CN1175975A - Process and composition for cleaning surfaces - Google Patents

Process and composition for cleaning surfaces Download PDF

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Publication number
CN1175975A
CN1175975A CN96192074A CN96192074A CN1175975A CN 1175975 A CN1175975 A CN 1175975A CN 96192074 A CN96192074 A CN 96192074A CN 96192074 A CN96192074 A CN 96192074A CN 1175975 A CN1175975 A CN 1175975A
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CN
China
Prior art keywords
composition
spraying
product
solvent
dosage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN96192074A
Other languages
Chinese (zh)
Inventor
H·A·巴尔尼斯
M·J·加尔维
M·J·利奇
M·沙普勒斯
G·史密斯
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Unilever PLC
Unilever NV
Original Assignee
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GBGB9503595.2A external-priority patent/GB9503595D0/en
Priority claimed from GBGB9514301.2A external-priority patent/GB9514301D0/en
Application filed by Unilever NV filed Critical Unilever NV
Publication of CN1175975A publication Critical patent/CN1175975A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents

Abstract

When products comprising aqueous solutions of nonionics or nonionic/solvent systems are sprayed as fine droplets to form a discontinuous film, either less cleaning effort can be used with the same level of product, or the same effort can be used with less product. It is believed that the effect is due to the presence of an increased number of menisci and evaporation of the aqueous liquor or part of any solvent component from the product on the surface, and further believed that this evaporation causes local increases in concentration and/or local turbulence which enhances the cleaning process. Accordingly, a first aspect of the invention provides a packaged, aqueous or solvent-containing, nonionic cleaning composition, in a container provided with a spray jet adapted to deliver the composition to a surface in the form of a spray, characterized in that the dosage applied to the surface by each operation of the spraying apparatus falls in the range 0.15-0.5 ml and the said dose is applied over an area of at least 50 cm<2> when the spray is operated 15 cm from the surface. A further aspect of the invention relates to a method using the above-mentionned packaged composition. Preferred compositions have a pH of > 10 and comprises, in admixture with water, nonionic surfactant, solvent, an alkanolamine, buffer/alkali and a polymer.

