CN117925397A - High-efficiency biocatalysis reactor - Google Patents

High-efficiency biocatalysis reactor Download PDF

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Publication number
CN117925397A
CN117925397A CN202410179151.1A CN202410179151A CN117925397A CN 117925397 A CN117925397 A CN 117925397A CN 202410179151 A CN202410179151 A CN 202410179151A CN 117925397 A CN117925397 A CN 117925397A
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China
Prior art keywords
reactor
wall
reactor shell
biocatalysis
shell
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Pending
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CN202410179151.1A
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Chinese (zh)
Inventor
吴希
云振宇
张卉
赵琳
吴琦
张梦妍
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China National Institute of Standardization
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China National Institute of Standardization
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Priority to CN202410179151.1A priority Critical patent/CN117925397A/en
Publication of CN117925397A publication Critical patent/CN117925397A/en
Pending legal-status Critical Current

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Abstract

The invention belongs to the technical field of biocatalysis reactors, in particular to a high-efficiency biocatalysis reactor, which comprises a reactor shell, wherein the top end of the reactor shell is detachably connected with a mounting cover, immobilized enzyme is placed in the reactor shell, the outer wall of the circumference of the reactor shell is fixedly provided with an external shell with an annular structure, the inner walls of two sides of the external shell are respectively fixedly provided with an electric guide rail with an arc-shaped structure, the electric guide rails are connected with a vertically extending movable frame, the electric guide rails reciprocate in the horizontal direction along with the movable frame, and one side of the movable frame is fixedly provided with a heating element. The invention uses the electric guide rail to carry the heating parts at two sides of the reactor shell to horizontally reciprocate, so that the direct conduction heated area is continuously changed, and the temperature difference exists in the horizontal direction of the liquid in the reactor shell, thereby the liquid flows alternately in the horizontal direction in the reactor shell, the contact effect of the liquid flow and the immobilized enzyme is improved, and the reaction efficiency is improved.

