CN117887295A - Fireproof coating and preparation method and application thereof - Google Patents

Fireproof coating and preparation method and application thereof Download PDF

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Publication number
CN117887295A
CN117887295A CN202410058666.6A CN202410058666A CN117887295A CN 117887295 A CN117887295 A CN 117887295A CN 202410058666 A CN202410058666 A CN 202410058666A CN 117887295 A CN117887295 A CN 117887295A
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parts
fireproof
coating
foaming agent
particle size
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CN202410058666.6A
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Inventor
张艮中
孙立柱
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Hebei Yanzhi Oxygen Environmental Protection Technology Co ltd
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Hebei Yanzhi Oxygen Environmental Protection Technology Co ltd
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Priority to CN202410058666.6A priority Critical patent/CN117887295A/en
Publication of CN117887295A publication Critical patent/CN117887295A/en
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Abstract

The invention relates to the technical field of coatings, in particular to a fireproof coating and a preparation method thereof. The fireproof paint provided by the invention comprises the following components: aluminum silicate, bentonite, silicon dioxide, quartz powder, white cement, water glass, a composite foaming agent, basalt fiber and water; each cubic meter of the fireproof paint contains 0.5-0.7 cubic meter of nitrogen. According to the fireproof coating provided by the invention, the inorganic materials or inorganic gel materials such as aluminum silicate, bentonite, silicon dioxide, quartz powder, white cement, water glass and basalt fiber are fully dispersed in the nitrogen foam formed by the nitrogen and the foaming agent, so that the advantages of the nitrogen foam and the inorganic materials or inorganic gel materials can be fully exerted, and the stability of the coating is improved, and the heat conductivity coefficient is reduced, so that the prepared coating has excellent fireproof, heat-insulating and heat-insulating properties.

