CN117771410A - Negative oxygen ion release liquid and preparation method and application thereof - Google Patents
Negative oxygen ion release liquid and preparation method and application thereof Download PDFInfo
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- CN117771410A CN117771410A CN202311822288.6A CN202311822288A CN117771410A CN 117771410 A CN117771410 A CN 117771410A CN 202311822288 A CN202311822288 A CN 202311822288A CN 117771410 A CN117771410 A CN 117771410A
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- negative oxygen
- oxygen ion
- release liquid
- ion release
- powder
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- 239000001301 oxygen Substances 0.000 title claims abstract description 94
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 94
- 239000007788 liquid Substances 0.000 title claims abstract description 52
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- -1 oxygen ion Chemical class 0.000 claims abstract description 101
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000000843 powder Substances 0.000 claims abstract description 30
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229940070527 tourmaline Drugs 0.000 claims abstract description 16
- 229910052613 tourmaline Inorganic materials 0.000 claims abstract description 16
- 239000011032 tourmaline Substances 0.000 claims abstract description 16
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims abstract description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229960005070 ascorbic acid Drugs 0.000 claims abstract description 13
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 13
- 239000001257 hydrogen Substances 0.000 claims abstract description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 12
- 239000007864 aqueous solution Substances 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 239000012279 sodium borohydride Substances 0.000 claims abstract description 10
- 229910000033 sodium borohydride Inorganic materials 0.000 claims abstract description 10
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims abstract description 9
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 13
- 239000002245 particle Substances 0.000 claims description 13
- 239000007789 gas Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 9
- 239000000243 solution Substances 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 241000894006 Bacteria Species 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- 239000000428 dust Substances 0.000 claims description 4
- 230000002411 adverse Effects 0.000 claims description 3
- 230000008859 change Effects 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 239000003344 environmental pollutant Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- 231100000719 pollutant Toxicity 0.000 claims description 3
- 230000001376 precipitating effect Effects 0.000 claims description 3
- 239000000779 smoke Substances 0.000 claims description 3
- 238000002791 soaking Methods 0.000 claims description 3
- 238000009210 therapy by ultrasound Methods 0.000 claims description 3
- 238000004887 air purification Methods 0.000 claims description 2
- 230000008030 elimination Effects 0.000 claims description 2
- 238000003379 elimination reaction Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 7
- 238000005507 spraying Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- 238000013401 experimental design Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 239000000443 aerosol Substances 0.000 description 3
- 241000700605 Viruses Species 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000003905 indoor air pollution Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
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- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
Abstract
The invention discloses a negative oxygen ion release liquid and a preparation method and application thereof, belongs to the technical field of negative oxygen ions, and aims to solve the problems that in the existing preparation method of the negative oxygen ion release liquid, the prepared negative oxygen ion release liquid is poor in stability, the service time of the negative oxygen ion release liquid is shortened, the dosage proportion of preparation raw materials is inaccurate, and the consistency of production of different batches is affected. The technical effects achieved are as follows: the mass ratio of the negative oxygen ion raw material alcohol aqueous solution, graphene oxide, citric acid, vitamin c, hydrazine hydrate, sodium borohydride and tourmaline powder is accurately controlled through experimental design, so that the stability and consistency of the negative oxygen ion release liquid in different batches can be ensured, the effect time of the negative oxygen ion release liquid can be prolonged by controlling the concentration and proportion of generated hydrogen ions, the pH value of the formula proportion of the negative oxygen ion release liquid is controlled to be 5-6, the stability of the state of the negative oxygen ion release liquid is improved, and the negative oxygen ion release effect is exerted to the greatest extent.
Description
Technical Field
The invention relates to the technical field of negative oxygen ions, in particular to a negative oxygen ion release liquid and a preparation method and application thereof.
Background
With the improvement of living standard, indoor air pollution is more and more concerned, the concentration of negative ions in the air is one of the marks of good air quality, and the indoor air negative ions have low concentration, which is unfavorable for human health, so that a preparation method of the high-efficiency pollution-free negative oxygen ion release liquid suitable for purifying the indoor air is needed.
