CN117524535A - Fluorescent condenser mixed photovoltaic effect stabilized isotope battery - Google Patents

Fluorescent condenser mixed photovoltaic effect stabilized isotope battery Download PDF

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Publication number
CN117524535A
CN117524535A CN202311663881.0A CN202311663881A CN117524535A CN 117524535 A CN117524535 A CN 117524535A CN 202311663881 A CN202311663881 A CN 202311663881A CN 117524535 A CN117524535 A CN 117524535A
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CN
China
Prior art keywords
fluorescent
quantum dot
concentrator
battery
photovoltaic
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Pending
Application number
CN202311663881.0A
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Chinese (zh)
Inventor
周涛
顿世雷
白宗艳
卢怀畅
刘晓芳
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Southeast University
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Southeast University
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Publication date
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Priority to CN202311663881.0A priority Critical patent/CN117524535A/en
Publication of CN117524535A publication Critical patent/CN117524535A/en
Pending legal-status Critical Current

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Classifications

    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21HOBTAINING ENERGY FROM RADIOACTIVE SOURCES; APPLICATIONS OF RADIATION FROM RADIOACTIVE SOURCES, NOT OTHERWISE PROVIDED FOR; UTILISING COSMIC RADIATION
    • G21H1/00Arrangements for obtaining electrical energy from radioactive sources, e.g. from radioactive isotopes, nuclear or atomic batteries
    • G21H1/12Cells using conversion of the radiation into light combined with subsequent photoelectric conversion into electric energy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/054Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means
    • H01L31/0547Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means comprising light concentrating means of the reflecting type, e.g. parabolic mirrors, concentrators using total internal reflection
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/054Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means
    • H01L31/055Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means where light is absorbed and re-emitted at a different wavelength by the optical element directly associated or integrated with the PV cell, e.g. by using luminescent material, fluorescent concentrators or up-conversion arrangements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/46Accumulators structurally combined with charging apparatus
    • H01M10/465Accumulators structurally combined with charging apparatus with solar battery as charging system
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02JCIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
    • H02J7/00Circuit arrangements for charging or depolarising batteries or for supplying loads from batteries
    • H02J7/34Parallel operation in networks using both storage and other dc sources, e.g. providing buffering
    • H02J7/35Parallel operation in networks using both storage and other dc sources, e.g. providing buffering with light sensitive cells

Abstract

The invention discloses a fluorescent concentrator mixed photovoltaic effect voltage stabilization isotope battery, which is characterized in that a set of isotope battery system which can stably and efficiently provide high-performance electrical output, save the use area of a photovoltaic module and improve the photoelectric conversion efficiency is established by optimizing the battery structure and the module. The battery consists of elements such as a nuclear energy fluorescent luminotron, a fluorescent quantum dot concentrator photovoltaic cell, a voltage transformation charger, a lithium battery, a lead and the like. The photovoltaic cell is optimized, and the variable-voltage charger and the lithium battery are arranged, so that the fluorescent luminous tube and the light energy in the external environment can be simultaneously utilized, and the electrical output power of the isotope battery is improved. In addition, the photoelectric conversion efficiency can be fully improved, the use area of the photovoltaic module is saved, the stability of the electrical output of the isotope battery is improved, and the endurance time is prolonged. The invention has wide application range, is simple, convenient and efficient, and can be applied to the fields of deep sea, deep space, polar region, remote region and the like.

