CN117944349A - Polyester composite board structure and manufacturing method thereof - Google Patents
Polyester composite board structure and manufacturing method thereof Download PDFInfo
- Publication number
- CN117944349A CN117944349A CN202211406973.6A CN202211406973A CN117944349A CN 117944349 A CN117944349 A CN 117944349A CN 202211406973 A CN202211406973 A CN 202211406973A CN 117944349 A CN117944349 A CN 117944349A
- Authority
- CN
- China
- Prior art keywords
- polyester
- manufacturing
- layer
- composite board
- panel structure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000728 polyester Polymers 0.000 title claims abstract description 52
- 239000002131 composite material Substances 0.000 title claims abstract description 40
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 19
- 229920006267 polyester film Polymers 0.000 claims description 12
- 238000001125 extrusion Methods 0.000 claims description 10
- 238000003475 lamination Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- 229920001225 polyester resin Polymers 0.000 claims description 6
- 239000004645 polyester resin Substances 0.000 claims description 6
- 230000001681 protective effect Effects 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 238000009823 thermal lamination Methods 0.000 claims 1
- 229920001169 thermoplastic Polymers 0.000 description 11
- 239000004416 thermosoftening plastic Substances 0.000 description 11
- 229920001896 polybutyrate Polymers 0.000 description 10
- 229920000139 polyethylene terephthalate Polymers 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 238000004134 energy conservation Methods 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000009993 protective function Effects 0.000 description 3
- 229920002799 BoPET Polymers 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/08—Polyesters modified with higher fatty oils or their acids, or with resins or resin acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
Abstract
The invention provides a polyester composite board structure and a manufacturing method thereof.
Description
Technical Field
The invention relates to a composite board structure and a manufacturing method thereof, and relates to a polyester composite board structure and a manufacturing method thereof.
Background
Most of the existing plastic composite boards are manufactured by using heterogeneous lamination (PVC glue coating and lamination PBS) or heterogeneous extrusion (PMMA/ABS), and are non-recyclable and non-environment-friendly products. The existing preparation method is characterized in that glue needs to be coated or impregnated by heterogeneous lamination, and solvent volatilization and heating lamination exist in the preparation process, so that the method belongs to a product with energy consumption and carbon emission.
Based on the above, a method for manufacturing a composite board is developed, which meets the current requirements of environmental protection, energy conservation and carbon reduction, and is an important subject for the current research.
Disclosure of Invention
The invention provides a polyester composite board structure and a manufacturing method thereof, wherein the composite board structure is manufactured by using a single material, and no gluing and hot pressing process is adopted, so that the requirements on environmental protection, energy conservation and carbon reduction are met.
The manufacturing method of the polyester composite board structure comprises the steps of extruding a polyester layer into a board by using a multi-layer extrusion device, and thermally bonding a polyester film by using a wheel in the extrusion process.
In one embodiment of the present invention, the melting temperature of the multilayer extrusion device is 250 ℃ to 290 ℃.
In one embodiment of the present invention, the polyester layer comprises a recycled polyester resin layer (which may be PET or a generally thermoplastic polyester, such as PC, PBT, PBAT, etc., having a thickness of 0.3mm to 6.0mm and providing mainly support for the composite board), a functional polyester layer (which may be PET or a generally thermoplastic polyester, such as PC, PBT, PBAT, etc., having a thickness of 0.12mm to 4.0mm and providing mainly functional properties of the composite board, such as color, pattern, etc.), or a protective polyester layer (which may be PET or a generally thermoplastic polyester, such as PC, PBT, PBAT, etc., having a thickness of 0.06mm to 1.0mm and providing mainly protective functions of the composite board, such as scratch resistance, solvent resistance, etc.).
In one embodiment of the present invention, the lamination temperature of the heat-laminated polyester film using the wheel is 80 to 180 ℃.
The polyester composite board structure is manufactured by the manufacturing method.
In one embodiment of the invention, the thickness is 0.6mm to 10mm.
In one embodiment of the present invention, the polyester film comprises 1 to 5 polyester layers and 1 to 2 polyester films (which may be a transparent PET film, a PET film with printing process, or a thermoplastic polyester film, such as PC, PBT, PBAT film, and the thickness is from 12um to 250um, and the thickness mainly provides additional functions of the composite board, such as decorative patterns, antibacterial, mildew-proof, wear-resistant, scratch-resistant performances, etc.).
In one embodiment of the present invention, the polyester layer comprises a recycled polyester resin layer (which may be PET or a generally thermoplastic polyester, such as PC, PBT, PBAT, etc., having a thickness of 0.3mm to 6.0mm and providing mainly support for the composite board), a functional polyester layer (which may be PET or a generally thermoplastic polyester, such as PC, PBT, PBAT, etc., having a thickness of 0.12mm to 4.0mm and providing mainly functional properties of the composite board, such as color, pattern, etc.), or a protective polyester layer (which may be PET or a generally thermoplastic polyester, such as PC, PBT, PBAT, etc., having a thickness of 0.06mm to 1.0mm and providing mainly protective functions of the composite board, such as scratch resistance, solvent resistance, etc.)