Description

The method and composition that is used for the clean surface
Invention field
The present invention relates to be used for the method and composition of clean surface.
Background of invention
People are known to spraying the spray film of the cleaning compositions that contains tensio-active agent from the teeth outwards, and this cleaning compositions is used from the teeth outwards.In known spray method, being deposited on lip-deep composition film is successive in most of zone, although can be observed the discontinuity zone of drop at the edge of spray-type shape.This method of application guarantees that product arrives required surf zone.Be used to spray the spraying plant of cleaning compositions, for example so-called " pull and penetrate the formula pump ", the form with big relatively drop sprays heavy dose of product usually, and it flows from the teeth outwards and is coalescent, thereby forms the continuous film of composition.
The also known foam of spraying from the teeth outwards of people, it is considered to uneven on a small scale.In addition, people are known penetrates a large amount of relatively product of formula pump ejection in order to pulling of this form ejection composition.
Invention is simple to be described
We find, when the product that contains nonionogenic tenside or nonionic/solvent system aqueous solution forms discontinuous film with the small droplet spraying, can be with less cleaning strength for identical consumption, or use less product for identical cleaning strength.We believe, this effect is owing to have the meniscus that increases number and the aqueous solution of product or the evaporation of any solvent composition of part from the teeth outwards.We also believe, this evaporation especially at the meniscus place, causes local increase of concentration and/or local turbulence, thereby improved washing process.We also find, also can be observed similar effects for foam.The detailed description of invention
Therefore, a first aspect of the present invention provides a kind of packing in container, moisture or contain solvent nonionic cleaning compositions, described container is equipped with and is suitable for the nozzle of Sprayable to surface ejection composition, it is characterized in that the each operation by spraying plant is 0.15-0.5ml to the dosage of surface applied, when nozzle during apart from surperficial 15cm operation, described dosage is applied in 50cm at least 2Area on.
A second aspect of the present invention relates to a kind of method of cleaning of hard surfaces, it comprises the composition that contains nonionogenic tenside from the container that nozzle is housed to the surface with the form injection of spraying, it is characterized in that the each operation by spraying plant is 0.15-0.5ml to the dosage of surface applied, when nozzle during apart from surperficial 15cm operation, described dosage is applied in 50cm at least 2Area on.
As mentioned above, we believe the meniscus cleaning effect that helps cleaning course by sprawling product with the dispersant liquid drop and/or the form of foam that do not form continuous film from the teeth outwards, having improved.A key character of the present invention is that from the teeth outwards coalescent of product should be reduced to minimum degree to form continuous film, although may occur obviously that some are coalescent.
Each operation by spraying plant is typically 0.2-0.4ml to the dosage of surface applied; Especially preferred dosage is 0.25-0.35ml.The previous each spray operation of using of the spraying that is used for hard surface cleaner typically sprays more than the 0.7ml, and is promptly big than spraying dosage of the present invention.In the present invention's practice, especially preferred dosage equals at 80cm 2At least the product of 0.3ml is provided on the area.
The preferred cone angle of spraying is that the 0.15-0.5ml product is applied on the border circular areas of 10cm diameter at least.Preferred droplet distribution from the teeth outwards is to circulate in the 10-40ml product of using calculating on every square metre of surface for each pump.
In embodiments of the invention, typical cone angle is the 25-75 degree.The previous spraying of using that is used for hard surface cleaner is used product or injection with narrow relatively circular cone usually, and each pump circulation provides the product of obvious more amount.As mentioned above, a key character of the present invention is the dosage that reduces compared with prior art and/or the coverage of increase.
Preferred droplets size distribution be to restrain liquid effluents for 10, and the product that is less than 350mg exists with the drop that has less than 7 microns particle size.The product that preferably is less than 700mg exists with the drop that has less than 30 microns particle size.
Average particle size typically will be the 50-100 micron.We believe the particle issues that this has been avoided existence to be breathed, thereby guarantee that product is applied to the surface, rather than are suspended in the air.We also believe, the surface coverage of using the distribution of this scope to produce has promoted above-mentioned meniscus cleaning effect.
For existing typical product on the market (' CIF multiuso ' (TM) pull penetrate formula packing), drop size range is the 30-700 micron, about 250 microns of peak value.