Description

Fireproof coating and preparation method and application thereof
Technical Field
The invention relates to the technical field of coatings, in particular to a fireproof coating and a preparation method and application thereof.
Background
Under the condition of shortage of global energy supply, energy conservation and heat preservation become a concern, a heat preservation plate is used as a current common heat preservation mode, but the heat preservation plate also has a certain problem, and in recent years, a plurality of high-rise buildings are in fire disaster, and fireproof building materials can gain time for fire extinguishment and personnel evacuation; therefore, the fireproof heat-insulating paint is used as heat-insulating material to replace plate. However, most of the current fireproof coatings are to add flame retardant to the coating to achieve the fireproof effect, but there are some problems such as: the flame retardant may contain harmful substances, which causes a certain risk to the environment and human health; the addition of the flame retardant can also affect the physical properties and the processing property of the paint, so that the adhesive force of the paint is poor; some efficient flame retardants are relatively high in formulation, which may increase the cost of the coating. Therefore, aiming at the problems that the existing fireproof paint has single technology and unstable performance and cannot give consideration to heat insulation effect, the development of a novel fireproof paint has important significance.
Disclosure of Invention
Aiming at the problems that the existing fireproof paint has single technology, unstable performance and poor adhesive force and cannot give consideration to heat insulation effect, the invention provides the antibacterial paint and the preparation method thereof.
In order to solve the technical problems, the technical scheme provided by the invention is as follows:
The first aspect of the invention provides a fireproof coating, which comprises the following raw material components in parts by weight: 10-30 parts of aluminum silicate, 15-18 parts of bentonite, 3-10 parts of silicon dioxide, 15-25 parts of quartz powder, 25-40 parts of white cement, 3-10 parts of water glass, 0.8-1.5 parts of composite foaming agent, 2-6 parts of basalt fiber and 148-287 parts of water; each cubic meter of the fireproof paint contains 0.5-0.7 cubic meter of nitrogen;
The content of animal protein in the composite foaming agent is 38% -42%, and the content of vegetable protein is 38% -40%.
Compared with the prior art, the fireproof coating provided by the invention has the advantages that aluminum silicate can absorb a large amount of heat and release energy at high temperature, the heating rate of the surface of the coating is slowed down, and the microporous structure of aluminum silicate is favorable for delaying heat transfer; the structure formed by bentonite in the paint can effectively prevent flame from spreading, so that the fireproof effect is achieved; the silicon dioxide and the quartz powder can enhance the hardness and the wear resistance of the coating, so that the coating of the coating is more compact, the heat absorption and the heat transfer are reduced, and the coating has excellent fireproof, heat preservation and heat insulation effects; the white cement and the water glass can form a firm framework structure when added into the paint, so that the intersection points inside the paint are more stable and firm, the stability of the paint coating is enhanced, and the fire resistance of the paint is further improved; the basalt fiber can prevent heat transfer, and the fire resistance and the heat insulation performance of the paint are obviously improved; the nitrogen and the specific foaming agent are doped in the coating through forming nitrogen foam, so that the stability is good, the combustible gas and the oxygen can be diluted, a compact foam layer can be formed on the surface of the coating, and a stable independent cavity is formed in the coating, so that the coating achieves the effects of fire prevention, heat preservation and heat insulation through reducing the heat conductivity coefficient.
According to the fireproof coating provided by the invention, the inorganic materials or inorganic gel materials such as aluminum silicate, bentonite, silicon dioxide, quartz powder, white cement, water glass and basalt fiber are fully dispersed in the nitrogen foam formed by the nitrogen and the foaming agent, so that the advantages of the nitrogen foam and the inorganic materials or inorganic gel materials can be fully exerted, and the stability of the coating is improved, and the heat conductivity coefficient is reduced, so that the prepared coating has excellent fireproof, heat-insulating and heat-insulating properties.
The preferred thickness of the coating is advantageous for further improving the fire, heat and thermal insulation properties of the coating.
Preferably, the particle size of the aluminum silicate is 2000-2500 meshes.
Preferably, the particle size of the bentonite is 150-200 meshes.
Preferably, the particle size of the silica is 150-200 mesh.
Preferably, the particle size of the quartz powder is 200-300 meshes.
Preferably, the particle size of the white cement is 200-300 meshes.
By limiting the particle size of the inorganic material and the inorganic gel material, the materials can be better dispersed in nitrogen foam, and the fireproof, heat-insulating and heat-insulating properties of the coating are further improved.
Preferably, the water glass has a modulus of 2.25-2.35.
Preferably, the compound foaming agent is Henan Huatai HTW-1 compound super-concentrated foaming agent.
The preferable foaming agent can stabilize the coating of the paint and further improve the fireproof, heat-insulating and heat-insulating effects of the paint.
Preferably, the tensile strength of the basalt fiber is 3000MPa-4800MPa.
By limiting the tensile strength of basalt fibers, the coating can be endowed with excellent mechanical properties, and the problems of cracking and the like of the coating are avoided, so that the fireproof, heat-insulating and heat-insulating properties of the coating are further improved.
The second aspect of the present invention provides a method for preparing the fireproof paint, comprising the following steps:
step 1, weighing the components according to a designed proportion, and mixing the composite foaming agent with water according to a mass ratio of 1:48-52 to obtain a foaming agent aqueous solution;
step 2, foaming the foaming agent aqueous solution, charging nitrogen, and stirring to obtain nitrogen foam;
And step 3, uniformly mixing the basalt fiber with the residual water, then adding aluminum silicate, bentonite, silicon dioxide, quartz powder, white cement and water glass, uniformly stirring, and then introducing nitrogen foam to obtain the fireproof coating.
Preferably, the diameter of the bubbles in the nitrogen foam is 0.4mm-0.8mm.
Preferably, in step 3, the apparatus used when introducing nitrogen foam may refer to application number CN202320489624.9.
In a third aspect, the invention provides a fire-retardant coating prepared from the fire-retardant coating.
Preferably, the thickness of the fireproof coating is 1.5cm-2cm.
The preparation method of the fireproof paint provided by the invention is simple to operate, suitable for industrial mass production, free of complex procedures, free of special equipment, low in cost, low in construction cost, high in construction efficiency and wide in market prospect.
Detailed Description
The present invention will be described in further detail with reference to the following examples in order to make the objects, technical solutions and advantages of the present invention more apparent. It should be understood that the specific embodiments described herein are for purposes of illustration only and are not intended to limit the scope of the invention.
Example 1
The embodiment provides a fireproof coating, which comprises the following raw material components in parts by weight: 30 parts of aluminum silicate with the particle size of 2000 meshes, 15 parts of bentonite with the particle size of 150 meshes, 10 parts of silicon dioxide with the particle size of 200 meshes, 15 parts of quartz powder with the particle size of 200 meshes, 40 parts of white cement with the particle size of 300 meshes, 3 parts of water glass with the modulus of 2.3, 0.8 part of river Tay HTW-1 composite super-concentrated foaming agent, 2 parts of basalt fiber with the tensile strength of 3000MPa and 211 parts of water; each cubic meter of fireproof paint contains 0.5 cubic meter of nitrogen;
the embodiment also provides a preparation method of the fireproof paint, which comprises the following steps:
Step 1, weighing the components according to a designed proportion, and mixing the composite foaming agent with water according to a mass ratio of 1:48 to obtain a foaming agent aqueous solution;
step 2, foaming the foaming agent aqueous solution, charging nitrogen, and stirring to obtain nitrogen foam;
And step 3, uniformly mixing the basalt fiber with the residual water, then adding aluminum silicate, bentonite, silicon dioxide, quartz powder, white cement and water glass, uniformly stirring, and then introducing nitrogen foam to obtain the fireproof coating.
Example 2
The embodiment provides a fireproof coating, which comprises the following raw material components in parts by weight: 10 parts of aluminum silicate with the particle size of 2500 meshes, 18 parts of bentonite with the particle size of 200 meshes, 3 parts of silicon dioxide with the particle size of 150 meshes, 25 parts of quartz powder with the particle size of 300 meshes, 25 parts of white cement with the particle size of 200 meshes, 10 parts of water glass with the modulus of 2.25, 1.5 parts of Henan Huatai HTW-1 composite super-concentrated foaming agent, 2 parts of basalt fiber and 187.5 parts of water; each cubic meter of fireproof paint contains 0.7 cubic meter of nitrogen;
the embodiment also provides a preparation method of the fireproof paint, which comprises the following steps:
Step 1, weighing the components according to a designed proportion, and mixing the composite foaming agent with water according to a mass ratio of 1:52 to obtain a foaming agent aqueous solution;
step 2, foaming the foaming agent aqueous solution, charging nitrogen, and stirring to obtain nitrogen foam;
And step 3, uniformly mixing the basalt fiber with the residual water, then adding aluminum silicate, bentonite, silicon dioxide, quartz powder, white cement and water glass, uniformly stirring, and then introducing nitrogen foam to obtain the fireproof coating.
Example 3
The embodiment provides a fireproof coating, which comprises the following raw material components in parts by weight: 20 parts of aluminum silicate with the particle size of 2300 meshes, 16 parts of bentonite with the particle size of 180 meshes, 8 parts of silicon dioxide with the particle size of 170 meshes, 20 parts of quartz powder with the particle size of 250 meshes, 30 parts of white cement with the particle size of 240 meshes, 8 parts of water glass with the modulus of 2.35, 1 part of river Tay HTW-1 composite super-concentrated foaming agent, 4 parts of basalt fiber and 164 parts of water; each cubic meter of fireproof paint contains 0.6 cubic meter of nitrogen;
the embodiment also provides a preparation method of the fireproof paint, which comprises the following steps:
step 1, weighing the components according to a designed proportion, and mixing the composite foaming agent with water according to a mass ratio of 1:50 to obtain a foaming agent aqueous solution;
step 2, foaming the foaming agent aqueous solution, charging nitrogen, and stirring to obtain nitrogen foam;
And step 3, uniformly mixing the basalt fiber with the residual water, then adding aluminum silicate, bentonite, silicon dioxide, quartz powder, white cement and water glass, uniformly stirring, and then introducing nitrogen foam to obtain the fireproof coating.
Comparative example 1
The comparative example provides a fireproof coating, which comprises the following raw material components in parts by weight: 30 parts of aluminum silicate with the particle size of 2000 meshes, 15 parts of bentonite with the particle size of 150 meshes, 10 parts of silicon dioxide with the particle size of 200 meshes, 15 parts of quartz powder with the particle size of 200 meshes, 40 parts of white cement with the particle size of 300 meshes, 3 parts of water glass with the modulus of 2.3, 0.8 part of river Tay HTW-1 composite super-concentrated foaming agent, 2 parts of basalt fiber with the tensile strength of 3000MPa and 211 parts of water; each cubic meter of fireproof paint contains 0.5 cubic meter of nitrogen;