Based on the above, the invention provides a polyester composite board structure and a manufacturing method thereof, wherein the composite board structure is made of a single material, and polyester film and the composite board are closely formed through the temperature of the wheel of the equipment on the premise of not coating glue or heating and pressing, so that the polyester composite board structure has the performances of decoration pattern, antibiosis, mildew resistance, wear resistance, scratch resistance and the like, and meets the current requirements on environmental protection, energy conservation and carbon reduction.
Detailed Description
Hereinafter, embodiments of the present invention will be described in detail. However, these embodiments are illustrative, and the present disclosure is not limited thereto.
In this document, a range from "one value to another value" is a shorthand way of referring individually to all the values in the range, which are avoided in the specification. Thus, recitation of a particular numerical range includes any numerical value within that range, as well as the smaller numerical range bounded by any numerical value within that range, as if the any numerical value and the smaller numerical range were written in the specification.
The invention provides a polyester composite board structure and a manufacturing method thereof.
In this embodiment, the melting temperature of the multi-layer extrusion apparatus is, for example, 250 ℃ to 290 ℃, and two or three multi-layer extrusion apparatuses can be used to manufacture the upper layer, the middle layer or the bottom layer, respectively. The polyester layer may include recycled polyester resin layer (which may be PET or general thermoplastic type polyester, such as PC, PBT, PBAT, etc. and has a thickness of 0.3mm to 6.0mm, and mainly provides support for the composite board), functional polyester layer (which may be PET or general thermoplastic type polyester, such as PC, PBT, PBAT, etc. and has a thickness of 0.12mm to 4.0mm, and mainly provides functional properties of the composite board, such as color, pattern, etc.), or protective polyester layer (which may be PET or general thermoplastic type polyester, such as PC, PBT, PBAT, etc. and has a thickness of 0.06mm to 1.0mm, and mainly provides protective functions of the composite board, such as scratch resistance, solvent resistance, etc.). The lamination temperature of the polyester film is 80 ℃ to 180 ℃ by using a wheel, and the wheel can comprise three rollers, for example, but the invention is not limited thereto. The polyester composite board structure manufactured by the manufacturing method of the invention has the thickness of 0.6mm to 10mm, for example, and can comprise 1 to 5 polyester layers and 1 to 2 polyester films.
In summary, the present invention provides a polyester composite board structure and a manufacturing method thereof, wherein a composite board structure is made of a single material, and the polyester film and the composite board are closely formed by the temperature of the wheel of the device and the thermoplastic property of polyester on the premise of not coating glue or heating and pressing, so that the polyester composite board structure has the performances of decoration pattern, antibiosis, mildew resistance, wear resistance, scratch resistance, etc., thereby meeting the requirements of environmental protection, energy conservation and carbon reduction. In addition, the recycled polyester resin layer can be used for extrusion into a plate, which accords with the trend of low-carbon green products.
Claims (8)
1. A method of manufacturing a polyester composite panel structure, comprising:
The polyester layer is extruded into a plate by using a multi-layer extrusion device, and the polyester film is thermally bonded by using a wheel in the extrusion process.
2. The method of manufacturing a polyester composite panel structure according to claim 1, wherein the melting temperature of the multilayer extrusion device is 250 ℃ to 290 ℃.
3. The method of manufacturing a polyester composite panel structure according to claim 1, wherein the polyester layer comprises a recycled polyester resin layer, a functional polyester layer, or a protective polyester layer.
4. The method of manufacturing a polyester composite panel structure according to claim 1, wherein the lamination temperature of the polyester film is 80 ℃ to 180 ℃ by using a wheel for thermal lamination.
5. A polyester composite panel structure, characterized in that it is manufactured using the manufacturing method of the polyester composite panel structure as claimed in any one of claims 1 to 4.
6. The polyester composite panel structure of claim 5, wherein the thickness is 0.6mm to 10mm.
7. The polyester composite panel structure of claim 5, comprising 1 to 5 polyester layers and 1 to 2 polyester films.
8. The polyester composite panel structure of claim 5, wherein the polyester layer comprises a recycled polyester resin layer, a functional polyester layer, or a protective polyester layer.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
TW111139347A TW202417218A (en) | 2022-10-18 | Polyester composite board structure and manufacturing method thereof | |
TW111139347 | 2022-10-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN117944349A true CN117944349A (en) | 2024-04-30 |
Family
ID=90626982
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202211406973.6A Pending CN117944349A (en) | 2022-10-18 | 2022-11-10 | Polyester composite board structure and manufacturing method thereof |
Country Status (3)
Country | Link |
---|---|
US (1) | US20240124707A1 (en) |
JP (1) | JP2024059538A (en) |
CN (1) | CN117944349A (en) |
-
2022
- 2022-11-10 CN CN202211406973.6A patent/CN117944349A/en active Pending
- 2022-11-24 US US17/993,882 patent/US20240124707A1/en active Pending
-
2023
- 2023-01-13 JP JP2023003429A patent/JP2024059538A/en active Pending
Also Published As
Publication number | Publication date |
---|---|
US20240124707A1 (en) | 2024-04-18 |
JP2024059538A (en) | 2024-05-01 |
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