CN117562073A - Weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone - Google Patents
Weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone Download PDFInfo
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- CN117562073A CN117562073A CN202311465546.XA CN202311465546A CN117562073A CN 117562073 A CN117562073 A CN 117562073A CN 202311465546 A CN202311465546 A CN 202311465546A CN 117562073 A CN117562073 A CN 117562073A
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- CN
- China
- Prior art keywords
- clomazone
- flupyrsulfuron
- oxaziclomefone
- weeds
- weeding composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000005499 Clomazone Substances 0.000 title claims abstract description 65
- KIEDNEWSYUYDSN-UHFFFAOYSA-N clomazone Chemical compound O=C1C(C)(C)CON1CC1=CC=CC=C1Cl KIEDNEWSYUYDSN-UHFFFAOYSA-N 0.000 title claims abstract description 65
- HCNBYBFTNHEQQJ-UHFFFAOYSA-N 2-[(4,6-dimethoxypyrimidin-2-yl)carbamoylsulfamoyl]-6-(trifluoromethyl)pyridine-3-carboxylic acid Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=C(N=2)C(F)(F)F)C(O)=O)=N1 HCNBYBFTNHEQQJ-UHFFFAOYSA-N 0.000 title claims abstract description 49
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/86—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P13/00—Herbicides; Algicides
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- Life Sciences & Earth Sciences (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to the field of herbicides, in particular to a weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone, which is used for solving the problem that the combined action effect of the existing weeding composition formed by compounding flupyrsulfuron, oxaziclomefone and clomazone is not verified yet; by reasonably compounding flusulfuron, oxazinone and clomazone, the flusulfuron, oxazinone and clomazone have different action mechanisms, can be absorbed and acted by weeds in various modes at the same time after being compounded, can expand weed killing spectrum, shows obvious synergistic effect, ensures that the weeds are difficult to eliminate the influence of different herbicides on metabolic pathways, further delays the generation of weed resistance, can reduce the dosage of single herbicide, can reduce environmental pollution, and has excellent control effect on annual and perennial grassy weeds, broadleaf weeds and sedge weeds.
Description
Technical Field
The invention relates to the field of herbicides, in particular to a weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone.
Background
The flusulfuron-methyl belongs to sulfonylurea herbicides, is an acetolactate synthase (ALS) inhibitor, can be used for treating soil or stems and leaves of paddy fields, and can inhibit biosynthesis of branched-chain amino acids such as valine, leucine and isoleucine by inhibiting acetolactate synthase of plants after being absorbed by roots, stems and leaves of the plants, so that synthesis of proteins is destroyed, synthesis of DNA and cell division and growth are interfered, and finally plant death is caused.
Oxazinone belongs to organic heterocyclic ring, is a systemic conduction type paddy field herbicide, is absorbed by roots of weeds to stop growth of new roots and new leaves, and is yellow in stem and leaf parts and dead of weeds, and is mainly used for preventing and killing important broadleaf weeds, sedge weeds, barnyard weeds and the like, and barnyard grass removing has special effects and can also be used for lawn weeding. Is safe to rice, and has no adverse effect on wheat, barley, carrot, cabbage, onion and the like of aftercrop crops.
Clomazone is a selective pre-emergence herbicide, can be upwards transmitted to each part of plants through root and bud absorption, so that synthesis of isoprene compounds is inhibited, biosynthesis of carotene and chlorophyll of sensitive plants is hindered, the plants can sprout out of soil, but have no pigment and die in a short period, and the clomazone is mainly used for preventing and killing broadleaf weeds and gramineous weeds in soybean fields, and can also be used for cassava, corn, rape, sugarcane and tobacco fields.
Although the flupyrsulfuron, oxazin and clomazone can effectively remove weeds, the weeding composition is limited by crop safety, the weeding spectrum is limited, the generation of weed resistance is easy to occur after long-term single use, and the environment is polluted.
How to verify the combined action effect of the weeding composition formed by compounding flupyrsulfuron, oxaziclomefone and clomazone is the key of the invention, so that a weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone is needed to solve the problems.
