CN1175066C - Environmental protection cable wire coating composition - Google Patents
Environmental protection cable wire coating composition Download PDFInfo
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- CN1175066C CN1175066C CNB011354828A CN01135482A CN1175066C CN 1175066 C CN1175066 C CN 1175066C CN B011354828 A CNB011354828 A CN B011354828A CN 01135482 A CN01135482 A CN 01135482A CN 1175066 C CN1175066 C CN 1175066C
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- environmental protection
- cable wire
- wire coating
- coating composition
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- 230000007613 environmental effect Effects 0.000 title claims abstract description 32
- 239000008199 coating composition Substances 0.000 title claims abstract description 29
- 239000000203 mixture Substances 0.000 claims abstract description 36
- 239000004698 Polyethylene Substances 0.000 claims abstract description 20
- 229920000573 polyethylene Polymers 0.000 claims abstract description 20
- 239000005038 ethylene vinyl acetate Substances 0.000 claims abstract description 18
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims abstract description 18
- -1 polyethylene Polymers 0.000 claims abstract description 13
- 229920000642 polymer Polymers 0.000 claims abstract description 12
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 9
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920001684 low density polyethylene Polymers 0.000 claims abstract 5
- 239000004702 low-density polyethylene Substances 0.000 claims abstract 5
- 239000000758 substrate Substances 0.000 claims description 10
- 239000012796 inorganic flame retardant Substances 0.000 claims description 7
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 7
- 238000012986 modification Methods 0.000 claims description 6
- 230000004048 modification Effects 0.000 claims description 6
- 239000004200 microcrystalline wax Substances 0.000 claims description 4
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 3
- 229920002545 silicone oil Polymers 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical group [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 2
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 150000002989 phenols Chemical class 0.000 claims description 2
- 150000007970 thio esters Chemical class 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims 1
- 239000000347 magnesium hydroxide Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 14
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 5
- 239000003063 flame retardant Substances 0.000 abstract description 5
- 238000012545 processing Methods 0.000 abstract description 4
- 239000003607 modifier Substances 0.000 abstract 2
- 229920000578 graft copolymer Polymers 0.000 abstract 1
- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 description 12
- 238000002485 combustion reaction Methods 0.000 description 12
- 239000004800 polyvinyl chloride Substances 0.000 description 10
- 229920000915 polyvinyl chloride Polymers 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 239000007789 gas Substances 0.000 description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 150000002431 hydrogen Chemical class 0.000 description 5
- 239000010954 inorganic particle Substances 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 235000021355 Stearic acid Nutrition 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 4
- 239000008117 stearic acid Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 239000002574 poison Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 239000002341 toxic gas Substances 0.000 description 3
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000013031 physical testing Methods 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 235000019260 propionic acid Nutrition 0.000 description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- VWGKEVWFBOUAND-UHFFFAOYSA-N 4,4'-thiodiphenol Chemical compound C1=CC(O)=CC=C1SC1=CC=C(O)C=C1 VWGKEVWFBOUAND-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- 239000003508 Dilauryl thiodipropionate Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241001214714 Niea Species 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 206010037423 Pulmonary oedema Diseases 0.000 description 1
- GWGQGJDKNKYSRM-UHFFFAOYSA-N S(C1=C(C=CC2=CC=CC=C12)C=O)C1=C(C=CC2=CC=CC=C12)C=O Chemical compound S(C1=C(C=CC2=CC=CC=C12)C=O)C1=C(C=CC2=CC=CC=C12)C=O GWGQGJDKNKYSRM-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 235000019304 dilauryl thiodipropionate Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical compound C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 1
- 235000019439 ethyl acetate Nutrition 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- YXVJNOXXPKIWIM-UHFFFAOYSA-N n-(2-hydroxyethyl)-n-(2-hydroxypropyl)nitrous amide Chemical compound CC(O)CN(N=O)CCO YXVJNOXXPKIWIM-UHFFFAOYSA-N 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-O oxonium Chemical compound [OH3+] XLYOFNOQVPJJNP-UHFFFAOYSA-O 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N pentanoic acid group Chemical group C(CCCC)(=O)O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 208000005333 pulmonary edema Diseases 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229940117958 vinyl acetate Drugs 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
The present invention relates to an environmental protection cable wire coating composition which comprises 100 parts by weight of base material polymer, 100 to 200 parts by weight of flame retardant, 1 to 4 parts by weight of antioxidant, 1 to 5 parts by weight of processing agent, and 5 to 20 parts by weight of polyethylene (PE) modifier, wherein the base material polymer is a composition of ethylene-vinyl acetate copolymer (eva) and low-density polyethylene (LDPE), and the polyethylene (PE) modifier is a graft polymer formed by grafting maleic anhydride on polyethylene.
