CN117798503A - Application of laser texturing to enhance surface bonding of metal and adhesive layers - Google Patents
Application of laser texturing to enhance surface bonding of metal and adhesive layers Download PDFInfo
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- CN117798503A CN117798503A CN202311834893.5A CN202311834893A CN117798503A CN 117798503 A CN117798503 A CN 117798503A CN 202311834893 A CN202311834893 A CN 202311834893A CN 117798503 A CN117798503 A CN 117798503A
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- poe
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- 239000002184 metal Substances 0.000 title claims abstract description 47
- 239000012790 adhesive layer Substances 0.000 title claims abstract description 33
- 239000007769 metal material Substances 0.000 claims abstract description 90
- 239000004814 polyurethane Substances 0.000 claims abstract description 33
- 229920002635 polyurethane Polymers 0.000 claims abstract description 33
- 239000000463 material Substances 0.000 claims abstract description 17
- 239000010410 layer Substances 0.000 claims description 23
- 239000003292 glue Substances 0.000 claims description 18
- 239000002033 PVDF binder Substances 0.000 claims description 15
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 15
- 238000003475 lamination Methods 0.000 claims description 11
- 239000011521 glass Substances 0.000 claims description 10
- 229920003023 plastic Polymers 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 abstract description 54
- 238000004381 surface treatment Methods 0.000 abstract description 35
- 238000007788 roughening Methods 0.000 abstract description 12
- 230000001965 increasing effect Effects 0.000 abstract description 5
- 230000003746 surface roughness Effects 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 56
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 54
- 239000004809 Teflon Substances 0.000 description 11
- 229920006362 Teflon® Polymers 0.000 description 11
- 230000000694 effects Effects 0.000 description 9
- 238000005070 sampling Methods 0.000 description 9
- 238000009832 plasma treatment Methods 0.000 description 7
- 230000007613 environmental effect Effects 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 238000005096 rolling process Methods 0.000 description 5
- 238000005488 sandblasting Methods 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 239000005341 toughened glass Substances 0.000 description 4
- 238000012790 confirmation Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 239000002313 adhesive film Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000009863 impact test Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 239000012968 metallocene catalyst Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
The invention belongs to the field of metal material bonding, and particularly relates to application of laser texturing to surface bonding of reinforced metal and adhesive layers (such as POE and polyurethane). Compared with the prior material surface treatment, the method greatly increases the surface tension of the metal material by carrying out surface treatment (laser texturing) on the metal material, thereby increasing the binding force between the material surface and the adhesive layer; compared with the prior material surface treatment, the surface roughness of the metal material is improved by adopting the surface treatment (laser roughening), so that the adhesive layer can be further permeated on the surface of the metal material after being melted at high temperature, and the bonding force between the adhesive layer and the adhesive layer is enhanced; the invention adopts the surface treatment (laser texturing) method, can increase the viscosity of the surface of the metal material and the adhesive layer, and does not have the risk of layering.
Description
Technical Field
The invention belongs to the field of metal material bonding, and particularly relates to application of laser texturing in reinforcing metal and adhesive layer surface bonding.
Background
With the rapid development of society, the requirements on the surface of materials are higher and higher due to the complexity of the product processing technology, and the surface treatment (laser texturing) takes a crucial place in order to improve the viscosity of the surface of the materials.
With the development of new energy industry at present, the bonding force between a metal material and a glue layer (such as POE plastic or polyurethane, wherein POE plastic is a thermoplastic elastomer which adopts ethylene and octene of a metallocene catalyst to realize in-situ polymerization) is also a focus, the current industry needs to test the viscosity between the surface of the metal material and the glue layer, and the metal material and the glue layer are as follows: the material is stuck on a corresponding object to be stuck for corresponding test, a 180-degree stripping force or a push-out test method is generally adopted, a certain force value standard range is set, but the test result is lower than the labeling range, and the performance of the product is greatly influenced.
The traditional surface treatment process of the metal material has corona treatment and plasma treatment, but the test effect is not ideal.