In the existing preparation method of the negative oxygen ion release liquid, the prepared negative oxygen ion release liquid is poor in stability, the negative oxygen ion release efficiency is affected, the service time of the negative oxygen ion release liquid is shortened, the dosage proportion of the prepared raw materials is inaccurate, and the consistency of production of different batches can be affected.
Disclosure of Invention
Therefore, the invention provides a negative oxygen ion release liquid, and a preparation method and application thereof, so as to solve the problems in the prior art.
In order to achieve the above object, the present invention provides the following technical solutions:
according to the first aspect of the invention, the raw material components of the negative oxygen ion release liquid comprise alcohol water solution, graphene oxide, citric acid, vitamin c, hydrazine hydrate, sodium borohydride and tourmaline powder, and the mass ratio of the alcohol water solution to the graphene oxide to the citric acid to the vitamin c is 100:0.5:1:2:2:0.1:5.
the preparation method of the negative oxygen ion release liquid comprises the following steps:
s1, adding negative oxygen ion powder into a reaction kettle, wherein the reaction kettle uses a clean container to ensure that the container does not adversely affect the negative oxygen ions;
s2, mixing the negative oxygen ion powder into water under the stirring condition, wherein the weight ratio of the negative oxygen ion powder to the water is 1:20, stirring in a stirrer for 1-2 hours, and controlling the stirring speed to be 200-300rpm, and completely mixing with the negative oxygen ion powder;
s3, after stopping stirring, taking out the mixture, putting the mixture into an ultrasonic machine for ultrasonic treatment for 1-2 hours, and then adding 0.1 part of sodium borohydride and 5 parts of tourmaline powder for mixing;
s4, stirring the mixture by using a stirrer to ensure that all negative oxygen ion raw materials are fully dissolved;
s5, filtering after standing and precipitating, and removing solid particles or impurities possibly existing by using a filter to obtain a clear negative oxygen ion release liquid.
Further, the negative oxygen ion powder comprises 100 parts of alcohol aqueous solution, 0.5 part of graphene oxide, 1 part of citric acid, 2 parts of vitamin c and 2 parts of hydrazine hydrate.
Further, grinding tourmaline to 600-1000 mesh, soaking the powder in 70-80% ethanol solution, and filtering to obtain tourmaline powder.
Further, the alcohol aqueous solution is prepared from ethanol and deionized water in a mass ratio of 1-20:100, and mixing the mixed solution.
Further, in the preparation process, the concentration and the proportion of generated hydrogen ions are controlled, the hydrogen ions are key factors for air purification and pollutant elimination, and the hydrogen ions can provide electrons and generate some active oxygen to forcedly change some harmful substances into harmless substances.
Further, the formula proportion of the negative oxygen ion release liquid is controlled to be pH 5-6, so that the stability of the state of the negative oxygen ion release liquid is improved.
Further, in the region sprayed with the negative oxygen ion releasing liquid, negative oxygen ions are continuously released, negative charges are conveyed to 0.001-100 micron gas dispersion and solid and gas small particles such as bacteria, dust, smoke particles, water drops and the like by the negative oxygen ions, and charges are combined with the solid and gas small particles and aggregated into balls to sink.
The invention has the following advantages: alcohol aqueous solution, graphene oxide, citric acid, vitamin c, hydrazine hydrate, sodium borohydride and tourmaline powder, wherein the mass ratio of the alcohol aqueous solution to the graphene oxide to the citric acid to the vitamin c is 100:0.5:2:1:2:2:0.1: and 5, accurately controlling the mass ratio of the negative oxygen ion raw material alcohol aqueous solution, graphene oxide, citric acid, vitamin c, hydrazine hydrate, sodium borohydride and tourmaline powder through experimental design, ensuring the stability and consistency of the negative oxygen ion release liquid in different batches, enabling hydrogen ions to provide electrons and generate some active oxygen, forcing some harmful substances into harmless substances, controlling the concentration and proportion of generated hydrogen ions to prolong the effect time of the negative oxygen ion release liquid, controlling the formula proportion of the negative oxygen ion release liquid to be 5-6, increasing the stability of the state of the negative oxygen ion release liquid, and exerting the negative oxygen ion release effect to the maximum extent.