Composition must have viscosity, makes it to use with Sprayable.We believe that also it is main that composition contains at least a nonionogenic tenside.Composition of the present invention can be simple solution or more complicated form, for example microemulsion.
Especially preferred composition contains the 2-30% nonionogenic tenside, more preferably the 3-13% nonionogenic tenside.Anion surfactant is chosen wantonly.Preferred nonionic comprises oxyalkylated alcohol, and especially every mol of alcohol has the ethoxylation C8-C18 alcohol of 3-8 oxyethane.Can use other nonionogenic tenside, many above-mentioned tensio-active agents are open in ' nonionogenic tenside ' (Arnold: tensio-active agent science series, the 1st volume) of Schick.
The preferred concentration of tensio-active agent is the 5-15% (weight) of total surfactant, and about 10% (weight) of content is especially preferred.These concentration are higher than the concentration of normally used spray composite, but since composition than low dosage and visible improves in the present invention practice cleaning efficiency, can reduce total consumption of tensio-active agent.This not only has direct environmental effect, but also has indirect effect, and the smaller container of promptly packing product consumes less fuel when using less wrapping material and transportation product.Also there is a kind of direct effect for the human consumer, promptly can obtains effective cleaning with lighter effective application device.
Hydrophobic oil is the optional component of the present composition.Suitable oil comprises easily the oil of dissolving tri-glyceride rapidly.When having oil, preferred oil comprises terpadiene, to cymene, dibutyl ether and butyl butyrate.
Solvent preferably exists with the content of 3-20% (weight), and content is that 5-10% (weight) is especially preferred.Glycol ether and/or the lower alcohol with 1-5 carbon atom are preferably used as solvent, though estimate also can use the short-chain alkyl ester, comprise ethyl acetate and/or pyrrolidone, comprise N-Methyl pyrrolidone.
Solvent is preferably selected from: propylene glycol list n-butyl ether, dipropylene glycol list n-butyl ether, propylene glycol list tertbutyl ether, dipropylene glycol list tertbutyl ether, Diethylene Glycol hexyl ether, methyl alcohol, ethanol, Virahol, ethylene glycol monobutyl ether, Diethylene Glycol single-butyl ether and their mixture.
Especially preferred solvent be selected from ethanol (preferred industrial methylated spirit), propylene glycol list n-butyl ether (with ' and Dowanol PnB ' [RTM] obtains) and Diethylene Glycol monobutyl ester (Butyl Carbitol ' [RTM] obtains with ' Butyl Digol ' [RTM] or ').But because cost capacitation and safety factors, these solvents are preferred.We find to select to use solvent for ink and the improved clean-up performance of dyestuff.
Although composition of the present invention can be alkalescence, acidity or neutral, preferred composition has great alkalescence, preferably has the pH greater than 10.
Especially preferredly be, composition contains the alkanolamine of 1-10%, and content is that 2-6% (weight) is especially preferred.
Especially suitable alkanolamine comprises 2-amino-2-methyl propyl alcohol, monoethanolamine and diethanolamine.These materials are considered to incrustation or aging dirt are brought the cleaning effect of improvement.
We find, especially advantageously comprise polymkeric substance in composition of the present invention, to reduce the content that forms especially thin drop, can be inhaled into and cause the content to the drop of user's stimulation.Suitable polymers comprises PVP, obtains with polymer P VP K-90 on market.
The appropriate level of PVP polymkeric substance is more than the 50ppm, the content of especially preferred 500-1500ppm.
Composition preferably has the pH greater than 10, and it contains and the following component of water blended:
A) 3-13% nonionogenic tenside
B) 0-10% solvent
C) 2-6% alkanolamine
D) 0-5% damping fluid/alkali and
E) 50-1500ppm polymkeric substance.
Composition especially preferably has the pH greater than 10, and it contains and the following component of water blended:
A) 3-13% nonionogenic tenside (C10-EO5 nonionic most preferably
Tensio-active agent)
B) 5-10% solvent (most preferably, Diethylene Glycol list n-butyl ether)
C) 2-6% alkanolamine (most preferably 2-amino-2-methyl-1-propanol)
D) 1-5% damping fluid/alkali (most preferably yellow soda ash or salt of wormwood) and
E) 500-1000ppm polymkeric substance (preferred PVP).
Above-mentioned composition is packaged in each spray operation and is suitable for producing in the container of 0.15-0.5ml product spraying.Above-mentioned spraying has the average droplet size of 30-300 micron.
For understanding the present invention better, the present invention is described for reference example and accompanying drawing.Embodiment
Clean-up performance is measured on DECAMEL (RTM, the ex Formica) paper that stains.On ' DECAMEL ' test surfaces of ' A4 ' size, pass through sprayed deposit 0.5mg/cm 2(based on non-volatile matter) dirt.Dirt contains 1% glycerol tripalmitate, 0.5% triolein, 0.5% kaolin, 0.2% whiteruss, 0.1% palmitinic acid, 0.02% carbon black in methylated spirit.Dirt at room temperature wore out 24 hours before cleaning.
Measure and remove the used effective force of dirt from this test surfaces with fiber sponge cloth.Embodiment 1
Prepare composition by component listed in the mixture table 1.
Table 1
10％ Inbentin91-35 (TM) C10-EO5 nonionogenic tenside
8％ Butyl Digol (TM): Diethylene Glycol list n-butyl ether
4％ 2-amino-2-methyl-1-propanol
