CN117447092A - Glazed glass and photovoltaic module - Google Patents

Glazed glass and photovoltaic module Download PDF

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Publication number
CN117447092A
CN117447092A CN202311798841.7A CN202311798841A CN117447092A CN 117447092 A CN117447092 A CN 117447092A CN 202311798841 A CN202311798841 A CN 202311798841A CN 117447092 A CN117447092 A CN 117447092A
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area
glazed
coating layer
glass
transition
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CN117447092B (en
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范喜燕
张舒
楚海元
王杰
王涛
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Trina Solar Co Ltd
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Trina Solar Co Ltd
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Priority to PCT/CN2024/091350 priority patent/WO2025138517A1/en
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F19/00Integrated devices, or assemblies of multiple devices, comprising at least one photovoltaic cell covered by group H10F10/00, e.g. photovoltaic modules
    • H10F19/80Encapsulations or containers for integrated devices, or assemblies of multiple devices, having photovoltaic cells
    • H10F19/804Materials of encapsulations
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F19/00Integrated devices, or assemblies of multiple devices, comprising at least one photovoltaic cell covered by group H10F10/00, e.g. photovoltaic modules
    • H10F19/80Encapsulations or containers for integrated devices, or assemblies of multiple devices, having photovoltaic cells
    • H10F19/807Double-glass encapsulation, e.g. photovoltaic cells arranged between front and rear glass sheets
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

The invention provides a glazing glass and a photovoltaic module, wherein the glazing glass comprises: a first glass sheet having opposing first and second surfaces, the first surface having a glazed region and a non-glazed region; the coating layer is positioned on the glaze plating area on the first surface, the coating layer comprises a central area and a transition area, the transition area is positioned at a part of the coating layer close to the non-glaze plating area, the central area is positioned at a part of the coating layer far away from the non-glaze plating area, and the stress of the surface of the coating layer positioned at the transition area gradually decreases from the edge close to the non-glaze plating area to the edge close to the central area.

Description

镀釉玻璃和光伏组件Glazed glass and photovoltaic modules

技术领域Technical field

本发明主要涉及光伏领域,尤其涉及一种镀釉玻璃和光伏组件。The present invention mainly relates to the field of photovoltaics, and in particular to a kind of glazed glass and photovoltaic components.

背景技术Background technique

为了提高双玻组件间隙光的利用率,业内通常会在双玻组件的背面玻璃板上设置一层具有较高反射率的镀膜层,然而高反射膜的厚度、成分以及主体材料的热膨胀系数与玻璃板存在差异,这导致钢化过程中玻璃板表面应力在镀釉区与非镀釉区存在较大差异,在使用过程中,技术人员发现在镀釉区与非镀釉区交界处的玻璃较易发生破碎,对其进行研究后技术人员发现:玻璃板表面在镀釉区的应力大小约为40MPa,而在非镀釉区的应力大小则可以达到100MPa,镀釉区与非镀釉区之间的应力急剧变化会导致该位置强度相对薄弱,当受热或遭到冲击时易出现破碎,并且钢化度越高该区域破碎机率越大。In order to improve the utilization of the gap light of double-glass modules, the industry usually sets a coating layer with higher reflectivity on the back glass plate of double-glass modules. However, the thickness and composition of the high-reflective film and the thermal expansion coefficient of the main material are different from There are differences in the glass plate, which leads to a large difference in the surface stress of the glass plate between the glazed area and the non-glazed area during the tempering process. During use, the technician found that the glass at the junction of the glazed area and the non-glazed area was relatively large. It is prone to breakage. After studying it, technicians found that the stress on the surface of the glass plate in the glazed area is about 40MPa, while the stress in the non-glazed area can reach 100MPa. Between the glazed area and the non-glazed area The sharp change in stress between the two parts will cause the strength of this location to be relatively weak, and it is prone to breakage when heated or impacted. The higher the degree of tempering, the greater the chance of breakage in this area.

发明内容Contents of the invention

本发明要解决的技术问题是提供一种保证钢化度高且表面应力不发生骤变的镀釉玻璃和光伏组件。The technical problem to be solved by the present invention is to provide a glazed glass and photovoltaic module that ensures a high degree of tempering and prevents sudden changes in surface stress.

为解决上述技术问题,本发明提供了一种镀釉玻璃,包括:第一玻璃板,第一玻璃板具有相对的第一表面和第二表面,第一表面具有镀釉区和非镀釉区;镀膜层,位于第一表面上的镀釉区上,镀膜层包括中心区和过渡区,过渡区位于镀膜层靠近非镀釉区的部分,中心区位于镀膜层远离非镀釉区的部分,并且镀膜层位于过渡区的表面的应力从靠近非镀釉区的边缘向靠近中心区的边缘逐渐减小。In order to solve the above technical problems, the present invention provides a kind of glazed glass, which includes: a first glass plate, the first glass plate has an opposite first surface and a second surface, and the first surface has a glazed area and a non-glazed area. ; The coating layer is located on the glazed area on the first surface, the coating layer includes a central area and a transition area, the transition area is located at the part of the coating layer close to the non-glazed area, and the central area is located at the part of the coating layer away from the non-glazed area, And the stress on the surface of the coating layer located in the transition zone gradually decreases from the edge close to the non-glazed zone to the edge close to the central zone.