Disclosure of Invention
With the complexity of the processing technology of the product, the requirement on the surface of the material is higher, the viscosity between the metal surface and the adhesive layer is lower, the performance of the product can be affected to a certain extent, aiming at the adhesion of the existing metal material and the adhesive layer, the invention discloses a laser roughening technology of the metal surface, which is a scanning processing of the metal surface through high energy and high focusing performance of a laser technology, the technology greatly increases the roughness of the surface of the metal material, and the metal material can be ensured to be completely adhered to the adhesive layer.
In order to solve the technical problems, the invention develops a method (laser texturing) of a surface treatment process to enhance the viscosity of a metal material and a glue layer, wherein the laser texturing is one of the processes of the surface treatment of the metal material, in the laser texturing process of the metal surface, a laser beam is irradiated on the metal material surface, and the roughness and the adhesive capability of the metal material surface are enhanced by adjusting parameters such as laser energy, line spacing, power, scanning speed and the like.
The application provides the following technical scheme:
the invention provides an application of laser texturing in enhancing the surface combination of metal and a glue layer, which comprises the following steps:
s1: laser texturing the surface of the metal material; the parameters of the laser texturing are as follows: the laser speed is 5000-8000mm/min, the line spacing is 0.2-0.4mm, and the power is 6-15%;
s2: covering the surface of the metal material subjected to laser texturing in the step S1 with a layer of adhesive layer respectively;
s3: and (3) carrying out vacuum lamination on the adhesive layer and the metal material in the step S2, and finishing the surface combination of the metal and the adhesive layer.
In the step S1, a ZX-30W laser machine is used for laser texturing, wherein the model is Suzhou Deliver card photoelectric technology Co.
Preferably, the adhesive layer is POE plastic or polyurethane adhesive film.
Preferably, in the step S2, the surface of the top of the metal material is covered with a glue layer and other material layers in sequence.
Preferably, in the step S3, the temperature of vacuum lamination is 80-170 ℃.
Preferably, in the step S3, the time of vacuum lamination is 50-600S.
Preferably, in the step S3, the laminate is allowed to stand at room temperature (25.+ -. 5 ℃ C.) for 4 hours or more after vacuum lamination.
Preferably, in the step S3, the vacuum lamination pressure is 0.1 to 0.3MPa.
Preferably, the other material layer is polyvinylidene fluoride (PVDF) or ink glass.
Compared with the prior art, the technical scheme of the invention has the following advantages:
1. by carrying out surface treatment (laser texturing) on the metal material, compared with the material before the surface treatment, the method greatly increases the surface tension of the metal material, thereby increasing the binding force between the surface of the material and the adhesive layer;
2. the surface treatment (laser roughening) is adopted, compared with the surface treatment before the material surface treatment, the surface roughness of the metal material is improved, the glue layer can be further permeated on the surface of the metal material after being melted at high temperature, and the binding force between the glue layer and the glue layer is enhanced;
3. by adopting the surface treatment (laser texturing) method, the viscosity between the surface of the metal material and the adhesive layer can be increased, and the risk of delamination does not occur.
Drawings
Fig. 1 is a drawing showing a step of placing tempered glass.
Fig. 2 is a POE placement step diagram.
Fig. 3 is a metal material placement step diagram.
Fig. 4 is a view of the teflon tape fixing step.
FIG. 5 is a view of PVDF placement step.
Fig. 6 is a material scribing step diagram.
Fig. 7 is a drawing force test procedure diagram.
Fig. 8 is a drawing force test chart.
Detailed Description
The present invention will be further described with reference to the accompanying drawings and specific examples, which are not intended to be limiting, so that those skilled in the art will better understand the invention and practice it.
1. Adhesion of POE to metal
In the following examples, the adhesion and test process of POE and metal are as follows:
1. placing a piece of toughened glass on a table top, cleaning the surface of the toughened glass by using pure IPA and dust-free cloth, and standing for 3-5 minutes until the IPA is completely volatilized; as in fig. 1.
2. Cutting two POEs with the size of A4, and placing one POE on the surface of toughened glass; as in fig. 2.
3. Placing a metal material (30 mm x 60 mm) on POE; as in fig. 3.
4. A piece of Teflon adhesive tape (30 mm is 50 mm) is taken and stuck to the lower end of the metal material at the position of 10-15 mm; as in fig. 4.
