CN1177011C - Neutral silicone sealant for stone material and making method thereof - Google Patents
Neutral silicone sealant for stone material and making method thereofInfo
- Publication number
- CN1177011C CN1177011C CNB011071672A CN01107167A CN1177011C CN 1177011 C CN1177011 C CN 1177011C CN B011071672 A CNB011071672 A CN B011071672A CN 01107167 A CN01107167 A CN 01107167A CN 1177011 C CN1177011 C CN 1177011C
- Authority
- CN
- China
- Prior art keywords
- stone material
- silicone sealant
- omega
- alpha
- neutral silicone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title claims abstract description 37
- 239000004575 stone Substances 0.000 title claims abstract description 32
- 239000004590 silicone sealant Substances 0.000 title claims abstract description 23
- 230000007935 neutral effect Effects 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title claims description 7
- -1 polysiloxane Polymers 0.000 claims abstract description 27
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 13
- 238000006243 chemical reaction Methods 0.000 claims abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000004519 manufacturing process Methods 0.000 claims abstract description 7
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 4
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 14
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 13
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 13
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 13
- 239000004902 Softening Agent Substances 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 8
- 230000003197 catalytic effect Effects 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 6
- 239000013008 thixotropic agent Substances 0.000 claims description 6
- XOLBLPGZBRYERU-UHFFFAOYSA-N SnO2 Inorganic materials O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 5
- 230000018044 dehydration Effects 0.000 claims description 5
- 238000006297 dehydration reaction Methods 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- NYMPGSQKHIOWIO-UHFFFAOYSA-N hydroxy(diphenyl)silicon Chemical compound C=1C=CC=CC=1[Si](O)C1=CC=CC=C1 NYMPGSQKHIOWIO-UHFFFAOYSA-N 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 claims description 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical group CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 239000004359 castor oil Substances 0.000 claims description 3
- 235000019438 castor oil Nutrition 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 claims description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 3
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 239000000565 sealant Substances 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims description 3
- 239000004971 Cross linker Substances 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 claims description 2
- 239000013522 chelant Substances 0.000 claims description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 2
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 claims description 2
- 229960001866 silicon dioxide Drugs 0.000 claims description 2
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 239000000470 constituent Substances 0.000 claims 1
- 239000011863 silicon-based powder Substances 0.000 claims 1
- 230000008901 benefit Effects 0.000 abstract description 5
- 238000010276 construction Methods 0.000 abstract description 3
- 239000000654 additive Substances 0.000 abstract description 2
- 230000032683 aging Effects 0.000 abstract description 2
- 239000004014 plasticizer Substances 0.000 abstract description 2
- 239000002699 waste material Substances 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 229920000548 poly(silane) polymer Polymers 0.000 abstract 1
- 150000003606 tin compounds Chemical class 0.000 abstract 1
- 150000003609 titanium compounds Chemical class 0.000 abstract 1
- 238000011056 performance test Methods 0.000 description 5
- WRQNANDWMGAFTP-UHFFFAOYSA-N Methylacetoacetic acid Chemical compound COC(=O)CC(C)=O WRQNANDWMGAFTP-UHFFFAOYSA-N 0.000 description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 231100000078 corrosiveness Toxicity 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000013464 silicone adhesive Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
Landscapes
- Sealing Material Composition (AREA)
Abstract
The present invention relates to a neutral silicone sealant for stone materials, which is characterized in that alpha, omega-dihydroxyl polysiloxane is used as a base material, silicane as an internal plasticizer and auxiliary additives, such as methylhydroxyl dimethyl polysilane, silicon dioxide, methyltrimethoxysilane and organic titanium compounds, organic tin compounds, etc., are added to the base material. Thus, the neutral silicone sealant for stone materials is prepared by the chemical reaction at the vacuum degree of 0.06 to 0.095MPa. The present invention has the advantages of convenient construction, strong binding power, favorable climate aging resistance, no pollution for stone materials, no corrosion, no three-waste generation in production processes, and obvious economic benefit and social benefit.
Description
The present invention relates to neutral silicone sealant for stone material and manufacture method thereof, belong to the polymer building material field.