在本发明的一实施例中,镀膜层在中心区沿第一玻璃板的法线方向的厚度是均匀的;镀膜层在过渡区沿法线方向的厚度在由中心区逐渐靠向非镀釉区的方向上呈下降趋势。In one embodiment of the present invention, the thickness of the coating layer in the central area along the normal direction of the first glass plate is uniform; the thickness of the coating layer in the transition area along the normal direction gradually approaches the non-glazed area from the central area. There is a downward trend in the direction of the area.

在本发明的一实施例中,镀膜层在过渡区中具有多个镂空部,多个镂空部的大小在由中心区逐渐靠向非镀釉区的方向上呈增大趋势。In one embodiment of the present invention, the coating layer has a plurality of hollow portions in the transition area, and the sizes of the plurality of hollow portions tend to increase in a direction from the central area to the non-glazed area.

在本发明的一实施例中,多个镂空部包括与过渡区远离中心区的边缘平行的多排镂空部集合,每排镂空部集合中的多个镂空部具有相同的大小,多排镂空部集合中的多个镂空部的大小在由中心区逐渐靠向非镀釉区的方向上呈增大趋势。In an embodiment of the present invention, the plurality of hollow portions include a plurality of rows of hollow portion sets parallel to the edge of the transition zone away from the central region, the plurality of hollow portions in each row of hollow portion sets have the same size, and the multiple rows of hollow portions The size of the plurality of hollow portions in the collection shows an increasing trend in the direction from the central area to the non-glazed area.

在本发明的一实施例中,镀膜层在过渡区中具有多个镂空部,多个镂空部的分布密度在由中心区逐渐靠向非镀釉区的方向上呈增大趋势。In one embodiment of the present invention, the coating layer has a plurality of hollow portions in the transition zone, and the distribution density of the plurality of hollow portions shows an increasing trend in the direction from the central area to the non-glazed area.

在本发明的一实施例中,镂空部的形状包括半圆形、圆形、矩形、三角形、齿状和条状中的一种或多种。In an embodiment of the present invention, the shape of the hollow portion includes one or more of semicircle, circle, rectangle, triangle, tooth shape and strip shape.

在本发明的一实施例中,镀釉区和镀膜层为网格状,非镀釉区为矩形。In one embodiment of the present invention, the glazed area and the coating layer are in a grid shape, and the non-glazed area is in a rectangular shape.

本发明还提供了一种光伏组件,包括:如前任一实施例的镀釉玻璃;第二玻璃板,第二玻璃板的表面不镀釉;以及电池片,电池片位于镀釉玻璃和第二玻璃板之间,且电池片与镀釉玻璃的第二表面接触。The present invention also provides a photovoltaic module, including: the glazed glass as in the previous embodiment; a second glass plate, the surface of the second glass plate is not glazed; and a battery sheet, the battery sheet is located between the glazed glass and the second between the glass plates, and the battery piece is in contact with the second surface of the glazed glass.

在本发明的一实施例中,镀釉玻璃位于电池片的背光面。In one embodiment of the present invention, the glazed glass is located on the backlight surface of the battery piece.

在本发明的一实施例中,电池片的边缘位于中心区的范围内。In an embodiment of the present invention, the edge of the battery sheet is located within the central area.

与现有技术相比,本发明提供的一种镀釉玻璃和光伏组件中玻璃板表面的镀膜层具有过渡部,通过在过渡部设置厚度渐变的镀膜或者设置大小、密度渐变的镂空使得该区域内镀釉玻璃表面的应力从靠近非镀釉区的边缘向靠近中心区的边缘逐渐减小,不会发生突变,增大了强度,降低了破损的风险。Compared with the prior art, the invention provides a kind of glazed glass and the coating layer on the surface of the glass plate in the photovoltaic module has a transition part. By arranging a coating with a gradient in thickness or a hollow with a gradient in size and density at the transition part, the area is made The stress on the surface of the inner glazed glass gradually decreases from the edge close to the non-glazed area to the edge close to the central area without sudden changes, which increases the strength and reduces the risk of breakage.

附图说明Description of the drawings

包括附图是为提供对本申请进一步的理解,它们被收录并构成本申请的一部分,附图示出了本申请的实施例,并与本说明书一起起到解释本发明原理的作用。附图中:The accompanying drawings are included to provide a further understanding of the present application, and are incorporated in and constitute a part of this application. They illustrate embodiments of the present application and together with the description serve to explain the principles of the present invention. In the attached picture:

图1是本申请一实施例的镀釉玻璃第一表面示意图。Figure 1 is a schematic diagram of the first surface of glazed glass according to an embodiment of the present application.

图2是本申请一实施例的镀釉玻璃第一表面局部示意图。Figure 2 is a partial schematic diagram of the first surface of glazed glass according to an embodiment of the present application.

图3是本申请另一实施例的镀釉玻璃第一表面局部示意图。Figure 3 is a partial schematic diagram of the first surface of glazed glass according to another embodiment of the present application.

图4是本申请一实施例的光伏组件示意图。Figure 4 is a schematic diagram of a photovoltaic module according to an embodiment of the present application.

