CN117558786A - Novel high-water-blocking composite photovoltaic tile - Google Patents

Novel high-water-blocking composite photovoltaic tile Download PDF

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Publication number
CN117558786A
CN117558786A CN202311490409.1A CN202311490409A CN117558786A CN 117558786 A CN117558786 A CN 117558786A CN 202311490409 A CN202311490409 A CN 202311490409A CN 117558786 A CN117558786 A CN 117558786A
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CN
China
Prior art keywords
layer
photovoltaic tile
novel high
adhesive film
acrylic resin
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202311490409.1A
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Chinese (zh)
Inventor
熊军
桂裕鹏
钱春虎
蔡双双
龚炜
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Flextech Co
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Flextech Co
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Publication date
Application filed by Flextech Co filed Critical Flextech Co
Priority to CN202311490409.1A priority Critical patent/CN117558786A/en
Publication of CN117558786A publication Critical patent/CN117558786A/en
Pending legal-status Critical Current

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B10/00Integration of renewable energy sources in buildings
    • Y02B10/10Photovoltaic [PV]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

Abstract

The invention discloses a novel high-water-blocking composite photovoltaic tile, which comprises a first packaging layer, a first packaging adhesive film layer, a first PET layer, a second packaging adhesive film layer, a battery piece layer, a third packaging adhesive film layer, a second PET layer, a fourth packaging adhesive film layer and a substrate which are sequentially laminated, laminated and integrally formed through a laminating machine; the cell layer comprises a plurality of solar cell strings; the first packaging layer is an FRP plate material containing acrylic resin. The high-water-resistance composite novel photovoltaic tile provided by the invention has the advantages of good bearing effect, impact resistance, water resistance, light weight, low cost, rich and colorful colors and excellent ultraviolet aging resistance.

