CN1174863A - Flame-retarded agent - Google Patents
Flame-retarded agent Download PDFInfo
- Publication number
- CN1174863A CN1174863A CN 96109528 CN96109528A CN1174863A CN 1174863 A CN1174863 A CN 1174863A CN 96109528 CN96109528 CN 96109528 CN 96109528 A CN96109528 A CN 96109528A CN 1174863 A CN1174863 A CN 1174863A
- Authority
- CN
- China
- Prior art keywords
- suppressing agent
- thanomin
- ammonium
- combustion suppressing
- follows
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- GEHMBYLTCISYNY-UHFFFAOYSA-N Ammonium sulfamate Chemical compound [NH4+].NS([O-])(=O)=O GEHMBYLTCISYNY-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 5
- 239000002904 solvent Substances 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 238000002485 combustion reaction Methods 0.000 claims description 16
- 239000004254 Ammonium phosphate Substances 0.000 claims description 12
- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 claims description 12
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 12
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 229940084106 spermaceti Drugs 0.000 claims description 2
- 239000012177 spermaceti Substances 0.000 claims description 2
- 239000003063 flame retardant Substances 0.000 abstract description 14
- 230000001954 sterilising effect Effects 0.000 abstract description 6
- 239000000463 material Substances 0.000 abstract description 4
- 238000005406 washing Methods 0.000 abstract description 3
- 238000003892 spreading Methods 0.000 abstract description 2
- 229920002472 Starch Polymers 0.000 abstract 1
- 230000002159 abnormal effect Effects 0.000 abstract 1
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical compound [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 abstract 1
- 238000004031 devitrification Methods 0.000 abstract 1
- 230000005611 electricity Effects 0.000 abstract 1
- 235000019698 starch Nutrition 0.000 abstract 1
- 239000008107 starch Substances 0.000 abstract 1
- 230000003068 static effect Effects 0.000 abstract 1
- 238000004659 sterilization and disinfection Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000004383 yellowing Methods 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Landscapes
- Fireproofing Substances (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a fire reatrdant whose composition is composed of (wt%) 10%-20% of triammonium phosphate, 8%-15% of ammonium sulfamate, 2%-5% of ethanolaamine and a proper quantity of solvent. The material treated by said fire retardant can keep it original form, colour, properties, and does not product devitrification, does not yellow or starch, has no abnormal smell, and has the several functions of preventing fire from spreading, sterilizing, resisting static electricity and washing fastness etc.
Description
The invention belongs to fire retardant, particularly a kind of combustion suppressing agent that adopts the amido series material.
Existing fire retardant kind is a lot, but all belongs to the composite fire retardant of element such as phosphorous, nitrogen, for example FRP-30 liquid flame retardant, WR-1 type fire retardant, the efficient flame retardant for textile of FP-FT.They have following deficiency:
1, use them to adopt and soak, spray, the scopiform formula is handled on the surface of article, and porous or be dissolved among the object does not fundamentally solve durable effectively fire-retardant.
2, some wash-resistant fabric product is after existing fire retardant is handled, the pulpboard of various degrees, and the phenomenon of losing colour has been destroyed the color and luster and the pliability of original article.
3, existing fire retardant only plays single anti-flaming function, does not have other function.As sterilization, sterilization, other function such as antistatic.
4, the fire-retardant intensity of existing fire retardant is also not very good, awaits further raising.
5, equal slant acidity of the general pH value of existing fire retardant or meta-alkalescence have the corrosion of distinct program to article.
The object of the present invention is to provide a kind of new combustion suppressing agent to overcome the deficiency that above-mentioned prior art exists.
The object of the present invention is achieved like this:
Its composition of a kind of combustion suppressing agent is by ammonium phosphate, Ammonium sulfamate, thanomin and solvent composition.Its main component content is as follows:
Ammonium phosphate 10%-20%
Ammonium sulfamate 8%-15%
Thanomin 2%-5%
All the other are moisture
For universal combustion suppressing agent, its component content is as follows:
Ammonium phosphate 10%-15%
Ammonium sulfamate 8%-10%
Thanomin 2%-5%
For the timber-work combustion suppressing agent, its component content is as follows:
Ammonium phosphate 10%-20%
Ammonium sulfamate 10%-15%
Thanomin 2%-5%
The present invention increases supplementary component and can reach additional function on the basis of main formula.The present invention can be further divided into several classes:
First kind disinfection sterilizing type combustion suppressing agent, its component content is as follows:
Ammonium phosphate 10%-15%
Ammonium sulfamate 8%-10%
Thanomin 2%-5%
Spermaceti alkyl brometo de amonio 2%
All the other are moisture
PH value=7
Second class is antistatic, washing type combustion suppressing agent, and its component content is as follows:
Ammonium phosphate 10%-15%
Ammonium sulfamate 8%-10%
Thanomin 2%-5%
Yi Bingchunan 2%
All the other are moisture
PH value=7
The present invention has following characteristics:
1, do not adopt the compound fire retardants of making of ignition-proof element such as conventional phosphorus, nitrogen, boron, but adopt the amido series material.