Disclosure of Invention
In order to overcome the technical problems, the invention aims to provide a weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone, which comprises the following components: by reasonably compounding flupyrsulfuron, oxazin and clomazone, as the action mechanisms of flupyrsulfuron, oxazin and clomazone are different, the flupyrsulfuron, oxazin and clomazone can be absorbed by weeds in a plurality of modes at the same time after being compounded, and the problem that the combined action effect of the existing weeding composition formed by compounding the flupyrsulfuron, oxazin and clomazone is not verified yet is solved.
The aim of the invention can be achieved by the following technical scheme:
the weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone comprises active ingredients and auxiliary materials;
the mass ratio of the active ingredients to the auxiliary materials is 1:0.5-4;
the active ingredients comprise flupyrsulfuron, oxazin and clomazone.
As a further scheme of the invention: the mass ratio of the flupyrsulfuron to the oxaziclomefone to the clomazone is 1-10:1-10:1-50.
As a further scheme of the invention: the mass ratio of the flupyrsulfuron to the oxaziclomefone to the clomazone is 1:1:50.
as a further scheme of the invention: the auxiliary materials are all raw materials except the effective components in the pesticide formulation of the weeding composition.
As a further scheme of the invention: the pesticide formulation is water aqua, soluble granule, wettable powder, oil suspending agent, aqueous emulsion and microemulsion.
As a further scheme of the invention: the use of the herbicidal composition for controlling weeds in crop fields.
As a further scheme of the invention: the weeds are annual and perennial grassy weeds, broadleaf weeds and sedge weeds.
The invention has the beneficial effects that:
the weeding composition containing flusulfuron, oxazinone and clomazone is prepared by reasonably compounding flusulfuron, oxazinone and clomazone, and has good control effects on annual and perennial grassy weeds, broadleaf weeds and sedge weeds as the action mechanisms of flusulfuron, oxazinone and clomazone are different and can be absorbed and acted by weeds in various modes at the same time after compounding, so that the weeding spectrum can be enlarged, obvious synergistic effect is shown, the influence of different herbicides on metabolic pathways is difficult to eliminate by the weeds, the generation of weed resistance is further delayed, the dosage of single herbicide can be reduced, and the environmental pollution is also reduced.
Detailed Description
The technical solutions of the embodiments of the present invention will be clearly and completely described below in conjunction with the embodiments of the present invention, and it is apparent that the described embodiments are only some embodiments of the present invention, not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Example 1:
the embodiment is a preparation method of a weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone, and the preparation method comprises the following steps:
step s11: the mass ratio is 1:1:1, weighing flupyrsulfuron, oxazin and clomazone, and uniformly mixing the three to obtain an effective component;
step s12: the mass ratio is 2.2:6.5:1.5:0.8:1.5:0.3:33 weighing calcium lignosulfonate, ethanol, dispersant NNO, fatty alcohol polyoxyethylene ether, organic bentonite, ammonium sulfate and water, and uniformly mixing to obtain auxiliary materials;
step s13: the mass ratio is 1:0.5 weighing the effective components and auxiliary materials, and uniformly mixing to obtain the weeding composition containing flupyrsulfuron-ethyl, oxaziclomefone and clomazone.
Example 2:
the embodiment is a preparation method of a weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone, and the preparation method comprises the following steps:
step s21: the mass ratio is 1:10:1, weighing flupyrsulfuron, oxazin and clomazone, and uniformly mixing the three to obtain an effective component;
step s22: the mass ratio is 2.2:6.5:1.5:0.8:1.5:0.3:33 weighing calcium lignosulfonate, ethanol, dispersant NNO, fatty alcohol polyoxyethylene ether, organic bentonite, ammonium sulfate and water, and uniformly mixing to obtain auxiliary materials;
step s23: the mass ratio is 1:1 weighing the effective components and auxiliary materials, and uniformly mixing to obtain the weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone.