the embodiment also provides a preparation method of the fireproof paint, which comprises the following steps:
Step 1, weighing the components according to a designed proportion, and mixing the composite foaming agent with water according to a mass ratio of 1:48 to obtain a foaming agent aqueous solution;
step 2, foaming the foaming agent aqueous solution, charging nitrogen, and stirring to obtain nitrogen foam;
And step 3, uniformly mixing the basalt fiber with the residual water, then adding aluminum silicate, bentonite, silicon dioxide, quartz powder, white cement and water glass, uniformly stirring, and then introducing nitrogen foam to obtain the fireproof coating.
Comparative example 2
The comparative example provides a fireproof coating, which comprises the following raw material components in parts by weight: 30 parts of aluminum silicate with the particle size of 2000 meshes, 15 parts of bentonite with the particle size of 150 meshes, 10 parts of silicon dioxide with the particle size of 200 meshes, 15 parts of quartz powder with the particle size of 200 meshes, 40 parts of white cement with the particle size of 300 meshes, 3 parts of water glass with the modulus of 2.3, 0.8 part of river Tay HTW-1 composite super-concentrated foaming agent, 2 parts of glass fiber with the tensile strength of 3000MPa and 211 parts of water; each cubic meter of fireproof paint contains 0.5 cubic meter of nitrogen;
the embodiment also provides a preparation method of the fireproof paint, which comprises the following steps:
Step 1, weighing the components according to a designed proportion, and mixing the composite foaming agent with water according to a mass ratio of 1:48 to obtain a foaming agent aqueous solution;
step 2, foaming the foaming agent aqueous solution, charging nitrogen, and stirring to obtain nitrogen foam;
And step 3, uniformly mixing the basalt fiber with the residual water, then adding aluminum silicate, bentonite, silicon dioxide, quartz powder, white cement and water glass, uniformly stirring, and then introducing nitrogen foam to obtain the fireproof coating.
Comparative example 3
The comparative example provides a fireproof coating, which comprises the following raw material components in parts by weight: 30 parts of aluminum silicate with the particle size of 2000 meshes, 15 parts of bentonite with the particle size of 150 meshes, 10 parts of silicon dioxide with the particle size of 200 meshes, 15 parts of quartz powder with the particle size of 200 meshes, 40 parts of gypsum dihydrate with the particle size of 300 meshes, 3 parts of water glass with the modulus of 2.3, 0.8 part of river Tay HTW-1 composite super-concentrated foaming agent, 2 parts of basalt fiber with the tensile strength of 3000MPa and 211 parts of water; each cubic meter of fireproof paint contains 0.5 cubic meter of nitrogen;
the embodiment also provides a preparation method of the fireproof paint, which comprises the following steps:
Step 1, weighing the components according to a designed proportion, and mixing the composite foaming agent with water according to a mass ratio of 1:48 to obtain a foaming agent aqueous solution;
step 2, foaming the foaming agent aqueous solution, charging nitrogen, and stirring to obtain nitrogen foam;
And step 3, uniformly mixing the basalt fiber with the residual water, then adding aluminum silicate, bentonite, silicon dioxide, quartz powder, white cement and water glass, uniformly stirring, and then introducing nitrogen foam to obtain the fireproof coating.
Comparative example 4
The comparative example provides a fireproof coating, which comprises the following raw material components in parts by weight: 30 parts of aluminum silicate with the particle size of 2000 meshes, 15 parts of bentonite with the particle size of 150 meshes, 10 parts of silicon dioxide with the particle size of 200 meshes, 15 parts of stone powder with the particle size of 200 meshes, 40 parts of white cement with the particle size of 300 meshes, 3 parts of water glass with the modulus of 2.3, 0.8 part of river Tay HTW-1 composite super-concentrated foaming agent, 2 parts of basalt fiber with the tensile strength of 3000MPa and 211 parts of water; each cubic meter of fireproof paint contains 0.5 cubic meter of nitrogen;
the embodiment also provides a preparation method of the fireproof paint, which comprises the following steps:
Step 1, weighing the components according to a designed proportion, and mixing the composite foaming agent with water according to a mass ratio of 1:48 to obtain a foaming agent aqueous solution;
step 2, foaming the foaming agent aqueous solution, charging nitrogen, and stirring to obtain nitrogen foam;
And step 3, uniformly mixing the basalt fiber with the residual water, then adding aluminum silicate, bentonite, silicon dioxide, quartz powder, white cement and water glass, uniformly stirring, and then introducing nitrogen foam to obtain the fireproof coating.
The limiting oxygen index, the combustion performance grade and the thermal conductivity of the fireproof coatings prepared in examples 1 to 3 and comparative examples 1 to 4 were tested, wherein the limiting oxygen index was tested according to GB/T2406.2 2009 "oxygen index method for combustion performance of plastics", the combustion performance grade was tested according to GB 8624-2012 "classification of combustion performance of building materials and products", the thermal conductivity was tested according to GB/T22588-2008 "flash method for measuring thermal diffusivity or thermal conductivity", and specific test results are shown in Table 1:
TABLE 1
As can be seen from Table 1, the fireproof coatings prepared in examples 1-3 of the invention have significantly lower thermal conductivity than the coatings prepared in comparative examples 1-4, have significantly higher limiting oxygen index than the coatings prepared in comparative examples 1-3, and have excellent fireproof, flame-retardant, heat-insulating properties, and combustion performance grade reaching A1.
The foregoing description of the preferred embodiments of the invention is not intended to be limiting, but rather is intended to cover all modifications, equivalents, or alternatives falling within the spirit and principles of the invention.