5. Covering another POE on the metal material, and aligning the POE with the four sides of the lower POE;
6. taking a piece of PVDF with the size of A4, placing the PVDF at the upper end of POE, and aligning with four sides of the POE; as in fig. 5.
7. Vacuum lamination of the samples (temperature: 160 ℃, time: 900S);
8. taking out the sample, and standing for more than 4H at normal temperature;
9. drawing a strip of PVDF with the width of 10mm at the position with the metal material by using a blade; as in fig. 6.
10. Pulling up the initial section of the sample at the location of the teflon tape; as shown in fig. 7.
11. Opening the drawing force testing machine, setting the speed to be 50mm/min, and fixing the sample on a tension machine bracket; fixing the initial end of the pulled sample on an upper clamp of a drawing force testing machine, starting the drawing force testing machine, and starting the test; as in fig. 8.
Example 1 selection of surface treatment Process
Respectively testing the stripping force of 3 (A initial, B corona and C plasma treatment) surface treatment processes by using a drawing force tester, wherein each process corresponds to 5 groups of data of each metal material, and the temperature and the humidity of the stripping force test are kept consistent, namely the humidity is 50RH and the temperature is 25 ℃ in order to eliminate the influence of environmental factors on experimental results; the test sample size is 30mm 60mm, in order to eliminate the viscosity between the surface of the metal material corresponding to different processes and POE, the test sample is placed on the same equipment for testing after the sample is prepared ok, the peeling force test speed is 50mm/min, the vacuum time is 900s, the temperature is 160 ℃, and the pressure is 0.2Mpa;
a sample: POE, 30mm x 60mm samples were placed on glass; metal material (initial), 30mm sample 60mm on POE; a teflon tape, 10mm x 30mm, was attached to the end of the metal material (initial); POE samples 30mm x 60mm were placed on the metallic material (initial); PVDF, 30mm x 150mm samples were placed on POE;
sample B: POE, 30mm x 60mm samples were placed on glass; metal material (corona), 30mm sample 60mm on POE; a teflon tape, 10mm by 30mm, was attached to the end of the metal material (corona); POE samples 30mm x 60mm were placed on metallic material (corona); PVDF, 30mm x 150mm samples were placed on POE.
C sample: POE, 30mm x 60mm samples were placed on glass; metal material (plasma treatment), 30mm by 60mm samples were placed on POE; a teflon tape, 10mm by 30mm, is attached to the end of the metal material (plasma treatment); POE samples 30mm x 60mm were placed on metallic material (plasma treatment); PVDF, 30mm x 150mm samples were placed on POE.
Example 2
Respectively testing the stripping force of 3 (D laser texturing, E sand blasting and F rolling) surface treatment processes by using a drawing force tester, wherein each process corresponds to 5 groups of data of the metal material, and the temperature and the humidity of the stripping force test are kept consistent, namely the humidity is 50RH and 25 ℃ in order to eliminate the influence of environmental factors on experimental results; the test sample size is 30mm 60mm, in order to eliminate the direct adhesion between the surface of the metal material corresponding to different processes and TPO, the test sample is placed on the same equipment for testing after the sample is prepared ok, the peeling force test speed is 50mm/min, the vacuum time is 900s, the temperature is 160 ℃, and the pressure is 0.2Mpa.
D sample: POE samples 30mm x 60mm were placed on glass; metal material (laser roughened), sampled 30mm x 60mm on POE; a teflon tape, 10mm by 30mm, is attached to the end of the metal material (laser roughened); POE samples 30mm x 60mm were placed on metallic material (laser roughened); PVDF, 30mm x 150mm samples were placed on POE.
E sample: POE samples 30mm x 60mm were placed on glass; metal material (sandblasted), sampled 30mm 60mm on POE; a teflon tape, 10mm by 30mm, was attached to the end of the metal material (sandblasted); POE samples 30mm x 60mm were placed on metallic material (grit blasted); PVDF, 30mm x 150mm samples were placed on POE.
F, sample: POE samples 30mm x 60mm were placed on glass; metal material (rolling), sample 30mm 60mm on POE; a teflon tape, 10mm by 30mm, is attached to the end of the metal material (rolling); POE samples 30mm x 60mm were placed on metallic material (roll-pressed); PVDF, 30mm x 150mm samples were placed on POE.
