CN117862659A - Explosion compounding method of tantalum-titanium-steel secondary explosion composite board - Google Patents

Explosion compounding method of tantalum-titanium-steel secondary explosion composite board Download PDF

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Publication number
CN117862659A
CN117862659A CN202410108510.4A CN202410108510A CN117862659A CN 117862659 A CN117862659 A CN 117862659A CN 202410108510 A CN202410108510 A CN 202410108510A CN 117862659 A CN117862659 A CN 117862659A
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China
Prior art keywords
plate
titanium
tantalum
explosion
explosive
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CN202410108510.4A
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Chinese (zh)
Inventor
庄乐
刘晓亮
刘洋
李子健
徐银炼
张迪
成泽滨
张鹏
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Dalian Shipbuilding Industry Explosive Processingresearch Co ltd
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Dalian Shipbuilding Industry Explosive Processingresearch Co ltd
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Priority to CN202410108510.4A priority Critical patent/CN117862659A/en
Publication of CN117862659A publication Critical patent/CN117862659A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K20/00Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
    • B23K20/06Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating by means of high energy impulses, e.g. magnetic energy
    • B23K20/08Explosive welding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K20/00Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
    • B23K20/24Preliminary treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K20/00Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
    • B23K20/26Auxiliary equipment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23PMETAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
    • B23P15/00Making specific metal objects by operations not covered by a single other subclass or a group in this subclass
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/18Dissimilar materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K2103/00Materials to be soldered, welded or cut
    • B23K2103/18Dissimilar materials
    • B23K2103/24Ferrous alloys and titanium or alloys thereof

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)

Abstract

The invention discloses an explosion compounding method of a tantalum-titanium-steel secondary explosion composite plate. Placing a steel plate on a foundation, placing supports with the thickness of 14mm on the steel plate, wherein the distance between each row and each column of adjacent supports is 300mm, placing a titanium plate on the supports, and laying an explosive layer on the titanium plate to perform first explosion composite operation. Placing a support with the thickness of 14mm on the titanium steel composite plate, placing a tantalum plate on the support, laying an explosive layer, and performing secondary explosion composite operation. The tantalum-titanium steel composite board is produced by adopting an explosion compounding method, so that the tantalum-titanium steel composite board has the corrosion resistance of tantalum, and has the strength and plasticity of a common steel plate as a structural member, so that the cost is greatly reduced, and the application field of the tantalum-titanium steel composite board material is continuously widened along with the continuous progress of the equipment manufacturing technology in China.