具体实施方式Detailed ways

为了更清楚地说明本申请的实施例的技术方案,下面将对实施例描述中所需要使用的附图作简单的介绍。显而易见地,下面描述中的附图仅仅是本申请的一些示例或实施例,对于本领域的普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图将本申请应用于其他类似情景。除非从语言环境中显而易见或另做说明,图中相同标号代表相同结构或操作。In order to explain the technical solutions of the embodiments of the present application more clearly, the following will briefly introduce the drawings needed to describe the embodiments. Obviously, the drawings in the following description are only some examples or embodiments of the present application. For those of ordinary skill in the art, without exerting creative efforts, the present application can also be applied according to these drawings. Other similar scenarios. Unless obvious from the locale or otherwise stated, the same reference numbers in the figures represent the same structure or operation.

如本申请和权利要求书中所示,除非上下文明确提示例外情形,“一”、“一个”、“一种”和/或“该”等词并非特指单数,也可包括复数。一般说来,术语“包括”与“包含”仅提示包括已明确标识的步骤和元素,而这些步骤和元素不构成一个排它性的罗列,方法或者设备也可能包含其他的步骤或元素。As shown in this application and claims, words such as "a", "an", "an" and/or "the" do not specifically refer to the singular and may include the plural unless the context clearly indicates an exception. Generally speaking, the terms "comprising" and "comprising" only imply the inclusion of clearly identified steps and elements, and these steps and elements do not constitute an exclusive list. The method or apparatus may also include other steps or elements.

除非另外具体说明,否则在这些实施例中阐述的部件和步骤的相对布置、数字表达式和数值不限制本申请的范围。同时,应当明白,为了便于描述,附图中所示出的各个部分的尺寸并不是按照实际的比例关系绘制的。对于相关领域普通技术人员已知的技术、方法和设备可能不作详细讨论,但在适当情况下,所述技术、方法和设备应当被视为授权说明书的一部分。在这里示出和讨论的所有示例中,任何具体值应被解释为仅仅是示例性的,而不是作为限制。因此,示例性实施例的其它示例可以具有不同的值。应注意到:相似的标号和字母在下面的附图中表示类似项,因此,一旦某一项在一个附图中被定义,则在随后的附图中不需要对其进行进一步讨论。The relative arrangement of components and steps, numerical expressions, and numerical values set forth in these examples do not limit the scope of the application unless specifically stated otherwise. At the same time, it should be understood that, for convenience of description, the dimensions of various parts shown in the drawings are not drawn according to actual proportional relationships. Techniques, methods and devices known to those of ordinary skill in the relevant art may not be discussed in detail, but where appropriate, such techniques, methods and devices should be considered part of the authorized specification. In all examples shown and discussed herein, any specific values are to be construed as illustrative only and not as limiting. Accordingly, other examples of the exemplary embodiments may have different values. It should be noted that similar reference numerals and letters refer to similar items in the following figures, so that once an item is defined in one figure, it does not need further discussion in subsequent figures.

在本申请的描述中,需要理解的是,方位词如“前、后、上、下、左、右”、“横向、竖向、垂直、水平”和“顶、底”等所指示的方位或位置关系通常是基于附图所示的方位或位置关系,仅是为了便于描述本申请和简化描述,在未作相反说明的情况下,这些方位词并不指示和暗示所指的装置或元件必须具有特定的方位或者以特定的方位构造和操作,因此不能理解为对本申请保护范围的限制;方位词“内、外”是指相对于各部件本身的轮廓的内外。In the description of this application, it should be understood that the orientation indicated by directional words such as "front, back, up, down, left, right", "horizontal, vertical, vertical, horizontal" and "top, bottom", etc. Or the positional relationship is usually based on the orientation or positional relationship shown in the drawings, which are only for the convenience of describing the present application and simplifying the description. Without explanation to the contrary, these directional words do not indicate and imply the referred devices or components. It must have a specific orientation or be constructed and operated in a specific orientation, so it cannot be understood as limiting the scope of the present application; the orientation words "inside and outside" refer to the inside and outside relative to the outline of each component itself.

为了便于描述,在这里可以使用空间相对术语,如“在……之上”、“在……上方”、“在……上表面”、“上面的”等,用来描述如在图中所示的一个器件或特征与其他器件或特征的空间位置关系。应当理解的是,空间相对术语旨在包含除了器件在图中所描述的方位之外的在使用或操作中的不同方位。例如,如果附图中的器件被倒置,则描述为“在其他器件或构造上方”或“在其他器件或构造之上”的器件之后将被定位为“在其他器件或构造下方”或“在其他器件或构造之下”。因而,示例性术语“在……上方”可以包括“在……上方”和“在……下方”两种方位。该器件也可以其他不同方式定位(旋转90度或处于其他方位),并且对这里所使用的空间相对描述作出相应解释。For the convenience of description, spatially relative terms can be used here, such as "on...", "on...", "on the upper surface of...", "above", etc., to describe what is shown in the figure. The spatial relationship between one device or feature and other devices or features. It will be understood that the spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. For example, if a feature in the figure is turned upside down, then one feature described as "above" or "on top of" other features or features would then be oriented "below" or "below" the other features or features. under other devices or structures". Thus, the exemplary term "over" may include both orientations "above" and "below." The device may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein interpreted accordingly.

