CN212846202U - Antifog photochromic resin lens - Google Patents

Antifog photochromic resin lens Download PDF

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CN212846202U
CN212846202U CN202021921798.0U CN202021921798U CN212846202U CN 212846202 U CN212846202 U CN 212846202U CN 202021921798 U CN202021921798 U CN 202021921798U CN 212846202 U CN212846202 U CN 212846202U
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layer
lens
photochromic
antifog
resin lens
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唐忆君
贺建友
周思成
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Shanghai Conant Optics Co Ltd
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Shanghai Conant Optics Co Ltd
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Abstract

The utility model provides an antifog photochromic resin lens, antifog photochromic resin lens is by outer to interior antireflection coating film layer, stereoplasm strengthening layer, transition layer, discoloration layer, resin substrate and the antifog coating that sets gradually. The utility model provides a lens can realize antifog and two functions of photochromism and each other do not influence simultaneously, keeps the original good effect of each function. Particularly, in the case of wearing a mask, the inner surface of the lens is a main fogging region, and the fogging coating is provided on the inner surface of the lens, whereby fogging of the lens can be prevented more directly and effectively.

Description

Antifog photochromic resin lens
Technical Field
The utility model belongs to the technical field of the lens, relate to the resin lens, especially, relate to an antifog photochromic resin lens.
Background
Compared with inorganic glass lenses, resin lenses are gaining more and more favor of consumers by virtue of the advantages of light weight, good toughness, low price and the like. However, people often suffer from the problem that the lenses are easy to fog in the process of wearing the glasses, and particularly, fog drops are easy to appear on the inner surfaces of the lenses when the glasses are worn on a mask or used for swimming, so that the sight of a wearer of the glasses is greatly influenced. In addition, the eyes of people are easy to generate visual fatigue in a strong light environment, and the photochromic lens can meet the requirement of people on reducing the optical strength outdoors.
At present, single-function lenses capable of achieving fog prevention or color change exist in the market, but products capable of achieving the two functions well do not exist, and especially under the condition that a mask is worn outdoors, the two functions of fog prevention and color change are needed.
CN106405691A discloses an antifogging optical resin lens and a preparation method thereof, wherein an anti-reflection antireflection film layer and a macromolecular hydrophilic film are bonded together through optically transparent glue, so that the transmittance of light is increased and the reflectance of light is reduced on the basis of not influencing the original function of the resin lens, the resin lens has new antifogging performance, and the refractive index of the resin lens is not influenced. Therefore, the resin lens has stronger functionality and better market prospect. However, the gluing method has the problems of weak adhesion and limited service life; in addition, the product of the optical resin lens for preventing is single in function, only has an anti-fog effect but has no photochromic function.
CN106772707A discloses a preparation method of a blue-light-proof antifogging coated resin lens, wherein silicon oxide, zirconium oxide and indium tin oxide are respectively deposited by vacuum coating, so as to achieve the effects of anti-reflection, anti-reflection and blue-light prevention, and the blue-light absorption rate (380 nm and 500nm) of the lens prepared by the preparation method reaches 25 percent; before the anti-fog film layer is plated on the anti-blue light film, the silicon oxide is subjected to surface treatment by using plasma to activate the hydrophilicity of the anti-fog film layer, and then the anti-fog film layer is dip-coated with the organic silicon modified hydrophilic resin anti-fog coating, so that the adhesive force of the anti-fog film layer is increased, and the anti-fog film layer can be cured at normal temperature. The resin lens prepared by the preparation method not only has the blue light prevention performance, but also has the antifogging performance, and has the advantages of more comprehensive functions, strong practicability and large market potential. However, such lenses do not have photochromic functionality and need to be further improved.
CN109116582A discloses a photochromic resin spectacle lens and a manufacturing method thereof, firstly, the manufacturing method utilizes the migration property of a color-changing substance by arranging a front protective layer, so that more color-changing powder has the tendency of inward migration, and the activity of the color-changing substance can be ensured because the front protective layer is softer; in the manufacturing method, the post-positioned protective layer is provided to prevent the damage of the discoloring substance caused by the intrusion of the hard reinforcing layer. Thus, the original dimming performance of the photochromic layer is better protected through different action effects of the two aspects, so that the faster photochromic effect and the longer service life are realized. However, this method can only perform one function of photochromism. And the lens surface is softened by the symmetrical multi-layer design of the front and back surfaces and is difficult to combine with a thicker antifogging functional hard coating.