Description

High-efficiency biocatalysis reactor
Technical Field
The invention relates to the technical field of biocatalysis reactors, in particular to a high-efficiency biocatalysis reactor.
Background
The biocatalysis reactor is equipment required by taking biological enzyme as a catalyst to perform reaction, is widely applied to industries such as biological medicine, fine chemical engineering and the like, and has the function of preparing specific products from specified reactants by taking the biological enzyme as the catalyst.
In the traditional biocatalysis reactor, generally, immobilized enzyme and a substrate are thrown into the reactor at one time, and the substrate and the immobilized enzyme are directly stirred through stirring to accelerate the reaction rate, but a stirring device often causes damage of the immobilized enzyme, the power of the stirring device is reduced, the reaction sufficiency is influenced, and the working efficiency is further reduced.
Disclosure of Invention
Based on the technical problems of the background technology, the invention provides a high-efficiency biocatalysis reactor.
The invention provides a high-efficiency biocatalysis reactor, which comprises a reactor shell, wherein the top end of the reactor shell is detachably connected with a mounting cover, immobilized enzyme is placed in the reactor shell, the outer wall of the circumference of the reactor shell is fixedly provided with an external shell with an annular structure, the inner walls of two sides of the external shell are respectively fixedly provided with an electric guide rail with an arc-shaped structure, the electric guide rails are connected with a vertically extending moving frame, the electric guide rails carry the moving frame to reciprocate in the horizontal direction, and one side of the moving frame is fixedly provided with a heating element; the top of the reactor shell is communicated with a liquid inlet pipe, the bottom of the reactor shell is communicated with a liquid outlet pipe, the middle position of the top of the installation cover is communicated with a feeding channel, and the bottom of the reactor shell is communicated with a plurality of aeration pipes.
Preferably, the bottom inner wall of the reactor shell is fixed with a ring-shaped array distribution rack, the rack is vertically extended and arranged, the rack is arranged into an outwards arched arc structure, a gap is reserved between two adjacent racks, the outer walls of two sides of the rack are provided with first meshes, immobilized enzymes are placed in the rack, and aeration pipes are distributed in the area between the racks.
Preferably, the position of the circumferential inner wall of the reactor shell corresponding to the external shell is provided with connecting parts distributed in an annular array, the connecting parts are vertically extended and arranged, the connecting parts protrude towards the inner side of the reactor shell, and the position of the outer wall of the reactor shell corresponding to the connecting parts is provided with inwards concave grooves.
Preferably, filter plates are horizontally arranged at the bottom positions among the plurality of racks in the reactor shell, and the filter plates reciprocate in the vertical direction.
Preferably, the outer wall of the filter plate is fixed with a mounting plate with an annular structure, the outer wall of the mounting plate is in sliding contact with the inner wall of the reactor shell, a through groove in sliding contact with the outer wall of the placing frame is formed in the top of the mounting plate, and an electric push rod is connected to the bottom of the mounting plate.
Preferably, a placing cylinder with an opening at the top end is fixed at the middle position of the bottom of the mounting cover, the feeding channel is communicated with the top end of the placing cylinder, and a second mesh is arranged on the outer wall of the placing cylinder.
Preferably, the perforation has all been seted up to the bottom both sides of placing the section of thick bamboo, the axle center position of perforation is provided with the lifter of vertical extension, and the outer wall of lifter is fixed with the piston piece that vertical direction equidistance was distributed, the top of lifter is fixed with the connecting plate, is connected with electric telescopic handle between the top of one end of connecting plate and external shell.
Preferably, the two lifting rods reciprocate reversely in the vertical direction, and the outer diameter of the piston block gradually decreases from the middle position towards the top end and the bottom end.
Preferably, the mounting groove is arranged at the middle position of the bottom end of the placing cylinder, the mounting ball is arranged in the mounting groove in a limiting rolling mode, the swinging rod is vertically arranged in a penetrating mode at the middle position of the mounting ball, and blades distributed in an annular array are fixed at the bottom end of the outer wall of the swinging rod.
Preferably, the swing rod outer wall is located the both sides position of placing in the section of thick bamboo and all is fixed with the dispersion pole, and the intermediate position of dispersion pole is upwards buckled, and the both ends of dispersion pole all incline from the intermediate position and set up downwards.
The beneficial effects of the invention are as follows:
1. In the embodiment of the invention, the electric guide rail is utilized to carry the heating parts at the two sides of the reactor shell to horizontally reciprocate, so that the direct conduction heated area in the reactor shell is continuously changed, and the temperature difference exists in the horizontal direction of the liquid in the reactor shell, so that the liquid flows alternately in the horizontal direction in the reactor shell, the contact effect of the liquid flow and the immobilized enzyme is improved, the reaction efficiency is improved, the damage to the immobilized enzyme is effectively avoided, the recycling effect of the immobilized enzyme is improved, and the accumulation and the blockage of viscous bottom materials or viscous reactants in the reactor shell are avoided.
2. According to the embodiment of the invention, the protruding connecting parts which are distributed in an annular manner are arranged, and the heating parts are matched with the reciprocating motion of the heating parts in the outer circumferential direction, so that the difference exists in the heating time of the liquid in the reactor shell, which is close to the inner wall, and the interactive dispersion effect of the liquid flow in the radial direction is increased.
3. In the embodiment of the invention, the electric push rod is utilized to carry the mounting plate and the filter plate to vertically reciprocate in the bottom area of the reactor shell in the reaction process, and through the solid arrangement of the mounting plate, liquid flows alternately flow in the inner area and the outer area of the placing frame and the immobilized enzyme, and the contact effect of the liquid flow and the immobilized enzyme is further improved by matching with the aeration operation of the bottom and the liquid flow movement guided by the peripheral heating piece, so that the reaction efficiency is further improved.
