CN117383747A - High-concentration chemical wastewater treatment method - Google Patents

High-concentration chemical wastewater treatment method Download PDF

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Publication number
CN117383747A
CN117383747A CN202311449275.9A CN202311449275A CN117383747A CN 117383747 A CN117383747 A CN 117383747A CN 202311449275 A CN202311449275 A CN 202311449275A CN 117383747 A CN117383747 A CN 117383747A
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China
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water
sewage
treatment
micro
reservoir
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CN202311449275.9A
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Chinese (zh)
Inventor
张雷
傅生元
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Suqian Leili Environmental Protection Technology Co ltd
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Suqian Leili Environmental Protection Technology Co ltd
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Priority to CN202311449275.9A priority Critical patent/CN117383747A/en
Publication of CN117383747A publication Critical patent/CN117383747A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46176Galvanic cells
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5281Installations for water purification using chemical agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/34Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions

Abstract

The invention discloses a high-concentration chemical wastewater treatment method, which comprises the following steps: step S01: filtering and removing impurities, and performing a step S02: natural sedimentation, step S03: high-efficiency oxidation, step S04: micro-electrolysis, step S05: sedimentation treatment, step S06: and (5) sand filtering. The beneficial effects of the invention are as follows: the chemical sewage treatment method provided by the invention has the advantages of simple process steps, low cost and easy operation realization, can be suitable for treating and purifying sewage with high turbidity, is suitable for treating and purifying large-batch chemical sewage, ensures the water treatment effect under the conditions of low energy consumption and low cost, further avoids the damage and pollution of the chemical sewage to the environment, and is suitable for popularization and use.