CN204855971U discloses a photochromic prevents blue light resin lens, it has fused the function of discolouing and has prevented the blue light function, photochromic prevents blue light resin lens except having the original function of correcting the eyesight of lens, can filter the harmful blue light that emits out in cell-phone screen, panel computer screen and the notebook computer screen for people again. Moreover, the photochromic blue-light-proof resin lens can realize quick color change under outdoor conditions by arranging the photochromic layer, block strong sunlight for people and prevent dizziness and transient blindness caused by strong light irradiation; meanwhile, the multifunctional outdoor mirror can be used as a necessary ornament for outdoor travel of people as a sunglass. However, the lens also has no antifogging function and needs to be further improved.
Therefore, how to combine the antifogging function and the photochromic function of the lens and ensure that the two functions are not influenced mutually, the original good effect of each function is maintained, and the problem which needs to be solved at present is provided.
SUMMERY OF THE UTILITY MODEL
Aiming at the defects in the prior art, the utility model aims to provide an antifogging photochromic resin lens which can realize two functions of antifogging and photochromic and keep the original good effect of each function; the problem of fogging of the inner mask under the condition of wearing the mask can be particularly solved.
To achieve the purpose, the utility model adopts the following technical proposal:
the utility model provides an antifog photochromic resin lens, antifog photochromic resin lens is by outer to interior antireflection coating film layer, stereoplasm strengthening layer, transition layer, discoloration layer, resin substrate and the antifog coating that sets gradually.
The outside is for being close to the object one side of looking, the inboard is for being close to eyes one side.
The utility model is composed of an anti-reflection coating layer, a hard strengthening layer, a transition layer, a color changing layer, a resin substrate and an anti-fog coating which are arranged in sequence; the antireflection coating layer can reduce the loss of the light transmittance of the lens while providing a waterproof and oil-proof effect; the hard strengthening layer has higher hardness and is matched with the antireflection coating layer to protect the lens from being scratched; the transition layer can prevent the color-changing substances in the color-changing layer from migrating to the hard reinforcing layer and can also enhance the combination effect of the hard reinforcing layer and the color-changing layer; the anti-fog photochromic resin lens achieves the photochromic function due to the arrangement of the photochromic layer, and the photochromic layer is arranged on the outer side of the resin substrate, so that the photochromic layer can be more easily excited by illumination; the antifogging coating is arranged on the inner side of the resin base material and can directly and effectively prevent the lens from fogging.
The utility model discloses a specific structure setting of antifog photochromic resin lens makes each functional layer mutually support, makes antifog photochromic resin lens can realize antifog and two functions of photochromism simultaneously to keep the original good effect of each function.
Preferably, the ratio of the thickness of the color change layer to the anti-fog coating is (1-2):1, and may be, for example, 1:1, 1.1:1, 1.2:1, 1.3:1, 1.4:1, 1.5:1, 1.6:1, 1.7:1, 1.8:1, 1.9:1, or 2:1, but is not limited to the recited values, and other values within this range are equally applicable.
Preferably, the color-changing layer has a thickness of 7 to 14 μm, and may be, for example, 7 μm, 8 μm, 9 μm, 10 μm, 11 μm, 12 μm, 13 μm or 14 μm, but is not limited to the values listed, and other values not listed in the range of the values are also applicable.
The color-changing layer adopted by the utility model is a photochromic layer.
The photochromic layer is a photochromic layer composed of materials conventional in the art, namely the photochromic layer is a photochromic layer conventional in the art. Illustratively, the material of the photochromic layer is a film-forming resin containing an organic photochromic material, the film-forming resin can be any one of polyacrylate, polyurethane, polyethylene and polysiloxane, and the organic photochromic material can be any one of phenoxazine, fulgide, spiropyran and azo. The skilled person will be able to select the material of the photochromic layer as desired, as long as the photochromic function is achieved.
The photochromic layer can effectively realize the photochromic of the lens under the strong light environment through the photochromic material, thereby avoiding the injury of human eyes.