Description
Technical field
The relevant a kind of cable wire coating composition of the present invention refers to a kind of environmental protection cable wire coating composition especially.
Background technology
Cable is widely used in power line, connection and optical fiber cable etc., and its flame resistivity influences the security of superelevation building, rapid transit, market, office block etc.In case cable is impaired because of fire, then the take refuge required fume exhaust system of escape, warning system, reporting chain etc. can't operate, and not only influence is escaped and also is unfavorable for the disaster rescue.Therefore, the material that lining is used outside the cable must be particular about flame resistivity especially.
The outer lining of existing cable is mainly with polyvinyl chloride (PVC, polyvinyl chloride) be base material, can disengage chlorion or spirit of salt etc. during owing to the PVC material combustion, it can catch the free radical that causes fire spread, reach the effect that suppresses chain reaction, so can slow down fire spread.Yet, not only produce dioxin poison gases such as (Dioxin) during the PVC material combustion, also can produce a large amount of black smokes and corrosive gases, the dense smoke that the scene of fire produces hinders take refuge escape and rescue work to carry out, corrosive gases can make the people suffer from pulmonary edema even death after sucking, simultaneously also corrode machinery equipment, cause greatest property damage.
In order to improve the problem that the PVC material combusting is caused, develop at present with polyolefin resin, polyethylene, polypropylene or its co-polymer (ethene-vinyl acetate polymkeric substance for example, (ethylene-vinyl acetatecopolymer is to call the EVA resin in the following text) is the cable serving of base material.Yet, these materials itself have combustibility, therefore must additionally add flame retardant to reach anti-combustion effect, because flame retardant is inorganic particle mostly, and substrate polymer is an organism, the consumption of inorganic particle very high (be generally substrate polymer 0.5 to 2 times), inorganic particle is difficult for being scattered in the substrate polymer, so the adulterant that is generated is heterogeneity phase (heterogeneity), when moulding, easily produce hole, cause the physical strength of cable serving to descend.The general way of compatibility that improves is for to carry out surface treatment with inorganic flame retardant with compounds such as stearic acid or oleic acid, with the dispersiveness that improves incombustible agent (referring to United States Patent (USP) the 4th, 671, No. 896), though this kind mode can solve inorganic particle and the not good problem of substrate polymer compatibility, its shortcoming is that required stearic acid or oleic processing cost are quite high.
Therefore, the invention provides a kind of environmental protection cable wire coating composition, to solve above-mentioned shortcoming.
Summary of the invention
The purpose of this invention is to provide a kind of environmental protection cable wire coating composition, the amount of being fuming during its burning is low far beyond the PVC plastics.
Another object of the present invention provides a kind of environmental protection cable wire coating composition, does not produce dioxin (Dioxin) and corrosive gases during its burning, to ensure HUMAN HEALTH and property device security.
Another purpose of the present invention provides a kind of environmental protection cable wire coating composition, and it has callable characteristic, to meet environmental benefit.
A further object of the present invention provides a kind of environmental protection cable wire coating composition, and it not only can guarantee safety and environmental protection, and does not damage the physical properties of made product.
Another object of the present invention provides a kind of environmental protection cable wire coating composition, and it can promote compatible and escapable cost between inorganic particle and the substrate polymer.
For achieving the above object, environmental protection cable wire coating composition of the present invention, it comprises:
A) substrate polymer of 100 weight parts, it is the mixture of ethylene-vinyl acetate copolymer (EVA) and new LDPE (film grade) (LDPE);
B) flame retardant of 100 to 200 weight parts;
C) antioxidant of 1 to 4 weight part;
D) silicone oil of 1 to 5 weight part, Microcrystalline Wax or stearate; And
E) polyethylene of 5 to 20 weight parts (PE) modification agent, it is the graftomer of maleic anhydride graft on polyethylene.
Embodiment
According to environmental protection cable wire coating composition of the present invention, mainly comprise following five kinds of compositions.