2, the article of treated mistake can not be lighted, and go up gasoline even sprinkle, and also can not form fire, can prevent to block spreading of flame effectively.
3, the article of treated mistake can keep original state, color, character, crystallization not, not yellowing, not pulpboard.
4, product all is neutral, does not corrode the article free from extraneous odour of treated mistake.
5, to have the function that penetrates in the man-made fiber effective for a long time for wash-resistant product.
6, using method is easy, and is various, can spray, brushes, soak, also can be according to the needs of different varieties, and directly be injected in the original masterbatch or implement to soak a pressing and rolling process in process of production, for the user provides sufficient choice and convenient.
Universal combustion suppressing agent has of many uses, is applicable to absorbent materials such as paper, various textiless, and not yellowing, does not lose colour, and pulpboard does not keep characteristics such as original pliability, and timber-work ends burner and is equipped with the not effect of crystallization.
The combustion suppressing agent of additional function, except that having better uninflammability, other has increased sterilization, sterilization or multinomial function antistatic, washing.
Claims (6)
1, a kind of combustion suppressing agent is characterized in that: its composition is by ammonium phosphate, Ammonium sulfamate, thanomin and solvent composition.
2, combustion suppressing agent according to claim 1, its component content is as follows:
Ammonium phosphate 10%-20%
Ammonium sulfamate 8%-15%
Thanomin 2%-5%
All the other are moisture
3, combustion suppressing agent according to claim 1 and 2, its component content is as follows:
Ammonium phosphate 10%-15%
Ammonium sulfamate 8%-10%
Thanomin 2%-5%
All the other are moisture
4, combustion suppressing agent according to claim 1 and 2, its component content is as follows:
Ammonium phosphate 10%-20%
Ammonium sulfamate 10%-15%
Thanomin 2%-5%
All the other are moisture
5, combustion suppressing agent according to claim 1 and 2, its component content is as follows:
Ammonium phosphate 10%-15%
Ammonium sulfamate 8%-10%
Thanomin 2%-5%
Spermaceti alkyl brometo de amonio 2%
All the other are moisture
6, combustion suppressing agent according to claim 1 and 2, its component content is as follows:
Ammonium phosphate 10%-15%
Ammonium sulfamate 8%-10%
Thanomin 2%-5%
Yi Bingchunan 2%
All the other are moisture
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96109528A CN1082537C (en) | 1996-08-26 | 1996-08-26 | Flame-retarded agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96109528A CN1082537C (en) | 1996-08-26 | 1996-08-26 | Flame-retarded agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1174863A true CN1174863A (en) | 1998-03-04 |
| CN1082537C CN1082537C (en) | 2002-04-10 |
Family
ID=5120410
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96109528A Expired - Fee Related CN1082537C (en) | 1996-08-26 | 1996-08-26 | Flame-retarded agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1082537C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102120896A (en) * | 2011-01-14 | 2011-07-13 | 吴波 | Multifunctional water-based paint and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1101930A (en) * | 1993-10-16 | 1995-04-26 | 罗运 | Flame-retardant composition |
| CN1114332A (en) * | 1994-07-01 | 1996-01-03 | 中国科学技术大学 | Halogen-free organophosphorous fire retardant, preparing process thereof and use for fire retarding paint |
-
1996
- 1996-08-26 CN CN96109528A patent/CN1082537C/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102120896A (en) * | 2011-01-14 | 2011-07-13 | 吴波 | Multifunctional water-based paint and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1082537C (en) | 2002-04-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: TIANJIN DEVELOPMENT ZONE ANWEI FLAME RETARDANT TE Free format text: FORMER OWNER: WU BO Effective date: 20070713 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |