CN1175602A - Shade-proof antifogging agent for synthtic resin and synthetic resin composition and agricultural film contg same - Google Patents
Shade-proof antifogging agent for synthtic resin and synthetic resin composition and agricultural film contg same Download PDFInfo
- Publication number
- CN1175602A CN1175602A CN97118507A CN97118507A CN1175602A CN 1175602 A CN1175602 A CN 1175602A CN 97118507 A CN97118507 A CN 97118507A CN 97118507 A CN97118507 A CN 97118507A CN 1175602 A CN1175602 A CN 1175602A
- Authority
- CN
- China
- Prior art keywords
- composition
- cloudy
- compound
- antifogging agent
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/25—Greenhouse technology, e.g. cooling systems therefor
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Protection Of Plants (AREA)
- Greenhouses (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Abstract
To obtain an anticlouding and antifogging agent which can impart excellent anticlouding properties and antifogging properties to a synthetic resin of polyalkene resin when added thereto, and agricultural film by utilizing the excellent anticlouding properties in low temperature, perdurability of anticlouding properties, transparency, and antifogging properties thereof. This anticlouding and antifogging agent for synthetic resin comprises a compound (A) a specifical polyoxyethylene alkylamine or amide (thereinafter called compound (1)) or fatty acid ester of compound (1), (B) an ester of a 2-18 carbon atom polyhydric alcohol with a fatty acid or an epoxy compound adduct of this ester and (C) a specifical branched higher fatty acid or an ester of this branched higher fatty acid. The mixing ratio among these components are such that (A+B)/C=50/50 to 98/2, and A/B=100/0 to 0/100 by weight.
Description
The invention relates to the anti-cloudy antifogging agent that synthetic resins is used, with its synthetic resin combination and agricultural film, more detailed saying, be about by in the synthetic resins of polyolefin-based resins etc., interpolation can pay good anti-negative can and the synthetic resins of anti-fog performance with anti-cloudy antifogging agent, and use its low temperature anti-negative, prevent cloudy persistence, the transparency, the agricultural film that antifog property is good.
Synthetic resins is because its advantageous property uses in extensive fields now.Yet originally all inconvenience owing to be hydrophobicity, so when using molded article, with conditions such as temperature and humidities, suction or agglomerative moisture are from the teeth outwards topped with tiny water droplet, because it is vaporific to produce the moon, is brought in the surface of synthetic resins.
For example, when plastic film is used for the cultivation of agricultural greenhouse or tunnel, from the face of land or the farm crop moisture evaporated, condense on the film internal surface with tiny water droplet, postponed the growth of farm crop, water droplet is dropped on the farm crop, becomes the reason that disease takes place.
In order to prevent these weak points, as the present method that adopts mostly, be when the shaping synthetic resin goods, cooperation is prevented cloudy agent and is carried out the blended method, perhaps, after shaping, prevents the method for cloudy agent in its surface coated.As anti-cloudy agent used in these methods.The polyvalent alcohol high-grade aliphatic ester that sorbitan high-grade aliphatic ester (special public clear 38-6572 number) and their ethylene oxide adduct (special public clear 55-9431 number), glycerin fatty acid ester (special public clear 38-4174 number), fatty acid polyglycerol ester (special public clear 43-8605 number) etc. are arranged.Yet these anti-cloudy agent are difficult to have simultaneously flat (the anti-feminine gender of low temperature, initial stage prevent negative) of anti-yin edema and lasting anti-feminine gender, in the bigger place of daily temperature difference, or the quite low region of temperature, its anti-feminine gender can be not enough fully.
As the anti-cloudy agent that addresses this is that polyoxyethylene alkyl amine (special public clear 44-15184 number) is arranged, the title complex (spy opens clear 48-104638) of its high-grade aliphatic ester (special public clear 62-33256 number) and these and polyvalent alcohol ester fat acid ester etc.The two kinds of anti-cloudy agent in back, though the anti-gentle persistence of yin edema is all fine,, film surface produces the frostization phenomenon and the transparency is significantly reduced, and can not durablely use.
Use the agricultural greenhouse and the tunnel that contain anti-cloudy agent synthetic resins made membrane, produced new problem sometimes.The temperature difference inside and outside the film is very big.During night that humidity is high and rainfall sooner or later, often can be observed in the phenomenon that produces mist near the film internal surface.The generation of this mist makes the crop of cultivation in greenhouse and the tunnel withered, perhaps rots, and then forms the reason of various diseases.
As the means that address these problems, its method is to sneak into to have cooperated and fluorine that anti-cloudy agent is called antifogging agent together is that tensio-active agent (special public clear 59-35573 number) and fluorine are oligopolymer (spy public clear 62-18579 number) etc. in synthetic resins.These additives, though can obtain good anti-fog effect, yet, high because of price, and the product manufacturing expense is increased.
Present inventors are for addressing these problems, and through a large amount of research, the result by add the anti-cloudy antifogging agent that can pay good anti-negative energy and anti-fog performance in synthetic resins such as polyolefin-based resins, has finished the present invention.
That is, the invention relates to by following (A), (B) and the synthetic resins that (C) forms with anti-cloudy antifogging agent composition, with weight ratio [(A)+(B)]/(C)=50/50～98/2, and ratio (A)/(B)=100/0～0/100.
By the compound (to call compound (1) in the following text) of (A) or (1) expression,
In the formula, R
1Be the alkyl of 12～22 carbon atoms, the acyl group of the alkenyl of 12～22 a carbon atoms or 12-22 carbon atom, m and n are the numbers more than 1 that forms m+n=2～10 (mean value),
Or the fatty acid ester of compound (1), still, lipid acid is in 2 hydroxys of saturated or unsaturated fatty acids, compound (1) of 12～22 carbon atoms, 0.5～2.0 forms and the ester bond of this lipid acid,
(B) be the fatty acid ester of the polyvalent alcohol of 2～18 carbon atoms, but lipid acid is the saturated or unsaturated fatty acids of 12～22 carbon atoms.
Or the alkylidene group epoxy adduct of this fatty acid ester, but the carbonatoms of alkylidene group epoxy is 2～3.Average addition mole number is 0.1～20 mole for 1 moles of fatty acids ester.
(C) the side chain higher fatty acid of representing with formula (2)
In the formula, R
2And R
3Be the straight or branched alkyl of 5-16 carbon atom,
Or the fatty acid ester of this side chain higher fatty acid (2) and compound (1), but, in 2 hydroxyls of compound (1), the ester bond of 0.5～2.0 formation and this lipid acid.
The invention relates to 100 weight part synthetic resins, contain 0.1～5 weight part, the compound resin composition of the antifog composition of the above-mentioned anti-the moon of best 0.5～4 weight part.
In addition, the invention relates to the agricultural film that forms by above-mentioned compound resin composition.
Have again, the invention relates to by one deck at least the made agricultural film of film that above-mentioned compound resin composition forms more than two layers.
The invention relates to by above-mentioned (A), (B) and the synthetic resins that (C) forms with anti-cloudy antifogging agent composition, wherein wt is than being [(A)+(B)]/(C)=70/0～90/5, and (A)/(B)=100/0～10/90.
The invention relates in above-mentioned (C) composition the R in the formula (2)
2And R
3It is the anti-cloudy antifogging agent composition of synthetic resins that has the branched-chain alkyl of the methyl more than 2 respectively.
The invention relates to the agricultural film that forms by above-mentioned anti-cloudy antifogging agent composition and polyolefin resin.
The invention relates in the following formula (1) R
1Be the alkyl-thiazolinyl or the acyl group of 16～22 subnumbers, m and n are the anti-cloudy antifogging agent compositions of counting more than 1 that forms m+n=2～4 (mean value).
