CN117944349A - Polyester composite board structure and manufacturing method thereof - Google Patents

Polyester composite board structure and manufacturing method thereof Download PDF

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Publication number
CN117944349A
CN117944349A CN202211406973.6A CN202211406973A CN117944349A CN 117944349 A CN117944349 A CN 117944349A CN 202211406973 A CN202211406973 A CN 202211406973A CN 117944349 A CN117944349 A CN 117944349A
Authority
CN
China
Prior art keywords
polyester
manufacturing
layer
composite board
panel structure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202211406973.6A
Other languages
Chinese (zh)
Inventor
廖德超
曹俊哲
郑文瑞
刘岳欣
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nan Ya Plastics Corp
Original Assignee
Nan Ya Plastics Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from TW111139347A external-priority patent/TW202417218A/en
Application filed by Nan Ya Plastics Corp filed Critical Nan Ya Plastics Corp
Publication of CN117944349A publication Critical patent/CN117944349A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/08Polyesters modified with higher fatty oils or their acids, or with resins or resin acids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16Dicarboxylic acids and dihydroxy compounds
    • C08G63/18Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181Acids containing aromatic rings
    • C08G63/183Terephthalic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/04Thermoplastic elastomer

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention provides a polyester composite board structure and a manufacturing method thereof.

Description

Polyester composite board structure and manufacturing method thereof
Technical Field
The invention relates to a composite board structure and a manufacturing method thereof, and relates to a polyester composite board structure and a manufacturing method thereof.
Background
Most of the existing plastic composite boards are manufactured by using heterogeneous lamination (PVC glue coating and lamination PBS) or heterogeneous extrusion (PMMA/ABS), and are non-recyclable and non-environment-friendly products. The existing preparation method is characterized in that glue needs to be coated or impregnated by heterogeneous lamination, and solvent volatilization and heating lamination exist in the preparation process, so that the method belongs to a product with energy consumption and carbon emission.
Based on the above, a method for manufacturing a composite board is developed, which meets the current requirements of environmental protection, energy conservation and carbon reduction, and is an important subject for the current research.
Disclosure of Invention
The invention provides a polyester composite board structure and a manufacturing method thereof, wherein the composite board structure is manufactured by using a single material, and no gluing and hot pressing process is adopted, so that the requirements on environmental protection, energy conservation and carbon reduction are met.
The manufacturing method of the polyester composite board structure comprises the steps of extruding a polyester layer into a board by using a multi-layer extrusion device, and thermally bonding a polyester film by using a wheel in the extrusion process.
In one embodiment of the present invention, the melting temperature of the multilayer extrusion device is 250 ℃ to 290 ℃.
In one embodiment of the present invention, the polyester layer comprises a recycled polyester resin layer (which may be PET or a generally thermoplastic polyester, such as PC, PBT, PBAT, etc., having a thickness of 0.3mm to 6.0mm and providing mainly support for the composite board), a functional polyester layer (which may be PET or a generally thermoplastic polyester, such as PC, PBT, PBAT, etc., having a thickness of 0.12mm to 4.0mm and providing mainly functional properties of the composite board, such as color, pattern, etc.), or a protective polyester layer (which may be PET or a generally thermoplastic polyester, such as PC, PBT, PBAT, etc., having a thickness of 0.06mm to 1.0mm and providing mainly protective functions of the composite board, such as scratch resistance, solvent resistance, etc.).
In one embodiment of the present invention, the lamination temperature of the heat-laminated polyester film using the wheel is 80 to 180 ℃.
The polyester composite board structure is manufactured by the manufacturing method.
In one embodiment of the invention, the thickness is 0.6mm to 10mm.
In one embodiment of the present invention, the polyester film comprises 1 to 5 polyester layers and 1 to 2 polyester films (which may be a transparent PET film, a PET film with printing process, or a thermoplastic polyester film, such as PC, PBT, PBAT film, and the thickness is from 12um to 250um, and the thickness mainly provides additional functions of the composite board, such as decorative patterns, antibacterial, mildew-proof, wear-resistant, scratch-resistant performances, etc.).
In one embodiment of the present invention, the polyester layer comprises a recycled polyester resin layer (which may be PET or a generally thermoplastic polyester, such as PC, PBT, PBAT, etc., having a thickness of 0.3mm to 6.0mm and providing mainly support for the composite board), a functional polyester layer (which may be PET or a generally thermoplastic polyester, such as PC, PBT, PBAT, etc., having a thickness of 0.12mm to 4.0mm and providing mainly functional properties of the composite board, such as color, pattern, etc.), or a protective polyester layer (which may be PET or a generally thermoplastic polyester, such as PC, PBT, PBAT, etc., having a thickness of 0.06mm to 1.0mm and providing mainly protective functions of the composite board, such as scratch resistance, solvent resistance, etc.)
Based on the above, the invention provides a polyester composite board structure and a manufacturing method thereof, wherein the composite board structure is made of a single material, and polyester film and the composite board are closely formed through the temperature of the wheel of the equipment on the premise of not coating glue or heating and pressing, so that the polyester composite board structure has the performances of decoration pattern, antibiosis, mildew resistance, wear resistance, scratch resistance and the like, and meets the current requirements on environmental protection, energy conservation and carbon reduction.
Detailed Description
Hereinafter, embodiments of the present invention will be described in detail. However, these embodiments are illustrative, and the present disclosure is not limited thereto.
In this document, a range from "one value to another value" is a shorthand way of referring individually to all the values in the range, which are avoided in the specification. Thus, recitation of a particular numerical range includes any numerical value within that range, as well as the smaller numerical range bounded by any numerical value within that range, as if the any numerical value and the smaller numerical range were written in the specification.
The invention provides a polyester composite board structure and a manufacturing method thereof.
In this embodiment, the melting temperature of the multi-layer extrusion apparatus is, for example, 250 ℃ to 290 ℃, and two or three multi-layer extrusion apparatuses can be used to manufacture the upper layer, the middle layer or the bottom layer, respectively. The polyester layer may include recycled polyester resin layer (which may be PET or general thermoplastic type polyester, such as PC, PBT, PBAT, etc. and has a thickness of 0.3mm to 6.0mm, and mainly provides support for the composite board), functional polyester layer (which may be PET or general thermoplastic type polyester, such as PC, PBT, PBAT, etc. and has a thickness of 0.12mm to 4.0mm, and mainly provides functional properties of the composite board, such as color, pattern, etc.), or protective polyester layer (which may be PET or general thermoplastic type polyester, such as PC, PBT, PBAT, etc. and has a thickness of 0.06mm to 1.0mm, and mainly provides protective functions of the composite board, such as scratch resistance, solvent resistance, etc.). The lamination temperature of the polyester film is 80 ℃ to 180 ℃ by using a wheel, and the wheel can comprise three rollers, for example, but the invention is not limited thereto. The polyester composite board structure manufactured by the manufacturing method of the invention has the thickness of 0.6mm to 10mm, for example, and can comprise 1 to 5 polyester layers and 1 to 2 polyester films.
In summary, the present invention provides a polyester composite board structure and a manufacturing method thereof, wherein a composite board structure is made of a single material, and the polyester film and the composite board are closely formed by the temperature of the wheel of the device and the thermoplastic property of polyester on the premise of not coating glue or heating and pressing, so that the polyester composite board structure has the performances of decoration pattern, antibiosis, mildew resistance, wear resistance, scratch resistance, etc., thereby meeting the requirements of environmental protection, energy conservation and carbon reduction. In addition, the recycled polyester resin layer can be used for extrusion into a plate, which accords with the trend of low-carbon green products.

