layer corresponding to the concave part is 400-650nm, and the thickness of the first infrared absorption layer and the second infrared absorption layer corresponding to the edge connecting part is 750-950nm.
Further, the materials of the first infrared absorption layer and the second infrared absorption layer comprise one of titanium pentoxide and aluminum oxide.
Further, the ultraviolet absorbing layer comprises triazine UVA:70-75 parts of film forming agent: 25-30 parts of a lubricant; the triazine UVA comprises one or two of hydroxyphenyl s-triazine and hydroxyethyl hexahydro s-triazine, and the film forming agent comprises fluorocarbon resin emulsion.
Further, the thickness of the ultraviolet absorbing layer is 140-220nm.
Further, the hardening layer comprises a hard layer and a protective layer, wherein the hard layer is zirconium dioxide, the thickness of the hard layer is 50-65nm, the protective layer is silicon dioxide, and the thickness of the protective layer is 40-80nm.
The invention also provides a preparation method of the infrared and ultraviolet resistant optical lens, which comprises the following steps:
S1, adding triazine UVA and a film forming agent into a mixing tank according to a proportion, stirring for 20-30min at 60-85 ℃, and then preparing the materials as an ultraviolet absorbing layer;
s2, cleaning the substrate, placing the substrate on a film coating bracket, and conveying the substrate into a vacuum film coating chamber;
S3, in the environment of 102-115 ℃ and the vacuum degree of-4 to-2 pa, sequentially evaporating an anti-reflection layer and a first infrared absorption layer on the surface of the substrate, cooling to 55-60 ℃, evaporating an ultraviolet absorption layer, then rapidly heating to 102-115 ℃, and evaporating a second infrared absorption layer and a hardening layer.
Compared with the prior art, the invention has the following beneficial effects:
In the invention, the coating film on the surface of the substrate comprises the anti-reflection layer, the infrared absorption layer, the ultraviolet absorption layer and the hardening layer which are sequentially arranged, meanwhile, the infrared absorption layer comprises the first infrared absorption layer and the second infrared absorption layer which are symmetrically arranged, a cavity formed by concave is arranged between the first infrared absorption layer and the second infrared absorption layer, and the ultraviolet absorption layer is wrapped in the cavity, so that the ultraviolet absorption layer is restrained and limited by the cavity formed by the infrared absorption layer, and the damage conditions such as deformation, displacement and the like caused by softening can be avoided. In the prior art, if a non-polymeric organic matter with a lower melting point is used for preparing the ultraviolet absorption layer, when the temperature is higher, the ultraviolet absorption layer is softened, so that the whole film coating mechanism is displaced and damaged. On the basis, the invention can use high-purity ultraviolet absorbing organic matters without increasing the melting point by polymerization, thereby greatly improving the ultraviolet absorbing capacity. In addition, on the basis of using high-concentration ultraviolet absorbing organic matters, a plurality of layers of coating films are not needed to improve the absorption effect, the number of coating film layers is reduced, and the problem that the light transmittance is affected is correspondingly improved.
Drawings
Fig. 1 is a schematic structural diagram of an embodiment of the present invention.
In the above figures: 1. a substrate; 2. an anti-reflection layer; 3. an infrared absorbing layer; 4. an ultraviolet absorbing layer; 5. a hardening layer; 31. a first red absorbing layer; 32. and a second infrared absorbing layer.
Detailed Description
The technical scheme of the invention is further described below with reference to the accompanying drawings and examples.
Example 1:
as shown in fig. 1, the embodiment of the present invention provides an optical lens resistant to infrared and ultraviolet, including:
A substrate 1; an anti-reflection layer 2 arranged on the surface of the substrate 1; the infrared absorption layer 3 is arranged on the surface of the anti-reflection layer 2, the infrared absorption layer 3 comprises a first infrared absorption layer 31 and a second infrared absorption layer 323 which are adjacently arranged, a closed flat cavity is formed between the first infrared absorption layer 3 and the second infrared absorption layer 323 in a surrounding mode, the first infrared absorption layer 3 and the second infrared absorption layer 323 are of symmetrical structures, and concave portions are respectively arranged on opposite faces of the first infrared absorption layer 3 and the second infrared absorption layer 323, so that the first infrared absorption layer and the second infrared absorption layer form a closed cavity when the first infrared absorption layer and the second infrared absorption layer are surrounded by an edge connecting portion; an ultraviolet absorbing layer 4 disposed inside the cavity; a hardening layer 5 provided on the surface of the infrared absorbing layer 3.