Table 1 experimental data for each sample example 1 and example 2
From the above 6 surface treatment process data, it can be concluded that:
(1) The laser roughening process for treating the metal surface is far greater than the traditional surface treatment method, sand blasting, corona and other processes;
(2) The laser roughening process can increase the roughness of the material surface by treating the metal surface, so that the binding force between the metal surface and POE is increased;
by comparing the 5 metal surface treatment processes, the laser roughening process is superior to other four processes, so that the laser roughening process is selected in the embodiment 3 to increase the binding force between the metal surface and POE; therefore, the confirmation of laser speed, line spacing and power becomes important; the laser texturing equipment is 30W power, and the bonding force between the metal surface and POE under different parameters is tested by selecting different laser speeds, line spacing and powers and using a drawing force tester.
Example 3 confirmation of laser texturing parameters for Metal surfaces
Respectively testing the stripping force of 2 (laser texturing treatment and laser texturing treatment) surface treatment processes by using a drawing force tester, wherein each process corresponds to 5 groups of data of the metal material, and the temperature and the humidity of the stripping force test are kept consistent, namely the humidity is 50RH and the temperature is 25 ℃ in order to eliminate the influence of environmental factors on experimental results; the test sample size is 30mm 60mm, in order to eliminate the viscosity between the surface of the metal material corresponding to different processes and POE, the test sample is placed on the same equipment for testing after the sample is prepared ok, the peeling force test speed is 50mm/min, the vacuum time is 900S, the temperature is 160 ℃, and the pressure is 0.2Mpa;
a sample: POE samples 30mm x 60mm were placed on glass; metal material (without laser texturing), 30mm sample 60mm was placed on POE; a teflon tape, 10mm by 30mm, was attached to the end of the metal material (without laser texturing); POE samples 30mm x 60mm were placed on metallic material (not laser roughened); PVDF, 30mm x 150mm samples were placed on POE;
sample B: POE samples 30mm 60mm, put on glass; metal material (laser texturing treatment), sampling 30mm by 60mm and placing on POE; a teflon tape, 10mm by 30mm, is attached to the end of the metal material (laser texturing treatment); POE samples 30mm x 60mm were placed on metallic material (laser texturing); PVDF, 30mm x 150mm samples were placed on POE (see table 2 for specific laser speeds, line spacing, power).
Effect evaluation 1
Table 2 effect of surface treatment process on peel force in example 3
In summary, the above 8 parameters can be chosen to conclude:
(1) Laser speed: 8000mm/min, line spacing: 0.4mm, power: 6% has the best effect on metal surface treatment and the best binding force with POE;
(2) The treatment effects of different parameters on the metal surface are different, so that the most suitable parameters are selected to be applied to the project of the user after multiple experimental tests.
TABLE 3 impact test of surface treatment process on peel force
To sum up:
(1) The bonding force between the surface and POE can be greatly improved by carrying out laser texturing treatment on the metal surface;
(2) The laser texturing treatment process under different parameters has difference on the binding force between the metal surface and POE, so that the metal surface is determined by multiple experimental tests.
2. Adhesion of polyurethane to metal
In the following examples, the adhesion between polyurethane and metal and the test procedure were as follows:
1. the adhesive film was cut into square coupons 10mm wide.
2. And placing the cut polyurethane sample on the surface of the metal material.
3. The metal material and polyurethane coupon were heated to: pre-bonding is carried out at 40-70 ℃ and under the pressure of 0.1-0.3MPa for 5-30 s.
4. And placing the object to be stuck on the other side of the glue layer on the other side of the pre-stuck glue layer.
5. Sample piece was set at temperature: final lamination is carried out at 80-120 ℃ and 0.3-0.5MPa for 30-90 s;
6. taking out the sample, and standing for more than 4H at normal temperature;
7. and opening the push-out force testing machine, setting the speed to be 10mm/min, fixing the sample on a support of the pushing machine, starting the pushing force testing machine, and starting the test.