Composition A
Composition A according to the present invention is substrate polymer (Base Polymer), it comprise ethylene-vinyl acetate copolymer (Ethylene-vinylacetate copolymer, EVA) and new LDPE (film grade) (LDPE).
Consumption with composition A is a benchmark, and EVA accounts for 40 to 90 weight %, and is preferably 60 to 80 weight %.
(melting index MI) is preferably between 0.5 to 10 gram/10 minutes the melting coefficient of LDPE, is more preferred between 1 to 5 gram/10 minutes.The melting coefficient of EVA is preferably between 0.5 to 10 gram/10 minutes, and the best is between 1 to 5 gram/10 minutes.
The content of the acetic ester among the EVA (vinyl acetate) is preferably 18 to 33 weight %, is more preferred from 20 to 30 weight %.
Composition B
Composition B according to the present invention is inorganic flame retardant.Utilizing inorganic flame retardant retarded combustion is that the present technique field is familiar with.The inorganic combustion inhibitor of composition B according to the invention is preferably W 4600 (Al (OH)
33H
2O) or hydronium(ion) oxidation magnesium etc., these hydrated things at high temperature thermal endothermic decomposition are oxide compound and water vapour, and the fire extinguishing effect that can reach cooling and suffocate also can discharge positively charged ion simultaneously, can suppress the free radical that combustion processes produces, so that slow down chain reaction.
Composition C
Composition C according to the present invention is an antioxidant, its function series is in order to slow down the macromolecular material automatic oxidation rate, and the condition of selecting for use is to have good oxidation-resistance, good with the macromolecular material compatibility, stable under processing temperature (with other auxiliary agent reaction, nondiscoloration), nontoxicity, do not influence high molecular other characteristic.The antioxidant that is fit to is for example phenols (for example comprising single phenol, polyphenol, Resorcinol, thiobisphenol) used always of present technique field, amine (pentanoic, Ursol D), thioesters class and composition thereof.
Preferable composition C be for for example Tyox B (dilauryl thiodipropionate), four [3-(3 ', 5 '-di-t-butyl-4 '-hydroxy phenyl) propionic acid] pentaerythritol ester (antioxidant, 1010), 1,1 '-thiobis (beta naphthal).
Components D
Be applicable to that components D of the present invention is a processing aid, main system mixes plastics and evenly and easily extrudes, and the silicone oil that uses with those skilled in the art, Microcrystalline Wax (microcrystalline wax), stearate etc. are preferable.
Composition E
Composition E according to the present invention is the PE modification agent, and its primary structure is a grafted maleic anhydride on the PE base material, and its effect system increases polymer interchain free volume, and the amount of being added flame retardant to promote promotes the compatibility between composition A and the composition B simultaneously.
Composition E be with maleic anhydride graft on polyethylene (PE) grafting base, weight with composition E is benchmark, wherein the content of maleic anhydride is 0.5 to 10 weight %, is preferably 1 to 5 weight %, and the content of polyethylene (PE) is 90 to 99.5 weight %, be preferably 95 to 99 weight %.
Embodiment 1 to 3
The lining of preparation cable
Three kinds of cables prescription that is covered is outward placed mixing tank respectively according to the part by weight of table one, then carry out mixing and granulate, then extrude cable in the hot compacting mode with existing method.Table one shows the composite formula of three kinds of made cable wire coatings, and it is respectively the lining of low elongation cable, the lining of high elongation rate cable and communication cable lining.
Table one. three kinds of cable lining prescriptions
| Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| A.1 EVA | 70 | 70 | 70 |
| A.2 LDPE | 25 | 25 | 25 |
| B aluminium hydroxide | 130 | 100 | 120 |
| C antioxidant * | 3 | 3 | 3 |
| The D stearic acid | 1 | 1 | 1 |
| E PE modification agent | 5 | 5 | 5 |
* four [3-(3 ', 5 '-di-t-butyl-4 '-hydroxy phenyl) propionic acid] pentaerythritol ester (antioxidant, 1010)
Physical testing
Above-mentioned three kinds of products are through physical testings such as elongation and tensile strength, and result such as table two all meet product specification.