In addition, the invention relates in above-mentioned (A) composition, the lipid acid of the fatty acid ester of compound (1) is the saturated or unsaturated fatty acids of 14～22 carbonatomss, in 2 hydroxyls of compound (1), and the anti-cloudy antifogging agent composition of the ester bond of 1.0～1.5 formation and this lipid acid.
The present invention is again about in above-mentioned (B) composition, the lipid acid of the fatty acid ester of the polyvalent alcohol of 3-18 carbonatoms is the saturated or unsaturated fatty acids of 14～18 carbonatomss, the carbonatoms of the alkylidene group epoxy of the alkylidene group epoxy adduct of this fatty acid ester is 2 or 3, average addition mole number is 1～6 mole anti-cloudy antifogging agent composition for 1 moles of fatty acids ester.
Have again, the invention relates in above-mentioned (C) composition the R in the formula (2)
2And R
3Be the alkyl of the straight or branched of 5-11 carbonatoms, in 2 hydroxyls of compound (1), the antifog composition of anti-the moon of the ester bond of 1.0～1.5 formation and this lipid acid.
In addition, agricultural of the present invention has the anti-feminine gender of good low temperature with film, and is lasting anti-negative, transparent and antifog property.
Below illustrate in greater detail the present invention.
Prevent cloudy agent as agricultural with film, general sorbitan high-grade aliphatic ester and the higher fatty acid polyglycerol ester etc. of using, flat as the anti-yin edema that improves these, the anti-negative and anti-negative auxiliary agent (being called moistening rising agent herein) of low temperature of initial stage uses the ethylene oxide adduct of polyhydric alcohol fatty acid ester and the ethylene oxide adduct of higher alcohols etc.When usually using these moistening rising agents and when interpolation relatively, lasting anti-negative can the reduction.
Though it is flat that (A) of the present invention component cpd (1) has good anti-yin edema,, lasting anti-negative poor when using separately, therefore, the present invention is with the high-grade aliphatic ester of compound (1) and (B) polyhydric alcohol fatty acid ester and the usefulness of composition.Can not reduce anti-lastingly feminine gender in view of the above, and it is flat to improve anti-yin edema, the initial stage prevents negative and low temperature is prevented negative.
In the compound (1), the carbonatoms of the alkyl R1 in the general expression (1) is 12～22.When under general environment, using this agent, 16～22 good especially.On the other hand, the addition mole number mean value of the oxyethane of representing with the m+n in the general expression (1) is 2～10 (m and n are the number more than 1), preferably m+n=2～4 (mean values).Particularly improve that anti-yin edema is flat, anti-feminine gender of initial stage and low temperature is anti-when negative, or when reducing melting point (liquid under the normal temperature) and suppressing atomizing, preferably uses a spot of m+n mean value greater than 4 compound.
In addition, the fatty acid ester of (A) of the present invention component cpd (1) also can use separately, and its anti-yin edema is flat, anti-negative, the anti-feminine gender of low temperature and lasting anti-negative very good of initial stage.The gamma value of this compound, for 1 mole compound (1), lipid acid is 0.5～2.0 mole of ester bond, 1.0～1.5 moles good especially.When gamma value is lower than these, can cause lasting anti-negative reduction or cause atomizing that when gamma value was too high, low temperature was prevented negative and anti-negative meeting reduction of initial stage.And employed lipid acid is saturated or unsaturated higher fatty acid, the carbonatoms of lipid acid be 12～22 the most suitable, but tetradecanoic acid, palmitinic acid, stearic acid, mountain Yu acid and their nitration mixture are good especially.
Above-mentioned (A) composition can use separately or with mixture more than 2 kinds.
Lipidol acid esters as (B) of the present invention composition polyvalent alcohol, the polyvalent alcohol that constitutes them is the alcohol of 2-18 carbonatoms, for example, preferably be selected from sorbitan, sorbyl alcohol, glycerol, polyglycerol, tetramethylolmethane, Dipentaerythritol, sucrose, ethylene glycol, polyoxyethylene glycol, propylene glycol, polypropylene glycol, neopentyl glycol, 1,4-butyleneglycol, 1,6-hexylene glycol and TriMethylolPropane(TMP), wherein: sorbitan, sorbyl alcohol, glycerol, polyglycerol, tetramethylolmethane, Dipentaerythritol, just lasting anti-negative aspect is best.The lipid acid that constitutes this ester is saturated or unsaturated higher fatty acid, the carbonatoms of lipid acid is 12～22, preferably 14～18.These lipid acid can use separately, also can be used in combination more than 2 kinds.
(B) composition of Shi Yonging has 1 ester group at least in the molecule in the present invention, in the same molecule, and hydroxyl groups number before (ester number)/esterification)≤0.5, the most desirable.
As the epoxide affixture of polyhydric alcohol fatty acid ester, the epoxide of 2～3 carbon atoms arranged, preferably the independent addition of oxyethane.Its addition mole number for 1 mole of this ester, is 0.1～20 mole, particularly during sorbitan-fatty acid ester, is preferably 1～10 mole.These epoxide affixtures, the mixture that can be used as more than 2 kinds uses.
Above-mentioned (B) composition can use separately, also can use by the mixture more than 2 kinds.
(A) composition and (B) proportioning of composition are any cooperation ratio between (A)/(B)=100/0～0/100 among the present invention, particularly make agricultural when use film by polyolefin-based resins, preferably 100/0～10/90, and (A) composition is necessary composition.Its reason is, by with (A) composition as must composition, not only do not reduce anti-cloudy persistence, and it is flat to improve anti-yin edema, the initial stage, anti-negative and low temperature was prevented feminine gender, and produced mist less.
(C) of the present invention composition is by the alkyl R in the side chain higher fatty acid formula of general expression (2) expression
2And R
3It is the straight or branched alkyl of 5-16 carbonatoms.As side chain higher fatty acid, R
2And R
3Be straight chained alkyl, 2-hexyl sebacic acid, 2-heptyl undecanoic acid, 2-octyl group dodecylic acid, 2-decyl tetradecanoic acid, 2-undecyl pentadecylic acid, 2-dodecyl hexadecanoic acid, 2-tetradecyl octadecanoic acid, 2-hexadecyl octadecanoic acid, 2-tetradecyl arachic acid, 2-hexadecyl arachic acid etc. are arranged.R
2And R
3Be branched-chain alkyl, have 2,10-dimethyl-5-undecanoic acid, 4,8-dimethyl-5-undecanoic acid (different tetradecanoic acid), 2,2,4,8,10,10-hexamethyl-5-undecanoic acid (isostearic acid), 4,12-dimethyl-9-pentadecylic acid etc.Wherein, when agricultural is used in film, in side chain higher fatty acid or this fatty acid ester, the R in the general expression (2)
2And R
3Be the branched-chain alkyl that has 2 above methyl respectively, generally comparatively desirable.When using polyolefin-based resins is effective.The ester of compound (1) and above-mentioned side chain higher fatty acid is to have carried out the compound of 0.5～2.0 mole of above-mentioned side chain higher fatty acid in conjunction with ester for 1 mole compound (1).
Feature of the present invention be with (C) composition as must composition, by adding (C) composition, can prevent to cause film surface frostization phenomenon, and can prevent the interior generation of agricultural greenhouse mist by anti-cloudy agent.As its function, following effect is arranged, control the amount of separating out of anti-cloudy agent, and suppressed the crystallization of the anti-cloudy agent on film surface, anti-fog effect, the alkyl carbon atoms number is many more, if same carbon atoms number, the side chain of alkyl (side chain) number is many more, good more.So, the R in the general expression (2)
2And R
3The alkyl that preferably contains 2 above methyl respectively.Above-mentioned (C) composition can use separately, also can use by the mixture more than 2 kinds.