In this embodiment, the substrate 1 is a glass lens.
The material of the anti-reflection layer 2 is titanium dioxide, and the thickness of the anti-reflection layer 2 is 40nm.
The thickness of the first infrared absorbing layer 3 and the second infrared absorbing layer 323 is 400nm corresponding to the concave portion and 750nm corresponding to the edge connecting portion. The first infrared absorbing layer and the second infrared absorbing layer 323 are made of titanium pentoxide.
The ultraviolet absorbing layer 4 is made of triazine UVA:70 parts of film forming agent: 30 parts; the triazine UVA is hydroxyphenyl s-triazine, and the film forming agent is fluorocarbon resin emulsion. The thickness of the ultraviolet absorbing layer 4 was 140nm.
The hardening layer 5 comprises a hard layer and a protective layer, wherein the hard layer is zirconium dioxide, the thickness of the hard layer is 50nm, the protective layer is silicon dioxide, and the thickness of the protective layer is 40nm.
In this embodiment, the method for preparing the optical lens includes the following steps:
S1, adding triazine UVA and a film forming agent into a mixing tank according to a proportion, stirring for 30min at 60 ℃, and then preparing the materials as an ultraviolet absorbing layer 4;
S2, cleaning the substrate 1, placing the substrate on a film coating bracket, and conveying the substrate into a vacuum film coating chamber;
S3, in the environment of 102 ℃ and the vacuum degree of-4 pa, the anti-reflection layer 2 and the first infrared absorption layer 3 are sequentially evaporated on the surface of the substrate 1, then the temperature is reduced to 55 ℃, the ultraviolet absorption layer 4 is evaporated, then the temperature is quickly increased to 102 ℃, and the second infrared absorption layer 323 and the hardening layer 5 are evaporated.
Example 2:
as shown in fig. 1, the embodiment of the present invention provides an optical lens resistant to infrared and ultraviolet, including:
a substrate 1; an anti-reflection layer 2 arranged on the surface of the substrate 1; the infrared absorption layer 3 is arranged on the surface of the anti-reflection layer 2, the infrared absorption layer 3 comprises a first infrared absorption layer 31 and a second infrared absorption layer 323 which are adjacently arranged, and a closed flat cavity is formed between the first infrared absorption layer 3 and the second infrared absorption layer 323 in a surrounding mode; the first infrared absorbing layer 3 and the second infrared absorbing layer 323 are symmetrical structures, and concave parts are respectively arranged on opposite surfaces of the first infrared absorbing layer 3 and the second infrared absorbing layer, so that a closed cavity is formed when the first infrared absorbing layer and the second infrared absorbing layer are surrounded by the edge connecting part. An ultraviolet absorbing layer 4 disposed inside the cavity; a hardening layer 5 provided on the surface of the infrared absorbing layer 3.
In this embodiment, the substrate 1 is a polymer resin lens.
The material of the anti-reflection layer 2 is titanium dioxide, and the thickness of the anti-reflection layer 2 is 50nm.
The thickness of the first infrared absorbing layer 3 and the second infrared absorbing layer 323 is 500nm corresponding to the concave portion and 850nm corresponding to the edge connecting portion. The first infrared absorbing layer and the second infrared absorbing layer 323 are made of aluminum oxide.
The ultraviolet absorbing layer 4 is made of triazine UVA:73 parts of film forming agent: 27 parts; the triazine UVA is hydroxyethyl hexahydro s-triazine, and the film forming agent comprises fluorocarbon resin emulsion. The thickness of the ultraviolet absorbing layer 4 is 180nm.