2％ Damping fluid/alkali (yellow soda ash)
To 100% Water
As can be seen from Table 1, compare with the conventional spray cleaning composition that contains have an appointment 4% weight tensio-active agent, 5% solvent, said composition is spissated (about tensio-active agent).
Table 2 and accompanying drawing 1 have shown the result that the use above-mentioned composition carries out 6 sprayings.Composition is sprayed on the contamination DECAMEL ceramic tile that does not serve as a contrast of preparation as mentioned above with various pumps.These pumps are used P1-3 and C1-3 explanation in table 2.The P series pump is by ' Prefect Valois ' (TM) obtains, and the C series pump (TM) is obtained by ' CALMAR '.The P series pump is as follows by manufacturers's coding key: P1:PZ2/290 4627, and P2:PZ2/290 3020, and P3:PZ2/290 2502.The C series pump is as follows by manufacturers's coding key: C1:M300 HV, C2:M300 60 degree holes, C3:M300 30 degree holes.
In form and accompanying drawing, ' DS ' expression from average 5 minutes of when spraying inherent air diameter less than the average particle concentration of every cc particulate of 7 microns.' DS ' of higher data is corresponding to average droplet size lower in spraying.
Obtain wider data by pump P1-3, be recorded in as in the following table 3.From these data, the mutual relationship between drop size of as above measuring ' DS ' and the average particle size that produces by spraying as can be seen.
Table 3
Mean particle dia, micron
Spraying ??‘DS’ ??260-85 ??85-30 ??30-5.8
????P1 ????952 ??38.9％ ??50.1％ ??11％
????P2 ????627 ??45.8％ ??44.7％ ??9.5％
????P3 ????417 ??50.4％ ??43.6％ ??6％
Come back to table 2, cone diameter is measured in 15 centimeters, and promptly it is the diameter that distributes apart from the spraying of fog-spray nozzle 15 centimeters.
Dosage is meant the dosage that is applied on the area that uses the product spraying on the ceramic tile.In all cases, spraying plant uses the circulation above.
Effective force is meant and cleans the required total effective force of ceramic tile fully, measures with Ns according to total strength that the operator uses.
Table 2
Spraying Dosage ??‘DS’ Cone diameter Effective force
????P1 ????0.59 ????952 ??14.0cm ????205
????P2 ????0.64 ????627 ??10.2cm ????326
????P3 ????0.62 ????417 ??7.6cm ????349
????C1 ????0.61 ????745 ??9.5cm ????277
????C2 ????0.62 ????551 ??8.0cm ????392
????C3 ????0.83 ????130 ??7.0cm ????410
Can calculate the dosage of per unit area and the cleaning efficiency of representing according to the required effective force of the every dosage product of per unit area of spraying by the data that provide in the table 2.Fig. 1 draws this efficient to ' drop size ' of two series of small droplet quantitaes (DS) curve of measuring result.Find out significantly from data, higher for bigger ' DS ' value efficient, that is, allow with less effective force clean surface with the product of the same quantity that distributes than small droplet.This all is certain for spraying of ' P ' series and the spraying of ' C ' series.Embodiment 2
For measuring the effect of polymkeric substance, experimentize in order to Calmar (TM) the M300 6/35/BB034 pump of finger from rear drive to droplets size distribution.These experiments show under the situation that does not have polymkeric substance, diameter is 315 less than the average particle concentration of every cc particulate of 7 microns from average 5 minutes inherent air of spraying, yet, in the presence of 500ppm PVP (polymer P VP K-90), average particle density loss to 79.
Following table 4 has provided the additional data that is used for background, and wherein finger pump (obtaining by Calmar) is by handle drives.
Table 4
????PVP The type of pump Drop
??200ppm M300 ????108
??350ppm M300 ????95
??500ppm M300 ????82
??500ppm M300 6/35+4mm extends post ????60
As can be seen from Table 4, use handle and elongation post further to reduce the content of the drop that can be breathed that produces.Embodiment 3
Effect for showing that directly product dosage mode changes prepares composition by the component that provides in the mixture table 5.
Table 5
10％ Nonidet91-6T (TM) C10-EO6 nonionogenic tenside
8％ Butyl Digol (TM): Diethylene Glycol list n-butyl ether
4％ 2-amino-2-methyl-1-propanol
1.25％ Damping fluid/alkali (yellow soda ash)
1000ppm PVP?K90
0.2％ Spices
To 100% Water
These compositions are in three kinds of modes, by pulling of routine penetrate the formula spraying, by volumetric pipette with according to low dosage of the present invention, be applied on the DECAMEL ceramic tile of contamination.Dosage (ml), required effective force (Ns) and the cleaning efficiency (10/[In (effective force) x dosage 1) of cleaning have been provided as following table 6.In this case, definition during efficient not with reference to the spraying coverage.
Table 6
Method Dosage Effective force Efficient
Volumetric pipette ????2 ????304 ????0.9
Pull the formula of penetrating ????1.17 ????169 ????1.7
The present invention ????0.76 ????199 ????2.4
From the result of table 6 as can be seen, with show some discontinuously arranged routine pull the higher dosage of penetrating the formula packing or especially the product of high dosage from volumetric pipette a large amount of divide to shed compare, feature low dosage of the present invention is used product can produce more effective cleaning.It should be noted, in these experiments, use identical composition in each case, may influence the result with the concentration of avoiding product.