Description

Novel high-water-blocking composite photovoltaic tile
Technical Field
The invention belongs to the technical field of photovoltaics, and particularly relates to a novel high-water-resistance composite photovoltaic tile.
Background
After the 70 s of the 20 th century, with the development of modern industry, the global energy crisis and the air pollution problem are increasingly prominent, the world is directing the eyes to renewable energy sources, and the renewable energy sources are expected to change the energy source structure of human beings, so that long-term sustainable development is maintained.
Solar energy is a focus of attention by its unique advantages. The abundant solar radiation energy is an important energy source, and is inexhaustible, pollution-free, low-cost and freely available for human beings. The energy of the solar energy reaching the ground per second is up to 800 megawatts, and if 0.1% of the solar energy on the surface of the earth is converted into electric energy, the conversion rate is 5%, and the annual energy generation capacity can reach 5.6X11012 kilowatt-hours, which is 40 times of the world energy consumption. Due to the unique advantages of solar energy, the types of solar cells are continuously increased after the 80 s of the 20 th century, the application range is increasingly wide, and the market scale is gradually enlarged.
When the existing photovoltaic tile products are widely applied to the BIPV field, a plurality of problems still exist:
1. the existing photovoltaic tile is different from the photovoltaic module with the traditional glass material structure, and cannot increase the bearing requirement of the original building roof;
2. the existing photovoltaic tile replaces the original roofing metal tile material, the edge of the photovoltaic tile is required to be of a borderless design, and as the solar panel has a multi-layer structure, the edge of the borderless photovoltaic tile product is directly contacted with air, the protection effect is poor, water vapor and oxygen are easy to invade from layers, the aging and the failure of the panel are accelerated, and even the layering of the panel is caused;
3. the existing photovoltaic tile is used as a photovoltaic building integrated BIPV product, and has excellent processing performance of a metal plate, so that the photovoltaic tile can adapt to the design of various complex shapes;
4. most of the existing photovoltaic tile substrates are made of aluminum alloy materials, the materials are heavy and high in price, and meanwhile, the products are required to be grounded;
5. the existing photovoltaic tile is used as a photovoltaic building integrated BIPV product, and needs to have higher strength and bear a certain load.
Disclosure of Invention
In view of the above, the invention provides a novel high-water-resistance composite photovoltaic tile which has the advantages of good bearing effect, impact resistance, water resistance, light weight, low cost, rich and colorful colors and excellent ultraviolet aging resistance.
The method comprises the following steps:
a novel high-water-resistance composite photovoltaic tile comprises a first packaging layer, a first packaging adhesive film layer, a first PET layer, a second packaging adhesive film layer, a battery piece layer, a third packaging adhesive film layer, a second PET layer, a fourth packaging adhesive film layer and a substrate which are sequentially laminated, laminated and integrally formed through a laminating machine; the cell layer comprises a plurality of solar cell strings; the first packaging layer is an FRP plate material containing acrylic resin.
Further, the acrylic resin comprises the following raw materials in percentage by weight: 40-50% of fluorine modified acrylic resin, 10-15% of curing agent, 30-40% of diluent and 3-5% of auxiliary agent.
Further, the fluorine modified acrylic resin comprises one or a mixture of several of the following materials: fluoroalkyl alcohol acrylic resin, fluorosilicone modified hydroxy acrylic resin, organofluorine modified acrylic resin, silicone fluorinated urethane acrylic resin.
Further, the curing agent is one or a mixture of more of the following materials: isocyanate, amino resin, titanium tetraisopropoxide and vinyl dimethyl acrylic acid.
Further, the diluent is one or a mixture of several of the following materials: styrene, ethyl acetate, ethanol, propylene glycol, isopropanol.
Further, the auxiliary agent is one or a mixture of more of the following materials: leveling agent, defoaming agent, color paste and accelerator.
Further, the first PET layer is a water-blocking reinforced composite PET, and is characterized in that it includes: reinforcing material and coated PET film material.
Further, the reinforcing material accounts for 30-40% of the weight of the first PET layer, and comprises one or more of the following materials: nano glass fiber, whisker and carbon fiber.
The substrate is a multilayer co-extrusion composite plate containing a special resin film material A and a resin base material B; the multilayer co-extrusion composite plate is manufactured by respectively carrying out melt extrusion on the raw materials of the special resin film material A and the resin substrate material B through an extruder, converging the raw materials at a co-extrusion die head through respective runners, and cooling the raw materials after casting and molding.
Further, the special resin film material A comprises any one of the following materials: PPS, PEI, ASA; the resin film material B comprises any one of the following materials: PVC, PMMA, PET.
The beneficial effects are that:
1. the FRP plate infiltrated by the fluorine-containing acrylic resin can replace the traditional glass and the fluorine film for packaging, so that the weight of the component can be reduced, the fluorine film has the ultraviolet resistance, and meanwhile, the plate has a bearing effect and plays a role in protecting the component;
2. the PET filled with the reinforcing material is used as the core material, so that the product has good strength, the impact strength is improved, and meanwhile, the nano-plating layer is combined, so that the product has high water blocking performance, and the battery assembly in the photovoltaic tile is protected;
3. the resin composite board is used as a base board, the weight of the product is further reduced, the price is reduced, and the board has excellent ultraviolet aging resistance by using a coextrusion technology, and meanwhile, the board can be further processed through a heating bending process.
Drawings
FIG. 1 is a schematic view of a novel high water blocking composite photovoltaic tile in an embodiment of the present invention;
Detailed Description
Exemplary embodiments of the present application will be described in more detail below with reference to the accompanying drawings. While exemplary embodiments of the present application are shown in the drawings, it should be understood that the present application may be embodied in various forms and should not be limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the disclosure to those skilled in the art.