Description

Fluorescent condenser mixed photovoltaic effect stabilized isotope battery
Technical Field
The invention relates to a fluorescent condenser mixed photovoltaic effect voltage stabilization isotope battery technology, and belongs to the technical field of isotope batteries and photovoltaic power generation.
Background
The isotope battery is a device for converting decay energy of radioactive isotopes into electric energy, is not influenced by external environment in the power supply process, has stable and reliable working condition, does not need manual intervention and maintenance, has the unique advantages of high energy density, stable energy source, sustainable self-power supply and the like, and can be applied for a long time in severe environments and occasions where human beings are difficult to reach, such as deep sea, deep space, polar regions, remote areas and cardiac pacemakers.
The solar fluorescent concentrator is an optical device capable of converting sunlight with low photoelectric conversion efficiency into fluorescent light with high quantum efficiency, and simultaneously transmitting the fluorescent light to the edge of the device by utilizing the principle of total reflection. The photoelectric conversion efficiency can be effectively improved, and the use area of the photovoltaic module is saved.
The ray fluorescence volt effect mechanism is to utilize particles emitted by RI to excite fluorescent substances to emit fluorescence, and then generate current under the photovoltaic effect, and the radiation photovoltaic effect isotope battery can be manufactured according to the principle. The nuclear battery is a nuclear battery with an indirect energy conversion mechanism, energy-carrying particles generated by decay of a radioactive isotope source are irradiated on a fluorescent layer to excite radiation-induced fluorescent photons, and finally the radiation-induced fluorescent photons are collected by a photovoltaic unit to form electrical output. The roqueen of the south kyo proprietary intellectual property company proposed to use a nuclear battery to equip a lithium battery for extended duration, but did not complete the specific implementation and did not solve the problem of lower output power of the isotope battery. The existing radiation-induced photovoltaic effect isotope battery still has a plurality of problems such as low energy conversion efficiency, low electrical output performance and unstable output voltage, so that the energy-induced photovoltaic effect isotope battery cannot meet the power and voltage requirements of electronic equipment and cannot be used as a direct power supply.
The photovoltaic power generation is an advanced and novel power generation technology, and has the advantages of environmental friendliness, safety, reliability, sanitation, no noise and the like compared with a coal power generation mode. However, the conventional photovoltaic power generation mode using solar energy has various problems such as low photoelectric conversion efficiency, large using area of the photovoltaic module, and harmful heat accumulation. The solar fluorescent condenser can fully utilize scattered and non-direct sunlight without installing a sunlight tracking system, can greatly reduce cost and save occupied area, and is widely applied to urban buildings.
In order to solve the defects in the prior art, the invention aims to provide the fluorescent condenser mixed photovoltaic effect stable voltage isotope battery, so that higher-performance electrical output is stably provided, the use area of a photovoltaic module can be saved, the photoelectric conversion efficiency is improved, and the endurance time is prolonged.
Disclosure of Invention
Technical problems: the invention provides a fluorescent condenser mixed photovoltaic effect stable-voltage isotope battery, which can not only stably and efficiently provide higher-performance electrical output, but also save the use area of a photovoltaic module and improve the photoelectric conversion efficiency.
The technical scheme is as follows: the invention discloses a fluorescent concentrator mixed photovoltaic effect voltage stabilization isotope battery, which comprises a nuclear energy fluorescent luminotron, fluorescent quantum dot concentrator photovoltaic cells, a voltage transformation charger and a lithium battery, wherein the total number of the fluorescent quantum dot concentrator photovoltaic cells is six, and the nuclear energy fluorescent luminotron is surrounded by the six fluorescent quantum dot concentrator photovoltaic cells; the six fluorescent quantum dot concentrator photovoltaic cells are connected through wires and then connected with the input end of the voltage transformation charger; the charging end of the lithium battery is connected with the output end of the voltage transformation charger, the output end of the lithium battery is connected with the electronic equipment and used for providing electrical output, and meanwhile, the use area of the photovoltaic module is saved, the photoelectric conversion efficiency is improved, and the endurance time is prolonged.
Further, the nuclear energy fluorescent luminotron comprises an isotope source and a radiation-induced fluorescent crystal.