此外,需要说明的是,使用“第一”、“第二”等词语来限定零部件,仅仅是为了便于对相应零部件进行区别,如没有另行声明,上述词语并没有特殊含义,因此不能理解为对本申请保护范围的限制。此外,尽管本申请中所使用的术语是从公知公用的术语中选择的,但是本申请说明书中所提及的一些术语可能是申请人按他或她的判断来选择的,其详细含义在本文的描述的相关部分中说明。此外,要求不仅仅通过所使用的实际术语,而是还要通过每个术语所蕴含的意义来理解本申请。In addition, it should be noted that the use of words such as "first" and "second" to define parts is only to facilitate the distinction between corresponding parts. Unless otherwise stated, the above words have no special meaning and therefore cannot be understood. To limit the scope of protection of this application. In addition, although the terms used in this application are selected from well-known and commonly used terms, some terms mentioned in the specification of this application may be selected by the applicant based on his or her judgment, and their detailed meanings are set out herein. stated in the relevant section of the description. Furthermore, the application is required to be understood not merely by the actual terms used, but also by the meaning connoted by each term.

图1是本申请一实施例的镀釉玻璃第一表面示意图,图2是本申请一实施例的镀釉玻璃第一表面局部示意图。结合参考图1-2所示,本申请提供了一种镀釉玻璃10,包括第一玻璃板100和镀膜层200,其中第一玻璃板100具有第一表面和第二表面,图1所示为镀釉玻璃10的第一表面。具体的,第一玻璃板100的第一表面具有镀釉区110和非镀釉区120,镀膜层200仅位于镀釉区110上,且镀膜层200进一步包括中心区210和过渡区220,中心区210位于镀膜层200远离非镀釉区120的部分,过渡区220位于镀膜层200靠近非镀釉区120的部分,且镀膜层220位于过渡区220的表面的应力从靠近非镀釉区120的边缘向靠近中心区210的边缘逐渐减小。FIG. 1 is a schematic diagram of the first surface of the glazed glass according to one embodiment of the present application. FIG. 2 is a partial schematic diagram of the first surface of the glazed glass according to one embodiment of the present application. With reference to Figures 1-2, the present application provides a glazed glass 10, including a first glass plate 100 and a coating layer 200, wherein the first glass plate 100 has a first surface and a second surface, as shown in Figure 1 It is the first surface of the glazed glass 10 . Specifically, the first surface of the first glass plate 100 has a glazed area 110 and a non-glazed area 120. The coating layer 200 is only located on the glazed area 110, and the coating layer 200 further includes a central area 210 and a transition area 220. The region 210 is located at a part of the coating layer 200 away from the non-glazed region 120 , the transition region 220 is located at a part of the coating layer 200 close to the non-glazed region 120 , and the stress on the surface of the coating layer 220 located at the transition region 220 changes from the region close to the non-glazed region 120 The edges gradually decrease toward the edge closer to the central area 210 .

可以理解的是,本发明旨在解决镀釉区与非镀釉区之间应力急剧变化的问题,并基于该目的将镀膜层200划分为中心区210和过渡区220,应力在过渡区220内平稳变化而非突变。在实际应用中,镀膜层200具有多种形状,无论何种情况,本发明所提供的一种镀釉玻璃10都保证中心区210不直接紧邻非镀釉区120,即二者之间设置有过渡区220。It can be understood that the present invention aims to solve the problem of sharp changes in stress between the glazed area and the non-glazed area, and based on this purpose, the coating layer 200 is divided into a central area 210 and a transition area 220 , and the stress is in the transition area 220 Smooth changes rather than sudden changes. In practical applications, the coating layer 200 has various shapes. In any case, the glazed glass 10 provided by the present invention ensures that the central area 210 is not directly adjacent to the non-glazed area 120, that is, there is a gap between the two. Transition zone 220.

图2示出了图1所示P区域内的局部具体特征,在如图1-2所示实施例中,镀釉区110和镀膜层200为网格状,非镀釉区120为矩形,这种情况下镀釉区110呈直线型,且部分位置存在折角(如图2所示),此时过渡区220位于中心区210的两侧,使得中心区210不直接接触非镀釉区120。Figure 2 shows the local specific features in the P area shown in Figure 1. In the embodiment shown in Figures 1-2, the glazed area 110 and the coating layer 200 are grid-shaped, and the non-glazed area 120 is rectangular. In this case, the glazed area 110 is linear, and there are corners in some locations (as shown in Figure 2). At this time, the transition areas 220 are located on both sides of the central area 210, so that the central area 210 does not directly contact the non-glazed area 120. .

以图2所示沿AA’方向延伸的镀釉区110的局部为例,此时中心区210沿AA’方向延伸,并且中心区210的左右两侧均具有过渡区220,为方便理解将左右两侧的过渡区220分别命名为220a和220b。具体的,镀釉玻璃10表面的应力在过渡区220a中从左侧边缘向右侧边缘逐渐减小,在过渡区220b中则从右侧边缘向左侧边缘逐渐减小。Take the part of the glazed area 110 extending along the direction AA' shown in Figure 2 as an example. At this time, the central area 210 extends along the direction AA', and there are transition areas 220 on the left and right sides of the central area 210. For the convenience of understanding, the left and right areas are The transition areas 220 on both sides are named 220a and 220b respectively. Specifically, the stress on the surface of the glazed glass 10 gradually decreases from the left edge to the right edge in the transition area 220a, and gradually decreases from the right edge to the left edge in the transition area 220b.