Example 3:
the embodiment is a preparation method of a weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone, and the preparation method comprises the following steps:
step s31: the mass ratio is 1:1:50, weighing flupyrsulfuron, oxazin and clomazone, and uniformly mixing the three to obtain an effective component;
step s32: the mass ratio is 5.4:7.9:3.4:1.4:2.8:0.9:46, weighing calcium lignosulfonate, ethanol, dispersant NNO, fatty alcohol polyoxyethylene ether, organic bentonite, ammonium sulfate and water, and uniformly mixing to obtain auxiliary materials;
step s33: the mass ratio is 1:2 weighing the effective components and auxiliary materials, and uniformly mixing to obtain the weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone.
Example 4:
the embodiment is a preparation method of a weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone, and the preparation method comprises the following steps:
step s41: the mass ratio is 1:10:50, weighing flupyrsulfuron, oxazin and clomazone, and uniformly mixing the three to obtain an effective component;
step s42: the mass ratio is 5.4:7.9:3.4:1.4:2.8:0.9:46, weighing calcium lignosulfonate, ethanol, dispersant NNO, fatty alcohol polyoxyethylene ether, organic bentonite, ammonium sulfate and water, and uniformly mixing to obtain auxiliary materials;
step s43: the mass ratio is 1: and 4, weighing the effective components and auxiliary materials, and uniformly mixing to obtain the weeding composition containing flupyrsulfuron-ethyl, oxaziclomefone and clomazone.
Example 5:
the embodiment is a preparation method of a weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone, and the preparation method comprises the following steps:
step s51: the mass ratio is 10:1:1, weighing flupyrsulfuron, oxazin and clomazone, and uniformly mixing the three to obtain an effective component;
step s52: the mass ratio is 2.2:6.5:1.5:0.8:1.5:0.3:33 weighing calcium lignosulfonate, ethanol, dispersant NNO, fatty alcohol polyoxyethylene ether, organic bentonite, ammonium sulfate and water, and uniformly mixing to obtain auxiliary materials;
step s53: the mass ratio is 1:0.5 weighing the effective components and auxiliary materials, and uniformly mixing to obtain the weeding composition containing flupyrsulfuron-ethyl, oxaziclomefone and clomazone.
Example 6:
the embodiment is a preparation method of a weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone, and the preparation method comprises the following steps:
step s61: the mass ratio is 10:10:1, weighing flupyrsulfuron, oxazin and clomazone, and uniformly mixing the three to obtain an effective component;
step s62: the mass ratio is 2.2:6.5:1.5:0.8:1.5:0.3:33 weighing calcium lignosulfonate, ethanol, dispersant NNO, fatty alcohol polyoxyethylene ether, organic bentonite, ammonium sulfate and water, and uniformly mixing to obtain auxiliary materials;
step s63: the mass ratio is 1:1 weighing the effective components and auxiliary materials, and uniformly mixing to obtain the weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone.
Example 7:
the embodiment is a preparation method of a weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone, and the preparation method comprises the following steps:
step s71: the mass ratio is 10:1:50, weighing flupyrsulfuron, oxazin and clomazone, and uniformly mixing the three to obtain an effective component;
step s72: the mass ratio is 5.4:7.9:3.4:1.4:2.8:0.9:46, weighing calcium lignosulfonate, ethanol, dispersant NNO, fatty alcohol polyoxyethylene ether, organic bentonite, ammonium sulfate and water, and uniformly mixing to obtain auxiliary materials;
step s73: the mass ratio is 1:2 weighing the effective components and auxiliary materials, and uniformly mixing to obtain the weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone.
Example 8:
the embodiment is a preparation method of a weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone, and the preparation method comprises the following steps:
step s81: the mass ratio is 10:10:50, weighing flupyrsulfuron, oxazin and clomazone, and uniformly mixing the three to obtain an effective component;
step s82: the mass ratio is 5.4:7.9:3.4:1.4:2.8:0.9:46, weighing calcium lignosulfonate, ethanol, dispersant NNO, fatty alcohol polyoxyethylene ether, organic bentonite, ammonium sulfate and water, and uniformly mixing to obtain auxiliary materials;
step s83: the mass ratio is 1: and 4, weighing the effective components and auxiliary materials, and uniformly mixing to obtain the weeding composition containing flupyrsulfuron-ethyl, oxaziclomefone and clomazone.