Further, the isotope sources include, but are not limited to, tritium-3, nickel-63, strontium-90 for producing radiant energy, and the radioisotope source is a solid sheet source, a liquid source, or a gel source; the radiation-induced fluorescence crystal comprises, but is not limited to, scintillation crystals of YAG: ce, GAGG: ce, luAG: pr, and the like, and is used for converting the radiation energy into light energy.
Further, the outer layer of the nuclear energy fluorescent luminous tube is provided with a radiation shielding layer which is made of resin or/and nano lead composite material or resin/nano lead sulfate composite material, so that the leakage of rays is prevented.
Further, the fluorescent quantum dot concentrator photovoltaic cell is of a double-layer symmetrical structure, a first glass cover plate, a first quantum dot film concentrator, a bottom plate, a second quantum dot film concentrator and a second glass cover plate are arranged from top to bottom respectively, high reflection films are arranged on the side wall and the bottom plate, and a photovoltaic plate is arranged at the rightmost end.
Furthermore, the first fluorescent quantum dot concentrator and the second fluorescent quantum dot concentrator are made by coating quantum dot mixed solution on the surface of a waveguide carrier.
Further, the waveguide carrier is glass or organic glass.
Further, the quantum dot mixed solution consists of quantum dots and a polymer solution. The quantum dot is selected from at least one of C quantum dot, cdSe/CdS quantum dot and perovskite quantum dot. The polymer is at least one selected from polyvinylpyrrolidone, polymethyl methacrylate, polystyrene and polydodecyl methacrylate.
Further, the mass content of the quantum dots in the quantum dot mixed solution is 1-15%, and the mass content of the polymer in the polymer solution is 5-20%.
Further, the material of the high-reflection film is silver, gold, copper or aluminum, and silver is most preferable.
Further, the glass cover plate has the size of 1200mm multiplied by 540mm multiplied by 5mm, the thin film condenser has the size of 1200mm multiplied by 540mm multiplied by 5mm, the photovoltaic panel has the size of 200mm multiplied by 500mm multiplied by 5m, and the output power under the condition of external normal illumination can be higher than 600W
Furthermore, the voltage transformation charger is connected with the fluorescent quantum dot concentrator photovoltaic cell and the lithium battery, and has the function of realizing electric energy conversion.
Further, the lithium battery is charged and stored by the voltage transformation charger, and electric energy is output outwards through the positive electrode and the negative electrode.
The beneficial effects are that: compared with the prior art, the invention has the beneficial effects that:
the double-layer symmetrical structure of the fluorescent quantum dot concentrator photovoltaic cell not only can convert light energy generated by the nuclear energy fluorescent luminous tube in the cell into electric energy, but also can utilize light energy in the external environment, thereby improving the electrical output of the isotope cell. Meanwhile, the use of the fluorescent quantum dot concentrator photovoltaic cell can improve the photoelectric conversion efficiency and save the use area of a photovoltaic module. The stability of the electrical output of the isotope battery is improved by the arrangement of the voltage transformation charger. Through setting up the lithium cell, the non-operating time stores the electric energy to provide the electricity output that can satisfy electronic equipment demand at operating time, solved the isotope battery and although can release a large amount of energy for a long time, the less problem of output electric energy in the unit time has improved duration.
Drawings
The accompanying drawings are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate the invention and together with the embodiments of the invention, and do not limit the invention. In the drawings:
FIG. 1 is a schematic perspective view of a fluorescent concentrator hybrid photovoltaic effect stabilized isotope battery in accordance with the present invention;
FIG. 2 is a front view of a fluorescent concentrator hybrid photovoltaic effect stabilized isotope battery in accordance with the present invention;
fig. 3 is a schematic structural view of a fluorescent quantum dot concentrator photovoltaic cell according to the present invention.
Detailed Description
The preferred embodiments of the present invention will be described below with reference to the accompanying drawings, it being understood that the preferred embodiments described herein are for illustration and explanation of the present invention only, and are not intended to limit the present invention.