Preferably, the antifogging coating has a thickness of 4 to 8 μm, and may be, for example, 4 μm, 4.5 μm, 5 μm, 5.5 μm, 6 μm, 6.5 μm, 7 μm, 7.5 μm or 8 μm, but is not limited to the recited values, and other values not recited within this range of values are equally applicable.
Illustratively, the material of the antifogging coating can be any one of polyacrylate, cellulose ester, amino resin, polyurethane and silicone resin.
The utility model controls the thickness of the color changing layer and the antifogging coating, on one hand, ensures that the content of variable color powder in the color changing layer is moderate, and keeps good color changing effect; on the other hand, the content of the hydrophilic auxiliary agent in the thicker antifogging coating is higher, and the longer-lasting antifogging effect is achieved through the process that the hydrophilic auxiliary agent slowly migrates and is released to the surface.
Preferably, the thickness of the anti-reflective coating layer is 200-400nm, such as 200nm, 220nm, 240nm, 260nm, 280nm, 300nm, 320nm, 340nm, 360nm, 380nm or 400nm, but not limited to the values listed, and other values not listed in the range of the values are also applicable.
The antireflection coating layer can reduce reflected light of the lens, increase light transmittance of the lens and improve field brightness in a weak light environment.
For example, the material of the anti-reflective coating layer may be any one of silicon dioxide, zirconium dioxide and indium oxide.
Preferably, the thickness of the hard reinforcing layer is 2 to 4 μm, and may be, for example, 2 μm, 2.2 μm, 2.4 μm, 2.6 μm, 2.8 μm, 3 μm, 3.2 μm, 3.4 μm, 3.6 μm, 3.8 μm or 4 μm, but is not limited to the values recited, and other values not recited within the range of values are also applicable.
The hard strengthening layer can improve the hardness of the lens and enhance the anti-falling performance of the lens.
Illustratively, the material of the hard reinforcing layer can be any one of polysiloxane, polyacrylate and polyurethane.
Preferably, the thickness of the transition layer is 1 to 3 μm, and may be, for example, 1 μm, 1.2 μm, 1.4 μm, 1.6 μm, 1.8 μm, 2 μm, 2.2 μm, 2.4 μm, 2.6 μm, 2.8 μm or 3 μm, but is not limited to the values recited, and other values not recited within the range of values are equally applicable.
The adhesion force is poor when the color-changing layer is directly combined with the hard strengthening layer, and the combination effect of the hard strengthening layer and the color-changing layer can be obviously improved by arranging the transition layer; and the color-changing substances in the color-changing layer can be prevented from migrating to the hard strengthening layer, so that the color-changing effect of the lens is ensured.
Illustratively, the material of the transition layer of the present invention may be any one of polyurethane, polyethylene or polysiloxane.
Preferably, the thickness of the resin substrate is 1 to 10mm, and may be, for example, 1mm, 2mm, 3mm, 4mm, 5mm, 6mm, 7mm, 8mm, 9mm or 10mm, but is not limited to the values listed, and other values not listed in the range of the values are also applicable.
The resin base material can effectively reduce the weight of the lens and improve the wearing comfort.
Illustratively, the resin substrate may be any of commercially available CR-39, MR-8, MR-10, or MR-174 (where CR is an acrylate; MR is a polyurethane).
Compared with the prior art, the beneficial effects of the utility model are that:
the utility model provides an antifog photochromic resin lens can realize antifog and two functions of photochromism and each other do not influence simultaneously, keeps the original good effect of each function, and initial antifog performance and lasting antifog performance all show excellently, and the luminousness generally maintains about 20% after discolouring. Particularly, in the case of wearing a mask, the inner surface of the lens is a main fogging region, and the fogging coating is provided on the inner surface of the lens, whereby fogging of the lens can be prevented more directly and effectively.
Drawings
Fig. 1 is a schematic structural view of an antifogging photochromic resin lens provided by the utility model.
Wherein: 1-antireflection coating layer; 2-a hard strengthening layer; 3-a transition layer; 4-a color-changing layer; 5-a resin substrate; 6-antifogging coating.