Anti-cloudy agent (A) composition+(B) composition and (C) proportioning of composition, with weight ratio is [(A)+(B)]/(C)=50/50～98/2, particularly making by polyolefin-based resins when using in the agricultural film, preferably [(A)+(B)]/(C)=70/30～95/5.When (C) ratio of composition was greater than above-mentioned scope, anti-feminine gender can degenerate, otherwise, when less than above-mentioned scope, inoperative to antifrost effect and anti-fog effect.When with (A) composition and time spent, the further anti-fog effect of performance.
Can use the synthetic resins of anti-cloudy antifogging agent of the present invention, polyvinyl chloride (PVC) RESINS or polyethylene, polypropylene, ethylene-vinyl acetate copolymer polyolefin-based resins such as (EVA) are arranged, be specially adapted to polyolefin-based resins.
As the method for using anti-cloudy antifogging agent of the present invention, for example, carry out the blended method during forming synthetic resin, or, anti-cloudy antifogging agent of the present invention is dissolved in the appropriate solvent, with the method for this solution coat to the forming synthetic resin product etc., preferably use and carry out the blended method when being shaped again.
The amount of interpolation anti-cloudy antifogging agent of the present invention is different with kind, thickness and the transmittance of molding in synthetic resins, but for 100 weight part synthetic resins, is the anti-cloudy antifogging agent of 0.1～5 weight part, preferably 0.5～4.0 weight part.During addition less than 0.1 weight part, can not fully obtain anti-negative energy.When surpassing 5 weight parts, in film, anti-cloudy antifogging agent of the present invention is too much, and to exosmosis, surfaces of tacky causes the frostization phenomenon, so can not be satisfactory.
In addition, use in the film at compound resin composition of the present invention and agricultural, except anti-cloudy antifogging agent of the present invention, also can add the anti-caking agent of plasticizer, oxidation inhibitor, photostabilizer, UV light absorber, silicon-dioxide etc. as required, reaching fluorine is tensio-active agent (antifogging agent), does not have any problem.
Agricultural synthetic resin multilayer film of the present invention, according to purposes, balance is carried out in ooze out control, dirt resistance, film severe character such as (density) to the mechanical properties (obdurability, tensile strength etc.) of film, heat retaining property, the transparency (resin itself), anti-cloudy agent, and used resin is unqualified.Yet in the synthetic resins multilayer film that form more than 2 layers, one deck must be a synthetic resin film of the present invention at least.Anti-cloudy antifogging agent of the present invention can add in random layer no matter be internal layer or skin, is not limited in 1 layer, can add in the layer more than 2 layers.Example as multilayer film, the EVA-EVA-EVA three-layer thin-film that has used different VA% (the content % of vinyl acetate between to for plastic unit) ethylene-vinyl acetate copolymer (EVA) is arranged, the three-layer thin-film of the three-layer thin-film of polyethylene (LDPE)-EVA-LDPE, straight-chain low density polyethylene (LLDPE)-EVA-LLDPE etc.
By anti-cloudy antifogging agent of the present invention being added to film of polyolefin resin and containing in its synthetic resins multilayer film, prevent negative, low temperature anti-negative, anti-cloudy persistence, the transparency and antifog property and brought into play the good initial stage
Embodiment
Below show embodiments of the invention, but the present invention is not limited in these embodiment.Embodiment and comparative example have been put down in writing polyvinyl chloride, new LDPE (film grade) (LDPE), straight-chain low density polyethylene (LLDPE), ethylene-vinyl acetate copolymer (EVA) be as matrix, the test-results of the anti-feminine gender of resulting single or multiple lift film, antifog property and the transparency.Anti-cloudy antifogging agent of the present invention is prepared as follows, and carries out various evaluations.
(A) composition:
By synthetic one-level alkylamine of lipid acid or acid amides, carry out the additional ring oxidative ethane.The fatty acid ester that again it is synthesized it as raw material.
(B) composition:
Have commercially availablely, just use it.Do not have commercially availablely, carry out esterification with the pure and mild lipid acid of multivalence.Carry out the oxyethane addition as required.
(C) composition:
Have commercially availablely, just use it, do not have commercially availablely, commercially available side chain higher alcohols is carried out oxidizing reaction under alkali dissolves, obtain the side chain higher fatty acid.
[anti-negative can the test]
Prevent negative can the test as follows.Promptly, make the small-sized room (vertical 330 * horizontal 290 * high 250mm of stainless steel control, deck becomes 12 degree angles with horizontal plane), the side covers commercially available agricultural vinyl film, and deck covers the film sample of anti-cloudy test usefulness, then, this room is immersed in the Water Tank with Temp.-controlled that keeps certain temperature, and be placed in the thermostatic chamber (fill up bed surface with the water surface and form closed system, make to be full of water vapor in the room).With anti-negative, the anti-negative and anti-cloudy persistence of low temperature of this device evaluation initial stage.Evaluation result is represented with following benchmark.
(opinion rating)
5: the complete transparent cloudy mist that do not have.
4: almost transparent, few water droplet is arranged.
3:, certain transparent feel is arranged though big water droplet is arranged.
2: all adhere to big water droplet, opaque.
1: all adhere to fine liquid particles, opaque.
Level between the example 4-5:4 and 5 is near 4.
Level between the 5-4:5 and 4 is near 5.
The evaluation of each performance is undertaken by following condition.
Initial stage is anti-negative:
With 15 ℃ of 5 ℃/water temperatures of room temperature, the anti-yin edema of placing after 2 hours is flat, as following metewand.
◎: after 2 hours, surpass 4 level.
After zero: 2 hour, 4 level.
△: after 2 hours, 3 level.
*: after 2 hours, 2 level.
After * *: 2 hours, 1 level.
Low temperature is anti-negative: the anti-yin edema of estimating after 15 ℃, 6 hours of the 5 ℃/water temperatures of room temperature is flat.
Anti-cloudy persistence: the anti-yin edema of estimating after 40 ℃, 100 days of the 5 ℃/water temperatures of room temperature is flat.
[anti-fog performance test]
4 rooms (vertical 330 * horizontal 290 * high 560mm) that the side fences up and makes to measure mist with plate, deck becomes 10 degree angles with horizontal plane), its deck and side inner face cover the film of estimating usefulness, and this room is soaked in the Water Tank with Temp.-controlled of 40 ℃ of maintenances, place 24 hours under 25 ℃ of room temperatures.Then, the limit remains on 40 ℃ with Water Tank with Temp.-controlled, and 5 ℃ thermostatic chamber is put on the limit.For room, portion is provided with and regulates the dividing plate insertion mouth that infeeds the water vapor amount within it, makes it on tank water surface top, regulates this dividing plate, makes its not dried wet steam that is produced by the tank water surface of scratching.Under such condition, be easy to observe the mist that produces near the film internal surface.This mist situation occurred after with the naked eye observing 15 minutes.Show this evaluation result with following master meter.
(opinion rating)
Zero: not observing near the film internal surface has mist to produce.
△: observing near the film internal surface has the mist of minute quantity to produce.
*: observing near the film internal surface has mist to produce.
* *: observes near the film internal surface has a large amount of mists to produce.
Example zero～△: the mist of generation zero and △ between, approach zero.
△～zero: the mist of generation approaches △ between △ and zero.