Claims (8)

1. A method of manufacturing a polyester composite panel structure, comprising:
The polyester layer is extruded into a plate by using a multi-layer extrusion device, and the polyester film is thermally bonded by using a wheel in the extrusion process.
2. The method of manufacturing a polyester composite panel structure according to claim 1, wherein the melting temperature of the multilayer extrusion device is 250 ℃ to 290 ℃.
3. The method of manufacturing a polyester composite panel structure according to claim 1, wherein the polyester layer comprises a recycled polyester resin layer, a functional polyester layer, or a protective polyester layer.
4. The method of manufacturing a polyester composite panel structure according to claim 1, wherein the lamination temperature of the polyester film is 80 ℃ to 180 ℃ by using a wheel for thermal lamination.
5. A polyester composite panel structure, characterized in that it is manufactured using the manufacturing method of the polyester composite panel structure as claimed in any one of claims 1 to 4.
6. The polyester composite panel structure of claim 5, wherein the thickness is 0.6mm to 10mm.
7. The polyester composite panel structure of claim 5, comprising 1 to 5 polyester layers and 1 to 2 polyester films.
8. The polyester composite panel structure of claim 5, wherein the polyester layer comprises a recycled polyester resin layer, a functional polyester layer, or a protective polyester layer.
CN202211406973.6A 2022-10-18 2022-11-10 Polyester composite board structure and manufacturing method thereof Pending CN117944349A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TW111139347A TW202417218A (en) 2022-10-18 Polyester composite board structure and manufacturing method thereof
TW111139347 2022-10-18

Publications (1)

Publication Number Publication Date
CN117944349A true CN117944349A (en) 2024-04-30

Family

ID=90626982

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202211406973.6A Pending CN117944349A (en) 2022-10-18 2022-11-10 Polyester composite board structure and manufacturing method thereof

Country Status (3)

Country Link
US (1) US20240124707A1 (en)
JP (1) JP2024059538A (en)
CN (1) CN117944349A (en)

Also Published As

Publication number Publication date
US20240124707A1 (en) 2024-04-18
JP2024059538A (en) 2024-05-01

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