Table two. the physical properties test result of three kinds of outer linings of cable
| Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| Elongation (%) | 250 (more than 125) | 382 (more than 350) | 320 (more than 300) |
| Tensile strength (MPa) | (10.8 more than 6.0) | 12 (more than 10) | 9 (more than 8) |
| The result | Qualified | Qualified | Qualified |
Annotate: the standard of the described product of expression in ()
Returnability
Above-mentioned three kinds of products all can the hot compacting mode extrude cable after crushed again.
Combustion test
Above-mentioned three kinds of products are carried out combustion test, and the result of data such as the oxygen index value value of gained, the amount of being fuming, burning gas potential of hydrogen, poison exponent, dioxin (Dioxin) content as shown in Table 3.
Wherein testing standard is as follows:
1. oxygen index value value-according to ASTM D2868
2. the amount of being fuming-get thickness is 0.5 ± 0.1 millimeter test piece, according to ASTM E662
3. burning gas potential of hydrogen-according to IEC 754-2
4. poison exponent-according to NES 713
5. dioxin (Dioxin) content-according to Environmental Protection Administration NIEA A810.10B
Table three. the combustion test result of three kinds of outer linings of cable
| Embodiment 1 | Embodiment 2 | Embodiment 3 | ||
| Oxygen index value value (%) | 34 | 28 | 31 | |
| The amount of being fuming | 191 | 125 | 120 | |
| The color of being fuming | In vain | In vain | In vain | |
| Burning gas potential of hydrogen (pH) | 4.5 | 4.0 | 4.0 | |
| The poison gas index | CO 2(％) | 0.1 | 0.1 | 0.1 |
| CO(ppm) | 9 | 8 | 9 | |
| NO x(ppm) | 1 | 1 | 1 | |
| Dioxin content (ng/g) | 0 | 0 | 0 | |
Relatively
Tradition is carried out combustion test as embodiment 1-3 with the outer lining of the cable of PVC substrate preparation, and its result as shown in Table 4.
The combustion test result of the outer lining of table four .PVC cable
| Test event | Data |
| Oxygen index value value (%) | 26 |
| The amount of being fuming | 397 | |
| The color of being fuming | Black | |
| Burning gas potential of hydrogen (pH) | 2.0 | |
| The poison gas index | CO 2(％) | 0.3 |
| CO(ppm) | 14 | |
| NO x(ppm) | 1 | |
| Dioxin content (ng/g) | 20 | |
Comparison sheet three and table four, can find that the amount of being fuming, poison gas and dioxin (Dioxin) content that the made cable wire coating of environmental protection cable wire coating composition of the present invention is produced is low far beyond adopting the made person of PVC base material when combustion test, oxygen index value and burning gas potential of hydrogen are then higher, therefore cable wire coating tool returnability uses the made cable wire coating of constituent of the present invention to have environmental protection and security concurrently simultaneously.
Quite high with required stearic acid of the inorganic flame retardant of surface treatment or oleic processing cost in the prior art, and in the environmental protection cable wire coating composition of the present invention, substrate polymer with 100 weight parts is a benchmark, only need the PE modification agent of 5 to 20 weight parts, and its cost only is about surface-treated 50%.In addition, the elongation of the cable wire coating that constituent of the present invention is made and tensile strength also show quite high level, and susceptible of proof PE modification agent can effectively be promoted the compatibility of base material polymerization and inorganic flame retardant.
Claims (14)
1. environmental protection cable wire coating composition, it comprises:
A) substrate polymer of 100 weight parts, it is the mixture of ethylene-vinyl acetate copolymer and new LDPE (film grade);
B) the inorganic flame retardant of 100 to 200 weight parts;
C) antioxidant of 1 to 4 weight part;
D) silicone oil of 1 to 5 weight part, Microcrystalline Wax or stearate; And
E) the polyethylene modification agent of 5 to 20 weight parts, it is the graftomer of maleic anhydride graft on polyethylene.
2. environmental protection cable wire coating composition as claimed in claim 1 is characterized in that, ethylene-vinyl acetate copolymer accounts for 40 to 90 weight % among the composition A.
3. environmental protection cable wire coating composition as claimed in claim 1 is characterized in that, the melting coefficient of ethylene-vinyl acetate copolymer is between 0.5 to 10 gram/10 minutes among the composition A.
4. environmental protection cable wire coating composition as claimed in claim 3 is characterized in that, the melting coefficient of ethylene-vinyl acetate copolymer is between 1 to 5 gram/10 minutes among the composition A.