Description

High-concentration chemical wastewater treatment method
Technical Field
The invention relates to the technical field of sewage treatment, in particular to a high-concentration chemical sewage treatment method.
Background
In recent years, with the rapid development of industries such as chemical fertilizers, smelting, pharmacy, petroleum industry and the like, a large amount of high-concentration industrial sewage is generated, if the sewage is discharged into a water body, the damage of hypoxia, eutrophication and the like of the water body can be caused, the self-cleaning capability of the water body is reduced, and the living environment of fishes and other organisms in the water and seriously harm human beings is damaged.
At present, the common treatment methods for high-concentration chemical wastewater in the prior art comprise an ozone oxidation method and a chlorine oxidation method, and the water treatment has good effect, but has large energy consumption and high cost, is not suitable for treating large-batch chemical wastewater, is difficult to meet the normal wastewater treatment requirement, and needs to be further developed and improved.
Disclosure of Invention
The invention aims to solve the problems that the common treatment methods for high-concentration chemical wastewater in the prior art comprise an ozone oxidation method and a chlorine oxidation method, and the water treatment is high in energy consumption and high in cost, is not suitable for treating large-batch chemical wastewater and is difficult to meet the normal wastewater treatment requirement, and provides the high-concentration chemical wastewater treatment method.
The invention realizes the above purpose through the following technical scheme: a high-concentration chemical wastewater treatment method comprises the following steps:
step S01: filtering and removing impurities, discharging the wastewater into a reservoir, and arranging a filter screen provided with an electromagnet at the inlet of the reservoir, wherein impurities and sundries with metal can be adsorbed when larger impurities and foreign matters in the wastewater are intercepted;
step S02: naturally settling, standing the sewage entering the reservoir for 1-2h, settling most of solid particles in the sewage at the bottom of the reservoir, and then pumping away the water above the sediment to obtain the water after primary settlement separation;
step S03: high-efficiency oxidation, namely sending the water body treated in the step S02 into an oxidation pond, adding a strong oxidant under ultraviolet irradiation, then putting an air pipe into water, carrying out aeration treatment on the water body in the oxidation pond for 10-20min, and then standing in the oxidation pond for 0.5-1 h to obtain oxidized water;
step S04: d, micro-electrolysis, namely sending the water treated in the step S03 into an electrolytic cell, generating current flow in the water through a cathode electrode and an anode electrode to enable colloid particles and micro-dispersed pollutants in the sewage to be adsorbed to the electrodes, and then separating the colloid particles and the micro-dispersed pollutants near the electrodes to obtain water after micro-electrolysis;
step S05: sedimentation treatment, namely sending the water treated in the step S04 into a sedimentation tank, adding a flocculating agent, stirring for 5-10min, standing for 0.5-1 h, and separating and discharging flocculated sediment to obtain water subjected to secondary sedimentation treatment;
step S06: and (3) sand filtering, namely sending the water treated in the step (S05) into a sand filtering tank for filtering treatment, and adding a disinfectant into the sand filtering tank to obtain water meeting the discharge standard.
Further, the strong oxidizer in the step S03 is a high-concentration hydrogen peroxide solution, and a catalyst containing ferrous chloride or potassium hydroxide as a main component is also added.
Further, the stirring speed in the step S05 is 30-60r/min.
Further, the flocculant in the step S05 is any one of ferric sulfate or polysilicic acid.
Compared with the prior art, the invention has the beneficial effects that: the chemical sewage treatment method provided by the invention has the advantages of simple process steps, low cost and easy operation realization, can be suitable for treating and purifying sewage with high turbidity, is suitable for treating and purifying large-batch chemical sewage, ensures the water treatment effect under the conditions of low energy consumption and low cost, further avoids the damage and pollution of the chemical sewage to the environment, and is suitable for popularization and use.
Drawings
Fig. 1 is a schematic perspective view of the present invention.
Detailed Description
The following description of the embodiments of the present invention will be made clearly and completely with reference to the accompanying drawings, in which it is apparent that the embodiments described are only some embodiments of the present invention, but not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
The method for treating the high-concentration chemical wastewater shown in the combination of FIG. 1 comprises the following steps:
a high-concentration chemical wastewater treatment method comprises the following steps:
step S01: filtering and removing impurities, discharging the wastewater into a reservoir, and arranging a filter screen provided with an electromagnet at the inlet of the reservoir, wherein impurities and sundries with metal can be adsorbed when larger impurities and foreign matters in the wastewater are intercepted;
step S02: naturally settling, standing the sewage entering the reservoir for 1-2h, settling most of solid particles in the sewage at the bottom of the reservoir, and then pumping away the water above the sediment to obtain the water after primary settlement separation;
step S03: high-efficiency oxidation, namely sending the water body treated in the step S02 into an oxidation pond, adding a strong oxidant under ultraviolet irradiation, then putting an air pipe into water, carrying out aeration treatment on the water body in the oxidation pond for 10-20min, and then standing in the oxidation pond for 0.5-1 h to obtain oxidized water;
step S04: d, micro-electrolysis, namely sending the water treated in the step S03 into an electrolytic cell, generating current flow in the water through a cathode electrode and an anode electrode to enable colloid particles and micro-dispersed pollutants in the sewage to be adsorbed to the electrodes, and then separating the colloid particles and the micro-dispersed pollutants near the electrodes to obtain water after micro-electrolysis;
step S05: sedimentation treatment, namely sending the water treated in the step S04 into a sedimentation tank, adding a flocculating agent, stirring for 5-10min, standing for 0.5-1 h, and separating and discharging flocculated sediment to obtain water subjected to secondary sedimentation treatment;
step S06: and (3) sand filtering, namely sending the water treated in the step (S05) into a sand filtering tank for filtering treatment, and adding a disinfectant into the sand filtering tank to obtain water meeting the discharge standard.
The strong oxidant in the step S03 is a high-concentration hydrogen peroxide solution, and a catalyst with ferrous chloride or potassium hydroxide as a main component is also added; the stirring speed in the step S05 is 30-60r/min; the flocculant in the step S05 is any one of ferric sulfate or polysilicic acid.
The invention is illustrated by the following more specific examples.