Claims (8)

1. a kind of packing in container moisture or contain solvent nonionic cleaning compositions, described container is equipped with and is suitable for the nozzle of Sprayable to the jet surface composition, it is characterized in that the each operation by spraying plant is 0.15-0.5ml to the dosage of surface applied, when nozzle during apart from surperficial 15cm operation, described dosage is applied in 50cm at least 2Area on.
2. the method for a cleaning of hard surfaces, this method comprises the step that contains the composition of nonionogenic tenside from the container that nozzle is housed with the form of spraying to jet surface, it is characterized in that the each operation by spraying plant is 0.15-0.5ml to the dosage of surface applied, when nozzle during apart from surperficial 15cm operation, described dosage is applied in 50cm at least 2Area on.
3. according to the method for claim 2, wherein the product droplets size distribution is for 10 gram liquid effluents in spraying, and the product that is less than 350mg exists with the drop that has less than 7 microns particle size.
4. according to the method for claim 2, wherein composition contains the 1-10% alkanolamine.
5. according to the method for claim 2, wherein composition contains polymkeric substance.
6. according to the method for claim 2, wherein composition has the pH value greater than 10.
7. according to the method for claim 2, wherein composition has the pH greater than 10, and it contains and the following component of water blended:
A) 3-13% nonionogenic tenside
B) 0-10% solvent
C) 2-6% alkanolamine
D) 0-5% damping fluid/alkali and
E) 50-1500ppm polymkeric substance.
8. according to the method for claim 2, wherein composition has the pH greater than 10, and it contains and the following component of water blended:
A) 3-13% nonionogenic tenside
B) 5-10% glycol ether solvent
C) 2-6% alkanolamine
D) 1-5% yellow soda ash or salt of wormwood and
E) 500-1000ppm polymkeric substance (preferred PVP),
Above-mentioned composition is packaged in each spray operation and is suitable for producing in the container of 0.15-0.5ml product spraying, and above-mentioned spraying has the average droplet size of 30-300 micron.
CN96192074A 1995-02-23 1996-02-07 Process and composition for cleaning surfaces Pending CN1175975A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB9503595.2 1995-02-23
GBGB9503595.2A GB9503595D0 (en) 1995-02-23 1995-02-23 Process and composition for cleaning surfaces
GBGB9514301.2A GB9514301D0 (en) 1995-07-13 1995-07-13 Process and composition for cleaning surfaces
GB9514301.2 1995-07-13