As shown in fig. 1, the novel high-water-blocking composite photovoltaic tile comprises a first packaging layer 1, a first packaging adhesive film layer 2, a first PET layer 3, a second packaging adhesive film layer 4, a battery piece layer 5, a third packaging adhesive film layer 6, a second PET layer 7, a fourth packaging adhesive film layer 8 and a substrate 9 which are sequentially stacked, laminated and integrally formed through a laminating machine; the cell layer comprises a plurality of solar cell strings; the first packaging layer is an FRP plate material containing acrylic resin.
Preferably, the cell layer can be a single-sided crystalline silicon solar cell, a double-sided crystalline silicon solar cell, an n-IBC cell, a thin film cell or a perovskite dye sensitized cell; when the battery layer is a PERC battery or other crystalline silicon batteries, welding strips are adopted for interconnection or overlapping tiles are adopted for interconnection.
The length and width dimensions of the first packaging layer 1, the first packaging adhesive film layer 2, the fourth packaging adhesive film layer 8 and the substrate 9 are the same, and are larger than the length and width dimensions of the first PET layer 3, the second packaging adhesive film layer 4, the battery sheet layer 5, the third packaging adhesive film layer 6 and the second PET layer 7.
The length and width dimensions of the first PET layer 3, the second packaging adhesive film layer 4, the battery piece layer 5, the third packaging adhesive film layer 6 and the second PET layer 7 are the same.
The length and width dimensions of the fourth packaging adhesive film layer and the substrate are the same, so that the fourth packaging adhesive film layer can be completely attached to the substrate, and the adhesive force is stronger.
During lamination, EVA or POE of the fourth packaging adhesive film layer flows into the edge area of the back surface of the photovoltaic panel, so that a self-overflowing sealing edge is formed.
Further, the second PET layer 7 is insulating PET.
Further, the first packaging adhesive film layer, the second packaging adhesive film layer, the third packaging adhesive film layer and the fourth packaging adhesive film layer are any one of EVA, POE, PVB.
Further, the acrylic resin comprises the following raw materials in percentage by weight: 40-50% of fluorine modified acrylic resin, 10-15% of curing agent, 30-40% of diluent and 3-5% of auxiliary agent. The sum of the specific gravities of the above raw materials was 100%.
40% -50% means [40% -50% ].
Further, the fluorine modified acrylic resin comprises one or a mixture of several of the following materials: fluoroalkyl alcohol acrylic resin, fluorosilicone modified hydroxy acrylic resin, organofluorine modified acrylic resin, silicone fluorinated urethane acrylic resin.
Further, the curing agent is one or a mixture of more of the following materials: isocyanate, amino resin, titanium tetraisopropoxide and vinyl dimethyl acrylic acid.
Further, the diluent is one or a mixture of several of the following materials: styrene, ethyl acetate, ethanol, propylene glycol, isopropanol.
Further, the auxiliary agent is one or a mixture of more of the following materials: leveling agent, defoaming agent, color paste and accelerator.
Further, the first PET layer is a water-blocking reinforced composite PET, and is characterized in that it includes: reinforcing material and coated PET film material.
Further, the reinforcing material accounts for 30-40% of the weight of the first PET layer, and comprises one or more of the following materials: nano glass fiber, whisker and carbon fiber.
The substrate is a multilayer co-extrusion composite plate containing a special resin film material A and a resin base material B; the multilayer co-extrusion composite plate is manufactured by respectively carrying out melt extrusion on the raw materials of the special resin film material A and the resin substrate material B through an extruder, converging the raw materials at a co-extrusion die head through respective runners, and cooling the raw materials after casting and molding.
Further, the special resin film material A comprises any one of the following materials: PPS, PEI, ASA; the resin base material B includes any one of the following materials: PVC, PMMA, PET.
In a first aspect of the invention, a method for preparing a photovoltaic tile is provided, comprising the steps of:
s1 lamination: the first packaging layer, the first packaging adhesive film layer, the first PET layer, the second packaging adhesive film layer, the battery piece layer, the third packaging adhesive film layer, the second PET layer, the fourth packaging adhesive film layer and the substrate are paved in sequence to prepare lamination;
s2, vacuumizing and dehumidifying: conveying the photovoltaic tile pavement pieces stacked in the step S1 to a vacuumizing chamber of a laminating machine through a conveying belt to vacuumize and dehumidify;
s3, laminating: conveying the photovoltaic tile paving piece subjected to vacuum pumping and dehumidification in the step S2 to a laminating cavity chamber of a laminating machine for lamination;
s4, cooling: conveying the photovoltaic tile laminate laminated in the step S3 to a cooling empty chamber of a laminating machine for cooling treatment;
s5, cutting: carrying out laser cutting on the photovoltaic tile laminate subjected to the cooling treatment in the step S4;
s6, edge folding: and (5) conveying the photovoltaic tile laminate cut in the step (S5) to a hot bending machine for heating and flanging.
The beneficial effects are that:
1. the FRP plate infiltrated by the fluorine-containing acrylic resin can replace the traditional glass and the fluorine film for packaging, so that the weight of the component can be reduced, the fluorine film has the ultraviolet resistance, and meanwhile, the plate has a bearing effect and plays a role in protecting the component;
2. the PET filled with the reinforcing material is used as the core material, so that the product has good strength, the impact strength is improved, and meanwhile, the nano-plating layer is combined, so that the product has high water blocking performance, and the battery assembly in the photovoltaic tile is protected;
3. the resin composite board is used as a base board, the weight of the product is further reduced, the price is reduced, and the board has excellent ultraviolet aging resistance by using a coextrusion technology, and meanwhile, the board can be further processed through a heating bending process.
It will be readily understood by those skilled in the art that the foregoing is merely illustrative of the preferred embodiments of the present invention and that various modifications, combinations, substitutions, improvements, etc. may be made without departing from the spirit and principles of the invention.