Description

Explosion compounding method of tantalum-titanium-steel secondary explosion composite board
Technical Field
The invention relates to a processing technology of metal equipment raw materials, in particular to an explosion compounding method of a tantalum-titanium-steel secondary explosion composite plate.
Background
The metal layered composite board can realize perfect metallurgical combination of different metals with extremely different strength, melting point and thermal expansion coefficient, integrates the advantages of different materials, fully plays the use characteristics of the different materials, greatly saves rare noble metal materials, reduces the manufacturing cost of equipment, and enables the application of the rare noble metal in a plurality of fields to be possible. The composite material produced by adopting the explosion composite technology can realize perfect combination of different metals, and the components and physical properties of the original material are not changed. The metal composite plate can be designed independently, and different materials can be designed and manufactured into the optimal use state according to the requirements. The metal composite board material not only has good weldability, formability, thermal conductivity and better mechanical property of carbon steel, but also has excellent corrosion resistance of various composite layers. Therefore, the method is widely applied to industries such as petroleum, chemical industry, metallurgy, light industry, salt chemical industry, auxiliary machines of power stations, sea water desalination shipbuilding, electric power, ocean engineering and the like. Tantalum also has very excellent chemical properties and has very high corrosion resistance. No matter the reaction is carried out on hydrochloric acid, concentrated nitric acid and aqua regia under the cold and hot conditions. Tantalum was immersed in 200 ℃ sulfuric acid for one year with the surface layer damaged only by 0.006 mm. However, the disadvantage is the relatively high cost, which is particularly the problem when used as a structural component. When tantalum is directly compounded with steel, brittle and hard intermetallic compounds are easily formed, and the bonding strength of the composite board is reduced.
Disclosure of Invention
Aiming at the problems, the invention provides an explosion compounding method of a tantalum-titanium-steel secondary explosion composite board, titanium is selected as a transition layer of the tantalum-steel composite board, and a novel explosion compounding mode is adopted, namely, titanium steel is firstly explosion compounded and then tantalum titanium steel is explosion compounded, so that the technical problem that rare metal is required to be processed by production design in the manufacturing of three-layer metal compounding equipment of tantalum, titanium or titanium alloy and steel is solved.
In order to achieve the above purpose, the invention provides an explosion composite method of a tantalum-titanium-steel secondary explosion composite board, which comprises the following steps:
s1, performing size cutting on a carbon steel plate, a titanium plate and a tantalum plate to enable the thickness of the composite tantalum plate and the titanium plate to be 3mm, and enabling the thickness of the carbon steel plate to be 20 mm;
s2, polishing the surface to be compounded of the steel plate, the two surfaces of the titanium plate and the surface to be compounded of the tantalum plate;
s3, placing the steel plate on a foundation;
s4, placing the supports with the thickness of 14mm on the steel plate, wherein the distance between every two adjacent supports in each row and each column is 300mm;
s5, placing the titanium plate on a support;
s6, laying an explosive layer on the titanium plate, wherein the thickness of the explosive is 35+/-1 mm;
s7, placing a detonator in the center of the explosive, and performing first-time explosion composite operation on the titanium plate-carbon steel plate;
s8, placing the supports with the thickness of 14mm on the titanium steel composite plate, wherein the distance between every two adjacent supports in each row and each column is 300mm;
s9, placing the tantalum plate on a support;
s10, laying an explosive layer on a tantalum plate, wherein the thickness of the explosive is 35+/-1 mm;
s11, placing the detonator in the center of the explosive, and performing tantalum-titanium steel secondary explosion composite operation.
Preferably, the test panel specifications (3+3+20) ×500×500=2, in mm.
Preferably, the explosive is selected from 2# rock emulsion explosive.
Preferably, the detonation velocity vd=2300 m/s to 2500m/s.
Preferably, the primary explosion and the secondary explosion of the first test plate are both in a central initiation mode, the primary explosion and the secondary explosion of the second test plate are both in an edge central initiation mode, and the two explosion initiation points of each test plate are controlled at the same position.
The binding rate and the shearing strength of the tantalum-titanium-steel explosion composite board meet the requirements of the standard of ASTMB898 active and refractory metal composite board, meet the development needs of industries such as domestic chemical industry and the like, reach the binding rate of more than 99 percent, and have the minimum shearing strength of more than or equal to 140mpa. The tantalum-titanium steel composite board produced by adopting the explosion compounding method has the corrosion resistance of tantalum and the strength and plasticity of a common steel plate as a structural member, so that the cost is greatly reduced, and the application field of the tantalum-titanium steel composite board material is continuously widened along with the continuous progress of the equipment manufacturing technology in China.
Drawings
FIG. 1 is a schematic diagram of explosive cladding of a titanium plate with a steel plate;
FIG. 2 is an explosive composition diagram of a tantalum plate and an explosive-compounded titanium steel composite plate.
Wherein, 1, foundation, 2, steel plate, 3, titanium plate, 4, tantalum plate, 5, support, 6, explosive, 7, detonator, 8, titanium steel composite board.
Detailed Description
Examples:
an explosion compounding method of a tantalum-titanium-steel secondary explosion composite board comprises the following steps:
s1, performing size cutting on a carbon steel plate, a titanium plate and a tantalum plate to enable the thickness of the composite tantalum plate and the titanium plate to be 3mm, and enabling the thickness of the carbon steel plate to be 20 mm;
s2, polishing the surface to be compounded of the steel plate, the two surfaces of the titanium plate and the surface to be compounded of the tantalum plate;
s3, placing the steel plate on a foundation;
s4, placing the supports with the thickness of 14mm on the steel plate, wherein the distance between every two adjacent supports in each row and each column is 300mm;
s5, placing the titanium plate on a support;
s6, laying an explosive layer on the titanium plate, wherein the thickness of the explosive is 35+/-1 mm;
s7, placing a detonator in the center of the explosive, and performing first-time explosion composite operation on the titanium plate-carbon steel plate;
s8, placing the supports with the thickness of 14mm on the titanium steel composite plate, wherein the distance between every two adjacent supports in each row and each column is 300mm;
s9, placing the tantalum plate on a support;
s10, laying an explosive layer on a tantalum plate, wherein the thickness of the explosive is 35+/-1 mm;
s11, placing the detonator in the center of the explosive, and performing tantalum-titanium steel secondary explosion composite operation.
Preferably, the test panel specifications (3+3+20) ×500×500=2, in mm.
Preferably, the explosive is selected from 2# rock emulsion explosive.
Preferably, the detonation velocity vd=2300 m/s to 2500m/s.
Preferably, the primary explosion and the secondary explosion of the first test plate are both in a central initiation mode, the primary explosion and the secondary explosion of the second test plate are both in an edge central initiation mode, and the two explosion initiation points of each test plate are controlled at the same position.
An explosive cladding method of the tantalum-titanium-steel secondary explosive clad plate will be further described with reference to the accompanying drawings.
1. Early preparation
(1) Cutting the carbon steel plate, the titanium plate and the tantalum plate according to the requirement, wherein the thickness of the composite tantalum plate and the titanium plate is 3mm, the thickness of the carbon steel plate is 20mm, and the specification of the test plate is (3+3+20) multiplied by 500 multiplied by 500=2;
wherein (3+3+20) ×500×500=2 means that the test boards are 2 pieces, and each test board has a specification of (3+3+20) ×500×500, in mm.
(2) Polishing the surface to be compounded of the steel plate, the two surfaces of the titanium plate and the surface to be compounded of the tantalum plate by using a kiloimpeller, wherein the surface finish reaches a delivery state;
(3) 2# rock emulsion explosive is selected as the main explosive;
(4) The titanium-steel explosion composite support is a support with the thickness of 14mm, and the tantalum-titanium steel explosion composite support is a support with the thickness of 14 mm;
(5) The medicine thickness H=35+/-1 mm, the detonation velocity Vd=2300 m/s-2500 m/s;
(6) The detonation mode is as follows: the primary explosion and the secondary explosion of the first test board adopt a central initiation mode; the primary explosion and the secondary explosion of the second test plate are respectively in an edge central detonating mode, and the two explosion detonating points of each test plate are controlled at the same position.
2. Detailed description of the preferred embodiments
(1) Leveling the foundation, filling ore powder, removing stones, and tamping the foundation;
(2) The steel plate is placed on the foundation, and redundant soil around the steel plate and on the upper surface of the steel plate is removed, so that the composite surface of the steel plate is kept clean;
(3) Uniformly placing the supports with the thickness of 14mm on the steel plate, wherein the distance between every two adjacent supports in each row and each column is 300mm;
(4) Cleaning the upper and lower surfaces of the titanium plate, and placing the titanium plate on a paved support;
(5) Laying an explosive layer on the titanium plate, and laying a 2# rock emulsion explosive, wherein the thickness of the explosive is 35+/-1 mm;
(6) Placing a detonator in the center of the 2# rock emulsion explosive, and performing one-time explosion composite operation of the titanium plate and the carbon steel plate, as shown in fig. 1;
(7) Cleaning the upper surface of the explosive-compounded titanium steel composite plate;
(8) Uniformly placing a support with the thickness of 14mm on a titanium steel plate;
(9) Cleaning the upper and lower surfaces of the tantalum plate, and placing the tantalum plate on a support;
(10) Laying an explosive layer on the tantalum plate, and laying a 2# rock emulsion explosive, wherein the thickness of the explosive is 35+/-1 mm;
(11) And (3) placing the detonator in the center of the No. 2 rock emulsion explosive, and performing tantalum-titanium steel secondary explosion composite operation, as shown in fig. 2.
3. Effect and performance contrast after explosive compounding
(1) Adopting an edge center detonating mode, and generating large-area non-bonded areas around after flaw detection, wherein the shearing strength of the composite board is 135Mpa and 141Mpa;
(2) The center detonation mode is adopted, flaw detection after explosion is good, the non-bonding range of the boundary is less than or equal to 50mm, and the shearing strength of the composite board is 189Mpa and 223Mpa;
(3) Therefore, a central explosion mode is adopted to simulate a product plate (3+3+40) ×800×800=1, the medicine thickness is 35+/-1 mm, the thickness of a support is 14mm, and the explosion speed Vd=2300 m/s-2500 m/s; post-explosion flaw detection condition: the positions except the center position of the detonating point are about 50 multiplied by 50 and are not attached, and other positions are good;
wherein (3+3+40) ×800×800=1 means that the product board is 1 block, and the specification is (3+3+40) ×800×800, unit mm;
(4) Then explosion is conducted to compound a 800 multiplied by 800 product plate, other parameters are the same, and the explosion speed Vd=2600 m/s-2800 m/s; post-explosion flaw detection condition: the periphery and the surface of the plate are provided with more non-bonding areas, and the surface of the composite plate is provided with cracks;