Fig. 1 is a schematic perspective view of a fluorescent concentrator mixed photovoltaic effect stable voltage isotope battery according to the invention, and fig. 3 is a schematic view of a fluorescent quantum dot concentrator photovoltaic cell according to the invention. As shown in the figure, the fluorescent concentrator mixed photovoltaic effect stable voltage isotope battery comprises a plurality of fluorescent quantum dot concentrator photovoltaic cells 1, a nuclear energy fluorescent luminous tube 2, a lithium battery 3, a voltage transformation charger 4 and two positive and negative electrodes 5 of the lithium battery. Each fluorescent quantum dot concentrator photovoltaic cell 1 comprises a first glass cover plate 61, a second glass cover plate 62, a first quantum dot thin film concentrator 71, a second quantum dot thin film concentrator 72, a bottom plate 8, a photovoltaic panel 9, and highly reflective thin films disposed on the bottom plate and sides.
In the embodiment of the invention, each fluorescent quantum dot concentrator photovoltaic cell (11, 12, 13, 14, 15, 16) has a double-layer symmetrical structure, so that not only can the light energy generated by the nuclear energy fluorescent tube 2 inside the cell be converted into electric energy, but also the light energy in the external environment can be utilized, thereby improving the electrical output of the isotope cell and realizing the mixed photovoltaic effect power generation of the isotope cell.
In the embodiment of the invention, sunlight in the external environment irradiates onto the first quantum dot film concentrator 71 through the first glass cover plate 61, low-quantum-efficiency fluorescence generated by the nuclear fluorescent tube 2 irradiates onto the second quantum dot film concentrator 72 through the second glass cover plate 62, and the first quantum dot film concentrator 71 and the second quantum dot film concentrator 72 respectively convert the sunlight in the external environment and the low-quantum-efficiency fluorescence generated by the nuclear fluorescent tube 2 into high-quantum-efficiency fluorescence. The high reflection film on the bottom plate 8 and the side surface uses the principle of total reflection to conduct fluorescence with high quantum efficiency to the right photovoltaic panel 9 for photoelectric conversion, thereby improving the photoelectric conversion efficiency and saving the use area of the photovoltaic module.
In the embodiment of the invention, the nuclear energy fluorescent luminotron 2 comprises an isotope source and a radiation-induced fluorescent crystal, and particles emitted by the isotope source excite fluorescent substances to emit fluorescence, so that light energy is provided, and the light energy is converted into electric energy through the fluorescent quantum dot concentrator photovoltaic cell 1. Meanwhile, the outer layer of the nuclear energy fluorescent luminotron 2 is provided with a radiation shielding layer which is made of resin or/and nano lead composite material or resin/nano lead sulfate composite material, so that the leakage of rays is prevented.
In the embodiment of the invention, the voltage transformation charger 4 has the function of electric energy conversion, the input end of the voltage transformation charger 4 is connected with the fluorescent quantum dot concentrator photovoltaic cell 1, and the voltage and the current generated by the fluorescent quantum dot concentrator photovoltaic cell 1 are connected with the lithium battery 3 through the power output end after passing through the amplifying circuit of the voltage transformation charger 4.
In the embodiment of the invention, the charging electrode of the lithium battery 3 is connected with the output end of the voltage transformation charger, the power supply positive electrode 51 and the power supply negative electrode 52 are connected with the electronic equipment, and the supply equipment operates normally. The lithium battery can store electric energy when the power supply does not need to supply power, and ensure higher-power electrical output when the power supply supplies power.
In the embodiment of the invention, the double-layer symmetrical structure of the fluorescent quantum dot concentrator photovoltaic cell not only can convert the light energy generated by the nuclear energy fluorescent tube inside the cell into electric energy, but also can utilize the light energy in the external environment, thereby improving the electrical output of the isotope cell. Meanwhile, the use of the fluorescent quantum dot concentrator photovoltaic cell can improve the photoelectric conversion efficiency and save the use area of a photovoltaic module. The stability of the electrical output of the isotope battery is improved by the arrangement of the voltage transformation charger. Through setting up the lithium cell, the non-operating time stores the electric energy to provide the electricity output that can satisfy electronic equipment demand at operating time, solved the isotope battery and although can release a large amount of energy for a long time, the less problem of output electric energy in the unit time has improved duration.
Those of ordinary skill in the art will appreciate that: the foregoing description is only a preferred embodiment of the present invention, and the present invention is not limited thereto, but it is to be understood that modifications and equivalents of some of the technical features described in the foregoing embodiments may be made by those skilled in the art, although the present invention has been described in detail with reference to the foregoing embodiments. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (9)