Drawings
Fig. 1 is a flow chart of a preparation method of a negative oxygen ion release liquid according to some embodiments of the present invention.
Detailed Description
Other advantages and advantages of the present invention will become apparent to those skilled in the art from the following detailed description, which, by way of illustration, is to be read in connection with certain specific embodiments, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Example 1
As shown in fig. 1, the preparation method of the negative oxygen ion release liquid in the embodiment of the first aspect of the present invention includes the following steps:
s1, adding negative oxygen ion powder into a reaction kettle, wherein the reaction kettle uses a clean container to ensure that the container does not adversely affect the negative oxygen ions;
s2, mixing the negative oxygen ion powder into water under the stirring condition, wherein the weight ratio of the negative oxygen ion powder to the water is 1:20, stirring in a stirrer for 1-2 hours, and controlling the stirring speed to be 200-300rpm, and completely mixing with the negative oxygen ion powder;
s3, after stopping stirring, taking out the mixture, putting the mixture into an ultrasonic machine for ultrasonic treatment for 1-2 hours, and then adding 0.1 part of sodium borohydride and 5 parts of tourmaline powder for mixing;
s4, stirring the mixture by using a stirrer to ensure that all negative oxygen ion raw materials are fully dissolved, adding a cosolvent during mixing, and increasing the temperature, so that the solubility can be improved, and the preparation efficiency of the negative oxygen ion release liquid can be improved;
s5, filtering after standing and precipitating, and removing solid particles or impurities possibly existing by using a filter to obtain a clear negative oxygen ion release liquid.
In the above embodiment, the negative oxygen ion raw material comprises the following components: alcohol aqueous solution, graphene oxide, citric acid, vitamin c, hydrazine hydrate, sodium borohydride and tourmaline powder, wherein the mass ratio of the alcohol aqueous solution to the graphene oxide to the citric acid to the vitamin c is 100:0.5:2:1:2:2:0.1:5, the negative oxygen ion powder is prepared by grinding tourmaline with the particle size of 600-1000 meshes, soaking the powder in 70-80% ethanol solution, and filtering to obtain tourmaline powder, wherein the mass ratio of ethanol to deionized water is (1-20): 100, and mixing the mixed solution.
The technical effects achieved by the embodiment are as follows: the mass ratio of the negative oxygen ion raw material alcohol aqueous solution, graphene oxide, citric acid, vitamin c, hydrazine hydrate, sodium borohydride and tourmaline powder is accurately controlled through experimental design, so that the stability and consistency of the negative oxygen ion release liquid in different batches can be ensured.
Example 2
As shown in fig. 1, the preparation method of the negative oxygen ion releasing liquid comprises the whole content of the embodiment 1, in addition, in the preparation process, the concentration and the proportion of generated hydrogen ions are controlled, the hydrogen ions are key factors for purifying air and eliminating pollutants, the hydrogen ions can provide electrons and generate some active oxygen to forcedly change some harmful substances into harmless substances, the formula proportion of the negative oxygen ion releasing liquid is controlled to be 5-6, and the stability of the state of the negative oxygen ion releasing liquid is improved.
The technical effects achieved by the embodiment are as follows: the concentration and the proportion of the generated hydrogen ions can be controlled to prolong the effect time of the negative oxygen ion release liquid, and the negative oxygen ion generation effect can be exerted to the greatest extent only by controlling the pH value of the negative oxygen ions.
Example 3
As shown in fig. 1, the application of the negative oxygen ion releasing liquid includes the whole content of example 1, and in addition, the region sprayed with the negative oxygen ion releasing liquid continuously releases negative oxygen ions, and the negative oxygen ions are delivered to the bacteria, dust, smoke particles, water drops and other 0.001-100 micron gas dispersion and solid and gas small particles, and the charges are combined with the gas dispersion and the solid and gas small particles to be aggregated into balls to sink.