Comparative example 1:
this comparative example differs from example 8 in that comparative example 1 is flupyrsulfuron-ethyl instead of the herbicidal composition containing flupyrsulfuron-ethyl, oxazin, clomazone.
Comparative example 2:
this comparative example differs from example 8 in that comparative example 2 is oxaziclomefone instead of the herbicidal composition containing flupyrsulfuron, oxaziclomefone, clomazone.
Comparative example 3:
this comparative example differs from example 8 in that comparative example 3 is clomazone instead of a herbicidal composition containing flupyrsulfuron, oxazin, clomazone.
Test examples
Test object: rice weeds: annual and perennial grassy weeds, broadleaf weeds and sedge weeds;
test agent: the agents of examples 1-8 and comparative examples 1-3;
the test method comprises the following steps: the weeds are in the 2-3 leaf stage, the medicament is diluted by 800 times by adding water, and the stem and leaf are sprayed for 1 time by adopting a knapsack sprayer, wherein the dosage of the medicament is 80g a.i/hm 2 Fresh weight control effect after 30 days of investigation.
The test results are shown in the following table:
medicament | Gramineous weeds preventing effect, percent | Broad leaf weed control effect, percent | Weeds of the family Cyperaceae% |
Example 1 | 94.9 | 94.0 | 92.8 |
Example 2 | 92.4 | 92.5 | 91.9 |
Example 3 | 96.1 | 94.8 | 95.3 |
Example 4 | 94.1 | 93.8 | 93.4 |
Example 5 | 91.8 | 91.7 | 91.3 |
Example 6 | 92.2 | 92.7 | 93.0 |
Example 7 | 93.6 | 93.9 | 93.2 |
Example 8 | 95.4 | 93.9 | 94.7 |
Comparative example 1 | 62.3 | 62.9 | 61.0 |
Comparative example 2 | 70.2 | 73.5 | 72.1 |
Comparative example 3 | 73.1 | 72.4 | 72.8 |
Referring to the data in the table, it can be known that the flucarbazone, oxazin and clomazone can be used independently to prevent and treat weeds, but the effect is not obvious enough, and the flucarbazone, oxazin and clomazone are reasonably compounded to play an optimal prevention effect, wherein when the mass ratio of the flucarbazone to the oxazin to the clomazone is 1:1: the prevention effect on weeds at 50 can reach 94.8% or more.
In the description of the present specification, the descriptions of the terms "one embodiment," "example," "specific example," and the like, mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the present invention. In this specification, schematic representations of the above terms do not necessarily refer to the same embodiments or examples. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The foregoing is merely illustrative and explanatory of the invention, as various modifications and additions may be made to the particular embodiments described, or in a similar manner, by those skilled in the art, without departing from the scope of the invention or exceeding the scope of the invention as defined in the claims.
Claims (7)
1. The weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone is characterized by comprising active ingredients and auxiliary materials;
the mass ratio of the active ingredients to the auxiliary materials is 1:0.5-4;
the active ingredients comprise flupyrsulfuron, oxazin and clomazone.
2. The weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone according to claim 1, wherein the mass ratio of flupyrsulfuron to oxaziclomefone to clomazone is 1-10:1-10:1-50.
3. The weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone according to claim 2, wherein the mass ratio of flupyrsulfuron to oxaziclomefone to clomazone is 1:1:50.
4. the weeding composition containing flupyrsulfuron, oxazin and clomazone according to claim 1, wherein the auxiliary materials are all raw materials except the effective components in the pesticide dosage form of the weeding composition.
5. The weeding composition containing flupyrsulfuron, oxaziclomefone and clomazone according to claim 4, wherein the pesticide is in the form of water, soluble granules, wettable powder, oil suspension, aqueous emulsion or microemulsion.
6. The weeding composition containing flupyrsulfuron, oxazin and clomazone according to claim 1, wherein the weeding composition is used for preventing and controlling weeds in crop fields.
7. A herbicidal composition comprising flupyrsulfuron, oxazin, clomazone as claimed in claim 6, wherein the weeds are annual and perennial grasses, broadleaf weeds and sedge weeds.
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