Silicone sealant has excellent weather, damp and hot, ultraviolet ray and ozone ageing performance thereof, is one of building sealant preferred material.Along with the widespread use of building curtain wall, silicone sealant has obtained swift and violent development.The dry-hang stone curtain wall rises rapidly, and stone material has become one of decoration of exterior wall main flow of top-grade building, so the application quantity of silicone sealant for stone material increases year by year.In order to improve the elongation of neutral silicone seal gum, reduce hardness, increase elasticity, improve extrudability, usually will add some softening agent in seal gum, as dioctyl phthalate (DOP), low viscosity methyl-silicone oil etc., these softening agent can not participate in cross-linking and curing reaction, after for some time, softening agent will be exuded to stone surface from colloid, pollute stone material, have a strong impact on the attractive in appearance and decorative quality of curtain wall.Chinese patent CN1110299A is entitled as " organic silicone structure sealant ", and it is made by raw materials such as organic silicone and silicate, can be used for the sealing structure of glass curtain wall aspect, but does not solve the pollution problem of silicone adhesive to stone material.
The objective of the invention is provides neutral silicone sealant for stone material and manufacture method thereof at the deficiencies in the prior art, being characterized in adopting α, alpha, omega-dihydroxy polysiloxane is base-material, introduce active siloxanes softening agent and supplementary additive thereof, make the free of contamination neutral silicone sealant for stone material of stone material.
Purpose of the present invention is realized that by following technical measures wherein said raw material umber is parts by weight except that specified otherwise.
10～90 parts of α, alpha, omega-dihydroxy polysiloxane
2～10 parts in softening agent
90～10 parts of fillers
1～10 part of thixotropic agent
1～10 part of linking agent
1～10 part of tackifier
0.1～5 part of catalytic curing agent
Wherein α, alpha, omega-dihydroxy polysiloxane are α, alpha, omega-dihydroxy polydimethyl siloxane, at least a in poly-di-ethyl siloxane of α, alpha, omega-dihydroxy and/or α, the poly-diphenyl siloxane of alpha, omega-dihydroxy.
The silane softening agent is α, ω-methyl hydroxyl polydimethylsiloxane, at least a in α, ω-ethyl hydroxyl polydimethylsiloxane and/or α, the ω-phenyl hydroxyl polydimethylsiloxane.
Filler is lime carbonate, wilkinite, at least a in activated clay and/or the talcum powder.
Thixotropic agent is at least a in silicon-dioxide, hydrogenated castor oil and/or the polyethylene wax.
Linking agent is a methyltrimethoxy silane, and ethyl trimethoxy silane and/or phenyltrimethoxysila,e are at least a.
Tackifier are isopropyl titanate, butyl (tetra) titanate, γ-An Bingjisanyiyangjiguiwan, at least a in the superfluous compound of the methyl aceto acetate of 1,2 epoxy oxyethyl group Trimethoxy silane and/or titanic acid ester.
Catalytic curing agent is at least a in dibutyl tin laurate, dibutyltin diacetate and/or the stannic oxide methyl aceto acetate complex compound.
The manufacture method of neutral silicone sealant for stone material:
A, with 10～90 parts of α, alpha, omega-dihydroxy polysiloxane, 90～10 parts of fillers add in the vacuum kneader, in 80～150 ℃ of temperature, vacuum tightness is 0.06～0.095MPa, dehydration blend 60～300 minutes moves in the planet stirring tank, and is standby,
B, at room temperature is with 1～10 part of silane crosslinker; 1～10 part of thixotropic agent, 1～10 part of tackifier, 0.1～5 part of catalytic curing agent and softening agent add in the planetary mixer for 2～10 parts, mix with α, alpha, omega-dihydroxy polysiloxane mixture, vacuum tightness is 0.06～0.095MPa, rotating speed is that 100～600rpm carried out chemical reaction 30～180 minutes, makes the neutral silicone sealant for stone material.Its reaction formula is:
R
1、R＝-CH
3，-CH
2CH
3，
n＝100～10000
The present invention has following advantage:
1. employing reactive plasticizer, product is pollution-free to porous materials such as stone materials; Do not have material after the construction and from seal gum, ooze out, can not form the spot stain yet the stone material edge.
2. adopt neutral curing system,, base material is had good bonding force base material non-corrosivenesss such as stone material, cement, glass and metals.
3. product easy construction, weather-resistant performance brilliance, water resistance is good, and integrated performance index reaches external like product.
4. in process of production can water consumption consumption low, no three wastes generation, environmentally safe has remarkable economic efficiency and social benefit.
Embodiment
Below by embodiment the present invention is carried out concrete description; be necessary to be pointed out that at this following examples only are used for the present invention is further specified; can not be interpreted as limiting the scope of the invention, the person skilled in the art in this field can make some nonessential improvement and adjustment to the present invention according to last content of the present invention.