[albefaction test]
For the frost phenomenon that the anti-cloudy agent of testing by film surface causes, film was handled for two weeks down at 40 ℃, measure the turbidity of film with Bayes's meter.In view of the above the transparency level of trying to achieve was represented with following 5 stages.
(transparency level)
Good, ◎＞zero＞△＞*＞* * bad.
Embodiment 1～11
Form:
Polyvinyl chloride (PVC) RESINS (mean polymerisation degree 1300) 100 weight parts
Two-2-ethylhexyl phthalate, 45 weight parts
(flower king's (strain), PVC ニ サ ィ ザ-80)
Tritolyl Phosphate 5 weight parts
(big eight chemical industry institutes (strain))
Stablizer (Ba-Zn system) 1.5 weight parts
(winning field processing (strain), BZ-330M)
Stablizer 1.0 weight parts
(winning field processing (strain) PSE-1020B)
Resins, epoxy (シ ェ Le, ェ ピ コ-ト 828) 1.5 weight parts
Methylene-bis stearylamide 0.3 weight part
(Japan changes into (strain), PVC ス ァ マ ィ De LA)
Anti-cloudy antifogging agent of the present invention (B) composition 2.0 weight parts
(C) composition 0.3 weight part
To after 7 minutes, under 160 ℃ temperature, carry out extruding in 5 minutes with the test roller melting mixing of 160 ℃ of surface temperatures by the above-mentioned title complex that forms formed, obtain the thick film of 100 μ m, be used for anti-feminine gender, antifog property and transparency test.The prescription of anti-cloudy antifogging agent is shown in table 1, and evaluation result is shown in table 2.
Comparative example 1～3
In order to compare, use has been added 3.0 weight part sorbitan list palmitates (flower king's (strain), レ ォ De-Le SP-P10) and has been replaced cooperating shown in the embodiment the present invention who forms to prevent the film (comparative example 1) that cloudy antifogging agent makes, and then to add 0.3 weight part fluorine be the film (comparative example 2) that tensio-active agent (ュ ニ ダ ィ Application DS-403) makes, with the film (comparative example 3) that does not have to add anti-cloudy agent, antifogging agent, prevent feminine gender, antifog property and transparency test.The prescription of anti-cloudy antifogging agent is shown in table 1, and evaluation result is shown in table 2.
Table 1
*1:POE represents polyoxyethylene, the numeral addition mole number in ().
| (A) composition | (B) composition | (A)/(B) cooperate ratio | (C) composition | |
| Embodiment 1 | ????— | Sorbitan list palmitate | ????0/100 | Hexadecanoic acid |
| Embodiment 2 | ????— | The sorbitan Monostearate | ????0/100 | The Kang Ji undecanoic acid |
| Embodiment 3 | ????— | Two glycerine sesquistearates | ????0/100 | The octyl group dodecylic acid |
| Embodiment 4 | ????— | The hard acid ester salt of four glycerine | ????0/100 | The decyl tetradecanoic acid |
| Embodiment 5 | ????— | The tetramethylolmethane Monostearate | ????0/100 | The undecyl pentadecylic acid |
| Embodiment 6 | ????— | Dipentaerythritol sesquialter palmitate | ????0/100 | Unimac 5680 |
| Embodiment 7 | ????— | The glycerine Monostearate | ????0/100 | Unimac 5680 |
| Embodiment 8 | ????— | The sorbitan Monostearate | ????0/100 | Unimac 5680 |
| Embodiment 9 | ????— | Sorbitan sesquistearate/two glycerine sesquistearate=7/3 | ????0/100 | Unimac 5680 |
| Embodiment 10 | ????— | Tetramethylolmethane Monostearate/two glycerine sesquistearate=5/5 | ????0/100 | Unimac 5680 |
| Embodiment 11 | ????— | Sorbitol Powder wine Monostearate/Sorbitol Powder wine Monostearate=5/5 | ????0/100 | Unimac 5680 |
| Comparative example 1 | ????— | Sorbitan list palmitate | ????0/100 | ???????— |
| Comparative example 2 | ????— | Sorbitan list palmitate | ????0/100 | ????ェニダィン ??????DS-403 |
| Comparative example 3 | ????— | ??????????— | ??????— | ???????— |
*2:POP represents polyoxytrimethylene, the numeral addition mole number in ().
*3: do not add anti-cloudy antifogging agent.
Table 2
| Initial stage is anti-negative | Low temperature is anti-negative | Anti-cloudy persistence | Antifog property | The transparency | ||||
| 25 days | 50 days | 75 days | 100 days | |||||
| Embodiment 1 | ???△ | ???3-4 | ????4 | ????4 | ????3 | ????3 | ????△ | ??○ |
| Embodiment 2 | ???○ | ????4 | ???4-5 | ????4 | ???4-3 | ???3-2 | ????△ | ??○ |
| Embodiment 3 | ???○ | ????4 | ???4-5 | ????4 | ???4-3 | ????3 | ??△～○ | ??○ |
| Embodiment 4 | ???△ | ???3-4 | ????4 | ???4-3 | ????3 | ????3 | ??△～○ | ??○ |
| Embodiment 5 | ???△ | ???4-3 | ????4 | ????4 | ???4-3 | ???3-4 | ??○～△ | ??○ |
| Embodiment 6 | ???△ | ???4-3 | ????4 | ????4 | ???3-4 | ????3 | ??○～△ | ??○ |
| Embodiment 7 | ???× | ???3-2 | ????3 | ????2 | ????1 | ????1 | ??○～△ | ??○ |
| Embodiment 8 | ???△ | ???3-4 | ????4 | ????4 | ????4 | ????3 | ????○ | ??○ |
| Embodiment 9 | ???○ | ????4 | ???4-5 | ????4 | ????4 | ????3 | ????○ | ??○ |
| Embodiment 10 | ???○ | ????4 | ???4-5 | ????4 | ????4 | ???3-4 | ????○ | ??○ |
| Embodiment 11 | ???○ | ????4 | ???4-5 | ????4 | ????4 | ???3-4 | ????○ | ??○ |
| Comparative example 1 | ???△ | ???3-4 | ????4 | ???3-4 | ????3 | ????2 | ????×× | ??○ |
| Comparative example 2 | ???△ | ???3-4 | ????4 | ???3-4 | ????3 | ????2 | ????○ | ??○ |
| Comparative example 3 | ???×× | ????1 | ????1 | ????1 | ????1 | ????1 | ????○ | ??◎ |
Embodiment 12～21
Form:
Ldpe resin (LDPE) 100 weight parts
(melt index 1.3)
Composition 1.5 weight parts of anti-cloudy antifogging agent of the present invention (A) composition+(B)
(C) composition 0.3 weight part
At first, with the anti-cloudy antifogging agent body mixture of double-shafted extruder making 5 (weight) %, afterwards; masterbatch and primary particles are mixed; be modulated into above-mentioned concentration, be processed into the thick film of 80 μ m, be used for anti-feminine gender, antifog property and transparency test with T mould single shaft extrusion machine.The prescription of anti-cloudy antifogging agent is shown in table 3, and evaluation result is shown in table 4.
Comparative example 4-8
In order to compare, add the sorbitan list palmitate (comparative example 4) of 1.5 weight parts, polyoxyethylene (2) stearylamide Monostearate (comparative example 5) replaces cooperating shown in the embodiment the anti-cloudy antifogging agent of the present invention who forms, the film of making, in the film of comparative example 4 and comparative example 5, the fluorine that further adds 0.3 weight part is the film (comparative example 6 and comparative example 7) that tensio-active agent (ュ ニ ダ ィ Application DS-403) is made, and not have to add anti-cloudy agent, antifogging agent film (comparative example 8), prevent feminine gender, antifog property and transparent the test.The prescription of anti-cloudy antifogging agent is shown in table 3, and evaluation result is shown in table 4.