The hardening layer 5 comprises a hard layer and a protective layer, wherein the hard layer is zirconium dioxide, the thickness of the hard layer is 60nm, the protective layer is silicon dioxide, and the thickness of the protective layer is 60nm.
In this embodiment, the method for preparing the optical lens includes the following steps:
S1, adding triazine UVA and a film forming agent into a mixing tank according to a proportion, stirring for 25min at 70 ℃, and then preparing the materials as an ultraviolet absorbing layer 4;
S2, cleaning the substrate 1, placing the substrate on a film coating bracket, and conveying the substrate into a vacuum film coating chamber;
S3, in the environment of 108 ℃ and vacuum degree of-3 pa, the anti-reflection layer 2 and the first infrared absorption layer 3 are sequentially evaporated on the surface of the substrate 1, then the temperature is reduced to 58 ℃, the ultraviolet absorption layer 4 is evaporated, then the temperature is quickly increased to 108 ℃, and the second infrared absorption layer 323 and the hardening layer 5 are evaporated.
Example 3:
as shown in fig. 1, the embodiment of the present invention provides an optical lens resistant to infrared and ultraviolet, including:
a substrate 1; an anti-reflection layer 2 arranged on the surface of the substrate 1; the infrared absorption layer 3 is arranged on the surface of the anti-reflection layer 2, the infrared absorption layer 3 comprises a first infrared absorption layer 31 and a second infrared absorption layer 323 which are adjacently arranged, and a closed flat cavity is formed between the first infrared absorption layer 3 and the second infrared absorption layer 323 in a surrounding mode; the first infrared absorbing layer 3 and the second infrared absorbing layer 323 are symmetrical structures, and concave parts are respectively arranged on opposite surfaces of the first infrared absorbing layer 3 and the second infrared absorbing layer, so that a closed cavity is formed when the first infrared absorbing layer and the second infrared absorbing layer are surrounded by the edge connecting part. An ultraviolet absorbing layer 4 disposed inside the cavity; a hardening layer 5 provided on the surface of the infrared absorbing layer 3.
In this embodiment, the substrate 1 is a polymer resin lens.
The material of the anti-reflection layer 2 is titanium dioxide, and the thickness of the anti-reflection layer 2 is 60nm.
The thickness of the first infrared absorbing layer 3 and the second infrared absorbing layer 323 is 650nm corresponding to the concave portion and 950nm corresponding to the edge connecting portion. The first infrared absorbing layer and the second infrared absorbing layer 323 are made of titanium pentoxide.
The ultraviolet absorbing layer 4 is made of triazine UVA:75 parts of film forming agent: 25 parts; the triazine UVA is an equal proportion mixture of hydroxyphenyl s-triazine and hydroxyethyl hexahydro s-triazine, and the film forming agent comprises fluorocarbon resin emulsion. The thickness of the ultraviolet absorbing layer 4 was 220nm.
The hardening layer 5 comprises a hard layer and a protective layer, wherein the hard layer is zirconium dioxide, the thickness of the hard layer is 65nm, the protective layer is silicon dioxide, and the thickness of the protective layer is 80nm.
In this embodiment, the method for preparing the optical lens includes the following steps:
s1, adding triazine UVA and a film forming agent into a mixing tank according to a proportion, stirring for 20min at 85 ℃, and then preparing the materials as an ultraviolet absorbing layer 4;
S2, cleaning the substrate 1, placing the substrate on a film coating bracket, and conveying the substrate into a vacuum film coating chamber;
S3, in the environment of 115 ℃ and the vacuum degree of-2 pa, the anti-reflection layer 2 and the first infrared absorption layer 3 are sequentially evaporated on the surface of the substrate 1, then the temperature is reduced to 60 ℃, the ultraviolet absorption layer 4 is evaporated, then the temperature is quickly increased to 115 ℃, and the second infrared absorption layer 323 and the hardening layer 5 are evaporated.
Finally, it is noted that the above embodiments are only for illustrating the technical solution of the present invention and not for limiting the same, and although the present invention has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications and equivalents may be made thereto without departing from the spirit and scope of the technical solution of the present invention, which is intended to be covered by the scope of the claims of the present invention.