4. In the embodiment of the invention, the sticky bottom materials are firstly put into the placing cylinder, the two lifting rods vertically reciprocate by utilizing the electric telescopic rods, and the piston blocks on the lifting rods are contacted at intervals at the perforation positions, so that the perforation intervals at two sides of the inner bottom of the placing cylinder are discharged into the reactor shell, the periphery of the placing frame is prevented from being blocked by one-time feeding, the dispersing effect of the sticky bottom materials is improved, the swinging rods reciprocate and swing in a direction changing manner by carrying the blades, the mounting balls and the dispersing rods, the materials sent out from the perforation holes are dispersed by the swinging blades, and the sticky bottom materials in the placing cylinder are dispersed by the swinging dispersing rods, so that the contact effect between the peripheral meshes II is improved.
Drawings
FIG. 1 is a schematic diagram of the overall structure of a high-efficiency biocatalysis reactor according to the present invention;
FIG. 2 is a schematic diagram of the internal structure of an external shell of a high-efficiency biocatalysis reactor according to the present invention;
FIG. 3 is a schematic view of the internal structure of a reactor housing of a high-efficiency biocatalysis reactor according to the present invention;
FIG. 4 is a schematic diagram of a rack distribution structure of a high-efficiency biocatalysis reactor according to the present invention;
FIG. 5 is a schematic view of the structure of the mounting plate and the filter plate of the high-efficiency biocatalysis reactor according to the present invention;
FIG. 6 is a schematic view of the internal structure of a placement barrel of a high-efficiency biocatalysis reactor according to the present invention;
fig. 7 is a schematic diagram of a swing rod structure of a high-efficiency biocatalysis reactor according to the present invention.
In the figure: 1 reactor shell, 101 leg column, 102 connecting part, 2 installation cover, 3 feed liquor pipe, 4 drain pipe, 5 feeding channel, 6 aeration pipe, 7 rack, 8 immobilized enzyme, 9 external shell, 10 electric guide rail, 11 movable rack, 12 heating piece, 13 mounting plate, 131 through groove, 14 filter plate, 15 electric push rod, 16 placing cylinder, 17 perforation, 18 lifter, 19 piston block, 20 electric telescopic rod, 21 installation ball, 22 swing rod, 23 blade, 24 dispersion rod.
Detailed Description
Example 1
Referring to fig. 1-5, a high-efficiency biocatalysis reactor comprises a reactor shell 1, wherein a plurality of leg columns 101 are fixed at the bottom of the reactor shell 1, a mounting cover 2 is detachably connected to the top end of the reactor shell 1, immobilized enzyme 8 is placed in the reactor shell 1, the reactor shell 1 is arranged into a cylindrical structure, an external shell 9 with an annular structure is fixed on the circumferential outer wall of the reactor shell 1, electric guide rails 10 with arc structures are fixed on the inner walls of two sides of the external shell 9, the electric guide rails 10 are horizontally placed, a vertically extending movable frame 11 is connected to the electric guide rails 10, the electric guide rails 10 reciprocate along with the movable frame 11 in the horizontal direction, and a heating element 12 is fixed at one side position of the movable frame 11, which is close to the reactor shell 1; the top of the reactor shell 1 is communicated with a liquid inlet pipe 3, the bottom of the reactor shell 1 is communicated with a liquid outlet pipe 4, the middle position of the top of the installation cover 2 is communicated with a feeding channel 5, the bottom end of the reactor shell 1 is communicated with a plurality of aeration pipes 6, so that more viscous base materials or more viscous intermediate products generated in the previous working procedure are thrown into the reactor shell 1 through the feeding channel 5, liquid is injected into the reactor shell 1 through the liquid inlet pipe 3, so that substrates are contacted with immobilized enzyme 8 in the reactor shell 1 for reaction, aeration is carried out at intervals upwards through the aeration pipes 6 at the bottom of the reactor shell 1 to increase liquid flow movement, and the reaction efficiency is improved through heating of an external heating part 12; in addition, during the reaction operation, the electric guide rail 10 is utilized to carry the heating pieces 12 on the two sides of the reactor shell 1 to horizontally reciprocate, so that the area of direct conduction and heating in the reactor shell 1 is continuously changed, and the temperature difference exists in the horizontal direction of the liquid in the reactor shell 1, so that the liquid flows alternately in the horizontal direction in the reactor shell 1, and the contact effect of the liquid flow and the immobilized enzyme 8 is improved by matching with the aeration operation in the vertical direction, the reaction efficiency is improved, and the excessive impact of direct stirring on the immobilized enzyme 8 is avoided by the natural flow of the liquid along with the temperature difference, thereby effectively avoiding the damage to the immobilized enzyme 8 and improving the recycling effect of the immobilized enzyme 8; and the liquid flow is dispersed and flowed in the horizontal and vertical directions by the horizontal reciprocating motion of the heating member 12 in cooperation with the aeration operation, so as to avoid clogging by accumulation of viscous bed material or products in the reactor shell 1.
In the invention, referring to fig. 1-5, the inner wall of the bottom of the reactor shell 1 is fixedly provided with annular array distributed racks 7, the racks 7 are vertically extended and arranged, the racks 7 are arranged into an outwards arched structure, gaps are reserved between two adjacent racks 7, the outer walls of two sides of each rack 7 are provided with meshes I, immobilized enzyme 8 is placed in each rack 7, aeration pipes 6 are distributed in the areas among the racks 7, during aeration operation, air flow introduced by the bottom aeration pipes 6 flows outwards from chambers among the racks 7, and the outer area in the reactor shell 1 is heated up near a heating element 12, so that the air flow inside and outside the racks 7 alternately flows in the areas among the two adjacent racks 7, and the dispersed flowing liquid is fully contacted with the distributed immobilized enzyme 8 through reasonable distribution of the immobilized enzyme 8 and matching with the movement of liquid flow driven by the heating element 12 and aeration, so as to further improve the reaction efficiency.