1. α, alpha, omega-dihydroxy polydimethyl siloxane 60kg and lime carbonate 60kg are added in the vacuum kneader, in 100 ℃ of temperature, vacuum tightness is 0.96～0.095MPa dehydration blend 60 minutes, moves in the planet stirring tank; At room temperature, with methyltrimethoxy silane 3kg, silica 1 0kg isopropyl titanate 1kg, α, ω-methyl hydroxyl polydimethylsiloxane 6kg and dibutyl tin laurate 0.5kg add in the stirring tank of entering a profession, mix with α, alpha, omega-dihydroxy polydimethyl siloxane mixture, vacuum tightness is 0.06～0.095MPa, rotating speed 350rpm, carried out chemical reaction 80 minutes, make neutral silicone sealant for stone material product, product and product see for details shown in table 1 and the table 2 in the The performance test results of different states.
2. α, the poly-di-ethyl siloxane 70kg of alpha, omega-dihydroxy and wilkinite 62kg are added in the vacuum kneader, in 110 ℃ of temperature, vacuum tightness is 0.06～0.095MPa, and dehydration blend 70 minutes moves in the planet stirring tank; At room temperature, with ethyl trimethoxy silicon 3kg, hydrogenated castor oil 8kg and butyl (tetra) titanate 0.8kg, α, ω ethyl hydroxyl polydimethylsiloxane 5kg and dibutyltin diacetate 1.5kg, add in the planet stirring tank, mix with α, the poly-di-ethyl siloxane mixture of alpha, omega-dihydroxy, vacuum tightness is 0.06～0.095MPa, rotating speed 360rpm, carried out chemical reaction 50 minutes, make neutral silicone sealant for stone material product, product and product see for details shown in table 1 and the table 2 in the The performance test results of different states.
3. α, the poly-diphenyl siloxane 50kg of alpha, omega-dihydroxy and activated clay 60kg are added in the vacuum kneader, in 115 ℃ of temperature, vacuum tightness is 0.06～0.095MPa dehydration blend 180 minutes, moves in the planet stirring tank; At room temperature, with phenyltrimethoxysila,e 3kg, the ethyl acetoacetate chelate 0.8kg of polyethylene wax 6kg and titanic acid ester, the methyl aceto acetate complex compound 0.5kg of α, ω-phenyl hydroxyl polydimethylsiloxane 3kg and stannic oxide, add in the planet stirring tank, mix with α, the poly-diphenyl siloxane mixture of alpha, omega-dihydroxy, vacuum tightness is 0.06～0.095MPa, rotating speed 380rpm, carried out chemical reaction 120 minutes, make neutral silicone sealant for stone material product, product and product see for details shown in table 1 and the table 2 in the The performance test results of different states.
Table 1 is the product performance test result
Table 2 is the The performance test results of product at different states
Claims (7)
1, neutral silicone sealant for stone material is characterized in that the formula constituent (by weight) of this sealant for stone material is:
α, 10～90 parts of alpha, omega-dihydroxy polysiloxane
2～10 parts in softening agent
90～10 parts of fillers
1～10 part of thixotropic agent
1～10 part of linking agent
1～10 part of tackifier
0.1～5 part of catalytic curing agent
α wherein, the alpha, omega-dihydroxy polysiloxane is α, alpha, omega-dihydroxy polydimethyl siloxane, α, poly-di-ethyl siloxane of alpha, omega-dihydroxy and/or α, the poly-diphenyl siloxane of alpha, omega-dihydroxy is at least a, softening agent is α, ω-methyl hydroxyl polydimethylsiloxane, α, ω-ethyl hydroxyl polydimethylsiloxane and/or α, at least a in ω-phenyl hydroxyl polydimethylsiloxane.
2, according to the described neutral silicone sealant for stone material of claim 1, wherein filler is at least a in lime carbonate, activated clay, silicon powder, wilkinite and/or the talcum powder.
3, according to the described neutral silicone sealant for stone material of claim 1, wherein thixotropic agent is at least a in silicon-dioxide, hydrogenated castor oil and/or the polyethylene wax.
4, according to the described neutral silicone sealant for stone material of claim 1, wherein linking agent is a methyltrimethoxy silane, at least a in ethyl trimethoxy silane and/or the phenyltrimethoxysila,e.
5, according to the described neutral silicone sealant for stone material of claim 1, wherein tackifier are isopropyl titanate, butyl (tetra) titanate, γ-An Bingjisanyiyangjiguiwan, 1, at least a in the ethyl acetoacetate chelate of 2-epoxy oxyethyl group Trimethoxy silane and/or titanic acid ester.
6, according to the described neutral silicone sealant for stone material of claim 1, wherein catalytic curing agent is a dibutyl tin laurate, at least a in dibutyltin diacetate and/or the stannic oxide acetyl triethyl complex compound.