Claims (10)
1. An infrared and ultraviolet resistant optical lens, comprising:
A substrate;
The anti-reflection layer is arranged on the surface of the substrate;
the infrared absorption layer is arranged on the surface of the anti-reflection layer and comprises a first infrared absorption layer and a second infrared absorption layer which are adjacently arranged, and a closed flat cavity is formed between the first infrared absorption layer and the second infrared absorption layer in a surrounding mode;
an ultraviolet absorbing layer disposed inside the cavity;
And a hardening layer provided on the surface of the infrared absorbing layer.
2. An infrared and ultraviolet resistant optical lens as set forth in claim 1, wherein: the substrate is a glass lens or a polymer resin material lens.
3. An infrared and ultraviolet resistant optical lens as set forth in claim 1, wherein: the anti-reflection layer is made of titanium dioxide, and the thickness of the anti-reflection layer is 40-60nm.
4. An infrared and ultraviolet resistant optical lens as set forth in claim 1, wherein: the first infrared absorption layer and the second infrared absorption layer are of symmetrical structures, and concave parts are respectively arranged on opposite surfaces of the first infrared absorption layer and the second infrared absorption layer, so that a closed cavity is formed when the first infrared absorption layer and the second infrared absorption layer are surrounded by the edge connecting part.
5. An infrared and ultraviolet resistant optical lens as recited in claim 4, wherein: the thickness of the first infrared absorption layer and the second infrared absorption layer corresponding to the concave part is 400-650nm, and the thickness of the first infrared absorption layer and the second infrared absorption layer corresponding to the edge connecting part is 750-950nm.
6. An infrared and ultraviolet resistant optical lens as set forth in claim 1, wherein: the materials of the first infrared absorption layer and the second infrared absorption layer comprise one of titanium pentoxide and aluminum oxide.
7. An infrared and ultraviolet resistant optical lens as set forth in claim 1, wherein: the ultraviolet absorbing layer is made of triazine UVA:70-75 parts of film forming agent: 25-30 parts of a lubricant; the triazine UVA comprises one or two of hydroxyphenyl s-triazine and hydroxyethyl hexahydro s-triazine, and the film forming agent comprises fluorocarbon resin emulsion.
8. An infrared and ultraviolet resistant optical lens as set forth in claim 1, wherein: the thickness of the ultraviolet absorbing layer is 140-220nm.
9. An infrared and ultraviolet resistant optical lens as set forth in claim 1, wherein: the hardening layer comprises a hard layer and a protective layer, wherein the hard layer is zirconium dioxide, the thickness of the hard layer is 50-65nm, the protective layer is silicon dioxide, and the thickness of the protective layer is 40-80nm.
10. A method for producing an infrared and ultraviolet resistant optical lens as claimed in any one of claims 1 to 9, comprising the steps of:
S1, adding triazine UVA and a film forming agent into a mixing tank according to a proportion, stirring for 20-30min at 60-85 ℃, and then preparing the materials as an ultraviolet absorbing layer;
s2, cleaning the substrate, placing the substrate on a film coating bracket, and conveying the substrate into a vacuum film coating chamber;
S3, in the environment of 102-115 ℃ and the vacuum degree of-4 to-2 pa, sequentially evaporating an anti-reflection layer and a first infrared absorption layer on the surface of the substrate, cooling to 55-60 ℃, evaporating an ultraviolet absorption layer, then rapidly heating to 102-115 ℃, and evaporating a second infrared absorption layer and a hardening layer.
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CN202311869768.8A CN117950210A (en) | 2023-12-29 | 2023-12-29 | Anti-infrared and anti-ultraviolet optical lens and preparation method thereof |
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CN202311869768.8A CN117950210A (en) | 2023-12-29 | 2023-12-29 | Anti-infrared and anti-ultraviolet optical lens and preparation method thereof |
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CN117950210A true CN117950210A (en) | 2024-04-30 |
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CN202311869768.8A Pending CN117950210A (en) | 2023-12-29 | 2023-12-29 | Anti-infrared and anti-ultraviolet optical lens and preparation method thereof |
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