如图1-2所示为本发明一优选实施例,该实施例中镀膜层200在过渡区220中具有多个为圆形的镂空部221,并且多个镂空部221的大小并不全部是一致的,而是在由中心区210逐渐靠向非镀釉区120的方向上呈增大趋势。同样,以图2所示沿AA’方向延伸的镀釉区110为例,中心区210左侧的过渡区220a中的多个镂空部221的大小在由中心区210向靠近非镀釉区120的方向上(即如图2所示从右向左的方向)呈增大趋势。同样的,中心区210右侧的过渡区220b中的多个镂空部221的大小在由中心区210向靠近非镀釉区120的方向上(即如图2所示从左向右的方向)呈增大趋势。As shown in Figures 1-2, a preferred embodiment of the present invention is shown. In this embodiment, the coating layer 200 has a plurality of circular hollow portions 221 in the transition area 220, and the sizes of the plurality of hollow portions 221 are not all It is consistent, but shows an increasing trend in the direction from the central area 210 to the non-glazed area 120 . Similarly, taking the glazed area 110 extending along the AA' direction as shown in FIG. 2 as an example, the size of the multiple hollow portions 221 in the transition area 220a on the left side of the central area 210 increases from the central area 210 toward the non-glazed area 120 direction (that is, from right to left as shown in Figure 2) shows an increasing trend. Similarly, the size of the plurality of hollow portions 221 in the transition area 220b on the right side of the central area 210 is in the direction from the central area 210 to the non-glazed area 120 (that is, from left to right as shown in Figure 2) Showing an increasing trend.

进一步的,该实施例中过渡区220a的多个镂空部221包括与过渡区220远离中心区210的边缘S1平行的三排镂空部集合,分别命名为230a、240a和250a。镂空部集合230a、240a和250a中均具有多个镂空部221,为方便理解,下文中分别用231a、241 a和251a来表示镂空部集合230a、240a和250a中的镂空部。具体的,每排镂空部集合中的多个镂空部221具有相同的大小,即:镂空部集合230a中的多个镂空部231a大小相同,镂空部集合240a中的多个镂空部241a大小相同,镂空部集合250a中的多个镂空部251a大小相同。更进一步的,三排镂空部集合230a、240a和250a中多个镂空部221的大小在由中心区210逐渐靠向非镀釉区120的方向上呈增大趋势,即镂空部231a、241 a和251a的大小关系为:231a>241a>251a。由于本实施例中,镂空部231a、241 a和251a各自以圆形或半圆形呈现,因此,上述大小关系或可以理解为孔径/直径大小。Further, in this embodiment, the plurality of hollow portions 221 of the transition area 220a include three rows of hollow portion sets parallel to the edge S1 of the transition area 220 away from the central area 210, named 230a, 240a and 250a respectively. Each of the hollow portion sets 230a, 240a and 250a has a plurality of hollow portions 221. For the convenience of understanding, the hollow portions in the hollow portion sets 230a, 240a and 250a are respectively referred to as 231a, 241a and 251a below. Specifically, the multiple hollow portions 221 in each row of the hollow portion set have the same size, that is, the multiple hollow portions 231a in the hollow portion set 230a have the same size, and the multiple hollow portions 241a in the hollow portion set 240a have the same size, The plurality of hollow portions 251a in the hollow portion set 250a have the same size. Furthermore, the size of the multiple hollow portions 221 in the three rows of hollow portion sets 230a, 240a and 250a shows an increasing trend in the direction from the central area 210 to the non-glazed area 120, that is, the hollow portions 231a, 241a The size relationship with 251a is: 231a>241a>251a. Since in this embodiment, the hollow portions 231a, 241a, and 251a each appear in a circular or semicircular shape, the above size relationship may be understood as aperture/diameter size.

同样的,过渡区220b的多个镂空部221包括与过渡区220远离中心区210的边缘S2平行的三排镂空部集合,分别命名为230b、240b和250b。镂空部集合230b、240b和250b中的镂空部分别表示为231b、241 b和251b。镂空部集合230b中的多个镂空部231b大小相同,镂空部集合240b中的多个镂空部241b大小相同,镂空部集合250b中的多个镂空部251b大小相同,并且镂空部231b、241 b和251b的大小关系为:231b>241b>251b。Similarly, the multiple hollow portions 221 of the transition area 220b include three rows of hollow portion sets parallel to the edge S2 of the transition area 220 away from the central area 210, named 230b, 240b and 250b respectively. The hollow parts in the hollow part sets 230b, 240b and 250b are respectively represented as 231b, 241b and 251b. The plurality of hollow portions 231b in the hollow portion set 230b are of the same size, the plurality of hollow portions 241b in the hollow portion set 240b are of the same size, the plurality of hollow portions 251b in the hollow portion set 250b are of the same size, and the hollow portions 231b, 241b and The size relationship of 251b is: 231b>241b>251b.

在玻璃的钢化过程中,镂空部221的冷却速度较其余位置更快,并且镀釉玻璃10在镂空部221位置的表面应力大于其余部分(中心区210以及过渡部220中非镂空的部分),过渡区220靠近边缘位置镂空部221逐步变大,从而可以达到使应力逐步变大的效果。During the tempering process of the glass, the cooling rate of the hollow part 221 is faster than that of the other positions, and the surface stress of the glazed glass 10 at the position of the hollow part 221 is greater than that of the other parts (the central area 210 and the non-hollow parts of the transition part 220). The hollow portion 221 near the edge of the transition zone 220 gradually becomes larger, thereby achieving the effect of gradually increasing the stress.

