CN1175604A - Filling mother particle for spinning resin - Google Patents
Filling mother particle for spinning resin Download PDFInfo
- Publication number
- CN1175604A CN1175604A CN 97100365 CN97100365A CN1175604A CN 1175604 A CN1175604 A CN 1175604A CN 97100365 CN97100365 CN 97100365 CN 97100365 A CN97100365 A CN 97100365A CN 1175604 A CN1175604 A CN 1175604A
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- CN
- China
- Prior art keywords
- grade resin
- spinning grade
- parent granule
- filler parent
- spinning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
A filling mother particle for spinning resin is made from spinnning resin (50-85%) which may be polyester, PET, polymide or polypropylene resin, clay (10-50%) which may be montmorillonite, kaolinite and powdered ore and has 0.01-2 microns of size, and disperser (1-6%) which may be amino acid or other through mixing, fusion and granulating, and features high dispersity easily being machined, wide frequency response and 85-90% of radiation rate.
Description
The present invention relates to a kind of thermoplastic resin composition, the filler parent granule that particularly a kind of spinning grade resin is used.
CN1052712 discloses the synthon of sneaking into aluminum oxide, titanium, platinum or palladium inorganic particulate powder, and this fibre product has warm effect.
CN1095118 discloses the man-made fiber that adopts far-infrared ceramic powder and high molecular polymer master batch to make, and this fiber has elasticity and flexibility.
But powder used in the above-mentioned prior art is mixed by several inorganic particulates, wherein each inorganic particulate has a far infrared radiation feature peak separately, therefore in fibre product, the inhomogeneous and narrowly distributing of inorganic particulate radiant ratio causes practical effect relatively poor.
It is inhomogeneous that the present invention has overcome in the prior art radiant ratio, the shortcoming of narrowly distributing and provide the high spinning grade resin of a kind of radiant ratio filler parent granule, goods to have good heat-insulating property.
The filler parent granule that spinning grade resin of the present invention is used comprises following component and weight (weight percentage):
Spinning grade resin 50-85
Clay 10-50
Dispersion agent 1-6
Above-mentioned spinning grade resin is polyester (PET), polymeric amide (nylon 6,66), acrylic resin.
Above-mentioned clay is kaolin, covers and hold in the palm soil or ore powder.The particle diameter of clay is 0.01-2 μ m, and preferable consumption is 20-40%.Inorganic substance homogeneous and that have flaky crystalline structure that clay of the present invention is made up of different chemical components such as aluminum oxide, silicon-dioxide, ferric oxide, titanium oxide, calcium oxide, magnesium oxide.
Above-mentioned dispersion agent is amino acid, ionic or nonionic surface active agent.As Triton TritonX and tween Tween, the preferable consumption of dispersion agent is 2-4%.
Above-mentioned ionogenic surfactant can be cationic surfactant or aniorfic surfactant.
The filler parent granule that spinning grade resin of the present invention is used has good dispersity, easily processing, the advantage that cost is low, the more important thing is that to have frequency response wide, radiant ratio height and radiant ratio be equally distributed characteristics in wide frequency ranges, and textile fabrics has good use properties.
Embodiment 1,
Get raw material polyester (PET) 70 grams, cover holder soil 30 grams, Triton 3 grams after mechanically mixing, melt extrude granulation at 260～280 ℃, make the polyester filler parent granule.Embodiment 2,
Get raw material nylon 6 70 grams, kaolin 30 grams, amino acid 3 grams after mechanically mixing, melt extrude granulation at 260～280 ℃, make the nylon filler parent granule.Embodiment 3,
Get raw material polypropylene 70 grams, ore powder 30 grams, tween 3 grams after mechanically mixing, melt extrude granulation at 200～240 ℃, make polypropylene and fill master batch.Embodiment 4,
Get raw material polypropylene 80 grams, ore powder 20 grams, tween 2 grams after mechanically mixing, melt extrude granulation at 200～240 ℃, make polypropylene and fill master batch.Comparative Examples,
Get raw material polypropylene 70 grams, ceramics powder 30 grams, tween (Tween) 3 grams after mechanically mixing, melt extrude granulation at 200～240 ℃, make polypropylene and fill master batch.