Claims (10)

1. The fireproof coating is characterized by comprising the following raw material components in parts by weight: 10-30 parts of aluminum silicate, 15-18 parts of bentonite, 3-10 parts of silicon dioxide, 15-25 parts of quartz powder, 25-40 parts of white cement, 3-10 parts of water glass, 0.8-1.5 parts of composite foaming agent, 2-6 parts of basalt fiber and 148-287 parts of water; each cubic meter of the fireproof paint contains 0.5-0.7 cubic meter of nitrogen;
The content of animal protein in the composite foaming agent is 38% -42%, and the content of vegetable protein is 38% -40%.
2. The fire retardant coating of claim 1 wherein the aluminum silicate has a particle size of 2000 to 2500 mesh.
3. The fire retardant coating of claim 1 wherein the bentonite has a particle size of 150 to 200 mesh.
4. The fire retardant coating of claim 1 wherein the silica has a particle size of 150 to 200 mesh.
5. The fire retardant coating of claim 1, wherein the silica flour has a particle size of 200-300 mesh.
6. The fire retardant coating of claim 1 wherein the white cement has a particle size of 200 to 300 mesh.
7. The fire retardant coating of claim 1, wherein the water glass has a modulus of from 2.25 to 2.35.
8. The fire retardant coating of claim 1, wherein the composite blowing agent is a henna HTW-1 composite super concentrate blowing agent.
9. The fire retardant coating of claim 1 wherein said basalt fiber has a tensile strength of 3000MPa to 4800MPa.
10. A method of preparing a fire retardant coating according to any one of claims 1 to 9, comprising the steps of:
step 1, weighing the components according to a designed proportion, and mixing the composite foaming agent with water according to a mass ratio of 1:48-52 to obtain a foaming agent aqueous solution;
step 2, foaming the foaming agent aqueous solution, charging nitrogen, and stirring to obtain nitrogen foam;
And step 3, uniformly mixing the basalt fiber with the residual water, then adding aluminum silicate, bentonite, silicon dioxide, quartz powder, white cement and water glass, uniformly stirring, and then introducing nitrogen foam to obtain the fireproof coating.
CN202410058666.6A 2024-01-16 2024-01-16 Fireproof coating and preparation method and application thereof Pending CN117887295A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202410058666.6A CN117887295A (en) 2024-01-16 2024-01-16 Fireproof coating and preparation method and application thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202410058666.6A CN117887295A (en) 2024-01-16 2024-01-16 Fireproof coating and preparation method and application thereof

Publications (1)

Publication Number Publication Date
CN117887295A true CN117887295A (en) 2024-04-16

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN202410058666.6A Pending CN117887295A (en) 2024-01-16 2024-01-16 Fireproof coating and preparation method and application thereof

Country Status (1)

Country Link
CN (1) CN117887295A (en)

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