可以理解的是,在本发明的其他一些实施例中,镂空部集合的排数可以更多或更少(最少两排),镂空部221的形状也可以为半圆形、圆形、矩形、三角形、齿状和条状中的一种或多种,本申请在此不做具体限制。图3是本申请另一实施例的镀釉玻璃第一表面局部示意图,该实施例中镂空部221即为矩形,并且矩形的大小在从中心区210逐渐靠向非镀釉区120(未示出)的方向上呈增大趋势。It can be understood that in other embodiments of the present invention, the number of rows of the hollow portion set can be more or less (at least two rows), and the shape of the hollow portion 221 can also be semicircular, circular, rectangular, One or more of triangular, tooth-shaped and strip-shaped, this application does not specifically limit it here. Figure 3 is a partial schematic diagram of the first surface of glazed glass according to another embodiment of the present application. In this embodiment, the hollow portion 221 is a rectangle, and the size of the rectangle gradually moves from the central area 210 to the non-glazed area 120 (not shown). out) shows an increasing trend.

进一步的,在本发明的其他一些实施例中,过渡区220中的多个镂空部221的大小是一致的,并且多个镂空部221的分布密度在由中心区210逐渐靠向非镀釉区120的方向上呈增大趋势。也就是说越靠近中心区210的位置,镂空部221的数量越少,排布越疏松;越靠近非镀釉区120的位置,镂空部221的数量越多,排布越紧密。这样的方式也可以同样起到应力在排布疏松的位置至排布紧密的位置逐渐变大的效果。Furthermore, in some other embodiments of the present invention, the sizes of the plurality of hollow portions 221 in the transition area 220 are consistent, and the distribution density of the plurality of hollow portions 221 gradually approaches from the central area 210 to the non-glazed area. There is an increasing trend in the direction of 120. That is to say, the closer to the central area 210, the smaller the number of hollow portions 221, and the looser the arrangement; the closer to the non-glazed area 120, the greater the number of hollow portions 221, and the tighter the arrangement. This method can also achieve the same effect of gradually increasing the stress from a loosely arranged position to a tightly arranged position.

更进一步的,在本发明的其他一些实施例中,镀膜层200的过渡区220部分可以不设置镂空部,而是采用令镀膜层200厚度渐变的方式实现应力的渐变。可以理解的是,在涂料材质不变的情况下,镀膜层200的厚度越小,该位置镀釉玻璃10表面的应力越接近非镀釉区120。具体的,镀膜层200在中心区210沿第一玻璃板100的法线方向(如图2所示BB’方向)的厚度是均匀的,镀膜层200在过渡区220沿法线BB’方向的厚度在由中心区210逐渐靠向非镀釉区120的方向上呈下降趋势,也就是说过渡区220中越靠近非镀釉区120的位置镀膜层200的厚度越小。Furthermore, in some other embodiments of the present invention, the transition region 220 part of the coating layer 200 may not be provided with a hollow part, but the gradient of the stress may be achieved by gradually changing the thickness of the coating layer 200 . It can be understood that, when the paint material remains unchanged, the smaller the thickness of the coating layer 200 , the closer the stress on the surface of the glazed glass 10 at this position is to the non-glazed area 120 . Specifically, the thickness of the coating layer 200 in the central area 210 along the normal direction of the first glass plate 100 (the BB' direction as shown in Figure 2) is uniform, and the thickness of the coating layer 200 in the transition area 220 along the normal line BB' direction is The thickness shows a decreasing trend in the direction from the central area 210 to the non-glazed area 120 , that is to say, the thickness of the coating layer 200 is smaller in the transition area 220 as it approaches the non-glazed area 120 .

图4是本申请一实施例的光伏组件示意图。参考图4所示,本发明还提供了一种光伏组件20,包括如前任一实施例的镀釉玻璃10、第二电池片30以及玻璃板(角度原因未示出)。第二玻璃板即为表面不镀釉的普通玻璃板,电池片30位于镀釉玻璃10和第二玻璃板之间,并且与镀釉玻璃10的第一表面,即设置有镀膜层200的表面接触,镀釉玻璃10位于电池片30的背光面,不会影响间隙光的反射。进一步的,在该实施例中电池片30的边缘40位于中心区210的范围内,防止透光。Figure 4 is a schematic diagram of a photovoltaic module according to an embodiment of the present application. Referring to FIG. 4 , the present invention also provides a photovoltaic module 20 , including the glazed glass 10 as in the previous embodiment, a second cell piece 30 and a glass plate (the angle is not shown). The second glass plate is an ordinary glass plate with an unglazed surface. The battery piece 30 is located between the glazed glass 10 and the second glass plate, and is in contact with the first surface of the glazed glass 10 , that is, the surface on which the coating layer 200 is provided. In contact, the glazed glass 10 is located on the backlight surface of the cell piece 30 and will not affect the reflection of the gap light. Furthermore, in this embodiment, the edge 40 of the cell sheet 30 is located within the central area 210 to prevent light transmission.

上文已对基本概念做了描述,显然,对于本领域技术人员来说,上述发明披露仅仅作为示例,而并不构成对本申请的限定。虽然此处并没有明确说明,本领域技术人员可能会对本申请进行各种修改、改进和修正。该类修改、改进和修正在本申请中被建议,所以该类修改、改进、修正仍属于本申请示范实施例的精神和范围。The basic concepts have been described above. It is obvious to those skilled in the art that the above disclosure of the invention is only used as an example and does not constitute a limitation of the present application. Although not explicitly stated herein, those skilled in the art may make various modifications, improvements, and corrections to this application. Such modifications, improvements and corrections are suggested in this application, so such modifications, improvements and corrections still fall within the spirit and scope of the exemplary embodiments of this application.