The radiant ratio of the foregoing description in different wavelength range sees Table 1.
Table 1,
| Wavelength (μ m) | Radiant ratio (%) | |||
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 Comparative Examples | |
| 8.00 8.55 9.50 10.6 12.0 14.0 17.0 19.0 21.0 23.0 | ????85 ????84 ????86 ????85 ????86 ????84 ????86 ????84 ????85 ????85 | ????86 ????87 ????86 ????86 ????87 ????88 ????86 ????90 ????84 ????90 | ????87 ????87 ????87 ????87 ????88 ????88 ????90 ????92 ????90 ????85 | ????86????84 ????87????61 ????86????71 ????86????81 ????87????94 ????87????89 ????89????- ????90????- ????90????- ????86????- |
Claims (10)
1, the filler parent granule used of a kind of spinning grade resin is characterized in that described filler parent granule comprises following component and content: (weight percentage)
Spinning grade resin 50-85
Clay 10-50
Dispersion agent 1-6
2, the filler parent granule used of a kind of spinning grade resin according to claim 1 is characterized in that described spinning grade resin is a polyester PET.
3, the filler parent granule used of a kind of spinning grade resin according to claim 1 is characterized in that described spinning grade resin is a polymeric amide.
4, the filler parent granule used of a kind of spinning grade resin according to claim 3 is characterized in that described spinning grade resin is nylon 6 or nylon 66.
5, the filler parent granule used of a kind of spinning grade resin according to claim 1 is characterized in that described spinning grade resin is an acrylic resin.
6, the filler parent granule used of a kind of spinning grade resin according to claim 1 is characterized in that described clay is the kaolin of particle diameter 0.01-2 μ m.
7, the filler parent granule used of a kind of spinning grade resin according to claim 6 is characterized in that described clay is illiteracy holder soil and the ore powder of particle diameter 0.01-2 μ m.
8, the filler parent granule used of a kind of spinning grade resin according to claim 1 is characterized in that described dispersion agent is a Triton.
9, the filler parent granule used of a kind of spinning grade resin according to claim 8 is characterized in that described dispersion agent is amino acid and tween.
10, the filler parent granule used of the described a kind of spinning grade resin of .9 according to Claim 8, the consumption that it is characterized in that described dispersion agent is 2-4%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97100365A CN1073599C (en) | 1997-01-31 | 1997-01-31 | Filling mother particle for spinning resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97100365A CN1073599C (en) | 1997-01-31 | 1997-01-31 | Filling mother particle for spinning resin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1175604A true CN1175604A (en) | 1998-03-11 |
| CN1073599C CN1073599C (en) | 2001-10-24 |
Family
ID=5164999
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97100365A Expired - Fee Related CN1073599C (en) | 1997-01-31 | 1997-01-31 | Filling mother particle for spinning resin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1073599C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101219367B (en) * | 2007-09-30 | 2010-05-19 | 四川大学 | Amino acid modified montmorillonite-synthesized polymer hybridisation microsphere, preparation method and application thereof |
| CN106633392A (en) * | 2016-12-02 | 2017-05-10 | 长兴天晟能源科技有限公司 | Functional master batch capable of improving antistatic property of polypropylene |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1055709C (en) * | 1995-05-19 | 2000-08-23 | 中国科学院化学研究所 | Glass fiber reinforced polyester (PET) composite material and its preparing method |
| CN1068022C (en) * | 1995-11-10 | 2001-07-04 | 中国科学院化学研究所 | High-toughness polypropylene composite material and preparing process thereof |
-
1997
- 1997-01-31 CN CN97100365A patent/CN1073599C/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101219367B (en) * | 2007-09-30 | 2010-05-19 | 四川大学 | Amino acid modified montmorillonite-synthesized polymer hybridisation microsphere, preparation method and application thereof |
| CN106633392A (en) * | 2016-12-02 | 2017-05-10 | 长兴天晟能源科技有限公司 | Functional master batch capable of improving antistatic property of polypropylene |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1073599C (en) | 2001-10-24 |
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