Table 3
| (A) composition | (B) composition | (A)/(B) cooperate ratio | (C) composition | |
| Embodiment 12 | POE (2) Stearyl Amine | ????????— | ????100/0 | Different tetradecanoic acid |
| Embodiment 13 | POE (2) Stearyl Amine Monostearate | ????????— | ????100/0 | Unimac 5680 |
| Embodiment 14 | ???????— | Sorbitan list palmitate | ????0/100 | Unimac 5680 |
| Embodiment 14 | ???????— | Two glycerine sesquistearates | ????0/100 | 2-octyl group dodecylic acid |
| Embodiment 16 | POE (2) Stearyl Amine | Two glycerine sesquistearates | ????40/60 | Unimac 5680 |
| Embodiment 17 | POE (2) Stearyl Amine Monostearate | Sorbitan list palmitate | ????70/30 | 2-undecyl pentadecylic acid |
| Embodiment 18 | POE (4) Stearyl Amine sesquialter palmitate | Four glycerine, three stearate | ????20/80 | POE (2) Stearyl Amine list isostearate |
| Embodiment 19 | POE (2) stearylamide | The tetramethylolmethane Monostearate | ????30/70 | POE (4) Stearyl Amine list isostearate |
| Embodiment 20 | POE (4) Stearyl Amine distearate/POE (2) lauric acid amine mono laurate salt=7/3 | ?????????— | ????100/0 | Unimac 5680 |
| Embodiment 21 | POE (2) docosoic amine Dan docosoic salt/oleic acid amine list oleates | ?????????— | ????100/0 | 2-undecyl 12 alkanoic acids |
| Comparative example 4 | ???????— | Sorbitan list palmitate | ????0/100 | ???????— |
| Comparative example 5 | POE (2) Stearyl Amine Monostearate | ?????????— | ????100/0 | ???????— |
| Comparative example 6 | ???????— | Sorbitan list palmitate | ????0/100 | ???ェニダィン ????DS-403 |
| Comparative example 7 | POE (2) Stearyl Amine Monostearate | ?????????— | ????100/0 | ???ェニダィン ????DS-403 |
| Comparative example 8 | ????????— | ?????????— | ??????— | ???????— |
Table 4
| Initial stage is anti-negative | Low temperature is anti-negative | Anti-cloudy persistence | Antifog property | The transparency | ||||
| 25 days | 50 days | 75 days | 100 days | |||||
| Embodiment 12 | ????◎ | ????5 | ??1-2 | ????1 | ????1 | ????1 | ?○～△ | ??△ |
| Embodiment 13 | ????○ | ????4 | ??5-4 | ???5-4 | ??4-5 | ??4-5 | ????○ | ??○ |
| Embodiment 14 | ????× | ????3 | ????4 | ????3 | ????2 | ????1 | ????○ | ??◎ |
| Embodiment 15 | ????× | ???3-4 | ????4 | ????4 | ????3 | ??3-2 | ?△～○ | ??○ |
| Embodiment 16 | ????◎ | ???5-4 | ??5-4 | ???5-4 | ??5-4 | ??4-5 | ????○ | ??○ |
| Embodiment 17 | ????○ | ????4 | ??5-4 | ???5-4 | ??4-5 | ????4 | ????○ | ??◎ |
| Embodiment 18 | ????○ | ????4 | ??4-5 | ???4-5 | ????4 | ????4 | ?○～△ | ??○ |
| Embodiment 19 | ????○ | ????4 | ??4-5 | ???4-5 | ????4 | ????4 | ??○～△ | ??○ |
| Embodiment 20 | ????◎ | ???5-4 | ??5-4 | ???5-4 | ??4-5 | ??4-5 | ????○ | ??○ |
| Embodiment 21 | ????○ | ???4-5 | ??5-4 | ???5-4 | ??4-5 | ????4 | ????○ | ??○ |
| Comparative example 4 | ????× | ????3 | ????4 | ????3 | ????2 | ????1 | ????×× | ??△ |
| Comparative example 5 | ????○ | ????4 | ??5-4 | ???5-4 | ??4-5 | ??4-5 | ????△ | ??×× |
| Comparative example 6 | ????× | ????3 | ????4 | ????3 | ????2 | ????1 | ????○ | ??△ |
| Comparative example 7 | ????○ | ????4 | ??5-4 | ???5-4 | ??4-5 | ??4-5 | ????○ | ??×× |
| Comparative example 8 | ????×× | ????1 | ????1 | ????1 | ????1 | ????1 | ????○ | ??◎ |
Embodiment 22～26
Be fine into:
Ethylene-vinyl acetate copolymer (EVA) resin 100 weight parts
(melt index 0.5, VA%=5%)
Composition 1.5 weight parts of anti-cloudy antifogging agent of the present invention (A) composition+(B)
(C) composition 0.3 weight part
At first; with the anti-cloudy antifogging agent masterbatch of double-shafted extruder making 5 (weight) %, afterwards masterbatch and primary particles are mixed, be modulated into above-mentioned concentration; be processed into the thick film of 80 μ m with T mould single shaft extrusion machine, be used for anti-feminine gender, antifog property and transparency test.The prescription of anti-cloudy antifogging agent is shown in table 5, and evaluation result is shown in table 6.
Comparative example 9～11
In order to compare, the sorbitan list palmitate (comparative example 9) that adds 1.5 weight parts replaces cooperating shown in the embodiment the present invention who forms to prevent the film that cloudy antifogging agent makes, and then interpolation 0.3 weight part fluorine is the film (comparative example 10) that tensio-active agent (ュ ニ ダ ィ Application DS-403) makes in the film of comparative example 9, do not add the film (comparative example 11) of anti-cloudy agent, antifogging agent, prevent feminine gender, antifog property and transparency test.The prescription of anti-cloudy antifogging agent is shown in table 5, and evaluation result is shown in table 6.