1. The utility model provides a fluorescent light concentrator mixes steady voltage isotope battery of photovoltaic effect, includes nuclear fluorescence luminotron, fluorescent quantum dot concentrator photovoltaic cell, vary voltage charger, lithium cell and wire, its characterized in that, fluorescent quantum dot concentrator photovoltaic cell totally has six, the nuclear fluorescence luminotron is surrounded by six fluorescent quantum dot concentrator photovoltaic cells; six fluorescent quantum dot concentrator photovoltaic cells are connected through a wire and then connected with the input end of the voltage transformation charger; the charging end of the lithium battery is connected with the output end of the voltage transformation charger, and the output end of the lithium battery is connected with the electronic equipment and used for providing electrical output.
2. The fluorescent concentrator mixed photovoltaic effect stable voltage isotope battery according to claim 1, wherein the fluorescent quantum dot concentrator photovoltaic cell is of a double-layer symmetrical structure, and comprises a first glass cover plate, a first quantum dot film concentrator, a bottom plate, a second quantum dot film concentrator and a second glass cover plate from top to bottom; the side wall and the bottom plate of the fluorescent quantum dot concentrator photovoltaic cell are both provided with high-reflection films, and the right end of the side wall and the bottom plate is provided with a photovoltaic plate.
3. The fluorescent concentrator mixed photovoltaic effect stable voltage isotope battery of claim 2 wherein the first and second fluorescent quantum dot concentrators are formed by coating a quantum dot mixed solution on the surface of a waveguide carrier.
4. A fluorescent concentrator hybrid photovoltaic effect stable voltage isotope battery as claimed in claim 3 wherein the waveguide carrier is glass or organic glass; the quantum dot mixed solution consists of quantum dots and polymer solution; the quantum dot is at least one of C quantum dot, cdSe/CdS quantum dot and perovskite quantum dot, and the polymer is at least one of polyvinylpyrrolidone, polymethyl methacrylate, polystyrene and polydodecyl methacrylate.
5. The fluorescent concentrator hybrid photovoltaic effect stable isotope battery of claim 2 wherein the highly reflective film is silver, gold, copper or aluminum.
6. The portable hybrid photovoltaic regulated isotope battery of claim 1 wherein said nuclear fluorescent tube comprises an isotope source and a radiogenic fluorescent crystal, particles emitted from the isotope source excite fluorescent material to fluoresce; and meanwhile, the radiation shielding layer is arranged on the outer layer of the nuclear energy fluorescent luminous tube and is made of resin or/and nano lead composite material or resin/nano lead sulfate composite material, so that the leakage of rays is prevented.
7. The portable hybrid photovoltaic regulated isotope battery of claim 6 wherein the isotope source includes but is not limited to tritium-3, nickel-63, strontium-90, the radioisotope source is a solid sheet source, a liquid source or a gel source; the radiation-induced fluorescence crystal comprises, but is not limited to, scintillation crystal of YAG: ce, GAGG: ce, luAG: pr material.
8. The portable hybrid photovoltaic effect stable voltage isotope battery of claim 1 wherein the input end of the voltage transformation charger is connected to the fluorescent quantum dot concentrator photovoltaic cell, and the voltage and current generated by the fluorescent quantum dot concentrator photovoltaic cell is connected to the lithium battery after passing through the amplifying circuit of the voltage transformation charger.
9. The portable hybrid photovoltaic effect stable isotope battery of claim 1 wherein the charging electrode of the lithium battery is connected to the output of the variable voltage charger and the power supply electrode is connected to the electronic device for normal operation of the device.
CN202311663881.0A 2023-12-06 2023-12-06 Fluorescent condenser mixed photovoltaic effect stabilized isotope battery Pending CN117524535A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202311663881.0A CN117524535A (en) 2023-12-06 2023-12-06 Fluorescent condenser mixed photovoltaic effect stabilized isotope battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202311663881.0A CN117524535A (en) 2023-12-06 2023-12-06 Fluorescent condenser mixed photovoltaic effect stabilized isotope battery

Publications (1)

Publication Number Publication Date
CN117524535A true CN117524535A (en) 2024-02-06

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Family Applications (1)

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Country Status (1)

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