Claims (10)

1. The novel high-water-resistance composite photovoltaic tile is characterized by comprising a first packaging layer, a first packaging adhesive film layer, a first PET layer, a second packaging adhesive film layer, a battery piece layer, a third packaging adhesive film layer, a second PET layer, a fourth packaging adhesive film layer and a substrate which are sequentially stacked, laminated and integrally formed through a laminating machine; the cell layer comprises a plurality of solar cell strings; the first packaging layer is an FRP plate material containing acrylic resin.
2. The novel high water blocking composite photovoltaic tile of claim 1, wherein the acrylic resin comprises the following raw materials in weight percent: 40-50% of fluorine modified acrylic resin, 10-15% of curing agent, 30-40% of diluent and 3-5% of auxiliary agent.
3. The novel high water blocking composite photovoltaic tile according to claim 2, wherein the fluorine modified acrylic resin comprises one or a mixture of several of the following materials: fluoroalkyl alcohol acrylic resin, fluorosilicone modified hydroxy acrylic resin, organofluorine modified acrylic resin, silicone fluorinated urethane acrylic resin.
4. The novel high water blocking composite photovoltaic tile according to claim 2, wherein the curing agent is one or a mixture of several of the following materials: isocyanate, amino resin, titanium tetraisopropoxide and vinyl dimethyl acrylic acid.
5. The novel high water blocking composite photovoltaic tile according to claim 2, wherein the diluent is one or a mixture of several of the following materials: styrene, ethyl acetate, ethanol, propylene glycol, isopropanol.
6. The novel high water blocking composite photovoltaic tile according to claim 2, wherein the auxiliary agent is one or a mixture of several of the following materials: leveling agent, defoaming agent, color paste and accelerator.
7. The novel high water blocking composite photovoltaic tile of claim 1, wherein the first PET layer is a water blocking enhanced composite PET, comprising: reinforcing material and coated PET film material.
8. The novel high water blocking composite photovoltaic tile according to claim 7, wherein the reinforcing material accounts for 30-40% of the weight of the first PET layer, and comprises one or more of the following materials: nano glass fiber, whisker and carbon fiber.
9. The novel high-water-blocking composite photovoltaic tile according to claim 1, wherein the substrate is a multilayer co-extrusion composite plate containing a special resin film material A and a resin base material B; the multilayer co-extrusion composite plate is manufactured by respectively carrying out melt extrusion on the raw materials of the special resin film material A and the resin substrate material B through an extruder, converging the raw materials at a co-extrusion die head through respective runners, and cooling the raw materials after casting and molding.
10. The novel high-water-blocking composite photovoltaic tile according to claim 7, wherein the raw materials of the special resin film material A comprise any one of the following materials: PPS, PEI, ASA; the raw materials of the resin film material B comprise any one of the following materials: PVC, PMMA, PET.
CN202311490409.1A 2023-11-08 2023-11-08 Novel high-water-blocking composite photovoltaic tile Pending CN117558786A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202311490409.1A CN117558786A (en) 2023-11-08 2023-11-08 Novel high-water-blocking composite photovoltaic tile

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202311490409.1A CN117558786A (en) 2023-11-08 2023-11-08 Novel high-water-blocking composite photovoltaic tile

Publications (1)

Publication Number Publication Date
CN117558786A true CN117558786A (en) 2024-02-13

Family

ID=89817770

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202311490409.1A Pending CN117558786A (en) 2023-11-08 2023-11-08 Novel high-water-blocking composite photovoltaic tile

Country Status (1)

Country Link
CN (1) CN117558786A (en)

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