同时,本申请使用了特定词语来描述本申请的实施例。如“一个实施例”、“一实施例”、和/或“一些实施例”意指与本申请至少一个实施例相关的某一特征、结构或特点。因此,应强调并注意的是,本说明书中在不同位置两次或多次提及的“一实施例”或“一个实施例”或“一替代性实施例”并不一定是指同一实施例。此外,本申请的一个或多个实施例中的某些特征、结构或特点可以进行适当的组合。At the same time, this application uses specific words to describe the embodiments of the application. For example, "one embodiment", "an embodiment", and/or "some embodiments" means a certain feature, structure or characteristic related to at least one embodiment of the present application. Therefore, it should be emphasized and noted that “one embodiment” or “an embodiment” or “an alternative embodiment” mentioned twice or more at different places in this specification does not necessarily refer to the same embodiment. . In addition, certain features, structures or characteristics in one or more embodiments of the present application may be appropriately combined.

同理,应当注意的是,为了简化本申请披露的表述,从而帮助对一个或多个发明实施例的理解,前文对本申请实施例的描述中,有时会将多种特征归并至一个实施例、附图或对其的描述中。但是,这种披露方法并不意味着本申请对象所需要的特征比权利要求中提及的特征多。实际上,实施例的特征要少于上述披露的单个实施例的全部特征。Similarly, it should be noted that in order to simplify the presentation of the disclosure of the present application and thereby facilitate understanding of one or more embodiments of the invention, in the foregoing description of the embodiments of the present application, multiple features are sometimes combined into one embodiment. accompanying drawings or descriptions thereof. However, this method of disclosure does not imply that the subject matter of the application requires more features than are mentioned in the claims. In fact, embodiments may have less than all features of a single disclosed embodiment.

一些实施例中使用了描述成分、属性数量的数字,应当理解的是,此类用于实施例描述的数字,在一些示例中使用了修饰词“大约”、“近似”或“大体上”来修饰。除非另外说明,“大约”、“近似”或“大体上”表明所述数字允许有±20%的变化。相应地,在一些实施例中,说明书和权利要求中使用的数值参数均为近似值,该近似值根据个别实施例所需特点可以发生改变。在一些实施例中,数值参数应考虑规定的有效数位并采用一般位数保留的方法。尽管本申请一些实施例中用于确认其范围广度的数值域和参数为近似值,在具体实施例中,此类数值的设定在可行范围内尽可能精确。In some embodiments, numbers are used to describe the quantities of components and properties. It should be understood that such numbers used to describe the embodiments are modified by the modifiers "about", "approximately" or "substantially" in some examples. Grooming. Unless otherwise stated, "about," "approximately," or "substantially" means that the stated number is allowed to vary by ±20%. Accordingly, in some embodiments, the numerical parameters used in the specification and claims are approximations that may vary depending on the desired features of the individual embodiment. In some embodiments, numerical parameters should account for the specified number of significant digits and use general digit preservation methods. Although the numerical ranges and parameters used to confirm the breadth of the ranges in some embodiments of the present application are approximations, in specific embodiments, such numerical values are set as accurately as feasible.

虽然本申请已参照当前的具体实施例来描述,但是本技术领域中的普通技术人员应当认识到,以上的实施例仅是用来说明本申请,在没有脱离本申请精神的情况下还可作出各种等效的变化或替换,因此,只要在本申请的实质精神范围内对上述实施例的变化、变型都将落在本申请的权利要求书的范围内。Although the present application has been described with reference to the current specific embodiments, those of ordinary skill in the art should realize that the above embodiments are only used to illustrate the present application, and may also be made without departing from the spirit of the present application. Various equivalent changes or substitutions are made. Therefore, as long as the changes and modifications to the above-described embodiments are within the scope of the essential spirit of the present application, they will fall within the scope of the claims of the present application.

Claims (10)