The technical effects achieved by the embodiment are as follows: the negative oxygen ion has the capability of adsorbing particulate matters such as dust, bacteria and viruses in the air, and the purpose of inhibiting aerosol formation and sedimentation of the aerosol in the air is achieved, so that the transmission probability of the viruses through the aerosol is reduced, and the negative oxygen ion release liquid can be used for improving indoor environments and improving air quality in offices, families and other occasions.
Claims (8)
1. Negative oxygen ion release liquid, its characterized in that: the negative oxygen ion release liquid comprises raw material components including alcohol water solution, graphene oxide, citric acid, vitamin c, hydrazine hydrate, sodium borohydride and tourmaline powder, wherein the mass ratio of the alcohol water solution to the graphene oxide to the citric acid to the vitamin c is 100:0.5:1:2:2:0.1:5.
2. a method for preparing the negative oxygen ion release liquid according to claim 1, which is characterized by comprising the following steps:
s1, adding negative oxygen ion powder into a reaction kettle, wherein the reaction kettle uses a clean container to ensure that the container does not adversely affect the negative oxygen ions;
s2, mixing the negative oxygen ion powder into water under the stirring condition, wherein the weight ratio of the negative oxygen ion powder to the water is 1:20, stirring in a stirrer for 1-2 hours, and controlling the stirring speed to be 200-300rpm, and completely mixing with the negative oxygen ion powder;
s3, after stopping stirring, taking out the mixture, putting the mixture into an ultrasonic machine for ultrasonic treatment for 1-2 hours, and then adding 0.1 part of sodium borohydride and 5 parts of tourmaline powder for mixing;
s4, stirring the mixture by using a stirrer to ensure that all negative oxygen ion raw materials are fully dissolved;
s5, filtering after standing and precipitating, and removing solid particles or impurities possibly existing by using a filter to obtain a clear negative oxygen ion release liquid.
3. The method for preparing the negative oxygen ion releasing liquid according to claim 2, characterized in that: the negative oxygen ion powder comprises, by mass, 100 parts of an alcohol aqueous solution, 0.5 part of graphene oxide, 1 part of citric acid, 2 parts of vitamin c and 2 parts of hydrazine hydrate.
4. The method for preparing the negative oxygen ion releasing liquid according to claim 2, characterized in that: grinding tourmaline to 600-1000 mesh, soaking in 70-80% ethanol solution, and filtering to obtain tourmaline powder.
5. The method for preparing the negative oxygen ion releasing liquid according to claim 2, characterized in that: the alcohol aqueous solution is prepared from ethanol and deionized water in a mass ratio of 1-20:100, and mixing the mixed solution.
6. The method for preparing the negative oxygen ion releasing liquid according to claim 2, characterized in that: in the preparation process, the concentration and the proportion of generated hydrogen ions are controlled, the hydrogen ions are key factors for air purification and pollutant elimination, and can provide electrons and generate some active oxygen to forcedly change some harmful substances into harmless substances.
7. The method for preparing the negative oxygen ion releasing liquid according to claim 2, characterized in that: the formula proportion of the negative oxygen ion release liquid is controlled to be pH 5-6, so that the stability of the state of the negative oxygen ion release liquid is improved.
8. Use of a negative oxygen ion releasing liquid, comprising a method for preparing a negative oxygen ion releasing liquid according to any one of claims 2 to 7, characterized in that: through the area of spraying negative oxygen ion releasing liquid, negative oxygen ions are released continuously, and negative charges are conveyed to bacteria, dust, smoke particles, water drops and other 0.001-100 micron gas dispersion and solid and gas small particles, and the charges are combined with the solid and gas small particles to form balls and sink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202311822288.6A CN117771410A (en) | 2023-12-27 | 2023-12-27 | Negative oxygen ion release liquid and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202311822288.6A CN117771410A (en) | 2023-12-27 | 2023-12-27 | Negative oxygen ion release liquid and preparation method and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN117771410A true CN117771410A (en) | 2024-03-29 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202311822288.6A Pending CN117771410A (en) | 2023-12-27 | 2023-12-27 | Negative oxygen ion release liquid and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN117771410A (en) |
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2023
- 2023-12-27 CN CN202311822288.6A patent/CN117771410A/en active Pending
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