Embodiment one:
a high-concentration chemical wastewater treatment method comprises the following steps:
step S01: filtering and removing impurities, discharging the wastewater into a reservoir, and arranging a filter screen provided with an electromagnet at the inlet of the reservoir, wherein impurities and sundries with metal can be adsorbed when larger impurities and foreign matters in the wastewater are intercepted;
step S02: naturally settling, standing the sewage entering the reservoir for 1h, settling most of solid particles in the sewage at the bottom of the reservoir, and then pumping away the water above the sediment to obtain the water after primary settlement separation;
step S03: high-efficiency oxidation, namely sending the water body treated in the step S02 into an oxidation pond, adding a strong oxidant under ultraviolet irradiation, then putting an air pipe into water, carrying out aeration treatment on the water body in the oxidation pond for 10min, and then standing in the oxidation pond for 0.5 h to obtain oxidized water;
step S04: d, micro-electrolysis, namely sending the water treated in the step S03 into an electrolytic cell, generating current flow in the water through a cathode electrode and an anode electrode to enable colloid particles and micro-dispersed pollutants in the sewage to be adsorbed to the electrodes, and then separating the colloid particles and the micro-dispersed pollutants near the electrodes to obtain water after micro-electrolysis;
step S05: sedimentation treatment, namely sending the water treated in the step S04 into a sedimentation tank, adding a flocculating agent, stirring for 5min, standing for 0.5 h, and separating and discharging flocculated sediment to obtain water subjected to secondary sedimentation treatment;
step S06: and (3) sand filtering, namely sending the water treated in the step (S05) into a sand filtering tank for filtering treatment, and adding a disinfectant into the sand filtering tank to obtain water meeting the discharge standard.
The strong oxidant in the step S03 is a high-concentration hydrogen peroxide solution, and a catalyst with ferrous chloride or potassium hydroxide as a main component is also added; the stirring speed in the step S05 is 30r/min; the flocculant in the step S05 is any one of ferric sulfate or polysilicic acid.
Embodiment two:
a high-concentration chemical wastewater treatment method comprises the following steps:
step S01: filtering and removing impurities, discharging the wastewater into a reservoir, and arranging a filter screen provided with an electromagnet at the inlet of the reservoir, wherein impurities and sundries with metal can be adsorbed when larger impurities and foreign matters in the wastewater are intercepted;
step S02: naturally settling, standing the sewage entering the reservoir for 1.5h, settling most of solid particles in the sewage at the bottom of the reservoir, and then pumping away the water above the sediment to obtain the water after primary settlement separation;
step S03: high-efficiency oxidation, namely sending the water body treated in the step S02 into an oxidation pond, adding a strong oxidant under ultraviolet irradiation, then putting an air pipe into water, carrying out aeration treatment on the water body in the oxidation pond for 15min, and then standing in the oxidation pond for 0.8 h to obtain oxidized water;
step S04: d, micro-electrolysis, namely sending the water treated in the step S03 into an electrolytic cell, generating current flow in the water through a cathode electrode and an anode electrode to enable colloid particles and micro-dispersed pollutants in the sewage to be adsorbed to the electrodes, and then separating the colloid particles and the micro-dispersed pollutants near the electrodes to obtain water after micro-electrolysis;
step S05: sedimentation treatment, namely sending the water treated in the step S04 into a sedimentation tank, adding a flocculating agent, stirring for 8min, standing for 0.8 h, and separating and discharging flocculated sediment to obtain water subjected to secondary sedimentation treatment;
step S06: and (3) sand filtering, namely sending the water treated in the step (S05) into a sand filtering tank for filtering treatment, and adding a disinfectant into the sand filtering tank to obtain water meeting the discharge standard.
The strong oxidant in the step S03 is a high-concentration hydrogen peroxide solution, and a catalyst with ferrous chloride or potassium hydroxide as a main component is also added; the stirring speed in the step S05 is 45r/min; the flocculant in the step S05 is any one of ferric sulfate or polysilicic acid.
Embodiment III:
a high-concentration chemical wastewater treatment method comprises the following steps:
step S01: filtering and removing impurities, discharging the wastewater into a reservoir, and arranging a filter screen provided with an electromagnet at the inlet of the reservoir, wherein impurities and sundries with metal can be adsorbed when larger impurities and foreign matters in the wastewater are intercepted;
step S02: naturally settling, standing the sewage entering the reservoir for 2 hours, settling most of solid particles in the sewage at the bottom of the reservoir, and then pumping away the water above the sediment to obtain the water after primary settlement separation;
step S03: high-efficiency oxidation, namely sending the water body treated in the step S02 into an oxidation pond, adding a strong oxidant under ultraviolet irradiation, then putting an air pipe into water, carrying out aeration treatment on the water body in the oxidation pond for 20min, and then standing in the oxidation pond for 1h to obtain oxidized water;
step S04: d, micro-electrolysis, namely sending the water treated in the step S03 into an electrolytic cell, generating current flow in the water through a cathode electrode and an anode electrode to enable colloid particles and micro-dispersed pollutants in the sewage to be adsorbed to the electrodes, and then separating the colloid particles and the micro-dispersed pollutants near the electrodes to obtain water after micro-electrolysis;
step S05: sedimentation treatment, namely sending the water treated in the step S04 into a sedimentation tank, adding a flocculating agent, stirring for 10min, standing for 1 hour, and separating and discharging flocculated sediment to obtain water subjected to secondary sedimentation treatment;
step S06: and (3) sand filtering, namely sending the water treated in the step (S05) into a sand filtering tank for filtering treatment, and adding a disinfectant into the sand filtering tank to obtain water meeting the discharge standard.
The strong oxidant in the step S03 is a high-concentration hydrogen peroxide solution, and a catalyst with ferrous chloride or potassium hydroxide as a main component is also added; the stirring speed in the step S05 is 60r/min; the flocculant in the step S05 is any one of ferric sulfate or polysilicic acid.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential characteristics thereof. The present embodiments are, therefore, to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.
Furthermore, it should be understood that although the present disclosure describes embodiments, not every embodiment is provided with a separate embodiment, and that this description is provided for clarity only, and that the disclosure is not limited to the embodiments described in detail below, and that the embodiments described in the examples may be combined as appropriate to form other embodiments that will be apparent to those skilled in the art.