Example 4 selection of surface treatment Process
Respectively testing the push-out force of 3 (A initial, B corona and C plasma treatment) surface treatment processes by using a thrust tester, wherein 5 groups of data are respectively tested on the metal materials corresponding to each process, and the temperature and the humidity of the peeling force test are kept consistent, namely the humidity is 50RH and the temperature is 25 ℃ in order to eliminate the influence of environmental factors on experimental results; the sizes of the tested samples are 10mm and 10mm, in order to eliminate the viscosity between the surfaces of the metal materials corresponding to different processes and polyurethane, the samples are placed on the same equipment for testing after ok, and the push-out force testing speed is 10mm/min;
a sample: polyurethane, sampling 10mm, placing 10mm on a metal material (initial), pre-attaching the metal material and a polyurethane sample wafer, placing an object attached to the other side of the adhesive layer on the other side of the pre-attached adhesive layer for final attaching, taking out the sample, standing at normal temperature for more than 4H, and testing;
sample B: polyurethane, sampling 10mm, placing 10mm on a metal material (corona), pre-attaching the metal material and a polyurethane sample piece, placing an object attached to the other side of the adhesive layer on the other side of the pre-attached adhesive layer for final attaching, taking out the sample, standing at normal temperature for more than 4H, and testing;
c sample: polyurethane, sampling 10mm, placing 10mm on a metal material (plasma treatment), pre-attaching the metal material and a polyurethane sample wafer, placing an object attached to the other side of the glue layer on the other side of the pre-attached glue layer for final attaching, taking out the sample, standing at normal temperature for more than 4H, and testing;
example 5
Respectively testing the stripping force of 3 (D laser texturing, E sand blasting and F rolling) surface treatment processes by using a push-out force tester, wherein 5 groups of data are respectively tested on the metal materials corresponding to each process, and the temperature and the humidity of the stripping force test are kept consistent, namely the humidity is 50RH and the temperature is 25 ℃ in order to eliminate the influence of environmental factors on experimental results; the test sample size is 10mm, in order to eliminate the direct adhesion between the surface of the metal material corresponding to different processes and polyurethane, the test sample is placed on the same equipment for testing after sample preparation ok, and the peeling force test speed is 10mm/min.
D sample: polyurethane, sampling 10mm, placing 10mm on a metal material (laser texturing), pre-attaching the metal material and a polyurethane sample wafer, placing an object attached to the other side of the adhesive layer on the other side of the pre-attached adhesive layer for final attaching, taking out the sample, standing at normal temperature for more than 4H, and testing;
e sample: polyurethane, sampling 10mm, placing 10mm on a metal material (sand blasting), pre-attaching the metal material and a polyurethane sample wafer, placing an object attached to the other side of the adhesive layer on the other side of the pre-attached adhesive layer for final attaching, taking out the sample, standing at normal temperature for more than 4H, and testing;
f, sample: polyurethane, sampling 10mm, placing 10mm on a metal material (rolling), pre-attaching the metal material and a polyurethane sample piece, placing an attached object on the other side of the adhesive layer on the other side of the pre-attached adhesive layer for final attaching, taking out the sample, standing at normal temperature for more than 4H, and testing.
Table 4 experimental data for each of samples example 4 and example 5
From the above 6 surface treatment process data, it can be concluded that:
(1) The laser roughening process for treating the metal surface is far greater than the traditional surface treatment method, sand blasting, corona and other processes;
(2) The laser roughening process can increase the roughness of the material surface by treating the metal surface, thereby increasing the binding force between the metal surface and polyurethane;
by comparing the 5 metal surface treatment processes, the laser roughening process is superior to other four processes, so the laser roughening process is selected in the embodiment 6 to increase the binding force between the metal surface and polyurethane; therefore, the confirmation of laser speed, line spacing and power becomes important; the laser texturing equipment is 30W power, and the bonding force between the metal surface and polyurethane under different parameters is tested by selecting different laser speeds, line spacing and powers and using a drawing force tester.