Publications (1)

Publication Number Publication Date
CN1175975A true CN1175975A (en) 1998-03-11

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EP (1) EP0811053B1 (en)
JP (1) JPH11500480A (en)
KR (1) KR19980702442A (en)
CN (1) CN1175975A (en)
AR (1) AR001005A1 (en)
AU (1) AU716833B2 (en)
CA (1) CA2211166A1 (en)
DE (1) DE69602355T2 (en)
ES (1) ES2131928T3 (en)
HU (1) HUP9801683A3 (en)
IN (1) IN186941B (en)
MY (1) MY111862A (en)
TR (1) TR199700839T1 (en)
TW (1) TW364923B (en)
WO (1) WO1996026263A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103221525A (en) * 2010-11-16 2013-07-24 陶氏环球技术有限责任公司 Hard surface cleaners comprising low VOC, low odor alkanolamines

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9626610D0 (en) * 1996-12-20 1997-02-05 Unilever Plc Cleaning composition comprising monoalkyl cationic surfactants
US20120186606A1 (en) * 2011-01-20 2012-07-26 Barss Steven H Cleaning of Nozzle Plate
EP3118293B1 (en) 2015-07-13 2020-09-09 The Procter and Gamble Company Cleaning product
EP3118299B1 (en) 2015-07-13 2018-10-17 The Procter and Gamble Company Cleaning product
EP3118294B1 (en) 2015-07-13 2018-10-17 The Procter and Gamble Company Cleaning product
EP3118301B1 (en) 2015-07-13 2018-11-21 The Procter and Gamble Company Cleaning product
EP3572491A1 (en) 2018-05-24 2019-11-27 The Procter & Gamble Company Spray container comprising a detergent composition
EP3572489A1 (en) 2018-05-24 2019-11-27 The Procter & Gamble Company Spray container comprising a detergent composition
EP3572493A1 (en) 2018-05-24 2019-11-27 The Procter & Gamble Company Spray container comprising a detergent composition
EP3572492A1 (en) 2018-05-24 2019-11-27 The Procter & Gamble Company Fine mist hard surface cleaning spray
EP3572490A1 (en) 2018-05-24 2019-11-27 The Procter & Gamble Company Spray container comprising a detergent composition

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2067588A (en) * 1980-01-17 1981-07-30 Unilever Ltd Ovens cleaning compositions
CA2074823C (en) * 1990-01-29 1998-01-20 Daniel W. Michael Liquid hard surface detergent compositions containing zwitterionic detergent surfactant and monoethanolamine and/or beta-aminoalkanol
US5382376A (en) * 1992-10-02 1995-01-17 The Procter & Gamble Company Hard surface detergent compositions
EP0630965A1 (en) * 1993-06-23 1994-12-28 The Procter & Gamble Company Concentrated liquid hard surface detergent compositions containing maleic acid-olefin copolymers

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103221525A (en) * 2010-11-16 2013-07-24 陶氏环球技术有限责任公司 Hard surface cleaners comprising low VOC, low odor alkanolamines

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AU4623196A (en) 1996-09-11
IN186941B (en) 2001-12-15
ES2131928T3 (en) 1999-08-01
TR199700839T1 (en) 1998-01-21
DE69602355T2 (en) 1999-10-21
JPH11500480A (en) 1999-01-12
EP0811053B1 (en) 1999-05-06
HUP9801683A3 (en) 1999-03-01
AR001005A1 (en) 1997-08-27
EP0811053A1 (en) 1997-12-10
WO1996026263A1 (en) 1996-08-29
DE69602355D1 (en) 1999-06-10
CA2211166A1 (en) 1996-08-29
MY111862A (en) 2001-01-31
AU716833B2 (en) 2000-03-09
HUP9801683A2 (en) 1999-01-28
TW364923B (en) 1999-07-21
KR19980702442A (en) 1998-07-15

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