4. preliminary conclusion
The tantalum titanium steel composite board is welded by explosion, low-explosion-speed explosive is selected, and a central explosion composite mode is adopted. Comparative example:
an explosion composite method of a tantalum-titanium-steel direct explosion composite board comprises the following specific steps:
1. early preparation
(1) Cutting the carbon steel plate, the titanium plate and the tantalum plate according to the requirement, wherein the thickness of the composite tantalum plate and the titanium plate is 3mm, the thickness of the carbon steel plate is 20mm, and the specification of the test plate is (3+3+20) multiplied by 500 multiplied by 500=2;
wherein (3+3+20) ×500×500=2 means that the test boards are 2, and each test board has a specification of (3+3+20) ×500×500, in mm.
(2) Polishing the surface to be compounded of the steel plate, the two surfaces of the titanium plate and the surface to be compounded of the tantalum plate by using a kiloimpeller, wherein the surface finish reaches a delivery state;
(3) 2# rock emulsion explosive is selected as the main explosive;
(4) The titanium-steel explosion composite support is a support with the thickness of 14mm, and the tantalum-titanium steel explosion composite support is a support with the thickness of 14 mm;
(5) The medicine thickness H=35+/-1 mm, the detonation velocity Vd=2300 m/s-2500 m/s;
(6) Adopting a central detonating mode;
2. detailed description of the preferred embodiments
(1) Leveling the foundation, filling ore powder, removing stones, and tamping the foundation;
(2) The steel plate is placed on the foundation, and redundant soil around the steel plate and on the upper surface of the steel plate is removed, so that the composite surface of the steel plate is kept clean;
(3) Uniformly placing supports with the thickness of 14mm on the carbon steel plate, wherein the distance between two adjacent supports in each row and each column is 300mm;
(4) Cleaning the upper and lower surfaces of the titanium plate, and placing the titanium plate on a paved support;
(5) Uniformly placing a support with the thickness of 14mm on a titanium steel plate;
(6) Cleaning the upper and lower surfaces of the tantalum plate, and placing the tantalum plate on a support on the titanium plate;
(7) Laying an explosive layer on the tantalum plate, and laying a 2# rock emulsion explosive, wherein the thickness of the explosive is 35+/-1 mm;
(8) And (3) placing the detonator in the center of the 2# rock emulsion explosive, and performing direct explosion compounding on tantalum, titanium and steel.
Conclusion: stretching, shearing, coloring and penetrating inspection and ultrasonic flaw detection are carried out according to the standard of ASTMB898 active and refractory metal composite plate;
the tantalum titanium steel composite board subjected to explosion compounding by adopting a direct explosion compounding mode has fine cracks around, a large-area non-lamination area appears on the surface of the flaw detection board, and the shearing strength is 128Mpa and 138Mpa. The tantalum titanium steel composite board subjected to explosive cladding in a secondary explosive cladding mode has excellent performance, and the non-bonding scope of the boundary is well controlled, so that the tantalum titanium steel composite board can meet the standard requirements.
The thickness of the middle bonding layer of the composite board shows the bonding condition of the composite board, and the thickness of the middle bonding layer is mainly the kinetic energy loss in the movement process of the composite board, chemical energy generated by explosive explosion is converted into the kinetic energy of the composite board, and the kinetic energy of the composite board is correspondingly reduced during explosion and compounding. In the comparative example, explosion compounding is directly carried out, chemical energy released by the explosive is converted into kinetic energy of the tantalum plate, and when the kinetic energy of the tantalum plate reaches the titanium plate and the steel plate, the kinetic energy of the composite plate is reduced more, so that the thickness of a bonding layer between the titanium plate and the steel plate is thinner and the situation that the thickness of a bonding layer of a region is uneven occurs. In the embodiment, the explosion compounding is carried out twice, so that the kinetic energy of the compound plate can be fully exerted when the explosion compounding is carried out each time, and the thickness of the middle bonding layer of the compound plate is obviously better than that of the bonding layer when the explosion compounding is directly carried out each time. Through ultrasonic flaw detection, the composite board of secondary explosion complex is except boundary non-laminating region and detonating point, and non-laminating region is less, and the large tracts of land non-laminating region appears in the compound face of direct explosion. In the shearing test, the samples are respectively taken from the parts with better ultrasonic flaw detection laminating areas, and the bonding strength of the secondary explosion composite is obviously superior to that of the direct explosion composite.
The binding rate and the shearing strength of the tantalum-titanium-steel explosion composite board meet the requirements of the standard of ASTMB898 active and refractory metal composite board, meet the development needs of industries such as domestic chemical industry and the like, reach the binding rate of more than 99 percent, and have the minimum shearing strength of more than or equal to 140mpa. The tantalum-titanium steel composite board produced by adopting the explosion compounding method has the corrosion resistance of tantalum and the strength and plasticity of a common steel plate as a structural member, so that the cost is greatly reduced, and the application field of the tantalum-titanium steel composite board material is continuously widened along with the continuous progress of the equipment manufacturing technology in China.
The foregoing is only a preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art, who is within the scope of the present invention, should be covered by the protection scope of the present invention by making equivalents and modifications to the technical solution and the inventive concept thereof.