Detailed Description
It is to be understood that in the description of the present invention, the terms "central," "longitudinal," "lateral," "upper," "lower," "front," "rear," "left," "right," "vertical," "horizontal," "top," "bottom," "inner," "outer," and the like are used in the orientation or positional relationship indicated in the drawings for the purpose of convenience and simplicity of description, and are not intended to indicate or imply that the referenced device or element must have a particular orientation, be constructed and operated in a particular orientation, and are not to be construed as limiting the present invention.
It should be noted that, unless explicitly stated or limited otherwise, the terms "disposed," "connected" and "connected" in the description of the present invention are to be construed broadly, and may for example be fixedly connected, detachably connected or integrally connected; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meaning of the above terms in the present invention can be understood by those of ordinary skill in the art through specific situations.
The technical solution of the present invention is further explained by the following embodiments with reference to the accompanying drawings.
Example 1
The embodiment provides an antifog photochromic resin lens as shown in fig. 1, the antifog photochromic resin lens comprises an antireflection coating layer 1, a hard strengthening layer 2, a transition layer 3, a color changing layer 4, a resin substrate 5 and an antifog coating layer 6 which are arranged in sequence from outside to inside, and the thickness and the material of each layer are shown in table 1.
TABLE 1
Thickness of Material of
Antireflection coating 300nm Silicon dioxide and zirconium dioxide
Hard strengthening layer 3μm Polysiloxanes
Transition layer 2μm Polyurethane
Color changing layer 11μm Polyacrylate phenoxazine-containing compounds
Resin base material 5mm CR-39
Antifogging coating 6μm Polyacrylate
Example 2
This embodiment provides an antifog photochromic resin lens, antifog photochromic resin lens is by outer to interior antireflection coating layer, stereoplasm strengthening layer, transition layer, discoloration layer, resin substrate and the antifog coating that sets gradually, and each layer thickness and material see table 2.
TABLE 2
Thickness of Material of
Antireflection coating 350nm Silicon dioxideAnd zirconium dioxide
Hard strengthening layer 3.5μm Polyurethane
Transition layer 2.5μm Polyethylene
Color changing layer 13μm Polyethylene containing spiropyrans
Resin base material 8mm MR-8
Antifogging coating 7μm Amino resin
Example 3
This embodiment provides an antifog photochromic resin lens, antifog photochromic resin lens is by outer to interior antireflection coating layer, stereoplasm strengthening layer, transition layer, discoloration layer, resin substrate and the antifog coating that sets gradually, and each layer thickness and material see table 3.
TABLE 3
Thickness of Material of
Antireflection coating 250nm Silicon dioxide and zirconium dioxide
Hard strengthening layer 2.5μm Polyacrylate
Transition layer 1.5μm Polysiloxanes
Color changing layer 9μm Polyacrylate containing fulgide
Resin base material 3mm MR-10
Antifogging coating 5μm Silicone resin
Example 4
This embodiment provides an antifog photochromic resin lens, antifog photochromic resin lens is by outer to interior antireflection coating layer, stereoplasm strengthening layer, transition layer, discoloration layer, resin substrate and the antifog coating that sets gradually, and each layer thickness and material see table 4.
TABLE 4
Thickness of Material of
Antireflection coating 400nm Silicon dioxide and zirconium dioxide
Hard strengthening layer 4μm Polysiloxanes
Transition layer 3μm Polyethylene
Color changing layer 14μm Polyacrylate phenoxazine-containing compounds
Resin base material 10mm MR-174
Antifogging coating 8μm Cellulose esters
Example 5
This embodiment provides an antifog photochromic resin lens, antifog photochromic resin lens is by outer to interior antireflection coating layer, stereoplasm strengthening layer, transition layer, discoloration layer, resin substrate and the antifog coating that sets gradually, and each layer thickness and material see table 5.
TABLE 5
Thickness of Material of
Antireflection coating 200nm Silicon dioxide and zirconium dioxide
Hard strengthening layer 2μm Polyurethane
Transition layer 1μm Polyurethane
Color changing layer 7μm Polyurethane containing spiropyrans
Resin base material 1mm MR-10
Antifogging coating 4μm Amino resin
Comparative example 1
The comparative example provides a resin lens, which comprises an antireflection coating layer, a first hard strengthening layer, a transition layer, a color-changing layer, a resin substrate and a second hard strengthening layer which are arranged in sequence from outside to inside, wherein the thickness and the material of each layer are shown in table 6.