Example 6 influence of laser texturing parameters on Metal surfaces
Respectively testing the stripping force of 2 (no laser texturing treatment and laser texturing treatment) surface treatment processes by using a push-out force tester, wherein each metal material corresponding to each process is respectively tested for 5 groups of data, and the temperature and the humidity of the stripping force test are kept consistent, namely the humidity is 50RH and the temperature is 25 ℃ in order to eliminate the influence of environmental factors on experimental results; the sizes of the tested samples are 10mm and 10mm, and in order to eliminate the viscosity between the surfaces of the metal materials corresponding to different processes and polyurethane, the samples are placed on the same equipment for testing after the sample preparation is completed;
a sample: sampling polyurethane, namely placing 10mm on a metal material (without laser roughening treatment), pre-attaching the metal material and a polyurethane sample piece, placing an attached object on the other side of the adhesive layer on the other side of the pre-attached adhesive layer for final attaching, taking out the sample, standing at normal temperature for more than 4H, and testing;
sample B: sampling polyurethane, namely placing 10mm on a metal material (laser texturing treatment), pre-attaching the metal material and a polyurethane sample piece, placing an attached object on the other side of the glue layer on the other side of the pre-attached glue layer for final attaching, taking out the sample, standing at normal temperature for more than 4H, and testing; (see Table 5 for specific laser speeds, line spacing, power).
Effect evaluation 2
TABLE 5 Effect of surface treatment Process on peel force in example 6
In summary, the above 8 parameters can be chosen to conclude:
(1) Laser speed: 8000mm/min, line spacing: 0.4mm, power: 6% has the best effect on metal surface treatment and the best binding force with polyurethane;
(2) The treatment effects of different parameters on the metal surface are different, so that the most suitable parameters are selected to be applied to the project of the user after multiple experimental tests.
TABLE 6 impact test of surface treatment process on peel force
To sum up:
(1) The bonding force between the surface and polyurethane can be greatly improved by carrying out laser texturing treatment on the metal surface;
(2) The laser texturing treatment process under different parameters has difference on the binding force between the metal surface and polyurethane, so that the metal surface is determined by multiple experimental tests.
It is apparent that the above examples are given by way of illustration only and are not limiting of the embodiments. Other variations and modifications of the present invention will be apparent to those of ordinary skill in the art in light of the foregoing description. It is not necessary here nor is it exhaustive of all embodiments. And obvious variations or modifications thereof are contemplated as falling within the scope of the present invention.
Claims (8)
1. The application of laser texturing to enhance the bonding of metal and bondline surfaces is characterized by comprising the steps of:
s1: laser texturing the surface of the metal material; the parameters of the laser texturing are as follows: the laser speed is 5000-8000mm/min, the line spacing is 0.2-0.4mm, and the power is 6-15%;
s2: covering the surface of the metal material subjected to laser texturing in the step S1 with a layer of adhesive layer;
s3: and (3) carrying out vacuum lamination on the metal material with the two sides covered with the adhesive layer in the step (S2) to finish the surface combination of the metal and the adhesive layer.
2. The use of laser texturing as claimed in claim 1 to enhance bonding of metal and bondline surfaces, wherein in step S2 the surface of the top of the metal material is covered in sequence with a bondline and other layers of material.
3. Use of laser texturing as claimed in claim 1 to enhance the bonding of metal to the surface of a glue layer, wherein the glue layer is POE plastic or polyurethane glue film.
4. The use of laser texturing as claimed in claim 1 to enhance the bonding of metal and bondline surfaces, wherein in step S3 the vacuum lamination is carried out at a temperature of 80-170 ℃.
5. The use of laser texturing as claimed in claim 1 to enhance bonding of metal and bondline surfaces, wherein in step S3, the vacuum lamination is for a period of time of 50 to 600S.
6. The use of laser texturing as claimed in claim 1 to enhance the bonding of metal and bondline surfaces, wherein in step S3, the laminate is vacuum laminated and then left at room temperature for more than 4 hours.
7. The use of laser texturing as claimed in claim 1 to enhance the bonding of metal and bondline surfaces, wherein in step S3 the vacuum lamination is carried out at a pressure of 0.1-0.3MPa.
8. The use of laser texturing as claimed in claim 1 to enhance bonding of metal and bondline surfaces, wherein said other material layer is polyvinylidene fluoride or ink glass.
Applications Claiming Priority (2)
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CN202311593640 | 2023-11-27 | ||
CN2023115936403 | 2023-11-27 |
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