1.一种镀釉玻璃,其特征在于,包括:1. A kind of glazed glass, characterized in that it includes: 第一玻璃板,所述第一玻璃板具有相对的第一表面和第二表面,所述第一表面具有镀釉区和非镀釉区;A first glass plate having opposite first and second surfaces, the first surface having a glazed area and a non-glazed area; 镀膜层,位于所述第一表面上的所述镀釉区上,所述镀膜层包括中心区和过渡区,所述过渡区位于所述镀膜层靠近所述非镀釉区的部分,所述中心区位于所述镀膜层远离所述非镀釉区的部分,并且所述镀膜层位于所述过渡区的表面的应力从靠近所述非镀釉区的边缘向靠近所述中心区的边缘逐渐减小。a coating layer located on the glazed area on the first surface; the coating layer includes a central area and a transition area; the transition area is located at a portion of the coating layer close to the non-glazed area; The central area is located in the part of the coating layer away from the non-glazed area, and the stress on the surface of the coating layer located in the transition area gradually increases from the edge close to the non-glazed area to the edge close to the central area. decrease. 2.如权利要求1所述的镀釉玻璃,其特征在于:2. The glazed glass as claimed in claim 1, characterized in that: 所述镀膜层在所述中心区沿所述第一玻璃板的法线方向的厚度是均匀的;The thickness of the coating layer in the central area along the normal direction of the first glass plate is uniform; 所述镀膜层在所述过渡区沿所述法线方向的厚度在由所述中心区逐渐靠向所述非镀釉区的方向上呈下降趋势。The thickness of the coating layer in the transition area along the normal direction shows a decreasing trend in the direction from the central area to the non-glazed area. 3.如权利要求1所述的镀釉玻璃,其特征在于,所述镀膜层在所述过渡区中具有多个镂空部,所述多个镂空部的大小在由所述中心区逐渐靠向所述非镀釉区的方向上呈增大趋势。3. The glazed glass according to claim 1, characterized in that the coating layer has a plurality of hollow parts in the transition zone, and the sizes of the plurality of hollow parts gradually approach from the central zone to the The direction of the non-glazed area shows an increasing trend. 4.如权利要求3所述的镀釉玻璃,其特征在于,所述多个镂空部包括与所述过渡区远离所述中心区的边缘平行的多排镂空部集合,每排所述镂空部集合中的多个镂空部具有相同的大小,所述多排镂空部集合中的所述多个镂空部的大小在由所述中心区逐渐靠向所述非镀釉区的方向上呈增大趋势。4. The glazed glass according to claim 3, wherein the plurality of hollow parts comprise a set of multiple rows of hollow parts parallel to the edge of the transition zone away from the central zone, and each row of hollow parts The plurality of hollow portions in the set have the same size, and the sizes of the plurality of hollow portions in the plurality of rows of hollow portions increase in a direction gradually approaching the non-glazed area from the central area. trend. 5.如权利要求1所述的镀釉玻璃,其特征在于,所述镀膜层在所述过渡区中具有多个镂空部,所述多个镂空部的分布密度在由所述中心区逐渐靠向所述非镀釉区的方向上呈增大趋势。5. The glazed glass according to claim 1, wherein the coating layer has a plurality of hollow parts in the transition zone, and the distribution density of the plurality of hollow parts gradually increases from the central zone to the There is an increasing trend toward the non-glazed area. 6.如权利要求3-5任一项所述的镀釉玻璃,其特征在于,所述镂空部的形状包括半圆形、圆形、矩形、三角形、齿状和条状中的一种或多种。6. The glazed glass according to any one of claims 3 to 5, wherein the shape of the hollow portion includes one of semicircle, circle, rectangle, triangle, tooth shape and strip shape or Various. 7.如权利要求1~5任一项所述的镀釉玻璃,其特征在于,所述镀釉区和所述镀膜层为网格状,所述非镀釉区为矩形。7. The glazed glass according to any one of claims 1 to 5, wherein the glazed area and the coating layer are in a grid shape, and the non-glazed area is in a rectangular shape. 8.一种光伏组件,其特征在于,包括:8. A photovoltaic module, characterized by comprising: 如权利要求1-7任一项所述的镀釉玻璃;The glazed glass according to any one of claims 1 to 7; 第二玻璃板,所述第二玻璃板的表面不镀釉;以及a second glass plate, the surface of the second glass plate being unglazed; and 电池片,所述电池片位于所述镀釉玻璃和所述第二玻璃板之间,且所述电池片与所述镀釉玻璃的所述第二表面接触。The battery sheet is located between the glazed glass and the second glass plate, and the battery sheet is in contact with the second surface of the glazed glass. 9.如权利要求8所述的光伏组件,其特征在于,所述镀釉玻璃位于所述电池片的背光面。9. The photovoltaic module according to claim 8, wherein the glazed glass is located on the backlight surface of the cell sheet. 10.如权利要求9所述的光伏组件,其特征在于,所述电池片的边缘位于所述中心区的范围内。10. The photovoltaic module according to claim 9, wherein the edge of the cell sheet is located within the range of the central area.
CN202311798841.7A 2023-12-26 2023-12-26 Glazed glass and photovoltaic module Active CN117447092B (en)

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CN208753346U (en) * 2018-09-05 2019-04-16 浙江宝利特新能源股份有限公司 A kind of anti-dazzle all black BIPV component
CN217025794U (en) * 2021-12-21 2022-07-22 天合光能股份有限公司 A grid glass and photovoltaic module
CN217158197U (en) * 2022-02-24 2022-08-09 泰州隆基乐叶光伏科技有限公司 Coated glass of dual glass assembly and dual glass assembly
CN115140950A (en) * 2022-09-05 2022-10-04 山东中清智能科技股份有限公司 Glass for photoelectric module and preparation method thereof
CN219642848U (en) * 2023-03-27 2023-09-05 江苏海博瑞光伏科技有限公司 Photovoltaic high-reflection black grid glass and photovoltaic cell panel

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN208753346U (en) * 2018-09-05 2019-04-16 浙江宝利特新能源股份有限公司 A kind of anti-dazzle all black BIPV component
CN217025794U (en) * 2021-12-21 2022-07-22 天合光能股份有限公司 A grid glass and photovoltaic module
CN217158197U (en) * 2022-02-24 2022-08-09 泰州隆基乐叶光伏科技有限公司 Coated glass of dual glass assembly and dual glass assembly
CN115140950A (en) * 2022-09-05 2022-10-04 山东中清智能科技股份有限公司 Glass for photoelectric module and preparation method thereof
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