Table 5
| (A) composition | (B) composition | (A)/(B) cooperate ratio | (C) composition | |
| Embodiment 22 | POE (2) Stearyl Amine Monostearate | ?????????— | ??100/0 | Unimac 5680 |
| Embodiment 23 | POE (2) Stearyl Amine | Two glycerine sesquialter resin acid salt/glycerine Monostearate=7/3 | ??40/60 | Unimac 5680 |
| Embodiment 24 | POE (4) Stearyl Amine sesquistearate | POE (3) sorbitan Monostearate | ??70/30 | POE (2) Stearyl Amine list isostearate |
| Embodiment 25 | POE (2) stearylamide | Four glycerine, three stearate | ??30/70 | 2-undecyl pentadecylic acid |
| Embodiment 26 | POE (2) docosoic amine | Two glycerine sesquistearates | ??40/60 | 2-undecyl pentadecylic acid |
| Comparative example 9 | ???????— | Sorbitan list palmitate | ??0/100 | ??????????— |
| Comparative example 10 | ???????— | Sorbitan list palmitate | ??0/100 | ??????ェニダィン ????????DS-403 |
| Comparative example 11 | ???????— | ???????????— | ????— | ??????????— |
Table 6
| Initial stage is anti-negative | Low temperature is anti-negative | Anti-cloudy persistence is antifog | The transparency | |||||
| 25 days | 50 days | 75 days | 100 days | The property | ||||
| Embodiment 22 | ????◎ | ??4-5 | ??5-4 | ?5-4 | ??5-4 | ?4-5 | ????○ | ??○ |
| Embodiment 23 | ????◎ | ??5-4 | ??5-4 | ?5-4 | ??5-4 | ?4-5 | ????○ | ??○ |
| Embodiment 24 | ????○ | ??4-5 | ??4-5 | ?4-5 | ??4-5 | ???4 | ??○～△ | ??○ |
| Embodiment 25 | ????○ | ???4 | ??4-5 | ?4-5 | ????4 | ???4 | ??○～△ | ??○ |
| Embodiment 26 | ????◎ | ??4-5 | ??5-4 | ?5-4 | ??4-5 | ?4-5 | ????○ | ??○ |
| Comparative example 9 | ????× | ???3 | ????4 | ???3 | ????2 | ???1 | ????×× | ??△ |
| Comparative example 10 | ????× | ???3 | ????4 | ???3 | ??2-3 | ???1 | ????○ | ??△ |
| Comparative example 11 | ????×× | ????1 | ????1 | ???1 | ????1 | ???1 | ????○ | ??◎ |
Embodiment 27～31
Form:
Straight-chain low density polyethylene resin (LLDPE) 100 weight parts
(melt index 1.9)
Composition 1.5 weight parts of anti-cloudy antifogging agent of the present invention (A) composition+(B)
(C) composition 0.3 weight part
At first; with the anti-cloudy antifogging agent masterbatch of double-shafted extruder making 5 (weight) %, afterwards masterbatch and primary particles are mixed, be modulated into above-mentioned concentration; be processed into the thick film of 80 μ m with T mould single shaft extrusion machine, be used for anti-feminine gender, antifog property and transparency test.The prescription of anti-cloudy antifogging agent is shown in table 7, and evaluation result is shown in table 8.
Comparative example 12～14
In order to compare, add 1.5 weight part sorbitan palmitates (comparative example 12) and replace cooperating shown in the embodiment the anti-cloudy antifogging agent of the present invention who forms, the fluorine that further adds 0.3 weight part in the film of comparative example 12 is the film (comparative example 13) that tensio-active agent (ュ ニ ダ ィ Application DS-403) is made, do not add the film (comparative example 14) of anti-cloudy agent, antifogging agent, prevent feminine gender, antifog property and transparency test, the prescription of anti-cloudy antifogging agent is shown in table 7, and evaluation result is shown in table 8.
Table 7
| (A) composition | (B) composition | (A)/(B) cooperate ratio | (C) composition | |
| Embodiment 27 | POE (2) Stearyl Amine Monostearate | ???????— | ??100/0 | Unimac 5680 |
| Embodiment 28 | POE (2) Stearyl Amine | Two glycerine sesquistearate/glycerine Monostearate=7/3 | ??40/60 | Unimac 5680 |
| Embodiment 29 | POE (2) Stearyl Amine Dan docosoic salt | The Dipentaerythritol sesquistearate | ??60/40 | POE (2) Stearyl Amine list isostearate |
| Embodiment 30 | POE (2) Stearyl Amine Monostearate | Four glycerine, three stearate | ??30/70 | 2-undecyl pentadecylic acid |
| Embodiment 31 | POE (2) stearylamide | Two glycerine sesquistearates | ??40/60 | 2-undecyl pentadecylic acid |
| Comparative example 12 | ????????— | Sorbitan list palmitate | ??0/100 | ?????— |
| Comparative example 13 | ????????— | Sorbitan list palmitate | ??0/100 | ??ェニダィン ????DS-403 |
| Comparative example 14 | ????????— | ???????— | ????— | ?????— |
Table 8
| Initial stage is anti-negative | Low humidity is anti-negative | Anti-cloudy persistence is antifog | The transparency | |||||
| 25 days | 50 days | 75 days | 100 days | The property | ||||
| Embodiment 27 | ????○ | ????4 | ??5-4 | ??5-4 | ??4-5 | ??4-5 | ??○ | ??○ |
| Embodiment 28 | ????◎ | ??4-5 | ??5-4 | ??5-4 | ??5-4 | ??4-5 | ??○ | ??○ |
| Embodiment 29 | ????○ | ????4 | ??4-5 | ??4-5 | ????4 | ????4 | ??○～△ | ??○ |
| Embodiment 30 | ????○ | ????4 | ??4-5 | ??4-5 | ??4-5 | ????4 | ??○～△ | ??○ |
| Embodiment 31 | ????○ | ????4 | ??4-5 | ??4-5 | ??4-5 | ????4 | ??○～△ | ??○ |
| Comparative example 12 | ????× | ????3 | ????4 | ????3 | ????2 | ????1 | ????×× | ??△ |
| Comparative example 13 | ????× | ????3 | ????4 | ????3 | ??2-3 | ????1 | ????○ | ??△ |
| Comparative example 14 | ????×× | ????1 | ????1 | ????1 | ????1 | ????1 | ????○ | ??◎ |
Embodiment 32～34
The outer composition:
Ethylene-vinyl acetate copolymer (EVA) resin 100 weight parts
(melt index 0.5, VA%=5%)
Composition 0.5 weight part of anti-cloudy antifogging agent of the present invention (A) composition+(B)
(C) composition 0.1 weight part
Internal layer is formed:
Ethylene-vinyl acetate copolymer (EVA) resin 100 weight parts
(fusing fat is several 0.5, VA%=15%)
Composition 2.5 weight parts of anti-cloudy antifogging agent of the present invention (A) composition+(B)
(C) composition 0.5 weight part
In above-mentioned cooperation, at first mix with double-shafted extruder, this particle is used in granulation afterwards, with 3 layers of machine-processed multilayer film that gets 100 μ m (skin/internal layer/skin=20 μ m/60 μ m/20 μ m) of blow molding.This film is prevented feminine gender, antifog property and transparency test.The prescription of anti-cloudy antifogging agent is shown in table 9, and evaluation result is shown in table 10.
Comparative example 15
In order to compare, interior layer segment adds 2.5 weight parts, outer layer segment adds the film (comparative example 15) that cooperates the anti-cloudy antifogging agent of the present invention who forms shown in the 0.5 weight part sorbitan palmitate replacement embodiment and make, and prevents feminine gender, antifog property and transparency test.The prescription of anti-cloudy antifogging agent is shown in table 9, and evaluation result is shown in table 10.
Table 9
| (A) composition | (B) composition | (A)/(B) cooperate ratio | (C) composition | |
| Embodiment 32 | POE (2) Stearyl Amine Monostearate | ??????— | ????100/0?? | Unimac 5680 |
| Embodiment 33 | POE (2) Stearyl Amine | Two glycerine sesquistearates | ????40/60 | 2-undecyl pentadecylic acid |
| Embodiment 34 | POE (2) Stearyl Amine Monostearate | Sorbitan list palmitate | ????70/30 | Unimac 5680 |
| Comparative example 15 | ??????— | Sorbitan list palmitate | ????0/100 | ??????— |
Table 10
| Initial stage is anti-negative | Low temperature is anti-negative | Anti-cloudy persistence | Antifog property | The transparency | ||||
| 25 days | 50 days | 75 days | 100 days | |||||
| Embodiment 32 | ????◎ | ????4-5 | ??5-4 | ???5-4 | ??5-4 | ??4-5 | ??○ | ??○ |
| Embodiment 33 | ????◎ | ????5-4 | ??5-4 | ???5-4 | ??5-4 | ??5-4 | ??○ | ??○ |
| Embodiment 34 | ????○ | ????4-5 | ??5-4 | ???5-4 | ??5-4 | ??4-5 | ??○ | ??○ |
| Comparative example 15 | ????× | ??????3 | ????4 | ???3-4 | ??3-2 | ??2-1 | ??×× | ??○ |
Embodiment 35～37
The outer composition:
New LDPE (film grade) (LDPE) resin 100 weight parts
(melt index 0.8)
Composition 0.5 weight part of anti-cloudy antifogging agent of the present invention (A) composition+(B)
(C) 0.1 weight part internal layer is formed:
Ethylene-vinyl acetate copolymer (EVA) resin 100 weight parts
(fusing fat is several 1.5, VA%=15%)
Composition 2.5 weight parts of anti-cloudy antifogging agent of the present invention (A) composition+(B)
(C) composition 0.5 weight part
After the above-mentioned cooperation, at first carry out mixing granulation, then use this particle, with 3 layers of machine-processed multilayer film that gets 100 μ m (skin/internal layer/skin=20 μ m/60 μ m/20 μ m) of blow molding with double-shafted extruder.This film is prevented feminine gender, antifog property and transparency test.The prescription of anti-cloudy antifogging agent is shown in table 11, and evaluation result is shown in table 12.