7, according to the manufacture method of the described neutral silicone sealant for stone material of claim 1, it is characterized in that:
A, with α, alpha, omega-dihydroxy polysiloxane 10～90 weight parts, filler 90～10 weight parts add in the vacuum kneader, in 80～150 ℃ of temperature, vacuum tightness is 0.06～0.095MPa, dehydration blend 60～300 minutes moves in the planet stirring tank, and is standby,
B, at room temperature is with silane crosslinker 1～10 weight part; Thixotropic agent 1～10 weight part, tackifier 1～10 weight part, catalytic curing agent 0.1～5 weight part and softening agent 2～10 weight parts add in the planetary mixer, with α, the alpha, omega-dihydroxy polysiloxane mixture mixes, and vacuum tightness is 0.06～0.095MPa, and rotating speed is that 100～600rpm carried out chemical reaction 30～180 minutes, make the neutral silicone sealant for stone material, its reaction formula is:
R
1、R＝-CH
3，-CH
2CH
3，
n＝100～10000。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011071672A CN1177011C (en) | 2001-02-23 | 2001-02-23 | Neutral silicone sealant for stone material and making method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011071672A CN1177011C (en) | 2001-02-23 | 2001-02-23 | Neutral silicone sealant for stone material and making method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1371953A CN1371953A (en) | 2002-10-02 |
| CN1177011C true CN1177011C (en) | 2004-11-24 |
Family
ID=4656117
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011071672A Expired - Lifetime CN1177011C (en) | 2001-02-23 | 2001-02-23 | Neutral silicone sealant for stone material and making method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1177011C (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1314774C (en) * | 2005-04-13 | 2007-05-09 | 成都硅宝科技实业有限责任公司 | Flameproofing silicone structure sealant and mfg. method thereof |
| CN100347264C (en) * | 2005-12-05 | 2007-11-07 | 叶照光 | Full automatic producing, filling and separate packing method of structural silicone sealant adhesive |
| CN100381535C (en) * | 2006-02-28 | 2008-04-16 | 成都硅宝科技实业有限责任公司 | Anti-fouling single-component room temperature sealing silicone sulfide glue and its production process |
| CN101298550B (en) * | 2008-07-03 | 2012-07-25 | 广东三和化工科技有限公司 | Nanometer mildewproof sealing neutral silicone resin |
| CN101353563B (en) * | 2008-09-11 | 2011-12-28 | 成都硅宝科技股份有限公司 | Single-component silicone fluid sealant for solar energy cell assembly and manufacturing method thereof |
| CN101812281B (en) * | 2009-10-23 | 2012-07-25 | 郑州中原应用技术研究开发有限公司 | Sealant with neutral and transparent silicone structure |
| CN102277126B (en) * | 2011-06-28 | 2015-01-14 | 成都硅宝科技股份有限公司 | Single-component dealcholization-type silicon sealant used for automobile lamp and preparation method thereof |
| CN102766431B (en) * | 2012-07-27 | 2013-07-31 | 广东欧利雅化工有限公司 | High-adhesion silicone sealant |
| CN103013430A (en) * | 2012-12-24 | 2013-04-03 | 成都硅宝科技股份有限公司 | Environment-friendly organosilicone sealant and manufacturing method thereof |
| CN105283518A (en) * | 2013-06-19 | 2016-01-27 | 阿克佐诺贝尔国际涂料股份有限公司 | A composition of high temperature resistent powder coating, a preparation method therefore, and use thereof |
| DE102014210309A1 (en) * | 2014-05-30 | 2015-12-03 | Wacker Chemie Ag | Crosslinkable compositions based on organyloxysilane-terminated polymers |
| CN107129790A (en) * | 2017-04-19 | 2017-09-05 | 常熟市恒信粘胶有限公司 | Neutral silicone sealant for stone material |
| CN106967381A (en) * | 2017-04-19 | 2017-07-21 | 常熟市恒信粘胶有限公司 | Neutral silicone prefabricated buildings special seal gum |
| CN107216851A (en) * | 2017-06-15 | 2017-09-29 | 广州市普金装饰材料有限公司 | It is a kind of applied to silicone sealant of stone material joint filling and preparation method thereof |
| CN109184121A (en) * | 2018-11-05 | 2019-01-11 | 江苏东保装饰集团有限公司 | A kind of installation method of building wall finishing material |
-
2001
- 2001-02-23 CN CNB011071672A patent/CN1177011C/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CN1371953A (en) | 2002-10-02 |
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