In the invention, referring to fig. 1-5, the circumferential inner wall of the reactor shell 1 is provided with connecting parts 102 distributed in annular array at the positions corresponding to the external shell 9, the connecting parts 102 are vertically extended and arranged, the connecting parts 102 are protruded towards the inner side of the reactor shell 1, the positions corresponding to the connecting parts 102 on the outer wall of the reactor shell 1 are provided with inwards concave grooves, and the protruding and annularly distributed connecting parts 102 are matched with the reciprocating motion of the heating element 12 in the outer circumferential direction, so that the liquid heating time near the inner wall position in the reactor shell 1 is different, namely, the liquid temperatures at different positions in the same time circumferential direction are different, so as to increase the liquid flow motion, and during the reciprocating motion of the heating element 12, the liquid flow collides with the connecting parts 102 and disperses when moving along the inner wall of the reactor shell 1, thereby further improving the liquid flow dispersing motion effect while avoiding direct stirring, and enhancing the contact reaction effect and catalytic efficiency of the liquid flow and the immobilized enzyme 8.
In the invention, referring to fig. 1-5, a filter plate 14 is horizontally arranged at the bottom position between a plurality of placing frames 7 in a reactor shell 1, the filter plate 14 reciprocates in the vertical direction, a mounting plate 13 with an annular structure is fixed on the outer wall of the filter plate 14, the outer wall of the mounting plate 13 is in sliding contact with the inner wall of the reactor shell 1, a through groove 131 in sliding contact with the outer wall of the placing frame 7 is formed at the top of the mounting plate 13, an electric push rod 15 is connected to the bottom of the mounting plate 13, a motor part of the electric push rod 15 is fixed on the bottom outer wall of the reactor shell 1, and a push rod part of the electric push rod 15 extends into the reactor shell 1 and vertically reciprocates in the bottom area of the reactor shell 1 by utilizing the electric push rod 15 to carry the mounting plate 13 and the filter plate 14 in the reaction process; during the lowering of the mounting plate 13 and the filter plate 14, the mounting plate 13 is solid, i.e. the peripheral flow in the reactor housing 1 below the mounting plate 13 moves towards the middle area, while the flow below the filter plate 14 in the middle area flows upwards; during the lifting of the mounting plate 13 and the filter plates 14, the flow above the filter plates 14 is downward and the peripheral flow above the mounting plate 13 is circulated toward the intermediate position; the contact effect of the liquid flow and the immobilized enzyme 8 is further improved by matching the aeration operation of the bottom and the liquid flow movement guided by the peripheral heating element 12, so that the reaction efficiency is further improved, and the deposition at the bottom of the reactor shell 1 and the blockage at the periphery of the placing frame 7 are avoided.
Example 2
Embodiment 2 includes all the structures and methods of embodiment 1, referring to fig. 1-7, a high-efficiency biocatalysis reactor, further comprising a placing cylinder 16 with an open top end fixed in the middle of the bottom of the mounting cover 2, a feeding channel 5 communicated with the top end of the placing cylinder 16, a second mesh opening formed on the outer wall of the placing cylinder 16, perforations 17 formed on both sides of the bottom of the placing cylinder 16, vertically extending lifting rods 18 arranged at the axle center of the perforations 17, piston blocks 19 distributed equidistantly in the vertical direction fixed on the outer wall of the lifting rods 18, a connecting plate fixed on the top end of the lifting rods 18, an electric telescopic rod 20 connected between one end of the connecting plate and the top of the external shell 9, wherein the two lifting rods 18 reciprocate in opposite directions in the vertical direction, namely, the moving directions of the lifting rods 18 reciprocate in two cycles in the vertical direction are always reversed, the outer diameter of the piston block 19 gradually decreases from the middle position towards the top end and the bottom end, and the more viscous base material or the more viscous intermediate product generated in the previous process is put into the placing cylinder 16 in the reactor shell 1 for one time, during the reaction, the more viscous base material or the more viscous intermediate product generated in the previous process is contacted with liquid through the second mesh of the outer wall of the placing cylinder 16, and the two lifting rods 18 are vertically reciprocated by utilizing the electric telescopic rods 20 to bring the piston blocks 19 on the lifting rods 18 into contact at the positions of the through holes 17 at intervals, so that the through holes 17 at the two sides of the inner bottom of the placing cylinder 16 are discharged into the reactor shell 1 at intervals, the periphery of the placing frame 7 is prevented from being blocked by one-time feeding, and the more viscous base material is improved, or the dispersion effect of the more viscous intermediate product produced in the preceding step; through the outer diameter change setting of the piston block 19, the piston block 19 improves the material guiding effect on the position of the perforation 17 and the viscous material in the peripheral area of the perforation 17 in the process of vertically reciprocating along with the lifting rod 18, and ensures the dispersed operation effect of the viscous base material passing through the perforation 17.
In the invention, referring to fig. 1-7, a mounting groove is arranged at the middle position of the bottom end of a placing cylinder 16, a mounting ball 21 is limited and rolled in the mounting groove, a swinging rod 22 is vertically and penetratingly arranged at the middle position of the mounting ball 21, the top end of the swinging rod 22 extends into the placing cylinder 16, the bottom end of the swinging rod 22 extends to the lower position of the outer wall of the bottom end of the placing cylinder 16, blades 23 distributed in an annular array are fixed at the bottom end of the outer wall of the swinging rod 22, dispersing rods 24 are fixed at the two side positions of the outer wall of the swinging rod 22 in the placing cylinder 16, the middle position of the dispersing rods 24 is bent upwards, the two ends of the dispersing rods 24 are downwards inclined from the middle position, so that in the reaction process, the two perforation holes 17 are reversed in the direction of the liquid flow guided by the movement of the piston block 19 by the reaction movement of the lifting rods 18 on the two sides in the vertical direction, and the blades 23 distributed between the two perforation holes 17 are inclined along with the liquid flow, so that the blades 23, the mounting balls 21 and the dispersing rods 24 are driven to swing in a reciprocating direction by the swinging rods 22, the materials sent out from the perforation holes 17 are dispersed by the swinging blades 23, the viscous base materials in the placing cylinder 16 are dispersed by the swinging dispersing rods 24, the contact effect between the peripheral mesh holes II is improved, the catalytic reaction efficiency is further improved, and the blockage is avoided.
The foregoing is only a preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art, who is within the scope of the present invention, should make equivalent substitutions or modifications according to the technical scheme of the present invention and the inventive concept thereof, and should be covered by the scope of the present invention.