Comparative example 16
In order to compare, add 2.5 weight parts at interior layer segment, the sorbitan palmitate that outer layer segment adds 0.5 weight part replaces the anti-cloudy antifogging agent of the present invention that combination is fine into shown in the embodiment to make film (comparative example 16), prevents feminine gender, antifog property and transparency test.The prescription of anti-cloudy antifogging agent is shown in table 11, and evaluation result is shown in table 12.
Table 11
| (A) composition | (B) composition | (A)/(B) cooperate ratio | (C) composition | |
| Embodiment 35 | POE (2) Stearyl Amine Monostearate | ?????— | ????100/0 | Unimac 5680 |
| Embodiment 36 | POE (2) Stearyl Amine | Two glycerine sesquialter stearates | ????40/60 | 2-undecyl pentadecylic acid |
| Embodiment 37 | POE (2) Stearyl Amine Monostearate | Sorbitan list palmitate | ????70/30 | Unimac 5680 |
| Comparative example 16 | ????????— | Sorbitan list palmitate | ????0/100 | ??????— |
Table 12
| Initial stage is anti-negative | Low temperature is anti-negative | Anti-cloudy persistence | Antifog property | The transparency | ||||
| 25 days | 50 days | 75 days | 100 days | |||||
| Embodiment 35 | ??○ | ????4 | ??5-4 | ??5-4 | ??5-4 | ??4-5 | ??○ | ??○ |
| Embodiment 36 | ??◎ | ??4-5 | ??5-4 | ??5-4 | ??5-4 | ??5-4 | ??○～△ | ??○ |
| Embodiment 37 | ??○ | ????4 | ??5-4 | ??5-4 | ??4-5 | ??4-5 | ??○ | ??○ |
| Comparative example 16 | ???× | ????3 | ????4 | ????3 | ??2-3 | ??2-1 | ??×× | ??◎ |
Embodiment 38～40
The outer composition:
Straight-chain low density polyethylene (LLDPE) resin 100 weight parts
(melt index 0.7)
Composition 0.5 weight part of anti-cloudy antifogging agent of the present invention (A) composition+(B)
(C) composition 0.1 weight part
Internal layer is formed:
Ethylene-vinyl acetate copolymer (EVA) resin 100 weight parts
(melt index 1.5, VA%=15%)
Composition 2.5 weight parts of anti-cloudy antifogging agent of the present invention (A) composition+(B)
(C) composition 0.5 weight part
After the above-mentioned cooperation, at first carry out mixing granulation, then use this particle, with 3 layers of machine-processed multilayer film that gets 100 μ m (skin/internal layer/skin=20 μ m/60 μ m/20 μ m) of blow molding with double-shafted extruder.This film is prevented feminine gender, antifog property and transparency test.The prescription of anti-cloudy antifogging agent is shown in table 13, and evaluation result is shown in table 14.
Comparative example 17
In order to compare, interior layer segment adds 2.5 weight parts, outer layer segment adds 0.5 weight part (comparative example 17) sorbitan list palmitate, replaces cooperating shown in the embodiment the anti-cloudy antifogging agent of the present invention who forms to make film, prevents feminine gender, antifog property and transparency test.The prescription of anti-cloudy antifogging agent is shown in table 13, and evaluation result is shown in table 14.
Table 13
| (A) composition | (B) composition | (A)/(B) cooperate ratio | (C) composition | |
| Embodiment 38 | POE (2) Stearyl Amine Monostearate | ?????— | ????100/0 | Unimac 5680 |
| Embodiment 39 | POE (2) Stearyl Amine | Two glycerine sesquialter stearates | ????40/60 | 2-undecyl pentadecylic acid |
| Embodiment 40 | POE (2) Stearyl Amine Monostearate | Sorbitan list palmitate | ????70/30 | Unimac 5680 |
| Comparative example 17 | ???????— | Sorbitan list palmitate | ????0/100 | ??????— |
Table 14
| Initial stage is anti-negative | Low temperature is anti-negative | Anti-cloudy persistence | Antifog property | The transparency | ||||
| 25 days | 50 days | 75 days | 100 days | |||||
| Embodiment 38 | ??○ | ????4 | ??5-4 | ??5-4 | ??4-5 | ????4-5 | ????○ | ????○ |
| Embodiment 39 | ??◎ | ??4-5 | ??5-4 | ??5-4 | ??4-5 | ????4-5 | ?○～△ | ????○ |
| Embodiment 40 | ??○ | ????4 | ??5-4 | ??4-5 | ??4-5 | ????4-5 | ????○ | ????○ |
| Comparative example 17 | ??× | ????3 | ????4 | ????3 | ??2-3 | ????1-2 | ????×× | ????◎ |
Embodiment 41～43
Form:
Ldpe resin (LDPE) 100 weight parts
(melt index 1,3)
Anti-cloudy antifogging agent of the present invention (A) becomes+(B) composition of composition+(C)
1.8 weight part
At first; make the anti-cloudy antifogging agent masterbatch of 5 (weight) % of double-shafted extruder; then masterbatch and primary particles are mixed; be modulated into above-mentioned concentration; be processed into the thick film of 80 μ m with T mould single shaft extrusion machine; be used for anti-feminine gender, antifog property and transparency test, anti-cloudy antifogging agent is shown in table 15, and evaluation result is shown in table 16.
Comparative example 18
For relatively, add 1.5 weight parts (comparative example 18) sorbitan stearate and replace the anti-cloudy antifogging agent of the present invention of the cooperation composition shown in the embodiment to make film, prevent feminine gender, antifog property and transparency test.Anti-cloudy antifogging agent is shown in table 15, and evaluation result is shown in table 16.