TABLE 6
Thickness of Material of
Antireflection coating 300nm Silicon dioxide and zirconium dioxide
A first hard strengthening layer 3μm Polysiloxanes
Transition layer 2μm Polyurethane
Color changing layer 11μm Polyacrylate phenoxazine-containing compounds
Resin base material 5mm CR-39
Second hard strengthening layer 3μm Polysiloxanes
Comparative example 2
The comparative example provides a resin lens, the resin lens comprises an anti-fog coating, a transition layer, a color changing layer, a resin substrate, a hard strengthening layer and an anti-reflection coating layer which are sequentially arranged from outside to inside, and the thickness and the material of each layer are shown in table 7.
TABLE 7
Figure BDA0002667221400000101
Figure BDA0002667221400000111
Evaluation of Performance
The anti-fog photochromic resin lenses provided in examples 1 to 5 and the resin lenses provided in comparative examples 1 to 2 were tested for photochromic properties and anti-fog properties.
The photochromic performance test instrument is a model UltraScan PRO from HunterLab.
Evaluation of photochromic properties, the value of light transmittance in the visible range was measured by irradiating with an ultraviolet lamp at room temperature for 2 minutes.
The antifogging properties are tested with reference to the test method in standard EN-166N.
1) Initial antifogging property test: placing the lens at room temperature 2cm above 80 ℃ warm water, and determining that the lens passes the test if no fogging phenomenon occurs within 1 minute;
2) testing the lasting antifogging property: the lens is soaked in water for 24 hours at room temperature, taken out and aired for 8 hours, then placed 3cm above warm water at 50 ℃, and no fogging phenomenon is considered to pass the test within 5 minutes.
The lens performance evaluation results of examples 1 to 5 and comparative examples 1 to 2 are shown in Table 8.
TABLE 8
Figure BDA0002667221400000112
Figure BDA0002667221400000121
From the above table, it can be seen that: the antifogging photochromic resin lenses provided by the embodiments 1 to 5 have good light transmittance after discoloration, and antifogging properties pass the test; the resin lens provided in comparative example 1 failed the antifogging property test because it did not have the antifogging coating; comparative example 2 provides a resin lens having an antifogging coating but disposed on the outside of the lens rather than the inside, so that the initial antifogging property test was passed but the permanent antifogging test was not passed.
Therefore, the utility model provides an antifog photochromic resin lens can realize antifog and two functions of photochromism and each other do not influence simultaneously, keeps the original good effect of each function, and initial antifog performance and lasting antifog performance all show excellently, and the luminousness generally maintains about 20% after discolouring. Particularly, in the case of wearing a mask, the inner surface of the lens is a main fogging region, and the fogging coating is provided on the inner surface of the lens, whereby fogging of the lens can be prevented more directly and effectively.
The applicant states that the above description is only a specific embodiment of the present invention, but the protection scope of the present invention is not limited thereto, and those skilled in the art should understand that any changes or substitutions easily conceivable by those skilled in the art within the technical scope of the present invention are within the protection scope and the disclosure scope of the present invention.

Claims (8)

1. The utility model provides an antifog photochromic resin lens which characterized in that, antifog photochromic resin lens is by outer to interior antireflection coating film layer, stereoplasm strengthening layer, transition layer, discoloration layer, resin substrate and the antifog coating that sets gradually.
2. The anti-fog photochromic resin lens of claim 1, wherein the ratio of the thickness of the color-changing layer to the anti-fog coating is (1-2): 1.
3. The anti-fog photochromic resin lens of claim 1 or 2, wherein the thickness of the color-changing layer is 7-14 μm.
4. The anti-fog photochromic resin lens of claim 3, wherein the anti-fog coating has a thickness of 4-8 μm.
5. The anti-fog photochromic resin lens of claim 1 wherein the anti-reflective coating layer has a thickness of 200-400 nm.
6. The anti-fog photochromic resin lens of claim 1 wherein the hard strengthening layer has a thickness of 2-4 μm.
7. The anti-fog photochromic resin lens of claim 1, wherein the thickness of the transition layer is 1-3 μm.
8. The anti-fog photochromic resin lens of claim 1, wherein the resin substrate has a thickness of 1-10 mm.
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