Claims (10)

1. The utility model provides a high-efficient biocatalysis reactor, includes reactor shell (1), the top of reactor shell (1) is detachably connected with installation lid (2), fixed enzyme (8) have been placed in reactor shell (1), a serial communication port, the circumference outer wall of reactor shell (1) is fixed with external shell (9) of annular structure, both sides inner wall of external shell (9) all is fixed with arc structure's electric guide rail (10), is connected with vertical movable rack (11) that extend on electric guide rail (10), and electric guide rail (10) carry movable rack (11) to reciprocate in the horizontal direction, one side of movable rack (11) is fixed with heating element (12);
The top intercommunication of reactor casing (1) has feed liquor pipe (3), and the bottom intercommunication of reactor casing (1) has drain pipe (4), the intermediate position intercommunication at installation lid (2) top has throw material passageway (5), the bottom intercommunication of reactor casing (1) has a plurality of aeration pipes (6).
2. The efficient biocatalysis reactor according to claim 1, characterized in that the inner wall of the bottom of the reactor shell (1) is fixed with a rack (7) distributed in an annular array, the rack (7) is vertically extended and arranged, the rack (7) is arranged into an outwards arched arc structure, a gap is reserved between two adjacent racks (7), the outer walls of two sides of the rack (7) are provided with first meshes, immobilized enzyme (8) is placed in the rack (7), and the aeration pipes (6) are distributed in the area between the racks (7).
3. The efficient biocatalysis reactor according to claim 2, characterized in that the circumferential inner wall of the reactor shell (1) is provided with connecting parts (102) distributed in an annular array at positions corresponding to the external shell (9), the connecting parts (102) are vertically extended, the connecting parts (102) protrude towards the inner side of the reactor shell (1), and the positions of the outer wall of the reactor shell (1) corresponding to the connecting parts (102) are provided with inwards concave grooves.
4. A high efficiency biocatalysis reactor according to claim 2, characterized in that the filter plate (14) is horizontally arranged at the bottom position between the plurality of racks (7) in the reactor shell (1), and the filter plate (14) reciprocates in the vertical direction.
5. The efficient biocatalysis reactor according to claim 4, characterized in that the outer wall of the filter plate (14) is fixed with a mounting plate (13) with an annular structure, the outer wall of the mounting plate (13) is in sliding contact with the inner wall of the reactor shell (1), a through groove (131) in sliding contact with the outer wall of the placing frame (7) is formed in the top of the mounting plate (13), and the bottom of the mounting plate (13) is connected with an electric push rod (15).
6. A high efficiency biocatalysis reactor according to any one of claims 2-5, characterized in that the middle position of the bottom of the mounting cover (2) is fixed with a placing cylinder (16) with an open top end, the feeding channel (5) is communicated with the top end of the placing cylinder (16), and the outer wall of the placing cylinder (16) is provided with a second mesh.
7. The high-efficiency biocatalysis reactor according to claim 6, wherein the two sides of the bottom of the placing cylinder (16) are provided with through holes (17), the axle center position of each through hole (17) is provided with a vertically extending lifting rod (18), the outer wall of each lifting rod (18) is fixedly provided with piston blocks (19) distributed at equal intervals in the vertical direction, the top end of each lifting rod (18) is fixedly provided with a connecting plate, and an electric telescopic rod (20) is connected between one end of each connecting plate and the top of the external shell (9).
8. A high efficiency biocatalytic reactor according to claim 7, characterized in that two of said lifting rods (18) reciprocate in opposite directions in the vertical direction, the outer diameter of said piston block (19) gradually decreasing from the intermediate position towards the top and bottom ends.
9. The efficient biocatalysis reactor according to claim 8, wherein a mounting groove is formed in the middle position of the bottom end of the placing cylinder (16), a mounting ball (21) is arranged in the mounting groove in a limited rolling mode, a swinging rod (22) is vertically arranged in the middle position of the mounting ball (21) in a penetrating mode, and blades (23) distributed in an annular array are fixed at the bottom end of the outer wall of the swinging rod (22).
10. The high-efficiency biocatalysis reactor according to claim 9, wherein the outer wall of the swinging rod (22) is fixed with a dispersing rod (24) at two sides of the inner wall of the placing cylinder (16), the middle position of the dispersing rod (24) is bent upwards, and two ends of the dispersing rod (24) are inclined downwards from the middle position.
CN202410179151.1A 2024-02-18 2024-02-18 High-efficiency biocatalysis reactor Pending CN117925397A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202410179151.1A CN117925397A (en) 2024-02-18 2024-02-18 High-efficiency biocatalysis reactor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202410179151.1A CN117925397A (en) 2024-02-18 2024-02-18 High-efficiency biocatalysis reactor