5. environmental protection cable wire coating composition as claimed in claim 1 is characterized in that, the content of the vinyl acetate among the composition A in the ethylene-vinyl acetate copolymer is 18 to 33 weight %.
6. environmental protection cable wire coating composition as claimed in claim 5 is characterized in that, the content of the vinyl acetate among the composition A in the ethylene-vinyl acetate copolymer is 20 to 30 weight %.
7. environmental protection cable wire coating composition as claimed in claim 1 is characterized in that, the melting coefficient of new LDPE (film grade) is between 1 to 10 gram/10 minutes among the composition A.
8. environmental protection cable wire coating composition as claimed in claim 7 is characterized in that, the melting coefficient of new LDPE (film grade) is between 1 to 5 gram/10 minutes among the composition A.
9. environmental protection cable wire coating composition as claimed in claim 1 is characterized in that, inorganic flame retardant is aluminium hydroxide or magnesium hydroxide.
10. environmental protection cable wire coating composition as claimed in claim 1 is characterized in that, described antioxidant is phenols, amine, thioesters class and composition thereof.
11. environmental protection cable wire coating composition as claimed in claim 1 is characterized in that, the content of the maleic anhydride among the composition E accounts for 0.5 to the 10 weight % of composition E.
12. environmental protection cable wire coating composition as claimed in claim 11 is characterized in that, the content of the maleic anhydride among the composition E accounts for 1 to the 5 weight % of composition E.
13. environmental protection cable wire coating composition as claimed in claim 1 is characterized in that, the poly content among the composition E accounts for 90 to the 99.5 weight % of composition E.
14. environmental protection cable wire coating composition as claimed in claim 13 is characterized in that, the poly content among the composition E accounts for 95 to the 99 weight % of composition E.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011354828A CN1175066C (en) | 2001-10-10 | 2001-10-10 | Environmental protection cable wire coating composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011354828A CN1175066C (en) | 2001-10-10 | 2001-10-10 | Environmental protection cable wire coating composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1410496A CN1410496A (en) | 2003-04-16 |
| CN1175066C true CN1175066C (en) | 2004-11-10 |
Family
ID=4673159
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011354828A Expired - Fee Related CN1175066C (en) | 2001-10-10 | 2001-10-10 | Environmental protection cable wire coating composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1175066C (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101698720B (en) * | 2009-10-28 | 2011-09-14 | 江苏达胜热缩材料有限公司 | Medium and low pressure single wall thermal shrinkage pipe and preparation method thereof |
| CN101701090B (en) * | 2009-10-28 | 2011-11-02 | 江苏达胜热缩材料有限公司 | High-pressure flame retardant single-wall heat-shrinkable pipe and preparation method thereof |
| CN101696294B (en) * | 2009-10-28 | 2011-09-14 | 江苏达胜热缩材料有限公司 | Semi-conducting high-voltage fire retardant single-wall heat-shrinkable tube and preparation method thereof |
| CN102690557A (en) * | 2012-05-30 | 2012-09-26 | 江苏鑫丰塑业有限公司 | Multifunctional plastic coated material and preparation method thereof |
| CN106432885B (en) * | 2012-12-04 | 2019-02-05 | 苏州亨利通信材料有限公司 | Convenient for squeezing out the polyolefine cable sheath material of processing |
| CN103571030B (en) * | 2013-09-30 | 2016-05-04 | 芜湖航天特种电缆厂 | Silane natural-crosslinked cable material of polyolefin of a kind of low smoke and zero halogen and preparation method thereof |
| CN104200890B (en) * | 2014-09-03 | 2016-04-20 | 承德可得电子有限责任公司 | A kind of environmental-protection flame-retardant fire-resistant wire and cable and preparation method thereof |
| CN104194141A (en) * | 2014-09-17 | 2014-12-10 | 朱忠良 | High-filling halogen-free fire-retardant cable material |
| CN105845263B (en) * | 2015-01-14 | 2017-11-03 | 安徽联嘉祥特种电缆有限公司 | Computer transmission cable and preparation method thereof |
| CN106787268A (en) * | 2016-11-22 | 2017-05-31 | 广东美芝制冷设备有限公司 | Compressor and the method for preparing permanent magnet for the compressor |
| TWI730723B (en) * | 2020-04-14 | 2021-06-11 | 雄獅鉛筆廠股份有限公司 | Coating composition and coated article |
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2001
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