Table 15
| (A) composition | (B) composition | (A)/(B) cooperate ratio | (C) composition | (A)+(B)+(C)/the cooperation ratio | |
| Embodiment 41 | POE (2) Stearyl Amine | Two glycerine sesquistearates | ??40/60 | Unimac 5680 | ??90/10 |
| Embodiment 42 | POE (2) Stearyl Amine Monostearate | ????— | ??100/0 | Unimac 5680 | ??85/15 |
| Embodiment 43 | POE (2) Stearyl Amine Monostearate | Sorbitan list palmitate | ??70/30 | Unimac 5680 | ??75/25 |
| Comparative example 18 | ????— | Sorbitan list palmitate | ??0/100 | ????— | ????— |
Table 16
| Initial stage is anti-negative | Low temperature is anti-negative | Anti-cloudy persistence | Antifog property | The transparency | ||||
| 25 days | 50 days | 75 days | 100 days | |||||
| Embodiment 41 | ???◎ | ??5-4 | ???5-4 | ???5-4 | ????5-4 | ????4-5 | ??○ | ?○～△ |
| Embodiment 42 | ???○ | ????4 | ???5-4 | ???5-4 | ????4-5 | ????4-5 | ??○ | ????○ |
| Embodiment 43 | ???○ | ????4 | ???5-4 | ???4-5 | ??????4 | ??????4 | ??○ | ????◎ |
| Comparative example 18 | ???× | ??3-2 | ?????4 | ?????3 | ??????2 | ??????1 | ??×× | ????△ |
Claims (11)
1, a kind of synthetic resins is with anti-cloudy antifogging agent composition, forms by following (A), (B) with (C), and its weight ratio is [(A)+(B)]/(C)=50/50～98/2, and ratio (A)/(B)=100/0～0/100:
(A) compound of representing with formula (1) (to call compound (1) in the following text),
In the formula, R
1Be the alkyl of 12～22 carbonatomss, the acyl group of the alkenyl of 12～22 carbonatomss or 12～22 carbon atoms, m and n are the numbers more than 1 that forms m+n=2～10 (mean value),
Or the fatty acid ester of compound (1), still, lipid acid is in 2 hydroxyls of saturated or unsaturated fatty acids, compound (1) of 12～22 carbonatomss, 0.5～2.0 forms and the ester bond of this lipid acid,
(B) be the fatty acid ester of the multivalence alcohol of 2～18 carbon atoms, but lipid acid is the saturated or unsaturated fatty acids of 12～22 carbon atoms,
Or the epoxide affixture of this fatty acid ester, but the carbonatoms of epoxide is 2～3, average addition mole number is 0.1～20 mole for 1 moles of fatty acids ester.
(C) the side chain higher fatty acid of representing with formula (2)
In the formula, R
2And R
3Be the straight or branched alkyl of 5-16 carbonatoms,
Or the fatty acid ester of this side chain higher fatty acid (2) and compound (1), but, in 2 hydroxyls of compound (1), the ester bond of 0.5～2.0 formation and this lipid acid.
2, a kind of compound resin composition for 100 weight part synthetic resins, contains the antifog composition of anti-the moon of 0.1～5 weight part claim 1 record.
3, a kind of compound resin composition for 100 weight part synthetic resins, contains the anti-cloudy antifogging agent composition of 0.5～4 weight part claim 1 record.
4, by the agricultural film of the compound resin composition of claim 2 record.
5, the agricultural film that forms by the compound resin composition of claim 3 record.
6,, wherein contain the film of the compound resin composition formation of 1 layer of claim 2 record at least by the agricultural film that forms more than 2 layers.
7,, wherein contain the film of the compound resin composition formation of one deck claim 3 record at least by the agricultural film that forms more than 2 layers.
8, the anti-cloudy antifogging agent composition of record in the claim 1 is characterized in that [(A)+(B)]/(C)=70/30～90/5, and (A)/(B)=100/0～10/90.
9, by the antifog agricultural film that forms to composition and polyolefin resin of anti-the moon of claim 8 record.
10, the antifog composition of anti-the moon of record in the claim 1, (C) in the composition, the R in the formula (2)
2And R
3It is respectively branched-chain alkyl with 2 above methyl.
11, the agricultural film that forms by the anti-cloudy antifogging agent composition and the polyolefin resin of claim 10 record.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP208395/96 | 1996-08-07 | ||
| JP20839596A JP3681827B2 (en) | 1996-08-07 | 1996-08-07 | Anti-fogging and anti-fogging agent for synthetic resin, and synthetic resin composition and agricultural film containing the same |
| JP208395/1996 | 1996-08-07 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1175602A true CN1175602A (en) | 1998-03-11 |
| CN1105739C CN1105739C (en) | 2003-04-16 |
Family
ID=16555554
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97118507A Expired - Lifetime CN1105739C (en) | 1996-08-07 | 1997-08-07 | Shade-proof antifogging agent for synthtic resin and synthetic resin composition and agricultural film contg same |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP3681827B2 (en) |
| CN (1) | CN1105739C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102558978A (en) * | 2011-12-05 | 2012-07-11 | 远纺工业(上海)有限公司 | Antifogging agent composition and preparation method and application thereof |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6046254A (en) * | 1997-03-27 | 2000-04-04 | E. I. Du Pont De Nemours And Company | Antifog composition for polyolefin packaging films |
| JP4043095B2 (en) * | 1998-04-07 | 2008-02-06 | 日泉化学株式会社 | Agricultural coating film |
| JP2011127017A (en) * | 2009-12-18 | 2011-06-30 | Sumitomo Chemical Co Ltd | Polymer composition and molded article comprising the same |
| BR112012017769A2 (en) | 2009-12-25 | 2016-04-19 | Sumitomo Chemical Co | polymer composition and molded articles thereof |
| CN113621146B (en) * | 2021-07-22 | 2024-02-27 | 厦门长塑实业有限公司 | Antifogging, antibacterial and mildew-proof polylactic acid master batch, film thereof and preparation method thereof |
-
1996
- 1996-08-07 JP JP20839596A patent/JP3681827B2/en not_active Expired - Fee Related
-
1997
- 1997-08-07 CN CN97118507A patent/CN1105739C/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102558978A (en) * | 2011-12-05 | 2012-07-11 | 远纺工业(上海)有限公司 | Antifogging agent composition and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3681827B2 (en) | 2005-08-10 |
| JPH1045944A (en) | 1998-02-17 |
| CN1105739C (en) | 2003-04-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1235957C (en) | Compositions | |
| CN1097090C (en) | Preparation of high Di (alkyl fatty ester) quaternary ammonium salt compound from triethanolamine | |
| CN1088595A (en) | Biodegradable cellulose ester composition and article | |
| CN1066859A (en) | Biodegradable polymer composition based on starch and thermoplastic polymer | |
| CN1241536C (en) | Humectant and cosmetics and external prepan. contg. same | |
| CN1362505A (en) | Transparent bar-type soap composition | |
| CN1105739C (en) | Shade-proof antifogging agent for synthtic resin and synthetic resin composition and agricultural film contg same | |
| CN1059933A (en) | Detergent composition | |
| CN1225530C (en) | Fabric softening compositions | |
| CN86101976A (en) | Cold rolling mill lubricant | |
| CN1025203C (en) | Blended compositions based on ethylene-vinyl alcohol copolymers haning properties impermeable to gas, thermoformable and/or resistancable repeated flexibility | |
| CN1845986A (en) | Method for increasing yield of biomass of and/or components of biomass from marine microorganisms | |
| CN1064813C (en) | A method for preparing low free formaldehyde methylolhydantoins and compositions thereof | |
| CN1117120C (en) | Method for recrystallizing diacetal in polyolefin resin | |
| CN1158881A (en) | Antifog film | |
| CN1161423C (en) | Synthetic resin film for agricultural use excellent in antifog and antimist properties | |
| CN1768100A (en) | Polyacetals with improved resistance to bleach | |
| CN1604794A (en) | Eye drops | |
| CN1154693C (en) | Vinylidene chloride resin compositions, process for producing same and film of the same | |
| CN1184956C (en) | Detergent composition | |
| CN1777642A (en) | Resin composition used in manufacturing functional resin articles | |
| CN1253910A (en) | Fine-particle synthetic copper aluminite compound, its preparation method and application | |
| CN1350027A (en) | Polymer composition containing halogen stabilized by crypto-thio-alcohol and mixture of zinc carboxylate and zinc chloride | |
| CN1040202C (en) | Mineral-fiber compositions | |
| CN1129644C (en) | Multiple degrading composition mother particle |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20030416 |