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Publication Number Publication Date
CN117925397A true CN117925397A (en) 2024-04-26

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB478721A (en) * 1934-10-01 1938-01-24 Adolf Schrey Method of and means for increasing effects by oscillations
EP1336428A2 (en) * 2002-02-15 2003-08-20 Air Products And Chemicals, Inc. Catalyst holder and agitation system for converting stirred tank reactor to fixed bed reactor
CN109835980A (en) * 2019-04-03 2019-06-04 东北大学 A kind of semi-fixed biological contact oxidation reactor
CN116286260A (en) * 2023-02-08 2023-06-23 广西百多收生物科技有限公司 Production equipment and process of polymerase
CN116688166A (en) * 2023-07-10 2023-09-05 深圳市乐华德服饰有限公司 Antibacterial surface fabric hot working sterilizing equipment

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB478721A (en) * 1934-10-01 1938-01-24 Adolf Schrey Method of and means for increasing effects by oscillations
EP1336428A2 (en) * 2002-02-15 2003-08-20 Air Products And Chemicals, Inc. Catalyst holder and agitation system for converting stirred tank reactor to fixed bed reactor
CN109835980A (en) * 2019-04-03 2019-06-04 东北大学 A kind of semi-fixed biological contact oxidation reactor
CN116286260A (en) * 2023-02-08 2023-06-23 广西百多收生物科技有限公司 Production equipment and process of polymerase
CN116688166A (en) * 2023-07-10 2023-09-05 深圳市乐华德服饰有限公司 Antibacterial surface fabric hot working sterilizing equipment

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