Claims (5)

1. The explosion composite method of the tantalum-titanium-steel secondary explosion composite plate is characterized by comprising the following steps of:
s1, performing size cutting on a carbon steel plate, a titanium plate and a tantalum plate to enable the thickness of the composite tantalum plate and the titanium plate to be 3mm, and enabling the thickness of the carbon steel plate to be 20 mm;
s2, polishing the surface to be compounded of the steel plate, the two surfaces of the titanium plate and the surface to be compounded of the tantalum plate;
s3, placing the steel plate on a foundation;
s4, placing the supports with the thickness of 14mm on the steel plate, wherein the distance between every two adjacent supports in each row and each column is 300mm;
s5, placing the titanium plate on a support;
s6, laying an explosive layer on the titanium plate, wherein the thickness of the explosive is 35+/-1 mm;
s7, placing a detonator in the center of the explosive, and performing first-time explosion composite operation on the titanium plate-carbon steel plate;
s8, placing the supports with the thickness of 14mm on the titanium steel composite plate, wherein the distance between every two adjacent supports in each row and each column is 300mm;
s9, placing the tantalum plate on a support;
s10, laying an explosive layer on a tantalum plate, wherein the thickness of the explosive is 35+/-1 mm;
s11, placing the detonator in the center of the explosive, and performing tantalum-titanium steel secondary explosion composite operation.
2. The explosive cladding method of tantalum-titanium-steel secondary explosive cladding board according to claim 1, wherein test board specification (3+3+20) ×500×500=2, unit mm.
3. The explosive cladding method of the tantalum-titanium-steel secondary explosive composite board according to claim 1, wherein the explosive is 2# rock emulsion explosive.
4. The explosive cladding method of a tantalum-titanium-steel secondary explosive cladding plate according to claim 1, wherein the explosion velocity vd=2300 m/s to 2500m/s.
5. The explosion compounding method of the tantalum-titanium-steel secondary explosion composite board is characterized in that the primary explosion and the secondary explosion of the first test board adopt a central detonation mode, the primary explosion and the secondary explosion of the second test board adopt an edge central detonation mode, and the two explosion detonating points of each board are controlled at the same position.
CN202410108510.4A 2024-01-26 2024-01-26 Explosion compounding method of tantalum-titanium-steel secondary explosion composite board Pending CN117862659A (en)

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CN202410108510.4A CN117862659A (en) 2024-01-26 2024-01-26 Explosion compounding method of tantalum-titanium-steel secondary explosion composite board

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CN202410108510.4A CN117862659A (en) 2024-01-26 2024-01-26 Explosion compounding method of tantalum-titanium-steel secondary explosion composite board

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