Claims (4)

1. The high-concentration chemical wastewater treatment method is characterized by comprising the following steps of:
step S01: filtering and removing impurities, discharging the wastewater into a reservoir, and arranging a filter screen provided with an electromagnet at the inlet of the reservoir, wherein impurities and sundries with metal can be adsorbed when larger impurities and foreign matters in the wastewater are intercepted;
step S02: naturally settling, standing the sewage entering the reservoir for 1-2h, settling most of solid particles in the sewage at the bottom of the reservoir, and then pumping away the water above the sediment to obtain the water after primary settlement separation;
step S03: high-efficiency oxidation, namely sending the water body treated in the step S02 into an oxidation pond, adding a strong oxidant under ultraviolet irradiation, then putting an air pipe into water, carrying out aeration treatment on the water body in the oxidation pond for 10-20min, and then standing in the oxidation pond for 0.5-1 h to obtain oxidized water;
step S04: d, micro-electrolysis, namely sending the water treated in the step S03 into an electrolytic cell, generating current flow in the water through a cathode electrode and an anode electrode to enable colloid particles and micro-dispersed pollutants in the sewage to be adsorbed to the electrodes, and then separating the colloid particles and the micro-dispersed pollutants near the electrodes to obtain water after micro-electrolysis;
step S05: sedimentation treatment, namely sending the water treated in the step S04 into a sedimentation tank, adding a flocculating agent, stirring for 5-10min, standing for 0.5-1 h, and separating and discharging flocculated sediment to obtain water subjected to secondary sedimentation treatment;
step S06: and (3) sand filtering, namely sending the water treated in the step (S05) into a sand filtering tank for filtering treatment, and adding a disinfectant into the sand filtering tank to obtain water meeting the discharge standard.
2. The method for treating high-concentration chemical wastewater as claimed in claim 1, wherein the strong oxidizer in the step S03 is a high-concentration hydrogen peroxide solution, and a catalyst containing ferrous chloride or potassium hydroxide as a main component is added.
3. The method for treating high-concentration chemical wastewater as claimed in claim 1, wherein the stirring speed in the step S05 is 30-60r/min.
4. The method for treating high-concentration chemical wastewater as claimed in claim 1, wherein the flocculant in the step S05 is any one of ferric sulfate or polysilicic acid.
CN202311449275.9A 2023-11-02 2023-11-02 High-concentration chemical wastewater treatment method Pending CN117383747A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202311449275.9A CN117383747A (en) 2023-11-02 2023-11-02 High-concentration chemical wastewater treatment method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202311449275.9A CN117383747A (en) 2023-11-02 2023-11-02 High-concentration chemical wastewater treatment method

Publications (1)

Publication Number Publication Date
CN117383747A true CN117383747A (en) 2024-01-12

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Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
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